Claims
- 1. Optically active compounds of the formula ##STR26## their optical antipodes and the racemates thereof wherein X and M are selected from the group consisting of keto, ##STR27## W is a single bond or a cis double bond and Z is a single bond or a trans double bond;
- Y is ##STR28## wherein R" is selected from the group consisting of alkanoyl of from two to five carbon atoms, cycloalkanoyl of from four to seven carbon atoms, benzoyl, monosubstituted benzoyl, alkylsulfonyl of from one to four carbon atoms, phenylsulfonyl and monosubstituted phenylsulfonyl wherein the phenyl and benzoyl substituent is selected from the group consisting of fluoro, chloro, bromo, trifluoromethyl, lower alkyl, lower alkoxy and phenyl; and Ar is selected from the group consisting of phenyl, .alpha.-naphthyl, .beta.-naphthyl and monosubstituted phenyl wherein the substituent is selected from the group consisting of fluoro, chloro, bromo, lower alkyl, lower alkoxy, phenyl and trifluoromethyl.
- 2. A compound of claim 1 wherein Ar is phenyl.
- 3. A compound of claim 1 wherein Ar is tolyl.
- 4. A compound of claim 3 wherein Ar is m-tolyl.
- 5. A compound of claim 1 wherein R" is benzoyl.
- 6. A compound of claim 1 wherein R" is methylsulfonyl.
- 7. A compound of claim 1 wherein X is keto.
- 8. A compound of claim 1 wherein W is a cis double bond and Z is a trans double bond.
- 9. A compound of claim 8 wherein Ar is phenyl.
- 10. A compound of claim 8 wherein Ar is tolyl.
- 11. A compound of claim 8 wherein R" is benzoyl.
- 12. A compound of claim 8 wherein R" is methylsulfonyl.
- 13. A compound of claim 9 wherein X is keto, M is keto and R" is methylsulfonyl.
- 14. A compound of claim 10 wherein X is keto, M is keto and R" is methylsulfonyl.
- 15. A compound of claim 9 wherein X is keto, M is ##STR29## and R" is methylsulfonyl.
Parent Case Info
This application is a division of application Ser. No. 589,386, filed June 23, 1975.
Non-Patent Literature Citations (2)
Entry |
derwent, Abstract 75530x/40, U.S. 3981-868, 14-07-71. |
Derwent, Abstract 72921w/20, FR. 2239-458, 31-07-73. |
Divisions (1)
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Number |
Date |
Country |
Parent |
589386 |
Jun 1975 |
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