The invention relates to a control system, which is used in a copper extraction process. Especially, the invention relates to copper extraction process having at least a leaching phase, a solvent extraction phase and an electrowinning phase.
A copper extraction process from ore comprises several steps. There are several different processes for the copper extraction. Usually, the ore is milled and then it goes through a flotation process. After the flotation there is a leaching phase. Before the leaching there can be a roasting phase and/or thickening phase of the flotation pulp of copper. After the leaching phase there is a solvent extraction phase and electrowinning. Effluent of the electrowinning phase is the final copper material of the copper extraction process.
Each phases and processes said above can comprise several subphases. Further, the processes depend of the copper ore achieved from a mine. Some of said phases may have control systems, but usually many control actions are based on manual measurements and manual dosing of different chemicals into the processes.
For example, in processes having at least the leaching phase, the solvent extraction phase and the electrowinning phase, the solvent extraction phase consumes organic solvent due to evaporation and with crud, which is removed from the solvent extraction. Therefore, the organic solvent is added into the extraction phase from time to time containing manual actions.
Another example is to dose polymer/s into the leaching phase. TSS measurements are made manually from the influent of the leaching process. The measurements are analyzed in a laboratory. Based on the analysis the polymer/sis dosed. The period between the dosings can be at least several hours. The processes have relatively long delays in order to react to the dosings done.
The object of the invention is to decrease the amount of the organic solvent, which is used in the solvent extraction phase of the copper extraction process. The object is achieved in a way described in the independent claims. Dependent claims illustrate different embodiments of the invention.
A control system according to the invention is for a copper extraction process having at least a leaching phase 9, a solvent extraction phase 15 and an electrowinning phase 16, the leaching phase comprising a post leach thickener 13. The control system comprises first measuring units M1, M2 to measure volume and total suspended solids in an influent of the post leach thickener 13, and at least one second measuring unit M3, M4, M5 to measure at least total suspended solids relating to effluent of the post leach thickener 13, The control system comprise also a control unit 31 to receive measurements of the first measuring units M1, M2 and the second measuring units M3, M4, M5. The control unit forms a control signal C1 to a polymer dosing into the influent of the post leach thickener 13.
An inventive method is used in controlling copper extraction process, which process has at least a leaching phase, a solvent extraction phase and an electrowinning phase, the leaching phase comprising a post leach thickening phase. The method comprises phases to measure volume and total suspended solids in an influent of the post leach thickening phase (61), to measure at least total suspended solids relating to effluent of the post leach thickening phase (62), to receive measurements of said measuring phases (63) by a control unit, and to form a control signal to a polymer dosing into the influent of the post leach thickening phase.
The idea of the invention is that by controlling the leaching phase efficiently in an automated way the amount of the solids in the effluent of the leaching phase can be decreased. The fluctuation of the amount of the solids in the effluent can also be decreased, which is also beneficial. Therefore, crud is not formed so much in the solvent extraction phase, which means that the solvent consumption decreases.
In the following, the invention is described in more detail by reference to the enclosed drawings, where
In order to understand the invention an example of a known copper extraction process is illustrated in
After the mills, the milled ore is supplied to a flotation phase. The flotation is a process where mineral, like copper sulphide, is separated from gangue by taking advantage of difference in hydrophobicity. Surfactants and wetting agents is usually used. The milled copper sulphide material will be submitted to a conventional flotation process 4. For example, a copper concentrate of between 34% and 38% can be produced. The concentrate is then feet to a roaster 5 where the partial sulphating roast creates a copper product known as calcine that is readily soluble in acid. When roasting sulphide ore is heated to a high temperature in presence of air. The roasting is a metallurgical process where gas-solid reactions are involved. During roasting, the copper sulfide is converted to the calcine, which is an oxide.
On the other hand, the milled copper oxide material will be submitted to a single-stage flotation process, known as pre-flotation 7, where the fraction of sulphide minerals present in the ore will be separated from the predominantly copper oxide containing material. The copper sulphides concentrate from this flotation step is supplied to the roaster 5. The flotation tail is feet to receiving thickeners 8, which are parts of so-called displacement wash circuit.
The thickeners are used in a thickening process where for example solid-liquid mixture is processed. The idea is to separate most of the solids from water or liquor. The process utilizes gravitation. The overflow of the thickener is water/liquor. The underflow of the thickener is slurry containing most of the solids. The displacement wash is a process to wash solid-phase particles with a minimum amount of water.
The purpose of the receiving thickeners 8 is to remove as much as possible process water from the flotation tails that is received from the concentrator, ie. from the pre-flotation process 7. The feed from the concentrator can be pumped into receiving tanks that distribute the feed to the receiving thickeners. The underflow 8A from the thickeners 8 can comprise about 55-60% wt solids, which is transferred into a pre-leach thickener mixing tanks, here to a counter-current decantation (CCD) process 10. The overflow 8B (water/liquor) from the receiving thickeners is returned to the pre-flotation 7 via the oxide milling 6.
The counter current decantation process has several tanks, like thickener tanks, sequentially. The underflow of each tank feeds the next tank in the sequence. The overflow of each tank feeds the previous tank in the sequence. In other words, the water, or solution flows against the slurry having most of solids and impurities.
Here, the purpose of the pre-leach CCD 10 is also to displace water with low grade raffinate 21B from a low grade solvent extraction process 21 to reduce acid consumption by using residual acid in the low grade raffinate to consume some gangue minerals and leach a small amount of copper. In the pre-leach CCD 10, slurry flows counter current to the low grade raffinate solution used for washing of the slurry. The slurry (underflow) 10A from the pre-leach CCD is then transferred to a leach process 9. The overflow 10B from the pre-leach CCD is supplied to, for example, an iron precipitation tanks, which are not shown in
The leaching process 9 illustrated in
The purpose of the leaching process is to contact the copper minerals with a lixiviant, for example sulphuric acid, to dissolve the minerals of interest and transform them into the liquid phase as dissolved metal salts. The partially leached slurry 10A from the displacement wash, i.e. the pre-leach CCD, is pumped to the leach storage tanks 9 where it is brought into contact with the acidified high grade raffinate 15B from a high grade solvent extraction 15 and calcine 5A from the roaster/s 5. The storage leach slurry 11A is then pumped to the leach tanks 12 where the pH is to be controlled using acidified raffinate. The leach slurry 12A is then pumped to a post leach thickener 13. The leach process 9 may comprise several leach trains with several leach tanks, like two leach trains each with 6 leach tanks.
The purpose of the post leach thickener 13 is to separate the solid and liquid phases of the leached slurry stream. The target metals are now present in the liquid phase as dissolved metal sulphides along with other dissolved metals such as aluminium, magnesium, calcium and iron. The post leach thickener 13 is the point of separation between the high-grade pregnant leach solution (PLS) and the low grade PLS. The high grade PLS 13B is the overflow of the post leach thickener 13 and it is fed to a high-grade solvent extraction. The low grade PLS is the underflow (slurry) 13A of the post leach thickener 13 and it is fed to a low-grade solvent extraction.
As said, the post-leach thickener 13 is fed from the leach tanks 12, the slurry is diluted using a forced dilution system to reduce the feed-well slurry density to 5-10% wt solids. Flocculant is added in a thickener feed-well and/or in a thickener feed pipe. In the embodiment of
The counter current decantation process 17 in the embodiment of
The purpose of the counter current decantation tanks 17 is to displace the base metal containing solution with acidified cobalt barren solution, to recover up to 99.5% of the PLS through the 7 CCD stages, for example. The first tank/thickener CCD 1 18 is fed with the underflow slurry 13A from the post leach thickener 13 and the overflow solution from the second CCD 2 19. The importance of CCD 1 18 is that the metal containing solution from it, from the overflow 17B, is the feed to the low-grade solvent extraction process 21.
The tanks CCD 2 to CCD 6 fed with underflow from CCD (X−1) and overflow from CCD (X+1). The tank CCD 7 20 receives slurry from CCD 6 and cobalt barren solution from a cobalt precipitation plant that serves as a washable solution. The underflow 17A from CCD 7 is known as acidic tailings and is pumped to a tailings neutralization plant. The cobalt precipitation plant and the tailings neutralization plant are not illustrated in
As can be seen, the embodiment of
So, the high-grade solvent extraction process is fed with the pregnant leach solution, PLS, originating from the post-leach thickener 13. The purpose of the high-grade solvent extraction is to selectively extract copper from the PLS, leaving any other dissolved metals. Extraction of the copper from the PLS is achieved by using an extractant, i.e. organic solvent, that is synthesised to selectively bind to the dissolved copper ions. The solvent extraction phase has internal circulation of the organic solvent. Organic solvent is added from time to time in order to compensate loss the organic solvent via evaporation and crud. The copper containing organic extractant is called loaded organic.
After the solvent extraction 13 the high-grade loaded organic 15A is then stripped in a subsequent process 16 by contacting the loaded organic with an acidic solution called lean electrolyte. This process is an industrial electrolytic process, which is called as electrowinning. In electrowinning, a current is passed from an anode through the lean electrolyte containing copper. The copper is deposited in an electroplating process onto the cathode from where the pure copper can be gathered. The barren organic can be recycled to the extraction stage (not shown in
The possible low-grade solvent extraction process 21 is fed with PLS originating from the CCD 1 18. The purpose of the low-grade solvent extraction process is to selectively extract copper from the low grade PLS, leaving behind any other dissolved metals. Extraction of the copper from the PLS is achieved by using an extractant, organic solvent, that is synthesised to selectively bind to the dissolved copper ions. The copper containing organic extractant is called loaded organic.
The low-grade loaded organic is then stripped in a subsequent electrowinning process 22. The barren organic is then recycled to the extraction stage. After the low grade PLS have been stripped of the copper in solution, the acidic solution is now known as low grade raffinate 21B, that is fed to the displacement wash CCDs, i.e. to the pre-leach CCD's 10.
In addition, the control system comprises a control unit 31 to receive measurements ME1 . . . ME6 of the first measuring units M1, M2 and the second measuring units M3, M4, M5, M6, to form a control signal C1 to a polymer dosing into the influent 12A of the post leach thickener. The control signal is arranged to control feed pump P1. The feed pump P1 is arranged to feed polymer into the influent of the post leach thickener. By controlling the feed pump the dosing of the polymer can be kept at desired levels, and the solids in the PLS can be decreased. The fluctuation of the among of the solids in the PLS can also be decreased. Since the amount of crud, which is removed in the solvent extraction phase, depends on the solids in the PLS, the loss of the organic solvent is decreased due to the efficient control of the polymer dosing in the leaching phase.
Another embodiment of the invention is performed when the above said control arrangement is also arranged to form another control signal C2 to an organic solvent dosing in the solvent extraction phase 15. The other control signal may also comprise another control signal C3 to another solvent dosing if the copper extraction process has the already said low-grade solvent extraction 21. The other control signals are arranged to control feed pumps or valves P2, P3. The feed pump P2 is arranged to feed organic solvent to the high-grade solvent extraction process 15, the feed pump (or a valve) P3 to the low-grade solvent extraction process 21. By controlling the feed pumps the dosing of the organic solvent can be kept at desired levels without any notable fluctuations. In other words, when controlling the addition of the organic solvent, it can be made in shorter intervals between the dosing moments. This has also an effect that crud (and organic solvent bound with the crud) is removed less from the solvent extraction process.
The control unit 31 is arranged to keep the measurements of the second measuring unit M3, M5, M6 relating to the total suspended solids, TSS, at a setpoint value by controlling the polymer dosing. In other words, when the measured TSS relating to the effluent of the post-leach thickener is kept at the desired value, when the post-leach thickener 13 runs properly, it also affects to the dosing rate for the organic solvent in the solvent extraction phase. So, the TSS level in the overflow 13B of the post leach thickener is kept at the setpoint, and therefore the high-grade solvent extraction process 15 can be run with less amount of the organic solvent, because the crud forming and crud fluctuation of the extraction process is minor. As said, the control unit 31 can also be arranged to utilize the setpoint value to form the control signal to the organic solvent dosing. The above said matters applies also to the low-grade solvent extraction process 21, if it is used in the copper extraction process.
As can be noted in
In addition, the control change signals may also relate to control dosing/addition of the organic solvent, in which case The control change signals 31C are transformed into the control signal/s 37, 38 by a transformation unit 31B in order that it/they can control the pumps P1, P2, P3 for dosing a correct amount of polymer ans organic solvent.
In other words, the transformation unit 31B convert the control change signals 31C to be suitable for the pumps.
The calculation unit is also arranged to use a setup value 31D for a desired parameter. In the invention the parameter is a TSS value relating to the effluent of the post leach thickener 13. This TSS value is kept at the setpoint value 31D by the control unit. If the measured TSS value differs from the setpoint value, the control unit gives the control signal 37 in order to change the dosing of the polymer by controlling the pumping rate of the pump P1. More precisely the calculation unit 31A calculates the control change signal 31C base on said difference/s between the setpoint TSS value and the measured TSS value, and the transformation unit 31B convert the control change signal to the controls signal 37, which is suitable for the pump P1. The polymers are used as flocculants in the post-leach thickener.
The setpoint value 31D is set for the use of the calculation unit 31A by taking into account process conditions of the post leach thickener in order to keep the post leach thickener running properly. The control unit 31 may have a setup unit 31E for making and adjusting the setup value. The setup unit can be arranged to take into account several parameters.
When the post-leach thickener runs properly, and the TSS value relating to effluent of the post-leach thickener is kept at the setpoint value, it also affect to the solvent extraction process 33 so that extraction process runs more stable and therefore the dosing/addition of the organic solvent into the extraction process is more steady. Crud is formed less in the solvent extraction phase, and therefore the loss of the organic solvent is lesser. This has an effect that the organic solvent can actually be dosed less. Further, in the steady process the organic solvent can be used more efficiently. So, the control unit is arranged to utilize the setpoint value 31D for the TSS value relating to the effluent of the post leach thickener.
The setpoint value may also be used to make the control signal 38 for the pump/valve P2 (and also to P3) to dose/add the organic solvent. There is a correlation between the said TSS value and the dosing/adding of the organic solvent. This correlation can be handled by a simple table or a more complicated control algorithm like those mentioned above.
As said,
The polymer dosing is arranged to supply the polymer into a feed pipe or a feed well of the post least thickener. The polymer dosing is controlled by controlling the pumping rate of the pump P1.
As illustrated in
Above, it is mostly described the overflow of the post leach clarifier unit, being the effluent of the post leach clarifier. However, the effluent can also be considered to comprise the underflow 13A of the process in question, in this case the underflow of the post leach thickener. As can be seen in
So, the solvent extraction phase comprises a high grade solvent extraction unit 15 having an influent from the leaching phase, more precisely from the overflow 13B of the post least thickener. As said, the control unit 31 may also be arranged to form the control signal C2 to the organic solvent dosing to the high grade solvent extraction unit 15.
In addition, the solvent extraction phase may also comprise a low grade solvent extraction unit 21 having an influent 17B from the overflow of the first current decantation tank 18 of the counter current decantation unit 17 The control unit may further arranged to form the control signal C3 to the organic solvent dosing to the low grade solvent unit 21.
The control unit 31 illustrated in
As said, in the other embodiment the control unit can be arranged to form other control change signal. The other control change signals are for the pump/s or valve/s P2, P3 dosing the organic solvent.
The first control unit 330 is in communication with the second control unit 301, which second control unit is arranged to utilize control change signal (and the other control change signals) to form the control signal to polymer dosing (and the organic solvent dosing).
The control unit 31 can be in the location of the copper extraction process, but as said it can also have a distributed structure. For example, the second control unit 301 may be situated with the copper extraction plant, and the first control unit 300 can be in a server in another location. In the distributed structure the communication between the measuring devices M1 . . . M6 and the first control unit, and between the first control unit 300 and the second control unit 301, are via a communication network/s. The communication network can be wireless network like a mobile phone network, or fixed network, or a combination of different communication networks. The functions of the first control unit can be served as a cloud service. It is practical to have a local control unit 301 to provide the control signals C1, C2, C3 to the local devices like the pumps in the case of
The method can be arranged to keep the measurements of the total suspended solids relating to effluent of the post leach thickening phase at a setpoint value by the control signal. The control unit may further arranged to utilize the setpoint value to form the other control signal to the organic solvent dosing as described above.
The method can also be arranged to utilize a 3rd degree polynomial function in order to form a control change signal as response to the measurements of the total suspended solids relating to effluent of the post leach thickening phase, which control change signal is utilized to form the control signal to polymer dosing as described above.
The inventive system and method are used in the copper extraction process having the leaching, solvent extraction and electrowinning phases. The leaching is in atmospheric condition. The invention makes it possible to consume less organic solvent in the solvent extraction phase than in know implementations. The organic solvent is the most expensive chemistry utilized in the copper extraction. The amount of the organic solvent removed with the crud correlates to the amount of suspended solids that pass to the solvent extraction unit/s. The solids, which pass via the effluent of the post leaching are decreased in the invention. So suitable locations to the turbidity or TSS measurement devices have been selected. The turbidity or the TSS measurement devices are arranged to withstand the harsh conditions (low pH) of a mining solution.
The invention is used for thickening and clarifier units to optimize the dosing of polymers for solid liquid separation. TSS levels are used as an indication of treatment efficacy. The TSS level is kept as low as possible, taking into account that the post leach thickener runs properly. The TSS level also, as already said, has effect for the required dosing/addition of the organic solvent for the solvent extraction unit/s.
Depending on the implementations of copper extraction plants, there can be many post leach thickeners and clarifiers and also many solvent extraction units.
It is evident from the above that the invention is not limited to the embodiments described in this text but can be implemented in many other different embodiments within the scope of the independent claims.
Number | Date | Country | Kind |
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20206086 | Oct 2020 | FI | national |
Filing Document | Filing Date | Country | Kind |
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PCT/FI2021/050728 | 10/28/2021 | WO |