The present invention is directed to a system, method, and device for optical techniques. More specifically, the present device provides a laser diode with broad or multi-peaked spectral output. In certain embodiments, multi-peak spectral output is obtained by having a single laser diode device generating multiple-peak or broad spectral outputs. In a specific embodiment, a laser diode is configured to operate in superluminescene mode. In other embodiments, a laser diode provides multiple-peak or broad spectral outputs by having an RF source and/or a feedback signal. In some embodiments, the multi-peak outputs are achieved by having multiple laser devices output different lasers at different wavelengths.
In 1960, the laser was first demonstrated by Theodore H. Maiman at Hughes Research Laboratories in Malibu. This laser utilized a solid-state flash lamp-pumped synthetic ruby crystal to produce red laser light at 694 nm. By 1964, blue and green laser output was demonstrated by William Bridges at Hughes Aircraft utilizing a gas laser design called an Argon ion laser. The Ar-ion laser utilized a noble gas as the active medium and produce laser light output in the UV, blue, and green wavelengths including 351 nm, 454.6 nm, 457.9 nm, 465.8 nm, 476.5 nm, 488.0 nm, 496.5 nm, 501.7 nm, 514.5 nm, and 528.7 nm. The Ar-ion laser had the benefit of producing highly directional and focusable light with a narrow spectral output, but the wall plug efficiency was <0.1%, and the size, weight, and cost of the lasers were undesirable as well.
As laser technology evolved, more efficient lamp pumped solid state laser designs were developed for the red and infrared wavelengths, but these technologies remained a challenge for blue and green and blue lasers. As a result, lamp pumped solid state lasers were developed in the infrared, and the output wavelength was converted to the visible using specialty crystals with nonlinear optical properties. A green lamp pumped solid state laser had 3 stages: electricity powers lamp, lamp excites gain crystal which lases at 1064 nm, 1064 nm goes into frequency conversion crystal which converts to visible 532 nm. The resulting green and blue lasers were called “lamped pumped solid state lasers with second harmonic generation” (LPSS with SHG) had wall plug efficiency of ˜1%, and were more efficient than Ar-ion gas lasers, but were still too inefficient, large, expensive, fragile for broad deployment outside of specialty scientific and medical applications. Additionally, the gain crystal used in the solid state lasers typically had energy storage properties which made the lasers difficult to modulate at high speeds which limited its broader deployment.
To improve the efficiency of these visible lasers, high power diode (or semiconductor) lasers were utilized. These “diode pumped solid state lasers with SHG” (DPSS with SHG) had 3 stages: electricity powers 808 nm diode laser, 808 nm excites gain crystal which lases at 1064 nm, 1064 nm goes into frequency conversion crystal which converts to visible 532 nm. The DPSS laser technology extended the life and improved the wall plug efficiency of the LPSS lasers to 5-10%, and further commercialization ensue into more high end specialty industrial, medical, and scientific applications. However, the change to diode pumping increased the system cost and required precise temperature controls, leaving the laser with substantial size, power consumption while not addressing the energy storage properties which made the lasers difficult to modulate at high speeds.
Various types of lasers as described above have many applications. Typically, these laser devices emit laser light having a spectrum width of less than 1 nm. For example, “spectral width” refers to the full-width at half-maximum (FWHM) of the spectral envelope emitted from the light emitting device. Narrow laser spectrum is preferred for certain type of application, such as laser pointing device. However, narrow spectrum laser devices are often unsuitable to applications such as laser-based projection. In various applications, broad spectrum (e.g., a spectral width of 1 nm or greater) is often desirable.
This invention provides a gallium and nitrogen containing (e.g., GaN) laser diode having a broad or multi-peaked spectral output. The device includes a gallium and nitrogen containing substrate having a first crystalline surface region orientation. The device also includes an active region having at least one quantum well, each of the quantum wells having a thickness of at least 2.0 nm and at least one barrier layer. Each of the barrier layers has a thickness ranging from about 2 nm to about 20 nm. Each of the barrier layers is configured between a pair of quantum wells. The device also includes a cavity member at least 100 um long over the active region. The cavity has a width of at least 0.5 um, with one end having reflectivity of at least 90% and the other end having reflectivity of 0.5% or less. The cavity member is emits laser light characterized by a spectral width of at least 1 nm.
In another embodiment the device also includes an active region including a barrier layer and a light emission layer characterized by a graduated profile associated with a peak emission wavelength gradient. The peak emission wavelength gradient has a deviation of about 1 to 40 nm. The device includes a cavity member over a first portion of the emission layer. The cavity member has a length of at least 100 um and a width of at least 0.5 um. A second cavity member overlies a second portion of the emission layer, the second portion of the emission layer being associated with a second wavelength which is within 50 nm of the first wavelength. The second cavity member has a length of at least 100 um and a width of at least 0.5 um.
In another embodiment, the first emission layer is characterized by a first gain peak wavelength, and the second emission layer is characterized by a second gain peak wavelength. The difference between the first gain peak wavelength and the second gain peak wave length is at least 1 nm.
A method for making the device includes growing a plurality of light emission layers within the active region using a selective area epitaxy process. In addition the method can include growing a first emission layer within the first active region, the first emission layer having a first gain peak wavelength. The method additionally includes defining a second active region by performing a selective etching process, and growing a second emission layer within the second active area, which is characterized by a second gain peak wavelength.
According to yet another embodiment, the device also includes an active region comprising a barrier layer and a plurality of light emission layers, which includes a first emission layer and a second emission layer. The barrier layer is characterized by a first energy level. The first emission layer is characterized by a first gain peak wavelength and a second lower energy level. The first emission layer has a first amount of atoms diffused from the barrier layer. The second emission layer is characterized by a second gain peak wavelength. The difference between the first gain peak wavelength and the second gain peak wave length is at least 1 nm.
According to yet another embodiment, the device includes a current source, and the first active region is electrically coupled to the current source. The first peak wavelength is based on a first amount of current received from the current source. The device also includes a second active region electrically coupled to the current source. The second peak wavelength is based on a second amount of current received from the current source.
According to yet another embodiment, the device includes an active region comprising at least one quantum well or double hetereostructure and one barrier layer. The device additionally includes an RF source electrically coupled to the active region for providing RF modulation, which is configured to induce mode hopping or modulation of the peak wavelength. The RF modulation can be applied in addition to the direct current (DC) or alternating current (AC) required to drive the laser for the given application. The RF signal functions to broaden the spectral output of the laser device by at least 20% or at least 50%. The cavity member is configured to emit laser characterized by a spectral width of at least 1 nm. In another embodiment, the device also includes an optical feedback signal source coupled to the optical cavity for inducing mode hopping or spectral broadening.
According to yet another embodiment, the device also includes a region of insulating material having two or more growth regions provided on the surface region. The two or more growth regions are exposed regions of the surface region. The device additionally includes an array configuration formed by the growth regions. The device also includes a first semi-polar gallium indium containing crystalline material provided on a portion of the first growth region of the gallium containing substrate structure, the first semi-polar gallium indium containing crystalline material having a thickness of about 1 nanometers to about 20 nanometers. A second semi-polar gallium indium containing crystalline material is provided on a portion of the second growth region. The second semi-polar gallium indium containing crystalline material having a thickness of about 1 nanometers to about 20 nanometers. The device includes a indium concentration characteristic associated with the wavelength characteristics.
According to yet another embodiment, the present invention provides a method for manufacturing an optical device. The method includes providing a gallium containing substrate structure having a surface region, then defining a region of insulating material having growth regions. The method includes providing a semi-polar gallium indium containing crystalline material on the growth regions, preferably having a thickness of about 1 nanometer to about 20 nanometers.
The present invention enables a cost-effective optical device for laser applications. The optical device can be manufactured in a relatively simple and cost effective manner. In some embodiments, the laser device is capable of emitting broad spectrum of wavelengths having a spectral width of about 1 nm to 10 nm. Preferably, the laser diode is formed on a nonpolar or semipolar gallium and nitrogen containing material such as the {20-21} or the {20-2-1} or miscuts from these planes configured for emissions at about 510 nm and greater.
In certain embodiments, multi-peak spectral output is obtained by having a single laser diode device generating multiple-peak spectral outputs. In a specific embodiment, a laser diode is configured to operate in superluminescene or like mode. In other embodiments, a laser diode provides multiple-peak spectral outputs by having an RF source and/or a feedback signal. In some other embodiments, multi-peak outputs are achieved by having multiple laser devices output different lasers at different wavelengths.
In various embodiments, the invention provides broad spectrum laser diode devices implemented using superluminescent diodes (SLD) on nonpolar and semipolar Ga-containing substrates for use as the light source in applications where broad spectral output is preferred. Since superluminescent diodes can be designed to achieve both high brightness and broad spectral properties while maintaining the beam characteristics and high output directionality of light laser diodes, such SLDs are suited for applications where typical laser diodes cannot provide adequate spectral width for optimal system performance. For example, wide spectrum laser devices are useful in laser display applications.
It is known that a superluminescent diode (SLD) is an edge-emitting semiconductor light source based on superluminescence scheme. It combines the high power and brightness of laser diodes with the low coherence of conventional light-emitting diodes. The typical emission band for SLD is about 10 to 100 nm wide.
The device illustrated in
The substrate 102 comprises gallium nitride material and is a bulk GaN substrate characterized by having a semipolar or non-polar crystalline surface region. In a specific embodiment, the bulk nitride GaN substrate includes nitrogen and has a surface dislocation density below 105 cm−2 to about 108 cm−2. The nitride crystal or wafer may comprise AlxInyGa1-x-yN, where 0≦x, y, x+y≦1. The GaN substrate usually has threading dislocations, at a concentration between about 105 cm−2 and about 108 cm−2, in a direction that is substantially orthogonal or oblique with respect to the surface. As a consequence of the dislocations, the surface dislocation density is below about 105 cm−2 or about 108 cm−2. The device can be fabricated on a slightly off-cut semipolar substrate as described in U.S. Provisional No. 61/164,409 filed Mar. 28, 2009, commonly assigned, and hereby incorporated by reference.
The optical device 100 also includes a cavity member 101. As shown in
The optical device 100 is formed using epitaxial growth and cleave properties on semipolar crystal planes oriented between the nonpolar m-plane and the polar c-plane. In particular, the substrate grown on the {30-31} and {20-21} families of crystal planes, which includes {30-3-1} and {20-2-1}. The epitaxy structures and cleaves allow efficient laser diodes operating at wavelengths from about 400 nm to green, e.g., 500 nm to 540 nm. These results include bright blue epitaxy in the 450 nm range, bright green epitaxy in the 520 nm range, and smooth naturally occurring cleave planes orthogonal to the projection of the c-direction. It is desirable to align the laser cavities parallel to the projection of the c-direction for maximum gain on this family of crystal planes. Using these technologies, we have demonstrated a laser device on {20-21} operating at 522 nm with a cavity oriented in the projection of the c-direction. An example of one or more laser devices is described in U.S. Provisional No. 61/243,502 filed Sep. 17, 2009, commonly assigned, and hereby incorporated by reference for all purposes.
In a preferred embodiment, the device has a first cleaved facet provided on the first end 107 of the laser stripe region and a second cleaved facet provided on the second end 109 of the cavity member 101. In one or more embodiments, the first cleaved is substantially parallel with the second cleaved facet. Smooth surfaces with different reflectivities are formed on each of the cleaved surfaces. The first cleaved facet comprises a highly reflective surface. For example, the reflectivity of the first surface is 90% or greater. In a preferred embodiment, the first cleaved surface is provided by a top-side skip-scribe scribing and breaking process. The scribing process can use any suitable techniques, such as a diamond scribe or laser scribe or combinations. Typically, the surface resulting from the scribing process is not up to a desired reflectivity. In a specific embodiment, the first mirror surface comprises a reflective coating, which increase cause the first mirror surface to have the desired reflectivity. The reflective coating is selected from silicon dioxide, hafnia, and titania, tantalum pentoxide, zirconia, including combinations, and the like.
The second cleaved surface comprises an anti-reflective coating. As explained above, the cleaved surface may not have the desired reflectivity (either high or low). To make the second cleaved surface anti-reflective (or have a very low level of reflectivity), an anti-reflective coating is applied. For example, the second cleaved surface is characterized by a reflectivity of less than 0.5%. In one specific embodiment, the second cleaved surface is characterized by a reflectivity of less than 0.05%.
As explained above, the optical device 100 is configured to provide wide spectrum laser with a spectral width of 1-20 nm. More specifically, the optical device 100 utilizes a superluminescent diode (SLD design). In a specific embodiment where a superluminescent diode is used, a laser diode geometry can be employed where the cavity length can range from 100 um to 3000 um and the cavity width can range from 0.5 um to 50 um.
Depending on the specific implementations, optical confinement of the mode or waveguiding can be achieved with index guiding or gain guiding. In one embodiment where an index guided scheme is used, transverse confinement is a result of the higher index associated with the light emitting layers relative to the cladding layers. In one specific embodiment, one or more InGaN emitting layers are sandwiched between GaN cladding layers.
Lateral index guiding could be achieved with various types of designs, which include surface ridge laser architectures, deep ridge architectures, buried hetereostructure architectures, and disordering of the light emitting constituent layers. In alternative embodiments, lateral modal confinement is provide to utilize gain guiding such that selective excitation of the gain providing material with electrical carriers dictates the lateral extent of the optical field. An example of this approach would be a wide stripe broad area laser that uses metal electrodes to selectively excite the material.
As described above, the cavity member 107 have cleaved surfaces at the first end 107 and the second end 109. Reflectivity of the cleaved surfaces can be modified in various ways, such as by application of coatings that can either increase the reflectivity for high-reflectivity (HR) coatings or decrease the reflectivity for anti-reflective (AR) coatings. Such coatings are often formed by deposition of carefully designed dielectric stacks in which the dielectric layers' index, thickness, and number of periods sets the reflectivity. Conventional laser diodes are designed with mirror reflectivity to provide the best efficiency trade-off of output power and threshold current for the required application. For applications where low threshold current and low power are required, HR coatings are often employed on both mirrors on the cavity with the front mirror where light will be collected from having slightly lower reflectivity. For applications where high powers are required and the threshold current has a reduced influence on the efficiency, an HR coating is used for the back mirror and an AR coating is often used for the front mirror since the reduced reflectivity of the AR-coated mirror will allow more light to escape the cavity for higher output powers. An alternative embodiment would use an angled mirror facet to reduce the reflectivity of the front mirror. This could be used in addition to an anti-reflective coating.
The SLD design according to embodiments of the present invention operates in accordance to superluminescent principles. For example, in case of spontaneous emission, semiconductors typically exhibit an emission spectra with a full width at half maximum (FWHM) on the order of 15-100 nm, depending on the material system and center emission wavelength. An example of such a device operating in nearly complete spontaneous regime would be a light emitting diode (LED). For case of the laser diode where optical feedback is present and stimulated emission is present, the emission spectra narrows as the optical intensity increases and the output becomes more coherent. In a conventional multi-longitudinal mode laser, the output spectrum narrows to ˜1 nm at the onset of lasing, which is not desirable for light sources in many applications. By reducing the reflectivity of the front mirror to the point where the device cannot achieve threshold, the lasing action, and hence spectral narrowing, can be suppressed and the device will operate as a superluminescent diode (SLD). By careful design and control over the cavity design, the SLD can be made to operate with spectral widths ranging from 1 to 20 nm.
In various embodiments, the present invention provides a method for fabricating SLD devices on nonpolar and semipolar Ga containing substrates for applications where high brightness and broad spectral width are desired. In one embodiments, conventional semiconductor laser fabrication techniques can be employed with emphasis on the gain and loss properties of the cavity such that the optimal spectral width and brightness can be achieved in an output beam similar to that of a laser diode. As shown in
In some embodiments multiple emitters operating at different peak wavelengths are used, i.e. two or more spectral lasing peaks. Two or more spectral peaks are achieved by positioning laser diode cavities adjacent to each other such that the side-by-side emitters operate at different peak wavelengths.
One way to create a lasing output spectrum with two or more peaks involves positioning two or more laser cavities side-by-side such that the individual output spectrums could be convolved and captured into a single beam. Adjacent laser diodes can utilize conventional in-plane laser geometries with cavity lengths ranging from 100 um to 3000 um and cavity widths ranging from 0.5 um to 50 um. In a specific embodiment, side-by-side lasers are separated from one another at distances of about 1 um to 500 um. Depending on the application, these lasers can share a common set of electrodes or use separate electrodes.
As shown in
In a specific embodiment, the device also has an overlying n-type gallium nitride layer 205, an active region 207, and an overlying p-type gallium nitride layer structured as a laser stripe region 209. In a specific embodiment, each of these regions is formed using at least an epitaxial deposition technique of metal organic chemical vapor deposition (MOCVD), molecular beam epitaxy (MBE), or other epitaxial growth techniques suitable for GaN growth. In a specific embodiment, the epitaxial layer is a high quality epitaxial layer overlying the n-type gallium nitride layer. In some embodiments the high quality layer is doped, for example, with Si or O to form n-type material, with a dopant concentration between about 1016 cm−3 and 1020 cm−3.
In a specific embodiment, an n-type AluInvGa1-u-vN layer, where 0≦u, v, u+v≦1, is deposited on the substrate. In a specific embodiment, the carrier concentration may lie in the range between about 1016 cm−3 and 1020 cm−3. The deposition may be performed using metalorganic chemical vapor deposition (MOCVD) or molecular beam epitaxy (MBE).
As an example, the bulk GaN substrate is placed on a susceptor in an MOCVD reactor. After closing, evacuating, and back-filling the reactor (or using a load lock configuration) to atmospheric pressure, the susceptor is heated to a temperature between about 1000 and about 1200 degrees Celsius in the presence of a nitrogen-containing gas. In one specific embodiment, the susceptor is heated to approximately 1100 degrees Celsius under flowing ammonia. A flow of a gallium-containing metalorganic precursor, such as trimethylgallium (TMG) or triethylgallium (TEG) is initiated, in a carrier gas, at a total rate between approximately 1 and 50 standard cubic centimeters per minute (sccm). The carrier gas may comprise hydrogen, helium, nitrogen, or argon. The ratio of the flow rate of the group V precursor (ammonia) to that of the group III precursor (trimethylgallium, triethylgallium, trimethylindium, trimethylaluminum) during growth is between about 2000 and about 12000. A flow of disilane in a carrier gas, with a total flow rate of between about 0.1 and 10 sccm, is initiated.
In a specific embodiment, the laser stripe region is made of the p-type gallium nitride layer 209. In a specific embodiment, the laser stripe is provided by an etching process selected from dry etching or wet etching. In a preferred embodiment, the etching process is dry. As an example, the dry etching process is an inductively coupled process using chlorine bearing species or a reactive ion etching process using similar chemistries. Again as an example, the chlorine bearing species are commonly derived from chlorine gas or the like. The device also has an overlying dielectric region, which exposes 213 contact region. In a specific embodiment, the dielectric region is an oxide such as silicon dioxide or silicon nitride. The contact region is coupled to an overlying metal layer 215. The overlying metal layer is a multilayered structure containing gold and platinum (Pt/Au), nickel gold (Ni/Au).
In a specific embodiment, the laser device has active region 207 which can include one to twenty quantum well regions. As an example following deposition of the n-type AluInvGa1-u-vN layer for a predetermined period of time, so as to achieve a predetermined thickness, an active layer comprised of multiple quantum wells can be formed, e.g. with 2-10 quantum wells. The quantum wells preferably, InGaN with GaN barrier layers separating them. In other embodiments, the well layers and barrier layers comprise AlwInxGa1-w-xN and AlyInzGa1-y-zN, respectively, where 0≦w, x, y, z, w+x, y+z≦1, where w<u, y and/or x>v, z so that the bandgap of the well layer(s) is less than that of the barrier layer(s) and the n-type layer. The well layers and barrier layers may each have a thickness between about 1 nm and about 20 nm. The composition and structure of the active layer are chosen to provide light emission at a preselected wavelength. The active layer may be left undoped (or unintentionally doped) or may be doped n-type or p-type.
The active region can also include an electron blocking region, and a separate confinement heterostructure. In some embodiments, an electron blocking layer is preferably deposited. The electron-blocking layer may comprise AlsIntGa1-s-tN, where 0≦s, t, s+t≦1, with a higher bandgap than the active layer, and may be doped p-type. In one specific embodiment, the electron blocking layer comprises AlGaN. In another embodiment, the electron blocking layer comprises an AlGaN/GaN super-lattice structure, comprising alternating layers of AlGaN and GaN, each with a thickness between about 0.2 nm and about 5 nm.
As noted, the p-type gallium nitride structure is deposited above the electron blocking layer and active layer(s). The p-type layer may be doped with Mg, to a level between about 1016 cm−3 and 1022 cm−3, and may have a thickness between about 5 nm and about 1000 nm. The outermost 1-50 nm of the p-type layer may be doped more heavily than the rest of the layer, so as to enable an improved electrical contact. In a specific embodiment, the laser stripe is provided by an etching process selected from dry etching or wet etching. In a preferred embodiment, the etching process is dry. The device also has an overlying dielectric region, which exposes 213 contact region. In a specific embodiment, the dielectric region is an oxide such as silicon dioxide.
In a specific embodiment, the metal contact is made of suitable material. The reflective electrical contact may comprise at least one of silver, gold, aluminum, nickel, platinum, rhodium, palladium, chromium, or the like. The electrical contact may be deposited by thermal evaporation, electron beam evaporation, electroplating, sputtering, or another suitable technique. In a preferred embodiment, the electrical contact serves as a p-type electrode for the optical device. In another embodiment, the electrical contact serves as an n-type electrode for the optical device.
Depending on the application, a laser device may include multiple quantum wells to widen spectral width of laser devices. For example, typical multi-longitudinal-mode Fabry-Perot laser diodes exhibit a lasing spectrum with envelope function containing the cavity modes that is 0.1 nm to 1.0 nm. As explained above, wider spectral envelopes would be desirable in laser display applications where speckle is a consideration. In various embodiments, blue lasers operating in the 435-460 nm range on nonpolar or semipolar substrates fabricated according to the present invention can have a broad lasing spectrum in the range of 3 to 6 nm. For example, the broad spectral range is accomplished by increasing the number of quantum wells from 3 to 7, in which a noticeable broadening is achieved (e.g., from which the full width at half maximum (FWHM) increases from about 1 nm to 2 nm). Further, when increasing the barrier thickness from the 4 nm to 7 nm range to the 8 nm to 12 nm range, the FWHM lasing spectrum can be increased to over 4 nm.
In one embodiment, a laser diode includes a gallium and nitrogen containing substrate including a first crystalline surface region orientation. The laser diode also includes an active region comprising at least four quantum wells, each of the quantum wells having a thickness of 3 nm and greater and one or more barrier layers, each of the barrier layers having a thickness of at least 4 nm, each of the barrier layers being configured between a pair of quantum wells. Additionally, the laser diode includes a cavity member overlaying the active region, the cavity member having a first end and a second end, the cavity member being configured to emit a highly directional beam of light characterized by a lasing spectrum full width half maximum of greater than 1.5 nm.
According to a specific embodiment, a laser diodes are fabricated on a nonpolar or semipolar substrate with a multiple quantum well active region containing 2 or more quantum wells that are 2 nm or greater in thickness, barriers that are 7 nm or greater, and a lasing spectrum full width half maximum of greater than 1.5 nm. In one embodiment, the peak wavelength of the lasing spectrum is in the 430 nm to 465 nm range. In another embodiment, the peak wavelength of the lasing spectrum is in the 510 nm to 550 nm range.
According to an embodiment, the as-grown material gain peak is varied spatially across a wafer. As a result, different peak wavelength can be obtained from one fabricated laser to the next laser on the same wafer. The as-grown gain peak wavelength can be shifted using various method according to embodiments of the present invention. The growth non-uniformity can be obtained a result of temperature and/or growth rate gradients in the light emitting layers in the epitaxial growth chamber. Such wavelength gradients can be intentional or non-intentional, and the differences in wavelengths range from 1 to 40 nm deviation. This method enables multiple lasers on the same chip to operate at different wavelengths.
According to an embodiment, the following steps are performed in a method for forming a device that includes laser devices having multiple wavelengths:
As explained above, the substrate member may have a surface region on the polar plane (c-plane), nonpolar plane (m-plane, a-plane), and semipolar plain ({11-22}, {10-1-1}, {20-21}, {30-31}. {20-2-1}, {30-3-1}). Depending on the specific application, the graduated profile for the light emission layer may be formed in various ways, such as providing temperature gradient when forming the emission layer. In a specific embodiment, the graduated profile for the light emission layer is formed having a growth rate gradient as the light emission layer is formed. There are other ways for obtaining graduated profile in the light emission layer as well.
In a specific embodiment, a laser apparatus having a broad spectrum is provided. The laser apparatus includes a gallium and nitrogen containing substrate including a first crystalline surface region orientation. For example, the substrate member may have a surface region on the polar plane (c-plane), nonpolar plane (m-plane, a-plane), and semipolar plain ({11-22}, {10-1-1}, {20-21}, {30-31}, {20-2-1}, {30-3-1}). The laser apparatus also includes an active region comprising a barrier layer and a light emission layer, the light emission layer being characterized by a graduated profile associated with a peak emission wavelength gradient, the peak emission wavelength gradient having a deviation of about 1 to 40 nm. In various embodiments, the active region may include multiple active and barrier layers, as well as cladding layers. For example, the various layers of the active layer are doped in n or p type. The laser apparatus includes a first cavity member overlaying a first portion of the emission layer, the first portion of the emission layer being associated with a first wavelength, the first cavity member being characterized by a length of at least 100 um and a width of at least 0.5 um. The laser apparatus also includes a second cavity member overlaying a second portion of the emission layer, the second portion of the emission layer being associated with a second wavelength, a difference between the first and second wavelengths being less than 50 nm, the second cavity member being characterized by a length of at least 100 um and a width of at least 0.5 um. Depending on the implementation, the laser apparatus may includes additional cavity members overlaying the active region and correspond to different wavelengths. For example, the cover members have mirror surfaces and function as waveguide for the laser devices.
According to an embodiment, the following steps, using SAE techniques, are performed in a method for forming a device that includes laser devices having multiple wavelengths:
It is to be appreciated that the method described above can be implemented using various types of substrate. As explained above, the substrate member may have a surface region on the polar plane (c-plane), nonpolar plane (m-plane, a-plane), and semipolar plain ({11-22}, {10-1-1}, {20-21}, {30-31}, {20-2-1}, {30-3-1}). For example, during the growth phase of the light emission layer, growth areas are defined by dielectric layers. In a specific embodiment, the emission layers at each of the growth area have different spatial dimensions (e.g., width, thickness) and/or compositions (e.g., varying concentrations for indium, gallium, and nitrogen). In a preferred embodiment, the growth areas a configured with one or more special structures that include from annular, trapezoidal, square, circular, polygon shaped, amorphous shaped, irregular shaped, triangular shaped, or any combinations of these. For example, each of the emission layers is associated with a specific wavelength. As explained above, differences in wavelength among the emission layers may can range from 1 nm to 40 nm.
In a specific embodiment, a laser apparatus manufactured using SAE process and having a broad spectrum is provided. The laser apparatus includes a gallium and nitrogen containing substrate including a first crystalline surface region orientation. For example, the substrate member may have a surface region on the polar plane (c-plane), nonpolar plane (m-plane, a-plane), and semipolar plain ({11-22}, {10-1-1}, {20-21}, {30-31}, {20-21}, {30-31}). The laser apparatus also includes an active region comprising a barrier layer and a plurality of light emission layers, the plurality of light emission layers including a first emission layer and a second emission layer, the first emission layer being characterized by a first gain peak wavelength, the second emission layer being characterized by a second gain peak wavelength, a difference between the first gain peak wavelength and the second gain peak wave length is at least 10 nm. In various embodiments, the active region may include multiple active and barrier layers, as well as cladding layers. For example, the various layers of the active layer are doped in n or p type. The laser apparatus additionally includes a first cavity member overlaying the first emission layer, the first cavity member being characterized by a length of at least 100 um and a width of at least 0.5 um. The laser apparatus further includes a second cavity member overlaying the second the emission layer, the second cavity member being characterized by a length of at least 100 um and a width of at least 0.5 um.
In certain embodiments of the present invention, multiple laser peak wavelength is obtained by providing multiple active regions, and each of the active regions is associated with a specific wavelength. More specifically, multiple growth of active regions is performed across a single chip. In this technique a wafer is loaded in a growth chamber for the growth of an active region with one gain peak. After this growth, the wafer is subjected to one or more lithography and processing steps to remove a portion of the active region in some areas of the wafer. The wafer would then be subjected to a second growth where a second active region with a second peak gain wavelength is grown. Depending on the specific need, the processes of growing and removing active regions can be repeated many times. Eventually, be followed by the fabrication of laser diodes strategically positioned relative to these different active regions to enable lasing at various wavelengths.
It is to be appreciated that the method described above can be implemented using various types of substrate. As explained above, the substrate member may have a surface region on the polar plane (c-plane), nonpolar plane (m-plane, a-plane), and semipolar plain ({11-22}, {10-1-1}, {20-21}, {30-31}, {20-21}, {30-31}). In the method described above, two active regions and two cavity members are formed. For example, each active region and cavity member pair is associated with a specific wavelength. Depending on the application, additional active regions and cavity members may be formed to obtain desired wavelengths and/or spectral width. In a preferred embodiment, each of the active regions is characterized by a specific spatial dimension associated with a specific wavelength.
In a specific embodiment, a laser apparatus having multiple active regions and a broad spectrum is provided. The laser apparatus includes a gallium and nitrogen containing substrate including a first crystalline surface region orientation. For example, the substrate member may have a surface region on the polar plane (c-plane), nonpolar plane (m-plane, a-plane), and semipolar plain ({11-22}, {10-1-1}, {20-21}, {30-31}, {20-21}, {30-31}). The laser apparatus includes a first active region comprising a barrier layer and a first emission, the first emission layer being characterized by a first gain peak wavelength. The laser apparatus also includes a second active region comprising a second emission layer, the second emission layer being characterized by a second gain peak wavelength, a difference between the first gain peak wavelength and the second gain peak wave length is 1 to 20 nm. In various embodiments, each of the active regions may include multiple active and barrier layers, as well as cladding layers. The laser apparatus also includes a first cavity member overlaying the first emission layer, the first cavity member being characterized by a length of at least 100 um and a width of at least 0.5 um. The laser apparatus includes a second cavity member overlaying the second the emission layer, the second cavity member being characterized by a length of at least 100 um and a width of at least 0.5 um.
In a specific embodiment, one or more layers of active regions are stacked on top of one another at different locations. More specifically, after initial growth of a first active region, one or more of the active regions could be selectively added or removed in different regions of the chip. As a result, multiple lasers with different wavelengths can be fabricated in locations that would result in different lasing wavelengths.
The rate at which this process takes place can be enhanced with the introduction of a catalyst. Using a lithographically definable catalyst patterning process, the QWI process can be made selective. This is the process by which virtually all selective QWI is performed, whether it is by the introduction of impurities or by the creation of vacancies. By using these techniques There are a great number of techniques that have evolved over the years to accomplish selective intermixing, such as impurity-induced disordering (IID), impurity-free vacancy-enhanced disordering (IFVD), photoabsorption-induced disordering (PAID), and implantation-enhanced interdiffusion to name just a few. Such methods are capable of shifting the peak gain wavelengths by 1 to over 100 nm. By employing one of these mentioned or any other QWI method to detune the gain peak of adjacent laser devices, the convolved lasing spectrum of the side by side devices can be altered.
Broad laser spectrum can also be achieved by way of current/voltage control, as described in certain embodiments of the present invention. More specifically, two or more lasers are positioned side by side and make use of separate p-electrodes such that the injected current into each laser could be independently controlled. For example, it is known that bandfilling, self-heating, and carrier induced refractive index changes alter the lasing wavelength as a function of applied current and voltage. Therefore, by having independent current/voltage control of two or more adjacent lasers, the wavelengths can be detuned from each other by 1 to 10 nm.
In certain embodiments, two or more lasers are positioned side by side and make use of a common p-electrode such that the injected current into each laser is dictated by the current divider rule resulting from the resistance differential of the two or more diodes. The side-by-side lasers can be designed to have different resistances by changing the current injection area. An example is to position two side-by-side laser cavities where the first laser cavity has a width of 2 um and the second cavity has a width of 4 um. Due to the wider area of the second laser, the resistance is lower and therefore more current are injected into the second laser. The difference in the amount of current injected creates a difference in the junction temperature (and/or in carrier density), resulting in a different peak lasing wavelengths between different lasers. For example, by having different resistances, differences in lasing wavelengths on the order of 1-5 nm are achieved.
Broad laser spectrum can also be achieved by having two or more lasers operating in different lateral mode orders positioned side-by-side.
In an exemplary embodiment, geometry for cavity members would be to position a first laser with 2 um (e.g., width 3) wide cavity member next to a second laser with a 4 um (e.g., width 2) wide cavity next to a third laser with a 6 um (e.g., width 3) wide cavity. As an example, all three lasers can be covered by a common or separate p-electrodes and the electrode(s) would be biased such that all lasers were beyond threshold. Since all lasers would operate with different peak wavelengths, a multi-peaked spectrum is achieved.
In certain embodiments, broad laser spectrum is obtained by having a single emitter operating at different peak wavelengths. More specifically, laser diodes are formed on nonpolar and semipolar Ga-containing substrates that operate with two or more spectral lasing peaks. Depending on the application, the two or more spectral peaks are produced in the same laser cavity and are excited simultaneously or sequentially. It is to be appreciated that embodiments of the present invention provides several ways to achieve multiple laser wavelengths.
An abrupt shift in the lasing wavelength is often referred to as a mode hope. Mode hops can occur for several reasons such as an instantaneous shift of the lasing mode from one longitudinal cavity mode to another, from one lateral mode to another, or excitation of additional lateral mode. Such hops can be induced by modulation of current, temperature, or optical feedback into the cavity. Here we want to claim any one of these methods as means to alter the spectrum in a favorable way for applications such as speckle reduction in displays
The multiple peak wavelength is obtained by applying an intentional RF-modulation on the gain region to induce mode hopping. More specifically, a laser device includes a gallium and nitrogen containing substrate including a first crystalline surface region orientation. For example, the substrate member may have a surface region on the polar plane (c-plane), nonpolar plane (m-plane, a-plane), and semipolar planes ({11-22}, {10-1-1}, {20-21}, {30-31}, {20-21}, {30-31}). The laser device includes an active region comprising at least one quantum well or double hetereostructure and a barrier layer. The laser device may additionally include one or more barrier layers, active layers, and/or cladding layers. The laser device includes a cavity member overlaying the active region, the cavity member being characterized by a length along a c-plane, the length being at least 100 um, the cavity having a width of at least 0.5 um, the cavity member being configured to emit laser characterized by a spectral width of at least 1 nm. For example, the cavity member functions as waveguides for laser diodes.
The laser device also includes an RF source electrically coupled to the active region through an electrode for providing RF modulation, the RF modulation being configured to induce mode hopping or spectral broadening. The RF signal may be applied to a singular electrode coupled to the p-type or n-type Ga-containing material for current injection into the laser diode in addition to the direct current (DC) or alternating current (AC) required to operate the laser in its given application. Alternatively, the device can be configured to have 2 or more electrodes coupled to the p-type or n-type Ga-containing material such that the RF signal can be applied to the laser through a separate electrode than the primary direct current (DC) or alternating current (AC) required to operate the laser in its given application.
The RF signals, when received by the laser device, cause a shift in wavelength. The RF signals can widen the spectral width of laser output.
During gain switching, the carrier density significantly changes during emission of the leading pulse peak. This leads to a spectral shift of the gain spectrum, favoring different spectral modes. This further increases the number of modes visible in the average spectrum. Additionally, each individual mode broadens due to chirp, as the refractive index changes with the carrier density.
It is to be appreciated that by increasing the spectral width (e.g., by providing RF signals), speckling effect can be reduced, as explained above. For example, speckle typically refers to random intensity pattern produced by the mutual interference of a set of wave fronts. This phenomenon has been investigated by scientists since the time of Newton, but speckles have come into prominence since the invention of the laser and have now found a variety of applications. Due to the longer coherence lengths of laser sources compared to bulbs or LEDs, speckle is considered to be a problem in laser based display systems like the Laser TV.
As an example, speckle effects are defined by Goodman's Speckle Phenomena in Optics, where
Conventional displays/projectors that use laser diode as light source typically use second-harmonic generation (SHG) technique to produce green laser light, which is both inefficient and prone to speckles.
Depending on the application, RF signals can be coupled to laser diodes in various ways to increase spectral width and reduce speckle. For example, by modulating laser diodes, the RF signals can induce gain switching and hence mode competition such that more cavity modes are excited on average which widens the spectral width. Further, carrier modulation effects the index in which shifts the gain peak and hence modulates the spectrum, and over time period, the spectrum is widened.
In another embodiment, multiple peak wavelength is obtained by applying an external optical feedback signal into the cavity to induce mode hopping or spectral broadening. More specifically, a laser device includes a gallium and nitrogen containing substrate including a first crystalline surface region orientation. For example, the substrate member may have a surface region on the polar plane (c-plane), non-polar plane (m-plane, a-plane), and semipolar plain ({11-22}, {10-1-1}, {20-21}, {30-31}, {20-21}, {30-31}). The laser device includes an active region comprising at least a quantum well or double hetereostructure emitting layer and a barrier layer. The laser device may additionally include one or more barrier layers, active layers, and/or cladding layers. The laser device includes a cavity member overlaying the active region, the cavity member being characterized by a length along a c-plane, the length being at least 100 um, the cavity having a width of at least 0.5 um, the cavity member being configured to emit laser characterized by a spectral width of at least 1 nm. For example, the cavity member functions as waveguides for laser diodes. The laser device additionally includes an optical feedback signal source coupled to the active region for inducing mode hopping.
In another embodiment, multiple peak wavelength is obtained by utilizing light generated in the laser diode in question or an adjacent light emitting device to provide optical feedback and induce mode hopping. It is to be appreciated that there are other ways to induce multiple peak wavelengths as well.
In certain embodiments, optical members are provided for combining laser beams emitted for two or more laser diodes.
While the above is a full description of the specific embodiments, various modifications, alternative constructions and equivalents may be used. Therefore, the above description and illustrations should not be taken as limiting the scope of the present invention which is defined by the appended claims.
This application is a divisional application of U.S. application Ser. No. 13/872,756 filed on Apr. 29, 2013, now allowed, which is a divisional application of U.S. application Ser. No. 13/108,645 filed on May 16, 2011, issued as U.S. Pat. No. 8,451,876, which claims the benefit under 35 U.S.C. 119(e) of U.S. Provisional Patent Application No. 61/345,561, filed on May 117, 2010, each of which is incorporated by reference in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
4318058 | Mito et al. | Mar 1982 | A |
4341592 | Shortes et al. | Jul 1982 | A |
4860687 | Frijlink | Aug 1989 | A |
4911102 | Manabe et al. | Mar 1990 | A |
5331654 | Jewell et al. | Jul 1994 | A |
5334277 | Nakamura | Aug 1994 | A |
5366953 | Char et al. | Nov 1994 | A |
5527417 | Iida et al. | Jun 1996 | A |
5607899 | Yoshida et al. | Mar 1997 | A |
5632812 | Hirabayashi | May 1997 | A |
5647945 | Matsuse et al. | Jul 1997 | A |
5696389 | Ishikawa et al. | Dec 1997 | A |
5821555 | Saito et al. | Oct 1998 | A |
5888907 | Tomoyasu et al. | Mar 1999 | A |
5926493 | O'Brien et al. | Jul 1999 | A |
5951923 | Horie et al. | Sep 1999 | A |
6069394 | Hashimoto et al. | May 2000 | A |
6072197 | Horino et al. | Jun 2000 | A |
6147953 | Duncan | Nov 2000 | A |
6153010 | Kiyoku et al. | Nov 2000 | A |
6195381 | Botez et al. | Feb 2001 | B1 |
6239454 | Glew et al. | May 2001 | B1 |
6451157 | Hubacek | Sep 2002 | B1 |
6586762 | Kozaki | Jul 2003 | B2 |
6635904 | Goetz et al. | Oct 2003 | B2 |
6639925 | Niwa et al. | Oct 2003 | B2 |
6680959 | Tanabe et al. | Jan 2004 | B2 |
6734461 | Shiomi et al. | May 2004 | B1 |
6755932 | Masuda et al. | Jun 2004 | B2 |
6809781 | Setlur et al. | Oct 2004 | B2 |
6814811 | Ose | Nov 2004 | B2 |
6833564 | Shen et al. | Dec 2004 | B2 |
6858081 | Biwa et al. | Feb 2005 | B2 |
6858882 | Tsuda et al. | Feb 2005 | B2 |
6920166 | Akasaka et al. | Jul 2005 | B2 |
7009199 | Hall | Mar 2006 | B2 |
7019325 | Li et al. | Mar 2006 | B2 |
7033858 | Chai et al. | Apr 2006 | B2 |
7053413 | D'Evelyn et al. | May 2006 | B2 |
7063741 | D'Evelyn | Jun 2006 | B2 |
7128849 | Setlur et al. | Oct 2006 | B2 |
7220324 | Baker et al. | May 2007 | B2 |
7303630 | Motoki et al. | Dec 2007 | B2 |
7312156 | Granneman et al. | Dec 2007 | B2 |
7323723 | Ohtsuka et al. | Jan 2008 | B2 |
7338828 | Imer et al. | Mar 2008 | B2 |
7358542 | Radkov et al. | Apr 2008 | B2 |
7358543 | Chua et al. | Apr 2008 | B2 |
7390359 | Miyanaga et al. | Jun 2008 | B2 |
7470555 | Matsumura | Dec 2008 | B2 |
7483466 | Uchida et al. | Jan 2009 | B2 |
7483468 | Tanaka | Jan 2009 | B2 |
7489441 | Scheible et al. | Feb 2009 | B2 |
7491984 | Koike | Feb 2009 | B2 |
7555025 | Yoshida | Jun 2009 | B2 |
7598104 | Teng et al. | Oct 2009 | B2 |
7691658 | Kaeding et al. | Apr 2010 | B2 |
7709284 | Iza et al. | May 2010 | B2 |
7727332 | Habel et al. | Jun 2010 | B2 |
7733571 | Li | Jun 2010 | B1 |
7749326 | Kim et al. | Jul 2010 | B2 |
7806078 | Yoshida | Oct 2010 | B2 |
7858408 | Mueller et al. | Dec 2010 | B2 |
7862761 | Okushima et al. | Jan 2011 | B2 |
7923741 | Zhai et al. | Apr 2011 | B1 |
7939354 | Kyono et al. | May 2011 | B2 |
7968864 | Akita et al. | Jun 2011 | B2 |
8017932 | Okamoto et al. | Sep 2011 | B2 |
8044412 | Murphy et al. | Oct 2011 | B2 |
8124996 | Raring et al. | Feb 2012 | B2 |
8126024 | Raring | Feb 2012 | B1 |
8143148 | Raring et al. | Mar 2012 | B1 |
8242522 | Raring | Aug 2012 | B1 |
8247887 | Raring et al. | Aug 2012 | B1 |
8252662 | Poblenz et al. | Aug 2012 | B1 |
8254425 | Raring | Aug 2012 | B1 |
8259769 | Raring et al. | Sep 2012 | B1 |
8284810 | Sharma et al. | Oct 2012 | B1 |
8294179 | Raring | Oct 2012 | B1 |
8314429 | Raring et al. | Nov 2012 | B1 |
8350273 | Vielemeyer | Jan 2013 | B2 |
8351478 | Raring et al. | Jan 2013 | B2 |
8355418 | Raring et al. | Jan 2013 | B2 |
8416825 | Raring | Apr 2013 | B1 |
8422525 | Raring | Apr 2013 | B1 |
8427590 | Raring | Apr 2013 | B2 |
8451876 | Raring | May 2013 | B1 |
8509275 | Raring et al. | Aug 2013 | B1 |
8638828 | Raring et al. | Jan 2014 | B1 |
20010048114 | Morita et al. | Dec 2001 | A1 |
20020027933 | Tanabe et al. | Mar 2002 | A1 |
20020050488 | Nikitin et al. | May 2002 | A1 |
20020085603 | Okumura | Jul 2002 | A1 |
20020105986 | Yamasaki | Aug 2002 | A1 |
20030000453 | Unno et al. | Jan 2003 | A1 |
20030001238 | Ban | Jan 2003 | A1 |
20030012243 | Okumura | Jan 2003 | A1 |
20030020087 | Goto et al. | Jan 2003 | A1 |
20030129810 | Barth | Jul 2003 | A1 |
20030140846 | Biwa et al. | Jul 2003 | A1 |
20030178617 | Appenzeller et al. | Sep 2003 | A1 |
20030200931 | Goodwin | Oct 2003 | A1 |
20030209191 | Purdy | Nov 2003 | A1 |
20040025787 | Selbrede et al. | Feb 2004 | A1 |
20040060518 | Nakamura et al. | Apr 2004 | A1 |
20040099213 | Adomaitis et al. | May 2004 | A1 |
20040104391 | Maeda et al. | Jun 2004 | A1 |
20040146264 | Auner et al. | Jul 2004 | A1 |
20040151222 | Sekine | Aug 2004 | A1 |
20040222357 | King et al. | Nov 2004 | A1 |
20040233950 | Furukawa et al. | Nov 2004 | A1 |
20040247275 | Vakhshoori et al. | Dec 2004 | A1 |
20050040384 | Tanaka et al. | Feb 2005 | A1 |
20050072986 | Sasaoka | Apr 2005 | A1 |
20050168564 | Kawaguchi et al. | Aug 2005 | A1 |
20050214992 | Chakraborty et al. | Sep 2005 | A1 |
20050218413 | Matsumoto et al. | Oct 2005 | A1 |
20050224826 | Keuper et al. | Oct 2005 | A1 |
20050229855 | Raaijmakers | Oct 2005 | A1 |
20050230701 | Huang | Oct 2005 | A1 |
20050247260 | Shin et al. | Nov 2005 | A1 |
20050285128 | Scherer et al. | Dec 2005 | A1 |
20050286591 | Lee | Dec 2005 | A1 |
20060033009 | Kobayashi et al. | Feb 2006 | A1 |
20060037529 | D'Evelyn | Feb 2006 | A1 |
20060060131 | Atanackovic | Mar 2006 | A1 |
20060077795 | Kitahara et al. | Apr 2006 | A1 |
20060078022 | Kozaki et al. | Apr 2006 | A1 |
20060079082 | Bruhns et al. | Apr 2006 | A1 |
20060086319 | Kasai et al. | Apr 2006 | A1 |
20060096521 | D'Evelyn et al. | May 2006 | A1 |
20060126688 | Kneissl | Jun 2006 | A1 |
20060144334 | Yim et al. | Jul 2006 | A1 |
20060175624 | Sharma et al. | Aug 2006 | A1 |
20060177362 | D'Evelyn et al. | Aug 2006 | A1 |
20060189098 | Edmond | Aug 2006 | A1 |
20060193359 | Kuramoto | Aug 2006 | A1 |
20060213429 | Motoki et al. | Sep 2006 | A1 |
20060216416 | Sumakeris et al. | Sep 2006 | A1 |
20060256482 | Araki et al. | Nov 2006 | A1 |
20060288928 | Eom et al. | Dec 2006 | A1 |
20070081857 | Yoon | Apr 2007 | A1 |
20070086916 | LeBoeuf et al. | Apr 2007 | A1 |
20070093073 | Farrell et al. | Apr 2007 | A1 |
20070101932 | Schowalter et al. | May 2007 | A1 |
20070110112 | Sugiura | May 2007 | A1 |
20070120141 | Moustakas et al. | May 2007 | A1 |
20070153866 | Shchegrov et al. | Jul 2007 | A1 |
20070163490 | Habel et al. | Jul 2007 | A1 |
20070184637 | Haskell et al. | Aug 2007 | A1 |
20070217462 | Yamasaki | Sep 2007 | A1 |
20070242716 | Samal et al. | Oct 2007 | A1 |
20070259464 | Bour et al. | Nov 2007 | A1 |
20070272933 | Kim et al. | Nov 2007 | A1 |
20070280320 | Feezell et al. | Dec 2007 | A1 |
20080029152 | Milshtein et al. | Feb 2008 | A1 |
20080087919 | Tysoe et al. | Apr 2008 | A1 |
20080092812 | McDiarmid et al. | Apr 2008 | A1 |
20080095492 | Son et al. | Apr 2008 | A1 |
20080121916 | Teng et al. | May 2008 | A1 |
20080124817 | Bour et al. | May 2008 | A1 |
20080149949 | Nakamura et al. | Jun 2008 | A1 |
20080149959 | Nakamura et al. | Jun 2008 | A1 |
20080164578 | Tanikella et al. | Jul 2008 | A1 |
20080173735 | Mitrovic et al. | Jul 2008 | A1 |
20080191192 | Feezell et al. | Aug 2008 | A1 |
20080191223 | Nakamura et al. | Aug 2008 | A1 |
20080193363 | Tsuji | Aug 2008 | A1 |
20080217745 | Miyanaga et al. | Sep 2008 | A1 |
20080232416 | Okamoto et al. | Sep 2008 | A1 |
20080251020 | Franken et al. | Oct 2008 | A1 |
20080283851 | Akita | Nov 2008 | A1 |
20080285609 | Ohta et al. | Nov 2008 | A1 |
20080291961 | Kamikawa et al. | Nov 2008 | A1 |
20080298409 | Yamashita et al. | Dec 2008 | A1 |
20080303033 | Brandes | Dec 2008 | A1 |
20080308815 | Kasai et al. | Dec 2008 | A1 |
20080315179 | Kim et al. | Dec 2008 | A1 |
20090021723 | De Lega | Jan 2009 | A1 |
20090058532 | Kikkawa et al. | Mar 2009 | A1 |
20090061857 | Kazmi | Mar 2009 | A1 |
20090066241 | Yokoyama | Mar 2009 | A1 |
20090078944 | Kubota et al. | Mar 2009 | A1 |
20090080857 | St. John-Larkin | Mar 2009 | A1 |
20090081857 | Hanser et al. | Mar 2009 | A1 |
20090141765 | Kohda et al. | Jun 2009 | A1 |
20090153752 | Silverstein | Jun 2009 | A1 |
20090159869 | Ponce et al. | Jun 2009 | A1 |
20090229519 | Saitoh | Sep 2009 | A1 |
20090250686 | Sato et al. | Oct 2009 | A1 |
20090267100 | Miyake et al. | Oct 2009 | A1 |
20090273005 | Lin | Nov 2009 | A1 |
20090301387 | D'Evelyn | Dec 2009 | A1 |
20090301388 | D'Evelyn | Dec 2009 | A1 |
20090309110 | Raring et al. | Dec 2009 | A1 |
20090309127 | Raring et al. | Dec 2009 | A1 |
20090310640 | Sato et al. | Dec 2009 | A1 |
20090316116 | Melville et al. | Dec 2009 | A1 |
20090320744 | D'Evelyn | Dec 2009 | A1 |
20090321778 | Chen et al. | Dec 2009 | A1 |
20100001300 | Raring et al. | Jan 2010 | A1 |
20100003492 | D'Evelyn | Jan 2010 | A1 |
20100006546 | Young et al. | Jan 2010 | A1 |
20100006873 | Raring et al. | Jan 2010 | A1 |
20100025656 | Raring et al. | Feb 2010 | A1 |
20100031875 | D'Evelyn | Feb 2010 | A1 |
20100044718 | Hanser et al. | Feb 2010 | A1 |
20100096615 | Okamoto et al. | Apr 2010 | A1 |
20100104495 | Kawabata et al. | Apr 2010 | A1 |
20100109126 | Arena | May 2010 | A1 |
20100140630 | Hamaguchi et al. | Jun 2010 | A1 |
20100140745 | Khan et al. | Jun 2010 | A1 |
20100151194 | D'Evelyn | Jun 2010 | A1 |
20100195687 | Okamoto et al. | Aug 2010 | A1 |
20100220262 | DeMille et al. | Sep 2010 | A1 |
20100276663 | Enya et al. | Nov 2010 | A1 |
20100295054 | Okamoto et al. | Nov 2010 | A1 |
20100302464 | Raring et al. | Dec 2010 | A1 |
20100309943 | Chakraborty et al. | Dec 2010 | A1 |
20100316075 | Raring et al. | Dec 2010 | A1 |
20100327291 | Preble et al. | Dec 2010 | A1 |
20110031508 | Hamaguchi et al. | Feb 2011 | A1 |
20110056429 | Raring | Mar 2011 | A1 |
20110057167 | Ueno et al. | Mar 2011 | A1 |
20110064100 | Raring et al. | Mar 2011 | A1 |
20110064101 | Raring et al. | Mar 2011 | A1 |
20110064102 | Raring et al. | Mar 2011 | A1 |
20110075694 | Yoshizumi et al. | Mar 2011 | A1 |
20110103418 | Hardy et al. | May 2011 | A1 |
20110129669 | Fujito et al. | Jun 2011 | A1 |
20110150020 | Haase et al. | Jun 2011 | A1 |
20110164637 | Yoshizumi et al. | Jul 2011 | A1 |
20110180781 | Raring | Jul 2011 | A1 |
20110182056 | Trottier et al. | Jul 2011 | A1 |
20110186874 | Shum | Aug 2011 | A1 |
20110186887 | Trottier et al. | Aug 2011 | A1 |
20110188530 | Lell | Aug 2011 | A1 |
20110216795 | Hsu et al. | Sep 2011 | A1 |
20110247556 | Raring et al. | Oct 2011 | A1 |
20110281422 | Wang et al. | Nov 2011 | A1 |
20110286484 | Raring et al. | Nov 2011 | A1 |
20120104359 | Felker et al. | May 2012 | A1 |
20120119218 | Su | May 2012 | A1 |
20120178198 | Raring et al. | Jul 2012 | A1 |
20120187371 | Raring et al. | Jul 2012 | A1 |
20120314398 | Raring et al. | Dec 2012 | A1 |
20130016750 | Raring et al. | Jan 2013 | A1 |
20130022064 | Raring et al. | Jan 2013 | A1 |
20130044782 | Raring | Feb 2013 | A1 |
20130064261 | Sharma et al. | Mar 2013 | A1 |
Number | Date | Country |
---|---|---|
101009347 | Mar 1987 | CN |
1538534 | Oct 2004 | CN |
1702836 | Nov 2005 | CN |
101099245 | Jan 2008 | CN |
10171692 | Apr 2008 | CN |
101079463 | Sep 2009 | CN |
3-287770 | Dec 1991 | JP |
07-162081 | Jun 1995 | JP |
2002-185082 | Jun 2002 | JP |
2002-009402 | Nov 2002 | JP |
2004-186527 | Feb 2004 | JP |
2004-152841 | May 2004 | JP |
2004-503923 | May 2004 | JP |
2006-091285 | Jun 2006 | JP |
2006-120923 | Nov 2006 | JP |
2007-173467 | Jul 2007 | JP |
2007-529910 | Oct 2007 | JP |
2007-068398 | Apr 2008 | JP |
2008-311640 | Dec 2008 | JP |
2009-021506 | Jan 2009 | JP |
2009-158893 | Jul 2009 | JP |
2009-170708 | Jul 2009 | JP |
2008-041521 | Apr 2008 | WO |
2010068916 | Jun 2010 | WO |
Entry |
---|
Abare “Cleaved and Etched Facet Nitride Laser Diodes,” IEEE Journal of Selected Topics in Quantum Electronics, Vol. 4, No. 3, pp. 505-509 (May 1998). |
Adesida et al., “Characteristics of chemically assisted ion beam etching of gallium nitride” Appl. Phys. Lett. 65 (7) (Aug. 1994), pp. 889-891. |
Aoki et al., “InGaAs/InGaAsP MQW Electroabsorption Modulator Integrated with a DFB Laser Fabricated by Band-Gap Energy Control Selective Area MOCVD, 1993,”IEEE J Quantum Electronics, vol. 29, pp. 2088-2096. |
Asano et al., “100-mW kink-Free Blue-Violet Laser Diodes with Low Aspect Ratio,” 2003, IEEE Journal of Quantum Electronics, vol. 39, No. 1, pp. 135-140. |
Asif Khan “Cleaved cavity optically pumped InGaN—GaN laser grown on spinel substrates,” Appl. Phys. Lett. 69 (16), pp. 2418-2420 (Oct. 14, 1996). |
Behfar et al., “Progress in etched Facet Technology for GaN and Blue Lasers” Proc. of SPIE vol. 6473 (2007), 8 pages. |
Bernardini et al., “Spontaneous Polarization and Piezoelectric Constants of III-V Nitrides,” 1997, Physical Review B, vol. 56, No. 16, pp. 10024-10027. |
Caneau et al., “Studies on Selective OMVPE of (Ga,In)/(As,P),” 1992, Journal of Crystal Growth, vol. 124, pp. 243-248. |
Chen et al., “Growth and Optical Properties of Highly Uniform and Periodic InGaN Nanostructures,” 2007, Advanced Materials, vol. 19, pp. 1707-1710. |
D'Evelyn et al., “Bulk GaN Crystal Growth by the High-Pressure Ammonothermal Method,” Journal of Crystal Growth, 2007, vol. 300, pp. 11-16. |
Franssila, “Tools for CVD and Epitaxy” Introduction to Microfabrication, 2004, pp. 329-336. |
Fujii et al., “Increase in the Extraction Efficiency of GaN-based Light-Emitting Diodes via Surface Roughening,” 2004, Applied Physics Letters, vol. 84, No. 6, pp. 855-857. |
Funato et al., “Blue, Green, and Amber InGaN/GaN Light-Emitting Diodes on Semipolar (1122) GaN Substrates,” 2006, Journal of Japanese Applied Physics, vol. 45, No. 26, pp. L659-L662. |
Funato et al., “Monolithic Polychromatic Light-Emitting Diodes Based on InGaN Microfacet Quantum Wells toward Tailor-Made Solid-State Lighting,” 2008, Applied Physics Express, vol. 1, pp. 011106-1-011106-3. |
Founta et al., ‘Anisotropic Morphology of Nonpolar a-Plane GaN Quantum Dots and Quantum Wells,’ Journal of Applied Physics, vol. 102, vol. 7, 2007, pp. 074304-1-074304-6. |
Gardner et al. “Blue-emitting InGaN—GaN double-heterostructure light-emitting diodes reaching maximum quantum efficiency above 200 A/cm2”, Applied Physics Letters 91, 243506 (2007). |
hap ://techon.nikkeibp. co jp/english/NEWS—EN/20080122/146009. |
Hiramatsu et al., Selective Area Growth and Epitaxial Lateral Overgrowth of GaN by Metalorganic Vapor Phase Epitaxy and Hydride Vapor Phase Epitaxy. Materials Science and Engineering B, vol. 59, May 6, 1999. pp. 104-111. |
Iso et al., “High Brightness Blue InGaN/GaN Light Emitting Diode on Nonpolar m-plane Bulk GaN Substrate,” 2007, Japanese Journal of Applied Physics, vol. 46, No. 40, pp. L960-L962. |
Kendall et al., “Energy Savings Potential of Solid State Lighting in General Lighting Applications,” 2001, Report for the Department of Energy, pp. 1-35. |
Kim et al, “Improved Electroluminescence on Nonpolar m-plane InGaN/GaN Qantum Well LEDs”, 2007, Physica Status Solidi (RRL), vol. 1, No. 3, pp. 125-127. |
Kuramoto et al., “Novel Ridge-Type InGaN Multiple-Quantum-Well Laser Diodes Fabricated by Selective Area Re-Growth on n-GaN Substrates,” 2007, Journal of Japanese Applied Physics, vol. 40, pp. 925-927. |
Lin et al., “Influence of Separate Confinement Heterostructure Layer on Carrier Distribution in InGaAsP Laser Diodes with Nonidentical Multiple Quantum Wells,” Japanese Journal of Applied Physics, vol. 43, No. 10, pp. 7032-7035 (2004). |
Masui et al. “Electrical Characteristics of Nonpolar InGaN-Based Light-Emitting Diodes Evaluated at Low Temperature,” Jpn. J. Appl. Phys. 46 pp. 7309-7310 (2007). |
Michiue et al. “Recent development of nitride LEDs and LDs,” Proceedings of SPIE, vol. 7216, 72161Z (2009). |
Nakamura et al., “InGaN/Gan/AlGaN-based Laser Diodes with Modulation-doped Strained-layer Superlattices Grown on an Epitaxially Laterally Grown GaN Substrate”, 1998, Applied Physics Letters, vol. 72, No. 12, pp. 211-213. |
Nam et al., “Later Epitaxial Overgrowth of GaN films on SiO2 Areas via Metalorganic Vapor Phase Epitaxy,” 1998, Journal of Electronic Materials, vol. 27, No. 4, pp. 233-237. |
Okamoto et al., “Pure Blue Laser Diodes Based on Nonpolar m-Plane Gallium Nitride with InGaN Waveguiding Layers,” 2007, Journal of Japanese Applied Physics, vol. 46, No. 35, pp. 820-822. |
Okamoto et. al “Continuous-Wave Operation of m-Plane InGaN Multiple Quantum Well Laser Diodes” The Japan Society of I Applied Physics JJAP Express LEtter, vol. 46, No. 9, 2007 pp. L 187-L 189. |
Okamoto et al. in “High-Efficiency Continuous-Wave Operation of Blue-Green Laser Diodes Based on Nonpolar m-Plane Gallium Nitride,” The Japan Society of Applied Physics, Applied Physics Express 1 (Jun. 2008). |
Park, “Crystal orientation effects on electronic properties of wurtzite InGaN/GaN quantum wells,” Journal of Applied Physics vol. 91, No. 12, pp. 9904-9908 (Jun. 2002). |
Purvis, “Changing the Crystal Face of Gallium Nitride.” The Advance Semiconductor Magazine, vol. 18, No. 8, Nov. 2005. |
Romanov “Strain-induced polarization in wurtzite III-nitride semipolar layers,” Journal of Applied Physics 100, pp. 023522-1 through 023522-10 (Jul. 25, 2006). |
Sato et al., “High Power and High Efficiency Green Light Emitting Diode on free-Standing Semipolar (1122) Bulk GaN Substrate,” 2007.Physica Status Solidi (RRL), vol. 1, pp. 162-164. |
Sato et al., “Optical Properties of Yellow Light-Emitting-Diodes Grown on Semipolar (1122) Bulk GaN Substrate,” 2008, Applied Physics Letter, vol. 92, No. 22, pp. 221110-1-221110-3. |
Schmidt et al., “Demonstration of Nonpolar m-plane InGaN/GaN Laser Diodes,” 2007, Journal of Japanese Applied Physics, vol. 46, No. 9, pp. 190-191. |
Schmidt et al., “High Power and High External Efficiency m-plane InGaN Light Emitting Diodes,” 2007, Japanese Journal of Applied Physics, vol. 46, No. 7, pp. L126-L128. |
Schoedl “Facet degradation of GaN heterostructure laser diodes,” Journal of Applied Physics vol. 97, issue 12, pp. 123102-1 to 123102-8 (2005). |
Shchekin et al., “High Performance Thin-film Flip-Chip InGaN—GaN Light-emitting Diodes,” 2006, Applied Physics Letters, vol. 89, pp. 071109-071109-3. |
Shen et al. “Auger recombination in InGaN measured by photoluminescence,” Applied Physics Letters, 91, 141101 (2007). |
Sizov et al., “500-nm Optical Gain Anisotropy of Semipolar (1122) InGaN Quantum Wells,” 2009, Applied Physics Express, vol. 2, pp. 071001-1-071001-3. |
Tomiya et. al. Dislocation related issues in the degradation of GaN-based laser diodes, IEEE Journal of Selected Topics in Quantum Electronics vol. 10, No. 6 (2004). |
Tyagi et al., “High Brightness Violet InGaN/GaN Light Emitting Diodes on Semipolar (1011) Bulk GaN Substrates,” 2007, Japanese Journal of Applied Physics, vol. 46, No. 7, pp. L129-L131. |
Tyagi et al., “Semipolar (1011) InGaN/GaN Laser Diodes on Bulk GaN Substrates” Japanese Journal of Applied Physics, vol. 46, No. 19, 2007, pp. L444-L445. |
Uchida et al.,“Recent Progress in High-Power Blue-violet Lasers,” 2003, IEEE Journal of Selected Topics in Quantum Electronics, vol. 9, No. 5, pp. 1252-1259. |
Waltereit et al., “Nitride Semiconductors Free of Electrostatic Fields for Efficient White Light-emitting Diodes,” 2000, Nature: International Weekly Journal of Science, vol. 406, pp. 865-868. |
Wierer et al., “High-power AlGaInN Flip-chip Light-emitting Diodes,” 2001, Applied Physics Letters, vol. 78, No. 22, pp. 3379-3381. |
Yamaguchi, A. Atsushi, “Anisotropic Optical Matrix Elements in Strained GaN-quantum Wells with Various Substrate Orientations,” 2008, Physica Status Solidi (PSS), vol. 5, No. 6, pp. 2329-2332. |
Yoshizumi et al. “Continuous-Wave operation of 520 nm Green InGaN-Based Laser Diodes on Semi-Polar {20-21} GaN Substrates,” Applied Physics Express 2 (2009). |
Yu et al., “Multiple Wavelength Emission from Semipolar InGaN/GaN Quantum Wells Selectively Grown by MOCVD,” in Conference on Lasers and Electro-Optics/Quantum Electronics and Laser Science Conference and Photonic Applications Systems Technologies, OSA Technical Digest (CD) (Optical Society of America, 2007), paper JTuA92. |
Zhong et al., “Demonstration of High Power Blue-Green Light Emitting Diode on Semipolar (1122) Bulk GaN Substrate,” 2007, Electron Letter, vol. 43, No. 15, pp. 825-826. |
Zhong et al., “High Power and High Efficiency Blue Light Emitting Diode on Freestanding Semipolar (1122) Bulk GaN Substrate,” 2007, Applied Physics Letter, vol. 90, No. 23, pp. 233504-233504-3. |
International Search Report of PCT Application No. PCT/US2011/037792, dated Sep. 8, 2011, 2 pages. |
International Search Report & Written Opinion of PCT Application No. PCT/US2011/060030, dated Mar. 21, 2012, 11 pages. |
Notice of Allowance of Jan. 28, 2013 for U.S. Appl. No. 13/108,645, 9 pages. |
Notice of Allowance of Oct. 30, 2013 for U.S. Appl. No. 13/872,756, 10 pages. |
Number | Date | Country | |
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61345561 | May 2010 | US |
Number | Date | Country | |
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Parent | 13872756 | Apr 2013 | US |
Child | 14097801 | US | |
Parent | 13108645 | May 2011 | US |
Child | 13872756 | US |