Container structure for removal of vacuum pressure

Information

  • Patent Grant
  • 8152010
  • Patent Number
    8,152,010
  • Date Filed
    Tuesday, September 30, 2003
    21 years ago
  • Date Issued
    Tuesday, April 10, 2012
    12 years ago
Abstract
A hot-fill PET container or bottle (10) for filling with a liquid at an elevated temperature has a side wall (9) extending to a lower portion including a pressure panel (11) and a base (2) in its unfolded or pre fill position. The panel (11) is transversely oriented and has a decoupling or hinge structure (13), an initiator portion (1) and control portion (5) of a steeply angled inverting conical section between 30 and 45 degrees. The control portion enables the inversion of the panel (11) into the container (10) to compensate for vacuum or reduced pressure induced within the container as the liquid cools down. The base (2) can also have a plurality of reinforcing ribs (3).
Description
RELATED APPLICATIONS

This application is related to New Zealand Patent Application, filed on Sep. 30, 2002, Application No. 521694; and International Application No. PCT/NZ2003/000220, filed on Sep. 30, 2003, which are fully incorporated herein by reference, and claims benefit therefrom.


TECHNICAL FIELD OF THE INVENTION

This invention relates generally to a container structure that allows for the removal of vacuum pressure. This is achieved by inverting a transversely oriented vacuum pressure panel located in the lower end-wall, or base region of the container.


BACKGROUND

So called ‘hot fill’ containers are well known in prior art, whereby manufacturers supply PET containers for various liquids which are filled into the containers and the liquid product is at an elevated temperature, typically at or around 85 degrees C. (185 degrees F.).


The container is manufactured to withstand the thermal shock of holding a heated liquid, resulting in a ‘heat-set’ plastic container. This thermal shock is a result of either introducing the liquid hot at filling, or heating the liquid after it is introduced into the container.


Once the liquid cools down in a capped container, however, the volume of the liquid in the container reduces, creating a vacuum within the container. This liquid shrinkage results in vacuum pressures that pull inwardly on the side and end walls of the container. This in turn leads to deformation in the walls of plastic bottles if they are not constructed rigidly enough to resist such force.


Typically, vacuum pressures have been accommodated by the use of vacuum panels, which distort inwardly under vacuum pressure. Prior art reveals many vertically oriented vacuum panels that allow containers to withstand the rigors of a hot fill procedure. Such vertically oriented vacuum panels generally lie parallel to the longitudinal axis of a container and flex inwardly under vacuum pressure toward this longitudinal axis.


In addition to the vertically oriented vacuum panels, many prior art containers also have flexible base regions to provide additional vacuum compensation. Many prior art containers designed for hot-filling have various modifications to their end-walls, or base regions to allow for as much inward flexure as possible to accommodate at least some of the vacuum pressure generated within the container.


All such prior art, however, provides for flat or inwardly inclined, or recessed base surfaces. These have been modified to be susceptible to as much further inward deflection as possible. As the base region yields to the force, it is drawn into a more inclined position than prior to having vacuum force applied.


Unfortunately, however, the force generated under vacuum to pull longitudinally on the base region is only half that force generated in the transverse direction at the same time. Therefore, vertically oriented vacuum panels are able to react to force more easily than a panel placed in the base. Further, there is a lot more surface area available around the circumference of a container than in the end-wall. Therefore, adequate vacuum compensation can only be achieved by placing vertically-oriented vacuum panels over a substantial portion of the circumferential wall area of a container, typically 60% of the available area.


Even with such substantial displacement of vertically-oriented panels, however, the container requires further strengthening to prevent distortion under the vacuum force.


The liquid shrinkage derived from liquid cooling, causes a build up of vacuum pressure. Vacuum panels deflect toward this negative pressure, to a degree lessening the vacuum force, by effectively creating a smaller container to better accommodate the smaller volume of contents. However, this smaller shape is held in place by the generating vacuum force. The more difficult the structure is to defied inwardly, the more vacuum force will be generated. In prior art, a substantial amount of vacuum is still present in the container and this tends to distort the overall shape unless a large, annular strengthening ring is provided in horizontal, or transverse, orientation at least a ⅓ of the distance from an end to the container.


Considering this, it has become accepted knowledge to believe that it is impossible to provide for full vacuum compensation through modification to the end-wall or base region alone. The base region offers very little surface area, compared to the side walls, and reacts to force at half the rate of the side walls.


Therefore it has become accepted practice to only expect partial assistance to the overall vacuum compensation to be generated through the base area. Further, even if the base region could provide for enough flexure to accommodate all liquid shrinkage within the container, there would be a significant vacuum force present, and significant stress on the base standing ring. This would place force on the sidewalls also, and to prevent distortion the smooth sidewalls would have to be much thicker in material distribution, be strengthened by ribbing or the like, or be placed into shapes more compatible to mechanical distortion (for example be square instead of circular).


For this reason it has not been possible to provide container designs in plastic that do not have typical prior art vacuum panels that are vertically oriented on the sidewall. Many manufacturers have therefore been unable to commercialize plastic designs that are the same as their glass bottle designs with smooth sidewalls.


U.S. Pat. No. 6,595,380 (Silvers), claims to provide for full vacuum compensation through the base region without requiring positioning of vertically oriented vacuum panels on the smooth sidewalls. This is suggested by combining techniques well-known and practiced in the prior art. Silvers provides for a slightly inwardly domed, and recessed base region to provide further inward movement under vacuum pressure. However, the technique disclosed, and the stated percentage areas required for efficiency are not considered by the present applicant to provide a viable solution to the problem.


In fact, flexure in the base region is recognised to be greatest in a horizontally flat base region, and maximizing such flat portions on the base has been well practiced and found to be unable to provide enough vacuum compensation to avoid also employing vertically oriented vacuum panels.


Silvers does provide for the base region to be strengthened by coupling it to the standing ring of the container, in order to assist preventing unwanted outward movement of the inwardly inclined or flat portion when a heated liquid builds up initial internal pressure in a newly filled and capped container. This coupling is achieved by rib structures, which also serve to strengthen the flat region. Whilst this may strengthen the region in order to allow more vacuum force to be applied to it, the ribs conversely further reduce flexibility within the base region, and therefore reduce flexibility.


It is believed by the present applicant that the specific ‘ribbed’ method proposed by Silvers could only provide for approximately 35% of the vacuum compensation that is required, as the modified end-wall is not considered capable of sufficient inward flexure to fully account for the liquid shrinkage that would occur. Therefore a strong maintenance of vacuum pressure is expected to occur. Containers employing such base structure therefore still require significant thickening of the sidewalls, and as this is done the base region also becomes thicker during manufacturing. The result is a less flexible base region, which in turn also reduces the efficiency of the vacuum compensation achieved.


The present invention relates to a hot-fill container which is a development of the hot-fill container described in our international application WO 02/18213 (the PCT specification), which specification is incorporated herein in its entirety where appropriate.


The PCT specification backgrounds the design of hot-fill containers and the problems with such designs which were overcome or at least ameliorated by the design disclosed in the PCT specification.


In the PCT specification a semi-rigid container was provided that had a substantially vertically folding vacuum panel portion. Such a transversely oriented vacuum panel portion included an initiator portion and a control portion which generally resisted being expanded from the collapsed state.


Further described in the PCT specification is the inclusion of the vacuum panels at various positions along the container wall.


A problem exists when locating such a panel in the end-wall or base region, whereby stability may be compromised if the panel does not move far enough into the container longitudinally to no longer form part of the container touching the surface the container stands on.


A further problem exists when utilizing a transverse panel in the base end-wall due to the potential for shock deflection of the inverted panel when a full and capped container is dropped. This may occur on a container with soft and unstructured walls that is dropped directly on its side. The shock deflection of the sidewalls causes a shock-wave of internal pressure that acts on the panel. In such cases improved panel configurations are desired that further prevent panel roll-out, or initiator region configurations utilized that optimize for resistance to such reversion displacement.


OBJECTS OF THE INVENTION

In view of the above, it is an object of one preferred embodiment of the present invention to provide a plastic container structure having a transversely oriented pressure panel in its lower portion that can provide for removal of vacuum pressure such that there is substantially no remaining force within the container.


It is a further object of one preferred embodiment of the present invention to provide a container which has a transversely oriented pressure panel that is decoupled to a degree from the adjoining wall such that greater inward and longitudinal movement can be achieved.


It is a further object of one preferred embodiment of the present invention to provide for a container to have a transversely oriented pressure panel that is inwardly displaced to a position above the standing ring of the final container configuration, such that a new base region is formed with a greater standing ring or foot print area, and the pressure panel is substantially protected from top load force applied to the container during commercial distribution.


It is a further object of one preferred embodiment of the present invention to provide for an improved transverses oriented pressure panel having an initiator portion which may utilize essentially the same angle as the control portion, such that greater removal of vacuum pressure can be obtained and such that greater resistance to outward deflection can also be obtained.


A further and alternative object of the present invention in all its embodiments, all the objects to be read disjunctively, is to at least provide the public with a useful choice.


SUMMARY OF THE INVENTION

According to one aspect of the present invention there is provided a container having a longitudinal axis, an upper portion having an opening into said container, a body portion extending from said upper portion to a lower portion, said lower portion including a base, said base closing off an end of said container, said container having at least one substantially transversely oriented pressure panel portion located in said lower portion, said pressure panel portion being capable of folding from one longitudinally inclined position to an inverted position to compensate for a change of pressure induced within the container.


According to a further aspect of the present invention a container has a longitudinal axis and a base, and at least one substantially transversely oriented vacuum panel portion located adjacent to said base, said vacuum panel portion being adapted in use to fold from a longitudinally inclined position to an inverted position to compensate for a change of pressure induced within the container following cooling of a liquid within the container after it has been capped, such that less force is exerted on the internal walls of said container.


According to a further aspect of the present invention a container has a longitudinal axis, a side wall and a base closing off one end, said container having a single substantially transversely oriented vacuum panel portion located within the base and joined to the side wall by a decoupling or hinge structure, said vacuum panel portion being adapted in use to fold from a longitudinally inclined position to an inverted position to compensate for a change of pressure induced within the container.


Preferably in one embodiment the vacuum panel portion may include an initiator section and a control section, said initiator section providing for folding before said control section.


Preferably in one embodiment a decoupling structure connects the pressure panel portion with the body portion and is of an area which allows for greater inward and upward longitudinal movement of the pressure panel.


Preferably in one embodiment the vacuum panel portion has no strengthening ribs to restrain substantial longitudinal movement and inversion.


Preferably in one embodiment the vacuum panel portion may include fluting structures or the like to allow an even circumferential distribution of folding forces to provide for increased control over folding the panel portion from one inclined position to another and to assist in preventing unwanted return to the original position.


Preferably in one embodiment after folding, the container standing support is provided by a lower part of the container sidewall that provides a replacement container standing support.


According to a further aspect of the invention a method of compensating for a change in pressure in a container as defined in any one of the preceding eight paragraphs is provided in which said method includes applying a force to the or each said panel portion to cause said folding to occur.


According to a further aspect of this invention there is provided a hot-fill container substantially as herein described with reference to any one of the embodiments of the accompanying drawings.


Further aspects of the invention which should be considered in all its novel aspects will become apparent from the following description.





BRIEF DESCRIPTION OF DRAWINGS


FIG. 1: shows a cross-sectional view of a hot-fill container according to one possible embodiment of the invention in its pre-collapsed condition;



FIG. 2: shows the container of FIG. 1 in its collapsed position;



FIG. 3: shows the base of FIG. 1 before collapsing;



FIG. 4: shows the base of FIG. 2 following collapsing;



FIG. 5: shows an underneath view of the base of the container of FIG. 1 before collapsing.



FIG. 6: shows the base of FIG. 1 before collapsing;



FIG. 7: shows the base of FIG. 2 following collapsing;



FIG. 8
a: shows a cross-sectional view of a hot-fill container according to an alternative embodiment of the invention in its pre-collapsed condition;



FIG. 8
b: shows a side view of the container shown in FIGS. 5b and 9 through line C-C;



FIG. 9: shows an underneath view of the base of the container of FIGS. 8a and 8b and FIG. 10 before collapsing



FIG. 10: shows a cross-sectional view of the container shown in FIG. 9 through line D-D



FIGS. 11
a-d: show cross-sectional views of the container according to an alternative embodiment of the invention incorporating a pusher to provide panel folding



FIGS. 12
a-d: show cross-sectional views of the container according to a further alternative embodiment of the invention incorporating a pusher to provide panel folding



FIG. 13: shows the base of an alternative embodiment of the invention before collapsing;



FIG. 14: shows the base of FIG. 13 during the initial stages of collapsing;



FIGS. 15
a-b: show side and cross-sectional views of the container shown in FIG. 9 including outwardly projecting fluting;



FIG. 15
c: shows an underneath view of the base of the container of FIGS. 15a and 15b with dotted contour section lines through lines E-E and F-F;



FIG. 15
d: shows a perspective view of the base of the container of FIGS. 15a-c;



FIG. 16
a: shows a side view of a container of FIG. 16c according to an alternative embodiment including inwardly projecting fluting through Line I-I;



FIG. 16
b: shows a cross-sectional view of the base of the container of FIG. 16c through Line J-J;



FIG. 16
c: shows an underneath view of the base of the container of FIGS. 16a and 16b with dotted contour section lines through lines G-G and H-H;



FIG. 16
d: shows a perspective view of the base of the container of FIGS. 16a-c;



FIGS. 17
a-d: show side, side perspective, end perspective and end views respectively of the container of FIG. 15.



FIGS. 18
a-d: show side, side perspective, end perspective and end views respectively of the container of FIG. 16;



FIG. 19
a: shows a side view of a hot-filled container of an alternative embodiment in its pre-collapsed condition;



FIG. 19
b: shows a cross-sectional view of the container of FIG. 19a through the line C-C in an initial stage of collapsing.





DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

The following description of preferred embodiments is merely exemplary in nature, and is in no way intended to limit the invention or its application or uses.


As discussed above, to accommodate vacuum forces during cooling of the contents within a heat set container, containers have typically been provided with a series of vacuum panels around their sidewalls and an optimized base portion. The vacuum panels deform inwardly, and the base deforms upwardly, under the influence of the vacuum forces. This prevents unwanted distortion elsewhere in the container. However, the container is still subjected to internal vacuum force. The panels and base merely provide a suitably resistant structure against that force. The more resistant the structure the more vacuum force will be present. Additionally, end users can feel the vacuum panels when holding the containers.


Typically at a bottling plant the containers will be filled with a hot liquid and then capped before being subjected to a cold water spray resulting in the formation of a vacuum within the container which the container structure needs to be able to cope with. The present invention relates to hot-fill containers and a structure that provides for the substantial removal or substantial negation of vacuum pressure. This allows much greater design freedom and light weighting opportunities as there is no longer any requirement for the structure to be resistant to vacuum forces which would otherwise mechanically distort the container.


As mentioned above and in the PCT specification, various proposals for hot-fill container designs have been put forward.


Further development of the hot-ill container of the POT specification has positioned an outwardly inclined and transversely oriented vacuum panel between the lower portion of the side wall and the inwardly domed base region. In this position the container has poor stability, insofar as the base region is very narrow in diameter and does not allow for a good standing ring support. Additionally, there is preferably provided a decoupling structure that provides a hinge joint to the juncture of the vacuum panel and the lower sidewall. This decoupling structure provides for a larger range of longitudinal movement of the vacuum panel than would occur if the panel was coupled to the side wall by way of ribs for example. One side of the decoupling structure remains adjacent the sidewall, allowing the opposite side of the decoupling structure, adjacent to an initiator portion to bend inwardly and upwardly. The decoupling structure therefore provides for increased deflection of the initiator portion, allowing increased movement of the panel portion longitudinally away from the previously outwardly inclined position, enabling the panel portion to fold inwardly relative to the container and upwardly relative to the initial base position. The lower sidewall is therefore subjected to lower force during such inversion. During this action, the base portion is translated longitudinally upward and into the container.


Further, as the panel portion folds inwardly and upwardly, the decoupling structure allows for the vacuum panel to now form part of the container base portion. This development has at least two important advantages.


Firstly, by providing the vacuum panel so as to form part of the base after folding, a mechanical force can now be provided immediately against the panel in order to apply inverting force. This allows much greater control over the action, which may for example be applied by a mechanical pusher, which would engage with the container base in resetting the container shape. This allows increased design options for the initiator portion.


Secondly, the transversely oriented vacuum panel is effectively completely removed from view as it is forced from an outward position to an inward position. This means that there no visible design features being imposed on the major portion of the side wall of the container in order to incorporate vacuum compensation. If required therefore, the major portion of the side wall of the present invention could have no structural features and the container could, if required, replicate a clear wall glass container. Alternatively, as there will be little or no vacuum remaining in the container after the panel is inverted, any design or shape can now be utilized, without regard for integrity against vacuum forces found in hot-fill packages.


Such a manoeuvre allows for a wide standing ring to be obtained. The decoupling structure provides for the panel to become displaced longitudinally so that there is no contact between any part of the panel or upwardly domed base portion with the contact surface below. A standing ring is then provided by the lower sidewall immediately adjacent the decoupling structure.


Further, by gaining greater control over the inverting motion and forces, it is possible to allow the initiator portion to share the same steep angle as the control portion. This allows for increased volume displacement during inversion and increased resistance to any reversion back to the original position.


Referring to the accompanying drawings, FIG. 1 shows, by way of example only, and in a diagrammatic cross sectional view, a container in the form of a bottle. This is referenced generally by arrow 10 with a typical neck portion 12 and a side wall 9 extending to a lower portion of the side wall 11 and an underneath base portion 2.


The container 10 will typically be blow moulded from any suitable plastics material but typically this will be polyethylene terephthalate (PET).


The base 2 is shown provided with a plurality of reinforcing ribs 3 so as to form the typical “champagne” base although this is merely by way of example only.


In FIG. 1 the lower side wall portion 11, which operates as a pressure panel, is shown in its unfolded position so that a ring or annular portion 6 is positioned above the level of the bottom of the base 2 which is forming the standing ring or support 4 for the container 10.


In FIG. 2 the lower side wall portion 11 is shown having folded inwardly so that the ring or annular portion 6 is positioned below the level of the bottom of the base 2 and is forming the new standing ring or support for the container 10.


To assist this occurring, and as will be seen particularly in FIGS. 3 and 4, immediately adjacent the ring or annular portion 6 there may be an instep or recess 8 and decoupling structure 13, in this case a substantially flat, non-ribbed region, which after folding enables the base portion 2 to effectively completely disappear within the bottom of the container and above the line A-A. Many other configurations for the decoupling structure 13 are envisioned, however.


Referring now particularly to FIG. 5, the base 2 with its strengthening ribs 3 is shown surrounded by the bottom annular portion 11 of the side wall 9 and the annular structure 13. The bottom portion 11 is shown in this particular embodiment as having an initiator portion 1 which forms part of the collapsing or inverting section which yields to a longitudinally-directed collapsing force before the rest of the collapsing or folding section. The base 2 is shown provided within the typical base standing ring 4, which will be the first support position for the container 10 prior to the inversion of the folding panel.


Associated with the initiator portion 1 is a control portion 5 which in this embodiment is a more steeply angled inverting section which will resist standing from the collapsed state.


Forming the outer perimeter of the bottom portion 11 of the side wall 9 is shown the side wall standing ring or annular portion 6 which following collapsing of the panel 11 will provide the new container support.


To allow for increased evacuation of vacuum it will be appreciated that it is preferable to provide a steep angle to the control portion 5 of the pressure panel 11. As shown in FIG. 6 the panel control portion 5 is generally set with an angle α varying between 30 degrees and 45 degrees. It is preferable to ensure an angle is set above 10 degrees at least. The initiator portion 1 may in this embodiment have a lesser angle β of perhaps at least 10 degrees less than the control portion.


By way of example, it will be appreciated that when the panel 11 is inverted by mechanical compression it will undergo an angular change that is double that provided to it. If the conical control portion 5 is set to 10 degrees it will provide a panel change equivalent to 20 degrees. At such a low angle it has been found to provide an inadequate amount of vacuum compensation in a hot-filled container. Therefore, it is preferable to provide much steeper angles.


Referring to FIGS. 6 and 7, it will be appreciated that the control portion 5 may be initially set to be outwardly inclined by approximately 35 degrees and will then provide an inversion and angle change of approximately 70 degrees. The initiator portion may in this example be 20 degrees.


Referring to FIGS. 8a and 8b, where the same reference numerals have been used where appropriate as previously, it is envisaged that in possible embodiments of this invention the initiator portion may be reconfigured so that pressure panel 11 would provide essentially a continuous conical area about the base 2.


The initiator portion 1 and the control portion 5 of the embodiment of the preceding figures will now be at a common angle, such that they form a uniformly inclined panel portion. However, initiator portion 1 may still be configured to provide the area of least resistance to inversion, such that although it shares the same angular extent as the control portion 5, it still provides an initial area of collapse or inversion. In this embodiment, initiator portion 1 causes the pressure panel 11 to begin inversion from the widest diameter adjacent the decoupling structure 13. Such an arrangement is shown in FIGS. 19a and 19b.


In the embodiment of FIGS. 8a and 8b the container side walls 9 are ‘glass-like’ in construction in that there are no additional strengthening ribs or panels as might be typically found in a container, particularly if required to withstand the forces of vacuum pressure. Additionally, however, structures may be added to the conical portions of the vacuum panel 11 in order to add further control over the inversion process. For example, the conical portion of the vacuum panel 11 may be divided into fluted regions. Referring to FIGS. 8a and 9 especially, panel portions that are convex outwardly, and evenly distributed around the central axis create regions of greater angular set 19 (δ) and regions of lesser angular set 18 (γ), may provide for greater control over inversion of the panel. Such geometry provides increased resistance to reversion of the panel, and a more even distribution of forces when in the inverted position.


Referring to FIGS. 15a-c and 17a-d, convex or downwardly outwardly projecting flutes are shown.


Concave or inwardly directed fluting arrangements are also envisioned, in addition to outwardly directed flutes. Inwardly directed flutes offer less resistance to initial inverting forces, coupled with increased resistance to reverting back out to the original position. In this way they behave in much the same manner as ribs to prevent the panel being forced back out to the outwardly inclined position, but allow for hinge movement from the first outwardly inclined position to the inwardly inclined position. Such inwardly or outwardly directed flutes or projections function as ribs to increase the force required to invert the panel. It will be appreciated that the mechanical action applied to invert the panel will be sufficient to overcome any rib-strengthened panel, and when the mechanical action is removed the rib-strengthened panel, for example by strong flutes, will be very resistant to reversion to the original position if the container is dropped or shocked.


Referring to FIGS. 16a-d and 18a-d concave or upwardly inwardly projecting flutes are shown, the contour lines G and H of FIG. 16c illustrating this concavity through two cross-sectional reliefs.


Further embodiments comprising arrays utilizing both concave and convex flutes are also intended within the scope of the invention.


In the embodiment as shown in FIGS. 11a-d the container may be blow moulded with the pressure panel 20 in the inwardly or upwardly inclined position. A force could be imposed on the folding panel 20 such as by means of a mechanical pusher 21 introduced through the neck region and forced downwardly in order to place the panel in the outwardly inclined position prior to use as a vacuum container for example, as shown in FIG. 11d.


In such an embodiment as shown in FIGS. 12a-d, following the filling and capping of the bottle and the use of cold water spray creating the vacuum within the filled bottle, a force could be imposed on the folding panel 20 such as by means of a mechanical pusher 22 or the creation of some relative movement of the bottle base relative to a punch or the like, in order to force the panel 20 from an outwardly inclined position to an inwardly inclined position. Any deformation whereby the bottle shape was distorted prior to inversion of the panel 20 would be removed as internal volume is forcibly reduced. The vacuum within the container is removed as the inversion of the panel 20 causes a rise in pressure. Such a rise in pressure reduces vacuum pressure until ambient pressure is reached or even a slightly positive pressure is achieved.


It will be appreciate that in a further embodiment of the invention the panel may be inverted in the manner shown in FIGS. 12a-d in order to provide a panel to accommodate internal force such as is found in pasteurization and the like. In such a way the panel will provide relief against the internal pressure generated and then be capable of accommodating the resulting vacuum force generated when the product cools down.


In this way, the panel will be inverted from an upwardly inclined position FIGS. 11a to 11b to a downwardly inclined position as shown in FIGS. 12a-d, except that the mechanical action is not provided. The force is instead provided by the internal pressure of the contents.


Referring again to FIGS. 12a-d it will be seen that by the provision of the folding portion 20 in the bottom of the side wall 9 of the container 10 the major portion of the side wall 9 could be absent any structural features so that the container 10 could essentially replicate a glass container if this was required.


Although particular structures for the bottom portion of the side wall 9 are shown in the accompanying drawings it will be appreciated that alternative structures could be provided. For example a plurality of folding portions could be incorporated about the base 2 in an alternative embodiment.


There may also be provided many different decoupling or hinge structures 13 without departing from the scope of the invention. With particular reference to FIGS. 6 and 7, it can be seen that the side of the decoupling structure 13 that is provided for the pressure panel 11 may be of an enlarged area to provide for increased longitudinal movement upwards into the container following inversion.


In a further embodiment of the present invention, and referring to FIGS. 13 and 14, it can be seen that the widest portions 30 of the pressure panel 11 may invert earlier than the narrower portions 31. The initiator portion may be constructed with this in mind, to allow for thinner material and so on, to provide for the panel 11 to begin inverting where it has the greater diameter, ahead of the narrower sections of the panel. In this case the portion 30 of the panel, which is radially set more distant from the central axis of the container inverts ahead of portion 31 to act as the initiator portion.


Where in the foregoing description, reference has been made to specific components or integers of the invention having known equivalents then such equivalents are herein incorporated as if individually set forth.


Although this invention has been described by way of example and with reference to possible embodiments thereof, it is to be understood that modifications or improvements may be made thereto without departing from the scope of the invention as defined in the appended claims.

Claims
  • 1. A container having a longitudinal axis, an upper portion having an opening into the container, a body portion extending from the upper portion to a lower portion, the lower portion including a base, the base closing off an end of the container, the container having at least one substantially transversely oriented pressure panel located in the lower portion, the pressure panel comprising a portion being inclined at an angle of more than 10° relative to a plane orthogonal to the longitudinal axis and the pressure panel portion being configured to be capable of folding from the inclined position to an inverted position to change an internal volume within the container, wherein the pressure panel is connected in the lower portion of the container by a decoupling or hinge structure and wherein the pressure panel is configured to invert longitudinally under an externally applied mechanical force.
  • 2. A container according to claim 1, wherein said portion that is inclined is inclined at an angle of between approximately 30° and approximately 45°.
  • 3. A container according to claim 1, wherein said inclined portion is inwardly inclined relative to an interior portion of the container and configured to be capable of folding from the inwardly inclined position to the inverted position to increase the internal volume within the container.
  • 4. A container according to claim 1, wherein said inclined portion is outwardly inclined relative to an interior portion of the container and configured to be capable of folding from the outwardly inclined position to the inverted position to reduce the internal volume within the container.
  • 5. A container according to claim 1, wherein the pressure panel comprises an initiator portion and a control portion, the initiator portion having less resistance to pressure folding forces and configured to provide for folding of the control portion.
  • 6. A container according to claim 5, wherein said inclined portion is outwardly inclined relative to an interior portion of the container and the initiator portion is configured to cause the control portion to invert and flex further inwardly into the container.
  • 7. A container according to claim 5, wherein the initiator portion is located adjacent to a widest periphery of the pressure panel.
  • 8. A container according to claim 5, wherein said inclined portion is the control portion.
  • 9. A container according to claim 5, wherein the initiator portion is inclined at an angle that is substantially the same as or less than that of the control portion.
  • 10. A container according to claim 7, wherein said inclined portion is outwardly inclined relative to an interior portion of the container and the initiator portion is outwardly inclined relative to an interior portion of the container at an angle to said orthogonal plane that is at least 10° less than the control portion.
  • 11. A container according to claim 10, wherein the control portion is outwardly inclined relative to an interior portion of the container at an angle of between approximately 30° and 45°.
  • 12. A container according to claim 1, wherein the pressure panel is capable of folding from the inclined position to the inverted position to compensate for a change of pressure induced in the container.
  • 13. A container according to claim 12, wherein the pressure panel provides compensation for reduced pressure induced within the container, in use, such that less force is exerted on walls of the container.
  • 14. A container according to claim 13, wherein the reduced pressure is induced by the cooling of a heated liquid within the container.
  • 15. A container according to or claim 14, wherein the compensation is such that there is substantially no reduced pressure within the container.
  • 16. A container according to claim 12, wherein the pressure panel is configured to be capable of folding from the inverted position to the inclined position to compensate for an increase in pressure induced in the container.
  • 17. A container according to claim 16, wherein the pressure panel is configured so that in use the pressure panel provides compensation for increased pressure induced within the container following heating of a liquid within the container.
  • 18. A container according to claim 1, wherein the pressure panel is configured to resist being expanded from the inverted position.
  • 19. A container according to claim 1, wherein the pressure panel is of varied width and inverts from a portion of the pressure panel furthest from the longitudinal axis to a portion of the pressure panel nearest the longitudinal axis.
  • 20. A container according to claim 1, wherein the pressure panel is configured to cause the base to retract longitudinally further into the body portion.
  • 21. A container according to claim 20, wherein the pressure panel is configured to cause a lowest portion of the base to be replaced as the structure providing a standing support for the container.
  • 22. A container according to claim 1, wherein the container includes a standing support connected with the base, the standing support providing a substantially flat rigid surface, and wherein the container structure is configured such that in use a top load applied to the container is transferred from the base to the standing support.
  • 23. A container according to claim 1, wherein the inclined portion of the pressure panel includes outwardly projecting portions.
  • 24. A container according to claim 1, wherein the inclined portion of the pressure panel includes inwardly projecting portions.
  • 25. A container according to claim 1, wherein the base further includes a substantially centrally located inwardly projecting portion joined adjacent to an inside border of the pressure panel and closing off a bottom of the container.
  • 26. A container according to claim 25, wherein the inwardly projecting portion is configured to move upwardly when the pressure panel inverts.
  • 27. A container according to claim 1, wherein the pressure panel is in the base.
  • 28. A container according to claim 1, wherein the inclined portion of the pressure panel includes a plurality of flutes forming a conical area in the base.
  • 29. A container according to claim 1, further including a standing ring surrounding the pressure panel for providing container stability when the pressure panel is in the inverted position.
  • 30. A container according to claim 29 and further including a recessed instep adjacent to an inside border of the standing ring, the instep surrounding the pressure panel portion and positioning the pressure panel further within the container.
  • 31. A container according to claim 30, wherein the decoupling or hinge structure connects the pressure panel portion with the instep.
  • 32. A container according to claim 31 wherein the decoupling structure is relatively flat when compared to a side wall of the container.
  • 33. A container according to claim 31 wherein the decoupling structure is relatively non-ribbed, and separates the pressure panel from the recessed instep.
  • 34. A container according to claim 1, wherein the pressure panel has no strengthening ribs to restrain substantial longitudinal movement and inversion.
  • 35. A container according to claim 1, wherein: the container includes a standing ring which defines a support surface upon which the container is supported,the base includes a central portion,the pressure panel circumscribes the central portion and defines an inwardly inclined shaped portion when the container is filled and sealed, the inwardly inclined shaped portion defined by a surface which is sloped toward the longitudinal axis of the container at an angle of more than about 10° relative to the support surface, andthe central portion and the pressure panel portion are configured to be moveable to accommodate vacuum forces generated within the container.
  • 36. A container having a longitudinal axis, an upper portion having an opening into the container, a body portion extending from the upper portion to a lower portion, the lower portion including a base, the base closing off an end of the container, the container having at least one substantially transversely oriented pressure panel located in the lower portion, the pressure panel comprising a portion being inclined at an angle of more than 10° relative to a plane orthogonal to the longitudinal axis and the pressure panel portion being configured to be capable of folding from the inclined position to an inverted position to change an internal volume within the container, wherein the pressure panel comprises an initiator portion and a control portion, the initiator portion having less resistance to pressure folding forces and configured to provide for folding of the control portion,wherein the initiator portion is located adjacent to a widest periphery of the pressure panel,wherein said inclined portion is outwardly inclined relative to an interior portion of the container and the initiator portion is outwardly inclined relative to an interior portion of the container at an angle to said orthogonal plane that is at least 10° less than the control portion.
  • 37. A container according to claim 36, the control portion is outwardly inclined relative to an interior portion of the container at an angle of between approximately 30° and 45°.
  • 38. A container having a longitudinal axis, an upper portion having an opening into the container, a body portion extending from the upper portion to a lower portion, the lower portion including a base, the base closing off an end of the container, the container having at least one substantially transversely oriented pressure panel located in the lower portion, the pressure panel comprising a portion being inclined at an angle of more than 10° relative to a plane orthogonal to the longitudinal axis and the pressure panel portion being configured to be capable of folding from the inclined position to an inverted position to change an internal volume within the container, wherein the pressure panel is connected in the lower portion of the container by a decoupling or hinge structure and wherein said portion that is inclined is inclined at an angle of between approximately 30° and approximately 45°.
  • 39. A container according to claim 38, wherein said inclined portion is inwardly inclined relative to an interior portion of the container and configured to be capable of folding from the inwardly inclined position to the inverted position to increase the internal volume within the container.
  • 40. A container according to claim 38, wherein said inclined portion is outwardly inclined relative to an interior portion of the container and configured to be capable of folding from the outwardly inclined position to the inverted position to reduce the internal volume within the container.
  • 41. A container according to claim 38, wherein the pressure panel comprises an initiator portion and a control portion, the initiator portion having less resistance to pressure folding forces and configured to provide for folding of the control portion.
  • 42. A container according to claim 41, wherein said inclined portion is outwardly inclined relative to an interior portion of the container and the initiator portion is configured to cause the control portion to invert and flex further inwardly into the container.
  • 43. A container according to claim 41, wherein the initiator portion is located adjacent to a widest periphery of the pressure panel.
  • 44. A container according to claim 41, wherein said inclined portion is the control portion.
  • 45. A container according to claim 41, wherein the initiator portion is inclined at an angle that is substantially the same as or less than that of the control portion.
  • 46. A container according to claim 43, wherein said inclined portion is outwardly inclined relative to an interior portion of the container and the initiator portion is outwardly inclined relative to an interior portion of the container at an angle to said orthogonal plane that is at least 10° less than the control portion.
  • 47. A container according to claim 38, wherein the pressure panel is capable of folding from the inclined position to the inverted position to compensate for a change of pressure induced in the container.
  • 48. A container according to claim 47, wherein the pressure panel provides compensation for reduced pressure induced within the container, in use, such that less force is exerted on walls of the container.
  • 49. A container according to claim 48, wherein the reduced pressure is induced by the cooling of a heated liquid within the container.
  • 50. A container according to or claim 49, wherein the compensation is such that there is substantially no reduced pressure within the container.
  • 51. A container according to claim 47, wherein the pressure panel is configured to be capable of folding from the inverted position to the inclined position to compensate for an increase in pressure induced in the container.
  • 52. A container according to claim 51, wherein the pressure panel is configured so that in use the pressure panel provides compensation for increased pressure induced within the container following heating of a liquid within the container.
  • 53. A container according to claim 38, wherein the pressure panel is configured to resist being expanded from the inverted position.
  • 54. A container according to claim 38, wherein the pressure panel is of varied width and inverts from a portion of the pressure panel furthest from the longitudinal axis to a portion of the pressure panel nearest the longitudinal axis.
  • 55. A container according to claim 38, wherein the pressure panel is configured to cause the base to retract longitudinally further into the body portion.
  • 56. A container according to claim 55, wherein the pressure panel is configured to cause a lowest portion of the base to be replaced as the structure providing a standing support for the container.
  • 57. A container according to claim 38, wherein the container includes a standing support connected with the base, the standing support providing a substantially flat rigid surface, and wherein the container structure is configured such that in use a top load applied to the container is transferred from the base to the standing support.
  • 58. A container according to claim 38, wherein the inclined portion of the pressure panel includes outwardly projecting portions.
  • 59. A container according to claim 38, wherein the inclined portion of the pressure panel includes inwardly projecting portions.
  • 60. A container according to claim 38, wherein the base further includes a substantially centrally located inwardly projecting portion joined adjacent to an inside border of the pressure panel and closing off a bottom of the container.
  • 61. A container according to claim 60, wherein the inwardly projecting portion is configured to move upwardly when the pressure panel inverts.
  • 62. A container according to claim 38, wherein the pressure panel is in the base.
  • 63. A container according to claim 38, wherein the inclined portion of the pressure panel includes a plurality of flutes forming a conical area in the base.
  • 64. A container according to claim 38, further including a standing ring surrounding the pressure panel for providing container stability when the pressure panel is in the inverted position.
  • 65. A container according to claim 64 and further including a recessed instep adjacent to an inside border of the standing ring, the instep surrounding the pressure panel portion and positioning the pressure panel further within the container.
  • 66. A container according to claim 65, wherein the decoupling or hinge structure connects the pressure panel portion with the instep.
  • 67. A container according to claim 66 wherein the decoupling structure is relatively flat when compared to a side wall of the container.
  • 68. A container according to claim 66, wherein the decoupling structure is relatively non-ribbed, and separates the pressure panel from the recessed instep.
  • 69. A container according to claim 38, wherein the pressure panel has no strengthening ribs to restrain substantial longitudinal movement and inversion.
  • 70. A container according to claim 38, wherein: the container includes a standing ring which defines a support surface upon which the container is supported,the base includes a central portion,the pressure panel circumscribes the central portion and defines an inwardly inclined shaped portion when the container is filled and sealed, the inwardly inclined shaped portion defined by a surface which is sloped toward the longitudinal axis of the container at an angle of more than about 10° relative to the support surface, and the central portion and the pressure panel portion are configured to be moveable to accommodate vacuum forces generated within the container.
Priority Claims (1)
Number Date Country Kind
521694 Sep 2002 NZ national
PCT Information
Filing Document Filing Date Country Kind 371c Date
PCT/NZ03/00220 9/30/2003 WO 00 12/15/2005
Publishing Document Publishing Date Country Kind
WO2004/028910 4/8/2004 WO A
US Referenced Citations (214)
Number Name Date Kind
1499239 Malmquist Jun 1924 A
D110624 Mekeel, Jr. Jul 1938 S
2124959 Vogel Jul 1938 A
2378324 Ray et al. Jun 1945 A
2880902 Owsen Apr 1959 A
2960248 Kuhlman Nov 1960 A
2971671 Shakman Feb 1961 A
2982440 Harrison May 1961 A
3043461 Glassco Jul 1962 A
3081002 Tauschinski et al. Mar 1963 A
3174655 Hurschman Mar 1965 A
3301293 Santelli Jan 1967 A
3397724 Bolen et al. Aug 1968 A
3409167 Blanchard Nov 1968 A
3426939 Young Feb 1969 A
3468443 Marcus Sep 1969 A
3483908 Donovan Dec 1969 A
3485355 Stewart Dec 1969 A
3693828 Kneusel et al. Sep 1972 A
3704140 Petit et al. Nov 1972 A
3727783 Carmichael Apr 1973 A
3819789 Parker Jun 1974 A
3883033 Brown May 1975 A
3904069 Toukmanian Sep 1975 A
3918920 Barber Nov 1975 A
3935955 Das Feb 1976 A
3941237 MacGregor Mar 1976 A
3942673 Lyu et al. Mar 1976 A
3949033 Uhlig Apr 1976 A
4036926 Chang Jul 1977 A
4037752 Dulmaine et al. Jul 1977 A
4117062 Uhlig Sep 1978 A
4125632 Vosti et al. Nov 1978 A
4134510 Chang Jan 1979 A
4170622 Uhlig et al. Oct 1979 A
4174782 Obsomer Nov 1979 A
4219137 Hutchens Aug 1980 A
4231483 Dechenne et al. Nov 1980 A
4247012 Alberghini Jan 1981 A
4301933 Yoshino et al. Nov 1981 A
4318489 Snyder et al. Mar 1982 A
4318882 Agrawal et al. Mar 1982 A
4321483 Dugan Mar 1982 A
4338765 Ohmori et al. Jul 1982 A
4355728 Ota et al. Oct 1982 A
4377191 Yamaguchi Mar 1983 A
4378328 Przytulla Mar 1983 A
4381061 Cerny et al. Apr 1983 A
D269158 Gaunt et al. May 1983 S
4386701 Galer Jun 1983 A
4412866 Schoenrock et al. Nov 1983 A
4436216 Chang Mar 1984 A
4444308 MacEwen Apr 1984 A
4450878 Takada et al. May 1984 A
4465199 Aoki Aug 1984 A
4497855 Agrawal et al. Feb 1985 A
4542029 Caner et al. Sep 1985 A
4610366 Estes et al. Sep 1986 A
4628669 Herron et al. Dec 1986 A
4642968 McHenry et al. Feb 1987 A
4645078 Reyner Feb 1987 A
4667454 McHenry et al. May 1987 A
4684025 Copland et al. Aug 1987 A
4685273 Caner et al. Aug 1987 A
D292378 Brandt et al. Oct 1987 S
4749092 Sugiura et al. Jun 1988 A
4773458 Touzani Sep 1988 A
4785949 Krishnakumar et al. Nov 1988 A
4785950 Miller et al. Nov 1988 A
4807424 Robinson et al. Feb 1989 A
4813556 Lawrence Mar 1989 A
4831050 Bettle May 1989 A
4836398 Leftault, Jr. et al. Jun 1989 A
4840289 Fait et al. Jun 1989 A
4850493 Howard, Jr. Jul 1989 A
4850494 Howard, Jr. Jul 1989 A
4865206 Behm et al. Sep 1989 A
4867323 Powers Sep 1989 A
4880129 McHenry et al. Nov 1989 A
4887730 Touzani Dec 1989 A
4892205 Powers et al. Jan 1990 A
4896205 Weber Jan 1990 A
4921147 Poirier May 1990 A
4967538 Leftault et al. Nov 1990 A
4976538 Ake Dec 1990 A
4978015 Walker Dec 1990 A
4997692 Yoshino Mar 1991 A
5004109 Bartley Apr 1991 A
5005716 Eberle Apr 1991 A
5014868 Wittig et al. May 1991 A
5024340 Alberghini et al. Jun 1991 A
5060453 Alberghini et al. Oct 1991 A
5067622 Garver et al. Nov 1991 A
5090180 Sorensen Feb 1992 A
5092474 Leigner Mar 1992 A
5133468 Brunson et al. Jul 1992 A
5141121 Brown et al. Aug 1992 A
5178290 Ota et al. Jan 1993 A
5199587 Ota et al. Apr 1993 A
5199588 Hayashi Apr 1993 A
5201438 Norwood et al. Apr 1993 A
5217737 Gygax et al. Jun 1993 A
5234126 Jonas et al. Aug 1993 A
5244106 Takacs Sep 1993 A
5251424 Zenger et al. Oct 1993 A
5255889 Collette et al. Oct 1993 A
5261544 Weaver, Jr. Nov 1993 A
5279433 Krishnakumar et al. Jan 1994 A
5281387 Collette et al. Jan 1994 A
5333761 Davis et al. Aug 1994 A
5341946 Vailliencourt et al. Aug 1994 A
5392937 Prevot Feb 1995 A
5411699 Collette et al. May 1995 A
5454481 Hsu Oct 1995 A
5472105 Krishnakumar et al. Dec 1995 A
5472181 Lowell Dec 1995 A
RE35140 Powers, Jr. Jan 1996 E
5484052 Pawloski et al. Jan 1996 A
5503283 Semersky Apr 1996 A
5593063 Claydon et al. Jan 1997 A
5598941 Semersky Feb 1997 A
5632397 Fandeux et al. May 1997 A
5642826 Melrose Jul 1997 A
5672730 Cottman Sep 1997 A
5690244 Darr Nov 1997 A
5704504 Bueno Jan 1998 A
5713480 Petre et al. Feb 1998 A
5730314 Wiemann et al. Mar 1998 A
5730914 Ruppmann, Sr. Mar 1998 A
5737827 Kuse et al. Apr 1998 A
5758802 Wallays Jun 1998 A
5762221 Tobias et al. Jun 1998 A
5780130 Hansen et al. Jul 1998 A
5785197 Slat Jul 1998 A
5819507 Kaneko Oct 1998 A
5829614 Collette et al. Nov 1998 A
5858300 Shimizu et al. Jan 1999 A
5860556 Robbins, III Jan 1999 A
5887739 Prevot et al. Mar 1999 A
5888598 Brewster et al. Mar 1999 A
5897090 Smith et al. Apr 1999 A
5906286 Matsuno et al. May 1999 A
5908128 Krishnakumar et al. Jun 1999 A
D415030 Searle et al. Oct 1999 S
5976653 Collette et al. Nov 1999 A
RE36639 Okhai Apr 2000 E
6065624 Steinke May 2000 A
6077554 Wiemann et al. Jun 2000 A
6105815 Mazda et al. Aug 2000 A
6213325 Cheng et al. Apr 2001 B1
6228317 Smith et al. May 2001 B1
6230912 Rashid May 2001 B1
6277321 Vailliencourt et al. Aug 2001 B1
6298638 Bettle Oct 2001 B1
6375025 Mooney Apr 2002 B1
6390316 Mooney May 2002 B1
6413466 Boyd et al. Jul 2002 B1
6439413 Prevot Aug 2002 B1
6467639 Mooney Oct 2002 B2
6485669 Boyd et al. Nov 2002 B1
6502369 Andison et al. Jan 2003 B1
6514451 Boyd et al. Feb 2003 B1
6585124 Boyd et al. Jul 2003 B2
6595380 Silvers Jul 2003 B2
6612451 Tobias et al. Sep 2003 B2
6662960 Hong et al. Dec 2003 B2
6749780 Tobias Jun 2004 B2
6763968 Boyd et al. Jul 2004 B1
6769561 Futral et al. Aug 2004 B2
6779673 Melrose et al. Aug 2004 B2
6923334 Melrose et al. Aug 2005 B2
6942116 Lisch et al. Sep 2005 B2
6983858 Slat et al. Jan 2006 B2
7051889 Boukobza May 2006 B2
7077279 Melrose Jul 2006 B2
7137520 Melrose Nov 2006 B1
7150372 Lisch et al. Dec 2006 B2
7159374 Abercrombie, III et al. Jan 2007 B2
7520400 Young et al. Apr 2009 B2
7717282 Melrose May 2010 B2
20010035391 Young et al. Nov 2001 A1
20020074336 Silvers Jun 2002 A1
20020096486 Bourque et al. Jul 2002 A1
20020153343 Tobias et al. Oct 2002 A1
20020158038 Heisel et al. Oct 2002 A1
20030015491 Melrose et al. Jan 2003 A1
20030186006 Schmidt et al. Oct 2003 A1
20030196926 Tobias et al. Oct 2003 A1
20030217947 Ishikawa et al. Nov 2003 A1
20040016716 Melrose et al. Jan 2004 A1
20040028910 Melrose Apr 2004 A1
20040074864 Melrose et al. Apr 2004 A1
20040149677 Slat et al. Aug 2004 A1
20040173565 Semersky et al. Sep 2004 A1
20040173656 Seong Sep 2004 A1
20040211746 Trude Oct 2004 A1
20040232103 Lisch et al. Nov 2004 A1
20060006133 Lisch et al. Jan 2006 A1
20060138074 Melrose Jun 2006 A1
20060231985 Kelley Oct 2006 A1
20060243698 Melrose Nov 2006 A1
20060255005 Melrose et al. Nov 2006 A1
20060261031 Melrose Nov 2006 A1
20070017892 Melrose Jan 2007 A1
20070045312 Abercrombie, III et al. Mar 2007 A1
20070051073 Kelley et al. Mar 2007 A1
20070084821 Bysick et al. Apr 2007 A1
20070125743 Pritchett et al. Jun 2007 A1
20070181403 Sheets et al. Aug 2007 A1
20070199915 Denner et al. Aug 2007 A1
20070199916 Denner et al. Aug 2007 A1
20070215571 Trude Sep 2007 A1
20070235905 Trude et al. Oct 2007 A1
20080047964 Denner et al. Feb 2008 A1
Foreign Referenced Citations (72)
Number Date Country
2077717 Mar 1993 CA
17 61 753 Jan 1972 DE
1761753 Jan 1972 DE
21 02 319 Aug 1972 DE
32 15 866 Nov 1983 DE
0 521 642 Jan 1993 EP
0 551 788 Jul 1993 EP
0 666 222 Aug 1995 EP
0 609 348 Jan 1997 EP
0 916 406 May 1999 EP
0 957 030 Nov 1999 EP
1 063 076 Dec 2000 EP
03748817 Jul 2007 EP
1571499 Jun 1969 FR
2607109 May 1988 FR
0 781103 Aug 1957 GB
1113988 May 1968 GB
2050919 Jan 1981 GB
2372977 Sep 2002 GB
677 Aug 2000 GE
48-31050 Sep 1973 JP
49-28628 Jul 1974 JP
54-72181 Jun 1979 JP
56-072730 Jun 1981 JP
55-114717 Feb 1982 JP
63-189224 Aug 1988 JP
64-009146 Jan 1989 JP
649146 Jan 1989 JP
03-043342 Feb 1991 JP
03-076625 Apr 1991 JP
05-193694 Aug 1993 JP
06-336238 Dec 1994 JP
07-300121 Nov 1995 JP
08-253220 Oct 1996 JP
09-039934 Feb 1997 JP
09-110045 Apr 1997 JP
10-167226 Jun 1998 JP
10-181734 Jul 1998 JP
10-230919 Sep 1998 JP
2000-229615 Aug 2000 JP
2002-127237 May 2002 JP
2006-501109 Jan 2006 JP
240448 Jun 1995 NZ
296014 Oct 1998 NZ
335565 Oct 1999 NZ
506684 Aug 2000 NZ
512423 Jun 2001 NZ
521694 Oct 2003 NZ
2021956 Oct 1994 RU
2096288 Nov 1997 RU
WO 9309031 May 1993 WO
WO 9312975 Jul 1993 WO
WO 9312975 Jul 1993 WO
WO 9405555 Mar 1994 WO
WO 9703885 Feb 1997 WO
WO 9703885 Feb 1997 WO
WO 9714617 Apr 1997 WO
WO 9734808 Sep 1997 WO
WO 9921770 May 1999 WO
WO 9921770 May 1999 WO
WO 0140081 Dec 1999 WO
WO 0051895 Sep 2000 WO
WO 0202418 Jan 2002 WO
WO 0218213 Mar 2002 WO
WO 0218213 Mar 2002 WO
WO 02085755 Oct 2002 WO
WO 2004028910 Apr 2004 WO
WO 2004106175 Dec 2004 WO
WO 2004106176 Dec 2004 WO
WO 2005012091 Feb 2005 WO
WO 2006113428 Oct 2006 WO
WO 2007127337 Nov 2007 WO
Related Publications (1)
Number Date Country
20060138074 A1 Jun 2006 US