This patent application claims the benefit of U.S. Provisional Patent Application No. 61/443,465, filed Feb. 16, 2011, the entire teachings and disclosure of which are incorporated herein by reference thereto.
This invention generally relates to methods and apparatuses to increase the extraction efficiency of flat organic light emitting diodes (OLEDs), i.e., small molecular OLEDs (SMOLEDs) and/or polymer LEDs (PLEDs), and more particularly to the design and manufacture of microlens arrays for use therewith.
The demand for organic and inorganic light emitting devices (LEDs) in lighting and displays is growing. Their overall external quantum efficiency is the product of the internal quantum efficiency and extraction efficiency. The internal quantum efficiency is the number of photons generated per injected electron. The extraction efficiency is the fraction of the generated photons that exits the (O)LED through its front (viewing) face.
Typical OLEDs are made on a transparent substrate, typically glass or plastic, through which the light is emitted. The light generated inside the OLED toward the front (viewing) face of the device is therefore emitted through the organic layers, the transparent indium tin oxide (ITO) anode, and the glass or plastic substrate.
However, there are innate limitations to the light extraction from the OLEDs due to the interface between the organic and indium tin oxide (ITO) anode layers and the glass substrate, and between the glass substrate and air. This results in part of the generated light being reflected back and trapped inside these layers by total internal reflection (TIR). Specifically, the index of refraction of the organic layers (1.7≦norg) and of the ITO (nITO≦2.0) is larger than that of the glass or plastic substrate (nglass˜nplastic˜1.5). Also, the index of refraction of the glass or plastic substrate is higher than that of air (nair=1.03). This results in significant fractions of the emitted light being totally internally reflected back to the organic and ITO layers, and back to the glass substrate, respectively. Almost all of the light trapped in the organic and ITO layers is reabsorbed and consequently lost. Most of the light trapped in the glass or plastic layer is waveguided to the edge of the OLED (glass mode) resulting in edge emissions through the glass. In both cases, the reflected light does not exit through the front of the device. This limits the OLED luminous and power efficiencies.
Indeed, it has been reported that the extraction efficiency, defined as the fraction of the light generated in the device that exits in the front (viewing) direction, in this typical geometry is
i.e., only ˜17% for the typical indices given above; ˜53% is trapped in the high-index organic and ITO layers, and ˜30% is waveguided through the glass to the edges of the device as illustrated in
There have been many attempts to increase the extraction efficiency by refractive index matching between each layer, using low n materials, and surface texturing or patterning. Among them, surface patterning with a periodic microlens array on the substrate has been developed and studied. The advantage of this method is that it does not change the original performance of the device because the microlens array pattern is fabricated on the blank side of the glass or plastic substrate. Unfortunately, the largest enhancement of the electroluminescence (EL) output compared to conventional ITO-coated glass-based OLEDs with a 7 μm diameter microlens array is only 68%. Construction of these microlens arrays is also difficult and costly.
There is a need, therefore, for a method of enhancing the EL of OLEDs using a microlens array that is economical and commercially viable. Embodiments of the present invention provide such methods and microlens arrays. These and other advantages of the invention, as well as additional inventive features, will be apparent from the description of the invention provided herein.
In view of the above, embodiments of the present invention provide new and improved microlens array geometry and methods of manufacture therefor that enhance the electroluminescence (EL) output of OLEDs beyond that achieved to date.
More specifically, embodiments of the present invention enhance the extraction efficiency of flat OLEDs (i.e., small molecular OLEDs (SMOLEDs) and/or polymer LEDs (PLEDs)) using a novel and nonobvious microlens array geometry patterned on the front face of such devices. In accordance with the teachings of the present invention, the geometry of the microlens array provides significant advantage over prior microlens arrays. Specifically, embodiments of the array of the present invention utilize individual microlenses whose dimensions are larger than those the OLED's individual pixel. Such embodiments of the present invention provide a design of the array that enhances the outcoupled light at a level unattained so far, creating a new (micro)luminaire that is structurally integrated with the OLED pixel. Further, embodiments of the present invention provide economical, commercially viable methods of enhancing light extraction from organic light emitting diodes (OLEDs) using such a microlens array. Still further, embodiments of the present invention provide methods of manufacturing such microlens arrays.
Other aspects, objectives and advantages of the invention will become more apparent from the following detailed description when taken in conjunction with the accompanying drawings.
The accompanying drawings incorporated in and forming a part of the specification illustrate several aspects of the present invention and, together with the description, serve to explain the principles of the invention. In the drawings:
While the invention will be described in connection with certain preferred embodiments, there is no intent to limit it to those embodiments. On the contrary, the intent is to cover all alternatives, modifications and equivalents as included within the spirit and scope of the invention as defined by the appended claims.
Turning now to the drawings, embodiments of both the manufacturing methods and resulting microlens arrays and OLEDs incorporating same will be discussed. As will become apparent, embodiments of the present invention provide an easy and cost effective method of making polymer-based microlens arrays with soft lithography. Indeed, preliminary results of embodiments of OLEDs patterned with 1.5 μm diameter microlens arrays constructed in accordance with the teachings of the present invention show 100% enhancement of the electroluminescence (EL) output compared to conventional ITO-coated glass-based OLEDs. This compares to the largest enhancement reported to date discussed above, with 7 μm diameter microlens array, which is 68%.
In the conventional OLED geometry, once light is reflected back into a waveguided mode, it can only escape as edge emission, be absorbed by the waveguiding medium, or be scattered. The microlens array can extract light in the guiding mode in the substrate to a normal direction. This extraction mechanism extracts more light not only in the light emitting area but also outside of the light emitting area as long as there is a guided light in the substrate as shown by
As such, extraction enhancement is governed by the area of the micro lens array patterned, as well as the period and dimensions of each microlens in the array. Embodiments of the present invention have a large area of microlens array, e.g. 16×16 mm2, compared to the light emitting area, e.g. OLED pixel area of 3.3×3 mm2. As will be discussed more fully below, use of such large area microlens confirms that extraction is not restricted only to the pixel area of the OLED.
Soft lithography is used to create various structures with critical dimensions of a few microns. The advantages of the technique include ease of fabrication, large area structures, and very ordered and uniform patterns. With this method, a structure may be generated with a PDMS mold that has an identical relief pattern to that which is desired. Once the mold has been filled with a suitable material, it is simply stamped on any surface to create the pattern. Like all molds, the crucial step is to create the relief pattern that is the inverse of the structure to be generated. For feature size of a few microns, PDMS is an excellent choice because of its flexibility and non-wetting properties. Typically, PDMS is poured onto a master stamp to create the relief pattern. After the PDMS is cured and solidified, it is peeled off the master stamp and is ready to use. As long as the master stamp is not physically damaged, it can be used repeatedly for making more molds, which can also be used many times until damaged through wear.
Returning to
In one embodiment, the microlens array only covers a portion of the ITO-coated glass as shown in
The ITO side of the glass is patterned and etched to form the electrodes for multiple OLED pixels. Before the OLED pixel array is fabricated, the ITO glass is thoroughly cleaned with detergent and organic solvents and subsequently treated in a UV ozone oven to adjust the ITO work function and facilitate hole injection as is known. The organic layers, CsF, LiF, or other buffer layer, and A1 cathode are all thermally deposited in a vacuum evaporation chamber (background pressure <5×10−6 ton) inside an Ar-filled glove box. The organic layers consist of a hole injecting layer, typically copper phthalocyanine (CuPc) or MoO3, a hole transport layer (HTL), typically N,N′-diphenyl-N,N′-bis(1-naphthylphenyl)-1,1′-biphenyl-4,4′-diamine (NPD), an emitting layer of any of various materials and blends, and an electron transport layer (ETL), typically tris(8-hydroxyquinoline) Al(Alq3) or 4,7-diphenyl-1,10-phenanthroline (BPhen).
Microlens embodiments of the present invention, as examples, were used on two different emitting materials to determine effectiveness thereof. The two materials were green light-emitting Alq3, and blue light-emitting 4,4′-bis(2,2′-diphenylvinyl)-1,1′-biphenyl (DPVBi). Following deposition of a 1 nm-thick LiF or CsF buffer layer, the final A1 cathode layer is deposited through a shadow mask to yield several 3 mm wide stripes. As a result, there are 8 OLED devices on the ITO glass. Half of them are on the plain glass portion of the substrate and the rest are on the glass substrate covered with the microlens array. The devices are encapsulated after fabrication to protect them from exposure to water and oxygen and subsequent degradation. Wires are connected to the electrodes of each pixel and to the power source for measurements. In this way, there can be a direct comparison between the textured and plain glass substrates. Measurements are done by placing the device on the opening of an integrating sphere. The signal collected in the integrating sphere is transmitted through an optical fiber to an Ocean Optics spectrometer (Model Number S2000PCI) for analysis.
In this
The spectra of the blue OLEDs (
When the pixels are placed in the middle of the opening of the integrating sphere, pixel 1 is covered by a larger area of the microlens array pattern in comparison to pixel 2. The measurement using this configuration indicates that extraction of the light waveguided in the glass is proportional to the microlens pattern area. Trace 700 illustrates ML pixel 1-4, and trace 702 illustrates ML pixel 1-3, whereas trace 706 illustrates the reference ITO pixel 1-1 and trace 704 illustrates reference ITO pixel 1-2. This clearly demonstrates that the microlens array is extracting light from the substrate outside of the light emitting pixel area and a large patterned area results in more extraction as long as there is a waveguiding substrate.
Embodiments of the invention are not limited to the OLED/microlens materials and structures described above. For example, embodiments of the OLEDs can be fabricated on a plastic substrate, including directly on the (modified) PU microlens array. A mirror can also be included in an embodiment to reflect the light that propagates in a direction opposite to the display direction. In another embodiment, the substrate on which the OLED pixels are fabricated is beveled on both sides of each pixel. In addition to common glass and plastic substrates, a substrate with a high refractive index is used in an embodiment. Encapsulated OLEDs are also subject to the described outcoupling enhancement. Importantly, as shown for green and blue OLEDs, mixed colors, such as red, green, and blue are utilized on the same OLED pixel array to enhance the outcoupling of all colors, including the resulting mixed white light are also included. Microcavity OLEDs also benefit from the outcoupling enhancement, and are also included.
All references, including publications, patent applications, and patents cited herein are hereby incorporated by reference to the same extent as if each reference were individually and specifically indicated to be incorporated by reference and were set forth in its entirety herein.
The use of the terms “a” and “an” and “the” and similar referents in the context of describing the invention (especially in the context of the following claims) is to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context. The terms “comprising,” “having,” “including,” and “containing” are to be construed as open-ended terms (i.e., meaning “including, but not limited to,”) unless otherwise noted. Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context. The use of any and all examples, or exemplary language (e.g., “such as”) provided herein, is intended merely to better illuminate the invention and does not pose a limitation on the scope of the invention unless otherwise claimed. No language in the specification should be construed as indicating any non-claimed element as essential to the practice of the invention.
Preferred embodiments of this invention are described herein, including the best mode known to the inventors for carrying out the invention. Variations of those preferred embodiments may become apparent to those of ordinary skill in the art upon reading the foregoing description. The inventors expect skilled artisans to employ such variations as appropriate, and the inventors intend for the invention to be practiced otherwise than as specifically described herein. Accordingly, this invention includes all modifications and equivalents of the subject matter recited in the claims appended hereto as permitted by applicable law. Moreover, any combination of the above-described elements in all possible variations thereof is encompassed by the invention unless otherwise indicated herein or otherwise clearly contradicted by context.
This invention was made in part with Government support under Grant Number DE-AC02-07CH11358 awarded by the Department of Energy. The Government has certain rights in this invention.
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Number | Date | Country | |
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61443465 | Feb 2011 | US |