Patent Grant
12000056
This disclosure relates to electrolysis cells for fuel production.
The trends towards the use of hydrogen as a fuel, increasing the importance of identifying alternative hydrogen producing feedstocks. One of the potential feedstocks is water through electrolysis. However, the electrolysis of water is an energy intensive process and uses water with high ionic concentrations, depending on the electrolysis products. The use of renewable energy is one solution for the energy demands, as electrolysis provides a valuable technique for storing energy.
Further, the use of seawater for the electrolysis would provide abundant feedstock. However, seawater poses various technical difficulties, including high TDS (Total Dissolved Salts), membrane clogging, precipitate formation, corrosion, and energy requirements, among others.
An embodiment described herein provides a tandem electrolysis cell. The tandem electrolysis cell includes a common enclosure that has two chambers. A first chamber is separated from a second chamber by a cation selective membrane. A common anode and a first cathode (cathode A) are disposed in the first chamber. The first cathode and the common anode are configured to electrolyze a saline solution to hydrogen and oxygen. A second cathode (cathode B) is disposed in the second chamber. The second cathode and the common anode are configured to electrolyze a brine solution in the first chamber to form chlorine and water in the second chamber to form hydrogen and hydroxide ions.
Another embodiment described herein provides a system for electrolyzing seawater. The system includes a tandem electrolysis cell. The tandem electrolysis cell includes a common enclosure that two chambers, wherein a first chamber is separated from a second chamber by a cation selective membrane. A common anode and a first cathode (cathode A) are disposed in the first chamber, wherein the first cathode and the common anode are configured to electrolyze a saline solution to hydrogen and oxygen in a first electrolysis reaction. A second cathode (cathode B) is disposed in the second chamber, wherein the second cathode and the common anode are configured to electrolyze a brine solution in the first chamber to form chlorine and water in the second chamber to form hydrogen and hydroxide ions in a second electrolysis reaction. The system includes an atmospheric water producer. The atmospheric water producer includes a solar panel to generate electricity and a battery to store the electricity, wherein the battery powers the tandem electrolysis cell. The atmospheric water producer includes a cooling system powered by the battery, wherein the cooling system harvests atmospheric moisture. The atmospheric water producer includes a water storage tank to collect the harvested atmospheric moisture, wherein the water storage tank provides the water to the second chamber.
Another embodiment described herein provides a method for using a tandem electrolysis cell (TEC) to form hydrogen, oxygen, chlorine, and sodium hydroxide. The method includes determining if a sodium ion concentration in a first chamber of the TEC is below a sodium ion threshold, and, while the sodium ion concentration remains below the sodium ion threshold, iteratively flowing saline water into a half-cell of a first chamber including a first cathode (cathode A); forming hydrogen at cathode A and oxygen at a common anode; and monitoring the sodium ion concentration in the first chamber. The method includes determining if a pH in a second chamber of the TEC is below a pH threshold, and, while the pH remains below the pH threshold, iteratively: flowing fresh water into a half-cell of a second chamber including a second cathode (cathode B); forming hydrogen and hydroxide ions at cathode B and oxygen at the common anode; and monitoring the pH in the first chamber.
Embodiments described herein provide a tandem electrolysis cell that produces hydrogen, chlorine gas, and sodium hydroxide from saline water, such as seawater. An integrated system includes the tandem electrolysis cell and a device to harvest atmospheric moisture to produce fresh water for use in the tandem electrolysis cell. The tandem electrolysis cell includes a single enclosure having two chambers, which hold three electrodes, including a first cathode (A), a second cathode (B) and a common anode. Cathode A and the common anode are in a first chamber, separated by a partial barrier extending below the electrodes to prevent mixing of the gases formed. Cathode B is in a separate chamber that is separated from the common anode by a sodium permeable membrane. The structure of the tandem electrolysis cell is discussed further with respect to
The proposed configuration operates in two stages by initially reducing alkalized saline water in the first chamber to produce hydrogen gas at cathode A. Simultaneously, oxygen is being produced at the common anode. This stage continues till the concentration of Na in the first chamber exceeds the desired sodium ion threshold of the sodium permeable membrane. In various embodiments, the threshold limit is about 100,000 ppm, or about 70,000 ppm, or about 50,000 ppm. Above the threshold limit, sodium ions permeate from the first chamber to the second chamber in sufficient amounts to support the electrolysis in the second chamber. Upon reaching equilibrium, the second stage begins by activating Cathode B in the second chamber to produce hydrogen, while the common anode will oxidize chloride ions to chlorine gas in the first chamber. The NaOH formed in the second chamber is pumped to an alkaline storage tank attached to the first chamber, for example, by flushing the second chamber with a fresh water being generated from the atmospheric moisture harvester device. The stages are discussed in more detail with respect to
The cathodes 102 and 104 are exposed to different environments, and can be made from the same or different materials. As cathode A 102 is in a saline environment, materials resistant to corrosion in the environment would provide longer operation. In some embodiments, cathode A is made from carbon with a surface impregnated with a catalytic metal, such as platinum or other noble metal. In some embodiments, cathode A 102 is made from a platinum mesh. In some embodiments, cathode A is made from a catalytic metal oxide, such as alumina, titania, or silica, among others, that is impregnated with one or more metals for conductivity and catalysis.
Cathode B 104 is in a less corrosive environment, and, thus, can be made from lower cost materials. In some embodiments, cathode B 104 is made from Rainey nickel. As used herein, a Rainey nickel electrode may be formed by etching aluminum from an aluminum nickel alloy, forming a porous nickel mesh. In some embodiments, cathode B 104 is a stainless steel electrode.
The common anode 106 is exposed to a more corrosive environment than either cathode A 102 or cathode B 104 as oxygen gas or chlorine gas is formed at the common anode 106. Accordingly, the selection of material for the common anode 106 is limited by the corrosivity of this environment. In some embodiments, the common anode 106 is made from carbon with a surface impregnated with catalytic metal. In some embodiments, the common anode 106 is a platinum mesh.
The container 108 is divided into two chambers 110 and 112 by a cation selective membrane, such as a sodium permeable membrane 114. The sodium permeable membrane 114 allows the transport of sodium ions from the first chamber 110 to the second chamber 112. In some embodiments, the sodium permeable membrane 114 includes a polymer, such as sulfonated tetrafluoroethylene, available as the Nafion® product line from DuPont de Nemours, Inc., of Wilmington, Del., USA. In some embodiments, the sodium permeable membrane 114 includes polyvinylidene fluoride copolymers.
The first chamber 110 is an electrolysis cell for the formation of hydrogen and oxygen from a saline solution. During operation, the saline solution, such as seawater, is introduced into the first chamber 110 through a saline port 116. An alkali solution may be introduced into the first chamber 110 through an alkali addition port 118. A gas barrier 120 separates cathode A 102 from the anode 106, preventing gas formed at each electrode from mixing. A hydrogen port 122 is located proximate to the cathode A 102 to remove hydrogen formed at the cathode A 102. And oxygen port 124 is located proximate to the anode 106 to remove oxygen formed at the anode.
The second chamber 112 is an electrolysis half-cell for the formation of hydrogen from freshwater. During the operation of the second chamber 112, freshwater is introduced into the second chamber 112 through a water port 126. Sodium ions pass through the sodium permeable membrane 114. As the water is electrolytes to form hydrogen, hydroxide ions are also formed. A sodium hydroxide solution exits the second chamber 112 to an alkali removal port 128. The hydrogen formed in the second chamber 112 exits through a second hydrogen port 130. Chlorine is formed at the anode 106, and exits the first chamber 110 through a chlorine removal port 132.
The two chambers 110 and 112 operate at different stages of the process. While the first chamber 110 is operational for the formation of hydrogen and oxygen, the ports 126, 128, 130, and 132 are closed, for example, with an electrically actuated valve. While the second chamber 112, and the anode in the first chamber 110, are functioning to form hydrogen and chlorine, the ports 116, 118, 122, and 124 are closed. This is discussed further with respect to
At a certain voltage, termed the critical voltage, between both electrodes, the electrodes start to produce hydrogen gas at the negative electrode, cathode A 102 and oxygen gas at the positively based electrode, the anode 106. The amount of gases produced per unit time is directly related to the current that passes through the electrolysis cell.
The pH is maintained at a high level, for example, above 8, 10, or above 12, by the addition of NaOH through the alkali port 118 from a NaOH tank 208, forcing oxygen production The electrolysis half reactions taking place between cathode A 102 and the anode 106 are:
Combining the half reaction pair yields the overall decomposition of water into oxygen and hydrogen:
The oxygen that exits the first chamber through the oxygen removal port 124. In some embodiments, the oxygen is conveyed by an oxygen line 210 to an ozone generator 212, which uses electricity from the solar panel 206 to generate ozone, for example, used to prevent microbial growth in a water storage tank 214.
The hydrogen exits the first chamber 110 through the hydrogen removal port 122. The hydrogen can then be collected and provided as a fuel for other devices or a feedstock for other processes. As water is being dissociated through electrolysis, over time, the concentration of NaCl in the first chamber 112 will increase and exceed the desired threshold limit of the sodium permeable membrane 114 that function as a barrier between the first chamber 110 and the second chamber 112.
In some embodiments, a controller 216 monitors parameters in each of the chambers 110 and 112 through sensors 218 and 220. Sensors 218 in the first chamber 110 may be used to monitor liquid level in the first chamber 110, the concentration of sodium ions. In these embodiments, when the concentration reaches a predetermined threshold level, such as 70,000 ppm, or higher, control lines 222 are used to switch off the first power supply 224 to cathode A 102 and switch on the second power supply 226, providing power to cathode B 104. In some embodiments, the first power supply 224 and the second power supply 226 are batteries charged from the solar cell 206 of the atmospheric water producer 204, allowing hydrogen production to continue for at least some period of time when energy is not being produced by the solar panel 206.
In some embodiments, the controller 216 activates valves (not shown) to close ports 122, 124, 116, and 118 after switching off the first power supply 224. In this embodiment, the controller 216 then activates valves (not shown) to open ports 126, 128, 130, and 132 prior to switching on the second power supply 226.
In some embodiments, the controller 216 communicates through communication lines 228, such as a universal serial bus (USB), with a control panel 230 in the atmospheric water producer 204. This allows the entry of control parameters into the controller 216, such as the concentrations at which to switch from the half-cell utilizing cathode A 102 to the half-cell cathode B 104.
The integrated electrolysis system 200 is not limited to the use of a controller 216 monitoring sensors 218 and 222 determine when to switch between half-cells. In some embodiments, a timer, for example, in the control panel 230, determines how long each half-cell should be running before switching to the other half-cell.
The water contained in the second chamber 112 is provided from the atmospheric water producer 204 through a water supply line 232, and fed to the second chamber through the water port 126. The amount of water provided to the second chamber 112 is controlled to maintain the ionic concentration used for conductivity. To allow for conductivity in the solution in the second chamber 112, a sodium chloride concentration is maintained in a range of about 180 g/L to about 200 g/L with a pH of about 1 to about 4.5.
During operation of the second half-cell, chloride ions are converted to chlorine at the anode 106. The chlorine exits the first chamber 110 though the chlorine removal port 132. Hydrogen is generated at cathode B 104 and exits the second chamber through the hydrogen removal port 130. As the hydrogen is formed from the water, hydroxyl ions are formed. To maintain charge balance, sodium ions migrate through the sodium permeable membrane 114 from the first chamber 110 to the second chamber 112. The sodium ions and hydroxyl ions form a sodium hydroxide solution that is removed from the second chamber through the alkali removal port 128. This solution is carried through an alkali line 234 to the sodium hydroxide storage tank 208 for use during operation of the first half-cell.
In the saturated brine, the chloride ions are oxidized at the anode 106 losing electrons to become chlorine gas and the water molecules are reduced at cathode B 104 forming hydrogen gas. The electrolysis half reaction taking place between cathode B 104 and the anode 106 are:
Combining the half reaction pair gives the overall reaction for the electrolysis of the brine into chlorine and hydrogen:
In some embodiments, the controller 216 monitors the parameters each of the chambers 110 and 112 through the sensors 218 and 220. For example, in some embodiments, when the pH or salt concentration in the second chamber 112 approaches the limits described above, the controller 216 switches off the second power supply 226 and closes valves on ports 126, 128, 130, and 132. The controller 216 then opens valves on ports 116, 118, 122, and 124 and switches on the first power supply 224 to return the operation to the first stage, described with respect to
In some embodiments, no valves are used on the ports. In these embodiments, the placement of reservoirs, such as the sodium hydroxide storage tank 208, the water storage tank 214, and a seawater tank (not shown) is used to drive the flow of the solutions instead. For example, the seawater tank and the sodium hydroxide storage tank 208 may be placed at the same level as the TEC 100. As electrolysis of the seawater in the first chamber 110 lowers the level of the liquid in the first chamber 110, liquids from the seawater tank and the sodium hydroxide storage tank 208 will then flow into the first chamber 110.
Similarly, as the level of the liquid in the second chamber 112 drops during hydrolysis, liquid from the reservoirs may be pulled into the second chamber 112. In this example, a water pump may be used to drive the flow of the sodium hydroxide from the second chamber 112 by pumping freshwater into the second chamber 112.
As the atmospheric water producer 204 may be used in environments that have a significant amount of particulates, a cleaning system may be included to keep the solar cell 206 clean. In some embodiments, the cleaning system may include a pump 306 used to draw water from the water storage tank 214 and provide the water to a nozzle 308 that sprays the water over the front of the solar panel 206. A catch basin 310 at the bottom of the solar panel 206 captures the water, which is passed through a filter 312 to remove the particulates prior to the water being returned to the water storage tank 214.
The water is generated by a cooling system, such as refrigeration system 314. In some embodiments, the refrigeration system 314 includes standard refrigeration components, such as a compressor to compress a refrigerant gas, a condenser to condense the refrigerant gas to a liquid, and a heat exchanger that is cooled by allowing the liquid refrigerant to flash back to a gas. The expanding refrigerant in the heat exchanger condenses water from the atmosphere, which is conveyed by a water line 316 to the water storage tank 214. In some embodiments, a water tap 318 is included to allow water from the water storage tank 214 to be accessed for other purposes. Similarly, ozone from the ozone generator 212 may be tapped for other uses 320.
Although the atmospheric water producer 204 shown in the example of
The quality of the harvested moisture was assessed by the measurement of different parameters that are listed in Table 1. From this table it can be clearly seen that the total dissolved solids (TDS) value is lower than seawater and some fresh water sources. Thus the harvested moisture can be used directly in the TEC without further treatment, lower energy costs.
At block 506, these sodium ion (Na+) concentration in the first chamber is monitored. At block 508, a determination is made as to whether the sodium ion concentration is above a threshold value, such as 70,000 ppm or higher. If the sodium ion concentration is not above the threshold value, process flow returns to block 502 and stage I of the process continues with the production of hydrogen at cathode A and oxygen at the anode.
If at block 508, the sodium ion concentration is above the threshold value, process flow moves to block 510 to begin stage II of the process. At block 510, freshwater is flowed into the cathode B half-cell of the second chamber. At block 512, power is supplied to cathode B and the anode, forming hydrogen at cathode B and chlorine at the anode. At block 514, a sodium hydroxide solution formed in the electrolysis in the cathode B half-cell is flowed out of the second chamber.
At block 516, the pH in the second chamber is monitored. At block 518, a determination is made as to whether the pH is below a threshold value, such as 8 or 9. If the pH is below the threshold value, process flow returns to block 510 and stage II of the process continues. If the pH is above a threshold value, or the sodium hydroxide concentration is above a threshold value, process flow returns to block 502 to restart stage I of the process.
As described above with respect to
The controller 602 includes a processor 608. The processor 608 may be a microprocessor, a multi-core processor, a multithreaded processor, an ultra-low-voltage processor, an embedded processor, or a virtual processor. In some embodiments, the processor 608 may be part of a system-on-a-chip (SoC) in which the processor 608 and the other components of the controller 602 are formed into a single integrated electronics package. In various embodiments, the processor 608 may include processors from Intel® Corporation of Santa Clara, Calif., from Advanced Micro Devices, Inc. (AMD) of Sunnyvale, Calif., or from ARM Holdings, LTD., Of Cambridge, England. Any number of other processors from other suppliers may also be used.
The processor 608 may communicate with other components of the controller 602 over a bus 610. The bus 610 may include any number of technologies, such as industry standard architecture (ISA), extended ISA (EISA), peripheral component interconnect (PCI), peripheral component interconnect extended (PCIx), PCI express (PCIe), or any number of other technologies. The bus 610 may be a proprietary bus, for example, used in an SoC based system. Other bus technologies may be used, in addition to, or instead of, the technologies above.
The bus 610 may couple the processor 608 to a memory 612. In some embodiments, such as in PLCs and other process control units, the memory 612 is integrated with a data store 614 used for long-term storage of programs and data. The memory 612 include any number of volatile and nonvolatile memory devices, such as volatile random-access memory (RAM), static random-access memory (SRAM), flash memory, and the like. In smaller devices, such as PLCs, the memory 612 may include registers associated with the processor itself. The data store 614 is used for the persistent storage of information, such as data, applications, operating systems, and so forth. The data store 614 may be a nonvolatile RAM, a solid-state disk drive, or a flash drive, among others. In some embodiments, the data store 614 will include a hard disk drive, such as a micro hard disk drive, a regular hard disk drive, or an array of hard disk drives, for example, associated with a DCS or a cloud server.
The bus 610 couples the processor 608 to a sensor interface 616. The sensor interface 616 connects the controller 602 to the sensors used to monitor the electrolysis. In some embodiments, the sensor interface 616 is a bank of analog-to-digital converters (ADCs), an I2C bus, a serial peripheral interface (SPI) bus, or a Fieldbus®, and the like. In some embodiments, a level sensor in the first chamber 618 and a level sensor in the second chamber 620. The level sensors 618 and 620 may include conductivity sensors, optical sensors, or float sensors, among others. In some embodiments, the level sensors 618 and 620 are not used, for example, if placement of the liquid storage vessels is used to maintain levels in the chambers.
In some embodiments, the sensors include an ion sensor in the first chamber 622. In some embodiments, the ion sensor in the first chamber 622 is a sodium ion sensor, a pH sensor, an oxidation-reduction potential (ORP) sensor, or a chloride ion sensor, among others. In some embodiments, the sensors include an ion sensor in the second chamber 624. In some embodiments, the ion sensor in the second chamber 624 is a pH sensor, a sodium ion sensor, or a chloride ion sensor, among others. Combinations of the sensors may be used to monitor the electrolysis process.
The bus 610 couples the processor 608 to a control interface 626 is used to couple the controller 602 to controls used to operate the TEC. In some embodiments, the controller interface 626 is a bank of relays, a bank of MOSFET power controllers, a serial peripheral interface (SPI), or a Fieldbus, and the like. In some embodiments, the controls include valves on the ports for the cathode A half-cell 628, as described with respect to
The bus 610 couples the processor 608 to a human machine interface (HMI) 632. The HMI 632 couples the controller 602 to a control panel 230, as described with respect to
The data store 614 includes blocks of stored instructions that, when executed, direct the processor 608 to implement the functions of the controller 602. The data store 614 includes a block 634 of instructions to direct the processor to activate the power supplies 224 and 226. In various embodiments this is performed, for example, by activating a relay in the controller interface to activate a power supply, activating a MOSFET in the controller interface to activate a power supply, or sending instructions over a bus to a control unit on the power supply.
The data store 614 includes a block 636 of instructions to direct the processor to open or close valves for one of the half-cells. For example, the instructions may instruct the valves for the cathode A half-cell to open while instructing the valves for the cathode B half-cell to close. In various embodiments, this is performed by activating relays to energize solenoid valves for opening and deactivating relays to deenergize solenoids allowing valves to close.
The data store 614 also includes a block 638 of instructions to monitor the ionic concentrations in each of the chambers 110 and 112 (
The data store 614 includes a block 640 of instructions to direct the processor to monitor the levels in each of the chambers 110 and 112 using the level sensors 618 and 620. In some embodiments, the monitoring is performed by determining a voltage level from a conductivity sensor. In some embodiments, the monitoring is performed continuously to allow the controller 602 to interrupt the process if a level in a chamber 110 or 112 drops below a preset threshold, such as about 90%, about 80%, or lower.
The data store 614 includes a block 642 of instructions to direct the processor to implement the process control for the TEC. As described in detail with respect to
In this embodiment, the data store 614 also includes a block 644 of instructions to direct the processor to implement a timer for switching between the half-cells. In many installations, the TEC and atmospheric water producer may be in a field or remote location. Accordingly, in some embodiments, the block 644 of instructions monitor the operation of the equipment and, in event of a failure, such as of a sensor, moved to a timed sequence for switching between the half-cells. In some embodiments, the ion sensors 622 and 624 and the block 642 of instructions 642 to implement the cycle control are omitted, and the timer is used to switch back and forth between the half-cells on a precalculated timeframe. For example, the timer may switch between cells on a timeframe of about 10 minutes, about 20 minutes, about 30 minutes, or longer. Further, the timer may be used with a power monitor to determine the amount of electrolysis that has occurred to increase the timeframe if the insolation on the solar panel has decreased, lowering the amount of power available.
An embodiment described herein provides a tandem electrolysis cell. The tandem electrolysis cell includes a common enclosure that has two chambers. A first chamber is separated from a second chamber by a cation selective membrane. A common anode and a first cathode (cathode A) are disposed in the first chamber. The first cathode and the common anode are configured to electrolyze a saline solution to hydrogen and oxygen. A second cathode (cathode B) is disposed in the second chamber. The second cathode and the common anode are configured to electrolyze a brine solution in the first chamber to form chlorine and water in the second chamber to form hydrogen and hydroxide ions.
In an aspect, the enclosure includes a corrosion resistant inner surface. In an aspect, the corrosion resistant inner surface is glass. In an aspect, the enclosure includes a ceramic.
In an aspect, the first chamber includes a gas barrier, wherein cathode A is on a first side of the gas barrier and the anode is on a second side of the gas barrier. The gas barrier extends below cathode A and the anode, and an opening below the gas barrier allows liquid flow between cathode A and the anode.
In an aspect, the tandem electrolysis cell includes a saline port proximate to cathode A on the first side of the gas barrier. In an aspect, the tandem electrolysis cell includes an alkali port proximate to cathode A on the first side of the gas barrier. In an aspect, the tandem electrolysis cell includes a hydrogen removal port proximate to cathode A on the first side of the gas barrier, wherein the hydrogen removal port is on a top surface of the enclosure.
In an aspect, the tandem electrolysis cell includes an oxygen removal port proximate to the anode on a second side of the gas barrier, wherein the oxygen removal port is on a top surface of the enclosure. In an aspect, the tandem electrolysis cell includes a chlorine removal port proximate to the anode on a second side of the gas barrier, wherein the chlorine removal port is on a top surface of the enclosure.
In an aspect, the cation selective membrane is a sodium permeable membrane. In an aspect, the sodium permeable membrane includes sulfonated tetrafluoroethylene or polyvinylidene fluoride copolymers or both.
In an aspect, the tandem electrolysis cell includes a water port on the second chamber. In an aspect, the tandem electrolysis cell includes an alkali removal port on the second chamber. In an aspect, the tandem electrolysis cell includes a hydrogen removal port on the second chamber.
Another embodiment described herein provides a system for electrolyzing seawater. The system includes a tandem electrolysis cell. The tandem electrolysis cell includes a common enclosure that two chambers, wherein a first chamber is separated from a second chamber by a cation selective membrane. A common anode and a first cathode (cathode A) are disposed in the first chamber, wherein the first cathode and the common anode are configured to electrolyze a saline solution to hydrogen and oxygen in a first electrolysis reaction. A second cathode (cathode B) is disposed in the second chamber, wherein the second cathode and the common anode are configured to electrolyze a brine solution in the first chamber to form chlorine and water in the second chamber to form hydrogen and hydroxide ions in a second electrolysis reaction. The system includes an atmospheric water producer. The atmospheric water producer includes a solar panel to generate electricity and a battery to store the electricity, wherein the battery powers the tandem electrolysis cell. The atmospheric water producer includes a cooling system powered by the battery, wherein the cooling system harvests atmospheric moisture. The atmospheric water producer includes a water storage tank to collect the harvested atmospheric moisture, wherein the water storage tank provides the water to the second chamber.
In an aspect, the system includes a sodium hydroxide storage tank to store sodium hydroxide produced during operation of the second chamber for use during operation of the first chamber. In an aspect, the system includes a first power supply to provide power to cathode A and the common anode. In an aspect, the system includes a second power supply to provide power to cathode B and the common anode.
In an aspect, the system includes an ion sensor in the first chamber. In an aspect, the ion sensor is a sodium electrode. In an aspect, the system includes an ion sensor in the second chamber. In an aspect, the ion sensor is a pH electrode. In an aspect, the system includes a level sensor in the first chamber, or a level sensor in the second chamber, or both.
In an aspect, the system includes a controller to control the tandem electrolysis cell, wherein the controller includes a processor and a data store. The data store includes instructions to direct the processor to determine if a sodium ion concentration in the first chamber is above a threshold, and, if so, turn off a first power supply providing power to cathode A and the common anode and turn on a second power supply to provide power to cathode B and the common anode. The data store includes instructions to direct the processor to determine if a pH in the second chamber is below a threshold, and, if so, turn off a second power supply providing power to cathode B and the common anode and turn on a first power supply to provide power to cathode A and the common anode.
In an aspect, the data store includes instructions to direct the processor to close valves for the first electrolysis reaction after turning off the first power supply and open valves for the second electrolysis reaction prior to turning on the second power supply. In an aspect, the data store includes instructions to direct the processor to close valves for the second electrolysis reaction after turning off the second power supply and open valves for the first electrolysis reaction prior to turning on the first power supply.
Another embodiment described herein provides a method for using a tandem electrolysis cell (TEC) to form hydrogen, oxygen, chlorine, and sodium hydroxide. The method includes determining if a sodium ion concentration in a first chamber of the TEC is below a sodium ion threshold, and, while the sodium ion concentration remains below the sodium ion threshold, iteratively flowing saline water into a half-cell of a first chamber including a first cathode (cathode A); forming hydrogen at cathode A and oxygen at a common anode; and monitoring the sodium ion concentration in the first chamber. The method includes determining if a pH in a second chamber of the TEC is below a pH threshold, and, while the pH remains below the pH threshold, iteratively: flowing fresh water into a half-cell of a second chamber including a second cathode (cathode B); forming hydrogen and hydroxide ions at cathode B and oxygen at the common anode; and monitoring the pH in the first chamber.
In an aspect, when the sodium ion concentration exceeds the sodium ion threshold in the first chamber, a first power supply that supplies power to cathode A and the common anode is powered off, and a second power supplies that supplies power to cathode B and the common anode is powered on.
In an aspect, when the pH drops below a pH threshold in the second chamber, a second power supply that supplies power to cathode B and the common anode is powered off, and a first power supplies that supplies power to cathode A and the common anode is powered on.
Other implementations are also within the scope of the following claims.
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