Claims
- 1. Compounds comprising the reaction product of a polyphenolic compound having the formula ##STR4## with an ester forming compound of the general formula ##STR5## which are then joined through a sulfur atom to form compounds having a general formula selected from the group consisting of ##STR6## wherein Z is a phenoxy radical derived from a polyphenolic compound having structural formula (A) and wherein R.sup.1 and R.sup.2 are the same or different radicals selected from the group consisting of hydrogen, alkyl radicals containing from 1 to 16 carbon atoms, cycloalkyl radicals containing from 5 to 8 carbon atoms, aralkyl radicals containing from 7 to 12 carbon atoms and unsubstituted aryl radicals containing from 6 to 12 carbon atoms, X is the same or different radical selected from the group consisting of (1) cyclic dienes with non-adjacent carbon to carbon double bonds within the ring structure having from 5 to 20 carbon atoms from which the divalent species are prepared and (2) divalent species selected from the group consisting of --S--, ##STR7## --O--, --CH.sub.2 -- and --S--S-- and wherein n is selected from the group consisting of 0 and integers from 1 to 5 and wherein R.sup.3 is selected from the group consisting of hydrogen and alkyl radicals having from 1 to 2 carbon atoms, R.sup.4 is selected from the group consisting of hydrogen, alkyl radicals having from 1 to 4 carbon atoms, aralkyl radicals having from 7 to 9 carbon atoms, substituted or unsubstituted aryl radicals having from 6 to 8 carbon atoms and wherein V is selected from the group consisting of chlorine, iodine and bromine.
- 2. Compounds as described in claim 1 wherein R.sup.1 is an alkyl radical having from 1 to 2 carbon atoms and is para to a phenolic hydroxyl group.
- 3. Compounds as described in claim 1 wherein the polyphenolic compounds are treated with from one mole to 0.1 mole of ester forming compound per functional hydroxyl group, more preferably at least one functional hydroxyl group per polyphenolic molecule esterified.
- 4. Compounds as described in claim 1 wherein the polyphenolic compounds are selected from the group consisting of 2,6-bis-(2-hydroxy-3-tert.butyl-5-methylbenzyl)-4-methylphenol; 2,2'-methylene-bis-(4-methyl-6-tert.butyl phenol); 2,2'-methylene-bis-(4-ethyl-6-tert.butylphenol); 2,2'-thio-bis-(4-methyl-6-tert.butylphenol); 2-(3,5-ditert.butyl 4-hydroxybenzyl)-4-methylphenol; 2-(3,5-ditert.butyl-4-hydroxybenzyl) phenol; 2-(3,5-ditert.butyl-4-hydroxybenzyl)-5-methylphenol, 2,6-bis-(2-hydroxy-3-tert.butyl-5-ethylbenzyl)-4-ethyl phenol and 2-(3,5-ditert.butyl-4-hydroxybenzyl)-4-isopropyl phenol.
- 5. Compounds as described in claim 1 wherein the cyclic dienes are selected from the group consisting of 1,5-cyclooctadiene; cyclopentadiene; bicyclo[2.2.1]-2,5-heptadiene; dicyclopentadiene; pentacyclo [8.2.1.1.sup.4.spsp.9.sup.7.0.sup.2.spsp.9.sup.9.0.sup.3.spsp.9.sup.8 ]-tetradeca-5,11-diene, and 1,5,9-cyclododecadiene.
- 6. Compounds as described in claim 1 wherein the ester forming compounds are selected from the group consisting of acryloyl chloride and methacryloyl chloride.
- 7. Compounds as described in claim 1 wherein R.sup.4 is selected from the group consisting of alkyl radicals having from 1 to 2 carbon atoms and phenyl.
Parent Case Info
This is a continuation application under 37 CFR 1.60, of pending prior application Ser. No. 192,593 filed on Sept. 30, 1980 now abandoned, which is a continuation of Ser. No. 24,752, filed on Mar. 28, 1979, now abandoned, which was a continuation of application Ser. No. 525,440, filed Nov. 20, 1974, abandoned.
US Referenced Citations (5)
Continuations (3)
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Number |
Date |
Country |
Parent |
192583 |
Sep 1980 |
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Parent |
24752 |
Mar 1979 |
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Parent |
525440 |
Nov 1974 |
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