This invention relates generally to wellbore casings, and in particular to wellbore casings that are formed using expandable tubing.
Conventionally, when a wellbore is created, a number of casings are installed in the borehole to prevent collapse of the borehole wall and to prevent undesired outflow of drilling fluid into the formation or inflow of fluid from the formation into the borehole. The borehole is drilled in intervals whereby a casing which is to be installed in a lower borehole interval is lowered through a previously installed casing of an upper borehole interval. As a consequence of this procedure the casing of the lower interval is of smaller diameter than the casing of the upper interval. Thus, the casings are in a nested arrangement with casing diameters decreasing in downward direction. Cement annuli are provided between the outer surfaces of the casings and the borehole wall to seal the casings from the borehole wall. As a consequence of this nested arrangement a relatively large borehole diameter is required at the upper part of the wellbore. Such a large borehole diameter involves increased costs due to heavy casing handling equipment, large drill bits and increased volumes of drilling fluid and drill cuttings. Moreover, increased drilling rig time is involved due to required cement pumping, cement hardening, required equipment changes due to large variations in hole diameters drilled in the course of the well, and the large volume of cuttings drilled and removed.
Conventionally, at the surface end of the wellbore, a wellhead is formed that typically includes a surface casing, a number of production and/or drilling spools, valving, and a Christmas tree. Typically the wellhead further includes a concentric arrangement of casings including a production casing and one or more intermediate casings. The casings are typically supported using load bearing slips positioned above the ground. The conventional design and construction of wellheads is expensive and complex.
Conventionally, a wellbore casing cannot be formed during the drilling of a wellbore. Typically, the wellbore is drilled and then a wellbore casing is formed in the newly drilled section of the wellbore. This delays the completion of a well.
The present invention is directed to overcoming one or more of the limitations of the existing procedures for forming wellbores and wellheads.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, one or more grooves formed in the tapered outer surface, and a solid lubricant deposited into one or more of the grooves.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, one or more grooves formed in the tapered outer surface, and a self-lubricating film deposited onto the surface and into one or more of the grooves.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, one or more grooves formed in the tapered outer surface, and a fluoropolymer coating deposited onto the surface and into one or more of the grooves.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, one or more grooves formed in the tapered outer surface, and a thermo-sprayed coating deposited onto the surface and into one or more of the grooves.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, a pattern of grooves formed in the tapered outer surface, and a solid lubricant deposited into the pattern of grooves.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, a pattern of grooves formed in the tapered outer surface, and a self-lubricating film deposited onto the surface and into the a pattern of grooves.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, a pattern of grooves formed in the tapered outer surface, and a fluoropolymer coating deposited onto the surface and into the pattern of grooves.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, a pattern of grooves formed in the tapered outer surface, and a thermo-sprayed coating deposited onto the surface and into the pattern of grooves.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, a textured surface formed in the tapered outer surface, and a solid lubricant deposited into the textured surface.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, a textured surface formed in the tapered outer surface, and a self-lubricating film deposited onto the textured surface.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, a textured surface formed in the tapered outer surface, and a fluoropolymer coating deposited onto the textured surface.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface, a textured surface formed in the tapered outer surface, and a thermo-sprayed coating deposited onto the textured surface.
According to another aspect of the invention the grooves, pattern or textured surface comprises with troughs to having depths of between 1 and 4 microns deep and the thin film is deposited into the troughs.
According to another aspect of the invention the grooves, pattern or textured surface comprises troughs to having depths of between 10 and 50 microns deep and the flouropolymer coating is deposited into the troughs.
According to another aspect of the invention the grooves, pattern or textured surface comprises troughs to having depths of between 50 and 150 microns deep and the thermo-sprayed coating is deposited into the troughs.
According to another aspect of the present invention, a method of expanding a tubular member in a wellbore is provided that includes forcing a lubricating grease from inside the expansion mandrel to the interface between the tubular member and the mandrel while the tubular member is being expanded by the mandrel within the wellbore.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface one or more grooves formed in the tapered outer surface, and one or more grease flow passages connected through the housing to one or more of the grooves.
According to one aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having a tapered outer surface one or more grooves formed in the tapered outer surface, and one or more grease flow passages connected through the housing to one or more of the grooves and means for forcing a lubricating grease through the grease flow passages into the grooves formed on the tapered outer surface of the mandrel.
According to another aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having an outer tapered surface including, one or more circumferential grooves formed in the outer surface of the tapered first end, and one or more grease flow passages connected through the mandrel housing to the grooves, and means for forcing a lubricating grease through the grease flow passages into the one or more circumferential grooves formed on the surface of the mandrel.
According to another aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing including an outer surface having one or more axial grooves formed in the outer surface of the tapered middle, and one or more grease flow passages connected through the mandrel housing to the grooves, and means for forcing a lubricating grease through the grease flow passages into the one or more axial grooves formed on the surface of the mandrel.
According to another aspect of the present invention, a self-lubricating expansion mandrel for expanding a tubular member is provided that includes a housing having an outer surface including one or more grooves formed in the outer tapered surface and further having a textured pattern comprising axial and circumferential components, and one or more grease flow passages connected to the grooves, and means for forcing a lubricating grease through the grease flow passages into grooves formed on the surface of the mandrel.
According to another aspect of the present invention, a method for manufacturing an expandable member used to complete a structure by radially expanding and plastically deforming the expandable member is provided that includes forming the expandable member from a steel alloy comprising a charpy energy of at least about 90 ft-lbs.
According to another aspect of the present invention, an expandable member for use in completing a structure by radially expanding and plastically deforming the expandable member is provided that includes a steel alloy comprising a charpy energy of at least about 90 ft-lbs.
According to another aspect of the present invention, a structural completion positioned within a structure is provided that includes one or more radially expanded and plastically deformed expandable members positioned within the structure; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from a steel alloy comprising a charpy energy of at least about 90 ft-lbs.
According to another aspect of the present invention, a method for manufacturing an expandable member used to complete a structure by radially expanding and plastically deforming the expandable member is provided that includes forming the expandable member from a steel alloy comprising a weight percentage of carbon of less than about 0.08%.
According to another aspect of the present invention, an expandable member for use in completing a wellbore by radially expanding and plastically deforming the expandable member at a downhole location in the wellbore is provided that includes a steel alloy comprising a weight percentage of carbon of less than about 0.08%.
According to another aspect of the present invention, a structural completion is provided that includes one or more radially expanded and plastically deformed expandable members positioned within the wellbore; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from a steel alloy comprising a weight percentage of carbon of less than about 0.08%.
According to another aspect of the present invention, a method for manufacturing an expandable member used to complete a structure by radially expanding and plastically deforming the expandable member is provided that includes forming the expandable member from a steel alloy comprising a weight percentage of carbon of less than about 0.20% and a charpy V-notch impact toughness of at least about 6 joules.
According to another aspect of the present invention, an expandable member for use in completing a structure by radially expanding and plastically deforming the expandable member is provided that includes a steel alloy comprising a weight percentage of carbon of less than about 0.20% and a charpy V-notch impact toughness of at least about 6 joules.
According to another aspect of the present invention, a structural completion is provided that includes one or more radially expanded and plastically deformed expandable members; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from a steel alloy comprising a weight percentage of carbon of less than about 0.20% and a charpy V-notch impact toughness of at least about 6 joules.
According to another aspect of the present invention, a method for manufacturing an expandable member used to complete a structure by radially expanding and plastically deforming the expandable member is provided that includes forming the expandable member from a steel alloy comprising the following ranges of weight percentages: C, from about 0.002 to about 0.08; Si, from about 0.009 to about 0.30; Mn, from about 0.10 to about 1.92; P, from about 0.004 to about 0.07; S, from about 0.0008 to about 0.006; Al, up to about 0.04; N, up to about 0.01; Cu, up to about 0.3; Cr, up to about 0.5; Ni, up to about 18; Nb, up to about 0.12; Ti, up to about 0.6; Co, up to about 9; and Mo, up to about 5.
According to another aspect of the present invention, an expandable member for use in completing a structure by radially expanding and plastically deforming the expandable member is provided that includes a steel alloy comprising the following ranges of weight percentages: C, from about 0.002 to about 0.08; Si, from about 0.009 to about 0.30; Mn, from about 0.10 to about 1.92; P, from about 0.004 to about 0.07; S, from about 0.0008 to about 0.006; Al, up to about 0.04; N, up to about 0.01; Cu, up to about 0.3; Cr, up to about 0.5; Ni, up to about 18; Nb, up to about 0.12; Ti, up to about 0.6; Co, up to about 9; and Mo, up to about 5.
According to another aspect of the present invention, a structural completion is provided that includes one or more radially expanded and plastically deformed expandable members; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from a steel alloy comprising the following ranges of weight percentages: C, from about 0.002 to about 0.08; Si, from about 0.009 to about 0.30; Mn, from about 0.10 to about 1.92; P, from about 0.004 to about 0.07; S, from about 0.0008 to about 0.006; Al, up to about 0.04; N, up to about 0.01; Cu, up to about 0.3; Cr, up to about 0.5; Ni, up to about 18; Nb, up to about 0.12; Ti, up to about 0.6; Co, up to about 9; and Mo, up to about 5.
According to another aspect of the present invention, a method for manufacturing an expandable tubular member used to complete a structure by radially expanding and plastically deforming the expandable member is provided that includes forming the expandable tubular member with a ratio of the of an outside diameter of the expandable tubular member to a wall thickness of the expandable tubular member ranging from about 12 to 22.
According to another aspect of the present invention, an expandable member for use in completing a structure by radially expanding and plastically deforming the expandable member is provided that includes an expandable tubular member with a ratio of the of an outside diameter of the expandable tubular member to a wall thickness of the expandable tubular member ranging from about 12 to 22.
According to another aspect of the present invention, a structural completion is provided that includes one or more radially expanded and plastically deformed expandable members positioned within the structure; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from an expandable tubular member with a ratio of the of an outside diameter of the expandable tubular member to a wall thickness of the expandable tubular member ranging from about 12 to 22.
According to another aspect of the present invention, a method of constructing a structure is provided that includes radially expanding and plastically deforming an expandable member; wherein an outer portion of the wall thickness of the radially expanded and plastically deformed expandable member comprises tensile residual stresses.
According to another aspect of the present invention, a structural completion is provided that includes one or more radially expanded and plastically deformed expandable members; wherein an outer portion of the wall thickness of one or more of the radially expanded and plastically deformed expandable members comprises tensile residual stresses.
According to another aspect of the present invention, a method of constructing a structure using an expandable tubular member is provided that includes strain aging the expandable member; and then radially expanding and plastically deforming the expandable member.
According to another aspect of the present invention, a method for manufacturing a tubular member used to complete a wellbore by radially expanding the tubular member at a downhole location in the wellbore comprising: forming a steel alloy comprising a concentration of carbon between approximately 0.002% and 0.08% by weight of the steel alloy.
A self-lubricating expansion mandrel is provided. In a exemplary implementation, the self-lubricating expansion mandrel is used in conjunction with one or more methods for expanding tubular members. In this manner, the expansion of a plurality of tubular members coupled to one another using the self-lubricating expansion mandrel may be optimized.
Alternative embodiments of a self-lubricating expansion mandrel is also provided to form a self-lubricating expansion mandrel. In illustrative implementations, the self-lubricating expansion mandrel includes one or more circumferential grooves, one or more axial grooves, both circumferential and axial grooves, one or more patterns of grooves having circumferential and axial components of length and width, and/or surface textures for holding and providing a supply of grease, solid lubricant, thermo-sprayed coatings, fluoropolymer coatings, and/or self-lubricating films to surface of the self-lubricating expansion mandrel and to the interface between the tapered outer surface of the self-lubricating expansion mandrel and a tubular member during the radial expansion process. In this manner, the frictional forces created during the radial expansion process are reduced which results in a reduction in the required operating pressures for radially expanding the tubular member. The depth of the grooves, patterns, or textured surface is selected to facilitate maintaining the supply of lubrication through a period of the expansion process depending in part upon the type of lubrication whether grease, solid lubricant, thermo-sprayed coating, fluoropolymer coating or thin self-lubricating film.
In several alternative embodiments, the apparatus and methods are used to form and/or repair wellbore casings, pipelines, and/or structural supports.
Referring initially to
In order to extend the wellbore 100 into the subterranean formation 105, a drill string 125 is used in a well known manner to drill out material from the subterranean formation 105 to form a new section 130.
As illustrated, an apparatus 200 for forming a wellbore casing in a subterranean formation is then positioned in the new section 130 of the wellbore 100. The apparatus 200 includes an expansion mandrel 205, a tubular member 210, a shoe 215, a lower cup seal 220, an upper cup seal 225, a fluid passage 230, a fluid passage 235, a fluid passage 240, seals 245, and a support member 250.
The expansion mandrel 205 is coupled to and supported by the support member 250. The expansion mandrel 205 is preferably adapted to controllably expand in a radial direction. The expansion mandrel 205 may comprise any number of conventional commercially available expansion mandrels modified in accordance with the teachings of the present disclosure to form a self-lubricating expansion mandrel 205. In an illustrative embodiment, the expansion mandrel 205 comprises a hydraulic expansion tool as disclosed in U.S. Pat. No. 5,348,095, the contents of which are incorporated herein by reference, modified in accordance with the teachings of the present disclosure.
The tubular member 210 is supported by the self-lubricating expansion mandrel 205. The tubular member 210 is expanded in the radial direction and extruded off of the self-lubricating expansion mandrel 205. The tubular member 210 may be fabricated from any number of conventional commercially available materials such as, for example, Oilfield Country Tubular Goods (OCTG), 13 chromium steel tubing/casing, or plastic tubing/casing. In a preferred embodiment, the tubular member 210 is fabricated from OCTG in order to maximize strength after expansion. The inner and outer diameters of the tubular member 210 may range, for example, from approximately 0.75 to 47 inches and 1.05 to 48 inches, respectively. In a preferred embodiment, the inner and outer diameters of the tubular member 210 range from about 3 to 15.5 inches and 3.5 to 16 inches, respectively in order to optimally provide minimal telescoping effect in the most commonly drilled wellbore sizes. The tubular member 210 preferably comprises a solid member.
In a preferred embodiment, the end portion 260 of the tubular member 210 is slotted, perforated, or otherwise modified to catch or slow down the mandrel 205 when it completes the extrusion of tubular member 210. In a preferred embodiment, the length of the tubular member 210 is limited to minimize the possibility of buckling. For typical tubular member 210 materials, the length of the tubular member 210 is preferably limited to between about 40 to 20,000 feet in length.
The shoe 215 is coupled to the self-lubricating expansion mandrel 205 and the tubular member 210. The shoe 215 includes fluid passage 240. The shoe 215 may comprise any number of conventional commercially available shoes such as, for example, Super Seal II float shoe, Super Seal II Down-Jet float shoe or a guide shoe with a sealing sleeve for a latch down plug modified in accordance with the teachings of the present disclosure. In a preferred embodiment, the shoe 215 comprises an aluminum down-jet guide shoe with a sealing sleeve for a latch-down plug available from Halliburton Energy Services in Dallas, Tex., modified in accordance with the teachings of the present disclosure, in order to optimally guide the tubular member 210 in the wellbore, optimally provide an adequate seal between the interior and exterior diameters of the overlapping joint between the tubular members, and to optimally allow the complete drill out of the shoe and plug after the completion of the cementing and expansion operations.
The shoe 215 illustrated in
In the embodiments as depicted in
In the illustrative embodiment depicted, a lower cup seal 220 is coupled to and supported by a support member 250. The lower cup seal 220 prevents foreign materials from entering the interior region of the tubular member 210 adjacent to the self-lubricating expansion mandrel 205. The lower cup seal 220 may comprise any number of conventional commercially available cup seals such as, for example, TP cups, or Selective Injection Packer (SIP) cups modified in accordance with the teachings of the present disclosure. In a preferred embodiment, the lower cup seal 220 comprises a SIP cup seal, available from Halliburton Energy Services in Dallas, Tex. in order to optimally block foreign material and might also contain a body of lubricant adjacent to the expansion mandrel.
The upper cup seal 225 is coupled to and supported by the support member 250. The upper cup seal 225 prevents foreign materials from entering the interior region of the tubular member 210. The upper cup seal 225 may comprise any number of conventional commercially available cup seals such as, for example, TP cups or SIP cups modified in accordance with the teachings of the present disclosure. In a preferred embodiment, the upper cup seal 225 comprises a SIP cup, available from Halliburton Energy Services in Dallas, Tex. in order to optimally block the entry of foreign materials and contain a body of lubricant.
The fluid passage 230 permits fluidic materials to be transported to and from the interior region of the tubular member 210 below the self-lubricating expansion mandrel 205. The fluid passage 230 is coupled to and positioned within the support member 250 and the self-lubricating expansion mandrel 205. The fluid passage 230 preferably extends from a position adjacent to the surface to the bottom of the self-lubricating expansion mandrel 205. The fluid passage 230 is preferably positioned along a centerline of the apparatus 200.
The fluid passage 240 permits fluidic materials to be transported to and from the region exterior to the tubular member 210 and shoe 215. The fluid passage 240 is coupled to and positioned within the shoe 215 in fluidic communication with the interior region of the tubular member 210 below the self-lubricating expansion mandrel 205. The fluid passage 240 preferably has a cross-sectional shape that permits a plug, or other similar device, to be placed in fluid passage 240 to thereby block further passage of fluidic materials. In this manner, the interior region of the tubular member 210 below the self-lubricating expansion mandrel 205 can be fluidicly isolated from the region exterior to the tubular member 210. This permits the interior region of the tubular member 210 below the self-lubricating expansion mandrel 205 to be pressurized. The fluid passage 240 is preferably positioned substantially along the centerline of the apparatus 200.
The fluid passage 240 is preferably selected to convey materials such as cement, drilling mud or epoxies at flow rates and pressures ranging from about 0 to 3,000 gallons/minute and 0 to 9,000 psi in order to optimally fill the annular region between the self-lubricating expansion mandrel and the tubular section so that the tapered or expansion conical surface of the mandrel is forced against the inside diameter of the tubular section to thereby expand the tubular member to the size of the maximum diameter of the self-lubricating expansion mandrel.
Pumping the fluid hydraulically forces the exterior tapered or conical surface of the self-lubricating expansion mandrel into direct sliding contact with the ID of the tubular member as the material of the tubular member is plastically deformed beyond the elastic limit of the tubular member thereby permanently deforming the tubular member to a larger diameter. Significant pressure and heat are generated at the interface between the tubular member and the surface of the self-lubricating expansion mandrel. The use of a self-lubricating expansion mandrel reduces the friction and facilitates the prevention of galling as a result of instantaneous surface to surface “welding” and subsequent relative movement that can occur when two metals slide under high pressure without lubrication.
The self-lubricating expansion mandrel provides grooves or troughs in a textured surface that are below the surface to surface interface contact area of the expansion mandrel. These troughs or grooves are filled with grease or with materials that are solid under normal heat and pressure conditions and that act as lubricants under high temperature and pressure conditions. Being solid or having a very high viscosity such as with grease, allows the lubricant to be retained within the groove or trough the relative motion and extreme pressure between the mandrel and the tubular member cause small quantities of the material to move between the interface contacting surfaces to act as a lubricant. The grooves or troughs act as relative low pressure areas on the interface surface so that a substantial quantity of the lubricant continues to be retained during the expansion. Only small quantities are required to avoid metal to metal contact at the solid lubricant until interface.
The self-lubricating expansion mandrel 205 preferably has a substantially annular cross section. The outside diameter of the self-lubricating expansion mandrel 205 is preferably tapered from a minimum diameter to a maximum diameter to provide a cone shape expansion surface. The wall thickness of the self-lubricating expansion mandrel 205 may range, for example, from about 0.125 to 3 inches. In a preferred embodiment, the wall thickness of the self-lubricating expansion mandrel 205 ranges from about 0.25 to 0.75 inches in order to optimally provide adequate compressive strength with minimal material. The maximum and minimum outside diameters of the expansion cone 928 may range, for example, from about 1 to 47 inches. In a preferred embodiment, the maximum and minimum outside diameters of the self-lubricating expansion mandrel range from about 3.5 to 19 in order to optimally provide expansion of generally available oilfield tubular members.
The self-lubricating expansion mandrel 205 may be fabricated from any number of conventional commercially available materials such as, for example, ceramic, tool steel, titanium or low alloy steel. In a preferred embodiment, the self-lubricating expansion mandrel 205 is fabricated from tool steel in order to optimally provide high strength and abrasion resistance. The surface hardness of the outer surface of the self-lubricating expansion mandrel may range, for example, from about 50 Rockwell C to 70 Rockwell C. In a preferred embodiment, the surface hardness of the outer surface of self-lubricating expansion mandrel 205 ranges from about 58 Rockwell C to 62 Rockwell C in order to optimally provide high yield strength. In a preferred embodiment, the self-lubricating expansion mandrel is heat treated to optimally provide a hard outer surface and a resilient interior body in order to optimally provide abrasion resistance and fracture toughness.
The lubrication of the interface between a self-lubricating expansion mandrel and a tubular member during the radial expansion process will now be described. During the radial expansion process, a self-lubricating expansion mandrel radially expands a tubular member by moving in an axial direction relative to the tubular member. The interface between the outer surface of the tapered portion of the expansion cone and the inner surface of the tubular member includes a leading edge portion and a trailing edge portion.
During the radial expansion process, the leading edge portion is lubricated by the presence of lubrication provided on the surface of the expansion cone. However, because the radial clearance between the expansion cone and the tubular member in the trailing edge portion during the radial expansion process is typically extremely small, and the operating contact pressures between the tubular member and the self-lubricating expansion mandrel are extremely high, the quantity of lubricating fluid provided to the trailing edge portion is typically greatly reduced. In typical radial expansion operations, this reduction in lubrication in the trailing edge portion increases the forces required to radially expand the tubular member. However the retained solid lubrication continues to provide a small quantity of lubrication to keep the metal to metal interface separated and to reduce the friction.
In an exemplary embodiment, a tribological system is used to reduce friction and thereby minimize the expansion forces required during the radial expansion and plastic deformation of the tubular member 210 that includes one or more of the following: (1) a tubular tribology system; (2) a drilling mud tribology system; (3) a lubrication tribology system; and (4) an expansion device tribology system.
In an exemplary embodiment, the tubular tribology system includes the application of coatings of lubricant to the interior surface of the tubular member 210.
In an exemplary embodiment, the drilling mud tribology system includes the addition of lubricating additives to the drilling mud.
In an exemplary embodiment, the lubrication tribology system includes the use of lubricating greases, self-lubricating expansion devices, automated injection/delivery of lubricating greases into the interface between the expansion device 205 and the expandable tubular member 210, surfaces within the interface between the expansion device and the expandable tubular member that are self-lubricating, surfaces within the interface between the expansion device and the expandable tubular member that are textured, self-lubricating surfaces within the interface between the expansion device and the expandable tubular member that include diamond and/or ceramic inserts, thermosprayed coatings, fluoropolymer coatings, PVD films, and/or CVD films.
In an exemplary embodiment, the expandable tubular member 210 includes one or more of the following characteristics: high burst and collapse, the ability to be radially expanded more than about 40%, high fracture toughness, defect tolerance, strain recovery @ 150 F, good bending fatigue, optimal residual stresses, and corrosion resistance to H2S in order to provide optimal characteristics during and after radial expansion and plastic deformation.
In an exemplary embodiment, the expandable tubular member 210 is fabricated from a steel alloy having a charpy energy of at least about 90 ft-lbs in order to provided enhanced characteristics during and after radial expansion and plastic deformation of the expandable tubular member.
In an exemplary embodiment, the expandable tubular member 210 is fabricated from a steel alloy having a weight percentage of carbon of less than about 0.08% in order to provide enhanced characteristics during and after radial expansion and plastic deformation of the expandable tubular member.
In an exemplary embodiment, the expandable tubular member 210 is fabricated from a steel alloy having reduced sulfur content in order to minimize hydrogen induced cracking.
In an exemplary embodiment, the expandable tubular member 210 is fabricated from a steel alloy having a weight percentage of carbon of less than about 0.20% and a charpy-V-notch impact toughness of at least about 6 joules in order to provide enhanced characteristics during and after radial expansion and plastic deformation of the expandable tubular member.
In an exemplary embodiment, the expandable tubular member 210 is fabricated from a steel alloy having a low weight percentage of carbon in order to enhance toughness, ductility, weldability, shelf energy, and hydrogen induced cracking resistance.
In several exemplary embodiments, expandable tubular member 210 is fabricated from a steel alloy having the following percentage compositions in order to provide enhanced characteristics during and after radial expansion and plastic deformation of the expandable tubular member
In an exemplary embodiment, the ratio of the outside diameter D of the expandable tubular member 210 to the wall thickness t of the expandable tubular member ranges from about 12 to 22 in order to enhance the collapse strength of the radially expanded and plastically deformed tubular member.
In an exemplary embodiment, the outer portion of the wall thickness of the radially expanded and plastically deformed expandable tubular member 210 includes tensile residual stresses in order to enhance the collapse strength following radial expansion and plastic deformation.
In several exemplary experimental embodiments, reducing residual stresses in samples of the expandable tubular member 210 prior to radial expansion and plastic deformation increased the collapse strength of the radially expanded and plastically deformed tubular member
In several exemplary experimental embodiments, the collapse strength of radially expanded and plastically deformed samples of the expandable tubular 210 were determined on an as-received basis, after strain aging at 250 F for 5 hours to reduce residual stresses, and after strain aging at 350 F for 14 days to reduce residual stresses as follows:
As indicated by the above table, reducing residual stresses in the expandable tubular member 210, prior to radial expansion and plastic deformation, significantly increased the resulting collapse strength—post expansion.
An improved self-lubricating expansion mandrel may be useful for permitting a wellbore casing to be formed in a subterranean formation by placing a tubular member and a self-lubricating expansion mandrel in a new section of a wellbore, and then extruding the tubular member off of the self-lubricating expansion mandrel by pressurizing an interior portion of the tubular member. The apparatus and method further permits adjacent tubular members in the wellbore to be joined using an overlapping joint that prevents fluid and or gas passage. The apparatus and method further permits a new tubular member to be supported by an existing tubular member by expanding the new tubular member into engagement with the existing tubular member. The apparatus and method further minimizes the reduction in the hole size of the wellbore casing necessitated by the addition of new sections of wellbore casing.
An improved self-lubricating expansion mandrel may be useful for permitting a tie-back liner to be created by extruding a tubular member off of a mandrel by pressurizing and interior portion of the tubular member. In this manner, a tie-back liner is produced. The apparatus and method further permits adjacent tubular members in the wellbore to be joined using an overlapping joint that prevents fluid and/or gas passage. The apparatus and method further permits a new tubular member to be supported by an existing tubular member by expanding the new tubular member into engagement with the existing tubular member.
An apparatus and method for expanding a tubular member is also provided that includes an expandable tubular member, self-lubricating expansion mandrel and a shoe. In one embodiment, the interior portions of the apparatus is composed of materials that permit the interior portions to be removed using a conventional drilling apparatus. In this manner, in the event of a malfunction in a downhole region, the apparatus may be easily removed.
An improved self-lubricating expansion mandrel may be useful for permitting a tubular liner to be attached to an existing section of casing. The apparatus and method further have application to the joining of tubular members in general.
An improved self-lubricating expansion mandrel may be useful for permitting a wellhead to be formed including a number of expandable tubular members positioned in a concentric arrangement. The wellhead preferably includes an outer casing that supports a plurality of concentric casings using contact pressure between the inner casings and the outer casing.
An improved self-lubricating expansion mandrel may be useful for permitting for forming a mono-diameter well casing. The apparatus and method permit the creation of a well casing in a wellbore having a substantially constant internal diameter. In this manner, the operation of an oil or gas well is greatly simplified.
An improved self-lubricating expansion mandrel may be useful for isolating one or more subterranean zones from one or more other subterranean zones is also provided. The apparatus and method permits a producing zone to be isolated from a nonproducing zone using a combination of solid and slotted tubulars. In the production mode, the teachings of the present disclosure may be used in combination with conventional, well known, production completion equipment and methods using a series of packers, solid tubing, perforated tubing, and sliding sleeves, which will be inserted into the disclosed apparatus to permit the commingling and/or isolation of the subterranean zones from each other.
An improved self-lubricating expansion mandrel maybe useful for forming a wellbore casing while the wellbore is drilled is also provided. In this manner, a wellbore casing can be formed simultaneous with the drilling out of a new section of the wellbore. Such an apparatus and method may be used in combination with one or more of the apparatus and methods disclosed in the present disclosure for forming wellbore casings using expandable tubulars. Alternatively, the method and apparatus can be used to create a pipeline or tunnel in a time efficient manner.
A method for manufacturing an expandable member used to complete a structure by radially expanding and plastically deforming the expandable member has been described that includes forming the expandable member from a steel alloy comprising a charpy energy of at least about 90 ft-lbs.
An expandable member for use in completing a structure by radially expanding and plastically deforming the expandable member has been described that includes a steel alloy comprising a charpy energy of at least about 90 ft-lbs.
A structural completion positioned within a structure has been described that includes one or more radially expanded and plastically deformed expandable members positioned within the structure; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from a steel alloy comprising a charpy energy of at least about 90 ft-lbs.
A method for manufacturing an expandable member used to complete a structure by radially expanding and plastically deforming the expandable member has been described that includes forming the expandable member from a steel alloy comprising a weight percentage of carbon of less than about 0.08%.
An expandable member for use in completing a wellbore by radially expanding and plastically deforming the expandable member at a downhole location in the wellbore has been described that includes a steel alloy comprising a weight percentage of carbon of less than about 0.08%.
A structural completion has been described that includes one or more radially expanded and plastically deformed expandable members positioned within the wellbore; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from a steel alloy comprising a weight percentage of carbon of less than about 0.08%.
A method for manufacturing an expandable member used to complete a structure by radially expanding and plastically deforming the expandable member has been described that includes forming the expandable member from a steel alloy comprising a weight percentage of carbon of less than about 0.20% and a charpy V-notch impact toughness of at least about 6 joules.
An expandable member for use in completing a structure by radially expanding and plastically deforming the expandable member has been described that includes a steel alloy comprising a weight percentage of carbon of less than about 0.20% and a charpy V-notch impact toughness of at least about 6 joules.
A structural completion has been described that includes one or more radially expanded and plastically deformed expandable members; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from a steel alloy comprising a weight percentage of carbon of less than about 0.20% and a charpy V-notch impact toughness of at least about 6 joules.
A method for manufacturing an expandable member used to complete a structure by radially expanding and plastically deforming the expandable member has been described that includes forming the expandable member from a steel alloy comprising the following ranges of weight percentages: C, from about 0.002 to about 0.08; Si, from about 0.009 to about 0.30; Mn, from about 0.10 to about 1.92; P, from about 0.004 to about 0.07; S, from about 0.0008 to about 0.006; Al, up to about 0.04; N, up to about 0.01; Cu, up to about 0.3; Cr, up to about 0.5; Ni, up to about 18; Nb, up to about 0.12; Ti, up to about 0.6; Co, up to about 9; and Mo, up to about 5.
An expandable member for use in completing a structure by radially expanding and plastically deforming the expandable member has been described that includes a steel alloy comprising the following ranges of weight percentages: C, from about 0.002 to about 0.08; Si, from about 0.009 to about 0.30; Mn, from about 0.10 to about 1.92; P, from about 0.004 to about 0.07; S, from about 0.0008 to about 0.006; Al, up to about 0.04; N, up to about 0.01; Cu, up to about 0.3; Cr, up to about 0.5; Ni, up to about 18; Nb, up to about 0.12; Ti, up to about 0.6; Co, up to about 9; and Mo, up to about 5.
A structural completion has been described that includes one or more radially expanded and plastically deformed expandable members; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from a steel alloy comprising the following ranges of weight percentages: C, from about 0.002 to about 0.08; Si, from about 0.009 to about 0.30; Mn, from about 0.10 to about 1.92; P, from about 0.004 to about 0.07; S, from about 0.0008 to about 0.006; Al, up to about 0.04; N, up to about 0.01; Cu, up to about 0.3; Cr, up to about 0.5; Ni, up to about 18; Nb, up to about 0.12; Ti, up to about 0.6; Co, up to about 9; and Mo, up to about 5.
A method for manufacturing an expandable tubular member used to complete a structure by radially expanding and plastically deforming the expandable member has been described that includes forming the expandable tubular member with a ratio of the of an outside diameter of the expandable tubular member to a wall thickness of the expandable tubular member ranging from about 12 to 22.
An expandable member for use in completing a structure by radially expanding and plastically deforming the expandable member has been described that includes an expandable tubular member with a ratio of the of an outside diameter of the expandable tubular member to a wall thickness of the expandable tubular member ranging from about 12 to 22.
A structural completion has been described that includes one or more radially expanded and plastically deformed expandable members positioned within the structure; wherein one or more of the radially expanded and plastically deformed expandable members are fabricated from an expandable tubular member with a ratio of the of an outside diameter of the expandable tubular member to a wall thickness of the expandable tubular member ranging from about 12 to 22.
A method of constructing a structure has been described that includes radially expanding and plastically deforming an expandable member; wherein an outer portion of the wall thickness of the radially expanded and plastically deformed expandable member comprises tensile residual stresses.
A structural completion has been described that includes one or more radially expanded and plastically deformed expandable members; wherein an outer portion of the wall thickness of one or more of the radially expanded and plastically deformed expandable members comprises tensile residual stresses.
A method of constructing a structure using an expandable tubular member has been described that includes strain aging the expandable member; and then radially expanding and plastically deforming the expandable member.
A method for manufacturing a tubular member used to complete a wellbore by radially expanding the tubular member at a downhole location in the wellbore has been described that includes forming a steel alloy comprising a concentration of carbon between approximately 0.002% and 0.08% by weight of the steel alloy.
It is understood that variations may be made to the foregoing without departing from the spirit of the invention. For example, the teachings of the present disclosure may be used to form and/or repair a wellbore casing, a pipeline, or a structural support. Furthermore, the various teachings of the present disclosure may combined, in whole or in part, with various of the teachings of the present disclosure.
Although illustrative embodiments of the invention have been shown and described, a wide range of modification, changes and substitution is contemplated in the foregoing disclosure. In some instances, some features of the present invention may be employed without a corresponding use of the other features. Accordingly, it is appropriate that the appended claims be construed broadly and in a manner consistent with the scope of the invention.
The present application is the National Stage patent application for PCT patent application serial number PCT/US2003/025675, filed on Aug. 18, 2003, which claimed the benefit of the filing dates of (1) U.S. provisional patent application Ser. No. 60/412,544, filed on Sep. 20, 2002, the disclosures of which are incorporated herein by reference. The present application is a continuation in part of U.S. utility patent application Ser. No. 10/382,325, filed on Mar. 5, 2003, which was a continuation of U.S. utility patent application Ser. No. 09/588,946, filed on Jun. 7, 2000 (now U.S. Pat. No. 6,557,640 issued May 6, 2003) The present application is related to the following: (1) U.S. patent application Ser. No. 09/454,139, filed on Dec. 3, 1999, (2) U.S. patent application Ser. No. 09/510,913, filed on Feb. 23, 2000, (3) U.S. patent application Ser. No. 09/502,350, filed on Feb. 10, 2000, (4) U.S. Pat. No. 6,328,113, (5) U.S. patent application Ser. No. 09/523,460, filed on Mar. 10, 2000, (6) U.S. patent application Ser. No. 09/512,895, filed on Feb. 24, 2000, (7) U.S. patent application Ser. No. 09/511,941, filed on Feb. 24, 2000, (8) U.S. patent application Ser. No. 09/588,946, filed on Jun. 7, 2000, (9) U.S. patent application Ser. No. 09/559,122, filed on Apr. 26, 2000, (10) PCT patent application serial no. PCT/US00/18635, filed on Jul. 9, 2000, (11) U.S. provisional patent application Ser. No. 60/162,671, filed on Nov. 1, 1999, (12) U.S. provisional patent application Ser. No. 60/154,047, filed on Sep. 16, 1999, (13) U.S. provisional patent application Ser. No. 60/159,082, filed on Oct. 12, 1999, (14) U.S. provisional patent application Ser. No. 60/159,039, filed on Oct. 12, 1999, (15) U.S. provisional patent application Ser. No. 60/159,033, filed on Oct. 12, 1999, (16) U.S. provisional patent application Ser. No. 60/212,359, filed on Jun. 19, 2000, (17) U.S. provisional patent application Ser. No. 60/165,228, filed on Nov. 12, 1999, (18) U.S. provisional patent application Ser. No. 60/221,443, filed on Jul. 28, 2000, (19) U.S. provisional patent application Ser. No. 60/221,645, filed on Jul. 28, 2000, (20) U.S. provisional patent application Ser. No. 60/233,638, filed on Sep. 18, 2000, (21) U.S. provisional patent application Ser. No. 60/237,334, filed on Oct. 2, 2000, (22) U.S. provisional patent application Ser. No. 60/270,007, filed on Feb. 20, 2001, (23) U.S. provisional patent application Ser. No. 60/262,434, filed on Jan. 17, 2001, (24) U.S. provisional patent application Ser. No. 60/259,486, filed on Jan. 3, 2001, (25) U.S. provisional patent application Ser. No. 60/303,740, filed on Jul. 6, 2001, (26) U.S. provisional patent application Ser. No. 60/313,453, filed on Aug. 20, 2001, (27) U.S. provisional patent application Ser. No. 60/317,985, filed on Sep. 6, 2001, (28) U.S. provisional patent application Ser. No. 60/3318,386, filed on Sep. 10, 2001, (29) U.S. utility patent application Ser. No. 09/969,922, filed on Oct. 3, 2001, (30) U.S. utility patent application Ser. No. 10/016,467, filed on Dec. 10, 2001, (31) U.S. provisional patent application Ser. No. 60/343,674, filed on Dec. 27, 2001, (32) U.S. provisional patent application Ser. No. 60/346,309, filed on Jan. 7, 2002, (33) U.S. provisional patent application Ser. No. 60/372,048, filed on Apr. 12, 2002, (34) U.S. provisional patent application Ser. No. 60/380,147, filed on May 6, 2002, (35) U.S. provisional patent application Ser. No. 60/387,486, filed on Jun. 10, 2002, (36) U.S. provisional patent application Ser. No. 60/387,961, filed on Jun. 12, 2002, (37) U.S. provisional patent application Ser. No. 60/394,703, filed on Jun. 26, 2002, (38) U.S. provisional patent application Ser. No. 60/397,284, filed on Jul. 19, 2002, (39) U.S. provisional patent application Ser. No. 60/398,061, filed on Jul. 24, 2002, (40) U.S. provisional patent application Ser. No, 60/405,610, filed on Aug. 23, 2002, (41) U.S. provisional patent application Ser. No. 60/405,394, filed on Aug. 23, 2002, (42) U.S. provisional patent application Ser. No. 60/412,542, filed on Sep. 20, 2002, (43) U.S. provisional patent application Ser. No. 60/412,487, filed on Sep. 20, 2002, (44) U.S. provisional patent application Ser. No. 60/412,488, filed on Sep. 20, 2002, (45) U.S. provisional patent application Ser. No. 60/412,177, filed on Sep. 20, 2002, (46) U.S. provisional patent application Ser. No. 60/412,653, filed on Sep. 20, 2002, (47) U.S. provisional patent application Ser. No. 60/412,544, filed on Sep. 20, 2002, (48) U.S. provisional patent application Ser. No. 60/412,196, filed on Sep. 20, 2002, (49) U.S. provisional patent application Ser. No. 60/412,187, filed on Sep. 20, 2002, and (50) U.S. provisional patent application Ser. No. 60/412,371, filed on Sep. 20, 2002, the disclosures of which are incorporated herein by reference.
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/US03/25675 | 8/18/2003 | WO | 00 | 11/8/2005 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2004/026500 | 4/1/2004 | WO | A |
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| 278517 | May 1990 | DE |
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| 2355738 | Apr 2000 | GB |
| 2343691 | May 2000 | GB |
| 2344606 | Jun 2000 | GB |
| 2345308 | Jul 2000 | GB |
| 2368865 | Jul 2000 | GB |
| 2346165 | Aug 2000 | GB |
| 2346632 | Aug 2000 | GB |
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| 2347950 | Sep 2000 | GB |
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| 2348223 | Sep 2000 | GB |
| 2348657 | Oct 2000 | GB |
| 2357099 | Dec 2000 | GB |
| 2356651 | May 2001 | GB |
| 2350137 | Aug 2001 | GB |
| 2361724 | Oct 2001 | GB |
| 2365898 | Feb 2002 | GB |
| 2359837 | Apr 2002 | GB |
| 2370301 | Jun 2002 | GB |
| 2371064 | Jul 2002 | GB |
| 2371574 | Jul 2002 | GB |
| 2373524 | Sep 2002 | GB |
| 2367842 | Oct 2002 | GB |
| 2374098 | Oct 2002 | GB |
| 2374622 | Oct 2002 | GB |
| 2375560 | Nov 2002 | GB |
| 2380213 | Apr 2003 | GB |
| 2380503 | Apr 2003 | GB |
| 2381019 | Apr 2003 | GB |
| 2343691 | May 2003 | GB |
| 2382364 | May 2003 | GB |
| 2382828 | Jun 2003 | GB |
| 2344606 | Aug 2003 | GB |
| 2347950 | Aug 2003 | GB |
| 2380213 | Aug 2003 | GB |
| 2380214 | Aug 2003 | GB |
| 2380215 | Aug 2003 | GB |
| 2348223 | Sep 2003 | GB |
| 2347952 | Oct 2003 | GB |
| 2348657 | Oct 2003 | GB |
| 2384800 | Oct 2003 | GB |
| 2384801 | Oct 2003 | GB |
| 2384802 | Oct 2003 | GB |
| 2384803 | Oct 2003 | GB |
| 2384804 | Oct 2003 | GB |
| 2384805 | Oct 2003 | GB |
| 2384806 | Oct 2003 | GB |
| 2384807 | Oct 2003 | GB |
| 2384808 | Oct 2003 | GB |
| 2385353 | Oct 2003 | GB |
| 2385354 | Oct 2003 | GB |
| 2385355 | Oct 2003 | GB |
| 2385356 | Oct 2003 | GB |
| 2385357 | Oct 2003 | GB |
| 2385358 | Oct 2003 | GB |
| 2385359 | Oct 2003 | GB |
| 2385360 | Oct 2003 | GB |
| 2385361 | Oct 2003 | GB |
| 2385362 | Oct 2003 | GB |
| 2385363 | Oct 2003 | GB |
| 2385619 | Oct 2003 | GB |
| 2385620 | Oct 2003 | GB |
| 2385621 | Oct 2003 | GB |
| 2385622 | Oct 2003 | GB |
| 2385623 | Oct 2003 | GB |
| 2387405 | Oct 2003 | GB |
| 2387861 | Oct 2003 | GB |
| 2388134 | Nov 2003 | GB |
| 2388860 | Nov 2003 | GB |
| 2355738 | Dec 2003 | GB |
| 2374622 | Dec 2003 | GB |
| 2388391 | Dec 2003 | GB |
| 2388392 | Dec 2003 | GB |
| 2388393 | Dec 2003 | GB |
| 2388394 | Dec 2003 | GB |
| 2388395 | Dec 2003 | GB |
| 2356651 | Feb 2004 | GB |
| 2368865 | Feb 2004 | GB |
| 2388860 | Feb 2004 | GB |
| 2388861 | Feb 2004 | GB |
| 2388862 | Feb 2004 | GB |
| 2391886 | Feb 2004 | GB |
| 2390628 | Mar 2004 | GB |
| 2391033 | Mar 2004 | GB |
| 2392686 | Mar 2004 | GB |
| 2393199 | Mar 2004 | GB |
| 2373524 | Apr 2004 | GB |
| 2390387 | Apr 2004 | GB |
| 2392686 | Apr 2004 | GB |
| 2392691 | Apr 2004 | GB |
| 2391575 | May 2004 | GB |
| 2394979 | May 2004 | GB |
| 2395506 | May 2004 | GB |
| 2392932 | Jun 2004 | GB |
| 2395734 | Jun 2004 | GB |
| 2396635 | Jun 2004 | GB |
| 2396639 | Jun 2004 | GB |
| 2396640 | Jun 2004 | GB |
| 2396641 | Jun 2004 | GB |
| 2396642 | Jun 2004 | GB |
| 2396643 | Jun 2004 | GB |
| 2396644 | Jun 2004 | GB |
| 2396646 | Jun 2004 | GB |
| 2373468 | Jul 2004 | GB |
| 2397261 | Jul 2004 | GB |
| 2397262 | Jul 2004 | GB |
| 2397263 | Jul 2004 | GB |
| 2397264 | Jul 2004 | GB |
| 2397265 | Jul 2004 | GB |
| 2390622 | Aug 2004 | GB |
| 2398087 | Aug 2004 | GB |
| 2398317 | Aug 2004 | GB |
| 2398318 | Aug 2004 | GB |
| 2398319 | Aug 2004 | GB |
| 2398320 | Aug 2004 | GB |
| 2398321 | Aug 2004 | GB |
| 2398322 | Aug 2004 | GB |
| 2398323 | Aug 2004 | GB |
| 2398326 | Aug 2004 | GB |
| 2382367 | Sep 2004 | GB |
| 2396641 | Sep 2004 | GB |
| 2396643 | Sep 2004 | GB |
| 2397261 | Sep 2004 | GB |
| 2397262 | Sep 2004 | GB |
| 2397263 | Sep 2004 | GB |
| 2397264 | Sep 2004 | GB |
| 2397265 | Sep 2004 | GB |
| 2399120 | Sep 2004 | GB |
| 2399579 | Sep 2004 | GB |
| 2399580 | Sep 2004 | GB |
| 2399848 | Sep 2004 | GB |
| 2399849 | Sep 2004 | GB |
| 2399850 | Sep 2004 | GB |
| 2384502 | Oct 2004 | GB |
| 2396644 | Oct 2004 | GB |
| 2400126 | Oct 2004 | GB |
| 2400393 | Oct 2004 | GB |
| 2400624 | Oct 2004 | GB |
| 2396640 | Nov 2004 | GB |
| 2396642 | Nov 2004 | GB |
| 2401136 | Nov 2004 | GB |
| 2401137 | Nov 2004 | GB |
| 2401138 | Nov 2004 | GB |
| 2401630 | Nov 2004 | GB |
| 2401631 | Nov 2004 | GB |
| 2401632 | Nov 2004 | GB |
| 2401633 | Nov 2004 | GB |
| 2401634 | Nov 2004 | GB |
| 2401635 | Nov 2004 | GB |
| 2401636 | Nov 2004 | GB |
| 2401637 | Nov 2004 | GB |
| 2401638 | Nov 2004 | GB |
| 2401639 | Nov 2004 | GB |
| 2381019 | Dec 2004 | GB |
| 2382368 | Dec 2004 | GB |
| 2394979 | Dec 2004 | GB |
| 2401136 | Dec 2004 | GB |
| 2401137 | Dec 2004 | GB |
| 2401138 | Dec 2004 | GB |
| 2403970 | Jan 2005 | GB |
| 2403971 | Jan 2005 | GB |
| 2403972 | Jan 2005 | GB |
| 2400624 | Feb 2005 | GB |
| 2404402 | Feb 2005 | GB |
| 2404676 | Feb 2005 | GB |
| 2404680 | Feb 2005 | GB |
| 2384807 | Mar 2005 | GB |
| 2388134 | Mar 2005 | GB |
| 2398320 | Mar 2005 | GB |
| 2398323 | Mar 2005 | GB |
| 2399120 | Mar 2005 | GB |
| 2399848 | Mar 2005 | GB |
| 2399849 | Mar 2005 | GB |
| 2405893 | Mar 2005 | GB |
| 2406117 | Mar 2005 | GB |
| 2406118 | Mar 2005 | GB |
| 2406119 | Mar 2005 | GB |
| 2406120 | Mar 2005 | GB |
| 2406125 | Mar 2005 | GB |
| 2406126 | Mar 2005 | GB |
| 2410518 | Mar 2005 | GB |
| 2406599 | Apr 2005 | GB |
| 2389597 | May 2005 | GB |
| 2399119 | May 2005 | GB |
| 2399580 | May 2005 | GB |
| 2401630 | May 2005 | GB |
| 2401631 | May 2005 | GB |
| 2401632 | May 2005 | GB |
| 2401633 | May 2005 | GB |
| 2401634 | May 2005 | GB |
| 2401635 | May 2005 | GB |
| 2401636 | May 2005 | GB |
| 2401637 | May 2005 | GB |
| 2401638 | May 2005 | GB |
| 2401639 | May 2005 | GB |
| 2408278 | May 2005 | GB |
| 2399579 | Jun 2005 | GB |
| 2409216 | Jun 2005 | GB |
| 2409218 | Jun 2005 | GB |
| 2401893 | Jul 2005 | GB |
| 2414749 | Jul 2005 | GB |
| 2414750 | Jul 2005 | GB |
| 2414751 | Jul 2005 | GB |
| 2398326 | Aug 2005 | GB |
| 2403970 | Aug 2005 | GB |
| 2403971 | Aug 2005 | GB |
| 2403972 | Aug 2005 | GB |
| 2380503 | Oct 2005 | GB |
| 2382828 | Oct 2005 | GB |
| 2398317 | Oct 2005 | GB |
| 2398318 | Oct 2005 | GB |
| 2398319 | Oct 2005 | GB |
| 2398321 | Oct 2005 | GB |
| 2398322 | Oct 2005 | GB |
| 2412681 | Oct 2005 | GB |
| 2412682 | Oct 2005 | GB |
| 2413136 | Oct 2005 | GB |
| 2414493 | Nov 2005 | GB |
| 2409217 | Dec 2005 | GB |
| 2410518 | Dec 2005 | GB |
| 2415003 | Dec 2005 | GB |
| 2415219 | Dec 2005 | GB |
| 2395506 | Jan 2006 | GB |
| 2412681 | Jan 2006 | GB |
| 2412682 | Jan 2006 | GB |
| 2415797 | Jan 2006 | GB |
| 2415983 | Jan 2006 | GB |
| 2415987 | Jan 2006 | GB |
| 2415988 | Jan 2006 | GB |
| 2416177 | Jan 2006 | GB |
| 2416361 | Jan 2006 | GB |
| 2416556 | Feb 2006 | GB |
| 2416794 | Feb 2006 | GB |
| 2416795 | Feb 2006 | GB |
| 2417273 | Feb 2006 | GB |
| 2417275 | Feb 2006 | GB |
| 2418216 | Mar 2006 | GB |
| 2418217 | Mar 2006 | GB |
| 2418690 | Apr 2006 | GB |
| 2418941 | Apr 2006 | GB |
| 2418942 | Apr 2006 | GB |
| 2418943 | Apr 2006 | GB |
| 2418944 | Apr 2006 | GB |
| 2419907 | May 2006 | GB |
| 2419913 | May 2006 | GB |
| 2400126 | Jun 2006 | GB |
| 2414749 | Jun 2006 | GB |
| 2420810 | Jun 2006 | GB |
| 2421257 | Jun 2006 | GB |
| 2421258 | Jun 2006 | GB |
| 2421259 | Jun 2006 | GB |
| 2421262 | Jun 2006 | GB |
| 2421529 | Jun 2006 | GB |
| 2422164 | Jul 2006 | GB |
| 2406599 | Aug 2006 | GB |
| 2418690 | Aug 2006 | GB |
| 2421257 | Aug 2006 | GB |
| 2421258 | Aug 2006 | GB |
| 2422859 | Aug 2006 | GB |
| 2422860 | Aug 2006 | GB |
| 2423317 | Aug 2006 | GB |
| 2424077 | Aug 2006 | GB |
| 2404676 | Sep 2006 | GB |
| 2414493 | Sep 2006 | GB |
| 2408277 | May 2008 | GB |
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| 102875 | Apr 1995 | JP |
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| 94068 | Apr 2000 | JP |
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| 2039214 | Jul 1995 | RU |
| 2056201 | Mar 1996 | RU |
| 2064357 | Jul 1996 | RU |
| 2068940 | Nov 1996 | RU |
| 2068943 | Nov 1996 | RU |
| 2079633 | May 1997 | RU |
| 2083798 | Jul 1997 | RU |
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| 641070 | Jan 1979 | SU |
| 909114 | May 1979 | SU |
| 832049 | May 1981 | SU |
| 853089 | Aug 1981 | SU |
| 874952 | Oct 1981 | SU |
| 894169 | Jan 1982 | SU |
| 899850 | Jan 1982 | SU |
| 907220 | Feb 1982 | SU |
| 953172 | Aug 1982 | SU |
| 959878 | Sep 1982 | SU |
| 976019 | Nov 1982 | SU |
| 976020 | Nov 1982 | SU |
| 989038 | Jan 1983 | SU |
| 1002514 | Mar 1983 | SU |
| 1041671 | Sep 1983 | SU |
| 1051222 | Oct 1983 | SU |
| 1086118 | Apr 1984 | SU |
| 1077803 | Jul 1984 | SU |
| 1158400 | May 1985 | SU |
| 1212575 | Feb 1986 | SU |
| 1250637 | Aug 1986 | SU |
| 1324722 | Jul 1987 | SU |
| 1324722 | Jul 1987 | SU |
| 1411434 | Jul 1988 | SU |
| 1430498 | Oct 1988 | SU |
| 1432190 | Oct 1988 | SU |
| 1601330 | Oct 1990 | SU |
| 1627663 | Feb 1991 | SU |
| 1659621 | Jun 1991 | SU |
| 1663179 | Jul 1991 | SU |
| 1663180 | Jul 1991 | SU |
| 1677225 | Sep 1991 | SU |
| 1677248 | Sep 1991 | SU |
| 1686123 | Oct 1991 | SU |
| 1686124 | Oct 1991 | SU |
| 1686125 | Oct 1991 | SU |
| 1698413 | Dec 1991 | SU |
| 1710694 | Feb 1992 | SU |
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| WO9717526 | May 1997 | WO |
| WO9717527 | May 1997 | WO |
| WO9720130 | Jun 1997 | WO |
| WO9721901 | Jun 1997 | WO |
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| Number | Date | Country | |
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| 20070131431 A1 | Jun 2007 | US |
| Number | Date | Country | |
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| 60412544 | Sep 2002 | US |