Patent Application
20220134651
Additive manufacturing systems produce three-dimensional (3D) objects by building up layers of material. Some additive manufacturing systems are referred to as “3D printing devices” because they use inkjet or other printing technology to apply some of the manufacturing materials. 3D printing devices and other additive manufacturing devices make it possible to convert a computer-aided design (CAD) model or other digital representation of an object directly into the physical object.
The accompanying drawings illustrate various examples of the principles described herein and are part of the specification. The illustrated examples are given merely for illustration, and do not limit the scope of the claims.
Throughout the drawings, identical reference numbers designate similar, but not necessarily identical, elements. The figures are not necessarily to scale, and the size of some parts may be exaggerated to more clearly illustrate the example shown. Moreover, the drawings provide examples and/or implementations consistent with the description; however, the description is not limited to the examples and/or implementations provided in the drawings.
Additive manufacturing systems form a three-dimensional (3D) object through the solidification of layers of a build material. Additive manufacturing systems make objects based on data in a 3D model of the object generated, for example, with a computer-aided drafting (CAD) computer program product. The model data is processed into slices, each slice defining portions of a layer of build material that is to be solidified.
In one example, to form the 3D object, a build material, which may be powder, is deposited on a bed. A fusing agent is then dispensed onto portions of the layer of build material that are to be fused to form a layer of the 3D object. The system that carries out this type of additive manufacturing may be referred to as a powder and fusing agent-based system. The fusing agent disposed in the desired pattern increases the energy absorption of the layer of build material on which the agent is disposed. The build material is then exposed to energy such as electromagnetic radiation. The electromagnetic radiation may include infrared light, laser light, or other suitable electromagnetic radiation. Due to the increased heat absorption properties imparted by the fusing agent, those portions of the build material that have the fusing agent disposed thereon heat to a temperature greater than the fusing temperature for the build material.
Accordingly, as energy is applied to a surface of the build material, the build material that has received the fusing agent, and therefore has increased energy absorption characteristics, fuses while that portion of the build material that has not received the fusing agent remains in powder form. Those portions of the build material that receive the agent and thus have increased heat absorption properties may be referred to as fused portions. By comparison, the applied heat is not so great so as to increase the heat of the portions of the build material that are free of the agent to this fusing temperature. Those portions of the build material that do not receive the agent and thus do not have increased heat absorption properties may be referred to as unfused portions.
Accordingly, a predetermined amount of heat is applied to an entire bed of build material, the portions of the build material that receive the fusing agent, due to the increased heat absorption properties imparted by the fusing agent, fuse and form the object while the unfused portions of the build material are unaffected, i.e., not fused, in the presence of such application of thermal energy. This process is repeated in a layer-wise fashion to generate a 3D object. The unfused portions of material can then be separated from the fused portions, and the unfused portions recycled for subsequent 3D formation operations.
Another way of 3D formation selectively applies binder to areas of loose build material. In this example, a “latent” part is prepared inside a build bed filled with build material. The build bed may be transferred to a furnace where a first heating step removes solvents present in the applied binder. As solvents are removed, the remaining binder hardens and glues together build material to convert the “latent” part into a “green” part. The green part is then removed from the bed. As a result of this operation, residual build material may be caked onto the green parts. It may be desirable to remove residual build material from green parts in a cleaning step. In some examples, the green parts are loaded into a sintering furnace where applied heat can cause binder decomposition and causes the build material powder particles to sinter or fuse together into a durable solid form.
In yet another example, a laser, or other power source is selectively aimed at a powder build material, or a layer of a powder build material, to form a slice of a 3D printed part. Such a process may be referred to as selective laser sintering. In yet another example, the additive manufacturing process may use selective laser melting where portions of the powder material, which may be metallic, are selectively melted together to form a slice of a 3D printed part. As yet another example, in fused deposition modeling melted build material is selectively deposited in a layer where it cools. As it cools it fuses together and adheres to a previous layer. This process is repeated to construct a 3D printed part.
In yet another example, the additive manufacturing process may involve using a light source to cure a liquid resin into a hard substance. Such an operation may be referred to as stereolithography. While such additive manufacturing operations have greatly expanded manufacturing and development possibilities, further development may make 3D printing a part of even more industries. Accordingly, a device which carries out any of these additive manufacturing processes may be referred to as an additive manufacturing device and in some cases a printer.
For example, the present specification describes a system and method to sequester a payload, such as unfused powder build material, inside shells of fused build material. This type of nodule can be thought of as an egg shell with powder trapped inside. Accordingly, upon rupture, or the application of a rupturing physical force, the payload of the shell is released. The payload may be of a variety of types. For example, the payload may be raw build material, doped build material, or even another material such as a liquid. In one particular example, the doped build material is a non-metallic build material doped with colorants. In yet another example, the payload may be a hardware structure such as a physical device such as a circuit board or other piece of electronic hardware. The container structure, or a portion thereof, may be pre-formed and placed during the additive manufacturing process. In some examples, the payload may be deposited at the time of formation of the container structure, during additive manufacturing, or in some cases after additive manufacturing. The payload inside a container structure, after the additive manufacturing process, is released when certain conditions occur.
As one particular example, colored or uncolored, unfused powder build material is enclosed in multiple container structures arranged in a planar matrix configuration as a small floormat. Upon application of pressure, for example by a foot stepping on the mat, container structures experiencing levels of pressure exceeding a designed threshold rupture, thus releasing the encapsulated unfused build material. This causes a visible change in the appearance of the mat in areas experiencing higher levels of applied pressure. The result is a visibly readable map of pressures over the bottom of a person's foot, when the individual is standing. While specific reference is made to a particular application, a large range of applications are enabled by the controlled release of the payload of a container structure, including, but not limited to: embedding information in parts, security, self-healing components, and a wide variety of sensors.
The present specification describes the placement of at least a portion of a container structure in a 3D printed object. In some examples, the container structure is embedded within a body of the 3D printed object and in other examples may be embedded on a surface of the 3D printed structure.
Specifically, the present specification describes an additive manufacturing system. The system includes an additive manufacturing device to form a three-dimensional (3D) printed object. The additive manufacturing system also includes a placement device to place at least a portion of a container structure in the 3D printed object. The container structure expels a payload when a predetermined condition is met. The additive manufacturing system also includes a controller to control additive manufacturing and placement of the container structure.
The present specification also describes a method. According to the method, slices of a 3D printed object are sequentially formed. In this example, the formation is interrupted to place a container structure in the 3D printed object. The container structure expels a payload when predetermined conditions are met. Forming of slices of the 3D printed object is resumed to embed the container structure in the 3D printed object.
In another example, the additive manufacturing system includes a build material distributor to deposit layers of powdered build material onto a bed and an agent distributor. The agent distributor forms a 3D printed object by depositing at least one agent onto a layer of powdered build material. A placement device places a container and a rupture device into the 3D printed object. The container and rupture device form a container structure. The additive manufacturing system also includes a controller to interrupt additive manufacturing for placement of the container structure and to resume additive manufacturing following placement of the container structure.
Such systems and methods 1) provide for a delayed release of a payload from a 3D printed object; 2) provide specific placement of the container structures forming a part of the 3D printed object; and 3) facilitate customization of the conditions that lead to structure rupture. However, it is contemplated that the systems and methods disclosed herein may address other matters and deficiencies in a number of technical areas.
Turning now to the figures,
The additive manufacturing system (100) also includes a placement device (104) to place at least a portion of a container structure into a body of the 3D printed object. That is, inside or on the surface of a 3D printed object, there may be formed another object, specifically, a container structure that may be a hollow structure filled with a payload. In some examples, the container structure may be enclosed within the 3D printed object. In others, the container structure may be on a surface of the 3D printed object. In other words, the container structure may form any part of the 3D printed object. The container structure is to expel a payload when a predetermined condition is met. The predetermined condition may be of a variety of types. For example, the predetermined condition may be a pressure condition, an electrical condition, or a temperature condition. In some examples, the predetermined condition may be met following additive manufacturing. However, in other examples, the predetermined condition may be met during additive manufacturing.
As a specific example, the container structure may expel the payload when a certain pressure is exerted on the container structure. For example, when a user's foot is placed on a mat, the pressure of the user's foot may cause the container structure to rupture, thereby expelling its contents. In some examples, the predetermined conditions may cause the container structure to rupture. For example, a rupture device may pierce a container causing the container to rupture. In other examples, the container structure may remain intact while expelling.
As a specific example, a container structure may have a lattice structure that traps something inside, for example physical particles having a dimension slightly greater than the openings in the lattice. Accordingly, when pressure is applied, the lattice deforms such that some of those holes will get bigger if the cage is stretched (or compressed) in an appropriate dimension. Enlarging a hole in the containing cage would allow (at least some of) the payload to escape. This occurs by distorting the cage, but not rupturing it. After release, the cage may optionally be restored to original conditions. Accordingly, in this example, a payload is released without rupturing the container structure. Thus, the formed container structure may be re-used to expel a payload multiple times. Accordingly, in this example, the additive manufacturing device (102) forms a container structure to expel contents, but not rupture.
In other examples, the predetermined condition is an electrical condition. For example, when a voltage of a predetermined value is applied to the container structure it ruptures. In yet another example, the predetermined condition may be a temperature condition. For example, the container structure may include a bi-metal strip embedded in the container structure such that when heat is applied, the different metals of the bi-metal strip expand differently, changing the shape of the bi-metal strip, thus causing a rupture in the container structure.
The payload may be of a variety of types. For example, the payload may include raw build material or doped build material. In another example, the payload may be a colored build material. In yet another example, the payload may be a liquid including, but not limited to an aroma and/or therapeutic compounds. In other examples, the payload may alter the characteristics of the surrounding material. For example, the payload may be a compound that heals a part or changes a stiffness of the surrounding material. For example, the payload may be an adhesive. In one particular example, the adhesive may be a 2-part epoxy-style resin-catalyst with each component stored in a different sub-chamber of the container structure. As the sub-chambers are ruptured, the resin and catalyst mix and harden. In either case, i.e., a one part adhesive that reacts upon contact with air or a two-part epoxy mixture, on release these components may affect part stiffness and/or may staunch an expanding crack.
As yet another example, the payload may be a physical structure such as an electronic circuit component. While specific reference is made to particular payloads, the container structure may hold different types of payloads of a variety of types.
In some examples, the placement device (104) places less than all of the container structure, with other components being printed by the additive manufacturing device (102). For example, in some examples, the placement device (104) just places a container of the container structure, and the additive manufacturing device (102) prints other components of the container structure, such as a rupture device, payload receptacle, spring device, and a travel-limiting collar.
In one example, the placement device (104) may include a suction cup. A suction device applies suction to the suction cup to retrieve the container structure. In this example, the suction cup is moved via a gantry over the 3D printed object and removes suction such that the container structure is placed in the 3D printed object.
The system (100) also includes a controller (106) to control the additive manufacturing and placement of the container structure. That is, the controller (106) instructs the additive manufacturing device (102) to form the 3D printed object, instructs the placement device (104) to place the container structure, and in some cases pauses additive manufacturing such that the container structure may be placed.
Specifically, during operation, the controller (106) may serve to provide instructions to a number of other devices associated with the additive manufacturing system (100) to accomplish the functionality of the additive manufacturing system (100). Specifically, in a fusing agent-based system, the controller (106) may direct the build material distributor to add a layer of build material. Further, the controller (106) may send instructions to direct the printhead to selectively deposit the agent onto the surface of a layer of the build material. The controller (106) may also direct the printhead to eject the agent at specific locations to form a 3D printed object slice.
In one particular example, the controller (106) may interrupt formation of the 3D printed object to place a container structure. In this example, the controller (106) interrupts formation to facilitate such a placement. In some examples, interrupting the additive manufacturing process includes deactivating the build material distributor and any build material hardening device. In the example where the build material distributor and agent distributor are placed on scanning carriage(s), the controller (106) also moves these scanning carriage(s) away from the component such that an object may be placed.
After the operation that is to be carried out during the pause is complete, the controller (106) resumes additive manufacturing. That is, the controller (106) selectively re-activates the build material distributor and a hardening device to continue the operation of sequentially operating to form slices of a 3D printed object.
Upon resumption, the additive manufacturing device (102), can be tuned to allow for a print resumption following placement of the container structure. For example, the controller (106) may alter the fusing agent distribution to ensure a proper adhesion of a portion of the 3D printed object formed before placement of the container structure, and the portion of the 3D printed object formed after placement of the container structure.
As another example, the container structure may not be flush with the most recently deposited layer. The controller (106) may control additive manufacturing to trigger deposition of at least one layer of powdered build material, and in some cases more, such that a surface of the powdered build material is flush with a protruding structure. In another example, the controller (106) may trigger deposition of a layer of powdered build material having an increased thickness such that the powdered build material is flush with a protruding component.
Accordingly, the present specification describes a system (100) wherein a container structure is integrated as part of, either embedded in or simply formed on a surface of, a 3D printed object and that expels a payload therein when a certain predetermined condition is met. In some examples, the release of the payload may result in an optical effect. For example, the payload may be a colored liquid/powder thus providing an indication of which container structures have been ruptured. Such may be the case as described above in a 3D pressure-sensitive floormat where a colored liquid/powder provides an indication of which container structures have been ruptured thus resulting in a pressure map of the foot. In some examples, what happens when a payload is released may be a non-optical effect. For example, the payload may change a conductivity in an electrical circuit element or deliver an aroma to a nearby user.
In one specific example, such a 3D printed object may be used to encode information. The ability to encode information is a part of a security solution. The present additive manufacturing system (100) allows a 3D printed object to carry encoded information in a manner that is encrypted and/or tamper evident. For example, in this case, the placement device (104) may embed container structures with different dopings of payload materials. In a particular example, different container structures may carry payloads doped with cyan, magenta, yellow, or black pigment particles. Accordingly, there are four unique payloads, so each container structure may encode two bits of information. In a particular example of securely encoding information, if an opaque build material such as fused polyamide 12 (PA12) surrounds the payload, there may not be a simple way to detect the different doping of materials inside. Accordingly, if validation is necessary, the container structures are ruptured and contents examined to see if they match an expected pattern. Accordingly, the present container structure layout may be used to impart a hidden, but readable, serial number, or other information, inside a part.
As yet another example conductive or magnetic compounds may be included in the payload. By encapsulating conductive, or magnetic compounds in the container structure, the container structures could be detected by non-optical means. In such an example, a ruptured container structure may have a different signal profile than a non-ruptured container structure, thereby providing a means to read information encoded in ruptured vs. non-ruptured container structures.
The controller (106) may include various hardware components, which may include a processor and memory. The processor may include the hardware architecture to retrieve executable code from the memory and execute the executable code. As specific examples, the controller as described herein may include computer readable storage medium, computer readable storage medium and a processor, an application specific integrated circuit (ASIC), a semiconductor-based microprocessor, a central processing unit (CPU), and a field-programmable gate array (FPGA), and/or other hardware device.
The memory may include a computer-readable storage medium, which computer-readable storage medium may contain, or store computer usable program code for use by or in connection with an instruction execution system, apparatus, or device. The memory may take many types of memory including volatile and non-volatile memory. For example, the memory may include Random Access Memory (RAM), Read Only Memory (ROM), optical memory disks, and magnetic disks, among others. The executable code may, when executed by the controller (106) cause the controller (106) to implement at least the functionality of interrupting printing and resuming printing as described below.
In an example of an additive manufacturing process, a layer of build material may be formed in a build area (210). As used in the present specification and in the appended claims, the term “build area” refers to an area of space wherein the 3D printed object (216) is formed. The build area (210) may refer to a space bounded by a bed (208). The build area (210) may be defined as a three-dimensional space in which the additive manufacturing system (100) can fabricate, produce, or otherwise generate a 3D printed object. That is, the build area (210) may occupy a three-dimensional space on top of the bed (208) surface. In one example, the width and length of the build area (210) can be the width and the length of bed (208) and the height of the build area (210) can be the extent to which bed (208) can be moved in the z direction. Although not shown, an actuator, such as a piston, can control the vertical position of bed (208).
The bed (208) may accommodate any number of layers of build material. For example, the bed (208) may accommodate up to 4,000 layers or more. In an example, a number of build material supply receptacles may be positioned alongside the bed (208). Such build material supply receptacles source the build material that is placed on the bed (208) in a layer-wise fashion.
In
In the additive manufacturing process, any number of functional agents may be deposited on the layer of build material. One such example is a fusing agent that facilitates the hardening of the powder build material. In this specific example, the fusing agent may be selectively distributed on the layer of build material in a pattern of a layer of a three-dimensional object. An energy source may temporarily apply energy to the layer of build material. The energy can be absorbed selectively into patterned areas formed by the fusing agent, while blank areas that have no fusing agent absorb less applied energy. This leads to selected zones of a layer of build material selectively fusing together. This process is then repeated, for multiple layers, until a complete physical object has been formed. Accordingly, as used herein, a build layer may refer to a layer of build material formed in a build area (210) upon which the functional agent may be distributed and/or energy may be applied.
Additional layers may be formed and the operations described above may be performed for each layer to thereby generate a three-dimensional printed object (216). Sequentially layering and fusing portions of layers of build material on top of previous layers may facilitate generation of the three-dimensional object (216). The layer-by-layer formation of a three-dimensional object (216) may be referred to as a layer-wise additive manufacturing process.
In another example, a binding agent is selectively deposited on to particular areas of the build material to adhere select areas of the build material together. This is again done in a layer-wise fashion. After all layers of the 3D printed object (216) have been formed, and solvents in the binding agent removed, a “green” part, defined by regions where binding agent is holding together build material, is passed to a sintering furnace to sinter build material particles together.
In one example, the additive manufacturing system (100) includes a build material distributor (214) to successively deposit layers of the build material in the build area (210). Each layer of the build material that is fused in the bed forms a slice of the 3D printed object (216) such that multiple layers of fused build material form the entire 3D printed object (216). The build material distributor (214) may acquire build material from build material supply receptacles, and deposit such acquired material as a layer in the bed (208), which layer may be deposited on top of other layers of build material already processed that reside in the bed (208).
In some examples, the build material distributor (214) may be coupled to a scanning carriage. In operation, the build material distributor (214) places build material in the build area (210) as the scanning carriage moves over the build area (210) along the scanning axis. While
The additive manufacturing system (100) includes an agent distributor (212) to form the 3D printed object (216) and in some examples, portions of the container structure. The agent distributor (212) does so by depositing at least one agent onto a layer of powdered build material.
In some examples, an agent distributor (212) includes at least one liquid ejection device to distribute a functional agent onto the layers of build material. A liquid ejection device may include at least one printhead (e.g., a thermal ejection based printhead, a piezoelectric ejection based printhead, etc.). In some examples, the agent distributor (212) is coupled to a scanning carriage, and the scanning carriage moves along a scanning axis over the build area (210). In one example, printheads that are used in inkjet printing devices may be used as an agent distributor (212). In this example, the functional agent may be a printing liquid. In other examples, an agent distributor (212) may include other types of liquid ejection devices that selectively eject small volumes of liquid.
As described above, the agent distributor (212) may distribute a variety of agents. One specific example of an agent is a fusing agent, which increases the energy absorption of portions of the build material that receive the fusing agent to selectively solidify portions of a layer of powdered build material.
The agent distributor (212) may deposit other agents as well. For example, the agent distributor (212) may distribute a detailing agent that sharpens the resolution of the 3D printed object (216) and any printed portion of the container structure formed therein and provides cooling to selected regions of the powdered build material.
While specific reference is made to agent-based systems, the additive manufacturing system (100) as described herein may be implemented in non-agent-based systems such as selective laser sintering and selective laser melting additive manufacturing processes.
In some examples, such as that depicted in
While
The rupture device (424) may be of varying types. For example, the rupture device (424) may be a mechanical rupture device, an electrical rupture device, or a thermal rupture device.
In some examples, the container structure (318) may also include a spring device (426). In the example depicted in
A rupture threshold of the 3D printed container structure (318) may be defined by the characteristics of the container structure (318), specifically the characteristics of the rupture device (424), the spring device (426), and container (422). As a specific example, a container (422) with thicker walls may require a larger pressure to rupture. As another example, a shorter rupture device (424) increases the distance the applied force needs to move the container (422) to effectuate a rupture.
While specific reference is made to a mechanical rupture device (424) other types of rupture devices may also be implemented. For example, the rupture device (424) may be an electrical rupture device (424). That is, the rupture device (424) may include an electrically resistive element to rupture the container (422). In this example, application of electrical energy causes rupture. In one particular example, voxels may be made conductive by doping them with metal particles delivered via suspension in ink jetted liquids. Accordingly, a resistor may be made via this or another process and placed adjacent to, or integral with, the container (422) shell. When a sufficient current is passed through the resistor, it will get hot enough to mechanically compromise the container (422), causing release of contents.
In another example, the rupture device (424) is a thermal rupture device (424). In this example, heating of the container structure (318) causes payload release. For example, a payload may be released if the 3D printed object (
In some examples, the container structure (318) includes a payload receptacle (428) to capture the expelled payload. For example, a user may want to capture the payload for subsequent analysis. The payload receptacle (428) facilitates such a collection for subsequent analysis. While FIG. 4 depicts a particular configuration of a container structure (318), other structures are possible as well.
In the examples depicted in
In some examples, a portion of the released payload may become trapped inside the stop collar (530) following rupture, which may make the effects of rupture more difficult to see. Accordingly, in some examples, the stop collar (430) includes holes (431) around the base of the stop collar (530). Accordingly, through these holes (431) released contents may escape from the inside of the stop collar (530) and spill out over the full floor of the payload receptacle (428) to make it easier to see/detect a past rupture event.
On application of pressure as indicated by the arrow in
In this example, each of the different chambers (632-1, 632-2, 632-3) rupture at different pressure thresholds. Accordingly, using such a multi-chamber (632) container (422), different payloads could be released depending on different conditions. As a specific example, a first chamber (632-1) may be filled with cyan-stained build material, a second chamber (632-2) may be filled with a magenta-stained build material, and a third chamber (632-3) may be filled with a yellow-stained build material. When a first pressure threshold is crossed, the cyan material would be released, then if a second threshold is exceeded, the magenta material is released, and finally when an even larger third pressure threshold is exceeded, yellow build material is released. Such a multi-chamber (632) container (422) allows for additional capabilities to be contained in a single container structure (318).
At some point during additive manufacturing, the controller (
Once the container structure (
As described above, where pressure is a condition upon which a container structure (318) ruptures and the contents therein indicate a pressure threshold was exceeded at that location, an array of container structures (318) may provide a map of applied pressure across a surface. As a specific example, an array of container structures (318) may form a floormat on which a user may stand. The pressure the user's foot exerts on the floormat may rupture some of the container structures (318) which may expel a visible colored liquid or colored powder. Accordingly, a visual indication of pressure levels is indicated on the floormat. Note that while
In one particular example, different of the multiple container structures (318) have different predetermined conditions at which point they release their payload. For example, some container structures (318) may rupture at five pounds per square inch while others do not rupture until ten pounds per square inch. As described above, this may be carried out by altering characteristics of the respective container structures (318). In one particular example, the payload of a container structure (318) may relate to the rupture threshold. For example, a red colored liquid may be included in a container structure (318) which ruptures at 5 pounds per square inch and a blue colored liquid may be included in a container structure (318) which ruptures at 10 pounds per square inch. Accordingly, a resultant array may not only indicate those areas that see a certain pressure, but indicate a value associated with the pressure exerted.
In some examples, the container structures (318) may be of varying types, meaning they have different physical structures or contain different payloads. For example, some container structures (318) may include information for security, while others would trigger a mechanical pressure threshold was exceeded.
As a specific example, a container structure (318) may have a lattice structure as depicted in
Accordingly, when force is applied as indicated by the arrows (934), the holes of the lattice may get bigger as the container structure (318) is stretched (or compressed). As depicted in
As described above, an array of these types of container structures (318) may be tiled across a surface such that one payload (932) is released under certain force conditions with an additional payload (932) being release with a higher force condition.
As yet a further, a single container structure (318) may be deformable to different degrees. For example, a single container structure (318) may expand to one particular pore size which allows a payload (932) of a first size to be released, followed by a larger expansion under higher force which allows for another payload (932) of a second size, but still captured in the container structure (318), to be released.
Such an expandable container structure (318) may allow for filling the container structure (318) following placement of the container structure (318). That is, with a reversible structure, the payload distributor (
In some examples, if a container structure (318) is sponge-like, it can pull in liquids by capillary action, and the liquid can subsequently be released by squeezing and/or by elevating temperature. In another example, a user may soak a 3D printed object (
Such systems and methods 1) provide for a delayed release of a payload from a 3D printed object; 2) provides specific placement of the container structures forming a part of the 3D printed object; and 3) facilitates customization of the conditions that lead to structure rupture. However, it is contemplated that the systems and methods disclosed herein may address other matters and deficiencies in a number of technical areas.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/US2019/042610 | 7/19/2019 | WO | 00 |
