Claims
- 1. A dyestuff of the formula ##SPC29##
- wherein
- m is 1, 2 or 3;
- R.sup.9 is selected from the group consisting of ##SPC30##
- wherein n is 0 or 1 and R" is hydrogen or lower alkyl and ##SPC31##
- wherein p is 1, 2 or 3;
- R.sup.10 is selected from the group consisting of C.sub.1-6 alkyl, benzyl, sulphobenzyl, phenylethyl, sulphophenylethyl, ##EQU13## wherein r is 2 to 6, ##SPC32##
- wherein R" has the meaning given above and the dyestuff as a whole contains only one group represented by Z; and
- Z is a cellulose-reactive group selected from the group consisting of
- 2.
- 2. 3-dichloroquinoxalin-5-sulphonyl,
- 2,3-dichloroquinoxalin-5-carbonyl,
- 2,3-dichloroquinoxalin-6-sulphonyl,
- 2,3-dichloroquinoxalin-6-carbonyl,
- 2,4-dichloroquinazolin-6-sulphonyl,
- 2,4-dichloroquinazolin-6-carbonyl,
- 2,4-dichloroquinazolin-7-sulphonyl,
- 2,4,6-trichloroquinazolin-7-sulphonyl,
- 2,4,6-trichloroquinazolin-8-sulphonyl,
- 2,4,7-trichloroquinazolin-6-sulphonyl,
- 2,4,8-trichloroquinazolin-6-sulphonyl,
- 1,4-dichlorophthalazin-6-carbonyl,
- .beta.(4,5-dichloropyridazon-1-yl) propionyl,
- 2. 4-dichloropyrimidin-5-carbonyl,
- 4-(4',5'-dichloropyridazon-1-yl) phenylsulphonyl,
- 2,4-dichloropyrimid-6-yl,
- 2,4,5-trichloropyrimid-6-yl,
- 2,4-dichloro-5-cyanopyrimid-6-yl,
- 2,4-difluoro-5-chloropyrimid-6-yl,
- 5-chloro-6-methyl-2-methylsulphonylpyrimid-4-yl,
- 2,4-dichloro-5-bromopyrimid-6-yl,
- 2,4-dichloropyrimidin-5-sulphonyl,
- 2,2,3,3-tetrafluorocyclobutylcarbonyl,
- 2,3,3-trifluorocyclobut-1-enyl carbonyl,
- .beta.-(2,2,3,3-tetrafluorocyclobutyl) acryloyl,
- .beta.-(2,3,3-trifluorocyclobut-1-enyl) acryloyl,
- 2-chlorobenzthiazol-6-carbonyl, ##EQU14## wherein X is Cl, NH.sub.2, lower alkoxy, phenoxy, sulphophenoxy, lower alkylamino, di(lower alkyl)amino, ##SPC33##
- wherein p is 1, 2 or 3, ##SPC34##
- wherein p is 1, 2 or 3, ##SPC35## ##SPC36##
- wherein X.sup.1 is CH.sub.3, Cl, OCH.sub.3 or CO.sub.2 H and q is 1 or 2, ##SPC37##
- wherein q and X have the meanings given above, and ##EQU15## wherein Ar is the N,N'-divalent radical of a diamine selected from the group consisting of 4,4'-diaminodiphenylether, 4,4'-diamino diphenylsulphone, 4,4'-diaminodiphenoxyethane-2,2'-disulphonic acid, 2,6-naphthalene-4,8-disulphonic acid, benzidine-2,2'-disulphonic acid, 4,4'-diamino-diphenylurea-2,2'-disulphonic acid, 4,4'-diamino-stilbene-2,2'-disulphonic acid, 1,3-diaminobenzene-4,6-disulphonic acid and 4,4'-diaminodiphenylsulphide-2,2'-disulphonic acid, and D is a second monovalent monoazo entity of the formula ##SPC38##
- wherein m is 1, 2 or 3; R.sup.9 is ##SPC39##
- wherein n and R" have the meaning given above or ##SPC40##
- wherein p has the meaning given above; and R.sub.10 is selected from the group consisting of C.sub.1-6 alkyl, benzyl, sulphobenzyl, phenylethyl, sulphophenylethyl, ##EQU16## where r is 2 to 6, ##SPC41##
- wherein R" has the meaning given above. 2. A dyestuff as claimed in claim 1 in which R.sup.9 is ##SPC42##
- and R.sup.10 is selected from the group consisting of C.sub.1-6 alkyl, benzyl, sulphobenzyl, phenylethyl and sulphophenylethyl, where n, R.sup.11 and Z have the meanings given in claim 1.
- 3. A dyestuff as claimed in claim 2 of the formula ##SPC43##
- wherein m, n, R.sup.10 and R.sup.11 have the meanings given in claim 2.
- 4. A dyestuff as claimed in claim 6 in which R.sup.9 is ##SPC44##
- and R.sup.10 is selected from the group consisting of ##EQU17## ##SPC45##
- where p, r, R.sup.11 and Z have the meanings given in claim 1.
- 5. A dyestuff as claimed in claim 4 of the formula ##SPC46##
- wherein R.sup.12 is selected from the group consisting of ##EQU18## ##SPC47## ##SPC48##
- in which the CH.sub.2 group is
- joined to the nitrogen of the pyridone ring, m, r, p and R" have the meanings given in claim 4 and Ar is the N,N'-divalent radical of a diamine selected from the group consisting of 4,4'-diamino-diphenylether, 4,4'-diamino diphenylsulphone, 4,4'-diamino-diphenoxyethane-2,2'-disulphonic acid, 2,6-naphthalene-4,8-disulphonic acid, benzidine-2,2'-disulphonic acid, 4,4'-diaminodiphenylurea-2,2'-disulphonic acid, 4,4'-diaminostilbene-2,2'-disulphonic acid, 1,3-diaminobenzene-4,6-disulphonic acid and 4,4'-diaminodiphenylsulphide-2,2'-disulphonic acid.
Priority Claims (1)
Number |
Date |
Country |
Kind |
15474/71 |
May 1971 |
UK |
|
Parent Case Info
This is a Continuation-in-Part of our earlier application Ser. No. 238,620 filed March 27, 1972, now abandoned.
US Referenced Citations (10)
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
238620 |
Mar 1972 |
|