The present invention relates to liners bonded to liquid containing metal structures and the method of applying and bonding the liner.
Liquid holding structures such as cooling towers, evaporative condensers, and other evaporative systems for cooling or condensing and holding evaporative liquid are subjected to great mechanical stresses and exposure to corrosive environments. Chemicals used in the water to control water chemistries and to prevent biological growth can also work against the metal structure sections to promote corrosion unless carefully monitored. Such structures are usually made of treated steel, stainless steel, or plastic to protect the basin from corrosion. Plastic or polymer structures may be made from FRP or Polypropylene or similar materials. Fasteners are used to attach the panels together. The seams between the panels are usually sealed separately to give added protection to these areas. These metal structures are more likely to leak at or around the seams. Seams are sealed with a butyl rubber tape and/or a caulk. Prior art systems involved the use of galvanized, plastic or stainless materials to hold the liquid and prevent corrosion. Galvanized basins and structures provide limited resistance to corrosion. Prolonged exposure, especially to treated water having high chlorides and the like, can break down the galvanized coating. The loss of the galvanized coating exposes the panels to the corrosive liquid resulting in a need to repair or replace the structure or sections. Stainless tanks and basins are expensive and may be susceptible to corrosion from certain water chemistries such as high chlorides. Vessels formed from galvanized panels use many more fasteners than are needed to structurally assemble the panels. The fasteners are positioned and inserted to seal the seams as well as hold the panels together. The fasteners may need a fastener hole formed in the aligned flanges. Stainless steel panels can be fastened together with to form the basin or vessel having good corrosion protection to some chemicals. Furthermore, most metal vessels also have square corners and joints making vessel cleaning difficult and drainage an issue as water can pool in a corner or at an angle joint.
Single or multi piece plastic or polymer basins are susceptible to cracking, and may not be structurally sound when containing large volumes. The plastic structures may be flammable, expensive, and damaged by heat or thermal shifts due to climates that have wide temperature range swings. Coatings such as epoxy and polymer coatings on metal have weaknesses especially when the coating is below the water line and exposed to chemicals and the water continuously. Such exposure can results in blistering, cracking, and peeling of the coating and thus exposing the metal substrate to the water and chemicals. Lining the basins with materials such as polyurethane may be difficult because of long cure times and expensive surface preparation. The lined basins are still susceptible to compatibility with sealer material like tape, caulk, and other sealants used which may react with the barrier coating after installation. Furthermore, the polyurethane liners are known to flow through cracks and seams in their liquid state before curing causing uneven coating especially where the liner is needed most, at the seams. Adhesion of the liner to the substrate can also be a problem especially on the bottom and walls below the water level. Water and chemicals attacking the edge interface between the liner and the substrate can penetrate between the liner and the substrate causing corrosion behind the liner. This corrosive damage can be very hard to repair and may damage the integrity of surrounding areas.
Steel structures have been used extensively in the prior art to build structures for holding liquid such as water and treated water for cooling and evaporative functions. A steel structure provides a cost/strength-valued construction, but must be insulated from the liquid. Those skilled in the art would recognize that the prior art teaches that corrosion protection is accomplished with a polymer coating the structure or an organic powder coating. Each coating requires several steps be satisfied. First, the surface must be thoroughly cleaned of all dirt, oil, oxidation products, and any other foreign matter. Second, sites to which the liner can bond must be available on the surface. Third, the coatings must be specially formulated to impart specific wear, adhesion, sealing, and corrosion resistant properties to the steel when applied in layered sequential coatings. Liner joints or seams below the water line can allow penetration of the liquid through the seam and behind the liner promoting corrosion and eventually causing a leak.
The U.S. Pat. No. 4,540,637 to Geary et al. for a PROCESS FOR THE APPLICATION OF ORGANIC MATERIAL TO GALVANIZED METAL is assigned to the assignee of the present invention and the disclosure is by this reference incorporated in its entirety in the present application. The liner protects the surface of the panels from chemical attack and corrosion caused by the water, treated water or other liquid contained in the vessel.
The '637 patent discloses and claims a process for the application of an organic powder coating to galvanized steel comprising a four step process. The panels are acid cleaned to remove contaminates and thoroughly rinsed and dried to prepare the metal galvanized surface for adhesion of the powder coating. The powder coating uses the galvanized layer as a back up corrosion resistant layer to protect and supplement especially where the panels are physically damaged in use destroying a portion of the powder coating.
The prior art also includes roll-on and spray on liners for application to the interior walls of a vessel. These “after market” liners do not adhere well to the substrate due to contamination and corrosion on the surface of the metal. These “after market” liners are more expensive to apply because of surface preparations and labor required for installation. In addition, these prior art liners use cleaners, primer coatings, and/or mechanical surface preparation such as sanding, sand blasting or the like to clean and prepare the surface. Sealants used to seal the seams are butyl tape and/or caulk and may react chemically with the liner and may create a loose attachment of the liner to the substrate causing a compromised installation.
The present invention is a factory-installed liner for use in evaporative cooling, condensing and similar systems holding and circulating hot and cold liquids for heat transfer and storage. The liner includes a coated metal such as galvanized steel as a structural substrate having a powdered polymer coating electrostatically applied and baked on the clean galvanized surface. The organic powder polymer bonds chemically and mechanically to the galvanized metal substrate and provides a clean, dry and possibly warm surface for the elastomeric barrier coating to mechanically and chemically adhere to. Additional support is provided for the barrier coating by holes formed in the substrate panels of the structure, forms placed in the corners, liner edges isolated from contact with flowing or standing water and seams attached without caulks and sealants. The holes are formed prior to application of the organic powder. The organic powder is applied to flow through sealing the hole and the surrounding galvanized material on the inside and outside surfaces. The forms provide better drainage to prevent standing water when the vessel is not in use. The forms are for allowing draining along the vessel edges where dirt, debris, and corrosive elements may become trapped and stand degrading the barrier coating. The panels are attached using mechanical fasteners in the standard manner of connecting panels to form a contiguous vessel wall. Fasteners are used in assembling the panels. The caulk or tape used in the prior art for sealing all sides with a homogenous application or sealing the seams are not used in the present invention. The present invention describes and claims a liner and method of application for sealing the seams and lining the panels with a homogenous application of an elastomeric material requiring fewer fasteners used and fewer holes in assembling the panels.
The present invention is directed to a liner for use on the inner surface of a vessel or basin comprising a first coating of zinc applied to the steel panels to galvanize them. A second coating comprises an organic powder coating on the galvanized coating and a third layer of a material such as polyurethane, polyurea, a polyurethane/polyurea blend, or similar. The organic powder is applied electrostatically to provide a uniform and even coating even in blind spots to a clean galvanized steel surface and baked to cure resulting in a sealing coat having good adhesion and providing a bonding surface for the third polyurethane barrier coating layer. The organic powder coating may be an epoxy-like material such as deposited by the Baltibond Corrosion Protection System available from Baltimore Air Coil and described and claimed in the aforementioned U.S. '637 patent. The organic coating is applied to the interior and exterior surfaces in the manufacture of the structure by a multi-step cleaning and drying process to maximize adhesion between the coating and the metal. The coated panels are assembled using threaded fasteners or rivets as is known in the art of mechanical assembly of a large metal vessel or structure. The method of the present invention does not require a separate sealing tape or sealant before application of the third barrier coating layer. The method includes applying the elastomeric material in liquid form over the seams and any portion of the fasteners exposed to the inside of the vessel. In the double break flange assembly of the vessel; all fasteners are typically outside the basin as shown in
The present invention is directed to a liner mechanically coupled to the key areas of the vessel such as sidewalls, high flowage areas and areas of high traffic. The mechanical coupling to the panels is achieved by punching link holes in the panels to allow the powder coating to coat in around and through each hole without closing the opening in the panel. The link holes allow the elastomeric barrier material to flow out of the link hole and form a button-like globule on the outside of the vessel tied to the barrier coating. The elastomeric barrier coating extends from the inside of the vessel to the outside of the panel through the link hole to mechanically attach the barrier coating to the sidewall. The clean dry surface of the organic powder second sealing layer allows the atomized spray of the elastomeric third layer to penetrate the pores and mechanically and chemically attach to the substrate. The organic coating over the galvanized steel provides a second protective layer as well as a bonding layer, and the sealing barrier coating provides a triple level of protection for the metal structure. The barrier coating is an inert material that resists corrosive water conditions and chemicals in the water better than stainless steel, especially in high chloride environments.
The present invention is directed to a process for assembling and sealing a cooling tower, water basin or the like for holding water for cooling, evaporative or condensing systems. The process comprises the steps of forming panels in preconfigured shapes and sizes. The operator punches holes in the panels in a predetermined pattern, the holes spaced from the edges of the panel for further attachment of the barrier coating. The panels are galvanized steel of a type G-235 to provide a first corrosion resistant coating. The number following the G designation refers to the total coating weight on both sides of the sheet in hundredths of an ounce per square foot (oz/ft2) of sheet. Thus, G235 would have a minimum total 02.350 oz/ft2 of coating. The panels comprise a pre-adapted collection of steel panels for assembly into a holding basin. The panels are cleaned by an acid type cleaning solution such as phosphoric acid to remove contaminates followed by a rinse with water to remove the cleaner. The next step is to rinse again to insure the acid solution is removed. Next, the operator dries the panels using air and heat to thoroughly dry the metal and immediately thereafter coat the panels with an organic powder coating such as, for example epoxy, polyester, acrylics or hybrids that are homogenous and designed for application to metals. The powder is applied by electrostatic spray on both sides of the panel especially around the link holes and edges to a typical thickness of 0.004 inches. The coated metal panels are baked usually at around 250-600 degrees for 1 to 20 minutes to thermoset the powder coating 56. The time and temperature are predetermined values depending on the coating and thickness of the steel to cure the coating. The panels are cooled after curing and the clean and coated panels are assembled into subassemblies for application of the barrier coating. The elastomeric barrier coating application steps comprise, first applying in a liquid state, directly over the seams to form a preseal for the seams and prevent the elastomeric material from leaking through the seams during application. Next, the forms, if desired, are placed in the corners and where adjoining panels meet; next spraying the elastomeric material onto the basin including double spraying the seams and any exposed fasteners. The barrier coating coats the interior of the vessel and extends out of the basin and over the basin flange such that the barrier coating extends above the maximum standing liquid level and beyond the attachment to the upper structural section.
The present invention is directed to an elastomeric barrier coating that is double applied over seams and fasteners and extends from in the liquid holding area to outside the liquid holding area by application to the basin and extension along the mounting flange of the basin to a point separated from the inside of the basin by the attachment of the adjacently upper panel attaching to the basin with the liner edge between the respective mounting flanges where possible. Additional attributes of the elastomeric barrier coating include extension of the barrier coating outside the basin, link holes punched in the panels forming a mechanical link to the panel by a button-like knob of barrier coating material formed on the outside of the basin by the liquid elastomeric material flowing out of the link hole and hardening. The link seals the adjacent link hole. The elastomeric barrier coating may be selected from elastomeric coatings and appropriate additives having acid resistance, fast cure times, inert properties, high durability, fire retardancy, and/or ablative properties.
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1. Forming panels 12 in reconfigured shapes and sizes from galvanized steel panels having a type G-235 galvanized coating to provide a first corrosion resistant layer and substrate for subsequent coatings 70.
2. Modifying the panels 12 by bending flanges 46 and punching fastener holes 18 in the flanges for interconnecting the panels 12. The fastener holes 18 formed in a predetermined pattern spaced, from the edges of the panel.
3. Cutting link holes 50 by punching, drilling or other means in the panel 12 to provide mechanical link 52 between the barrier coating 26 and the panel 12.
4. Cutting source and drain holes in the panels at predetermined locations. The holes are sized to receive the outside diameter of the pipe stub therein.
5. Attaching source or drain pipe stubs concentrically into the respective source and drain holes by inserting the pipe stub in the respective hole having the inside end of the stub flush with the inside surface 44 of the basin 10 and welding the stub in place to sealingly attach the stub to the basin 10.
6. Cleaning the panels 12 by an acid type cleaning solution such as phosphoric acid to remove contaminates.
7. Rinsing the panels 12 with water to remove the acid type cleaner.
8. Rinsing the panels a second time to remove as much of the acid solution as possible from the panels 12.
9. Drying the panels using heat to thoroughly dry the metal and immediately thereafter,
10. Coating the panels including the inside and outside surface, including any attached pipe stubs with an organic powder coating such as, for example epoxy, polyester, acrylics or hybrids that are homogenous and designed for application to metals, by electrostatic spray on both sides of the panel especially around the binding holes and edges to a typical thickness of 0.004 inches.
11. Baking the coated metal panels to cure or thermoset the organic coating. The baking process performed in the preferred embodiment at around 250-600 degrees Fahrenheit for 1 to 20 minutes depending on the coating and thickness of the steel.
12. Cooling the panels after curing.
13. Assembling the coated panels into sub assemblies as required for shipping to the installation site.
14. Mixing any selected additives into the barrier coating components for desired mechanical or chemical properties of the barrier coating.
15. Sealing the seams between the panels 12 by application of a liquid state barrier coating material directly over the seams. The liquid barrier coating material preseals the seams and prevents the barrier coating material from leaking through the seams during the barrier coating application
16. Placing the forms, if desired, in the corners, between adjacent panels and where sides meet to provide a smooth transition between adjacent panels.
17. Spraying the elastomer barrier coating onto the inside of the basin 10 to form a seamless barrier coating 26 on the interior of the basin 10, including double spraying the seams and any exposed fasteners and spraying into each pipe stub a predetermined distance and along the vertical walls 32 of the basin and along the mounting flange 46.
18. Curing the barrier coating by time, heat or other method.
19. Shipping the subassemblies to the assembly site for further assembly of the unit structure.
20. Assembling the subassemblies together in a manner that minimizes the exposure of the edge of the barrier coating to water in the basin by capturing the liner 15 between adjacent subassemblies.
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In use, the basin is formed from prepared steel panels 12 made of galvanized steel with a zinc coating 70 thereon. The first protective layer is zinc applied during the galvanizing process. The second protective layer 56 is an organic powder electrostatically applied and cured on top of the zinc 70. Applying the organic powder coating 56 provides a clean dry surface and enhance the adhesion of the barrier coating 26 to the basin 10 also seals and protects the galvanized steel panels. The panels 12 are assembled into a basin 10 or other sub structure for holding water or liquid and other subassemblies are also assembled. The third protective layer comprising an elastomer material is sprayed on the basin 10. The elastomer barrier coating 26 material is applied first in liquid form to the seams 24, and joints and areas around the connecting pipes 47 to preseal 25 those areas. The third layer elastomeric barrier coating 26 is then applied by spraying the same or different multi-part elastomer material evenly over the entire inner surface 44 of the basin 10 to form a contiguous coating 26 over the entire interior surface of the basin 10 having the barrier coating 26 extending up to and out of the top of the basin along the mounting flange 46. The barrier coating 26 should preferably be sprayed to a minimum thickness such that the pre-seal layers are covered, and the liner 15 is a uniform thickness forming a smooth interior surface across the entire basin. The third elastomeric layer 26 is applied to a minimum is 1/16″ up to a preferred maximum of ⅛″. The third layer barrier coating 26 can be thicker to 1″ if the environment and liquid conditions require this thickness of protection. The barrier coating 26 is preferably extended above the maximum standing water level in the basin 10 to isolate the liner edge 48 from the water.
After preparing the panels 12 by cutting, punching, bending and welding, the organic powder coating 56 is applied to both sides of each panel, on the inside surface of the link holes 50 and over and inside the pipe stubs 47 and their welded connection to the panel 12. The organic coating 56 provides a fresh surface where the elastomeric barrier coating 26 adheres to the organic coating 56 better than adhering to the galvanized 70 (
The elastomer barrier coating 26 is preferably a two part polyurethane mixture. The multiple parts are mixed during the application process. In the present invention a spray gun is provided having inputs for each of the individual barrier coating components wherein the parts are mixed at a predetermined ratio while being atomized and propelled out of the gun at the nozzle to be applied to the surface of the vessel 10. The elastomeric barrier coating 26 materials may also be polyurea or a mixture of polyurea and polyurethane. It should also be understood the barrier coating material may have additives to adjust the cure time, improve UV resistance, change impact, slip and chemical resistance, add color to the barrier coating, and improve fire retardancy, and increase durability and traction among other attributes. Additional chemicals or accelerants can be mixed with the barrier coating mixture to accelerate cure time. In the preferred environment the partial cure time or setup time is calculated to be less than one minute to allow ongoing work on the vessel 10 shortly after application of the elastomer barrier coating 26, to reduce uneven application due to dripping, and allow multiple spray layers as in the pre-sealing of the seams of the basin. Additives with solvent properties to the organic bonding layer 56 may be added to the elastomer barrier coating 12 materials to provide an additional chemical bonding to the organic powder coating. Upon application the elastomer barrier coating material 12 would soften the outside surface of the organic coating causing a chemical mixture with the liquid barrier coating material. Upon curing the two layers, organic coating and barrier coating would be chemically bonded as well.
The elastomer third layer barrier coating 26 is applied to the inside wall 44 from the top flange 46 into each pipe stub 47 and along the sides 32 and bottom 30 and over the top flange 46 on the other side. The elastomer barrier coating 26 is applied to the basin 10 along the interior wall 44 of the sides 32 and the bottom 30 panels 12. The barrier coating 26 flows over the first coat preseal 25, applied to the seams 24 and fasteners 16, to form a multilayer homogenous barrier coating 26 sealing the seams 24 and protecting the substrate. The elastomer barrier coating 26 is preferably applied before the pre-seal 25 is fully set up to allow the maximum bonding between the barrier coating layer 26 and the preseal 25. The barrier coating 26 should preferably be sprayed to a thickness such that the pre-seal layers are covered, and the liner is a uniform thickness across the entire basin. The elastomer barrier coating is extended up along the sidewalls 32 and over mounting wall flange 46 to a point outside the basin where possible. The liner edge 48 is captured and compressed between the top flange 46 of the basin sub assembly and the bottom flange 148 of the mating panel to prevent any chance of water attacking the edge bond to the panel 12. Liner edge 48 is disposed outside the interior wall 44 of the basin 10 along the wall flange 46 between the fastener holes 18 and the panel edge 14 but may extend out to the edge of the flange 46. Link holes 50 are formed to extend through the panels 12 from the inside 44 to the outside 54. During application, the elastomer barrier coating 26 material flows out through the link holes 50 and forms a retaining knob 62 adjacent the exterior wall 54 of the basin 10 creating a mechanical button like link between the outer layer 54 and the inner layer 44 wherein the button 62 cannot pull through the link hole 50 and thereby holds the barrier coating to the panel 12, filling the hole and forming a mechanical link to the panel and the elastomer barrier coating 26, while simultaneously increasing the bonding surface area for greater adhesion compared to a flat surface only. The tie 60 and the knob 62 are formed of the elastomeric material of the barrier layer 26 which flows through the link hole 50 upon application of the barrier coating 26.
The vessel is filled with water usually treated with chemicals to control water chemistry and to prevent biological growth and circulated in the system for cooling or heat transfer, etc. The barrier coating protects the metal structure and seals the seams and link holes to contain the water and protect the steel panels. The seams 25 and link holes 50 provide a tattletale status of a leak or water seeping behind the barrier coating and next to the panel 12. If a rip or fault in the barrier coating 26 allows water between the barrier coating and the basin substrate, the water will seep out of the seam or link hole to indicate a problem with the barrier coating. This early indicator may allow repair of the barrier coating before corrosive damage happens to the underlying structural panel.
Although the invention has been described above in connection with particular embodiments and examples, it will be appreciated by those skilled in the art that the invention is not necessarily so limited, and that numerous other embodiments, examples, uses, modifications and departures from the embodiments, examples and uses are intended to be encompassed by the claims attached hereto. The entire disclosure of each patent and publication cited herein is incorporated by reference, as if each such patent or publication were individually incorporated by reference herein.
This application is a division of U.S. application Ser. No. 11/454,648, filed Jun. 16, 2006 now abandoned.
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Number | Date | Country | |
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20110117285 A1 | May 2011 | US |
Number | Date | Country | |
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Parent | 11454648 | Jun 2006 | US |
Child | 12931107 | US |