Weather can damage products. The damage includes fading, yellowing, color change, strength loss, embrittlement, oxidation, gloss loss, cracking, hazing and chalking, to name a few. Not only can sunlight cause damage to products, rain, including acid rain, can also damage products.
Most automobiles include a clear coating overtop a painted substrate, which can be metal or plastic. Damage to the automotive coating can occur from acid rain. “Water spot” etches can be formed from acid catalyzed hydrolysis that occurs in areas where acid rain occurred and temperatures were high. Etches are formed when material is lost from the surface of the coating. When enough bonds are broken, polymer molecules or fragments become detached from the rest of the coating and are washed away.
Attempts have been made at developing laboratory techniques to predict etch resistance of automotive clear coats. Accelerated weather testing apparatus have been developed to predict the affects of weather on coated substrates. Such accelerating weather testing apparatus include a test chamber into which a specimen is placed. Known accelerating weather testing apparatus do not accurately simulate the effects of acid rain and sunlight on coated substrates. Accordingly, it is desirable to provide such a weather testing apparatus, as well as methods for testing the performance of test specimens in such an apparatus.
Even though an accelerated weather testing apparatus is described with reference to etch resistance of a coating in the presence of acid rain, the apparatus described below is not limited to testing specimens only for acid rain performance. The apparatus can be used to examine the effects of light and/or corrosive solutions on a number of products including wood, roofing, textiles, inks, adhesives, sealants, packaging, plastics, metal, etc. The weather testing apparatus described below is amenable to other applications as well and is limited only by scope of the appended claims.
An accelerated weather testing apparatus includes a test chamber, a lamp, a dispenser, and a specimen support. The lamp is capable of generating UV radiation and directing the radiation towards the specimen support. The dispenser connects to an associated liquid source to dispense either water or an acid solution, or both. The specimen support is disposed in the test chamber below the lamp and the dispenser. The specimen support is configured such that it supports a test specimen in at least a substantially horizontal orientation.
A method for generating the effect of a corrosive solution on a test specimen in an accelerated weathering apparatus is also provided. The method includes positioning a test specimen at least substantially horizontally on the specimen support. The method further includes wetting the test specimen. The method further includes selectively emitting radiation from the lamp such that the radiation contacts the test specimen. The method also includes controlled drying of the test specimen.
A method for accelerated weathering of a test specimen in an accelerated weathering apparatus is provided. The method includes positioning a test specimen in the test chamber, selecting a desired irradiance, selecting a desired chamber air temperature, selecting a desired black panel temperature, selecting a desired chamber relative humidity, sensing the black panel temperature, sensing the chamber air temperature and sensing the chamber relative humidity. The method further includes comparing the sensed black panel temperature to the desired black panel temperature. The method also includes comparing the sensed chamber air temperature to the desired chamber air temperature. The method also includes adjusting the blower system in response to the previously mentioned comparing steps.
An accelerated weathering apparatus 10 includes a test chamber 12 that can include or communicate with a number of different components and systems, which will be described in more detail below. The accelerated weathering apparatus 10 includes a specimen support 14 disposed in the chamber 12, a lamp 16 that directs light toward the specimen support 14, and fluid dispensers 18 and 20 that dispense fluid towards the specimen support 14.
The test chamber 12 is large enough to hold a plurality of test samples. The test chamber 12 can also be large enough to hold lamps 16 and plumbing leading to the fluid dispensers 18 and 20. The test chamber can also be large enough to allow adequate space between the lamps 16 and the test specimens as well as allowing for adequate space between the fluid dispensers 18 and 20 and the test specimens. Adequate space allows for more uniform distribution of radiation and liquid onto test specimens.
The specimen support 14 is situated below the lamps 16 and the fluid dispensers 18 and 20. The specimen support can be a rack or tray large enough to hold a plurality of specimens. The specimen support, preferably, does not include upwardly extending sidewalls that would impede the flow of liquid running off of the samples. Alternatively, the specimen support includes drain holes to allow excess liquid to freely run off of the specimens so that the specimens are not submerged in liquid as they dry off. The specimen support is designed to support test specimens in a substantially horizontal orientation. Such a substantially horizontal orientation is preferably less than 15 degrees from horizontal, and more preferably less than 10 degrees from horizontal. Such a horizontal orientation advantageously simulates the orientation of the hood, top, or trunk of an automobile. The horizontal orientation promotes the formation of water droplets on the test specimens, which more accurately simulates the hood, top, or trunk of an automobile in that rain does not easily run off those substantially flat horizontal surfaces so that the droplets dry in place. The specimen support may be stationary or can move, for example rotate.
The lamp 16, which can be a xenon lamp or other suitable lamp, mounts near reflectors 22 and infrared (IR) mirrors 24. Furthermore, the lamp 16 can be filtered using filters 26 to simulate the spectrum that is emitted by sunlight. Such filters and filtering systems are known in the art. One lamp is shown schematically in
An irradiance controller 28 adjusts the lamp 16 output. The irradiance controller 28 can include a dimmer that controls the amount of power delivered to the lamp 16 to adjust the output. The irradiance controller 28 communicates with the lamp 16 and an irradiance sensor of the lamp 30, which measures the amount of light in the test chamber 12 and provides this information to the irradiance controller 28. The irradiance controller 28 can adjust the lamp output in accordance with values set by a user via an input control panel (not shown). An accelerated weathering apparatus including examples of an irradiance controller and an input control panel are shown for example in U.S. Pat. No. 5,206,518, hereby incorporated by reference.
A ballast 32 controls the power delivered to the lamp 16. The ballast 32 can communicate with the lamp 16 through a switch and timer mechanism 34 to control how long power is delivered to the lamp 16. The ballast 32 also communicates with the irradiance controller 28 to control the power delivered to the lamp in response to the input of the user. By using the switch and timer mechanism 34, the lamp 16 can be cycled, i.e. turned off and on to simulate day or night conditions. The switch and timer mechanism 34 can receive input from an input panel (not shown) so that the user can set specific cycle times.
In addition to subjecting the test specimen to radiation, the specimens can also be subjected to corrosive solutions. Two dispensers 18 and 20 are shown and described; however, one dispenser or a plurality of dispensers can be provided. The wetting of the specimens will be described with reference to apparatus that spray liquid onto the specimens; however, the specimen can be wet in any conventional manner. For example, the specimen can be immersed in solution. To immerse the specimen, the specimen can be placed in a tray having side walls and solution can be introduced into the tray to immerse the specimen.
With reference to
Describing the flow of the corrosive solution, a reservoir 42 stores the corrosive solution. The reservoir 42 communicates with a pump assembly 44 through a pipe 46. The pump assembly 44 pumps the corrosive solution through a pipe 48 towards a check valve 50 and the first dispenser 18. The first dispenser 18 includes the nozzles 36, which are disposed in the test chamber 12. The pipes and components in the flow path of the corrosive solution are constructed of suitable material such that they do not degrade in the presence of the corrosive solutions flowing through them.
Describing the flow of water from a water source (not shown), the water passes through a pipe 52 and communicates with a water filter 54 through a water inlet valve 56. The water is filtered in the water filter 54 and then passes into a pipe 58. Pipe 58 connects to a tee 62 where a pipe 64 connects at one outlet of the tee 62 and a flow switch 66 connects at the other outlet of the tee. The flow switch 66 controls the amount of water passing through it, sending any excess water through pipe 64 via tee 62. Pipe 64 connects to a water feed assembly 68 via pipe 72. The flow switch 66 communicates with a flow meter 74. The flow meter 74 measures the amount of water delivered to the second dispenser 20. The flow meter 74 communicates with a solenoid valve 76 via pipe 78. The solenoid valve 76 controls the amount of water delivered to the second dispenser 20. The solenoid valve 76 communicates with a pressure regulator 82 via pipe 84. A pressure gauge 86 is provided to measure the pressure of the water passing through the pressure regulator 82. The pressure regulator 82 regulates the pressure of the water delivered to the second dispenser 20. The pressure regulator 82 communicates with a pipe 88 which communicates with the second dispenser 20 via a check valve 92. The second dispenser 20 includes the nozzles 38, which are disposed in the test chamber 12.
The chamber 12 includes a drain 94 to remove the liquid from the chamber. The drain 94 connects with a pipe 96. The pipe 96 communicates with a drain pipe 98 through a coupling 102. The drain pipe 98 connects to a tee 104 that communicates with an outlet pipe 106 through a first outlet and the water feed assembly 68 via a second outlet. The water feed assembly supplies water to a humidifier, which will be described in more detail below, via a pipe 108.
To control the drying of the specimens in the test chamber 12, a conditioning system for controlling air conditions in the test chamber is provided. One embodiment of the conditioning system is shown including multiple blowers in communication with the test chamber 12. Nevertheless, other conditioning systems, for example one having a single blower and a damper, can also be used to control the air conditions inside the test chamber 12.
With reference to
Optionally, a first air temperature sensor 126 measures the air temperature, the operation of which will be described more fully below, before passing into a test chamber 12. The air flows into the test chamber and over one or more samples 132 disposed on the specimen support 14. Preferably, a black panel temperature 136 sensor mounts to the specimen support 14.
After passing around the specimen support 14, the air flows out of the test chamber 12 and into an exhaust duct 140, where a second chamber air temperature sensor 142 and a chamber humidity sensor 144 measure the exhaust air temperature and either relative humidity or wet bulb temperature. At this point, a recirculation air blower 146 optionally draws a portion of the air from the exhaust duct back into the air mixing duct 116 through a recirculated air inlet 148, where it mixes with the fresh air drawn in by the fresh air blower 112, for circulation through the system again. Air that is not drawn back into the system through the recirculation air blower 146 flows out of the system through an exhaust 150. As is described more fully below, a blower controller 152 controls the speeds of the fresh air blower 112 and the recirculation air blower 146 in order to control both the chamber air and black panel temperatures. While
Prior to performing a test in the weathering apparatus 10, an operator specifies or sets the applicable test parameters. Preferably, the desired irradiance (IRRSP) and at least one of the following: (i) the desired black panel temperature (BPTSP), and (ii) desired chamber air temperature (CATSP) are set. In addition, the desired relative humidity (RHSP) may be selected by the operator if the test to be performed requires such. It is to be appreciated that if only one of the CAT and BPT is specified, the other is estimated, either by formula or through a lookup table.
Artisans will appreciate that actual chamber air temperature (CAT) cannot be measured directly in the test chamber 12, because of the heating effect of the radiation from the lamps 16. Therefore, chamber air temperature is typically measured at the chamber outlet using the second chamber air temperature sensor 142. Alternatively, the actual chamber air temperature or dry bulb temperature is measured using an average of the temperature readings from the first chamber air sensor 126, which is located at the test chamber inlet, and the temperature reading of the second chamber air temperature sensor 142 located at the chamber outlet. It is to be appreciated that either a weighted or simple average of the temperatures from the first and second chamber air temperature sensors may be employed.
In one embodiment, the black panel temperature sensor 136 includes an uninsulated black panel sensor, which measures actual black panel temperature (BPT). Alternately, the black panel temperature sensor 136 includes an insulated black panel sensor which measures actual black standard temperature (BST). It is to be appreciated that in the below-described control methods, BPT and BST may be used interchangeably, depending on the requirements of the weathering test being performed. In one embodiment, the chamber humidity sensor 144 includes a conventional relative humidity sensor. In an alternate embodiment, relative humidity is calculated or looked up based on measurements from a wet-bulb temperature sensor, along with temperature readings from one or both of the chamber air temperature sensors 126, 142, which provide dry bulb temperatures.
With reference to
With reference to
With reference to
Concurrently, the chamber air temperature (CAT) is measured 240 and compared 260, 280 to the CAT set point, CATSP. More particularly, if the CAT is above the set point, the speed of the recirculation blower is decreased 290. Further, if the CAT is below the set point 280, the air heater is enabled 295. It is to be appreciated that in this embodiment the two blowers are controlled by the blower controller as two automatic closed-loop systems. That is, the speed of the fresh air blower (SF) controls and is determined by the BPT, while the speed of the recirculation air blower (SR) controls and is determined by the CAT. Alternatively, the blower controller controls the two blowers as two automatic closed-loop systems where SF controls and is determined by CAT, while SR controls and is determined by BPT. In this embodiment, as the measured temperatures rise, the respective blowers increase in speed. In this embodiment, the air heater may be used in conjunction with the fresh air blower to provide an additional range for the CAT.
With reference to
Initially, the desired irradiance is set 300. In addition, the desired BPT and CAT are set 310, 320. The measured BPT 330 is compared 340 to the set BPT. In addition, the CAT is measured 350 and compared 360 to the CAT set point. In this embodiment, if the BPT is at the set point, and the CAT is below the set point, the fresh air fraction RFRESH is decreased 370, while the total blower speed STOTAL is held constant. In other words, the speed of the fresh air blower is reduced while the speed of the recirculated air blower is increased. If the BPT is below the set point, while the CAT is at or above the set point, the fresh air fraction remains constant while the total blower speed is reduced 380. In other words, both the fresh air blower speed and the recirculated air blower speed are decreased. In this embodiment, the air heater may be used to increase the range of temperatures that is achievable.
With reference to
The radiance is set 400 to the desired value. In addition, the BPT and CAT are both set 410, 420 to their respective desired values. Both the BPT and CAT are measured 430, 450 and compared 440, 460 to the respective set points. In this embodiment, if the BPT is at the set point, but the CAT is below the set point, STOTAL is held constant, while the blower speed ratio RSPEED is decreased 470. In other words, the fresh air blower speed SF is reduced, while the recirculated air blower speed SR is increased. Alternately, if the BPT is below the set point, while the CAT is at or above the set point, the blower speed ratio RSPEED remains constant while the total blower speed STOTAL is decreased, that is, both SF and SR are decreased. In this embodiment, the air heater may be used to increase the range of achievable temperatures.
In an alternative embodiment, the blower controller controls the fresh air blower and the recirculation air blower as two open-loop systems. In this embodiment, the speed of the fresh air blower and the speed of the recirculation air blower are each independently controlled manually, such as with a potentiometer attached to a motor speed controller. By adjusting the two blower speeds, the BPT and CAT of the system are each adjusted, although somewhat interdependently, to fall within specified ranges. If desired, one or more air heaters are employed in conjunction with the fresh air and/or recirculated air blowers to provide a greater range of chamber temperatures.
It is to be appreciated that in any of the above-identified multiple-blower temperature control methods, the blower speeds may be held within fixed maximum and minimum values, and/or within floating maximum and minimum values, depending on the operation of each of the blowers. The floating limits are useful because a minimum speed of one blower may be necessary to block the flow from the other blower passing the wrong way through it. For example, if 100% fresh air is required for a certain test, the fresh air blower spins at the speed which provides the needed airflow. However, if the recirculation air blower is stopped, a significant amount of fresh air reverse flows through the recirculated air blower and out the machine exhaust. To prevent this, the recirculation air blower is operated at a slower “blocking” speed, thereby stopping this leakage and providing the full output of the fresh air blower to the test chamber.
Further, if desired, once the blower speeds are established, the speed of the fresh air blower may be increased by a nominal amount, 10% for example, and the recirculation air blower adjusted to yield the equivalent total flow. In this embodiment, the air heater fine tunes the air temperature, yielding more stable temperatures.
Referring again to
The apparatus described above provides the user great flexibility in conducting weathering tests on specimens. Tests can be run where the specimen is dosed with a solution that simulates acid rain. For example, the dispensing of solution onto the test specimen can be controlled to dispense so that droplets form on the specimen ranging from one cm to 24 cm (as seen in
The apparatus and method have been described with reference to the preferred embodiment. Modifications and alterations will occur to others upon a reading and understanding of the preceding detailed description. It is intended that the invention be construed as including all such modifications and alterations insofar as they come within the scope of the appended claims or the equivalents thereof.
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/US04/06123 | 3/1/2004 | WO | 3/24/2006 |
Number | Date | Country | |
---|---|---|---|
60505669 | Sep 2003 | US |