1,2,3-triazole based metal-organic framework as photo-active materials

Abstract

A TAF compound that can have substitutions on either of the two benzene rings and/or the C-5 position of the triazole to alter the properties of the TAF compound can be

Description

REFERENCE TO SEQUENCE LISTING, A TABLE, OR A COMPUTER PROGRAM LISTING COMPACT DISC APPENDIX

Not Applicable

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

FIG. 1 is a representative structure of the ligand design and modification.

FIG. 2 is the reaction for TAMOF production.

DETAILED DESCRIPTION OF THE INVENTION

A first embodiment can be triazole-modified compound TAF. The TAF compound can have substitutions on either of the two benzene rings and/or the C-5 position of the triazole to alter the properties of the TAF. The TAF compound can be

wherein X can be H, an aromatic group, a hetero aromatic group, an alkyl or any substituted alkyl group, ketone, aldyhyde, carboxylic acid derivatives; Y¹, Y², Y³, Y⁴, and Y⁵ can be one or more of H, aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives; and Z¹, Z², Z³, Z⁴ and Z⁵ can be one or more of H aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives.

TAF can be prepared from bifunctional 1,2,3-triazoles by treatment with Zn(N0₃)₂. About 1-5 mmol of the 1,2,3-triazole solutions wherein the solvents can be water, acetonitrile, DMSO, DMF, DEF, any alcohol, THF. This solution can be added to about 1-5 mmol Zn(N0₃)₂ solutions at a concentration between about 0.1 mmol to about 2 mol wherein the solvents can be water, acetonitrile, DMSO, DMF, DEF, any alcohol, THF. The solutions can be kept at an effective temperature which can range from about room temperature to about 180° C. for an effective time from about 1 hour to about 7 days to prepare TAF.

FIG. 2 details the TAMOF preparation.

The TAF compound can be used as a photoactive material and/or catalyst. The absorption wavelength could be easily adjusted by the substitution of different aryl groups such as F, CN, Cl, OMe, phenyl, or heteroaromatic structures on the TAF compound. The N-aryl triazoles possess unique molecular orbital distributions. This feature makes the preparation of solar-light absorbing linkers for the preparation of metal-organic frameworks feasible. The orbital distribution made triazole one unique compound to express interesting photo and electronic properties. TAF has a band gap around 2.8 eV which is optimal for a photocatalysis as seen in FIG. 1. The HOMO and LUMO were confirmed locating on the triazole ring and H-bonding between C-4-H and CO₂ was revealed with a calculated 17 kcal/mol of binding energy.

These terms and specifications, including the examples, serve to describe the invention by example and not to limit the invention. It is expected that others will perceive differences, which, while differing from the forgoing, do not depart from the scope of the invention herein described and claimed. In particular, any of the function elements described herein may be replaced by any other known element having an equivalent function.

Claims

1. A method comprising preparing a compound of the formula:

2. The method of claim 1 wherein the effective temperature is from about room temperature to about 180° C.

3. The method of claim 1 wherein the effective time is from about 1 hour to about 7 days.

4. The method of claim 2 wherein the effective time is from about 1 hour to about 7 days.

5. The method of claim 1, wherein when Y3 is COOH then Z3 is other than COOH, and wherein Z3 is COOH then Y3 is other than COOH.

6. The method of claim 5 wherein the effective temperature is from about room temperature to about 180° C.

7. The method of claim 5 wherein the effective time is from about 1 hour to about 7 days.

8. The method of claim 6 wherein the effective time is from about 1 hour to about 7 days.

9. The method of claim 5, wherein Y3 is COOH and Z3 is other than COOH.

10. The method of claim 9 wherein the effective temperature is from about room temperature to about 180° C.

11. The method of claim 9 wherein the effective time is from about 1 hour to about 7 days.

12. The method of claim 10 wherein the effective time is from about 1 hour to about 7 days.

13. The method of claim 5, wherein Z3 is COOH and Y3 is other than COOH.

14. The method of claim 13 wherein the effective temperature is from about room temperature to about 180° C.

15. The method of claim 13 wherein the effective time is from about 1 hour to about 7 days.

16. The method of claim 14 wherein the effective time is from about 1 hour to about 7 days.

17. The method of claim 1, wherein X is H, Y1, Y2, Y4, and Y5 are each H, Z1, Z2, Z4 and Z5 are each H, and Y3 and Z3 are each COOH.

18. The method of claim 17 wherein the effective temperature is from about room temperature to about 180° C.

19. The method of claim 17 wherein the effective time is from about 1 hour to about 7 days.

20. The method of claim 18 wherein the effective time is from about 1 hour to about 7 days.