A FRAGRANCE MIXTURE CONTAINING ISOCITRONELLOL

Information

  • Patent Application
  • 20240173227
  • Publication Number
    20240173227
  • Date Filed
    April 13, 2021
    3 years ago
  • Date Published
    May 30, 2024
    6 months ago
Abstract
Suggested is a fragrance mixture containing or consisting of (a) 5,7-dimethyloct-6-en-1-ol and (b) at least one other fragrance.
Description

The present invention is in the field of fragrances and relates to novel combinations of fragrances.


TECHNOLOGICAL BACKGROUND

In perfume industry, there is a great demand for fragrances, especially for notes that allow the fragrance palette to be expanded. Particularly high is the demand for fragrances that, at small dosages, have a great effect on other fragrances and change them for the better.


RELEVANT STATE OF THE ART

T. Moroe et al. (J-Stage, 72(9), p 1175-1177 (1952) describe the synthesis of isocitronellol from levulic acid by the following two routes. One is the reduction of the lactone (4, 7-dimethyl-1, 4-octanolide) to glycol with subsequent dehydration, while the other is the ring cleavage of the lactone with hydrogen chloride and ethanol, followed by dehydrochlorination to unsaturated ester, and finally by the Bouveault-Blanc reduction, the respective yield being 14% and 16.5% of the theoretical amount.


From FR 1328641 A1 (IFF), the recovery of 5,7-dimethyloct-6-en-1-ol (isocitronellol) by reaction of 5,7-dimethylocta-1,6-diene with aluminum alkyls in aprotic solvents is known. The product is characterized with an odor similar to citronellol.


According to EP 3661993 A1 (P2SCIENCE) isocitronellol is a useful starting material for making polyethers.


OBJECT OF THE INVENTION

Therefore, the object of the present invention has been providing a fragrance mixture, particularly a mixture comprising or consisting of at least one primary fragrance having a woody, amber, fruity or musky odor, wherein said woody, amber, fruity or musky perception is modified and/or intensified by adding small quantities of at most 5 wt.-percent of a secondary fragrance compound.







DESCRIPTION OF THE INVENTION

A first object of the present invention refers to a fragrance mixture containing or consisting of

    • (a) 5,7-dimethyloct-6-en-1-ol and
    • (b) at least one other fragrance, preferably a fragrance having a
      • (b1) woody,
      • (b2) amber,
      • (b3) fruity or
      • (b4) musky
      • odor.


Surprisingly it has been observed that adding 5,7-dimethyloct-6-en-1-ol (isocitronellol) as a secondary fragrance to at least one other primary fragrance, preferably a fragrance having a woody, amber, fruity or musky odor, leads even in small amounts of at most 5 wt.-percent to a significant modification and/or intensification of the odor of the primary fragrance or blend of primary fragrances.


5,7-Dimethyloct-6-en-1-ol as the Secondary Fragrance

5,7-Dimethyloct-6-en-1-ol follows formula (I)




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and is also known as isocitronellol; it is usually present as a mixture of different enantiomers.


For its preparation, dimethylocta-1,6-diene (anomadiene) is assumed to be a byproduct of the preparation of dihydromyrcene from alpha-pinene according to the following scheme:




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Anomadiene can then be reacted in a known manner with diisobutyl-aluminum in heptane to give 5,7-dimethyloct-6-en-1-ol, as known, for example, from FR 1328641 A1 of 1962.


Primary Fragrances with Woody Odor

Suitable primary fragrances with woody odor perception (b1) are selected from the group consisting of:














INCI
Tradename
Supplier







(Ethoxymethoxy)cyclododecane
AMBERWOOD ®
Symrise


β-2,2,3-Tetramethylcyclopent-3-ene-1-
BRAHMANOL ®
Symrise


butanol


alpha-Ethyl-2,2,6-
MADRANOL ®
Symrise


trimethylcyclohexanepropanol


Octahydro-4,7-methano-1H-indenemethyl
MYROSE ®
Symrise


acetate
ACETATE


1,1-Dimethoxy-cyclododecane
PALISANDAL ®
Symrise


Methoxycyclododecane
PALISANDIN ®
Symrise


(2E)-2-Ethyl-4-(2,2,3)-trimethylcyclopent-
SANDRANOL ®
Symrise


3-en-1-yl) but-2-en-1-ol


2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-
SYMROXANE ®
Symrise


hexahydro-7-methoxy-1,1,5,5-tetramethyl-


4-Methyl-4-phenylpentan-2-one
VETIKON ®
Symrise


4-Cyclohexyl-4-methylpentan-2-one
VETIRAL ®
Symrise


1′,1′,5′,5′-Tetramethylhexahydro-spiro[1,3-
YSAMBER ® K
Symrise


dioxolane-2,8′(5′H)-2H-2,4a-


methanonaphthalene]









Primary Fragrances with Amber Odor

Suitable primary fragrances with amber odor perception (b2) are selected from the group consisting of:














INCI
Tradename
Supplier







(4aR,5R,7aS,9R)-Octahydro-
AMBROCENIDE ®
Symrise


2,2,5,8,8,9a-hexamethyl-4H-


4a,9-methanoazuleno[5,6-


d]-1,3-dioxole


3a,6,6,9a-Tetramethyl-
AMBROXIDE ®
Symrise


dodecahydronaphtho[2,1-


b]furan









Primary Fragrances with Fruity Odor

Suitable primary fragrances with fruity odor perception (b3) are selected from the group consisting of:














INCI
Tradename
Supplier







Acetophenone

Symrise


2-tert.-butyl cyclohexyl acetate
AGRUMEX ® HC
Symrise


Octadecanal
ALDEHYDE C18
Symrise


Allyl caproate

Symrise


Allyl cyclohexyl propionate

Symrise


Allyl heptoate

Symrise


Allyl phenoxy acetal

Symrise


5-Hexyldihydro-4-methylfuran-
APRIFLOREN ®
Symrise


2(3H)-one


Benzaldehyde

Symrise


Benzyl alcohol

Symrise


1,5-Dimethyl-bicyclo[3.2.1]octan-
BUCCOXIME ®
Symrise


8-one oxime


1-Cyclohexylethyl-2-butenoate
DATILAT ®
Symrise


3,7-Dimethyloct-1,6-diene
DIHYDROMYRCENE
Symrise


Ethyl acetoacetate

Symrise


Ethyl butyrate

Symrise


Ethyl caproate

Symrise


Ethyl heptoate

Symrise


Ethyl isovalerate

Symrise


Ethyl methyl butyrate-2

Symrise


Ethyl propionate

Symrise


(2E)-5-Methylhept-2-en-4-one
FILBERTONE ®
Symrise


2,4,6-Trimethyl-4-phenyl-1,3-dioxane
FLOROPAL ®
Symrise


Ethyl 2,4-dimethyl-1,3-dioxolane-
FRAGOLANE ®
Symrise


2-acetate


4-(4-Methoxyphenyl)butan-2-one
FRAMBION
Symrise



METHL ETHER


1,3-Dimethylbutyl 2-butenoate
FRUTINAT ®
Symrise


Hexyl acetate

Symrise


Isoamyl butyrate

Symrise


Isoamyl isovalerate

Symrise


(2E)-1-(2,4,4-Trimethylcyclohex-2-
ISODAMASCONE
Symrise


en-1-yl) but-2-en-1-one


Ethyl (2-methyl-1,3-dioxolan-2-
JASMAPRUNAT ®
Symrise


yl)acetate


Methyl phenyl acetate

Symrise


6-Butyl-tetrahydro-pyran-2-one
NONALACTONE
Symrise



DELTA


2-Methyl-4-propyl-[1,3]-oxathiane
OXANTHIA ®
Symrise


1,1′-Bi(cyclopentyl)-2-yl (2E)-but-2-
PYROPRUNAT ®
Symrise


enoate


2-Cyclopentene-1-acetic acid, ethyl
SULTANENE ®
Symrise


ester


rel-(2R,4S,6R)-2,4,6-Trimethyl-4-
VERTACETAL ®
Symrise


phenyl-1,3 dioxane
COEUR


1,3-Dimethyl-3-phenylbutylacetate
VERTICOLACETAT ®
Symrise









Primary Fragrances with Musk Odor

Suitable primary fragrances with musk odor perception (b4) are selected from the group consisting of:














INCI
Tradename
Supplier







Oxacycloheptadec-10-en-2-one
AMBRETTOLIDE ®
Symrise


Cyclohexadec-8(7)-en-1-one
AURELIONE ®
Symrise


Oxacyclohexadecen-2-one
GLOBALIDE ®
Symrise


Cyclohexadec-8-en-1-one
GLOBANONE ®
Symrise


Cyclohexadecanone
ISOMUSCONE
Symrise


Oxacyclohexadecan-2-one
MACROLIDE ®
Symrise


Pentadecan-15-olide
MACROLIDE ®
Symrise



SUPRA


1,4-Dioxacycloheptadecan-5,17-dion
ETHYLENE
Merck



BRASSYLATE









In a preferred embodiment, the mixtures may comprise components (a) and (b) in a weight ratio of about 0.01:99.99 to 5:95, preferably in a weight ratio of from about 0.1:99.9 to 2:98 and more preferably from about 0.3:99.7 to 1:99.


COSMETIC COMPOSITIONS

Another object of the present invention refers to a cosmetic composition, in particular a skin care, personal care, sun care or hair care product or product formulation, comprising the fragrance mixture as defined above in a working amount, for example about 0.1 to about 10% b.w., preferably about 0.5 to about 8% b.w. and particularly from about 1 to about 5% b.w.-calculated on the composition(s). The composition may represent for example a cosmetic cream, lotion, spray, emulsion, ointment, gel or mouse and the like.


The preparations according to the invention may contain antidandruff agents, irritation-preventing agents, irritation-inhibiting agents, antioxidants, adstringents, perspiration-inhibiting agents, antiseptic agents, ant-statics, binders, buffers, carrier materials, chelating agents, cell stimulants, cleansing agents, care agents, deodorizing agents, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibres, film-forming agents, fixatives, foamforming agents, foam stabilizers, substances for preventing foaming, foam boosters, gelling agents, gel-forming agents, hair care agents, hair-setting agents, hair-straightening agents, moisture-donating agents, moisturizing substances, moisture-retaining substances, bleaching agents, strengthening agents, stain-removing agents, optically brightening agents, impregnating agents, dirt-repellent agents, friction-reducing agents, lubricants, moisturizing creams, ointments, opacifying agents, plasticizing agents, covering agents, polish, gloss agents, polymers, powders, proteins, re-oiling agents, abrading agents, silicones, hair promotion agents, cooling agents, skin-cooling agents, warming agents, skin-warming agents, stabilizers, UV-absorbing agents, UV filters, detergents, thickeners, vitamins, oils, waxes, fats, phospholipids, saturated fatty acids, mono- or polyunsaturated fatty acids, a-hydroxy acids, polyhydroxyfatty acids, liquefiers, dyestuffs, colour-protecting agents, pigments, odoriferous substances, polyols, surfactants, electrolytes, organic solvents or silicone derivatives and the like as additional auxiliaries and additives.


Surfactants

Preferred auxiliaries and additives are anionic and/or amphoteric or zwitterionic surfactants. Non-ionic and cationic surfactants can be also present in the composition. Suitable examples are mentioned along with the paragraph dealing with emulsifiers.


Typical examples for anionic and zwitterionic surfactants encompass: Almondamidopropylamine Oxide, Almondamidopropyl Betaine, Aminopropyl Laurylglutamine, Ammonium C12-15 Alkyl Sulfate, Ammonium C12-16 Alkyl Sulfate, Ammonium Capryleth Sulfate, Ammonium Cocomonoglyceride Sulfate, Ammonium Coco-Sulfate, Ammonium Cocoyl Isethionate, Ammonium Cocoyl Sarcosinate, Ammonium C12-15 Pareth Sulfate, Ammonium C9-10 Perfluoroalkylsulfonate, Ammonium Dinonyl Sulfosuccinate, Ammonium Dodecylbenzenesulfonate, Ammonium Isostearate, Ammonium Laureth-6 Carboxylate, Ammonium Laureth-8 Carboxylate, Ammonium Laureth Sulfate, Ammonium Laureth-5 Sulfate, Ammonium Laureth-7 Sulfate, Ammonium Laureth-9 Sulfate, Ammonium Laureth-12 Sulfate, Ammonium Lauroyl Sarcosinate, Ammonium Lauryl Sulfate, Ammonium Lauryl Sulfosuccinate, Ammonium Myreth Sulfate, Ammonium Myristyl Sulfate, Ammonium Nonoxynol-4 Sulfate, Ammonium Nonoxynol-30 Sulfate, Ammonium Oleate, Ammonium Palm Kernel Sulfate, Ammonium Stearate, Ammonium Tallate, AMPD-Isostearoyl Hydrolyzed Collagen, AMPD-Rosin Hydrolyzed Collagen, AMP-Isostearoyl Hydrolyzed Collagen, AMP-Isostearoyl Hydrolyzed Keratin, AMP-Isostearoyl Hydrolyzed Soy Protein, AMP-Isostearoyl Hydrolyzed Wheat Protein, Apricotamidopropyl Betaine, Arachidic Acid, Arginine Hexyldecyl Phosphate, Avocadamidopropyl Betaine, Avocado Oil Glycereth-8 Esters, Babassu Acid, Babassuamidopropylamine Oxide, Babassuamidopropyl Betaine, Beeswax Acid, Behenamidopropyl Betaine, Behenamine Oxide, Beheneth-25, Beheneth-30, Behenic Acid, Behenyl Betaine, Bis- Butyldimethicone Polyglyceryl-3, Butoxynol-5 Carboxylic Acid, Butoxynol-19 Carboxylic Acid, Butyldimoniumhydroxypropyl Butylglucosides Chloride, Butyldimoniumhydroxypropyl Laurylglucosides Chloride, Butyl Glucoside, Butylglucoside Caprate, Butylglucosides Hydroxypropyltrimonium Chloride, Butyloctanoic Acid, C18-36 Acid, C20-40 Acid, C30-50 Acid, C16-22 Acid Amide MEA, Calcium Dodecylbenzenesulfonate, Calcium Lauroyl Taurate, C9-16 Alkane/Cycloalkane, C10-14 Alkyl Benzenesulfonic Acid, C12-14 Alkyl Diaminoethylglycine HCL, C9-15 Alkyl Phosphate, Candida Bombicola/Glucose/Methyl Rapeseedate Ferment, Canolamidopropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glucoside, Capryl/Capramidopropyl Betaine, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Caprylic Acid, Capryloyl Collagen Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids, Caprylyl/Capryl Glucoside, Caprylyl/Capryl Wheat Bran/Straw Glycosides, Caprylyl Glucoside, Caprylyl Glyceryl Ether, Caprylyl Pyrrolidone, Carnitine, Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Ceteareth-4 Phosphate, Ceteareth-5 Phosphate, Ceteareth-10 Phosphate, Ceteth-20, Ceteth-23, Ceteth24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Cetoleth-22, Cetoleth-24, Cetoleth-25, Cetoleth-30, Cetyl Betaine, Chrysanthemum Sinense Flower Extract, C12-14 Hydroxyalkyl Hydroxyethyl BetaAlanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidoethyl Betaine, Cocamidopropylamine Oxide, Cocamidopropyl Betainamide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid, Coceth-7 Carboxylic Acid, Coceth-4 Glucoside, Cocoamphodipropionic Acid, Cocobetainamido Amphopropionate, Coco-Betaine, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Coco-Glucoside, Cocoglucosides Hydroxypropyltrimonium Chloride, Coco-Hydroxysultaine, Coco-Morpholine Oxide, Coconut Acid, Coconut Oil Glycereth-8 Esters, Coco/Oleamidopropyl Betaine, Coco-Sultaine, Coco/Sunfloweramidopropyl Betaine, Cocoylcholine Methosulfate, Cocoyl Glutamic Acid, Cocoyl Hydrolyzed Collagen, Cocoyl Hydrolyzed Keratin, Cocoyl Hydrolyzed Oat Protein, Cocoyl Hydrolyzed Rice Protein, Cocoyl Hydrolyzed Silk, Cocoyl Hydrolyzed Soy Protein, Cocoyl Hydrolyzed Wheat Protein, Cocoyl Sarcosine, Corn Acid, Cottonseed Acid, Cottonseed Oil Glycereth-8 Esters, C10-16 Pareth-1, C10-16 Pareth-2, C11-13 Pareth-6, C11-13 Pareth-9, C11-13 Pareth-10, C11-15 Pareth-30, C11-15 Pareth-40, C12-13 Pareth-1, C12-13 Pareth- 23, C12-14 Pareth-5, C12-14 Pareth-9, C13-15 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 Carboxylic Acid, C9-11 Pareth-8 Carboxylic Acid, C11-15 Pareth-7 Carboxylic Acid, C12-13 Pareth-5 Carboxylic Acid, C12-13 Pareth-7 Carboxylic Acid, C12-13 Pareth-8 Carboxylic Acid, C12-13 Pareth-12 Carboxylic Acid, C12-15 Pareth-7 Carboxylic Acid, C12-15 Pareth-8 Carboxylic Acid, C12-15 Pareth- 12 Carboxylic Acid, C14-15 Pareth-8 Carboxylic Acid, C6-10 Pareth-4 Phosphate, C12-13 Pareth-2 Phosphate, C12-13 Pareth-10 Phosphate, C12-15 Pareth-6 Phosphate, C12-15 Pareth-8 Phosphate, C12-15 Pareth-10 Phosphate, C12-16 Pareth-6 Phosphate, C4-18 Perfluoroalkylethyl Thiohydroxypropyltrimonium Chloride, Cupuassuamidopropyl Betaine, DEA-C12-13 Alkyl Sulfate, DEA-C12-15 Alkyl Sulfate, DEA-Ceteareth-2 Phosphate, DEA-Cetyl Sulfate, DEA-Cocoamphodipropionate, DEA-C12-13 Pareth-3 Sulfate, DEACyclocarboxypropyloleate, DEA-Dodecylbenzenesulfonate, DEA-Isostearate, DEA-Laureth Sulfate, DEA-Lauryl Sulfate, DEA-Linoleate, DEA-Methyl Myristate Sulfonate, DEA-Myreth Sulfate, DEA-Myristate, DEA-Myristyl Sulfate, DEA-Oleth-5 Phosphate, DEA-Oleth-20 Phosphate, DEA PG-Oleate, Deceth-7 Carboxylic Acid, Deceth-7 Glucoside, Deceth-9 Phosphate, Decylamine Oxide, Decyl Betaine, Decyl Glucoside, Decyltetradeceth-30, Decyltetradecylamine Oxide, Diammonium Lauramido-MEA Sulfosuccinate, Diammonium Lauryl Sulfosuccinate, Diammonium Oleamido PEG-2 Sulfosuccinate, Dibutoxymethane, Di-CI 2-15 Pareth-2 Phosphate, Di-CI 2-15 Pareth-4 Phosphate, Di-CI 2-15 Pareth-6 Phosphate, Di-C12-15 Pareth-8 Phosphate, Di-CI 2-15 Pareth-10 Phosphate, Didodecyl Butanetetracarboxylate, Diethylamine Laureth Sulfate, Diethylhexyl Sodium Sulfosuccinate, Dihydroxyethyl C8-10 Alkoxypropylamine Oxide, Dihydroxyethyl C9-11 Alkoxypropylamine Oxide, Dihydroxyethyl C12-15 Alkoxypropylamine Oxide, Dihydroxyethyl Cocamine Oxide, Dihydroxyethyl Lauramine Oxide, Dihydroxyethyl Stearamine Oxide, Dihydroxyethyl Tallowamine Oxide, Dimethicone PEG-7 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG/PPG-7/4 Phosphate, Dimethicone PEG/PPG-12/4 Phosphate, Dimethicone/Polyglycerin-3 Crosspolymer, Dimethicone Propyl PG-Betaine, Dimyristyl Phosphate, Dioleoylamidoethyl Hydroxyethylmonium Methosulfate, DIPA-Hydrogenated Cocoate, DIPA-Lanolate, DIPA-Myristate, Dipotassium Capryloyl Glutamate, Dipotassium Lauryl Sulfosuccinate, Dipotassium Undecylenoyl Glutamate, Disodium Babassuamido MEA-Sulfosuccinate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Capryloyl Glutamate, Disodium Cetearyl Sulfosuccinate, Disodium Cetyl Phenyl Ether Disulfonate, Disodium Cetyl Sulfosuccinate, Disodium Cocamido MEASulfosuccinate, Disodium Cocamido MIPA PEG-4 Sulfosuccinate, Disodium Cocamido MIPASulfosuccinate, Disodium Cocamido PEG-3 Sulfosuccinate, Disodium Coceth-3 Sulfosuccinate, Disodium Cocoamphocarboxyethylhydroxypropylsulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Coco-Glucoside Sulfosuccinate, Disodium Coco-Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 Sulfosuccinate, Disodium Cocoyl Glutamate, Disodium C12-14 Pareth-1 Sulfosuccinate, Disodium C12-14 Pareth-2 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium C12-14 Sec-Pareth-3 Sulfosuccinate, Disodium C12-14 Sec-Pareth-5 Sulfosuccinate, Disodium C12-14 Sec-Pareth-7 Sulfosuccinate, Disodium C12-14 Sec-Pareth-9 Sulfosuccinate, Disodium C12-14 Sec-Pareth-12 Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosuccinate, Disodium Decyl Phenyl Ether Disulfonate, Disodium Dihydroxyethyl Sulfosuccinylundecylenate, Disodium Ethylene Dicocamide PEG-15 Disulfate, Disodium Hydrogenated Cottonseed Glyceride Sulfosuccinate, Disodium Hydrogenated Tallow Glutamate, Disodium Hydroxydecyl Sorbitol Citrate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamido MEA-Sulfosuccinate, Disodium Isostearamido MIPA-Sulfosuccinate, Disodium Isostearoamphodiacetate, Disodium Isostearoamphodipropionate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramido MEA-Sulfosuccinate, Disodium Lauramido MIPA Glycol Sulfosuccinate, Disodium Lauramido PEG-2 Sulfosuccinate, Disodium Lauramido PEG-5 Sulfosuccinate, Disodium Laureth-5 Carboxyamphodiacetate, Disodium Laureth-7 Citrate, Disodium Laureth Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lauriminobishydroxypropylsulfonate, Disodium Lauriminodiacetate, Disodium Lauriminodipropionate, Disodium Lauriminodipropionate Tocopheryl Phosphates, Disodium Lauroamphodiacetate, Disodium Lauroamphodipropionate, Disodium N-Lauroyl Aspartate, Disodium Lauroyl Glutamate, Disodium Lauryl Phenyl Ether Disulfonate, Disodium Lauryl Sulfosuccinate, Disodium Myristamido MEASulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamido MEA-Sulfosuccinate, Disodium Oleamido MIPA-Sulfosuccinate, Disodium Oleamido PEG-2 Sulfosuccinate, Disodium Oleoamphodipropionate, Disodium Oleth-3 Sulfosuccinate, Disodium Oleyl Phosphate, Disodium Oleyl Sulfosuccinate, Disodium Palmitamido PEG-2 Sulfosuccinate, Disodium Palmitoleamido PEG-2 Sulfosuccinate, Disodium PEG-4 Cocamido MIPA-Sulfosuccinate, Disodium PEG-12 Dimethicone Sulfosuccinate, Disodium PEG-8 Palm Glycerides Sulfosuccinate, Disodium PPG-2-Isodeceth-7 Carboxyamphodiacetate, Disodium Ricinoleamido MEA-Sulfosuccinate, Disodium Sitostereth-14 Sulfosuccinate, Disodium Soyamphodiacetate, Disodium Stearamido MEA-Sulfosuccinate, Disodium Steariminodipropionate, Disodium Stearoamphodiacetate, Disodium Stearoyl Glutamate, Disodium Stearyl Sulfosuccinamate, Disodium Stearyl Sulfosuccinate, Disodium 2-Sulfolaurate, Disodium 2-Sulfopalmitate, Disodium Tallamido MEA-Sulfosuccinate, Disodium Tallowamido MEA-Sulfosuccinate, Disodium Tallowamphodiacetate, Disodium Tallowiminodipropionate, Disodium Tallow Sulfosuccinamate, Disodium Tridecylsulfosuccinate, Disodium Undecylenamido MEA-Sulfosuccinate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Undecylenoyl Glutamate, Disodium Wheat Germamido MEA-Sulfosuccinate, Disodium Wheat Germamido PEG-2 Sulfosuccinate, Disodium Wheatgermamphodiacetate, Di-TEA-Cocamide Diacetate, Di-TEA-Oleamido PEG-2 Sulfosuccinate, Di-TEA-Palmitoyl Aspartate, Ditridecyl Sodium Sulfosuccinate, Dodecylbenzene Sulfonic Acid, Erucamidopropyl Hydroxysultaine, Ethylhexeth-3 Carboxylic Acid, Ethyl PEG-15 Cocamine Sulfate, Glyceryl Capryl Ether, Hexyldecanoic Acid, Hydrogenated Coconut Acid, Hydrogenated Laneth-25, Hydrogenated Menhaden Acid, Hydrogenated Palm Acid, Hydrogenated Palm Kernel Amine Oxide, Hydrogenated Tallow Acid, Hydrogenated Tallowamine Oxide, Hydrogenated Tallow Betaine, Hydrogenated Talloweth-25, Hydrogenated Tallowoyl Glutamic Acid, Hydrolyzed Candida Bombicola Extract, Hydroxyceteth-60, Hydroxyethyl Acetomonium PG-Dimethicone, Hydroxyethylbutylamine Laureth Sulfate, Hydroxyethyl Carboxymethyl Cocamidopropylamine, Hydroxyethyl Hydroxypropyl C12-15 Alkoxypropylamine Oxide, Hydroxylauryl/Hydroxymyristyl Betaine, Hydroxystearic Acid, Hydroxysuccinimidyl C10-40 Isoalkyl Acidate, Hydroxysuccinimidyl C21-22 Isoalkyl Acidate, Hydroxysultaines, IPDI/PEG-15 Soyamine Oxide Copolymer, IPDI/PEG-15 Soyethonium Ethosulfate Copolymer, IPDI/PEG-15 Soy Glycinate Copolymer, Isoceteth-30, Isolaureth-4 Phosphate, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropanolamine Lanolate, Isopropylamine Dodecylbenzenesulfonate, Isostearamidopropylamine Oxide, Isostearamidopropyl Betaine, Isostearamidopropyl Morpholine Oxide, Isosteareth-8, Isosteareth-16, Isosteareth-22, Isosteareth-25, Isosteareth-50, Isostearic Acid, Isostearoyl Hydrolyzed Collagen, Jojoba Oil PEG-150 Esters, Jojoba Wax PEG-80 Esters, Jojoba Wax PEG-120 Esters, Laneth-20, Laneth-25, Laneth-40, Laneth-50, Laneth-60, Laneth75, Lanolin Acid, Lauramidopropylamine Oxide, Lauramidopropyl Betaine, Lauramidopropyl Hydroxysultaine, Lauramine Oxide, Lauraminopropionic Acid, Laurdimoniumhydroxypropyl Decylglucosides Chloride, Laurdimoniumhydroxypropyl Laurylglucosides Chloride, Laureth16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-38, Laureth-40, Laureth-3 Carboxylic Acid, Laureth-4 Carboxylic Acid, Laureth-5 Carboxylic Acid, Laureth- 6 Carboxylic Acid, Laureth-8 Carboxylic Acid, Laureth-10 Carboxylic Acid, Laureth-11 Carboxylic Acid, Laureth-12 Carboxylic Acid, Laureth-13 Carboxylic Acid, Laureth-14 Carboxylic Acid, Laureth-17 Carboxylic Acid, Laureth-6 Citrate, Laureth-7 Citrate, Laureth-1 Phosphate, Laureth-2 Phosphate, Laureth-3 Phosphate, Laureth-4 Phosphate, Laureth-7 Phosphate, Laureth8 Phosphate, Laureth-7 Tartrate, Laurie Acid, Laurimino Bispropanediol, Lauriminodipropionic Acid, Lauroamphodipropionic Acid, Lauroyl Beta-Alanine, Lauroyl Collagen Amino Acids, Lauroyl Ethyltrimonium Methosulfate, Lauroyl Hydrolyzed Collagen, Lauroyl Hydrolyzed Elastin, Lauroyl Methyl Glucamide, Lauroyl Sarcosine, Lauroyl Silk Amino Acids, Lauryl Betaine, Lauryl Dimethicone/Polyglycerin-3 Crosspolymer, Lauryldimoniumhydroxypropyl Cocoglucosides Chloride, Lauryl Glucoside, Laurylglucosides Hydroxypropyltrimonium Chloride, Lauryl Glycol Hydroxypropyl Ether, Lauryl Hydroxysultaine, Lauryl Malamide, Lauryl Methylglucamide, Lauryl/Myristyl Glycol Hydroxypropyl Ether, Lauryl/Myristyl Wheat Bran/Straw Glycosides, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Pyrrolidone, Lauryl Sultaine, Linoleic Acid, Linolenic Acid, Linseed Acid, Lysine Cocoate, Macadamia Seed Oil Glycereth-8 Esters, Magnesium Coceth Sulfate, Magnesium Coco-Sulfate, Magnesium Isododecylbenzenesulfonate, Magnesium Laureth-11 Carboxylate, Magnesium Laureth Sulfate, Magnesium Laureth-5 Sulfate, Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfonate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myreth Sulfate, Magnesium Oleth Sulfate, Magnesium/TEA-Coco-Sulfate, Manicouagan Clay, MEA-Cocoate, MEA-Laureth-6 Carboxylate, MEA- Laureth Sulfate, MEA-Lauryl Sulfate, MEA PPG-6 Laureth-7 Carboxylate, MEA-PPG-8-Steareth-7 Carboxylate, MEA-Undecylenate, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, Methoxy PEG-450 Amidoglutaroyl Succinimide, Methoxy PEG-450 Amido Hydroxysuccinimidyl Succinamate, Methoxy PEG-450 Maleimide, Methyl Morpholine Oxide, Milkamidopropyl Amine Oxide, Milkamidopropyl Betaine, Minkamidopropylamine Oxide, Minkamidopropyl Betaine, MIPA C12-15 Pareth Sulfate, MIPA-Dodecylbenzenesulfonate, MIPA-Laureth Sulfate, MIPALauryl Sulfate, Mixed Isopropanolamines Lanolate, Mixed Isopropanolamines Lauryl Sulfate, Mixed Isopropanolamines Myristate, Morpholine Oleate, Morpholine Stearate, Myreth-3 Carboxylic Acid, Myreth-5 Carboxylic Acid, Myristalkonium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myristamine Oxide, Myristaminopropionic Acid, Myristic Acid, Myristoyl Ethyltrimonium Methosulfate, Myristoyl Glutamic Acid, Myristoyl Hydrolyzed Collagen, Myristoyl Sarcosine, Myristyl Betaine, Myristyl/Cetyl Amine Oxide, Myristyldimoniumhydroxypropyl Cocoglucosides Chloride, Myristyl Glucoside, Myristyl Phosphate, Nonoxynol-20, Nonoxynol-23, Nonoxynol-25, Nonoxynol-30, Nonoxynol-35, Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 Carboxylic Acid, Nonoxynol-8 Carboxylic Acid, Nonoxynol-10 Carboxylic Acid, Nonoxynol-3 Phosphate, Nonoxynol-4 Phosphate, Nonoxynol-6 Phosphate, Nonoxynol-9 Phosphate, Nonoxynol-10 Phosphate, Nonyl Nonoxynol-30, Nonyl Nonoxynol-49, Nonyl Nonoxynol-100, Nonyl Nonoxynol-150, Nonyl Nonoxynol-7 Phosphate, Nonyl Nonoxynol-8 Phosphate, Nonyl Nonoxynol-9 Phosphate, Nonyl Nonoxynol-10 Phosphate, Nonyl Nonoxynol-11 Phosphate, Nonyl Nonoxynol-15 Phosphate, Nonyl Nonoxynol-24 Phosphate, Oatamidopropyl Betaine, Octoxynol-16, Octoxynol-25, Octoxynol-30, Octoxynol-33, Octoxynol-40, Octoxynol-70, Octoxynol-20 Carboxylic Acid, Octyldodeceth-20, Octyldodeceth-25, Octyldodeceth-30, Oleamidopropylamine Oxide, Oleamidopropyl Betaine, Oleamidopropyl Hydroxysultaine, Oleamine Oxide, Oleic Acid, Oleoyl Hydrolyzed Collagen, Oleoyl Sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleth-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Olivamidopropylamine Oxide, Olivamidopropyl Betaine, Olive Acid, Olivoyl Hydrolyzed Wheat Protein, Ophiopogon Extract Stearate, Ozonized Oleth-10, Ozonized PEG-10 Oleate, Ozonized PEG-14 Oleate, Ozonized Polysorbate 80, Palm Acid, Palmamidopropyl Betaine, Palmeth-2 Phosphate, Palmitamidopropylamine Oxide, Palmitamidopropyl Betaine, Palmitamine Oxide, Palmitic Acid, Palmitoyl Collagen Amino Acids, Palmitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Milk Protein, Palmitoyl Hydrolyzed Wheat Protein, Palmitoyl Keratin Amino Acids, Palmitoyl Oligopeptide, Palmitoyl Silk Amino Acids, Palm Kernel Acid, Palm Kernelamidopropyl Betaine, Peach Kernel Oil Glycereth-8 Esters, Peanut Acid, PEG-10 Castor Oil, PEG-40 Castor Oil, PEG-44 Castor Oil, PEG-50 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibehenate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soyate, PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tallowate, PEG-80 Glyceryl Tallowate, PEG-82 Glyceryl Tallowate, PEG-130 Glyceryl Tallowate, PEG-200 Glyceryl Tallowate, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG54 Hydrogenated Castor Oil, PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin, PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG- 26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG- 70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glycerides, PEG-20 Mannitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG120 Methyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanate, PEG-30 Oleamine, PEG-20 Oleate, PEG-23 Oleate, PEG-32 Oleate, PEG-36 Oleate, PEG-75 Oleate, PEG-150 Oleate, PEG-20 Palmitate, PEG-150 Polyglyceryl-2 Tristearate, PEG/PPG-28/21 Acetate Dimethicone, PEG/PPG-24/18 Butyl Ether Dimethicone, PEG/PPG-3/17 Copolymer, PEG/PPG-5/35 Copolymer, PEG/PPG-8/55 Copolymer, PEG/PPG10/30 Copolymer, PEG/PPG-10/65 Copolymer, PEG/PPG-12/35 Copolymer, PEG/PPG-16/17 Copolymer, PEG/PPG-20/9 Copolymer, PEG/PPG-20/20 Copolymer, PEG/PPG-20/60 Copolymer, PEG/PPG- 20/65 Copolymer, PEG/PPG-22/25 Copolymer, PEG/PPG-28/30 Copolymer, PEG/PPG-30-35 Copolymer, PEG/PPG-30/55 Copolymer, PEG/PPG-35/40 Copolymer, PEG/PPG-50/40 Copolymer, PEG/PPG-150/35 Copolymer, PEG/PPG-160/30 Copolymer, PEG/PPG-190/60 Copolymer, PEG/PPG-200/40 Copolymer, PEG/PPG-300/55 Copolymer, PEG/PPG-20/22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG/PPG-4/2 Propylheptyl Ether, PEG/PPG-6/2 Propylheptyl Ether, PEG-7/PPG-2 Propylheptyl Ether, PEG/PPG-8/2 Propylheptyl Ether, PEG/PPG- 10/2 Propylheptyl Ether, PEG/PPG-14/2 Propylheptyl Ether, PEG/PPG-40/2 Propylheptyl Ether, PEG/PPG-10/2 Ricinoleate, PEG/PPG-32/3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEGRapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glycerides, PEG-75 Shorea Butter Glycerides, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-10 44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearamide Carboxylic Acid, PEG-9 Stearamide Carboxylic Acid, PEG-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG-50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG- 120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallate, PEG-50 Tallow Amide, PEG-2 Tallowamide DEA, PEG-20 Tallowate, PEG-66 Trihydroxystearin, PEG-200 Trihydroxystearin, PEG-60 Tsubakiate Glycerides, Pelargonic Acid, Pentadoxynol-200, Pheneth-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288, Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG/PPG-24/19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium- 82, Pomaderris Kumerahou Flower/Leaf Extract, Poria Cocos Extract, Potassium Abietoyl Hydrolyzed Collagen, Potassium Babassuate, Potassium Behenate, Potassium C9-15 Alkyl Phosphate, Potassium C11-15 Alkyl Phosphate, Potassium C12-13 Alkyl Phosphate, Potassium C12-14 Alkyl Phosphate, Potassium Caprate, Potassium Capryloyl Glutamate, Potassium Capryloyl Hydrolyzed Rice Protein, Potassium Castorate, Potassium Cocoate, Potassium Cocoyl Glutamate, Potassium Cocoyl Glycinate, Potassium Cocoyl Hydrolyzed Casein, Potassium Cocoyl Hydrolyzed Collagen, Potassium Cocoyl Hydrolyzed Corn Protein, Potassium Cocoyl Hydrolyzed Keratin, Potassium Cocoyl Hydrolyzed Oat Protein, Potassium Cocoyl Hydrolyzed Potato Protein, Potassium Cocoyl Hydrolyzed Rice Bran Protein, Potassium Cocoyl Hydrolyzed Rice Protein, Potassium Cocoyl Hydrolyzed Silk, Potassium Cocoyl Hydrolyzed Soy Protein, Potassium Cocoyl Hydrolyzed Wheat Protein, Potassium Cocoyl Hydrolyzed Yeast Protein, Potassium Cocoyl PCA, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Cornate, Potassium Cyclocarboxypropyloleate, Potassium Dihydroxyethyl Cocamine Oxide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecylbenzenesulfonate, Potassium Hempseedate, Potassium Hydrogenated Cocoate, Potassium Hydrogenated Palmate, Potassium Hydrogenated Tallowate, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolate, Potassium Laurate, Potassium Laureth-3 Carboxylate, Potassium Laureth-4 Carboxylate, Potassium Laureth-5 Carboxylate, Potassium Laureth-6 Carboxylate, Potassium Laureth-10 Carboxylate, Potassium Laureth Phosphate, Potassium Lauroyl Collagen Amino Acids, Potassium Lauroyl Glutamate, Potassium Lauroyl Hydrolyzed Collagen, Potassium Lauroyl Hydrolyzed Pea Protein, Potassium Lauroyl Hydrolyzed Soy Protein, Potassium Lauroyl PCA, Potassium Lauroyl Pea Amino Acids, Potassium Lauroyl Sarcosinate, Potassium Lauroyl Silk Amino Acids, Potassium Lauroyl Wheat Amino Acids, Potassium Lauryl Phosphate, Potassium Lauryl Sulfate, Potassium Linoleate, Potassium Metaphosphate, Potassium Methyl Cocoyl Taurate, Potassium Myristate, Potassium Myristoyl Glutamate, Potassium Myristoyl Hydrolyzed Collagen, Potassium Octoxynol-12 Phosphate, Potassium Oleate, Potassium Oleoyl Hydrolyzed Collagen, Potassium Olivate, Potassium Olivoyl Hydrolyzed Oat Protein, Potassium Olivoyl Hydrolyzed Wheat Protein, Potassium Olivoyl/Lauroyl Wheat Amino Acids, Potassium Olivoyl PCA, Potassium Palmate, Potassium Palmitate, Potassium Palmitoyl Hydrolyzed Corn Protein, Potassium Palmitoyl Hydrolyzed Oat Protein, Potassium Palmitoyl Hydrolyzed Rice Protein, Potassium Palmitoyl Hydrolyzed Sweet Almond Protein, Potassium Palmitoyl Hydrolyzed Wheat Protein, Potassium Palm Kernelate, Potassium Peanutate, Potassium Rapeseedate, Potassium Ricinoleate, Potassium Safflowerate, Potassium Soyate, Potassium Stearate, Potassium Stearoyl Hydrolyzed Collagen, Potassium Tallate, Potassium Tallowate, Potassium Taurate, Potassium Taurine Laurate, Potassium Trideceth-3 Carboxylate, Potassium Trideceth-4 Carboxylate, Potassium Trideceth-7 Carboxylate, Potassium Trideceth-15 Carboxylate, Potassium Trideceth-19 Carboxylate, Potassium Trideceth-6 Phosphate, Potassium Trideceth-7 Phosphate, Potassium Tsubakiate, Potassium Undecylenate, Potassium Undecylenoyl Hydrolyzed Collagen, Potassium Undecylenoyl Hydrolyzed Rice Protein, PPG-30- Buteth-30, PPG-36-Buteth36, PPG-38-Buteth-37, PPG-30-Capryleth-4 Phosphate, PPG-10 Cetyl Ether Phosphate, PPG-2 C9-11 Pareth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylic Acid, PPG-30 Ethylhexeth-4 Phosphate, PPG-20-Glycereth-30, PPG-2 Hydroxyethyl Coco/Isostearamide, PPG-2-Isodeceth-8, PPG-2-Isodeceth-10, PPG-2-Isodeceth-18, PPG-2-Isodeceth-25, PPG-4-Isodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Acid, Rice Bran Acid, Rice Oil Glycereth-8 Esters, Ricinoleamidopropyl Betaine, Ricinoleic Acid, Ricinoleth-40, Safflower Acid, Sapindus Oahuensis Fruit Extract, Saponaria Officinalis Root Powder, Saponins, Sekken-K, Sekken-Na/K, Sekken Soji, Sekken Soji-K, Sesame Oil Glycereth-8 Esters, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butteramidopropyl Betaine, Shea Butter Glycereth-8 Esters, Sodium Arachidate, Sodium Arganampohoacetate, Sodium Astrocaryum Murumuruate, Sodium Avocadoate, Sodium Babassuamphoacetate, Sodium Babassuate, Sodium Babassu Sulfate, Sodium Behenate, Sodium Bisglycol Ricinosulfosuccinate, Sodium Bis- Hydroxyethylglycinate Coco-Glucosides Crosspolymer, Sodium Bis-Hydroxyethylglycinate Lauryl-Glucosides Crosspolymer, Sodium Borageamidopropyl PG-Dimonium Chloride Phosphate, Sodium Butoxynol-12 Sulfate, Sodium Butylglucosides Hydroxypropyl Phosphate, Sodium C13-17 Alkane Sulfonate, Sodium C14-18 Alkane Sulfonate, Sodium C12-15 Alkoxypropyl Iminodipropionate, Sodium C10-16 Alkyl Sulfate, Sodium C11-15 Alkyl Sulfate, Sodium C12-13 Alkyl Sulfate, Sodium C12-15 Alkyl Sulfate, Sodium C12-18 Alkyl Sulfate, Sodium C16-20 Alkyl Sulfate, Sodium C9-22 Alkyl Sec Sulfonate, Sodium C14-17 Alkyl Sec Sulfonate, Sodium Caprate, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropylsulfonate, Sodium Caproamphopropionate, Sodium Caproyl Methyltaurate, Sodium Caprylate, Sodium Capryleth-2 Carboxylate, Sodium Capryleth-9 Carboxylate, Sodium Capryloamphoacetate, Sodium Capryloamphohydroxypropylsulfonate, Sodium Capryloamphopropionate, Sodium Capryloyl Glutamate, Sodium Capryloyl Hydrolyzed Wheat Protein, Sodium Caprylyl PG-Sulfonate, Sodium Caprylyl Sulfonate, Sodium Castorate, Sodium Ceteareth-13 Carboxylate, Sodium Cetearyl Sulfate, Sodium Ceteth-13 Carboxylate, Sodium Cetyl Sulfate, Sodium Cocamidopropyl PG-Dimonium Chloride Phosphate, Sodium Cocaminopropionate, Sodium Coceth Sulfate, Sodium Coceth-30 Sulfate, Sodium Cocoabutteramphoacetate, Sodium Cocoa Butterate, Sodium Cocoamphoacetate, Sodium Cocoamphohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cocoate, Sodium Coco/Babassu/Andiroba Sulfate, Sodium Coco/Babassu Sulfate, Sodium Cocoglucosides Hydroxypropyl Phosphate, Sodium Cocoglucosides Hydroxypropylsulfonate, Sodium CocoGlucoside Tartrate, Sodium Cocoglyceryl Ether Sulfonate, Sodium Coco/Hydrogenated Tallow Sulfate, Sodium Cocoiminodiacetate, Sodium Cocomonoglyceride Sulfate, Sodium Cocomonoglyceride Sulfonate, Sodium Coco PG-Dimonium Chloride Phosphate, Sodium CocoSulfate, Sodium Coco Sulfoacetate, Sodium Cocoyl Alaninate, Sodium Cocoyl Amino Acids, Sodium Cocoyl Collagen Amino Acids, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutaminate, Sodium Cocoyl Glycinate, Sodium Cocoyl/Hydrogenated Tallow Glutamate, Sodium Cocoyl Hydrolyzed Collagen, Sodium Cocoyl Hydrolyzed Keratin, Sodium Cocoyl Hydrolyzed Rice Protein, Sodium Cocoyl Hydrolyzed Silk, Sodium Cocoyl Hydrolyzed Soy Protein, Sodium Cocoyl Hydrolyzed Sweet Almond Protein, Sodium Cocoyl Hydrolyzed Wheat Protein, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Isethionate, Sodium Cocoyl Methylaminopropionate, Sodium Cocoyl Oat Amino Acids, Sodium Cocoyl/Palmoyl/Sunfloweroyl Glutamate, Sodium Cocoyl Proline, Sodium Cocoyl Sarcosinate, Sodium Cocoyl Taurate, Sodium Cocoyl Threoninate, Sodium Cocoyl Wheat Amino Acids, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium Cornamphopropionate, Sodium Cottonseedamphoacetate, Sodium C13-15 Pareth-8 Butyl Phosphate, Sodium C9-11 Pareth-6 Carboxylate, Sodium C11-15 Pareth-7 Carboxylate, Sodium C12-13 Pareth-5 Carboxylate, Sodium C12-13 Pareth-8 Carboxylate, Sodium C12-13 Pareth-12 Carboxylate, Sodium C12-15 Pareth-6 Carboxylate, Sodium C12-15 Pareth-7 Carboxylate, Sodium C12-15 Pareth-8 Carboxylate, Sodium C14-15 Pareth-8 Carboxylate, Sodium C12-14 Sec-Pareth-8 Carboxylate, Sodium C14-15 Pareth-PG Sulfonate, Sodium C12-13 Pareth-2 Phosphate, Sodium C13-15 Pareth-8 Phosphate, Sodium C9-15 Pareth-3 Sulfate, Sodium C10-15 Pareth Sulfate, Sodium C10-16 Pareth-2 Sulfate, Sodium C12-13 Pareth Sulfate, Sodium C12-15 Pareth Sulfate, Sodium C12-15 Pareth-3 Sulfate, Sodium C13-15 Pareth-3 Sulfate, Sodium C12-14 Sec-Pareth-3 Sulfate, Sodium C12-15 Pareth-3 Sulfonate, Sodium C12-15 Pareth-7 Sulfonate, Sodium C1215 Pareth-15 Sulfonate, Sodium Deceth-2 Carboxylate, Sodium Deceth Sulfate, Sodium Decylbenzenesulfonate, Sodium Decylglucosides Hydroxypropyl Phosphate, Sodium Decylglucosides Hydroxypropylsulfonate, Sodium Dilaureth-7 Citrate, Sodium Dilaureth-10 Phosphate, Sodium Dilinoleamidopropyl PG-Dimonium Chloride Phosphate, Sodium Dilinoleate, Sodium Dioleth-8 Phosphate, Sodium Dodecylbenzenesulfonate, Sodium Ethyl 2-Sulfolaurate, Sodium Glyceryl Oleate Phosphate, Sodium Grapeseedamidopropyl PG-Dimonium Chloride Phosphate, Sodium Grapeseedamphoacetate, Sodium Grapeseedate, Sodium Hempseedamphoacetate, Sodium Hexeth-4 Carboxylate, Sodium Hydrogenated Cocoate, Sodium Hydrogenated Cocoyl Methyl Isethionate, Sodium Hydrogenated Palmate, Sodium Hydrogenated Tallowate, Sodium Hydrogenated Tallowoyl Glutamate, Sodium Hydroxylauryldimonium Ethyl Phosphate, Sodium Hydroxypropyl Palm Kernelate Sulfonate, Sodium Hydroxypropylphosphate Decylglucoside Crosspolymer, Sodium Hydroxypropylphosphate Laurylglucoside Crosspolymer, Sodium Hydroxypropylsulfonate Cocoglucoside Crosspolymer, Sodium Hydroxypropylsulfonate Decylglucoside Crosspolymer, Sodium Hydroxypropylsulfonate Laurylglucoside Crosspolymer, Sodium Hydroxystearate, Sodium Isostearate, Sodium Isosteareth-6 Carboxylate, Sodium Isosteareth-11 Carboxylate, Sodium Isostearoamphoacetate, Sodium Isostearoamphopropionate, Sodium N-Isostearoyl Methyltaurate, Sodium Laneth Sulfate, Sodium Lanolate, Sodium Lardate, Sodium Lauramido Diacetate, Sodium Lauraminopropionate, Sodium Laurate, Sodium Laureth-3 Carboxylate, Sodium Laureth-4 Carboxylate, Sodium Laureth-5 Carboxylate, Sodium Laureth-6 Carboxylate, Sodium Laureth-8 Carboxylate, Sodium Laureth-11 Carboxylate, Sodium Laureth-12 Carboxylate, Sodium Laureth-13 Carboxylate, Sodium Laureth-14 Carboxylate, Sodium Laureth-16 Carboxylate, Sodium Laureth-17 Carboxylate, Sodium Laureth Sulfate, Sodium Laureth-5 Sulfate, Sodium Laureth-7 Sulfate, Sodium Laureth-8 Sulfate, Sodium Laureth-12 Sulfate, Sodium Laureth-40 Sulfate, Sodium Laureth-7 Tartrate, Sodium Lauriminodipropionate, Sodium Lauroamphoacetate, Sodium Lauroamphohydroxypropylsulfonate, Sodium Lauroampho PG-Acetate Phosphate, Sodium Lauroamphopropionate, Sodium Lauroyl Aspartate, Sodium Lauroyl Collagen Amino Acids, Sodium Lauroyl Glycine Propionate, Sodium Lauroyl Hydrolyzed Collagen, Sodium Lauroyl Hydrolyzed Silk, Sodium Lauroyl Hydroxypropyl Sulfonate, Sodium Lauroyl Isethionate, Sodium Lauroyl Methylaminopropionate, Sodium Lauroyl Methyl Isethionate, Sodium Lauroyl Millet Amino Acids, Sodium Lauroyl/Myristoyl Aspartate, Sodium Lauroyl Oat Amino Acids, Sodium Lauroyl Sarcosinate, Sodium Lauroyl Silk Amino Acids, Sodium Lauroyl Taurate, Sodium Lauroyl Wheat Amino Acids, Sodium Lauryl Diethylenediaminoglycinate, Sodium Lauryl Glucose Carboxylate, Sodium Laurylglucosides Hydroxypropyl Phosphate, Sodium Laurylglucosides Hydroxypropylsulfonate, Sodium Lauryl Glycol Carboxylate, Sodium Lauryl Hydroxyacetamide Sulfate, Sodium Lauryl Phosphate, Sodium Lauryl Sulfate, Sodium Lauryl Sulfoacetate, Sodium Linoleate, Sodium Macadamiaseedate, Sodium Mangoamphoacetate, Sodium Mangoseedate, Sodium/MEA Laureth-2 Sulfosuccinate, Sodium Methoxy PPG-2 Acetate, Sodium Methyl Cocoyl Taurate, Sodium Methyl Lauroyl Taurate, Sodium Methyl Myristoyl Taurate, Sodium Methyl Oleoyl Taurate, Sodium Methyl Palmitoyl Taurate, Sodium Methyl Stearoyl Taurate, Sodium Methyl 2-Sulfolaurate, Sodium Methyl 2-Sulfopalmitate, Sodium Methyltaurate Isopalmitamide, Sodium Methyltaurine Cocoyl Methyltaurate, Sodium Myreth Sulfate, Sodium Myristate, Sodium Myristoamphoacetate, Sodium Myristoyl Glutamate, Sodium Myristoyl Hydrolyzed Collagen, Sodium Myristoyl Isethionate, Sodium Myristoyl Sarcosinate, Sodium Myristyl Sulfate, Sodium Nonoxynol-6 Phosphate, Sodium Nonoxynol-9 Phosphate, Sodium Nonoxynol-1 Sulfate, Sodium Nonoxynol-3 Sulfate, Sodium Nonoxynol-4 Sulfate, Sodium Nonoxynol-6 Sulfate, Sodium Nonoxynol-8 Sulfate, Sodium Nonoxynol-10 Sulfate, Sodium Nonoxynol-25 Sulfate, Sodium Octoxynol-2 Ethane Sulfonate, Sodium Octoxynol-2 Sulfate, Sodium Octoxynol-6 Sulfate, Sodium Octoxynol-9 Sulfate, Sodium Oleate, Sodium Oleoamphoacetate, Sodium Oleoamphohydroxypropylsulfonate, Sodium Oleoamphopropionate, Sodium Oleoyl Hydrolyzed Collagen, Sodium Oleoyl Isethionate, Sodium Oleth Sulfate, Sodium Oleyl Methyl Isethionate, Sodium Oleyl Sulfate, Sodium Olivamphoacetate, Sodium Olivate, Sodium Olivoyl Glutamate, Sodium Palmamphoacetate, Sodium Palmate, Sodium Palm Glyceride Sulfonate, Sodium Palmitate, Sodium Palmitoyl Hydrolyzed Collagen, Sodium Palmitoyl Hydrolyzed Wheat Protein, Sodium Palmitoyl Sarcosinate, Sodium Palm Kernelate, Sodium Palm Kerneloyl Isethionate, Sodium Palmoyl Glutamate, Sodium Passiflora Edulis Seedate, Sodium Peanutamphoacetate, Sodium Peanutate, Sodium PEG-6 Cocamide Carboxylate, Sodium PEG-8 Cocamide Carboxylate, Sodium PEG-4 Cocamide Sulfate, Sodium PEG-3 Lauramide Carboxylate, Sodium PEG-4 Lauramide Carboxylate, Sodium PEG-8 Palm Glycerides Carboxylate, Sodium Pentaerythrityl Hydroxypropyl Iminodiacetate Dendrimer, Sodium Propoxy PPG-2 Acetate, Sodium Rapeseedate, Sodium Ricebranamphoacetate, Sodium Ricinoleate, Sodium Ricinoleoamphoacetate, Sodium Rose Hipsamphoacetate, Sodium Rosinate, Sodium Safflowerate, Sodium Saffloweroyl Hydrolyzed Soy Protein, Sodium Sesameseedate, Sodium Sesamphoacetate, Sodium Sheabutteramphoacetate, Sodium Soyate, Sodium Soy Hydrolyzed Collagen, Sodium Stearate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Stearoyl Casein, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl Hydrolyzed Silk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Lactalbumin, Sodium Stearoyl Methyl Isethionate, Sodium Stearoyl Oat Protein, Sodium Stearoyl Pea Protein, Sodium Stearoyl Soy Protein, Sodium Stearyl Dimethyl Glycine, Sodium Stearyl Sulfate, Sodium Sunflowerseedamphoacetate, Sodium Surfactin, Sodium Sweetalmondamphoacetate, Sodium Sweet Almondate, Sodium Tallamphopropionate, Sodium Tallate, Sodium Tallowamphoacetate, Sodium Tallowate, Sodium Tallow Sulfate, Sodium Tamanuseedate, Sodium Taurate, Sodium Taurine Cocoyl Methyltaurate, Sodium Taurine Laurate, Sodium/TEA-Lauroyl Collagen Amino Acids, Sodium/TEA-Lauroyl Hydrolyzed Collagen, Sodium/TEA-Lauroyl Hydrolyzed Keratin, Sodium/TEA-Lauroyl Keratin Amino Acids, Sodium/TEA-Undecylenoyl Collagen Amino Acids, Sodium/TEA-Undecylenoyl Hydrolyzed Collagen, Sodium/TEA-Undecylenoyl Hydrolyzed Corn Protein, Sodium/TE-AUndecylenoyl Hydrolyzed Soy Protein, Sodium/TEA-Undecylenoyl Hydrolyzed Wheat Protein, Sodium Theobroma Grandiflorum Seedate, Sodium Trideceth-3 Carboxylate, Sodium Trideceth-4 Carboxylate, Sodium Trideceth-6 Carboxylate, Sodium Trideceth-7 Carboxylate, Sodium Trideceth-8 Carboxylate, Sodium Trideceth-12 Carboxylate, Sodium Trideceth-15 Carboxylate, Sodium Trideceth-19 Carboxylate, Sodium Trideceth Sulfate, Sodium Tridecylbenzenesulfonate, Sodium Tridecyl Sulfate, Sodium Trimethylolpropane Hydroxypropyl Iminodiacetate Dendrimer, Sodium Undeceth-5 Carboxylate, Sodium Undecylenate, Sodium Undecylenoamphoacetate, Sodium Undecylenoamphopropionate, Sodium Undecylenoyl Glutamate, Sodium Wheat Germamphoacetate, Sorbeth-160 Tristearate, Soy Acid, Soyamidopropylamine Oxide, Soyamidopropyl Betaine, Soybean Oil Glycereth-8 Esters, Stearamidopropylamine Oxide, Stearamidopropyl Betaine, Stearamine Oxide, Steareth-15, Steareth-16, Steareth20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth- 40, Steareth-50, Steareth80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyltrimonium Chloride, Stearoyl Glutamic Acid, Stearoyl Sarcosine, Stearyl Betaine, Stearyldimoniumhydroxypropyl Butylglucosides Chloride, Stearyldimoniumhydroxypropyl Decylglucosides Chloride, Stearyldimoniumhydroxypropyl Laurylglucosides Chloride, Sulfated Castor Oil, Sulfated Coconut Oil, Sulfated Glyceryl Oleate, Sulfated Olive Oil, Sulfated Peanut Oil, Sunfloweramide MEA, Sunflower Seed Acid, Sunflowerseedamidopropyl Hydroxyethyldimonium Chloride, Sunflower Seed Oil Glycereth-8 Esters, Tall Oil Acid, Tallow Acid, Tallowamidopropylamine Oxide, Tallowamidopropyl Betaine, Tallowamidopropyl Hydroxysultaine, Tallowamine Oxide, Tallow Betaine, Tallow Dihydroxyethyl Betaine, Tallowoyl Ethyl Glucoside, TEA-Abietoyl Hydrolyzed Collagen, TEA-C12-14 Alkyl Phosphate, TEA-C10-15 Alkyl Sulfate, TEA-C11-15 Alkyl Sulfate, TEA-C12-13 Alkyl Sulfate, TEA-C12-14 Alkyl Sulfate, TEAC12-15 Alkyl Sulfate, TEA C14-17 Alkyl Sec Sulfonate, TEA-Canolate, TEA-Cocamide Diacetate, TEA-Cocoate, TEA-Coco-Sulfate, TEA-Cocoyl Alaninate, TEA-Cocoyl Glutamate, TEACocoyl Glutaminate, TEA-Cocoyl Glycinate, TEA-Cocoyl Hydrolyzed Collagen, TEA-Cocoyl Hydrolyzed Soy Protein, TEA-Cocoyl Sarcosinate, TEA-Dimethicone PEG-7 Phosphate, TEA-Dodecylbenzenesulfonate, TEA-Hydrogenated Cocoate, TEA-Hydrogenated Tallowoyl Glutamate, TEA-Isostearate, TEA-Isostearoyl Hydrolyzed Collagen, TEA-Lauraminopropionate, TEA-Laurate, TEA-Laurate/Myristate, TEA-Laureth Sulfate, TEA-Lauroyl Collagen Amino Acids, TEA-Lauroyl Glutamate, TEA-Lauroyl Hydrolyzed Collagen, TEA-Lauroyl Keratin Amino Acids, TEA-Lauroyl Methylaminopropionate, TEA-Lauroyl/Myristoyl Aspartate, TEA-Lauroyl Sarcosinate, TEA-Lauryl Phosphate, TEA-Lauryl Sulfate, TEA-Myristaminopropionate, TEAMyristate, TEA-Myristoyl Hydrolyzed Collagen, TEA-Oleate, TEA-Oleoyl Hydrolyzed Collagen, TEA-Oleoyl Sarcosinate, TEA-Oleyl Sulfate, TEA-Palmitate, TEA-Palm Kernel Sarcosinate, TEAPEG-3 Cocamide Sulfate, TEA-Rosinate, TEA-Stearate, TEA-Tallate, TEA-T ridecylbenzenesulfonate, TEA-Undecylenate, TEA-Undecylenoyl Hydrolyzed Collagen, Tetramethyl Decynediol, Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate, TIPA-Laureth Sulfate, TIPA-Lauryl Sulfate, TIPA-Myristate, TIPA-Stearate, Tocopheryl Phosphate, Trehalose Undecylenoate, TMC12-15 Pareth-2 Phosphate, TM-C12-15 Pareth-6 Phosphate, TM-C12-15 Pareth-8 Phosphate, TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Trideceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate, Tridecylbenzenesulfonic Acid, Trilaureth-9 Citrate, Trimethylolpropane Hydroxypropyl BisHydroxyethylamine Dendrimer, Trisodium Lauroampho PG-Acetate Chloride Phosphate, Undecanoic Acid, Undeceth-5 Carboxylic Acid, Undecylenamidopropylamine Oxide, Undecylenamidopropyl Betaine, Undecylenic Acid, Undecylenoyl Collagen Amino Acids, Undecylenoyl Glycine, Undecylenoyl Hydrolyzed Collagen, Undecylenoyl Wheat Amino Acids, Undecyl Glucoside, Wheat Germ Acid, Wheat Germamidopropylamine Oxide, Wheat Germamidopropyl Betaine, Yucca Schidigera Leaf/Root/Stem Extract, Yucca Schidigera Stem Extract, Zinc Coceth Sulfatea and Zinc Coco-Sulfate.


Preferred are one or more compounds selected from the group consisting of Sodium Laureth Sulfate, Cocamidopropyl Betaine, Sodium Cocoamphoacetate, CocoGlucoside and Ammonium Lauryl Sulfosuccinate.


The percentage content of surfactants in the preparations may be from 0.1 to 10% by weight and is preferably from 0.5 to 5% by weight, based on the preparation.


Oil Bodies

Suitable oil bodies, which form constituents of the O/W emulsions, are, for example, Guerbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of linear C6-C22-fatty acids with linear or branched C6-C22-fatty alcohols or esters of branched C6-C13-carboxylic acids with linear or branched C6-C22-fatty alcohols, such as, for example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate. Also suitable are esters of linear C6-C22-fatty acids with branched alcohols, in particular 2-ethylhexanol, esters of C18-C38-alkylhydroxy carboxylic acids with linear or branched C6-C22-fatty alcohols, in particular Dioctyl Malate, esters of linear and/or branched fatty acids with polyhydric alcohols (such as, for example, propylene glycol, dimerdiol or trimertriol) and/or Guerbet alcohols, triglycerides based on C6-C10-fatty acids, liquid mono-/di-/triglyceride mixtures based on C6-C18-fatty acids, esters of C6-C22-fatty alcohols and/or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, esters of C2-C12-dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C6-C22-fatty alcohol carbonates, such as, for example, Dicaprylyl Carbonate (Cetiol® CC), Guerbet carbonates, based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of benzoic acid with linear and/or branched C6-C22-alcohols (e.g. Finsolv® TN), linear or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as, for example, dicaprylyl ether (Cetiol® OE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicones, silicone methicone grades, etc.) and/or aliphatic or naphthenic hydrocarbons, such as, for example, squalane, squalene or dialkylcyclohexanes.


Emulsifiers

Other non-ionic or cationic surfactants may also be added to the preparations as emulsifiers, including for example:

    • products of the addition of 2 to 30 mol ethylene oxide and/or 0 to 5 mol propylene oxide onto linear C8-22 fatty alcohols, onto C12-22 fatty acids and onto alkyl phenols containing 8 to 15 carbon atoms in the alkyl group;
    • C12/18 fatty acid monoesters and diesters of addition products of 1 to 30 mol ethylene oxide onto glycerol;
    • glycerol mono- and diesters and sorbitan mono- and diesters of saturated and unsaturated fatty acids containing 6 to 22 carbon atoms and ethylene oxide addition products thereof;
    • addition products of 15 to 60 mol ethylene oxide onto castor oil and/or hydrogenated castor oil;


polyol esters and, in particular, polyglycerol esters such as, for example, polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimerate isostearate. Mixtures of compounds from several of these classes are also suitable;

    • addition products of 2 to 15 mol ethylene oxide onto castor oil and/or hydrogenated castor oil;
    • partial esters based on linear, branched, unsaturated or saturated C6/22 fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (for example sorbitol), alkyl glucosides (for example methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (for example cellulose);


mono-, di and trialkyl phosphates and mono-, di- and/or tri-PEG-alkyl phosphates and salts thereof;

    • wool wax alcohols;
    • polysiloxane/polyalkyl polyether copolymers and corresponding derivatives;
    • mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol and/or mixed esters of C6 22 fatty acids, methyl glucose and polyols, preferably glycerol or polyglycerol,
    • polyalkylene glycols and
    • glycerol carbonate.


The addition products of ethylene oxide and/or propylene oxide onto fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or onto castor oil are known commercially available products. They are homologue mixtures of which the average degree of alkoxylation corresponds to the ratio between the quantities of ethylene oxide and/or propylene oxide and substrate with which the addition reaction is carried out. C12/18 fatty acid monoesters and diesters of addition products of ethylene oxide onto glycerol are known as lipid layer enhancers for cosmetic formulations. The preferred emulsifiers are described in more detail as follows:


Partial glycerides. Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, linolenic acid monoglyceride, linolenic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid monoglyceride, malic acid diglyceride and technical mixtures thereof which may still contain small quantities of triglyceride from the production process. Addition products of 1 to 30 and preferably 5 to 10 mol ethylene oxide onto the partial glycerides mentioned are also suitable.


Sorbitan esters. Suitable sorbitan esters are sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diricinoleate, sorbitan triricinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and technical mixtures thereof. Addition products of 1 to 30 and preferably 5 to 10 mol ethylene oxide onto the sorbitan esters mentioned are also suitable.


Polyglycerol esters. Typical examples of suitable polyglycerol esters are Polyglyceryl-2 Dipolyhydroxystearate (Dehymuls& PGPH), Polyglycerin-3-Diisostearate (Lameform& TGI), Polyglyceryl-4 Isostearate (Isolan& GI 34), Polyglyceryl-3 Oleate, Diisostearoyl Polyglyceryl-3 Diisostearate (Isolan® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care® 450), Polyglyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010/90), Polyglyceryl-3 Cetyl Ether (Chimexane® NL), Polyglyceryl-3 Distearate (Cremophor® GS 32) and Polyglyceryl Polyricinoleate (Admul® WOL 1403), Polyglyceryl Dimerate Isostearate and mixtures thereof. Examples of other suitable polyolesters are the mono-, di- and triesters of trimethylol propane or pentaerythritol with lauric acid, cocofatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like optionally reacted with 1 to 30 mol ethylene oxide.


Tetraalkyl ammonium salts. Cationically active surfactants comprise the hydrophobic high molecular group required for the surface activity in the cation by dissociation in aqueous solution. A group of important representatives of the cationic surfactants are the tetraalkyl ammonium salts of the general formula: (R1R2R3R4N+) X. Here R1 stands for C1-C8 alk(en)yl, R2, R3 and R4, independently of each other, for alk(en)yl radicals having 1 to 22 carbon atoms. X is a counter ion, preferably selected from the group of the halides, alkyl sulfates and alkyl carbonates. Cationic surfactants, in which the nitrogen group is substituted with two long acyl groups and two short alk(en)yl groups, are particularly preferred.


Esterquats. A further class of cationic surfactants particularly useful as co-surfactants for the present invention is represented by the so-called esterquats. Esterquats are generally understood to be quaternised fatty acid triethanolamine ester salts. These are known compounds which can be obtained by the relevant methods of preparative organic chemistry. Reference is made in this connection to International patent application WO 91/01295 A1, according to which triethanolamine is partly esterified with fatty acids in the presence of hypophosphorous acid, air is passed through the reaction mixture and the whole is then quaternised with dimethyl sulphate or ethylene oxide. In addition, German patent DE 4308794 C1 describes a process for the production of solid esterquats in which the quaternisation of triethanolamine esters is carried out in the presence of suitable dispersants, preferably fatty alcohols.


Typical examples of esterquats suitable for use in accordance with the invention are products of which the acyl component derives from monocarboxylic acids corresponding to formula RCOOH in which RCO is an acyl group containing 6 to 10 carbon atoms, and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid and technical mixtures thereof such as, for example, socalled head-fractionated fatty acid. Esterquats of which the acyl component derives from monocarboxylic acids containing 8 to 10 carbon atoms, are preferably used. Other esterquats are those of which the acyl component derives from dicarboxylic acids like malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and/or dodecanedioic acid, but preferably adipic acid. Overall, esterquats of which the acyl component derives from mixtures of monocarboxylic acids containing 6 to 22 carbon atoms, and adipic acid are preferably used. The molar ratio of mono and dicarboxylic acids in the final esterquat may be in the range from 1:99 to 99:1 and is preferably in the range from 50:50 to 90:10 and more particularly in the range from 70:30 to 80:20. Besides the quaternised fatty acid triethanolamine ester salts, other suitable esterquats are quaternized ester salts of mono-/dicarboxylic acid mixtures with diethanolalkyamines or 1,2dihydroxypropyl dialkylamines. The esterquats may be obtained both from fatty acids and from the corresponding triglycerides in admixture with the corresponding dicarboxylic acids. One such process, which is intended to be representative of the relevant prior art, is proposed in European patent EP 0750606 B1. To produce the quaternised esters, the mixtures of mono- and dicarboxylic acids and the triethanolamine - based on the available carboxyl functions - may be used in a molar ratio of 1.1:1 to 3:1. With the performance properties of the esterquats in mind, a ratio of 1.2:1 to 2.2:1 and preferably 1.5:1 to 1.9:1 has proved to be particularly advantageous. The preferred esterquats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9.


Superfatting Agents and Consistency Factors

Superfatting agents may be selected from such substances as, for example, lanolin and lecithin and also polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, the fatty acid alkanolamides also serving as foam stabilizers.


The consistency factors mainly used are fatty alcohols or hydroxyfatty alcohols containing 12 to 22 and preferably 16 to 18 carbon atoms and also partial glycerides, fatty acids or hydroxyfatty acids. A combination of these substances with alkyl oligoglucosides and/or fatty acid N-methyl glucamides of the same chain length and/or polyglycerol poly-12hydroxystearates is preferably used.


Thickening Agents and Rheology Additives

Suitable thickeners are polymeric thickeners, such as Aerosil® types (hydrophilic silicas), polysaccharides, more especially xanthan gum, guar-guar, agar-agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, also relatively high molecular weight polyethylene glycol monoesters and diesters of fatty acids, polyacrylates (for example Carbopols® [Goodrich] or Synthalens® [Sigma]), polyacrylamides, polyvinyl alcohol and polyvinyl pyrrolidone, surfactants such as, for example, ethoxylated fatty acid glycerides, esters of fatty acids with polyols, for example pentaerythritol or trimethylol propane, narrow-range fatty alcohol ethoxylates and electrolytes, such as sodium chloride and ammonium chloride.


Polymers

Suitable cationic polymers are, for example, cationic cellulose derivatives such as, for example, the quaternized hydroxyethyl cellulose obtainable from Amerchol under the name of Polymer JR 400®, cationic starch, copolymers of diallyl ammonium salts and acrylamides, quaternized vinyl pyrrolidone/vinyl imidazole polymers such as, for example, Luviquat® (BASF), condensation products of polyglycols and amines, quaternized collagen polypeptides such as, for example, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen (Lamequat® L, Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers such as, for example, amodimethicone, copolymers of adipic acid and dimethylaminohydroxypropyl diethylenetriamine (Cartaretine®, Sandoz), copolymers of acrylic acid with dimethyl diallyl ammonium chloride (Merquat® 550, Chemviron), polyaminopolyamides and crosslinked water-soluble polymers thereof, cationic chitin derivatives such as, for example, quaternized chitosan, optionally in microcrystalline distribution, condensation products of dihaloalkyls, for example dibromobutane, with bis-dialkylamines, for example bisdimethylamino-1,3-propane, cationic guar gum such as, for example, Jaguar® CBS, Jaguar& C17, Jaguar&C-16 of Celanese, quaternized ammonium salt polymers such as, for example, Mirapol® A-15, Mirapol& AD-1, Mirapol& AZ-1 of Miranol and the various polyquaternium types (for example 6, 7, 32 or 37) which can be found in the market under the tradenames Rheocare® CC or Ultragel® 300.


Suitable anionic, zwitterionic, amphoteric and nonionic polymers are, for example, vinyl acetate/crotonic acid copolymers, vinyl pyrrolidone/vinyl acrylate copolymers, vinyl acetate/butyl maleate/isobornyl acrylate copolymers, methyl vinylether/maleic anhydride copolymers and esters thereof, uncrosslinked and polyol-crosslinked polyacrylic acids, acrylamidopropyl trimethylammonium chloride/acrylate copolymers, octylacrylamide/methyl methacrylate/tert .- butylaminoethyl methacrylate/2-hydroxypropyl methacrylate copolymers, polyvinyl pyrrolidone, vinyl pyrrolidone/vinyl acetate copolymers, vinyl pyrrolidone/dimethylaminoethyl methacrylate/vinyl caprolactam terpolymers and optionally derivatized cellulose ethers and silicones.


Pearlizing Waxes

Suitable pearlising waxes are, for example, alkylene glycol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially cocofatty acid diethanolamide; partial glycerides, especially stearic acid monoglyceride; esters of polybasic, optionally hydroxysubstituted carboxylic acids with fatty alcohols containing 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; fatty compounds, such as for example fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates which contain in all at least 24 carbon atoms, especially laurone and distearylether; fatty acids, such as stearic acid, hydroxystearic acid or behenic acid, ring opening products of olefin epoxides containing 12 to 22 carbon atoms with fatty alcohols containing 12 to 22 carbon atoms and/or polyols containing 2 to 15 carbon atoms and 2 to 10 hydroxyl groups and mixtures thereof.


Silicones

Suitable silicones can be chosen from the group consisting of: Acefylline Methylsilanol Mannuronate, Acetylmethionyl Methylsilanol Elastinate Acrylates/Behenyl, Acrylate/Dimethicone Methacrylate Copolymer, Acrylates/Behenyl Methacrylate/Dimethicone Methacrylate Copolymer, Acrylates/Bis-Hydroxypropyl Dimethicone Crosspolymer, Acrylates/Dimethicone Copolymer, Acrylates/Dimethicone Methacrylate/Ethylhexyl Acrylate CoCopolymer, Acrylates/Ethylhexyl Acry-polymer, Acrylates/Dimethiconol Acrylate late/Dimethicone Methacrylate Copolymer, Acrylates/Octylacrylamide/Diphenyl Amodimethicone Copolymer, Acrylates/Polytrimethylsiloxymethacrylate Copolymer, Acrylates/Propyl Trimethicone Methacrylate Copolymer, Acrylates/Stearyl Acrylate/Dimethicone Methacrylate Copolymer, Acrylates/Tridecyl Acrylate/Triethoxysilylpropyl Methacrylate/Dimethicone Methacrylate Copolymer, Acrylates/Trifluoropropylmethacrylate/Polytrimethyl Siloxymethacrylate Copolymer, Amino Bispropyl Dimethicone, Aminoethylaminopropyl Dimethicone, Aminopropyl Dimethicone, Aminopropyl Phenyl Trimethicone, Aminopropyl Triethoxysilane, Ammonium Dimethicone PEG-7 Sulfate, Amodimethicone, Amodimethicone Hydroxystearate, Amodimethicone/Silsesquioxane Copolymer, Ascorbyl Carboxydecyl Trisiloxane, Ascorbyl Methylsilanol Pectinate, Behenoxy Dimethicone, Behentrimonium Dimethicone PEG-8 Phthalate, Behenyl Dimethicone, Bisamino PEG/PPG-41/3 Aminoethyl PG-Propyl Dimethicone, Bis-Aminopropyl/Ethoxy Aminopropyl Dimethicone, Bis(Butylbenzoate) Diaminotriazine Aminopropyltrisiloxane, Bis-Butyldimethicone Polyglyceryl-3, BisButyloxyamodimethicone/PEG-60 Copolymer, Bis(C13-15 Alkoxy) Hydroxybutamidoamodimethicone, Bis(C13-15 Alkoxy) PG-Amodimethicone, Bis-(C1-8 Alkyl Lauroyl Lysine Decylcarboxamide) Dimethicone, Bis-Cetyl Cetyl Dimethicone, Bis-Cetyl/PEG-8 Cetyl PEG-8 Dimethicone, Bis-Diphenylethyl Disiloxane, Bis-Ethyl Ethyl Methicone, BisGluconamidoethylaminopropyl Dimethicone, Bis-Hydrogen Dimethicone, Bis-Hydroxyethoxypropyl Dimethicone Bis-Hydroxylauryl, Dimethicone/IPDI Copolymer, Bis-Hydroxy/Methoxy Amodimethicone, Bis-Hydroxypropyl Dimethicone Behenate, Bis-Hydroxypropyl Dimethicone/SMDI Copolymer, Bis-Isobutyl PEG-14/Amodimethicone Copolymer, Bis-Isobutyl PEG15/Amodimethicone Copolymer, Bis-Isobutyl PEG/PPG-20/35/Amodimethicone Copolymer, Bis-Isobutyl PEG/PPG-10/7/Dimethicone Copolymer, Bis-Isobutyl PEG-24/PPG-7/Dimethicone Copolymer, Bis-PEG-1 Dimethicone, Bis-PEG-4 Dimethicone, Bis-PEG-8 Dimethicone, Bis-PEG-12 Dimethicone, Bis-PEG-20 Dimethicone, Bis-PEG-12 Dimethicone Beeswax, Bis-PEG-12 Dimethicone Candelillate, Bis-PEG-15 Dimethicone/IPDI Copolymer, Bis-PEG-15 Methyl Ether Dimethicone, Bis-PEG-18 Methyl Ether Dimethyl Silane, Bis-PEG/PPG-14/14 Dimethicone, Bis-PEG/PPG-15/5 Dimethicone, Bis-PEG/PPG-18/6 Dimethicone, Bis-PEG/PPG-20/20 Dimethicone, Bis-PEG/PPG-16/16 PEG/PPG-16/16 Dimethicone, Bis-PEG/PPG-20/5 PEG/PPG-20/5 Dimethicone, Bisphenylhexamethicone, Bis-Phenylpropyl Dimethicone, Bispolyethylene Dimethicone, Bis-(Polyglyceryl-3 Oxyphenylpropyl) Dimethicone, Bis-(Polyglyceryl7 Oxyphenylpropyl) Dimethicone, Bis-PPG-15 Dimethicone/IPDI Copolymer, Bis(PPG-7 Undeceneth-21) Dimethicone, Bis-Stearyl Dimethicone, Bis-Trimethoxysilylethyl Tetramethyldisiloxyethyl Dimethicone, Bis-Vinyldimethicone, Bis-Vinyl Dimethicone/Dimethicone Copolymer, Borage Seed Oil PEG-7 Dimethicone Esters, Butyl Acrylate/C6-14 Perfluoroalkylethyl Acrylate/Mercaptopropyl Dimethicone Copolymer, Butyl Acrylate/Hydroxypropyl Dimethicone Acrylate Copolymer, Butyl Dimethicone Acrylate/Cyclohexylmethacrylate/Ethylhexyl Acrylate Copolymer, Butyldimethicone Methacrylate/Methyl Methacrylate Crosspolymer, tButyl Dimethyl SilyI Grape Seed Extract, Butyl Polydimethylsiloxyl Ethylene/Propylene/Vinylnorbornene Copolymer, C6-8 Alkyl C3-6 Alkyl Glucoside Dimethicone, C20-24 Alkyl Dimethicone,C24-28 Alkyl Dimethicone, C26-28 Alkyl Dimethicone, C30-45 Alkyl Dimethicone, C30-60 Alkyl Dimethicone, C32 Alkyl Dimethicone, C30-45 Alkyl Dimethicone/Polycyclohexene Oxide Crosspolymer, C26-28 Alkyldimethylsilyl Polypropylsilsesquioxane, C30-45 Alkyldimethylsilyl Polypropylsilsesquioxane, C20-24 Alkyl Methicone, C24-28 Alkyl Methicone, C26-28 Alkyl Methicone, C30-45 Alkyl Methicone, C20-28 Alkyl Perfluorodecylethoxy Dimethicone, C26-54 Alkyl Tetradecyl Dimethicone, Capryl Dimethicone, Caprylyl Dimethicone Ethoxy Glucoside, Caprylyl Methicone, Caprylyl Trimethicone, Carboxydecyl Trisiloxane, Castor Oil Bis-Hydroxypropyl Dimethicone Esters Cerotyl Dimethicone, Cetearyl Dimethicone Crosspolymer, Cetearyl Dimethicone/Vinyl Dimethicone Crosspolymer, Cetearyl Methicone, Cetrimonium Carboxydecyl PEG-8 Dimethicone, Cetrimonium Dimethicone PEG-7 Phthalate, Cetyl Behenyl Dimethicone, Cetyl Dimethicone, Cetyl Dimethicone/BisVinyldimethicone Crosspolymer, Cetyl Hexacosyl Dimethicone, Cetyloxy Dimethicone, Cetyl PEG-8 Dimethicone, Cetyl PEG/PPG-15/15 Butyl Ether Dimethicone, Cetyl PEG/PPG-7/3 Dimethicone, Cetyl PEG/PPG-10/1 Dimethicone, Cetyl Triethylmonium Dimethicone PEG-8 Phthalate, Cetyl Triethylmonium Dimethicone PEG-8 Succinate, Copper Acetyl Tyrosinate Methylsilanol, Copper PCA Methylsilanol, C4-14 Perfluoroalkylethoxy Dimethicone, Cycloethoxymethicone, Cycloheptasiloxane, Cyclohexasiloxane, Cyclomethicone, Cyclopentasiloxane, Cyclophenylmethicone, Cyclotetrasiloxane, mCyclovinylmethicone, Cystine Bis-PG-Propyl Silanetriol, DEA PG-Propyl PEG/PPG-18/21 Dimethicone, Diisostearoyl Trimethylolpropane Siloxy Silicate, Dilauroyl Trimethylolpropane Siloxy Silicate, Dilinoleamidopropyl Dimethylamine Dimethicone PEG-7 Phosphate, Dimethicone, Dimethicone Crosspolymer, Dimethicone Crosspolymer-3, Dimethicone/Divinyldimethicone/Silsesquioxane Crosspolymer, Dimethicone Ethoxy Glucoside, Dimethicone Hydroxypropyl Trimonium Chloride, Dimethicone/Mercaptopropyl Methicone Copolymer, Dimethicone PEG-15 Acetate Dimethicone PEG-8 Adipate, Dimethicone PEG-7 Avocadoate, Dimethicone PEG-8 Avocadoate, Dimethicone PEG-8 Beeswax, Dimethicone PEG-8 Benzoate, Dimethicone PEG-8 Borageate, Dimethicone PEG-7 Cocoate, Dimethicone/PEG-10 Crosspolymer, Dimethicone/PEG-10/15 Crosspolymer, Dimethicone/PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG-8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG-8 Lanolate, Dimethicone PEG-8 Laurate, Dimethicone PEG-8 Meadowfoamate, Dimethicone PEG-7 Octyldodecyl Citrate, Dimethicone PEG-7 Olivate, Dimethicone PEG-8 Olivate, Dimethicone PEG-7 Phosphate, Dimethicone PEG-8 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG-7 Phthalate, Dimethicone PEG-8 Phthalate, Dimethicone PEG-8 Polyacrylate, Dimethicone PEG/PPG20/23 Benzoate, Dimethicone PEG/PPG-7/4 Phosphate, Dimethicone PEG/PPG-12/4 Phosphate, Dimethicone PEG-7 Succinate, Dimethicone PEG-8 Succinate, Dimethicone PEG-7 Sulfate, Dimethicone PEG-7 Undecylenate, Dimethicone PG-Diethylmonium Chloride, Dimethicone/Phenyl Vinyl Dimethicone Crosspolymer, Dimethicone/Polyglycerin-3 Crosspolymer, Dimethicone/PPG-20 Crosspolymer, Dimethicone Propylethylenediamine Behenate, Dimethicone Propyl PG-Betaine, Dimethicone/Silsesquioxane Copolymer, Dimethicone Silylate, Dimethicone/?inyl Dimethicone Crosspolymer, Dimethicone/Vinyltrimethylsiloxysilicate Crosspolymer, Dimethiconol, Dimethiconol Arginine, Dimethiconol Beeswax, Dimethiconol Behenate, Dimethiconol Borageate, Dimethiconol Candelillate, Dimethiconol Carnaubate, Dimethiconol Cysteine, Dimethiconol Dhupa Butterate, Dimethiconol Fluoroalcohol Dilinoleic Acid, Dimethiconol Hydroxystearate, Dimethiconol Illipe Butterate, Dimethiconol/IPDI Copolymer,


Dimethiconol Isostearate, Dimethiconol Kokum Butterate, Dimethiconol Lactate, Dimethiconol Meadowfoamate, Dimethiconol Methionine, Dimethiconol/Methylsilanol/Silicate Crosspolymer, Dimethiconol Mohwa Butterate, Dimethiconol Panthenol, Dimethiconol Sal Butterate, Dimethiconol/Silica Crosspolymer, Dimethiconol/Silsesquioxane Copolymer, Dimethiconol Stearate, Dimethiconol/Stearyl, Methicone/Phenyl Trimethicone Copolymer, Dimethoxysilyl Ethylenediaminopropyl Dimethicone, Dimethylaminopropylamido PCA Dimethicone, Dimethyl Oxobenzo Dioxasilane, Dimethylsilanol Hyaluronate, Dioleyl Tocopheryl Methylsilanol, Diphenyl Amodimethicone, Diphenyl Dimethicone, Diphenyl Dimethicone Crosspolymer Diphenyl Dimethicone?/inyl Diphenyl Dimethicone/Silsesquioxane Crosspolymer, Diphenylethyl Benzyloxy Dilsiloxane, Diphenylisopropyl Dimethicone, Diphenylsiloxy Phenyl/Propyl Trimethicone, Diphenylsiloxy Phenyl Trimethicone Disiloxane, Disodium Amodimethicone Disuccinamide, Disodium PEG-12 Dimethicone Sulfosuccinate, Disodium PEG-8 Lauryl Dimethicone Sulfosuccinate, Divinyldimethicone/Dimethicone Copolymer, Divinyldimethicone/Dimethicone Crosspolymer, Drometrizole Trisiloxane, Ethylhexyl Acrylate/VP/Dimethicone Methacrylate Copolymer, Ethyl Methicone, Ethyl Trisiloxane, Fluoro C28 Alkyldimethicone, Gluconamidopropyl Aminopropyl Dimethicone, 4-(2-BetaGlucopyranosiloxy) Propoxy-2-Hydroxybenzophenone, Glyceryl Undecyl Dimethicone, Glycidoxy Dimethicone, Hexadecyl Methicone, Hexyl Dimethicone, Hexyl Methicone, Hexyltrimethoxysilane, Hydrogen Dimethicone, Hydrogen Dimethicone/Octyl Silsesquioxane Copolymer, Hydrolyzed Collagen PG-Propyl Dimethiconol, Hydrolyzed Collagen PG-Propyl Methylsilanediol, Hydrolyzed Collagen PG-Propyl Silanetriol, Hydrolyzed Keratin PG-Propyl Methylsilanediol, Hydrolyzed Sesame Protein PG-Propyl Methylsilanediol, Hydrolyzed Silk PGPropyl Methylsilanediol, Hydrolyzed Silk PG-Propyl Methylsilanediol Crosspolymer, Hydrolyzed Soy Protein/Dimethicone PEG-7 Acetate, Hydrolyzed Soy Protein PG-Propyl Methylsilanediol, Hydrolyzed Vegetable Protein PG-Propyl Silanetriol, Hydrolyzed Wheat Protein/Cystine Bis-PG-Propyl Silanetriol Copolymer, Hydrolyzed Wheat Protein/Dimethicone PEG-7 Acetate, Hydrolyzed Wheat Protein/Dimethicone PEG-7 Phosphate Copolymer, Hydrolyzed Wheat Protein PG-Propyl Methylsilanediol, Hydrolyzed Wheat Protein PG-Propyl Silanetriol, Hydroxyethyl Acetomonium PG-Dimethicone, Hydroxypropyldimethicone, Hydroxypropyl Dimethicone Behenate, Hydroxypropyl Dimethicone Isostearate, Hydroxypropyl Dimethicone Stearate, Isobutylmethacrylate/Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isobutylmethacrylate/Trifluoroethylmethacrylate/Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isopentyl Trimethoxycinnamate Trisiloxane, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropyl Titanium Triisostearate/Triethoxysilylethyl, Polydimethylsiloxyethyl Dimethicone Crosspolymer, Isostearyl Carboxydecyl PEG-8 Dimethicone, Lactoyl Methylsilanol Elastinate, Lauryl Dimethicone, Lauryl Dimethicone PEG-15 Crosspolymer, Lauryl Dimethicone PEG-10 Phosphate, Lauryl Dimethicone/Polyglycerin-3 Crosspolymer, Lauryl Methicone, Lauryl PEG-8 Dimethicone, Lauryl PEG-10 Methyl Ether Dimethicone, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Lauryl PEG/PPG-18/18 Methicone, Lauryl Phenylisopropyl Methicone, Lauryl Phenylpropyl Methicone, Lauryl Polydimethylsiloxyethyl Dimethicone/Bis-Vinyldimethicone Crosspolymer, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Trimethicone, Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone, Methacryloyl Propyltrimethoxysilane, Methicone, Methoxy Amodimethicone/Silsesquioxane Copolymer, Methoxycinnamidopropyl Polysilsesquioxane, Methoxycinnamoylpropyl Silsesquioxane Silicate, Methoxy PEG-13 Ethyl Polysilsesquioxane, Methoxy PEG/PPG-7/3 Aminopropyl Dimethicone, Methoxy PEG/PPG-25/4 Dimethicone, Methoxy PEG-10 Propyltrimethoxysilane, Methyleugenyl PEG-8 Dimethicone, Methylpolysiloxane Emulsion, Methylsilanol Acetylmethionate, Methylsilanol Acetyltyrosine, Methylsilanol Ascorbate, Methylsilanol Carboxymethyl Theophylline, Methylsilanol Carboxymethyl Theophylline Alginate, Methylsilanol Elastinate, Methylsilanol Glycyrrhizinate, Methylsilanol Hydroxyproline, Methylsilanol Hydroxyproline Aspartate, Methylsilanol Mannuronate, Methylsilanol PCA, Methylsilanol PEG-7 Glyceryl Cocoate, Methylsilanol/Silicate Crosspolymer, Methylsilanol Spirulinate, Methylsilanol Tri-PEG-8 Glyceryl Cocoate, Methyl Trimethicone, Methyltrimethoxysilane, Myristylamidopropyl Dimethylamine Dimethicone PEG-7 Phosphate, Myristyl Methicone, Myristyl Trisiloxane, Nylon-611/Dimethicone Copolymer, PCA Dimethicone, PEG-7 Amodimethicone, PEG-8 Amodimethicone, PEG-8 Cetyl Dimethicone, PEG-3 Dimethicone, PEG-6 Dimethicone, PEG-7 Dimethicone, PEG-8 Dimethicone, PEG-9 Dimethicone, PEG-10 Dimethicone, PEG-12 Dimethicone, PEG-14 Dimethicone, PEG-17 Dimethicone, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoleate, PEG-8 Dimethicone/Dimer Dilinoleic Acid Copolymer, PEG-10 Dimethicone/Vinyl Dimethicone Crosspolymer, PEG-8 Distearmonium Chloride PG-Dimethicone, PEG-10/Lauryl Dimethicone Crosspolymer, PEG-15/Lauryl Dimethicone Crosspolymer, PEG-15/Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, PEG-8 Methicone, PEG-6 Methicone Acetate, PEG-6 Methyl Ether Dimethicone, PEG-7 Methyl Ether Dimethicone, PEG-8 Methyl Ether Dimethicone, PEG-9 Methyl Ether Dimethicone, PEG-10 Methyl Ether Dimethicone, PEG-11 Methyl Ether Dimethicone, PEG-32 Methyl Ether Dimethicone, PEG-8 Methyl Ether Triethoxysilane, PEG-10 Nonafluorohexyl Dimethicone Copolymer, PEG-4 PEG-12 Dimethicone, PEG-8 PG-Coco-Glucoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG/PPG-20/22 Butyl Ether Dimethicone, PEG/PPG-22/22 Butyl Ether Dimethicone, PEG/PPG-23/23 Butyl Ether Dimethicone, PEG/PPG-24/18 Butyl Ether Dimethicone, PEG/PPG-27/9 Butyl Ether Dimethicone, PEG/PPG-3/10 Dimethicone, PEG/PPG-4/12 Dimethicone, PEG/PPG-6/4 Dimethicone, PEG/PPG-6/11 Dimethicone, PEG/PPG-8/14 Dimethicone, PEG/PPG-8/26 Dimethicone, PEG/PPG-10/2 Dimethicone, PEG/PPG-12/16 Dimethicone, PEG/PPG-12/18 Dimethicone, PEG/PPG-14/4 Dimethicone, PEG/PPG-15/5 Dimethicone, PEG/PPG15/15 Dimethicone, PEG/PPG-16/2 Dimethicone, PEG/PPG-16/8 Dimethicone, PEG/PPG-17/18 Dimethicone, PEG/PPG-18/6 Dimethicone, PEG/PPG-18/12 Dimethicone, PEG/PP-G18/18 Dimethicone, PEG/PPG-19/19 Dimethicone, PEG/PPG-20/6 Dimethicone, PEG/PPG-20/15 Dimethicone, PEG/PPG-20/20 Dimethicone, PEG/PPG-20/23 Dimethicone, PEG/PPG-20/29 Dimethicone, PEG/PPG-22/23 Dimethicone, PEG/PPG-22/24 Dimethicone, PEG/PPG-23/6 Dimethicone, PEG/PPG-25/25 Dimethicone, PEG/PPG-27/27 Dimethicone, PEG/PPG-30/10 Dimethicone, PEG/PPG-25/25 Dimethicone/Acrylates Copolymer, PEG/PPG-20/22 Methyl Ether Dimethicone, PEG/PPG-24/24 Methyl Ether Glycidoxy Dimethicone, PEG/PPG-10/3 Oleyl Ether Dimethicone, PEG/PPG-5/3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorocaprylyl riethoxysilylethyl Methicone, Perfluorononyl Dimethicone, Perfluorononyl Dimethicone/Methicone/Amodimethicone Crosspolymer, Perfluorononylethyl Carboxydecyl Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Hexacosyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl/Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl Dimethicone, Perfluorononylethyl Carboxydecyl PEG-8 Dimethicone, Perfluorononylethyl Carboxydecyl PEG-10 Dimethicone, Perfluorononylethyl Dimethicone/Methicone Copolymer, Perfluorononylethyl PEG-8 Dimethicone, Perfluorononylethyl Stearyl Dimethicone, Perfluorooctylethyl/Diphenyl Dimethicone Copolymer, Perfluorooctylethyl Triethoxysilane, Perfluorooctylethyl Trimethoxysilane, Perfluorooctylethyl Trisiloxane, Perfluorooctyl Triethoxysilane, PG-Amodimethicone, Phenethyl Dimethicone, Phenethyl Disiloxane, Phenyl Dimethicone, Phenylisopropyl Dimethicone, Phenyl Methicone, Phenyl Methiconol, Phenylpropyldimethylsiloxysilicate, Phenylpropyl Ethyl Methicone, Phenyl Propyl Trimethicone, Phenyl Propyl Trimethicone/Diphenylmethicone, Phenyl Trimethicone, Platinum Divinyldisiloxane, Polyacrylate-6, Polydiethylsiloxane, Polydimethylsiloxyethyl Dimethicone/Bis-Vinyldimethicone Crosspolymer, Polydimethylsiloxyethyl Dimethicone/Methicone Copolymer, Polydimethylsiloxy PEG/PPG-24/19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-3 Disiloxane Dimethicone, Polyglyceryl3/Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Poly(Glycol Adipate)/Bis-Hydroxyethoxypropyl Dimethicone Copolymer, Polymethylsilsesquioxane, Polymethylsilsesquioxane/Trimethylsiloxysilicate, Polyphenylsilsesquioxane, Polypropylsilsesquioxane, Polysilicone-1, Polysilicone-2, Polysilicone-3, Polysilicone-4, Polysilicone-5, Polysilicone-6, Polysilicone-7, Polysilicone-8, Polysilicone-9, Polysilicone-10, Polysilicone-11, Polysilicone-12, Polysilicone-13, Polysilicone-14, Polysilicone-15, Polysilicone-16, Polysilicone-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysilicone-21, Polysilicone-18 Cetyl Phosphate, Polysilicone-1 Crosspolymer, Polysilicone-18 Stearate, Polyurethane-10, Potassium Dimethicone PEG-7 Panthenyl Phosphate, Potassium Dimethicone PEG-7 Phosphate, PPG-12 Butyl Ether Dimethicone, PPG-2 Dimethicone, PPG-12 Dimethicone, PPG-27 Dimethicone, PPG-4 Oleth-10 Dimethicone, Propoxytetramethyl Piperidinyl Dimethicone, Propyl Trimethicone, Quaternium-80, Retinoxytrimethylsilane, Silanediol Salicylate, Silanetriol, Silanetriol Arginate, Silanetriol Glutamate, Silanetriol Lysinate, Silanetriol Melaninate, Silanetriol Trehalose Ether, Silica, Silica Dimethicone Silylate, Silica Dimethyl Silylate, Silica Silylate, Silicon Carbide, Silicone Quaternium-1, Silicone Quaternium-2, Silicone Quaternium-2 Panthenol Succinate, Silicone Quaternium-3, Silicone Quaternium-4, Silicone Quaternium-5, Silicone Quaternium-6, Silicone Quaternium-7, Silicone Quaternium8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, SiliconeQuaternium-16, Silicone Quaternium-16/Glycidoxy Dimethicone Crosspolymer, Silicone Quaternium-17, Silicone Quaternium-18, Silicone Quaternium-19, Silicone Quaternium-20, Silicone Quaternium-21, Silicone Quaternium-22, Silicone Quaternium-24, Silicone Quaternium-25, Siloxanetriol Alginate, Siloxanetriol Phytate, Simethicone, Sodium Carboxydecyl PEG-8 Dimethicone, Sodium Dimethicone PEG-7 Acetyl Methyltaurate, Sodium Hyaluronate Dimethylsilanol, Sodium Lactate Methylsilanol, Sodium Mannuronate Methylsilanol, Sodium PCA Methylsilanol, Sodium PG-Propyldimethicone Thiosulfate Copolymer, Sodium PG-Propyl Thiosulfate Dimethicone, Sodium Propoxyhydroxypropyl Thiosulfate Silica, Sorbityl Silanediol, Soy Triethoxysilylpropyldimonium Chloride, Stearalkonium Dimethicone PEG-8 Phthalate, Stearamidopropyl Dimethicone, Steardimonium Hydroxypropyl Panthenyl PEG-7 Dimethicone Phosphate Chloride, Steardimonium Hydroxypropyl PEG-7 Dimethicone Phosphate Chloride, Stearoxy Dimethicone, Stearoxymethicone/Dimethicone Copolymer, Stearoxytrimethylsilane, Stearyl Aminopropyl Methicone, Stearyl Dimethicone, Stearyl/Lauryl Methacrylate Crosspolymer, Stearyl Methicone, Stearyl Triethoxysilanek, Stearyl Trimethicone, Styrene/Acrylates/Dimethicone Acrylate Crosspolymer, Styrene/Acrylates/Dimethicone Copolymer, TEA-Dimethicone PEG-7 Phosphate, Tetrabutoxypropyl Trisiloxane, Tetramethyl Hexaphenyl Tetrasiloxane, Tetramethyl Tetraphenyl Trisiloxane, Tocopheryloxypropyl Trisiloxane, Trideceth-9 PG-Amodimethicone, Triethoxycaprylylsilane, Triethoxysilylethyl Dimethicone/Methicone Copolymer, Triethoxysilylethyl Polydimethylsiloxyethyl Dimethicone, Triethoxysilylethyl Polydimethylsiloxyethyl Hexyl Dimethicone, Triethoxysilylpropylcarbamoyl Ethoxypropyl Butyl Dimethicone, Trifluoromethyl C1-4 Alkyl Dimethicone, Trifluoropropyl Cyclopentasiloxane, Trifluoropropyl Cyclotetrasiloxane, Trifluoropropyl Dimethicone, Trifluoropropyl Dimethicone/PEG-10 Crosspolymer, Trifluoropropyl Dimethicone/Trifluoropropyl Divinyldimethicone Crosspolymer, Trifluoropropyl Dimethicone/Vinyl Trifluoropropyl, Dimethicone/Silsesquioxane Crosspolymer, Trifluoropropyl Dimethiconol, Trifluoropropyldimethyl/trimethylsiloxysilicate, Trifluoropropyl Methicone, Trimethoxycaprylylsilane, Trimethoxysilyl Dimethicone, Trimethyl Pentaphenyl Trisiloxane, Trimethylsiloxyamodimethicone, Trimethylsiloxyphenyl Dimethicone, Trimethylsiloxysilicate, Trimethylsiloxysilicate/Dimethicone Crosspolymer, Trimethylsiloxysilicate/Dimethiconol Crosspolymer, Trimethylsiloxysilylcarbamoyl Pullulan, Trimethylsilyl Hydrolyzed Conchiolin Protein PG-Propyl Methylsilanediol Crosspolymer, Trimethylsilyl Hydrolyzed Silk PG-Propyl Methylsilanediol Crosspolymer, Trimethylsilyl Hydrolyzed Wheat Protein PG-Propyl Methylsilanediol Crosspolymer, Trimethylsilyl Pullulan, Trimethylsilyl Trimethylsiloxy Glycolate, Trimethylsilyl Trimethylsiloxy Lactate, Trimethylsilyl Trimethylsiloxy Salicylate, Triphenyl Trimethicone, Trisiloxane, Tris-Tributoxysiloxymethylsilane, Undecylcrylene Dimethicone, Vinyl Dimethicone, Vinyl Dimethicone/Lauryl Dimethicone Crosspolymer, Vinyl Dimethicone/Methicone Silsesquioxane Crosspolymer, Vinyldimethyl/Trimethylsiloxysilicate Stearyl Dimethicone Crosspolymer, VP/Dimethiconylacrylate/Polycarbamyl/Polyglycol Ester, Zinc Carboxydecyl Trisiloxane and Zinc Dimethicone PEG-8 Succinate and mixtures thereof.


More preferably the silicones to be contained in the mixture according to the inventions are Dimethicone, Cyclomethicone, Phenyl Trimethicone, Cyclohexasiloxane and Cyclopentasiloxane. A detailed overview of suitable volatile silicones can be found in Todd et al. in Cosm. Toil. 91, 27 (1976).


Waxes and Stabilizers

Besides natural oils used, waxes may also be present in the preparations, more especially natural waxes such as, for example, candelilla wax, carnauba wax, Japan wax, espartograss wax, cork wax, guaruma wax, rice oil wax, sugar cane wax, ouricury wax, montan wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), uropygial fat, ceresine, ozocerite (earth wax), petrolatum, paraffin waxes and microwaxes; chemically modified waxes (hard waxes) such as, for example, montan ester waxes, sasol waxes, hydrogenated jojoba waxes and synthetic waxes such as, for example, polyalkylene waxes and polyethylene glycol waxes.


Metal salts of fatty acids such as, for example, magnesium, aluminium and/or zinc stearate or ricinoleate may be used as stabilizers.


Primary Sun Protection Filters

Primary sun protection filters in the context of the invention are, for example, organic substances (light filters) which are liquid or crystalline at room temperature and which are capable of absorbing ultraviolet radiation and of releasing the energy absorbed in the form of longer-wave radiation, for example heat.


The formulations according to the invention advantageously contain at least one UVA filter and/or at least one UV-B filter and/or a broadband filter and/or at least one inorganic pigment. Formulations according to the invention preferably contain at least one UV-B filter or a broadband filter, more particularly preferably at least one UV-A filter and at least one UV-B filter.


The UV filters cited below which can be used within the context of the present invention are preferred but naturally are not limiting. UV filters which are preferably used are selected from the group consisting of one, two, three, four, five or more of the following species:














UV FILTER
TRADEMARK
SUPPLIER







4-Methylbenzylidene Camphor
Neo Heliopan ® MBC
Symrise


Anthranilic Acid Menthyl Ester
Neo Heliopan ® MA
Symrise


Benzophenone-3
Neo Heliopan ® BB
Symrise


Benzophenone-4
Uvinul ® MS40
BASF


Bis-Ethylhexyloxyphenol
Neo Heliopan ®BMT
Symrise


Methoxyphenyl Triazine


Butyl Methoxydibenzoylmethane
Neo Heliopan ®357
Symrise


Diethylamine Hydroxybenzoyl
Uvinul ® A Plus
BASF


Hexyl Benzoate


Diethylhexyl Butylamido
Iscotrizinol
3V


Triazone


Disodium Phenyl Dibenimidazole
Neo Heliopan ® AP
Symrise


Sulfonic Acid


Ethylhexyl Methoxycinnamate
Neo Heliopan ® AV
Symrise


Ethylhexyl salicylate
Neo Heliopan ® OS
Symrise


Ethylhexyl triazone
Uvinul ® T150
BASF


Homoslate
Neo Heliopan ® HMS
Symrise


Isoamyl p-Methoxycinnamate
Neo Heliopan ® E
Symrise



1000


Methoxypropylamine

BASF


Cyclohexenylidene Ethoxyethyl-


cyanoacetate


Methylene Bis-Benzotriazolyl
Tinosorb ® M
BASF


Tetramethylbutylphhenol (nano)


Octocrylene
Neo Heliopan ® 303
Symrise


Phenylbenzimidazole Sulfonic
Neo Heliopan ®
Symrise


Acid
Hydro


Phenylene Bis Diphenyltriazone
Triasorb
Pierre Fabre


Polysilicone-15
Parsol ®SLX
DSM


Tris-Biphenyl Triazine (nano)
Tinosorb ® A2B
BASF









In a preferred embodiment the sun protection filter forming component (ii) represents a blend of UV-A- and UV-B-filters selected from the group consisting of homosalate, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, butyl methoxydibenzoylmethane, ethylhexyl salicylate and mixtures thereof. Particular preferred is a blend of all these filters which is commercially available in the market under the trademark NeoHeliopan® Flat (SYMRISE), which also subject to WO 2020 088778 A1.


Suitable pigments encompass oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminium (Al2O3), cerium (e.g. Ce2O3) and/or mixtures thereof.


In a further preferred embodiment a formulation according to the invention contains a total amount of sunscreen agents, i.e. in particular UV filters and/or inorganic pigments (UV filtering pigments) so that the formulation according to the invention has a light protection factor of greater than or equal to 5 and up to 50. Such formulations according to the invention are particularly suitable for protecting the skin and hair.


Secondary Sun Protection Filters

Besides the groups of primary sun protection factors mentioned above, secondary sun protection factors of the antioxidant type may also be used. Secondary sun protection factors of the antioxidant type interrupt the photochemical reaction chain which is initiated when UV rays penetrate into the skin. Typical examples are amino acids (for example glycine, histidine, tyrosine, tryptophane) and derivatives thereof, imidazoles (for example urocanic acid) and derivatives thereof, peptides, such as D,L-carnosine, D-carnosine, L-carnosine and derivatives thereof (for example anserine), carotinoids, carotenes (for example alphacarotene, beta-carotene, lycopene) and derivatives thereof, chlorogenic acid and derivatives thereof, liponic acid and derivatives thereof (for example dihydroliponic acid), aurothioglucose, propylthiouracil and other thiols (for example thioredoxine, glutathione, cysteine, cystine, cystamine and glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, alpha-linoleyl, cholesteryl and glyceryl esters thereof) and their salts, dilaurylthiodipropionate, distearylthiodipropionate, thiodipropionic acid and derivatives thereof (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and sulfoximine compounds (for example butionine sulfoximines, homocysteine sulfoximine, butionine sulfones, penta-, hexaand hepta-thionine sulfoximine) in very small compatible dosages, also (metal) chelators (for example alpha-hydroxyfatty acids, palmitic acid, phytic acid, lactoferrine), alpha-hydroxy acids (for example citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and derivatives thereof, unsaturated fatty acids and derivatives thereof (for example linoleic acid, oleic acid), folic acid and derivatives thereof, ubiquinone and ubiquinol and derivatives thereof, vitamin C and derivatives thereof (for example ascorbyl palmitate, Mg ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (for example vitamin E acetate), vitamin A and derivatives (vitamin A palmitate) and coniferyl benzoate of benzoin resin, rutinic acid and derivatives thereof, glycosyl rutin, ferulic acid, furfurylidene glucitol, carnosine, butyl hydroxytoluene, butyl hydroxyanisole, nordihydroguaiac resin acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and derivatives thereof, mannose and derivatives thereof, superoxide dismutase, titanium dioxide (for example dispersions in ethanol), zinc and derivatives thereof (for example ZnO, ZnSO4), selenium and derivatives thereof (for example selenium methionine), stilbenes and derivatives thereof (for example stilbene oxide, trans-stilbene oxide) and derivatives of these active substances suitable for the purposes of the invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids).


Advantageous inorganic secondary light protection pigments are finely dispersed metal oxides and metal salts which are also mentioned in WO 2005 123101 A1. The total quantity of inorganic pigments, in particular hydrophobic inorganic micro-pigments in the finished cosmetic preparation according to the present invention is advantageously from 0.1 to 30% by weight, preferably 0.5 to 10.0% by weight, in each case based on the total weight of the preparation.


Also preferred are particulate UV filters or inorganic pigments, which can optionally be hydrophobed, can be used, such as the oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminium (Al2O3), cerium (e.g. Ce2O3) and/or mixtures thereof.


Biogenic Agents and Antioxidants

Biogenic active substances include, for example, tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy)ribonucleic acid and its fragmentation products, ßglucans, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts, such as such as prunus extract, bambaranus extract and vitamin complexes.


Antioxidants interrupt the photochemical reaction chain which is triggered when UV radiation penetrates the skin. Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides like D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (e.g. - carotene, lycopene) and their derivates, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrolic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamin and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, linoleyl, cholesteryl and glyceryl esters) and their salts Dilaurylthiodipropionate, ditearylthiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) as well as sulfoximine compounds (e.g. (e.g. buthionine sulfoximines, homocysteine sulfoximines, butionine sulfones, penta-, hexa-, heptathionine sulfoximines) in very low tolerated dosages (e.g. pmol to mol/kg), furthermore (metal) chelators (e.g. hydroxy fatty acids, palmitic acid, phytinic acid, lactoferrin), hydroxy acids (e.g. (e.g. citric acid, lactic acid, malic acid), humic acid, gallic acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g. linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (e.g. ascorbyl palmitate, Mg-ascorbyl phosphate, ascorbylacetate), tocopherols and derivatives (e.g. vitamin E acetate), vitamin A and derivates (vitamin A palmitate) as well as conifer aryl benzoate of benzoic resin, rutinic acid and its derivatives, glycosylrutin, ferulic acid, furfurylidene glucitol, carnosine, butyl hydroxytoluene, butylhydroxyanisole, nordihydroguaiac resin acid, nordihydroguajaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (e.g. e.g. ZnO, ZnSO4) selenium and its derivatives (e.g. selenium-methionine), stilbenes and their derivatives (e.g. styrene oxide, trans-stilbene oxide) and the derivatives suitable for the invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these named active substances.


Actives Modulating Hair Pigmentation

Preferred active ingredients for hair lightening are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinols and 4-(1-phenylethyl)1,3-dihydroxybenzene (phenylethyl resorcinol), cyclohexylcarbamates (preferably one or more cyclohexyl carbamates disclosed in WO 2010/122178 and WO 2010/097480), sulfur-containing molecules, preferably glutathione or cysteine, alpha-hydroxy acids (preferably citric acid, lactic acid, malic acid), salts and esters thereof, N-acetyl tyrosine and derivatives, undecenoyl phenylalanine, gluconic acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethyl phosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, thujaplicin and derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably senkyunolide, vinyl guiacol, ethyl guiacol, dionic acids, preferably octodecene dionic acid and/or azelaic acid, inhibitors of nitrogen oxide synthesis, preferably L-nitroarginine and derivatives thereof, 2,7-dinitroindazole or thiocitrulline, metal chelators (preferably alpha-hydroxy fatty acids, phytic acid, humic acid, bile acid, bile extracts, EDTA, EGTA and derivatives thereof), retinoids, soy milk and extract, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for skin and hair lightening, the latter preferably used in the form of an extract from plants, preferably bearberry extract, rice extract, papaya extract, turmeric extract, mulberry extract, bengkoang extract, nutgrass extract, liquorice root extract or constituents concentrated or isolated therefrom, preferably glabridin or licochalcone A, artocarpus extract, extract of rumex and ramulus species, extracts of pine species (pinus), extracts of vitis species or stilbene derivatives isolated or concentrated therefrom, saxifrage extract, scutelleria extract, grape extract and/or microalgae extract, in particular Tetraselmis suecica Extract.


Advantageous skin and hair tanning active ingredients in this respect are substrates or substrate analogues of tyrosinase such as L-tyrosine, N-acetyl tyrosine, L-DOPA or Ldihydroxyphenylalanine, xanthine alkaloids such as caffeine, theobromine and theophyl-line and derivatives thereof, proopiomelanocortin peptides such as ACTH, alpha-MSH, peptide analogues thereof and other substances which bind to the melanocortin receptor, peptides such as Val-Gly-Val-Ala-Pro-Gly, Lys-lle- Gly-Arg-Lys or Leu-lle-Gly-Lys, purines, pyrimidines, folic acid, copper salts such as copper gluconate, chloride or pyrrolidonate, 1,3,4-oxadiazole-2-thiols such as 5-pyrazin-2-yl-1,3,4-oxadiazole-2-thiol, curcumin, zinc diglycinate (Zn(Gly)2), manganese(II) bicarbonate complexes (“pseudocat-alases”) as described for example in EP 0 584 178, tetrasubstituted cyclohexene deriva-tives as described for example in WO 2005/032501 , isoprenoids as described in WO 2005/102252 and in WO 2006/010661 , melanin derivatives such as Melasyn-100 and MelanZe, diacyl glycerols, aliphatic or cyclic diols, psoralens, prostaglandins and ana-logues thereof, activators of adenylate cyclase and compounds which activate the transfer of melanosomes to keratinocytes such as serine proteases or agonists of the PAR-2 receptor, extracts of plants and plant parts of the chrysanthemum species, san-guisorba species, walnut extracts, urucum extracts, rhubarb extracts, microalgae extracts, in particular Isochrysis galbana, trehalose, erythru-lose and dihydroxyacetone. Flavonoids which bring about skin and hair tinting or brown-ing (e.g. quercetin, rhamnetin, kaempferol, fisetin, genistein, daidzein, chrysin and api-genin, epicatechin, diosmin and diosmetin, morin, quercitrin, naringenin, hesperidin, phloridzin and phloretin) can also be used.


The amount of the aforementioned examples of additional active ingredients for the modulation of skin and hair pigmentation (one or more compounds) in the products according to the invention is then preferably 0.00001 to 30 wt.%, preferably 0.0001 to 20 wt.%, particularly preferably 0.001 to 5 wt.%, based on the total weight of the preparation.


Hair Growth Activators or Inhibitors

Formulations and products according to the present invention may also comprise one or more hair growth activators, i.e. agents to stimulate hair growth. Hair growth activators are preferably selected from the group consisting of pyrimidine derivatives such as 2,4diaminopyrimidine-3-oxide (Aminexil), 2,4-diamino-6-piperidinopyrimidine-3-oxide (Minoxidil) and derivatives thereof, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and its derivatives, xanthine alkaloids such as caffeine, theobromine and theophylline and derivatives thereof, quercetin and derivatives, dihydroquercetin (taxifolin) and derivatives, potassium channel openers, antiandrogenic agents, synthetic or natural 5-reductase inhibitors, nicotinic acid esters such as tocopheryl nicotinate, benzyl nicotinate and C1-C6 alkyl nicotinate, proteins such as for example the tripeptide Lys-Pro-Val, diphencypren, hormons, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, cyproterone acetate, spironolactone and other diuretics, calcineurin inhibitors such as FK506 (Tacrolimus, Fujimycin) and its derivatives, Cyclosporin A and derivatives thereof, zinc and zinc salts, polyphenols, procyanidins, proanthocyanidins, phytosterols such as for example beta-sitosterol, biotin, eugenol, (+)-beta-citronellol, panthenol, glycogen for example from mussels, extracts from microorganisms, algae, plants and plant parts of for example the genera dandelion (Leontodon or Taraxacum), Orthosiphon, Vitex, Coffea, Paullinia, Theobroma, Asiasarum, Cucurbita or Styphnolobium, Serenoa repens (saw palmetto), Sophora flavescens, Pygeum africanum, Panicum miliaceum, Cimicifuga racemosa, Glycine max, Eugenia caryophyllata, Cotinus coggygria, Hibiscus rosa-sinensis, Camellia sinensis, Ilex paraguariensis, Isochrysis galbana, licorice, grape, apple, barley or hops or/nd hydrolysates from rice or wheat.


Alternatively, formulations and products according to the present invention may comprise one or more hair growth inhibitors (as described above), i.e. agents to reduce or prevent hair growth. Hair growth inhibitors are preferably selected from the group consisting of activin, activin derivatives or activin agonists, ornithine decarboxylase inhibitors such as alpha-difluoromethylornithine or pentacyclic triterpenes like for example ursolic acid, betulin, betulinic acid, oleanolic acid and derivatives thereof, 5alpha-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, gamma-glutamyl transpeptidase inhibitors, transglutaminase inhibitors, soybean-derived serine protease inhibitors, extracts from microorganisms, algae, different microalgae or plants and plant parts of for example the families Leguminosae, Solanaceae, Graminae, Asclepiadaceae or Cucurbitaceae, the genera Chondrus, Gloiopeltis, Ceramium, Durvillea, Glycine max, Sanguisorba officinalis, Calendula officinalis, Hamamelis virginiana, Arnica montana, Salix alba, Hypericum perforatum or Gymnema sylvestre.


Physiological Cooling And Warming Agents

Physiological cooling agents are preferably selected from the following list: menthol and menthol derivatives (for example L-menthol, D-menthol, racemic menthol, isomenthol, neoisomenthol, neomenthol) menthylethers (for example (I-menthoxy)-1,2-propandiol, (Imenthoxy)-2-methyl-1,2-propandiol), menthone glyceryl acetal, menthone glyceryl ketal or mixtures of both, menthylesters (for example menthylformiate, menthyhydroxyisobutyrat, menthyllactates, L-menthyl-L-lactate, L-menthyl-D-lactate, menthyl-(2-methoxy)acetate, menthyl-(2-methoxyethoxy)acetate, menthylpyroglutamate), menthylcarbonates (for example menthylpropyleneglycolcarbonate, menthylethyleneglycolcarbonate, menthylglycerolcarbonate or mixtures thereof), the semi-esters of menthols with a dicarboxylic acid or derivatives thereof (for example mono-menthylsuccinate, mono-menthylglutarate, monomenthylmalonate, O-menthyl succinic acid ester-N,N-(dimethyl)amide, O-menthyl succinic acid ester amide), menthanecarboxylic acid amides (in this case preferably menthanecarboxylic acid-N-ethylamide [WS3] or Na-(menthanecarbonyl)glycinethylester [WS5], as described in U.S. Pat. No. 4,150,052, menthanecarboxylic acid-N-(4-cyanophenyl)amide or menthanecarboxylic acid-N-(4-cyanomethylphenyl)amide as described in WO 2005 049553 A1, menthanecarboxylic acid-N-(alkoxyalkyl)amides), menthone and menthone derivatives (for example Lmenthone glycerol ketal), 2,3-dimethyl-2-(2-propyl)-butyric acid derivatives (for example 2,3dimethyl-2-(2-propyl)-butyric acid-N-methylamide [WS23]), isopulegol or its esters (I-(−)isopulegol, I-(−)-isopulegolacetate), menthane derivatives (for example p-menthane-3,8-diol), cubebol or synthetic or natural mixtures, containing cubebol, pyrrolidone derivatives of cycloalkyldione derivatives (for example 3-methyl-2(1-pyrrolidinyl)-2-cyclopentene-1-one) or tetrahydropyrimidine-2-one (for example iciline or related compounds, as described in WO 2004 026840 A1), further carboxamides (for example N-(2-(pyridin-2-yl)ethyl)-3-pmenthanecarboxamide or related compounds), (1R,2S,5R)-N-(4-Methoxyphenyl)-5-methyl-2(1-isopropyl)cyclohexane-carboxamide [WS12], oxamates (preferably those described in EP 2033688 A2) and [(1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl] 2-(ethylamino)-2-oxoacetate (X Cool).


Physiological warming agents can be selected from the group consisting of capsaicin, dihydrocapsaicin, nordihydrocapsaicin, homocapsaicin, homodihydrocapsaicin nonivamid, and chili extracts.


Anti-Inflammatory Agents

Suitable anti-inflammatory agents may be selected from the group formed by:

    • (i) steroidal anti-inflammatory substances of the corticosteroid type, in particular hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone,
    • (ii) non-steroidal anti-inflammatory substances, in particular oxicams such as piroxicam or tenoxicam, salicylates such as aspirin, disalcid, solprin or fendosal, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or clindanac, fenamates such as mefenamic, meclofenamic, flufenamic or niflumic, propionic acid derivatives such as ibuprofen, naproxen or benoxaprofen, pyrazoles such as phenylbutazone, oxyphenylbutazone, febrazone or azapropazone,
    • (iii) natural or naturally occuring anti-inflammatory substances or substances that alleviate reddening and/or itching, in particular extracts or fractions from camomile, Aloe vera, Commiphora species, Rubia species, willow, willow-herb, oats, calendula, arnica, St John's wort, honeysuckle, rosemary, Passiflora incarnata, witch hazel, ginger or Echinacea, or single active compounds thereof,
    • (iv) histamine receptor antagonists, serine protease inhibitors (e.g. of Soy extracts), TRPV1 antagonists (e.g. 4-t-Butylcyclohexanol), NK1 antagonists (e.g. Aprepitant, Hydroxyphenyl Propamidobenzoic Acid), cannabinoid receptor agonists (e.g. Palmitoyl Ethanolamine) and TRPV3 antagonists.


Anti-Microbial Agents

Suitable anti-microbial agents are, in principle, all substances effective against Grampositive bacteria, such as, for example, 4- hydroxybenzoic acid and its salts and esters, N-(4chlorophenyl)-N′-(3,4- dichlorophenyl)urea, 2,4,4′-trichloro-2′-hydroxy-diphenyl ether (triclosan), 4-chloro-3,5-dimethyl-phenol, 2,2′-methylenebis(6-bromo-4- chlorophenol), 3-methyl4-(1-methylethyl)phenol, 2-benzyl-4-chloro-phenol, 3-(4-chlorophenoxy)-1,2-propanediol, 3iodo-2-propynyl butylcarbamate, chlorhexidine, 3,4,4′-trichlorocarbanilide (TTC), antibacterial fragrances, thymol, thyme oil, eugenol, oil of cloves, menthol, mint oil, farnesol, phenoxyethanol, glycerol monocaprate, glycerol monocaprylate, glycerol monolaurate (GML), diglycerol monocaprate (DMC), salicylic acid N-alkylamides, such as, for example, noctylsalicylamide or n-decylsalicylamide.


Enzyme Inhibitors

Suitable enzyme inhibitors are, for example, esterase inhibitors. These are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and, in particular, triethyl citrate (Hydagen CAT). The substances inhibit enzyme activity, thereby reducing the formation of odour. Other substances which are suitable esterase inhibitors are sterol sulfates or phosphates, such as, for example, lanosterol, cholesterol, campesterol, stigmasterol and sitosterol sulfate or phosphate, dicarboxylic acids and esters thereof, such as, for example, glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid and diethyl malonate, hydroxycarboxylic acids and esters thereof, such as, for example, citric acid, malic acid, tartaric acid or diethyl tartrate, and zinc glycinate.


Odour Absorbers and Antiperspirant Active Agents

Suitable odour absorbers are substances which are able to absorb and largely retain odour-forming compounds. They lower the partial pressure of the individual components, thus also reducing their rate of diffusion. It is important that perfumes must remain unimpaired in this process. Odour absorbers are not effective against bacteria. They comprise, for example, as main constituent, a complex zinc salt of ricinoleic acid or specific, largely odourneutral fragrances which are known to the person skilled in the art as “fixatives”, such as, for example, extracts of labdanum or styrax or certain abietic acid derivatives. The odour masking agents are fragrances or perfume oils, which, in addition to their function as odour masking agents, give the deodorants their respective fragrance note. Perfume oils which may be mentioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts from flowers, stems and leaves, fruits, fruit peels, roots, woods, herbs and grasses, needles and branches, and resins and balsams. Also suitable are animal products, such as, for example, civet and castoreum. Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol, and hydrocarbon type. Fragrance compounds of the ester type are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styrallyl propionate and benzyl salicylate. The ethers include, for example, benzyl ethyl ether, and the aldehydes include, for example, the linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal, the ketones include, for example, the ionones and methyl cedryl ketone, the alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linaool, phenylethyl alcohol and terpineol, and the hydrocarbons include mainly the terpenes and balsams. Preference is, however, given to using mixtures of different fragrances which together produce a pleasing fragrance note. Essential oils of relatively low volatility, which are mostly used as aroma components, are also suitable as perfume oils, e.g. sage oil, camomile oil, oil of cloves, melissa oil, mint oil, cinnamon leaf oil, linden flower oil, juniperberry oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil and lavandin oil. Preference is given to using bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, a-hexylcinnamaldehyde, geraniol, benzylacetone, cyclamen aldehyde, linalool, boisambrene forte, ambroxan, indole, hedione, sandelice, lemon oil, mandarin oil, orange oil, allyl amyl glycolate, cyclovertal, lavandin oil, clary sage oil, Bdamascone, geranium oil bourbon, cyclohexyl salicylate, Vertofix coeur, iso-E-super, Fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, irotyl and floramat alone or in mixtures.


Suitable astringent antiperspirant active ingredients are primarily salts of aluminium, zirconium or of zinc. Such suitable antihydrotic active ingredients are, for example, aluminium chloride, aluminium chlorohydrate, aluminium dichlorohydrate, aluminium sesquichlorohydrate and complex compounds thereof, e.g. with 1,2- propylene glycol, aluminium hydroxyallantoinate, aluminium chloride tartrate, aluminium zirconium trichlorohydrate, aluminium zirconium tetrachlorohydrate, aluminium zirconium pentachlorohydrate and complex compounds thereof, e.g. with amino acids, such as glycine.


Film Formers and Anti-Dandruff Agents

Standard film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinyl pyrrolidone, vinyl pyrrolidone/vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid and salts thereof and similar compounds.


Suitable antidandruff agents are Pirocton Olamin (1-hydroxy-4-methyl-6-(2,4,4trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), Baypival® (Climbazole), Ketoconazol® (4-acetyl-1-{4-[2-(2,4-dichlorophenyl) r-2-(1H-imidazol-1-ylmethyl)-1,3-dioxylanc-4-ylmethoxyphenyl}-piperazine, ketoconazole, elubiol, selenium disulfide, colloidal sulfur, sulfur polyethylene glycol sorbitan monooleate, sulfur ricinol polyethoxylate, sulfur tar distillate, salicylic acid (or in combination with hexachlorophene), undecylenic acid, monoethanolamide sulfosuccinate Na salt, Lamepon® UD (protein/undecylenic acid condensate), zinc pyrithione, aluminium pyrithione and magnesium pyrithione/dipyrithione magnesium sulfate.


Carriers and Hydrotropes

Preferred cosmetics carrier materials are solid or liquid at 25° C. and 1013 mbar (including highly viscous substances) as for example glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water and mixtures of two or more of said liquid carrier materials with water. Optionally, these preparations according to the invention may be produced using preservatives or solubilizers. Other preferred liquid carrier substances, which may be a component of a preparation according to the invention are selected from the group consisting of oils such as vegetable oil, neutral oil and mineral oil.


Preferred solid carrier materials, which may be a component of a preparation according to the invention are hydrocolloids, such as starches, degraded starches, chemically or physically modified starches, dextrins, (powdery) maltodextrins (preferably with a dextrose equivalent value of 5 to 25, preferably of 10-20), lactose, silicon dioxide, glucose, modified celluloses, gum arabic, ghatti gum, traganth, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, carob bean flour, alginates, agar, pectin and inulin and mixtures of two or more of these solids, in particular maltodextrins (preferably with a dextrose equivalent value of 15-20), lactose, silicon dioxide and/or glucose.


In addition, hydrotropes, for example ethanol, isopropyl alcohol or polyols, may be used to improve flow behaviour. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols may contain other functional groups, more especially amino groups, or may be modified with nitrogen. Typical examples are

    • glycerol;
    • alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1000 Dalton;
    • technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10, such as for example technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight;
    • methylol compounds such as, in particular, trimethylol ethane, trimethylol propane, trimethylol butane, pentaerythritol and dipentaerythritol;
    • lower alkyl glucosides, particularly those containing 1 to 8 carbon atoms in the alkyl group, for example methyl and butyl glucoside;
    • sugar alcohols containing 5 to 12 carbon atoms, for example sorbitol or mannitol,
    • sugars containing 5 to 12 carbon atoms, for example glucose or sucrose;
    • amino sugars, for example glucamine;
    • dialcoholamines, such as diethanolamine or 2-aminopropane-1,3-diol.


Preservatives and/or Product Protection Agents

Suitable preservatives are, for example, phenoxyethanol, sodium benzoate or sorbic acid, blends of the mentioned ingredients and the other classes of compounds listed in Appendix 6, Parts A and B of the Kosmetikverordnung (“Cosmetics Directive”). Alternative products which could improve the product protection are for example 1,2-alkanediols such as for example 1,2-penatnediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, 1,2dodecanediol and mixtures thereof, 4-hydroxy acetophenone.


Dyes

Suitable dyes are any of the substances suitable and approved for cosmetic purposes as listed, for example, in the publication “Kosmetische Färbemittel” of the Farbstoffkommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pages 81 to 106. Examples include cochineal red A (C.I. 16255), patent blue V (C.I. 42051), indigotin (C.I. 73015), chlorophyllin (C.I. 75810), quinoline yellow (C.I. 47005), titanium dioxide (C.I. 77891), indanthrene blue RS (C.I. 69800) and madder lake (C.I. 58000). Luminol may also be present as a luminescent dye. Advantageous coloured pigments are for example titanium dioxide, mica, iron oxides (e.g. Fe203 Fe304, FeO(OH)) and/or tin oxide. Advantageous dyes are for example carmine, Berlin blue, chromium oxide green, ultramarine blue and/or manganese violet.


Preparations

Preferred compositions according to the present inventions are selected from the group of products for treatment, protecting, care and cleansing of the skin and/or hair or as a make-up product, preferably as a leave-on product (meaning that the one or more compounds stay on the skin and/or hair for a longer period of time, compared to rinse-off products).


The formulations according to the invention are preferably in the form of an emulsion, e.g. W/O (water-in-oil), O/W (oil-in-water), W/O/W (water-in-oil-in-water), O/W/O (oil-in-water-in-oil) emulsion, PIT emulsion, Pickering emulsion, emulsion with a low oil content, micro- or nanoemulsion, a solution, e.g. in oil (fatty oils or fatty acid esters, in particular C6C32 fatty acid C2-C30 esters) or silicone oil, dispersion, suspension, creme, lotion or milk, depending on the production method and ingredients, a gel (including hydrogel, hydrodispersion gel, oleogel), spray (e.g. pump spray or spray with propellant) or a foam or an impregnating solution for cosmetic wipes, a detergent, e.g. soap, synthetic detergent, liquid washing, shower and bath preparation, bath product (capsule, oil, tablet, salt, bath salt, soap, etc.), effervescent preparation, a skin care product such as e.g. an emulsion (as described above), ointment, paste, gel (as described above), oil, balsam, serum, powder (e.g. face powder, body powder), eau de perfume, eau de toilette, after-shave, a mask, a pencil, stick, roll-on, pump, aerosol (foaming, non-foaming or post-foaming), a deodorant and/or antiperspirant, mouthwash and mouth rinse, a foot care product (including keratolytic, deodorant), an insect repellent, a sunscreen, aftersun preparation, a shaving product, aftershave balm, pre- and aftershave lotion, a depilatory agent, a hair care product such as e.g. shampoo (including 2in-1 shampoo, anti-dandruff shampoo, baby shampoo, shampoo for dry scalps, concentrated shampoo), conditioner, hair tonic, hair water, hair rinse, styling creme, pomade, perm and setting lotion, hair spray, styling aid (e.g. gel or wax), hair smoothing agent (detangling agent, relaxer), hair dye such as e.g. temporary direct-dyeing hair dye, semi-permanent hair dye, permanent hair dye, hair conditioner, hair mousse, eye care product, make-up, make-up remover or baby product.


Auxiliary substances and additives can be included in quantities of 5 to 99% b.w., preferably 10 to 80% b.w., based on the total weight of the formulation. The amounts of cosmetic or dermatological auxiliary agents and additives and perfume to be used in each case can easily be determined by the person skilled in the art by simple trial and error, depending on the nature of the particular product.


The preparations can also contain water in a quantity of up to 99 wt.-percent., preferably from about 5 to about 80 wt.-percent. and more preferably either from about 10 to about 50 or from about 60 to about 80 wt.-percent. based on the total weight of the preparation.


PERFUME COMPOSITIONS

Another object of the present invention refers to a perfume composition comprising the fragrance mixture as claimed above and at least one carrier. Suitable carriers can be selected from the group consisting of benzyl benzoate, diethyl phthalate, dipropylene glycol, ethyl alcohol (ethanol), iso-propyl myristate, triethyl citrate, dipropylenglycol monomethylether, IsoPar L (isoparaffin mixture from ExxonMobile), triacetine and their mixtures. The preferred carrier is ethanol. The perfume compositions may comprise the fragrance mixture in an amount ranging from about 0.5 to about 25 wt.-percent, preferably from about 1 to about 2 wt.-percent.


INDUSTRIAL APPLICATION

Another object of the present invention refers to a method for modifying and/or intensifying the olfactory perception of a fragrance encompassing or consisting of the following steps:

    • (a) providing at least one fragrance with woody, amber, fruity or musky odor;
    • (b) providing 5,7-dimethyloct-6-en-1-ol; and
    • (c) adding said 5,7-dimethyloct-6-en-1-ol to said at least one other fragrance in an amount of from 0.01 to about 5 wt.-percent, preferably 0.1 to 2 wt.-percent and particularly preferred from 0.3 to 1 wt.-percent—calculated on the total amount of the mixture thus obtained.


A final object of the present invention is directed to the use of 5,7-dimethyloct-6-en1-ol for modifying and/or intensifying of the perception of fragrances with woody, amber, fruity or musky odor, preferably in the amounts as cited above.


For the sake of good order, it should be noted that all the above-mentioned preferred embodiments, mixtures, ratios and the like also apply to the process or use according to the invention. It is therefore unnecessary to repeat them.


WORKING EXAMPLES
Examples 1 to 6. Comparative Examples C1 to C6
Olfactory Evaluations

Mixtures of different fragrances were prepared once with and once without the addition of 1 and 0.3 wt.% isocitronellol, respectively, and the olfactory perception was assessed by a panel consisting of 5 experienced fragrance experts on a scale from (1)=weak to (5)=strongly pronounced. The results are summarized in Tables 1 to 6. The mean values are given.









TABLE 1







Modification of DBCB by Isocitronellol









Perception categories














Primary
Secondary



bright-


No.
fragrance
fragrance
fruity
pear
raspberry
ness





C1
Dimethyl

3
3
3
3



benzylcarbinyl


1
butyrate
+1 wt.-%
4
4
4
5




Isocitronellol
















TABLE 2







Modification of Agrumex HC by Isocitronellol









Perception categories














Primary
Secondary



bright-


No.
fragrance
fragrance
fruity
juicy
apple
ness





C2
2-tert.-butyl

3
2
3
3



cyclohexyl


2
acetate
+1 wt.-%
4
3
4
5



(Agrumex HC)
Isocitronellol
















TABLE 3







Modification of Aldehyde C14 by Isocitronellol









Perception categories














Primary
Secondary



bright-


No.
fragrance
fragrance
top note
fruity
juicy
ness





C3
Tetradecanal

5
3
3
3


3
(Aldehyde C14)
+1 wt.-%
2
4
4
5




Isocitronellol
















TABLE 4







Modification of Galaxolide by Isocitronellol









Perception categories














Primary
Secondary
pow-


bright-


No.
fragrance
fragrance
dery
amber
fruity
ness





C4
1,3,4,6,7,8-

2
3
3
3



Hexahydro-


4
4,6,6,7,8,8-
+0.3 wt.-%
3
4
4
5



hexamethyl-
Isocitronellol



cyclopenta[g]-



2-benzopyran



(Galaxolide



50% DPG)
















TABLE 5







Modification of Ethylene Brassylate by Isocitronellol











Primary
Secondary
Perception categories













No.
fragrance
fragrance
powdery
balm
volume
musk





C5
Ethylene

2
3
2
4



Brassylate


5

+0.3 wt.-%
3
4
4
5




Isocitronellol
















TABLE 6







Modification of Globalide by Isocitronellol










Secondary
Perception categories











No.
Primary fragrance
fragrance
top note
dirty





C6
Oxacyclohexadecen-2-one

4
4


6
(Globalide)
+0.3 wt.-%
2
3




Isocitronellol









The data provide above clearly demonstrate that even the addition of small amounts of isocitronellol significantly improve the positive odor sensations of quite different fragrances. As far as examples 3 and 6 are concerned, the unpleasant top notes were reduced in each case.


FORMULATION EXAMPLES FOR COSMETIC COMPOSITIONS

The following examples F1 to F55 show various formulations for cosmetic compositions. Formulation 1 stands for each of the fragrance mixtures according to Working Examples 1 to 6.









TABLE F1







Liquid soap; transparent (Amounts in % b.w.)









Ingredients
INCI Name
Amount












Tagat O 2
PEG-20 Glyceryl Oleate
2.5


Coconut oil diethanolamine
Cocamide DEA
5.0


condensate


Abil B 8842
Cyclomethicone
0.5


Sodium laurylethersulfate.
Sodium Laureth Sulfate
35.0


28%


Tego-Betaine L7
Cocamidopropyl Betaine
5.0


Soap. 25%
Coconut acid. Potassium salt.
20.0



Potassium Oleate


Hydrolite ® 5
1,2-propanediol
0.4


Formulation 1

0.3


Water
Water
Ad 100
















TABLE F2







Syndet soap. liquid (Amounts in % b.w.)









Ingredients
INCI Name
Amount












Elfan OS 46
Sodium Olefin C14-C16 Sulfonate
35.5


Armoteric LB
Lauryl Betaine
8.0


Elfan SG

10.0


Elfacos GT 282 L
Talloweth-60 Myristyl Glycol
3.0


PCL-Liquid 100
Cetearyl Ethylhexanoate
4.0


Hydrolite ® 5 Green
Hydrolite ® 5 Green
0.4


Preservative
Methylchloroisothiazolinone
0.1


Formulation 1

0.4


Water
Water
Ad 100
















TABLE F3







Cosmetic lotion for body wash (Amounts in % b.w.)









Ingredients
INCI Name
Amount












Lumerol K 28
Disodium Laureth Sulfosuccinate.
33.0



Cocamidopropyl Betaine. Magnesium



Lauryl Sulfate


Amphotensid B 4
Cocamidopropyl Betaine
10.0


Perlglanzmittel
MIPA-Pareth-25 Sulfate. Glycol Stearate
4.0


GM 4055


Sodium Chloride
Sodium Chloride
2.0


Avocado oil

Persea Gratissima (Avocado) Oil

3.0


Water
Water
Ad 100


Hydrolite ® 5
Hydrolite ® 5 Green
0.5


Euxyl ® K727
Phenoxyethanol. Methyldibromo
0.3



Glutaronitrile. Isothiazolinones


Formulation 1

0.6
















TABLE F4







Cosmetic lotion for body wash with Triclosan (Amounts in % b.w.)









Ingredients
INCI Name
Amount












Texapon N 25
Sodium Laureth Sulfate
37.5


Lamepon S
Potassium Cocoyl Hydrolyzed Collagen
28.0


Lamesoft LMG
Hydrogenated Tallow Glycerides. TEA-
5.0



Cocoyl Hydrolyzed Collagen


Lamesoft 156
Glyceryl Laurate. TEA-Cocoyl Hydrolyzed
5.0



Collagen


Sodium Chloride
Sodium Chloride
1.7


Irgasan DP 300
Triclosan
0.5


Water
Water
Ad 100


Hydrolite ® 5
Hydrolite ® 5 Green
0.3


Euxyl ® K703
Phenoxyethanol. Benzoic Acid.
0.4



Dehydroacetic Acid


Formulation 1

0.4
















TABLE F5







Intimate wash (Amounts in % b.w.)









Ingredients
INCI Name
Amount












Tegobetaine HS
Cocamidopropyl Betaine. Glyceryl
15.0



Laurate


Tagat L 2
PEG-20 Glyceryl Laurate
2.0


Arlacide G
Chlorhexidine Digluconate
0.1


Rewoquat B 50
Benzalkonium Chloride
0.1


Lactic Acid. 80%
Lactic Acid
0.1


Water
Water
Ad 100


Hydrolite ® 5
Hydrolite ® 5 Green
0.2


Euxyl ® K700
Potassium Sorbate. Benzyl Alcohol.
0.3



Phenoxyethanol


Formulation 1

0.5
















TABLE F6







Liquid soap (Amounts in % b.w.)











Ingredient
INCI
Amount















Deionized water
Water
2.0



Soap bases mix
Sodium tallowates/palmitates
95.8



Titanium dioxide
Titanium dioxide
1.0



Hydrolite ® 5
Hydrolite ® 5 Green
1.2



Preservatives
Phenoxyethanol
0.5



Formulation 1

0.5

















TABLE F7







Shampoo (Amounts in % b.w.)








Ingredients
Amount











Sodium lauryl ether sulfate (e.g. Texapon NSO)
12


Cocamidopropyl betaine (e.g. Dehyton K)
2


Sodium chloride
1.4


Citric acid
1.3


1,2-pentanediol (Hydrolite ® 5)
0.3


Phenoxyethanol. methyl-. ethyl-. butyl- and propylparaben
0.5


Formulation 1
0.5


Water
Ad 100
















TABLE F8







2-in-1 Shampoo (Amounts in % b.w.)









Ingredients
INCI Name
Amount





Deionized water
Water
Ad 100


Plantacare PS 10
Sodium Laureth Sulfate. Lauryl Glucoside
20.0


Euperlan PK 771
Glycol Distearate. Sodium Lauryl Sulfate.
6.0



Cocamide MEA. Laureth-10


Sodium chloride
Sodium Chloride
1.4


Citric acid
Citric acid
0.1


monohydrate


crystalline


Hydrolite ® 5
Hydrolite ® 5 Green
0.5


Dragocid Liquid
Phenoxyethanol, Parabens
0.5


Formulation 1

0.5
















TABLE F9







Anti-dandruff Shampoo (Amounts in % b.w.)










Ingredients
Amount














Climbazole
0.50



Sodium Laureth Sulfate
37.00



Cocamidopropyl Betaine
8.00



PEG-6 Caprylic/Capric Glycerides
2.50



Laureth-2
2.00



Water (Aqua). Glycerol. Thymus Vulgaris
0.50



(Thyme). Flower/Leaf Extract




Rosmarinus Officinalis (Rosemary) Leaf Water.

0.50



Water (Aqua). Butylene Glycol. Pentylene



Glycol



Bisabolol
0.10



Panthenol
0.50



Polyquaternium-10
0.40



1,2-pentanediol (Hydrolite ® 5)
0.50



Phenoxyethanol. Methylparaben. Ethylparaben.
0.70



Butylparaben. Propylparaben. Isobutylparaben



Formulation 1
0.30



Water (Aqua)
Ad 100

















TABLE F10







Hair conditioner with Crinipan. rinse-off (Amounts in % b.w.)









Ingredients
INCI Name
Amount





Lanette ® O
Cetearyl Alcohol
4.00


Dragoxat 89
Ethylhexyl Isononanoate
2.00


Genamin ® KDM-P
Behentrimonium Chloride
1.00


SF 1550
Phenyl Trimethicone
0.10


Neo Heliopan ®
Benzophenone-3
0.10


BB


Crinipan ® AD
Climbazole
0.80


Glycerol 99.5 P.
Glycerol
6.00


Water
Water (Aqua)
Ad 100


Actipone ® Alpha
Water (Aqua). Butylene Glycol. Malic
0.50


Pulp
Acid. Actinidia Chinensis (Kiwi)Fruit



Juice. Citrus. Aurantium Dulcis (Orange).



Juice. Citrus Paradisi (Grapefruit) Juice.




Pyrus Malus (Apple) Juice. Trideceth-9.





PrunusAmygdalus Dulcis (Sweet




Almond) Seed Extract


Extrapone ®
Propylene Glycol. Water (Aqua). Butylene
0.50


Bamboo P
Glycol. Bambusa Vulgaris Shoot Extract


Sodium Hydroxide
Sodium Hydroxide
0.40


10% solution


Colour I
Colour
0.60


Colour II
Colour
0.30


Hydrolite ® 5
Hydrolite ® 5 Green
0.40


Preservative
Methylparaben
0.20


Formulation 1
Hydroxyacetophenone
0.70
















TABLE F11







Sprayable hair conditioner with zinc pyrithrione.


leave-on (Amounts in % b.w.)









Ingredients
INCI Name
Amount












Monomuls 60-35 C
Hydrogenated Palm Glycerides
1.70


Cetiol OE
Dicaprylyl Ether
7.20


Abil 100
Dimethicone
3.60


Dehyquart F 75
Distearoylethyl Hydroxyethylmonium.
4.00



Methosulfate. Cetearyl Alcohol


Eumulgin B1
Ceteareth-12
3.50


Cetiol S
Diethylhexylcyclohexane
7.20


D-Panthenol
Panthenol
0.10


Glycerol 99.5 P.
Glycerol
1.50


Water
Water (Aqua)
Ad 100


Actipone ®
Water (Aqua). Propylene. Glycol.
0.10


Rosemary

Rosmarinus Officinalis. (Rosemary)




Leaf Extract


Frescolat ® ML
Menthyl Lactate
0.50


Cryst.


Dragosantol100
Bisabolol
0.10


Zinc Omadine
Zinc pyrithione
0.10


Hydrolite ® 5
Hydrolite ® 5
0.40


Phenonip ®
phenoxyethanol. methylparaben.
0.30



ethylparaben. butylparaben.



propylparaben. isobutylparaben


Formulation 1

0.5
















TABLE F12







Hair conditioner with UV protection (Amounts in % b.w.)









Ingredients
INCI Name
Amount





Renex PEG 6000
PEG-150
2.50


Hair Conditioner
Cetyl alcohol. behentrimonium chloride.
3.00


Base

Triticum Vulgare (Wheat) bran extract.




linoleic acid


PCL-Solid
Stearyl heptanoate. stearyl caprylate
0.50


Dow Corning 5200
Laurylmethicone copolyol
0.50


Natrosol 250 HR
Hydroxyethylcellulose
0.50


Benzophenone-4
Benzophenone-4
1.00


Neo Heliopan AP
Disodiumphenyldibenz-imidazole
1.00



tetrasulphonate


Amino methyl
Amino methyl propanol
2.00


propanol


Dow Corning 949
Amodimethicone. cetrimonium chloride.
2.00


cationic emulsion
trideceth-12


Hydrolite ® 5
Hydrolite ® 5
0.80


1.2-hexanediol
1.2-hexanediol
0.50


Formulation 1

0.50


Water
Water (Aqua)
Ad 100
















TABLE 13







Shower gel (Amounts in % b.w.)









Ingredients
INCI
Amount





Deionized water
Water
Ad 100


Plantacare PS 10
Sodium Laureth Sulfate. Lauryl
20.0



Glucoside


Sodium chloride
Sodium Chloride
1.4


Citric acid monohydrate
Citric Acid
1.3


crystalline


Hydrolite ® 5
Hydrolite ® 5
0.6


SymDiol ®68
1.2-hexanediol. Caprylyl glycol
0.4


Formulation 1

0.4
















TABLE F14







Shaving foam (Amounts in % b.w.)








Ingredients
Amount











Dem. Water
77.2


Triethanolamine
4.0


Edenor L2 SM (Stearinic acid. Palmitinic acid) (Cognis)
5.3


Laureth-23
3.0


Stearylalcohol
0.5


Sodium lauryl sulfate
3.0


Extrapone Seaweed (water. propylene glycol. potassium iodide.
1.0



Fucus Vesiculosus Extract)



Dragosantol (Bisabolol. Farnesol)
0.1


1,2-pentanediol (Hydrolite ® 5)
1.0


Euxyl ® K220 (Methylisothiazolinone. Ethylhexylglyerol)
0.6


Formulation 1
0.3


Propane. butane 4.2 Bar
4.0
















TABLE F15







Depilatory cream (Amounts in % b.w.)








Ingredients
Amount











Cetearyl alcohol
10.0


Ceteareth-12
2.0


PCL-Liquid (Cetearylethylhexanoate. Isopropylmyristate)
3.0


Dragosantol (Bisabolol. Farnesol)
0.1


Edenor L2 SM (Stearinic acid. Palmitinic acid)
1.0


Dem. Water
52.2


Urea
5.0


Dem. Water
10.0


Calcium thioglycolate
6.0


Sodium hydroxide solution. 10%
10.0


1,2-pentanediol (Hydrolite ® 5)
0.5


Neo Dragocid Powder (Methyl parabene. sorbinic acid. Dehydro
0.2


acetic acid. Propyl parabene)


Formulation 1
0.4
















TABLE F16







After Shave Tonic (Amounts in % b.w.)









Ingredients
INCI
Amount





SymSol ® PF-3
Water (Aqua). Pentylene Glycol. Sodium
3.00



Lauryl Sulfoacetate. SodiumOleoyl



Sarcosinate. Sodium Chloride. Disodium



Sulfoacetate. SodiumOleate. Sodium Sulfate


SymSitive ®
Pentylene Glycol. 4-t-Butylcyclohexan ol
1.00


1609


Frescolat ® ML
Menthyl Lactate
0.30


Glycerol 99.5 P.
Glycerol
5.00


Water
Water (Aqua)
Ad 100


Extrapone ®
Glycerol. Water (Aqua)
1.00


Glacier Water


GW


SymCalmin ®
Butylene Glycol. Pentylene Glycol.
0.50



Hydroxyphenyl Propamidobenzoic Acid


Dragosine ®
Carnosine
0.10


Hydrolite ® 5
Pentylene Glycol
5.00


Ethanol 96%
Alcohol Denat.
5.00


Colour Pigment
Colour Pigment
0.05


Hydrolite ® 5
1,2-pentanediol
0.15


Formulation 1
Hydroxyacetophenone
1.00
















TABLE F17







Deodorant formulation in the form of


a roll-on gel (Amounts in % b.w.)










Ingredients
Amount







1.3-butylene glycol
2.00



PEG-40-hydrogenated castor oil
2.00



Hydroxyethylcellulose
0.50



1,2-pentanediol (Hydrolite ® 5)
0.30



1.3-propanediol
0.50



3-phenylpropanol
0.40



Ethylhexyl glycerin
0.10



Formulation 1
0.50



Water
ad 100.00

















TABLE F18







Clear deo anti-perspirant roll-on (Amounts in % b.w.)









Ingredients
INCI
Amount












Methocel E4M Premium
Hydroxypropyl Methylcellulose
0.50


Water
Water (Aqua)
Ad 100


Neo-PCL Water
Trideceth-9. PEG-5 Ethylhexanoate.
1.00


Soluble N
Water (Aqua)


Solubilizer
PEG-40 Hydrogenated Castor Oil.
3.00



Trideceth 9. Propylene Glycol.



Water (Aqua)


Deolite
Dimethyl Phenylpropanol. Pentylene
0.50



Glycol


Locron LW
Aluminium Chlorohydrate
25.00


Aloe Vera Gel

Aloe Barbadensis Leaf Juice

1.00


Concentrate 10/1


Propylene Glycol -1.2
Propylene Glycol
4.00


99 P GC


Ethanol 96%
Alcohol Denat.
30.00


Hydrolite ® 5
1,2pentanediol
1.00


Formulation 1
Hydroxyacetophenone
0.25
















TABLE F19







Deodorant stick (Amounts in % b.w.)










Ingredients
Amount














Sodium stearate
8.00



PPG-3 Myristyl ether
70.00



1.2-propylene glycol
10.00



1.1-dimethyl-3-phenylpropanol
0.20



2-butyloctanoic acid
0.20



1,2-pentanediol (Hydrolite ® 5)
0.60



Heptoxy-1.2-propanediol
0.20



Phenoxyethanol
0.30



Formulation 1
0.50



Water
Ad 100

















TABLE F20







Zirconium suspensoid antiperspirant stick (Amounts in % b.w.)









Ingredients
INCI
Amount





PCL Liquid 100
Cetearyl ethylhexanonate
to 100


Silicone Fluid 345
Cyclomethicone
10.00


CRODACOL C90
Cetyl Alcohol
8.00


SYNCROWAX HGLC
C18-36 Triglyceride
8.00


CRODAMOL PTC
Pentaerythritol Tetracaprylate/Caprate
5.00


SYNCROWAX HRC
Tribehenin
4.00


VOLPO N5
Oleth-5
1.00


Titanium Dioxide

1.00


Rezal 36GP
Aluminium Tetrachlorohydrex GLY
20.00


Dry Flo C
Aluminium Starch Octenyl Succinate
22.50


Hydrolite ® 5
1,2-pentanediol
0.60


Preservative
Phenoxyethanol
0.40


Hexoxy-1.2-propanediol

0.10


Formulation 1

0.40
















TABLE F21







Deodorant pump spray with SymClariol (Amounts in % b.w.)









Ingredients
INCI
Amount





SymClariol ®
Decylene Glycol
0.50


Solubilizer
PEG-40 Hydrogenated Castor Oil.
4.00



Trideceth-9. Propylene Glycol.



Water (Aqua)


Neo-PCL Water
Trideceth-9. PEG-5 Ethylhexanoate.
1.50


Soluble N
Aqua


SymRelief ®
Bisabolol. Zingiber Officinale
0.10



(Ginger) Root Extract


Water
Water (Aqua)
Ad 100


1.2 Propylene
Propylene Glycol
6.00


Glycol


Hydrolite ® 5
1,2-pentanediol
0.40


SymDiol ® 68
1.2-Hexanediol. Caprylyl Glycol
0.20


Formulation 1

0.40
















TABLE F22







Antiperspirant formulations (Amounts in % b.w.)










Ingredients
Amounts














Reach AZP-908 SUF
24.00



Cyclomethicone (Pentamer)
Ad 100



Polydecene (Silkflo 364 NF)
17.50



Neo Heliopan OS (ethylhexyl salicylate)
2.50



L-Menthyl lactate (Frescolate ML)
0.25



Polyethylene
3.00



Hydrogenated castor oil
2.00



Promyristyl PM-3
7.00



PEG-8 Distearate
3.00



Silicon dioxide (Cab-O-Sil M-5)
1.00



Stearyl alcohol
15.00



Octyldodecanol
0.10



1,2-pentanediol (Hydrolite ® 5)
0.80



3-Phenylpropanol
0.40



Formulation 1
0.60

















TABLE F23







Deodorant spray with Triclosan (Amounts in % b.w.)










Ingredients
Amount














PEG-40-hydrogenated castor oil
3.00



Ethylhexylglycerol (Octoxyglycerol)
0.80



Ethanol
40.00



Citrate buffer
0.50



Triclosan ® (5-chloro-2-(2.4-dichlorophenoxy)phenol)
0.25



1,2-pentanediol (Hydrolite ® 5)
0.75



Phenoxyethanol
0.40



Formulation 1
0.40



Water
Ad 100

















TABLE F24







O/W lotion (Amounts in % b.w.)










Ingredients
Amount







Paraffin oil
5.00



Isopropyl palmitate
5.00



Cetyl alcohol
2.00



Beeswax
2.00



Ceteareth-20
2.00



PEG-20-glyceryl stearate
1.50



Glycerol
3.00



1,2-pentanediol (Hydrolite ® 5)
0.30



Methylparaben
0.30



Formulation 1
0.60



Water
ad 100.00

















TABLE F25







Body lotion (Amounts in % b.w.)








Ingredients
Amount











Cetearyl Alcohol
2.00


Ethylhexyl Isononanoate
5.00


Cetearyl Ethylhexanoate. Isopropyl Myristate
3.00


Glyceryl Oleate Citrate. Caprylic/Capric Triglyceride
4.00


Water (Aqua)
79.50


Carbomer
0.30


Sodium Benzoate
0.100


Propylene Glycol
5.00


Sodium Hydroxide 30% solution
0.30


1,2-pentanediol (Hydrolite ® 5)
0.30


Triethylene Glycol. Imidazolidinyl Urea. Methylparaben.
0.30


Propylparaben. Dehydroacetic Acid


Formulation 1
0.20
















TABLE F26







Cream (Amounts in % b.w.)










Ingredients
Amount














Paraffin oil
10.00



Ozokerite
4.00



Vaseline
4.00



Vegetable oil
10.00



Wool wax alcohol
2.00



Aluminum stearate
0.40



1,2-pentanediol (Hydrolite ® 5)
2.00



Phenoxyethanol
0.50



Formulation 1
0.50



Water
ad 100.00

















TABLE F27







Cream (Amounts in % b.w.)









Ingredients
INCI
Amount





Dracorin ® CE
Glyceryl Stearate Citrate
1.00


Lanette ® O
Cetearyl Alcohol
2.00


Cutina ® GMS-V
Glyceryl Stearate
1.00


Tegosoft ® MM
Myristyl Myristate
1.00


Xiameter ® PMX-
Cyclohexasiloxane (and)
0.50


0246. Cyclosiloxane
Cyclopentasiloxane


Dragoxat ® 89
Ethylhexyl Isononanoate
2.00


PCL-Liquid 100
Cetearyl Ethylhexanoate
4.00


Neutral Oil
Caprylic/Capric Triglyceride
4.00


Carbopol ® Ultrez 21
Acrylates/C10-30 Alkyl Acrylate
0.20



Crosspolymer


Keltrol ® CG-T
Xanthan Gum
0.10


Water
Water (Aqua)
Ad 100


Glycerol 99.5 P.
Glycerol
3.00


Propylene Glycol -1.2
Propylene Glycol
2.00


99 P GC


Sodium Benzoate
Sodium Benzoate
0.10


Sodium Hydroxide
Sodium Hydroxide
0.50


10% solution


Hydrolite ® 5
1,2-pentanediol
0.30


Euxyl ® K702
Dehydroacetic Acid. Benzoic Acid.
0.30



Phenoxyethanol.Polyaminopropyl



Biguanide. Ethylhexylglycerin


Formulation 1

0.70
















TABLE F28







Hand and body cream (Amounts in % b.w.)









Ingredients
INCI
Amount





Dracorin ® GOC
Glyceryl Oleate Citrate. Caprylic/
2.00



Capric Triglycerde


PCL-Solid
Stearyl Heptanoate. Stearyl Caprylate
2.50


Lanette ® O
Cetearyl Alcohol
1.50


Cutina ® GMS-V
Glyceryl Stearate
1.00


Dragoxat ® 89
Ethylhexyl Isononanoate
3.00


PCL-Liquid 100
Cetearyl Ethylhexanoate
7.00


Isodragol ®
Triisononanoin
4.00


Xiameter ® PMX-
Cyclopentasiloxane (and)
0.50


0345 Cyclosiloxane
Cyclohexasiloxane


Water
Water (Aqua)
Ad 100


Carbopol ® Ultrez
Acrylates/C10-30 Alkyl Acrylate
0.20


21
Crosspolymer


Keltrol ® CG-RD
Xanthan Gum
0.10


Glycerol 85 P.
Glycerol
3.00


DragoBetaGlucan
Water (Aqua). Butylene Glycol.
1.50



Glycerol. Avena Sativa (Oat) Kernel



Extract


Potassium Sorbat
Potassium Sorbate
0.10


Sodium Hydroxide
Sodium Hydroxide
0.50


10% solution


Hydrolite ® 5
1,2-pentanediol
0.20


Euxyl ® K300
Methyl-. Butyl-. Ethyl-. Propyl.
0.30



Isobutylparaben. Phenoxyethanol.


Formulation 1

0.30
















TABLE F29







Face cream (Amounts in % b.w.)









Ingredients
INCI
Amount












Emulsiphos ®
Potassium Cetyl Phosphate.
1.50



Hydrogenated Palm Glycerides


Cutina ® GMS-V
Glyceryl Stearate
1.70


Lanette ® O
Cetearyl Alcohol
3.00


Tegosoft ® MM
Myristyl Myristate
1.00


PCL-Liquid 100
Cetearyl Ethylhexanoate
1.00


Isodragol ®
Triisononanoin
3.00


Dragoxat ® 89
Ethylhexyl Isononanoate
4.00


Avocado Oil

Persea Gratissima (Avocado) Oil

3.00


Abil ® 350
Dimethicone
0.50


Covi-ox ® T-70
Tocopherol
0.10


Edeta ® BD
Disodium EDTA
0.10


Carbopol ® Ultrez 21
Acrylates/C10-30 Alkyl Acrylate
0.30



Crosspolymer


Keltrol ® CG-RD
Xanthan Gum
0.150


Water
Water (Aqua)
Ad 100


Glycerol 99.5 P.
Glycerol
4.00


Propylene Glycol -1.2
Propylene Glycol
3.00


99 P GC


SymMatrix ®
Maltodextrin. Rubus Fruticosus
0.50



(Blackberry) Leaf Extract


Sodium Hydroxide
Sodium Hydroxide
0.50


10% solution


Hydrolite ® 5
1,2-pentanediol
0.30


Euxyl ® K712
Sodium Benzoate. Potassium Sorbate
0.20


Formulation 1

0.60
















TABLE F30







Moisturizing body care cream (Amounts in % b.w.)










Ingredient
Amount














PEG-7 hydrogenated castor oil
6.00



Cetearyl ethyl hexanoate
10.00



Isopropyl myristate
5.00



Mineral oil
7.00



Shea Butter (Butyrospermum parkii)
0.50



Aluminum stearate
0.50



Magnesium stearate
0.50



Bisabolol
0.20



Quaternium-18-Hectorit
0.70



Dipropylene glycol
5.0



Magnesium sulfate
0.70



1,2-pentanediol (Hydrolite ® 5)
4.00



Preservative (Phenoxyethanol)
0.20



Formulation 1
0.40



Aqua dem.
58.90

















TABLE F31







Anti-wrinkle cream (Amounts in % b.w.)










Ingredients
Amount







Glyceryl Stearate Citrate
1.00



Glyceryl Laurate
1.00



Cetearyl Alcohol (and) Myristyl Myristate
3.00



Cetearyl Ethylhexanoate
4.00



Mineral oil
4.00



Cyclohexasiloxane
0.50



Acrylates/C10-30 Alkyl Acrylate Crosspolymer
0.20



Water
Ad 100



1.2-Hexanediol
2.00



Sodium Hydroxide 10% solution
0.10



Narcissus Tazetta Bulb Extract
1.00



1,2-pentanediol (Hydrolite ® 5)
0.30



Formulation 1
0.50

















TABLE F32







Functional skin oil for disinfection (Amounts in % b.w.)











Ingredients
INCI
Amount







Neutral Oil
Caprylic/Capric Triglyceride
Ad 100



Sweet Almond Oil
Prunus Dulcis
20.00



Dragoxat ® 89
Ethylhexyl Isononanoate
4.00



Isopropyl Palmitate
Isopropyl Palmitate
6.00



PCL-Liquid 100
Cetearyl Ethylhexanoate
15.00



Dragosantol ® 100
Bisabolol
0.20



Retinyl Acetate In
Retinyl Acetate
0.50



Oil (1 Mio. Ie/G)



Vitamin E Acetate
Tocopheryl Acetate
0.50



Covi-ox ® T-70
Tocopherol
0.10



Hydrolite ® 5
1,2-pentanediol
0.30



Preservative
Methyl-. Butyl-. Ethyl-.
0.30




Propylparaben



Formulation 1

0.40

















TABLE F33







Septic wound cream (Amounts in % b.w.)










Ingredients (INCI)
Amount














Sorbitan Isostearate. Hydrogenated
6.00



Castor Oil. Ceresin. Beeswax (Cera Alba)



Petrolatum
21.00



Cera Alba
5.00



Cetearyl Alcohol
7.00



Prunus Dulcis
7.00



Lanolin
5.00



Paraffinum Liquidum
12.00



Water (Aqua)
Ad 100



Panthenol
7.00



Magnesium Sulfate
0.70



1,2-pentanediol (Hydrolite ® 5)
1.00



Tocopheryl Acetate
1.00



Octenidine dihydrochloride
0.10



Phenoxyethanol
0.50



Formulation 1
0.50

















TABLE F34







Moisturizing and disinfecting face mask (Amounts in % b.w.)









Ingredients
INCI
Amount





Water
Water (Aqua)
Ad 100


Stabileze QM
PVM/Ma Decadiene Crosspolymer
0.50


Biotive ® L-Arginine
Arginine
0.75


Actipone ® Laminaria
Glycerol. Water (Aqua). Laminaria
1.00


Saccharina GW
Saccharina Extract


Extrapone ® Cucumber
Water (Aqua). Propylene Glycol.
1.00




Cucumis Sativus (Cucumber) Juice



Glycerol 99.5 P.
Glycerol
7.00


Neo Actipone ® Soap
Sapindus Mukurossi Peel Extract
0.50


Nutshell


Colour I
Colour
0.01


Hydrolite ® 5
Pentylene Glycol
5.00


Solubilizer
PEG-40 Hydrogenated Castor Oil.
0.60



Trideceth-9. Water (Aqua)


Hydrolite ® 5
1,2-pentanediol
0.08


Preservative
Phenoxyethanol
0.40


Formulation 1

0.40
















TABLE F35







Sprayable disinfecting gel (Amounts in % b.w.)









Ingredients
INCI
Amount





Water
Water (Aqua)
Ad 100


Stabileze QM
PVM/Ma Decadiene Crosspolymer
0.25


Sodium Hydroxide
Sodium Hydroxide
0.40


10% solution


Coffein pure
Caffeine
0.50


Extrapone ® Horse
Propylene Glycol. Water (Aqua).
1.00


Chestnut
Glucose. Aesculus Hippocastanum (Horse



Chestnut) Seed Extract. Lactic Acid


Hydrolite ® 5
1,2-pentanediol
3.00


1.3 Butylene Glycol
Butylene Glycol
5.00


Biotive ® Esculin
Esculin
0.30


Sesquihydrate


Ethanol 96%
Alcohol Denat.
10.00


Solubilizer
PEG-40 Hydrogenated Castor Oil.
0.50



Trideceth-9. Water (Aqua)


Preservative
Phenoxyethanol
0.70


Formulation 1

0.30
















TABLE F36







Mineral wash and cleaning gel (Amounts in % b.w.)









Ingredients
INCI
Amount





Water
Water (Aqua)
Ad 100


Pionier ® NP 37 G
Sodium Carbomer
1.50


SymSol ® PF-3
Water (Aqua). Pentylene Glycol.



Sodium Lauryl Sulfoacetate.
5.00



SodiumOleoyl Sarcosinate. Sodium



Chloride. Disodium Sulfoacetate.



SodiumOleate.
1.00


Hydroviton ® 24
Water (Aqua). Pentylene Glycol.



Glycerol. Sodium Lactate. Lactic



Acid. Serine. Urea. Sorbitol.



Sodium Chloride. Allantoin


Extrapone ® Silk GW
Water (Aqua). Glycerol. Hydrolyzed
1.00



Silk


Hydrolite ® 5 Green
Hydrolite ® 5 Green
4.00


Actipearls Red Star
Water (Aqua). Propylene Glycol.
1.00


# DH10402/6
Algin. Gellan Gum. Xanthan Gum.



CalciumChloride. CI 12490 (Pigment



Red 5). Mica (CI 77019). Titanium



Dioxide (CI 77891)


1,2-pentanediol
1,2-pentanediol
0.50


(Hydrolite ® 5)


3-Phenylpropanol

0.70


Formulation 1

0.30
















TABLE F37







Anti-acne wash (Amounts in % b.w.)








Ingredients (INCI)
Amount











Water (Aqua)
45.70


Polyquaternium-7
0.50


Cocamidopropyl Betaine 9.000
9.00


Coco Glucoside 2.000
2.00


Polysorbate 80. Glycerol. Gossypium Herbaceum.
1.00


(Cotton) Seed Oil. Water (Aqua)


Trideceth-9. PEG-5 Ethylhexanoate. Water (Aqua)
1.00


Glycereth-90 Isostearate. Laureth-2
0.50


Sodium Laureth Sulfate 37.000
37.00


Glycerol. Triticum Vulgare (Wheat) Gluten. Water (Aqua)
1.00


Sodium Chloride
0.30


1,2-pentanediol (Hydrolite ® 5)
1.00


Formulation 1
0.50
















TABLE F38







Cosmetic sun protection composition (Amounts in % b.w.)










Ingredient
Amount







Ethylhexyl cinnamic acid
7.50



Benzophenon-3
2.00



Polyglyceryl dimer soyate
0.80



Sorbitane stearate
1.00



Tocopheryl acetate
0.50



Glyceryl stearate. PEG-100 Stearate
3.00



PEG-40. hydrogenated castor oil
1.00



Titanium dioxide. aluminum oxide hydrate.
3.00



Dimethicon/Methicon Copolymer




Butyrospermum parkii (Shea Butter)

1.00



C12-15 alkyl benzoate
6.50



Butylene glycol
5.00



Xanthan gum
0.30



Disodium EDTA
0.10



Allantoin
0.10



Polyacryl amide. C13-14 isoparaffin. Laureth-7
1.00



1,2-pentanediol (Hydrolite ® 5)
5.00



4-t Butylcyclohexanol
1.00



Preservatives (Methyl-. Butyl-. Ethyl-.
0.30



Propylparaben. Phenoxyethanol)



Formulation 1
0.60



Aqua dem.
Ad 100

















TABLE F39







Sun protection spray (Amounts in % b.w.)









Ingredients
INCI
Amount












Water. demineralized
Water (aqua)
69.50


Glycerol
Glycerol
4.00


1.3 butylene glycol
Butylene glycol
5.00


D-Panthenol
Panthenol
0.50


Lara Care A-200
Galactoarabinan
0.25


Baysilone oil M 10
Dimethicone
1.00


Edeta BD
Disodium EDTA
0.10


Copherol 1250
Tocopheryl acetate
0.50


Cetiol OE
Dicaprylyl ether
3.00


Neo Heliopan ® HMS
Homosalate
5.00


Neo Heliopan ® AV
Ethylhexyl methoxycinnamate
6.00


Neo Heliopan ® 357
Butyl methoxydibenzoylmethane
1.00


Corapan TQ
Diethylhexylnaphthalate
2.00


Alpha Bisabolol
Bisabolol
0.10


Pemulen TR-2
Acrylates/C10-30 alkyl
0.25



acrylate crosspolymer


NaOH. 10%
Sodium hydroxide
0.60


Hydrolite ® 5
1,2-pentanediol
0.20


Phenoxyethanol
Phenoxyethanol
0.40


Solbrol M
Methylparaben
0.10


Solbrol P
Propylparaben
0.10


Formulation 1

0.50
















TABLE F40







Sunscreen spray O/W. SPE 15-20 (Amounts in % b.w.)









Ingredients
INCI
Amount





Dracorin ® GOC
Glyceryl Oleate Citrate. Caprylic/
2.00



Capric Triglyceride


Corapan ® TQ
Diethylhexyl 2.6-Naphthalate
3.00


Neo Heliopan ® HMS
Homosalate
7.00


Neo Heliopan ® OS
Ethylhexyl Salicylate
5.00


Neo Heliopan ® 357
Butyl Methoxydibenzoylmethane
3.00


Isoadipate
Diisopropyl Adipate
6.00


Baysilone ® Oil M10
Dimethicone
1.00


Edeta ® BD
Disodium EDTA
0.10


Vitamin E Acetate
Tocopheryl Acetate
0.50


Dragosantol ® 100
Bisabolol
0.10


Pemulen ® TR-2
Acrylates/C10-30 Alkyl Acrylate
0.25



Crosspolymer


Water
Water (Aqua)
Ad 100


Glycerol 99.5 P.
Glycerol
4.00


Butylene Glycol
Butylene Glycol
5.00


Neo Heliopan ® Hydro
Phenylbenzimidazole Sulfonic Acid
8.00


(103089). used as 25%


aq. solution


Biotive ® L-Arginine
Arginine
0.55


Hydrolite ® 5
1,2-pentanediol
0.40


Sobrol M
Methylparaben
0.30


Formulation 1

0.60
















TABLE F41







Sun protection soft cream (W/O). SPF 40 (Amounts in % b.w.)









Ingredients
INCI
Amount












Dehymuls PGPH
Polyglyceryl-2
5.00



dipolyhydroxystearate


Copherol 1250
Tocopheryl acetate
0.50


Permulgin 3220
Ozocerite
0.50


Zinc stearate
Zinc stearate
0.50


Tegosoft TN
C12-15 Alkyl benzoate
10.00


Neo Heliopan ® E1000
Isoamyl-p-methoxycinnamate
2.00


Neo Heliopan ® 303
Octocrylene
5.00


Neo Heliopan ® MBC
4-Methylbenzylidene camphor
3.00


Zinc oxide. neutral
Zinc oxide
5.00


Water. distilled
Water (aqua)
Add 100


EDETA BD
Disodium EDTA
0.10


Glycerol
Glycerol
4.00


Magnesium sulfate
Magnesium sulfate
0.50


Hydrolite ® 5
1,2-pentanediol
0.30


Symdiol ® 68
1.2-Hexanediol. Caprylylglycol
0.30


Formulation 1

0.80
















TABLE F42







Sun protection milk (W/O) (Amounts in % b.w.)









Ingredients
INCI
Amount












Dehymuls PGPH
Polyglyceryl-2
3.00



dipolyhydroxystearate


Beeswax 8100
Beeswax
1.00


Monomuls 90-0-18
Glyceryl oleate
1.00


Zinc stearate
Zinc stearate
1.00


Cetiol SN
Cetearyl isononanoate
5.00


Cetiol OE
Dicaprylyl ether
5.00


Tegosoft TN
C12-15 alkyl benzoate
4.00


Vitamin E
Tocopherol
0.50


Neo Heliopan ® OS
Ethylhexyl salicylate
5.00


Neo Heliopan ® AV
Ethylhexyl methoxycinnamate
7.50


Uvinul ® T150
Ethylhexyl triazone
1.50


Water. distilled
Water (Aqua)
To 100


Trilon BD
Disodium EDTA
0.10


Glycerol
Glycerol
5.00


Neo Heliopan ® AP
Disodium phenyl dibenzimidazole
15.00


10% solution.
tetrasulfonate


neutralized with NaOH


Hydrolite ® 5
1,2-pentanediol
0.25


Alpha bisabolol
Bisabolol
0.10


SymOcide ® PT
Phenoxyethanol. Tropolone
0.25


Formulation 1

0.25
















TABLE F43







After sun gel (Amounts in % b.w.)









Ingredients
INCI
Amount












SymSol ® PF-3
Water (Aqua). Pentylene Glycol. Sodium
3.000



Lauryl Sulfoacetate. SodiumOleoyl



Sarcosinate. Sodium Chloride. Disodium



Sulfoacetate. SodiumOleate. Sodium



Sulfate


Glycerol 99.5 P.
Glycerol
5.000


SymHelios ®
Benzylidene Dimethoxydimethylin danone
0.100


1031


Water
Water (Aqua)
Ad 100


Pemulen ® TR-2
Acrylates/C10-30 Alkyl Acrylate
1.000



Crosspolymer


D-Panthenol 75
Panthenol
0.500


W


SymFinity ® 1298
Echinacea Purpurea Extract
0.100


Extrapone ® Pearl
Water (Aqua). Glycerol. Hydrolyzed
1.000


GW
Pearl. Xanthan Gum


Sodium Hydroxide
Sodium Hydroxide
2.500


10% solution


Ethanol 96%
Alcohol Denat.
15.000


Hydrolite ® 5
1,2-pentanediol
0.20


SymOcide ® PS
Phenoxyethanol. 1.2-Hexanediol.
0.50



Decyleneglycol


Formulation 1

0.50
















TABLE F44







After sun lotion (Amounts in % b.w.)










Ingredients
Amount














Acrylate/C10-30 alkylacrylate crosspolymer
0.4



Cetearylethyl hexanoate
15.0



Bisabolol
0.2



Tocopheryl acetate
1.0



Panthenol
1.0



Alcohol
15.0



Glycerol
3.0



1.2-Hexanediol
0.60



Formulation 1
0.30



1,2-pentanediol (Hydrolite ® 5)
4.0



Aqua dem.
Ad 100



Triethanolamine
0.2

















TABLE F45







Hair styling gel (Amounts in % b.w.)








Ingredients
Amount





Water
Ad 100


PVM/MA Decadiene Crosspolymer
0.60


PVP
3.00


Isocetyl Stearate
4.00


Ethylhexyl Methoxycinnamate
0.50


Aminomethyl Propanol
0.40


1,2-pentanediol (Hydrolite ® 5)
0.60


SymDiol ® 68T (1.2-Hexanediol. 1.2-Octanediol. Tropolone)
0.30


Phenoxyethanol
0.20


Formulation 1
0.40
















TABLE F46







Silicone emulsion (Amounts in % b.w.)








Ingredients
Amount





Potassium Cetyl Phosphate. Hydrogenated Palm Glycerides
1.00


Cyclohexasiloxane
4.00


Cetearyl Alcohol
1.50


Phenyl Trimethicone
3.00


Stearyl Heptanoate. Stearyl Caprylate
3.00


Dimethicone
1.00


Xanthan Gum
0.20


Isoamyl p-Methoxycinnamate
5.00


Water
Ad 100


Methylpropanediol
3.00


1,2-pentanediol (Hydrolite ® 5)
0.30


Diazolidinyl urea
0.10


Formulation 1
0.50
















TABLE F47







Microemulsion gel (Amounts in % b.w.)










Ingredient
Amount







Glycerol isostearate
1.80



Octoxyglycerol
1.00



Ceteareth-15
5.20



PEG-150 Distearate
1.00



Aluminium chlorohydrate
5.00



Isotridecylisononanoate
3.30



Cyclomethicone
6.60



1,2-pentanediol (Hydrolite ® 5)
0.70



Euxyl ® K145 (Methylchloroisothiazolinone.
0.10



Methylisothiazlinone. Bronopol)



Formulation 1
0.40



Water
Ad 100

















TABLE F48







Air freshener in gel form (Amounts in % b.w.)










Ingredient
Amount







Demineralised water
Ad 100



Genugel ® X-6424 (carrageenan)
2.00



Arkopal ® N 100 or Tergitol ® NP 10 (Emulsifer)
3.50



1,2-pentanediol (Hydrolite ® 5)
0.60



Preventol ® D 7 (5-chloro-2-methyl-4-isothiazolin-
0.10



3-one. 2-methyl-2H isothiazol-3-one)



Formulation 1
0.80

















TABLE F55







Dish washing concentrate (Amounts in % b.w.)










Ingredients
Amount














Palm tree glucosides
4.0



Sodium lauryl sulfate
45.0



Coco betaine
8.0



Ethyl alcohol 96%
1.0



Colorant (C.I. Pigment Blue 15)
0.05



1,2-pentanediol (Hydrolite ® 5)
0.2



Formulation 1
0.7



Water
Ad 100

















TABLE F56







Solution for wet wipes (Amounts in % b.w.)









Ingredients
INCI
Amount





SymSol ® PF-3
Water (Aqua). Pentylene Glycol. Sodium
2.00



Lauryl Sulfoacetate. SodiumOleoyl



Sarcosinate. Sodium Chloride. Disodium



Sulfoacetate. SodiumOleate. Sodium



Sulfate


Dragosantol ® 100
Bisabolol
0.10


Glycerol 99.5 P.
Glycerol
5.00


Water
Water (Aqua)
Ad 100


Hydrolite ® 5
1,2-pentanediol
5.00


D-Panthenol 75 W
Panthenol
0.80


DragoCalm ®
Water (Aqua). Glycerol. Avena Sativa
1.00



(Oat) Kernel Extract


Witch Hazel-

Hamamelis Virginiana (Witch Hazel)

1.00


Distillate
Water. Water (Aqua). Alcohol


Allplant Essence ®

Pelargonium Graveolens Flower/Leaf/

1.00


Org. Rose Geranium
Stem Water


P


Preservative
Phenoxyethanol
0.30


Formulation 1

0.50








Claims
  • 1. A fragrance mixture, comprising (a) 5,7-dimethyloct-6-en-1-ol, and(b) at least one other different fragrance.
  • 2. The mixture according to claim 1, wherein the fragrance forming component (b) has a woody, amber, fruity or musky odor.
  • 3. The mixture according to claim 1, wherein a primary fragrance forming a component (b1) and having a woody odor, is selected from the group consisting of:
  • 4. The mixture according to claim 1, wherein a the primary fragrance forming a component (b2) and having an amber fragrance, is selected from the group consisting of:
  • 5. The mixture according to claim 1, wherein a the primary fragrance forming a component (b3) and having a fruity scent, is selected from the group consisting of:
  • 6. The mixture according to claim 1, wherein a the primary fragrance forming a component (b4) and having a musky scent, is selected from the group consisting of:
  • 7. The mixture according to claim 1, wherein the components (a) and (b) are present in a weight ratio of about 0.01:99.99 to 5:95.
  • 8. The mixture according to claim 7, wherein components (a) and (b) are present in a weight ratio of from about 0.1:99.9 to 2:98.
  • 9. A cosmetic preparation containing the perfume mixture mixtures according to claim 1.
  • 10. The preparation according to claim 9, representing a skin care, personal care, hair care or sun care product.
  • 11. A perfume composition comprising the fragrance mixture of claim 1 and at least one carrier.
  • 12. The composition of claim 11, wherein the carrier is selected from the group consisting of benzyl benzoate, diethyl phthalate, dipropylene glycol, ethyl alcohol (ethanol), iso-propyl myristate, triethyl citrate, dipropylenglycol monomethylether, IsoPar L, triacetine, and mixtures thereof.
  • 13. The composition of claim 11, comprising the fragrance mixture in an amount ranging from about 0.5 to about 25 wt.-percent.
  • 14. A method for modifying and/or intensifying the olfactory perception of a fragrance, comprising the following steps: (a) providing at least one fragrance with woody, amber, fruity or musky odor;(b) providing 5,7-dimethyloct-6-en-1-ol; and(c) adding said 5,7-dimethyloct-6-en-1-ol to said at least one other fragrance in an amount of from 0.01 to about 5 wt.-percent, calculated on the total amount of the mixture thus obtained.
  • 15. The method of claim 14, comprising the step of modifying and/or intensifying of the perception of fragrances with woody, amber, fruity or musky odor.
PCT Information
Filing Document Filing Date Country Kind
PCT/EP2021/059489 4/13/2021 WO