Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring

CCHEMISTRY METALLURGY C07Organic chemistry C07CACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring

C07C29/03by addition of hydroxy groups to unsaturated carbon-to-carbon bonds C07C29/04by hydration of carbon-to-carbon double bonds C07C29/05with formation of absorption products in mineral acids and their hydrolysis C07C29/06the acid being sulfuric acid C07C29/08the acid being phosphoric acid C07C29/09by hydrolysis C07C29/095of esters of organic acids C07C29/10of ethers, including cyclic ethers C07C29/103of cyclic ethers C07C29/106of oxiranes C07C29/12of esters of mineral acids C07C29/124of halides C07C29/128by alcoholysis C07C29/1285of esters of organic acids C07C29/132by reduction of an oxygen containing functional group C07C29/136of >C=O containing groups C07C29/14of a -CHO group C07C29/141with hydrogen or hydrogen-containing gases C07C29/143of ketones C07C29/145with hydrogen or hydrogen-containing gases C07C29/147of carboxylic acids or derivatives thereof C07C29/149with hydrogen or hydrogen-containing gases C07C29/15by reduction of oxides of carbon exclusively C07C29/151with hydrogen or hydrogen-containing gases C07C29/1512characterised by reaction conditions C07C29/1514the solvents being characteristic C07C29/1516Multisteps C07C29/1518one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis C07C29/152characterised by the reactor used C07C29/153characterised by the catalyst used C07C29/154containing copper, silver, gold, or compounds thereof C07C29/156containing iron group metals, platinum group metals or compounds thereof C07C29/157containing platinum group metals or compounds thereof C07C29/158containing rhodium or compounds thereof C07C29/159with reducing agents other than hydrogen or hydrogen-containing gases C07C29/16by oxo-reaction combined with reduction C07C29/17by hydrogenation of carbon-to-carbon double or triple bonds C07C29/172with the obtention of a fully saturated alcohol C07C29/175with simultaneous reduction of an oxo group C07C29/177with simultaneous reduction of a carboxy group C07C29/19in six-membered aromatic rings C07C29/20in a non-condensed ring substituted with hydroxy groups C07C29/32increasing the number of carbon atoms by reactions without formation of -OH groups C07C29/34by condensation involving hydroxy groups or the mineral ester groups derived therefrom C07C29/36increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy C07C29/38by reaction with aldehydes or ketones C07C29/40with compounds containing carbon-to-metal bonds C07C29/42with compounds containing triple carbon-to-carbon bonds C07C29/44increasing the number of carbon atoms by addition reactions C07C29/46by diene-synthesis C07C29/48by oxidation reactions with formation of hydroxy groups C07C29/50with molecular oxygen only C07C29/52in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed C07C29/54starting from compounds containing carbon-to-metal bonds and followed by conversion of the -O- metal to -OH groups C07C29/56by isomerisation C07C29/58by elimination of halogen C07C29/60by elimination of -OH groups C07C29/62by introduction of halogen by substitution of halogen atoms by other halogen atoms C07C29/64by simultaneous introduction of -OH groups and halogens C07C29/66by addition of hypohalogenous acids, which may be formed in situ, to carbon-to-carbon unsaturated bonds C07C29/68Preparation of metal alcoholates C07C29/685by converting O-metal groups to other O-metal groups C07C29/70by converting hydroxy groups to O-metal groups C07C29/705by transalcoholysis C07C29/72by oxidation of carbon-to-metal bonds C07C29/74Separation purification use of additives C07C29/76by physical treatment C07C29/78by condensation or crystallisation C07C29/80by distillation C07C29/82by azeotropic distillation C07C29/84by extractive distillation C07C29/86by liquid-liquid treatment C07C29/88by treatment giving rise to a chemical modification of at least one compound C07C29/90using hydrogen only C07C29/92by a consecutive conversion and reconstruction C07C29/94Use of additives