Claims
- 1. A reagent which is self-regenerating in air, and which, on contact with a reducing gas, oxidizes the gas and is reduced from an oxidized state to a reduced state, the reagent comprising a mixture of a palladium salt, a compound which includes a complex ion of a metal selected from the group consisting of molybdenum, tungsten and vanadium, and a salt of a metal selected from the group consisting of copper, nickel and iron, said salt being present in an amount sufficient to cause the reagent to oxidize from the reduced state caused by contact with the reducing gas to the oxidized state in the presence of air and absence of the reducing gas, and a hydrophilic carrier for the mixture.
- 2. A reagent according to claim 1 in which the mixture is deposited on a carrier containing OH groups.
- 3. A reagent according to claim 1 in which the mixture is deposited on a carrier selected from the group consisting of polymeric alcohols, polyglycols, cellulose, silica, alumina, glass wool, and sponge.
- 4. A reagent according to claim 1 in which the mixture is a solid powder having a particle size which passes through about 50 mesh.
- 5. A reagent for oxidizing a reducing gas comprising a silica gel coated with a mixture of a palladium salt, a molybdate complex, and a salt of a meta selected from the group consisting of copper and nickel.
- 6. A reagent according to claim 5 in which the palladium salt is selected from the group consisting of PdSO.sub.4, Pd.sub.2 Cl, Pd(NO.sub.3).sub.2, palladium acetate, palladium trifluoroacetate and palladium acetylacetonate.
- 7. A reagent according to claim 5 in which the molybdate complex is a silicomolybdate.
- 8. A reagent according to claim 7 in which the silicomolybdate complex is a product of the reaction between silica gel and a material selected from the group consisting of a heteropolyacid of molybdenum, a water-soluble salt of a molybdic acid, a water-soluble salt of a heteropolyacid of molybdenum, a molybdic acid phosphate, and a molybdic acid borate.
- 9. A reagent according to claim 7 in which the silicomolybdate complex is a product of the reaction between silica gel in a mildly acid aqueous suspension and MoCl.sub.5, KMoCl.sub.6 , Li.sub.2 MoO.sub.4, Na.sub.2 MoO.sub.4, K.sub.2 MoO.sub.4, and (NH.sub.4).sub.2 MoO .sub.4.
- 10. A reagent according to claim 5 which includes a salt selected from the group consisting of CuF.sub.2, CuCl.sub.2, CuI.sub.2, CuBr.sub.2, CuSO.sub.4, Cu(NO.sub.3).sub.2, copper formate, copper acetate, copper trifluoroacetate , copper acetylacetonate, and NiCl.sub.2.
- 11. A reagent according to claim 5 which includes a silicomolybdate complex, which is oxidized by atmospheric oxygen to one oxidation state at which it exhibits a characteristic color, and which is reduced by a reducing gas to a lower oxidation state where it has a different color.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of our copending applications Ser. Nos. 491,338 and 491,464 filed July 24, 1974, and both now abandoned.
US Referenced Citations (4)
Non-Patent Literature Citations (2)
Entry |
Shepherd, "Rapid Determination of Small Amounts of Carbon Monoxide," Anal. Chem., vol. 19, (2), 1947, pp. 77-81. |
Chemical Abstracts, "Carbon Monoxide Indication," vol. 56, 1962, p. 3778a. |
Related Publications (1)
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Number |
Date |
Country |
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491464 |
Jul 1974 |
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Continuation in Parts (1)
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Number |
Date |
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491338 |
Jul 1974 |
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