Claims
- 1. A 2 in 1 shampoo composition having improved anti static properties comprising:
- (a) an anionic surfactant selected from the group consisting of ROSO.sub.3 Mt and RO(C.sub.2 H.sub.4 O).sub.z SO.sub.3 Mt wherein R is alkyl or alkenyl of from about 10 to about 20 carbon atoms, z ranges from 1 to about 10, and Mt is a water soluble monovalent cation selected from the group consisting of alkali metal cations, ammonium cation, substituted ammonium cations or triethanolamine cation;
- a nonionic surfactant selected from the group consisting of an alkanolamide and an ethoxylated amides;
- an amphoteric surfactant selected from the group consisting of amine oxides and betaine compounds; used either singly in combination with themselves;
- or a mixture thereof in an amount ranging up to about 14 weight percent;
- (b) a suspending agent selected from the group consisting of the alkanol amides of fatty acids and alkyl dimethyl amine oxides having from about 16 to about 22 carbon atoms, and the cross linked anionic homopolymers or copolymers of vinylsulfonic acid, acrylic or methacrylic acid, acrylic acid, the alkali metal and ammonium salts of acrylic acid, methacrylic acid, the alkali metal and ammonium salts of methacrylic acid, acrylamide, methacrylamide, the N-alkyl substituted amides, the N-aminoalkylamides, the corresponding N-alkylaminoalkyl substituted amides, the aminoalkyl acrylates, the aminoalkyl methacrylamides, and the N-alkyl substituted aminoalkyl esters of either acrylic or methacrylic acids polymerized or copolymerized with monomers selected from the group consisting of ethylene, propylene, isobutylene, styrene, alpha-methylstyrene, vinyl acetate, vinyl formate, alkyl ethers, acrylonitrile, methacrylonitrile, vinyl chloride, vinylidene chloride, alkyl acrylates, alkylmethacrylates, alkyl fumarates, and alkyl maleates at a level of from about 0.2 to about 5.0% by weight;
- (c) a high molecular weight, high viscosity silicone-polyether copolymer of the general formula:
- MD.sub.x D'.sub.y M
- wherein;
- M is an endcapping unit of the formula R.sup.4.sub.3 SiO.sub.1/2, wherein each R.sup.4 is the same or different and independently represents hydrogen or a monovalent substituted or unsubstituted hydrocarbon radical of from 1 to 30 carbon atoms;
- D represents a difunctional siloxy unit of the formula R.sup.4.sub.2 SiO.sub.2/2 wherein each R.sup.4 is as defined above; and D' represents a difunctional siloxy of the formula R.sup.4 R.sup.5 SiO.sub.2/2 wherein;
- R.sup.4 is as defined above, and
- R.sup.5 is a polyalkylene ether of the formula R.sup.6.sub.a --(OR.sup.7).sub.n --OR.sup.8 where
- R.sup.6 is a substituted or unsubstituted alkylene group of from 1 to about 20 carbon atoms,
- R.sup.7 is selected from the group consisting of --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH(CH.sub.3)--, and --CH.sub.2 C(CH.sub.3).sub.2 --;
- R.sup.8 is a hydrogen atom, hydroxyl or hydrocarbon radical selected from the group consisting of ethyl, propyl, butyl, phenyl, alkenyl, and acetyl;
- n has a value of from about 5 to about 20, and a is 0 or 1; and x is above about 1 and y is above about 1 and the molecular weight of the silicone ether copolymer ranges from about 30,000 to about 150,000 on a weight average basis in an amount ranging from about 4 to about 44.5 weight percent;
- (d) a quaternary ammonium compound selected from the group consisting of distearyldimethylammonium chloride, dicetyldimethylammonium bromide, dimethyldi(hydrogenated tallow)ammonium chloride, dibehenyl dimonium sulfate, hydroxypropyl bis-stearyl-ammonium chloride, tricetyl methyl ammonium chloride, tri-C.sub.8-10 methyl ammonium chloride, tri(isodecyl)amine, tri-C.sub.13 amine, and quaternary imidazolinium chlorides in an amount ranging from about 0.75 to about 1.40 weight percent; and
- (e) water in an amount ranging from about 20 to about 95 weight percent.
- 2. A shampoo composition as defined in claim 1 wherein said surfactant comprises an anionic surfactant.
- 3. A shampoo composition as defined in claim 2 wherein said anionic surfactant (a) is selected from the group consisting of alkyl sulfates, ethoxylated alkyl sulfates, olefin sulfates, succinamates and beta-alkyloxyalkane sulfonates.
- 4. A shampoo composition as defined in claim 1 wherein said suspending agent (b) comprises a cross-linked acrylic polymer.
- 5. A shampoo composition as defined in claim 4 wherein said cross-linked acrylic polymer comprises a polyacrylic acid or a metal salt of a polyacrylic acid.
- 6. A shampoo composition as defined in claim 1 wherein said high molecular, weight high viscosity silicone-polyether copolymer (c) has a weight average molecular weight of greater than about 30,000.
- 7. A shampoo composition as defined in claim 1 wherein said high molecular, weight high viscosity silicone-polyether copolymer (c) comprises those having the general formula:
- MD.sub.x D'.sub.y M
- wherein M represents trialkylsiloxy endcapping units of the general formula R.sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms;
- D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above;
- D' is an oxyalkylene siloxy unit of the general formula R.sup.4 R.sup.5 SiO.sub.2/2 where R.sup.4 is as defined above, and R.sup.5 is a polyoxyalkylene ether residue of the formula --(R.sup.6).sub.a --(OR.sup.7).sub.n --OR.sup.8 wherein each individual R.sup.6 is a substituted or unsubstituted alkylene radical having from 2 to 20 carbon atoms, R.sup.7 is --CH.sub.2 CH.sub.2 --, R.sup.8 is a hydrogen atom, hydroxy, or a hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value of from about 5 to about 20, and a has a value of zero or 1;
- x is above about 1; and
- y is above about 1, said high molecular weight high viscosity silicone-polyether copolymer having a weight average molecular weight greater than about 30,000.
- 8. A shampoo composition as defined in claim 7 wherein the ratio of x:y ranges from 3:2 to 4:1.
- 9. A shampoo composition as defined in claim 7 wherein each R.sup.4 represents methyl.
- 10. A shampoo composition as defined in claim 1 wherein said component (c) comprises said high molecular weight, high viscosity silicone-polyether copolymer in combination with a fatty alcohol.
- 11. A shampoo composition as defined in claim 10 wherein said fatty alcohol comprises stearyl alcohol or cetyl alcohol or a mixture thereof.
- 12. A composition as defined in claim 1 wherein said quaternary compound (d) comprises a quaternary imidazolinium compound.
- 13. A shampoo composition as defined in claim 12 wherein said quaternary imidazolinium compound comprises methyl-1-tallow amido ethyl-2-tallow imidazolinium methyl sulfate.
- 14. A hair conditioning composition comprising the 2 in 1 shampoo composition as defined in claim 1 wherein said high molecular weight, high viscosity silicone-polyether copolymer comprises those having the general formula
- MD.sub.x D'.sub.y M
- wherein
- M represents trialkylsiloxy endcapping units of the general formula R.sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms;
- D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above;
- D' is an oxyalkylene siloxy unit of the general formula R.sup.4 R.sup.5 SiO.sub.2/2 where R.sup.4 is as defined above, and R.sup.5 is a polyoxyalkylene ether residue of the formula --(R.sup.6).sub.a --(OR.sup.7).sub.n --OR.sup.8 wherein each individual R.sup.6 is a substituted or unsubstituted alkylene radical having from 2 to 20 carbon atoms, R.sup.7 is --CH.sub.2 CH.sub.2 --, R.sup.8 is a hydrogen atom, hydroxy, or a hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value of from about 5 to about 20, and a has a value of zero or 1; and x and y are each above 1 and provide a copolymer having a weight average molecular weight of greater than about 30,000, and where the ratio of x:y varies from about 1:1 to about 20:1, said high molecular weight high viscosity silicone-polyether copolymer having a weight average molecular weight greater than about 50,000.
- 15. A hair conditioning composition as defined in claim 14 wherein each R.sup.4 represents methyl.
- 16. A hair conditioning composition as defined in claim 14 wherein said high molecular weight, high viscosity silicone-polyether copolymer is employed in combination with a fatty alcohol.
- 17. A hair conditioning composition as defined in claim 14 wherein said quaternary compound comprises a quaternary imidazolinium compound.
- 18. A 2 in 1 shampoo composition having improved anti static properties consisting essentially of:
- (a) an anionic surfactant, a nonionic surfactant, an amphoteric surfactant, or a mixture thereof;
- (b) a suspending agent;
- (c) a high molecular weight, high viscosity silicone-polyether copolymer having the general formula
- MD.sub.x D'.sub.y M
- wherein
- M represents trialkylsiloxy endcapping units of the general formula R.sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms;
- D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above;
- D' is an oxyalkylene siloxy unit of the general formula R.sup.4 R.sup.5 SiO.sub.2/2 where R.sup.4 is as defined above, and R.sup.5 is a polyoxyalkylene ether residue of the formula --(R.sup.6).sub.a --(OR.sup.7).sub.n --OR.sup.8 wherein each individual R.sup.6 is a substituted or unsubstituted alkylene radical having from 2 to 20 carbon atoms, R.sup.7 is --CH.sub.2 CH.sub.2 --, R.sup.8 is a hydrogen atom, hydroxy, or a hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value of from about 5 to about 20, and a has a value of zero or 1; and x and y are each above 1 and provide a copolymer having a weight average molecular weight of greater than about 30,000, and where the ratio of x:y varies from about 1:1 to about 20:1, said high molecular weight high viscosity silicone-polyether copolymer having a weight average molecular weight greater than about 50,000.
- 19. An improved 2 in 1 shampoo composition comprising a surfactant, a suspending agent, a quaternary compound and water, the improvement comprising an effective amount of a high molecular weight silicone ether copolymer having the general formula
- MD.sub.x D'.sub.y M
- wherein
- M represents trialkylsiloxy endcapping units of the general formula R.sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms;
- D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above;
- D' is an oxyalkylene siloxy unit of the general formula R.sup.4 R.sup.5 SiO.sub.2/2 where R.sup.4 is as defined above, and R.sup.5 is a polyoxyalkylene ether residue of the formula --(R.sup.6).sub.a --(OR.sup.7).sub.n --OR.sup.8 wherein each individual R.sup.6 is a substituted or unsubstituted alkylene radical having from 2 to 20 carbon atoms, R.sup.7 is --CH.sub.2 CH.sub.2 --, R.sup.8 is a hydrogen atom, hydroxy, or a hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value of from about 5 to about 20, and a has a value of zero or 1; and x and y are each above 1 and provide a copolymer having a weight average molecular weight of greater than about 30,000, and where the ratio of x:y varies from about 1:1 to about 20:1, said high molecular weight high viscosity silicone-polyether copolymer having a weight average molecular weight greater than about 50,000, in combination with a fatty alcohol, whereby the anti static properties of the shampoo composition are improved.
- 20. A process for making a 2 in 1 shampoo composition having improved anti static properties comprising:
- (a) removing water from a terminally unsaturated polyalkylene glycol polyether;
- (b) removing water from a hydride fluid, MD.sub.400 D'.sub.18 M, wherein M represents trialkylsiloxy endcapping units of the general formula .sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms; D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above;
- (c) reacting said polyether with said hydride in the presence of a platinum catalyst to produce a high molecular weight, high viscosity silicone-polyether copolymer having the general formula:
- MD.sub.x D'.sub.y M
- wherein M represents trialkylsiloxy endcapping units of the general formula R.sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms; D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above; D' is an oxyalkylene siloxy unit of the general formula R.sup.4 R.sup.5 SiO.sub.2/2 where R.sup.4 is as defined above, and R.sup.5 is a polyoxyalkylene ether residue of the formula --(R.sup.6).sub.a --(OR.sup.7).sub.n --OR.sup.8 wherein each individual R.sup.6 is a substituted or unsubstituted alkylene radical having from 2 to 20 carbon atoms, R.sup.7 is --CH.sub.2 CH.sub.2 --, R.sup.8 is a hydrogen atom, hydroxy, or a hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value of from about 5 to about 20, and a has a value of zero or 1; and x and y are each above 1 and provide a copolymer having a weight average molecular weight of greater than about 50,000, and where the ratio of x:y varies from about 1:1 to about 20:1
- (d) adding a fatty alcohol to the high molecular weight, high viscosity silicone-polyether copolymer produced in step (c);
- (e) adding a quaternary compound selected from the group consisting of distearyldimethylammonium chloride, dicetyldimethyl ammonium bromide, dimethyldi(hydrogenated tallow) ammonium chloride, dibehenyl dimonium sulfate, hydroxypropyl bis-stearyl-ammonium chloride, tricetylmethylammonium chloride, tri(isodecyl)amine, and methyl-1-tallow amido ethyl imidazolinium;
- (f) adding an anionic surfactant, a nonionic surfactant, an amphoteric surfactant or a mixture thereof; and
- (g) adding water
- 21. A process for making a 2 in 1 shampoo composition having improved anti static properties comprising:
- (a) removing water from a terminally unsaturated polyalkylene glycol polyether;
- (b) removing water from a hydride fluid, MD.sub.400 D'.sub.18 M, wherein M represents trialkylsiloxy endcapping units of the general formula .sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms; D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above;
- (c) reacting said polyether with said hydride in the presence of a platinum catalyst to produce a high molecular weight, high viscosity silicone-polyether copolymer having the general formula:
- MD.sub.x D'.sub.y M
- wherein M represents trialkylsiloxy endcapping units of the general formula R.sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms; D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above; D' is an oxyalkylene siloxy unit of the general formula R.sup.4 R.sup.5 SiO.sub.2/2 where R.sup.4 is as defined above, and R.sup.5 is a polyoxyalkylene ether residue of the formula --(R.sup.6).sub.a --(OR.sup.7).sub.n --OR.sup.8 wherein each individual R.sup.6 is a substituted or unsubstituted alkylene radical having from 2 to 20 carbon atoms, R.sup.7 is --CH.sub.2 CH.sub.2 --, R.sup.8 is a hydrogen atom, hydroxy, or a hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value of from about 5 to about 20, and a has a value of zero or 1; and x and y are each above 1 and provide a copolymer having a weight average molecular weight of greater than about 50,000, and where the ratio of x:y varies from about 1:1 to about 20:1
- (d) contacting a quaternary compound selected from the group consisting of distearyldimethylammonium chloride, dicetyldimethyl ammonium bromide, dimethyldi(hydrogenated tallow) ammonium chloride, dibehenyl dimonium sulfate, hydroxypropyl bis-stearyl-ammonium chloride, tricetylmethylammonium chloride, tri(isodecyl)amine, and methyl-1-tallow amido ethyl imidazolinium with a fatty alcohol;
- (e) adding the product from step (d) to the high molecular weight, high viscosity silicone-polyether copolymer produced in step (c);
- (f) adding an anionic surfactant, a nonionic surfactant, an amphoteric surfactant or a mixture thereof; and
- (g) adding water.
- 22. A shampoo composition as made by the process of claim 21 wherein said surfactant comprises an anionic surfactant.
- 23. A shampoo composition as made by the process of defined in claim 21 wherein said anionic surfactant (a) is selected from the group consisting of alkyl sulfates, ethoxylated alkyl sulfates, olefin sulfates, succinamates and beta-alkyloxyalkane sulfonates.
- 24. A shampoo composition as made by the process of claim 21 wherein said suspending agent (b) comprises a cross-linked acrylic resin.
- 25. A shampoo composition as made by the process of claim 21 wherein said cross-linked acrylic resin comprises a polyacrylic acid or a metal salt of a polyacrylic acid.
- 26. A shampoo composition as made by the process of claim 21 wherein said high molecular, weight high viscosity silicone-polyether copolymer (c) has a weight average molecular weight of greater than about 50,000.
- 27. A shampoo composition as made by the process of claim 21 wherein said high molecular weight, high viscosity silicone-polyether copolymer (c) comprises those having the general formula
- MD.sub.x D'.sub.y M
- wherein
- M represents trialkylsiloxy endcapping units of the general formula R.sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms;
- D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above;
- D' is an oxyalkylene siloxy unit of the general formula R.sup.4 R.sup.5 SiO.sub.2/2 where R.sup.4 is as defined above, and R.sup.5 is a polyoxyalkylene ether residue of the formula --(R.sup.6).sub.a --(OR.sup.7).sub.n --OR.sup.8 wherein each individual R.sup.6 is a substituted or unsubstituted alkylene radical having from 2 to 20 carbon atoms, R.sup.7 is --CH.sub.2 CH.sub.2 --, R.sup.8 is a hydrogen atom, hydroxy, or a hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value of from about 5 to about 20, and a has a value of zero or 1;
- x is above about 1; and
- y is above about 1, said high molecular weight high viscosity silicone-polyether copolymer having a weight average molecular weight greater than about 30,000.
- 28. A shampoo composition as defined in claim 27 wherein the ratio of x:y ranges from 3:2 to 4:1.
- 29. A shampoo composition as defined in claim 27 wherein each R.sup.4 represents methyl.
- 30. A shampoo composition as defined in claim 27 wherein said component (c) comprises said high molecular weight, high viscosity silicone-polyether copolymer in combination with a fatty alcohol.
- 31. A shampoo composition as defined in claim 30 wherein said fatty alcohol comprises stearyl alcohol or cetyl alcohol or a mixture thereof.
- 32. A composition as defined in claim 30 wherein said quaternary compound (d) comprises a quaternary imidazolinium compound.
- 33. A shampoo composition as defined in claim 32 wherein said quaternary imidazolinium compound comprises methyl-1-tallow amido ethyl-2-tallow imidazolinium methyl sulfate.
- 34. A hair conditioning composition comprising the 2 in 1 shampoo composition as defined in claim 1 wherein said high molecular weight, high viscosity silicone-polyether copolymer comprises those having the general formula
- MD.sub.x D'.sub.y M
- wherein
- M represents trialkylsiloxy endcapping units of the general formula R.sup.4.sub.3 SiO.sub.1/2 where each R.sup.4 is the same or different and is independently an alkyl group of from 1 to 30 carbon atoms;
- D represents dialkylsiloxy units of the general formula R.sup.4.sub.2 SiO.sub.2/2 where each R.sup.4 is the same or different and is independently as defined above;
- D' is an oxyalkylene siloxy unit of the general formula R.sup.4 R.sup.5 SiO.sub.2/2 where R.sup.4 is as defined above, and R.sup.5 is a polyoxyalkylene ether residue of the formula --(R.sup.6).sub.a --(OR.sup.7).sub.n --OR.sup.8 wherein each individual R.sup.6 is a substituted or unsubstituted alkylene radical having from 2 to 20 carbon atoms, R.sup.7 is --CH.sub.2 CH.sub.2 --, R.sup.8 is a hydrogen atom, hydroxy, or a hydrocarbon radical of from 1 to about 12 carbon atoms, n has a value of from about 5 to about 20, and a has a value of zero or 1; and x and y are each above 1 and provide a copolymer having a weight average molecular weight of greater than about 30,000 and where the ratio of x:y varies from about 1:1 to about 20:1, said high molecular weight high viscosity silicone-polyether copolymer having a weight average molecular weight greater than about 30,000.
- 35. A hair conditioning composition as defined in claim 34 wherein each R.sup.4 represents methyl.
- 36. A hair conditioning composition as defined in claim 34 wherein said high molecular weight, high viscosity silicone-polyether copolymer is employed in combination with a fatty alcohol.
- 37. A hair conditioning composition as defined in claim 34 wherein said quaternary compound comprises a quaternary imidazolinium compound.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of U.S. Ser. No. 07/974,020, filed Nov. 9, 1992, now abandoned.
US Referenced Citations (23)
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
974020 |
Nov 1992 |
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