Polymerisation catalysts

CCHEMISTRY METALLURGY C08Organic compounds C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F4/00Polymerisation catalysts

C08F4/005Friedel-Crafts catalysts in general C08F4/02Carriers therefor C08F4/022Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts C08F4/025Metal oxides C08F4/027Polymers C08F4/04Azo-compounds C08F4/06Metallic compounds other than hydrides and other than metallo-organic compounds Boron halide or aluminium halide complexes with organic compounds containing oxygen C08F4/08of alkali metals C08F4/083an alkali metal bound to oxygen C08F4/086an alkali metal bound to nitrogen C08F4/10of alkaline earth metals, zinc, cadmium, mercury, copper or silver C08F4/12of boron, aluminium, gallium, indium, thallium or rare earths C08F4/14Boron halides or aluminium halides Complexes thereof with organic compounds containing oxygen C08F4/16of silicon, germanium, tin, lead, titanium, zirconium or hafnium C08F4/18Oxides C08F4/20of antimony, bismuth, vanadium, niobium or tantalum C08F4/22of chromium, molybdenum or tungsten C08F4/24Oxides C08F4/26of manganese, iron group metals or platinum group metals C08F4/28Oxygen or compounds releasing free oxygen C08F4/30Inorganic compounds C08F4/32Organic compounds C08F4/34Per-compounds with one peroxy-radical C08F4/36Per-compounds with more than one peroxy radical C08F4/38Mixtures of peroxy-compounds C08F4/40Redox systems C08F4/42Metals Metal hydrides Metallo-organic compounds Use thereof as catalyst precursors C08F4/44selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides C08F4/46selected from alkali metals C08F4/461Catalysts containing at least two different components covered by the same or by different subgroups of group C08F4/46 C08F4/463selected from sodium or potassium C08F4/465Metalic sodium or potassium C08F4/466an alkali metal bound to a cyclic carbon C08F4/468at least two metal atoms in the same molecule C08F4/48selected from lithium, rubidium, caesium or francium C08F4/482Metallic lithium, rubidium, caesium or francium C08F4/484an alkali metal bound to a cyclic carbon C08F4/486at least two metal atoms in the same molecule C08F4/488at least two lithium atoms in the same molecule C08F4/50selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver C08F4/52selected from boron, aluminium, gallium, indium, thallium or rare earths C08F4/54together with other compounds thereof C08F4/545rare earths being present C08F4/56Alkali metals being the only metals present C08F4/565Lithium being present C08F4/58together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof C08F4/60together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof C08F4/60003the metallic compound containing a multidentate ligand C08F4/60006Bidentate ligand C08F4/6001Neutral ligand C08F4/60013NN C08F4/60017NO C08F4/6002NS C08F4/60024OS C08F4/60027PN C08F4/60031PO C08F4/60034PP C08F4/60037PS C08F4/60041Monoanionic ligand C08F4/60044NN C08F4/60048NO C08F4/60051NS C08F4/60055ON C08F4/60058OO C08F4/60062PN C08F4/60065PO C08F4/60068Dianionic ligand C08F4/60072NN C08F4/60075NO C08F4/60079OO C08F4/60082Tridentate ligand C08F4/60086Neutral ligand C08F4/60089NNN C08F4/60093NNO C08F4/60096NNS C08F4/60099NSN C08F4/60103PNN C08F4/60106PNP C08F4/6011Monoanionic ligand C08F4/60113NNN C08F4/60117NNO C08F4/6012ONN C08F4/60124ONO C08F4/60127ON*O C08F4/60131PNO C08F4/60134SNN C08F4/60137SNO C08F4/60141Dianionic ligand C08F4/60144NN(R)C C08F4/60148NN(R)N C08F4/60151NNO C08F4/60155ON(R)C C08F4/60158ONO C08F4/60162O*O*P C08F4/60165OSO C08F4/60168Tetra- or multi-dentate ligand C08F4/60172Neutral ligand C08F4/60175ONNO C08F4/60179PNNN C08F4/60182Monoanionic ligand C08F4/60186Dianionic ligand C08F4/60189ONNO C08F4/60193OOOO C08F4/60196OSSO C08F4/602Component covered by group C08F4/60 with an organo-aluminium compound C08F4/6022Component of C08F4/60 containing at least two different metals C08F4/6024containing magnesium C08F4/6026containing aluminium C08F4/6028with an alumoxane C08F4/603Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound C08F4/6032Component of C08F4/60 containing at least two different metals C08F4/6035containing magnesium C08F4/6037containing aluminium C08F4/605Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/602 or C08F4/603 C08F4/6052Component of C08F4/60 containing at least two different metals C08F4/6055containing magnesium C08F4/6057containing aluminium C08F4/606Catalyst comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by groups C08F4/60 C08F4/6065containing silicium C08F4/607Catalyst containing a specific non-metal or metal-free compound C08F4/608inorganic C08F4/609organic C08F4/6091hydrocarbon C08F4/6092containing aliphatic unsaturation C08F4/6093containing halogen C08F4/6094containing oxygen C08F4/6095containing nitrogen C08F4/6096containing sulfur C08F4/6097containing phosphorus C08F4/6098containing another heteroatom C08F4/61Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44 C08F4/611Pretreating with non-metals or metal-free compounds C08F4/612Pretreating with metals or metal-containing compounds C08F4/613with metals covered by group C08F4/60 or compounds thereof C08F4/614with magnesium or compounds thereof C08F4/6141and metals of C08F4/60 or compounds thereof C08F4/6143halides of magnesium C08F4/6145and metals of group C08F4/60 or compounds thereof C08F4/6146organo-magnesium compounds C08F4/6148magnesium or compounds thereof not provided for in C08F4/6143 or C08F4/6146 C08F4/615with aluminium or compounds thereof C08F4/6152and metals of C08F4/60 or compounds thereof C08F4/6155and magnesium or compounds thereof C08F4/6157and metals of C08F4/60 or compounds thereof C08F4/616with silicon or compounds thereof C08F4/6162and metals of C08F4/60 or compounds thereof C08F4/6165and magnesium or compounds thereof C08F4/6167and aluminium or compounds thereof C08F4/617with metals or metal-containing compounds, not provided for in groups C08F4/613 - C08F4/616 C08F4/6172and metals of C08F4/60 or compounds thereof C08F4/6174and magnesium or compounds thereof C08F4/6176and aluminium or compounds thereof C08F4/6178and silicon or compounds thereof C08F4/618with metals or metal-containing compounds, provided for in at least two of the groups C08F4/613 - C08F4/617 C08F4/6181and metals of C08F4/60 or compounds thereof C08F4/6183and magnesium or compounds thereof C08F4/6185and aluminium or compounds thereof C08F4/6186and silicon or compounds thereof C08F4/6188and metals or metal-containing compounds of C08F4/617 C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond C08F4/61904in combination with another component of C08F4/60 C08F4/61908in combination with an ionising compound other than alumoxane C08F4/61912in combination with an organoaluminium compound C08F4/61916supported on a carrier C08F4/6192containing at least one cyclopentadienyl ring, condensed or not C08F4/61922containing at least two cyclopentadienyl rings, fused or not C08F4/61925two cyclopentadienyl rings being mutually non-bridged C08F4/61927two cyclopentadienyl rings being mutually bridged C08F4/62Refractory metals or compounds thereof C08F4/62003the metallic compound containing a multidentate ligand C08F4/62006Bidentate ligand C08F4/6201Neutral ligand C08F4/62013NN C08F4/62017NO C08F4/6202NS C08F4/62024OS C08F4/62027PN C08F4/62031PO C08F4/62034PP C08F4/62037PS C08F4/62041Monoanionic ligand C08F4/62044NN C08F4/62048NO C08F4/62051NS C08F4/62055ON C08F4/62058OO C08F4/62062PN C08F4/62065PO C08F4/62068Dianionic ligand C08F4/62072NN C08F4/62075NO C08F4/62079OO C08F4/62082Tridentate ligand C08F4/62086Neutral ligand C08F4/62089NNN C08F4/62093NNO C08F4/62096NNS C08F4/62099NSN C08F4/62103PNN C08F4/62106PNP C08F4/6211Monoanionic ligand C08F4/62113NNN C08F4/62117NNO C08F4/6212ONN C08F4/62124ONO C08F4/62127ON*O C08F4/62131PNO C08F4/62134SNN C08F4/62137SNO C08F4/62141Dianionic ligand C08F4/62144NN(R)C C08F4/62148NN(R)N C08F4/62151NNO C08F4/62155ON(R)C C08F4/62158ONO C08F4/62162O*O*P C08F4/62165OSO C08F4/62168Tetra- or multi-dentate ligand C08F4/62172Neutral ligand C08F4/62175ONNO C08F4/62179PNNN C08F4/62182Monoanionic ligand C08F4/62186Dianionic ligand C08F4/62189ONNO C08F4/62193OOOO C08F4/62196OSSO C08F4/622Component covered by group C08F4/62 with an organo-aluminium compound C08F4/6222Component of C08F4/62 containing at least two different metals C08F4/6224containing magnesium C08F4/6226containing aluminium C08F4/6228with an aluminoxane C08F4/623Component covered by group C08F4/62 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound C08F4/6232Component of C08F4/62 containing at least two different metals C08F4/6235containing magnesium C08F4/6237containing aluminium C08F4/625Component covered by group C08F4/62 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/622 or C08F4/623 C08F4/6252Component of C08F4/62 containing at least two different metals C08F4/6255containing magnesium C08F4/6257containing aluminium C08F4/626Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/62 C08F4/6265containing silicium C08F4/627Catalysts containing a specific non-metal or metal-free compound C08F4/628inorganic C08F4/629organic C08F4/6291hydrocarbon C08F4/6292containing aliphatic unsaturation C08F4/6293containing halogen C08F4/6294containing oxygen C08F4/6295containing nitrogen C08F4/6296containing sulfur C08F4/6297containing phosphorus C08F4/6298containing another heteroatom C08F4/63Pretreating the metal or compound covered by group C08F4/62 before the final contacting with the metal or compound covered by group C08F4/44 C08F4/631Pretreating with non-metals or metal-free compounds C08F4/632Pretreating with metals or metal-containing compounds C08F4/633with metals covered by group C08F4/62 or compounds thereof C08F4/634with magnesium or compounds thereof C08F4/6341and metals of C08F4/62 or compounds thereof C08F4/6343halides of magnesium C08F4/6345and metals of C08F4/62 or compounds thereof C08F4/6346organo-magnesium compounds C08F4/6348magnesium or compounds thereof not provided for in C08F4/6345 or C08F4/6346 C08F4/635with aluminium or compounds thereof C08F4/6352and metals of C08F4/62 or compounds thereof C08F4/6355and magnesium or compounds thereof C08F4/6357and metals of C08F4/62 or compounds thereof C08F4/636with silicon or compounds thereof C08F4/6362and metals of C08F4/62 or compounds thereof C08F4/6365and magnesium or compounds thereof C08F4/6367and aluminium or compounds thereof C08F4/637with metals or metal-containing compounds, not provided for in groups C08F4/633 - C08F4/636 C08F4/6372and metals of C08F4/62 or compounds thereof C08F4/6374and magnesium or compounds thereof C08F4/6376and aluminium or compounds thereof C08F4/6378and silicon or compounds thereof C08F4/638with metals or metal-containing compounds, not provided for in a single group of groups C08F4/633 - C08F4/637 C08F4/6381and metals or metal-containing compounds of C08F4/62 C08F4/6383and magnesium or compounds thereof C08F4/6385and aluminium or compounds thereof C08F4/6386and silicon or compounds thereof C08F4/6388and metals or metal-containing compounds of C08F4/637 C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond C08F4/63904in combination with another component of C08F4/62 C08F4/63908in combination with an ionising compound other than alumoxane C08F4/63912in combination with an organoaluminium compound C08F4/63916supported on a carrier C08F4/6392containing at least one cyclopentadienyl ring, condensed or not C08F4/63922containing at least two cyclopentadienyl rings, fused or not C08F4/63925two cyclopentadienyl rings being mutually non-bridged C08F4/63927two cyclopentadienyl rings being mutually bridged C08F4/64Titanium, zirconium, hafnium or compounds thereof C08F4/64003the metallic compound containing a multidentate ligand C08F4/64006Bidentate ligand C08F4/6401Neutral ligand C08F4/64013NN C08F4/64017NO C08F4/6402NS C08F4/64024OS C08F4/64027PN C08F4/64031PO C08F4/64034PP C08F4/64037PS C08F4/64041Monoanionic ligand C08F4/64044NN C08F4/64048NO C08F4/64051NS C08F4/64055ON C08F4/64058OO C08F4/64062PN C08F4/64065PO C08F4/64068Dianionic ligand C08F4/64072NN C08F4/64075NO C08F4/64079OO C08F4/64082Tridentate ligand C08F4/64086Neutral ligand C08F4/64089NNN C08F4/64093NNO C08F4/64096NNS C08F4/64099NSN C08F4/64103PNN C08F4/64106PNP C08F4/6411Monoanionic ligand C08F4/64113NNN C08F4/64117NNO C08F4/6412ONN C08F4/64124ONO C08F4/64127ON*O C08F4/64131PNO C08F4/64134SNN C08F4/64137SNO C08F4/64141Dianionic ligand C08F4/64144NN(R)C C08F4/64148NN(R)N C08F4/64151NNO C08F4/64155ON(R)C C08F4/64158ONO C08F4/64162O*O*P C08F4/64165OSO C08F4/64168Tetra- or multi-dentate ligand C08F4/64172Neutral ligand C08F4/64175ONNO C08F4/64179PNNN C08F4/64182Monoanionic ligand C08F4/64186Dianionic ligand C08F4/64189ONNO C08F4/64193OOOO C08F4/64196OSSO C08F4/642Component covered by group C08F4/64 with an organo-aluminium compound C08F4/6421Titanium tetrahalides with organo-aluminium compounds C08F4/6423Component of C08F4/64 containing at least two different metals C08F4/6425containing magnesium C08F4/6426containing aluminium C08F4/6428with an aluminoxane C08F4/643Component coverd by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound C08F4/6432Component of C08F4/64 containing at least two different metals C08F4/6435containing magnesium C08F4/6437containing aluminium C08F4/645Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643 C08F4/6452Component of C08F4/64 containing at least two different metals C08F4/6455containing magnesium C08F4/6457containing aluminium C08F4/646Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 C08F4/6465containing silicium C08F4/647Catalysts containing a specific non-metal or metal-free compound C08F4/648inorganic C08F4/649organic C08F4/6491hydrocarbon C08F4/6492containing aliphatic unsaturation C08F4/6493containing halogen C08F4/6494containing oxygen C08F4/6495containing nitrogen C08F4/6496containing sulfur C08F4/6497containing phosphorus C08F4/6498containing another heteroatom C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44 C08F4/651Pretreating with non-metals or metal-free compounds C08F4/652Pretreating with metals or metal-containing compounds C08F4/653with metals of C08F4/64 or compounds thereof C08F4/654with magnesium or compounds thereof C08F4/6541and metals of C08F4/64 or compounds thereof C08F4/6543halides of magnesium C08F4/6545and metals of C08F4/64 or compounds thereof C08F4/6546organo-magnesium compounds C08F4/6548magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546 C08F4/655with aluminium or compounds thereof C08F4/6552and metals of C08F4/64 or compounds thereof C08F4/6555and magnesium or compounds thereof C08F4/6557and metals of C08F4/64 or compounds thereof C08F4/656with silicon or compounds thereof C08F4/6562and metals of C08F4/64 or compounds thereof C08F4/6565and magnesium or compounds thereof C08F4/6567and aluminium or compounds thereof C08F4/657with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656 C08F4/6572and metals of C08F4/64 or compounds thereof C08F4/6574and magnesium or compounds thereof C08F4/6576and aluminium or compounds thereof C08F4/6578and silicon or compounds thereof C08F4/658with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657 C08F4/6581and metals of C08F4/64 or compounds thereof C08F4/6583and magnesium or compounds thereof C08F4/6585and aluminium or compounds thereof C08F4/6586and silicon or compounds thereof C08F4/6588and metals or metal-containing compounds of C08F4/657 C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond C08F4/65904in combination with another component of C08F4/64 C08F4/65908in combination with an ionising compound other than alumoxane C08F4/65912in combination with an organoaluminium compound C08F4/65916supported on a carrier C08F4/6592containing at least one cyclopentadienyl ring, condensed or not C08F4/65922containing at least two cyclopentadienyl rings, fused or not C08F4/65925two cyclopentadienyl rings being mutually non-bridged C08F4/65927two cyclopentadienyl rings being mutually bridged C08F4/68Vanadium, niobium, tantalum or compounds thereof C08F4/68008the metallic compound containing a multidentate ligand C08F4/68017Bidentate ligand C08F4/68025Neutral ligand C08F4/68034NN C08F4/68043NO C08F4/68051NS C08F4/6806OS C08F4/68068PN C08F4/68077PO C08F4/68086PP C08F4/68094PS C08F4/68103Monoanionic ligand C08F4/68112NN C08F4/6812NO C08F4/68129NS C08F4/68137ON C08F4/68146OO C08F4/68155PN C08F4/68163PO C08F4/68172Dianionic ligand C08F4/68181NN C08F4/68189NO C08F4/68198OO C08F4/68206Tridentate ligand C08F4/68215Neutral ligand C08F4/68224NNN C08F4/68232NNO C08F4/68241NNS C08F4/6825NSN C08F4/68258PNN C08F4/68267PNP C08F4/68275Monoanionic ligand C08F4/68284NNN C08F4/68293NNO C08F4/68301ONN C08F4/6831ONO C08F4/68318ON*O C08F4/68327PNO C08F4/68336SNN C08F4/68344SNO C08F4/68353Dianionic ligand C08F4/68362NN(R)C C08F4/6837NN(R)N C08F4/68379NNO C08F4/68387ON(R)C C08F4/68396ONO C08F4/68405O*O*P C08F4/68413OSO C08F4/68422Tetra- or multi-dentate ligand C08F4/68431Neutral ligand C08F4/68439ONNO C08F4/68448PNNN C08F4/68456Monoanionic ligand C08F4/68465Dianionic ligand C08F4/68474ONNO C08F4/68482OOOO C08F4/68491OSSO C08F4/685Vanadium or compounds thereof in combination with titanium or compounds thereof C08F4/69Chromium, molybdenum, tungsten or compounds thereof C08F4/69008the metallic compound containing a multidentate ligand C08F4/69017Bidentate ligand C08F4/69025Neutral ligand C08F4/69034NN C08F4/69043NO C08F4/69051NS C08F4/6906OS C08F4/69068PN C08F4/69077PO C08F4/69086PP C08F4/69094PS C08F4/69103Monoanionic ligand C08F4/69112NN C08F4/6912NO C08F4/69129NS C08F4/69137ON C08F4/69146OO C08F4/69155PN C08F4/69163PO C08F4/69172Dianionic ligand C08F4/69181NN C08F4/69189NO C08F4/69198OO C08F4/69206Tridentate ligand C08F4/69215Neutral ligand C08F4/69224NNN C08F4/69232NNO C08F4/69241NNS C08F4/6925NSN C08F4/69258PNN C08F4/69267PNP C08F4/69275Monoanionic ligand C08F4/69284NNN C08F4/69293NNO C08F4/69301ONN C08F4/6931ONO C08F4/69318ON*O C08F4/69327PNO C08F4/69336SNN C08F4/69344SNO C08F4/69353Dianionic ligand C08F4/69362NN(R)C C08F4/6937NN(R)N C08F4/69379NNO C08F4/69387ON(R)C C08F4/69396ONO C08F4/69405O*O*P C08F4/69413OSO C08F4/69422Tetra- or multi-dentate ligand C08F4/69431Neutral ligand C08F4/69439ONNO C08F4/69448PNNN C08F4/69456Monoanionic ligand C08F4/69465Dianionic ligand C08F4/69474ONNO C08F4/69482OOOO C08F4/69491OSSO C08F4/695Manganese, technetium, rhenium or compounds thereof C08F4/70Iron group metals, platinum group metals or compounds thereof C08F4/7001the metallic compound containing a multidentate ligand C08F4/7003Bidentate ligand C08F4/7004Neutral ligand C08F4/7006NN C08F4/7008NO C08F4/7009NS C08F4/7011OS C08F4/7013PN C08F4/7014PO C08F4/7016PP C08F4/7018PS C08F4/7019Monoanionic ligand C08F4/7021NN C08F4/7022NO C08F4/7024NS C08F4/7026ON C08F4/7027OO C08F4/7029PN C08F4/7031PO C08F4/7032Dianionic ligand C08F4/7034NN C08F4/7036NO C08F4/7037OO C08F4/7039Tridentate ligand C08F4/704Neutral ligand C08F4/7042NNN C08F4/7044NNO C08F4/7045NNS C08F4/7047NSN C08F4/7049PNN C08F4/705PNP C08F4/7052Monoanionic ligand C08F4/7054NNN C08F4/7055NNO C08F4/7057ONN C08F4/7059ONO C08F4/706ON*O C08F4/7062PNO C08F4/7063SNN C08F4/7065SNO C08F4/7067Dianionic ligand C08F4/7068NN(R)C C08F4/707NN(R)N C08F4/7072NNO C08F4/7073ON(R)C C08F4/7075ONO C08F4/7077O*O*P C08F4/7078OSO C08F4/708Tetra- or multi-dentate ligand C08F4/7081Neutral ligand C08F4/7083ONNO C08F4/7085PNNN C08F4/7086Monoanionic ligand C08F4/7088Dianionic ligand C08F4/709ONNO C08F4/7091OOOO C08F4/7093OSSO C08F4/7095Cobalt, nickel or compounds thereof C08F4/7096Cobalt or compounds thereof C08F4/7098Nickel or compounds thereof C08F4/72selected from metals not provided for in group C08F4/44 C08F4/74selected from refractory metals C08F4/76selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum C08F4/78selected from chromium, molybdenum or tungsten C08F4/80selected from iron group metals or platinum group metals C08F4/82Pi-Allyl complexes