Not Applicable
The present invention relates to a process for manufacturing compact coils of ultra-fine grained, martensite-free steel bars.
The process of spooling the ribbed steel bars in compact coils is a big step ahead in storage, transport, handling, compared to the straight bar production.
The spooling process can be applied to ribbed steel bars with diameters ranging from 6 to 40 mm, for example from 6 to 32 mm, as well to smooth rounds.
The compact coils are unwound by means of machines which can both straighten the ribbed bar at room temperature, as well as to create rebar stirrups.
The spooling process is performed as shown in
This cooling can be applied in two different solutions.
The most common solution (
The surface quenching results in a mixed martensitic-bainitic structure, because of suppression of the diffusive transformation of the austenite, due to the high cooling speed.
After the quenching step, the bar undergoes a step of equalization in air, in which the heat of the core spreads towards the surface area, tempering the martensitic-bainitic structure. The bar is then wounded into a spooler to form a compact coil.
Results on final product of this process solution is a compromise between mechanical strength (whose contribution is mainly from the surface area) and toughness (whose contribution is mainly from the mixed ferrite and pearlite of the core).
The composite structure obtained with the quenching and self-tempering allows to comply with the mechanical characteristics established by the various national and international standards for rebars, with a billet chemical composition poorer than those used typically for not-quenched ribbed bar production.
On the other hand, an aspect of this QTS process is that the high hardness of the surface area, when unwinding the coil, gives higher wear of the straightening machine equipment, compared to non-quenched material, and thus a rougher straightening operation.
Another common process (
The target of the SQ process is to optimize the microstructure of the different steel grades avoiding undesirable grain growth and drastic cooling that would lead to a thick martensite layer.
In the SQ process, the cooling of the material is fractioned in multiple steps after the last finishing rolling stand and before the winding machine. The cooling steps are separated by equalizations spaces.
The final microstructure obtained with SQ process is different with respect to QTS traditional treatment. For the Soft Quenching the presence of mixture of tempered martensite and bainite on the surface is reduced compared to the QTS, but not avoided, maintaining the gradual transitioning to a mixture of ferrite and pearlite at the bar core.
However, an international market analysis shows that the use of quenched steel for rebar is not accepted in all markets, both as a consequence of local regulatory laws (for example China, Taiwan) and because, even in the absence of specific regulations, some markets do not accept quenched bars (for example Japan). This depends on the fact that the steel rebar is widely used as reinforcement for concrete in the civil construction of buildings. In particularly seismic areas such as China and Japan, these countries require bars with high ductility, given by a microstructure lacking the presence of fragile phases, such as martensite and bainite, typical of quenching treatment.
In particular, the newly revised Chinese national standard GB/T 1499.2018 (Steel for the reinforcement of concrete—part 2: Hot rolled ribbed bars) makes significant changes to the manufacture and supply of steel reinforcement bars for reinforced concrete in China, directly addressing the results obtained with poor-quality rebar material.
In order to guarantee the tight standard requirements or in any case to satisfy some markets requirements, additional alloying elements such as niobium (Nb), vanadium (V) and titanium (Ti) are necessary. However, the addition of the alloying elements mentioned above inevitably implies a significant increase in production costs.
It is an object of the present invention to develop a process for manufacturing compact coils of steel bars that allows production of ultra-fine grained, martensite-free and high ductility grades of spooled steel bars without addition of (or minimizing) microalloying elements (Nb, V, Ti), with lower production costs.
It is a further object of the present invention to produce a coil of steel bar having a microstructure with an grain size equal to or higher than 9 according to standard ASTM E112, and wherein the difference of hardness (HV, preferably HV 0,5, i.e. the Vickers hardness measured with load of 4.903 N) measured between surface and core of the steel bar is less or equal to 40 HV, for example in the range 10-40 HV.
The present invention achieves such objects and other objects, which will become apparent in the light of the present description, by means of a process for manufacturing coils of ultra-fine grained, martensite-free steel bars comprising the stages of claim 1.
According to a further aspect of the invention, a plant is provided for manufacturing compact coils of ultra-fine grained, martensite-free steel bars, the plant being suitable for carrying out said process, the plant comprising
Advantageously, the steel bars treated with the process of the invention do not have the characteristic microstructure obtained by means of quenched surface processes (i.e. an outer ring of martensite with a ferrite and pearlite core) but they present a microstructure composed exclusively of a mixture of ferrite and pearlite evenly distributed over the whole cross section of the bar. The mechanical properties are obtained thanks to the austenitic grain refinement produced using alternated cooling-equalizing-rolling stages, which can be synthetized as thermomechanical rolling. A small austenitic grain quickly transforms in a fine-grained ferritic-pearlitic texture. Comparing to the classic hot-rolled products, standing the same chemical composition, the ultra-fine grained product presents better mechanical properties, in particular a higher ductility. These cooling-equalizing-rolling stages can be repeated multiple times, using a variable number of cooling devices, for example cooling boxes, such as water boxes, that according to the plant throughput permit to reach the desired bar surface temperature at the entry of the finishing rolling stands group.
The heat treatment according to the invention is particularly suitable to produce compact coils of ribbed steel bars for concrete reinforcement, with Yield stress ranging from 200 to 1200 MPa, for example from 400 to 1000 MPa, or from 400 to 700 MPa for the most common composition ranges of low/medium carbon steel.
Optionally, a further contribution to the mechanical properties can also come from the subsequent unwinding and straightening operation (work hardening), and from a possible natural ageing. In this particular embodiment, the mechanical properties of the finished product are therefore obtained by means of a combination of thermomechanical rolling, heat treatment on the cooling line, straightening and possible ageing.
Below are some of the further advantages of the solution of the present invention with respect to the state of the art:
Further features and advantages of the invention will become more apparent in the light of the detailed description of illustrative, but non-exclusive embodiments.
The dependent claims describe particular embodiments of the invention.
Reference is made in the description of the invention to the appended drawing tables, which are given by way of non-limiting examples, wherein:
The present invention relates to a process for manufacturing compact coils of steel bars that allows production of ultra-fine grained, martensite-free and high ductility grades of spooled steel bars without addition of, or minimizing, microalloying elements with lower production costs.
In this description, the term “compact coil” means a coil having a filling coefficient higher than or equal to 65%, preferably in the range 65-74%, said filling coefficient being defined, considering the volume of the coil, as the ratio between density of the coil and theoretical density of the steel.
The term “ultra-fine grained”, instead, means that the microstructure has an average grain size equal to or higher than 9 according to standard ASTM E112.
The steel bar of the coil produced by means the process of the invention can have a size (i.e. diameter) preferably in the range of 8-40 mm.
The coil weight is in the range 1,0-10,0 tons, preferably in the range from 2,0 to 8,0 tons.
In all embodiments of the invention, the process for manufacturing compact coils of ultra-fine grained, martensite-free steel bars comprises the following steps:
a) rolling a steel billet with an initial surface temperature of 850-1200° C., preferably 900-1100° C., by means of a roughing rolling mill 1, producing a steel bar;
b) performing at least one first cooling stage 2 so that the steel bar has a surface temperature higher than the martensite start temperature Ms, and performing at least one first equalization stage in air to minimize the difference of temperature between core and surface of the steel bar until reaching the surface temperature in a range of 850-920° C.;
c) rolling the steel bar by means of at least one intermediate rolling mill 3, for example only one intermediate rolling mill;
d) performing at least one second cooling stage 4 always maintaining the surface temperature higher than the martensite start temperature Ms, and performing at least one second equalization stage in air to minimize the difference of temperature between core and surface of the steel bar until reaching the surface temperature in a range of 700-900° C., preferably of 750-840° C. or 750-820° C.;
e) rolling the steel bar by means of a finishing rolling mill 5 in a non-recrystallization temperature range, maintaining the whole cross-section of the steel bar within said non-recrystallization temperature range, and with a total reduction between 25 and 50% with respect to the cross-section of the steel bar at the entry of the finishing rolling mill 5, in order to obtain an ultra-fine-grained austenitic matrix;
f) winding the steel bar in a compact coil, by means at least one spooling device 7, for example two spooling devices 7, at a winding temperature in a range of 500-800° C., preferably 500-750 or 650-730° C., so that the ultra-fine-grained austenitic matrix transforms in a mixture of ferrite and pearlite.
The process of the invention can be performed according to the above mentioned steps, in the specific case of a low/medium carbon steel, in a plant with a throughput of 90-120 t/h.
The steel billet of step a) enters the roughing rolling mill 1 coming from either a reheating furnace, for example a gas furnace or an induction heater, or directly from a continuous casting machine (not shown). The surface temperature of the steel bar at the entry of the first group of rolling stands, i.e. the roughing rolling mill 1, is in the range 850-1200° C., preferably 900-1100° C.
Preferably, the steel billet is a billet of low or medium carbon steel.
Said low/medium carbon steel comprises or consists of, in weight percentage, carbon lower than or equal to 0,28%, silicon lower than or equal to 0,80%, manganese lower than or equal to 1,60%, the remaining being iron and unavoidable or possible impurities.
Preferably, the low/medium carbon steel comprises or consists of, in weight percentage, carbon in a range of 0,20-0,25%, silicon in a range of 0,20-0,70%, manganese in a range of 0,80-1,30%, possible vanadium in a range of 0,020-0,050%, the remaining being iron and unavoidable or possible impurities.
Two non-limiting examples of the steel composition are disclosed in the following table for a steel bar having a size (diameter) of 8-40 mm.
In an embodiment of the process, after the roughing rolling mill 1, the steel bar is cooled by means of at least one first cooling stage 2 so that the surface thereof does not reach the martensite start temperature (Ms), that can be calculated as per the formula
Ms(° C.)=512−453*C−16,9*Ni+15*Cr−9,5*Mo+217*C2−71,5*(C*Mn)−67,6*(C*Cr),
or, simply, Ms(° C.)=512−453*C+217*C2−71,5*(C*Mn).
An air equalization space is provided between said at least one first cooling stage 2 and the following intermediate rolling mill 3.
In a variant there is provided only one first cooling stage 2 (as shown in the
At least two second cooling stages 4 are provided after the intermediate rolling mill 3 for a higher bar surface temperature reduction, but always maintaining the surface temperature above Ms. One second equalization stage in air is provided both between the at least two second cooling stages 4 and between the last second cooling stage 4 and the finishing rolling mill 5. In said step d) no microstructural modification occurs, and both the surface and the core of the bar remain completely in the austenitic phase.
Preferably there are provided two or three second cooling stages 4, and a respective second equalization stage in air is provided between two subsequent second cooling stages 4 and between the last second cooling stage 4 and the finishing rolling mill 5. Therefore, if two second cooling stages 4 are provided there will be two second equalization stages in air. Instead, if three second cooling stages 4 are provided there will be three second equalization stages in air.
Optionally, the equalization spaces between two subsequent second cooling stages 4 can vary from 8 to 25 m, according to the plant throughput; instead, the equalization space between the last second cooling stage and the following finishing rolling mill 5 can vary between 25 and 50 m according to the plant throughput.
Preferably, the cooling-equalizing-intermediate rolling stages can be repeated multiple times, and with a variable number of second cooling stages 4 according to the plant throughput to reach the desired bar surface temperature at the entry of the finishing rolling mill 5. In this case more than one intermediate rolling mill 3 is provided. The additional intermediate rolling mills 3 are provided between two respective subsequent second cooling stages 4, in particular between the equalization space, provided after a cooling stage 4, and the subsequent cooling stage 4.
Thanks to the cooling applied in the second cooling stages 4, the surface temperature is gradually reduced until reaching the range 700-900° C., preferably of 750-840° C. or 750-820° C., at the entry of the finishing rolling mill 5.
During all the finishing rolling passes, the bar surface temperature is maintained inside the non-recrystallization range (see for example
Advantageously, the number of finishing rolling passes should be lower than or equal to four. A higher number of rolling passes may give temperature growth inside the rolled bar, that can jeopardize the microstructural process.
At the exit of the finishing rolling mill 5, as a result of the austenitic grain size refinement and of the subsequent possible controlled cooling, the final grain size is ultra-fine, resulting in values equal to or above 9, as per standard ASTM E112.
The absence of fragile phases, such as martensite and bainite, has been certified by the reduced difference of hardness (HV, preferably HV 0,5, i.e. the Vickers hardness measured with load of 4.903 N) measured between surface and core of the steel bar. Such difference is advantageously less than or equal to 40 HV, preferably in the range 10-40 HV.
Preferably, between the finishing rolling step e) and the winding step f), there are provided at least one third cooling stage 6 and at least one third equalization stage in air to minimize the difference of temperature between core and surface of the steel bar, always avoiding martensite formation, until reaching the predetermined winding temperature.
In a variant, there are provided at least two third cooling stages 6, and one third equalization stage in air is provided both between the at least two third cooling devices stages 6 and between the last third cooling stage 6 and the at least one spooling device 7.
Anyway, the one or more third cooling stages 6 are optional. These cooling stages 6 can be avoided if the bar surface temperature, coming out from the finishing rolling mill 5, is appropriate for the winding operation.
Preferably, when provided, the third cooling stages 6 are in number comprised from two to six.
The number and distance between two subsequent cooling stages 6 depend on the plant throughput. Said distance can be always equal (as shown in
One or more cooling stages 6 can be used to obtain different winding temperatures along the same steel bar in order to uniform the cooling profile of different coil layers and limit as much as possible the spread of mechanical properties. Optionally, in the winding step first and last coil layers are wound at 20-50° C. warmer than the rest of the coil layers. The reference temperature range for the winding operation is 500-800° C., preferably 650-730° C., including the higher temperatures for the first and last coil layers.
In a first embodiment, shown in
In a second embodiment, shown in
In a third embodiment, shown in
In a fourth embodiment, shown in
In these embodiments of
The horizontal dotted line represents a martensite start temperature Ms at about 500° C.
In all the steps of the process of the invention the surface temperature of the steel bar is always maintained above said martensite start temperature Ms, differently from the cooling curves of steel bars (see
Preferably, at least one first cooling stage 2 is carried out by means of a respective first cooling device, at least one second cooling stage 4 is carried out by means of a respective second cooling device, and at least one possible third cooling stage 6 is carried out by means of a respective third cooling device.
As an example, first, second and third cooling stages are water cooling stages and first, second and third cooling devices are cooling boxes, for example water cooling boxes. Preferably, the work pressure used in all the cooling stages 2, 4, 6 is in the range of 0,2-0.6 MPa.
The distance between two subsequent cooling boxes can vary from 8 to 25 m, according to the plant throughput; whereas the distance between the last cooling box and the following rolling mill can vary between 25 and 50 m according to the plant throughput.
The number of cooling boxes and the distances between each other of them and between the last cooling box and the following group of rolling stands, depend on the line throughput and the steel grade to be treated. Downstream the last cooling box of the plant, two or more spooling devices 7 are provided for winding the material treated, for example on reels.
Optionally, in all the embodiments the surface temperatures of the steel bar can be monitored by means of sensors, for example pyrometers, installed both at entry and exit of each of roughing rolling mill 1, intermediate rolling mill 3 and finishing rolling mill 5. Operative parameters of said at least one first cooling stage 2, said at least one second cooling stage 4, and possibly of said at least one third cooling stage 6 can be managed through a closed-loop automatic control, operating in both feedforward and feedback control, based on readings of said sensors.
The number of cooling stages provided along the whole line makes it possible to adapt the intensity of cooling to the steel bar chemical composition, and to the final product required mechanical properties. In the same way, the chemical composition can be used to balance the necessity of achieving higher mechanical properties, but without exceeding with the cooling inside the cooling stages, or with the lowering of the rolling temperature. Micro alloyed steel billets can be used for this purpose.
During and immediately after the winding step, the ultra-fine-grained austenitic matrix transforms in a fine mixture of ferrite and pearlite. The result is a material that, compared with the spooled rebar with quenched surface, given the same final product yield strength, has a higher ductility.
After the winding operation is completed, the compact coil can be transferred to a storage area through a transferring device 8, for example a walking beam, where a natural or forced or retarded cooling is applied to the coil.
Preferably, the surface temperature of the coil when loaded on the transferring device 8 is in the range of 600-700° C.
Along the transferring device 8 the coil can be cooled by natural air convection, or its cooling profile can be modified using an appropriate equipment. The cooling profile can be accelerated using for example fans, by blowing air or air mist, installed along the transferring device 8, or it can be retarded using for example hoods, or active soaking furnaces, covering the transferring device. Modifying the coil cooling profile can be a helpful tool to further influence the morphology of the ferritic-pearlitic mixture.
Optionally, after a cooling to room temperature in the storage area, the coil can be unwound and straightened. This operation results in an increase of the yield and tensile strength (in a minor extent), and in a reduction of the fracture elongation. By means of the straightening parameters, it is possible to apply the work hardening in different extents. Anyway, the ductility of the steel bar remains satisfactory.
As an example, and in order to better understand the essence of the invention, below are provided some typical mechanical properties, that can be obtained in compliance with the GB 1499-2:2018 standard—grade HRBF400E:
where
YS=Yield Stress;
UTS=Ultimate Tensile Stress;
El=fracture elongation.
The ratio between Ultimate Tensile Stress and Yield Stress gives an idea of the ductility of the material.
Number | Date | Country | Kind |
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102020000016153 | Jul 2020 | IT | national |
This application claims priority to PCT International Application No. PCT/EP2021/068416 filed on Jul. 2, 2021, which application claims priority to Italian Patent Application No. 102020000016153 filed on Jul. 3, 2020, the entire disclosures of which are expressly incorporated herein by reference.
Filing Document | Filing Date | Country | Kind |
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PCT/EP2021/068416 | 7/2/2021 | WO |