Patent Application
20200002228
The present invention relates to a coated granule suitable for defining the upper surface of a bituminous roofing membrane, in particular for making a cool roof designed to reflect more sunlight and absorb less heat than a standard roof while at the same time having depolluting properties.
A cool roof can benefit a building and its occupants by:
Beyond the building itself, cool roofs can also benefit the environment, especially when many buildings in a community have them. Cool roofs can:
It is well known to suggest bituminous roofing membranes in the form of a bituminous web having a protective layer of mineral granules, such as coarse sand, covering the upper surface of the bituminous web; the granules may sometimes be coated in which case the coating may have such a color that the roofing membrane presents itself with a desired colored appearance.
Typically the coated granules are formed by applying in a mixer the coating onto each granule. The individual granules may, by way of example, be formed by the sintering of a ceramic mixture, see WO2013/192,336, and WO2016/001,303, the latter suggesting mixtures comprising up to 32% by weight of cristobalite.
Alternatively, coatings may be applied on the bitumen membrane, see WO 2004/070,107 where the coating comprises TiO2 as a whitener and selected in amounts that give the roofing membrane high reflective properties.
Manufacturing membranes using the aforementioned granules allows a controlling of the reflectance TSR (Total Solar Reflectance) of incident light but involves relatively high costs.
In addition, a high TSR (Total Solar Reflectance) can only be maintained for a relatively short period of time since pollution will typically reduce the reflective properties over time through the formation of dark spots on the roofing membrane. Hence, additional measures are required to maintain the high TSR.
Depolluting roofing membranes are known from i.a. WO 2009/056,492. A soot resistant roofing membrane is disclosed in GB 1,234,071, wherein a hydrophobic surface coating degrades to become a hydrophilic surface coating.
As may be understood it is known that the provision of a top layer on a bitumen membrane of a composition comprising i.a. i) TiO2 in its anatase form and ii) a binder, will give a depolluting effect through the conversion—by the TiO2 in its anatase form—of polluting NOx agents settled on the roofing membrane into substances that are easily flushed off during rainfalls, thereby keeping the roofing membrane essentially free from dark stains/spots.
In the following text individual granules of the roofing membrane will interchangeably also be referred to by the term “core” it being understood that the individual granule/core is coated to form a coated granule.
Particles of TiO2 in its anatase form for use in depolluting roofing membranes has a blueish color darker than particles of TiO2 in its rutile form. For this reason the use of particles of TiO2 in its rutile form can be preferred as a component in white coating compositions for the whitening of granules. When using TiO2 in its anatase form in coating compositions the further addition of pigments to the coating composition is required to obtain high TSR-values of the roofing membrane, with ensuing costs.
The present inventors have found that by selecting as the core that is coated a granule with a relatively high cristobalite content, preferably comprising only cristobalite and little impurities, a high TSR (Total Solar Reflectance) and a high SRI (Solar Reflectance Index) of a roofing membrane with a multiplicity of such coated granules may be achieved. Thereby the overall ability of the membrane to reject solar heat is enhanced, the transmittance being low.
Thus, with the present invention high TSR-values of the roofing membrane above around 70% may still be achieved despite the use of a coating composition comprising TiO2 in its anatase form.
More specifically, the present inventors propose herewith a coated granule suitable for use in a bituminous roofing membrane, the coated granule consisting of:
i) a granule,
ii) a first coating on the surface of the granule,
iii) an oil barrier coating on the first coating,
It follows that the present invention also concerns a bituminous roofing membrane comprising a bituminous web having a first side, a plurality of the aforementioned coated granules being spread over said first side to define a surface of the membrane.
The oil barrier defined by the additional, second layer applied directly onto the first coating is preferably selected to be degradable upon exposure to UV-radiation after a few days or weeks, thereby exposing the first coating to the environment, allowing the anatase TiO2 to act as a depollutant. In some cases this degradation of the coating defining the oil barrier is assisted by photocatalytic action of the anatase titanium dioxide TiO2 of the first coating.
As the skilled person will understand, for each coated granule the thickness of the first coating may vary locally due to eg. the fact that the first coating is applied onto a surface which is not even. Preferably, the first coating covers at least 50%, preferably at least 70% of the surface of the granule on the aforementioned first side of the bituminous roofing membrane.
When applying the first coating, such as in a coating procedure using the aforementioned mixer, the applying may be adjusted such that the first coating on average covers at least at least 60% and at most 90% of the surface of the granules. The granules are then spread over the aforementioned side to make the bituminous roofing membrane.
Moreover, the first coating preferably has an average thickness in the range of 10 μm to 20 μm, preferably 5 μm to 15 μm, preferably with a maximum thickness at any place of 100 μm. Applicant presently prefers to use particles of anatase TiO2 having a size in the order of 0.2 μm-0.4 μm, such as around 0.3 μm.
The cristobalite raw material granule may be in a naturally occurring form, or may be manufactured on the basis of naturally occurring materials, with normal impurities.
The oil barrier prevents or restricts migration of oil components to the surface of the membrane from the bituminous web onto which a multiplicity of the granules have been applied. Such migration could lead to an undesired formation of spots/stains of migrated oil on the surface, as discussed generally in WO14015876, detrimental to the desired low transmittance and high reflectivity.
An embodiment of the invention will now be described in further details, with reference to
Each shown granule 10 is a cristobalite granule/core having a size in the order of 1 mm and carrying directly thereon a first covering or coating layer 5 in the form of a composition comprising or consisting of i) TiO2 in its anatase form and ii) a binder, such as a monoaluminiumphosphate binder. In this embodiment the thickness of this layer 5 is in the range of 10 to 20 μm, with particles of anatase TiO2 having a size in the order of 0.2 μm-0.4 μm, such as around 0.3 μm, so that the bituminous roofing membrane 1 provides a depolluting effect and at the same time highly desirable TSR and SRI values. Preferably, no granules of other type and no granules having any first coating layer 5 of other composition are distributed onto the bituminous web 11. Specifically, the first coating layer 5 may in one embodiment have the following composition:
During manufacture of the coated granule 10 an additional second layer is applied directly onto the first coating layer 5 to form an oil barrier defining the outer surface of the coated granule 10. In the membrane 1 a portion 12 of this second layer will be in contact with the bituminous material of the web 11 by the coated granule 10 being partially embedded therein through a rolling procedure during the final steps of the manufacturing of the membrane 1. Another portion 13 of the second layer is exposed to the environment. The second layer forms a firm bond to the first layer 5 and to the bituminous material of the web 11 on the other hand. Specifically, the second layer forms an oil barrier coating, which may be transparent, preventing or restricting migration of oil components of the bituminous web towards the surface of the membrane 1. At the same time the aforementioned portion 13 of the oil barrier (defined by the second layer) is by selection of the compound for the oil barrier, degradable upon exposure to UV-radiation, such as typically after a few days or weeks after application of the membrane on a building roof/building surface, such as after 4 weeks, to thereby expose the first layer 5 and, hence, the titanium dioxide TiO2 containing first layer to the environment, allowing the anatase TiO2 to act as a depollutant. In some cases this degradation/exposing of the first layer 5 is assisted by photocatalytic action of the titanium dioxide TiO2 of the first layer.
The compound defining the oil barrier may by way of example be an organosilicon compound, such as polymethylhydrogensiloxane, which may be mixed with an acrylic resin. The acrylic resin has the further advantageous effect of binding any free dust particles to the surface of the granules with the oil barrier during the process of manufacturing the coated granules. Such free dust would be of disadvantage when the coated granules are applied to the bituminous web on manufacturing the roofing membrane in causing problems with the adhering of the coated granules to the bituminous web as well as causing possible respiratory health problems to workers making the roofing membrane ; an increased resistance against staining of the roofing membrane may also obtained by this binding, in the case of dust having bitumen oil absorption properties. Examples of useful acrylic resins are compounds having a glass transition temperature of the order of −20° C.-0° C., or chosen in the family of polyacrylate polymers, styrene-acrylic copolymers, or the like.
Using an oil barrier with an acrylic resin composition has no significant effect on the Total Solar Reflectance as depicted in
As can be seen from the figures, including the blueish TiO2 in its anatase form in the coating composition defining the first coating layer 5 on granules 10 comprising a relatively high % by weight of cristobalite, allows for a high reflectance, i.e. higher values of the SRI, compared to
| Number | Date | Country | Kind |
|---|---|---|---|
| 17158120.0 | Feb 2017 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2018/054565 | 2/23/2018 | WO | 00 |
