Abrasive articles having abrasive layer bond system derived from solid, dry-coated binder precursor particles having a fusible, radiation curable component

Abstract

The present invention involves the use of powder coating methods to form coated abrasives. In one embodiment, the powder is in the form of a multiplicity of binder precursor particles comprising a radiation curable component. In other embodiments, the powder comprises at least one metal salt of a fatty acid and optionally an organic component that may be a thermoplastic macromolecule, a radiation curable component, and/or a thermally curable macromolecule. In either embodiment, the powder exists as a solid under the desired dry coating conditions, but is easily melted at relatively low temperatures and then solidified also at reasonably low processing temperatures. The principles of the present invention can be applied to form make coats, size coats, and/or supersize coats, as desired.

Description

FIELD OF THE INVENTION

This invention is in the field of abrasive articles. More specifically, this invention relates to abrasive articles in which a powder of fusible particles is dry coated, liquefied, and then cured to form at least a portion of the bond system of the abrasive article.

BACKGROUND OF THE INVENTION

Coated abrasive articles generally comprise a backing to which a multiplicity of abrasive particles are bonded by a suitable bond system. A common type of bond system includes a make coat, a size coat, and optionally a supersize coat. The make coat includes a tough, resilient polymer binder that adheres the abrasive particles to the backing. The size coat, also including a tough resilient polymer binder that may be the same or different from the make coat binder, is applied over the make coat to reinforce the particles. The supersize coat, including one or more antiloading ingredients or perhaps grinding aids, may then be applied over the size coat if desired.

In a conventional manufacturing process, the ingredients that are used to form the make coat are dispersed or dissolved, as the case may be, in a sufficient amount of a solvent, which may be aqueous or nonaqueous, to provide the make coat formulation with a coatable viscosity. The fluid formulation is then coated onto the backing, after which the abrasive particles are applied to the make coat formulation. The make coat formulation is then dried to remove the solvent and at least partially cured. The ingredients that are used to form the size coat are also dispersed in a solvent, and the resultant fluid formulation is then applied over the make coat and abrasive particles, dried and cured. A similar technique is then used to apply the supersize coat over the size coat.

The conventional manufacturing process has some drawbacks, however, because all of the coating formulations are solvent-based. Typical make and size coat formulations may include 10 to 50 weight percent of solvent. Supersize coating formulations, in particular, require even more solvent in order to form useful coatings having the desired coating weight and viscosity. Solvents, however, can be expensive to purchase and/or to handle properly. Solvents also must be removed from the coatings, involving substantial drying costs in terms of capital equipment, energy costs, and cycle time. There are also further costs and environmental concerns associated with solvent recovery or disposal. Solvent-based coating formulations also typically require coating methods involving contact with underlying layers at the time of coating. Such contact can disrupt the orientation of the coated abrasive particles, adversely affecting abrading performance.

Not surprisingly, solventless manufacturing techniques have been investigated. One promising approach involves powder coating techniques in which a coating is formed by dry coating a powder of extremely fine, curable binder particles onto a suitable backing, melting the coated powder so that the particles fuse together to form a uniform melt layer, and then curing the melt layer to form a solid, thermoset, binder matrix. For example, PCT patent publication WO 97/25185 describes forming a binder for abrasive particles from dry powders. The dry powders comprise thermally curable phenolic resins that are dry coated onto a suitable backing. After coating, the particles are melted. Abrasive particles are then applied to the melted formulation. The melted formulation is then thermally cured to form a solid, make coat binder matrix. A size coat may be applied in the same way. Significantly, the make and size coats are formed without any solvent, and the size coat powder may be deposited without contacting, and hence disrupting, the underlying abrasive particles.

Notwithstanding the advantages offered by powder coating techniques described in PCT patent publication WO 97/25185, the powders described in this document incorporate resins that are thermally cured. The use of such resins poses substantial challenges during manufacture. Thermally cured resins generally tend to be highly viscous at reasonable processing temperatures, and thus are difficult to get to flow well. This makes it somewhat challenging to cause the binder particles to melt and fuse together in a uniform manner. The thermally curable resins also typically require relatively high temperatures to achieve curing. This limits the kinds of materials that can be incorporated into an abrasive article. In particular, many kinds of otherwise desirable backing materials could be damaged or degraded upon exposure to the temperatures required for curing. It is also difficult to control the start and rate of thermal curing. Generally, thermal curing begins as soon as heat is applied to melt the powder particles. As a consequence, the cure reaction may proceed too far before the powder particles are adequately fused. Further, the resultant bond between the cured binder and the adhesive particles may end up being weaker than is desired.

Accordingly, there is still a need for a solventless manufacturing technique for making abrasive articles that avoids disrupting abrasive particle orientation as the various component layers of the abrasive bond system are formed.

SUMMARY OF THE INVENTION

The present invention involves the use of powder coating methods to form coated abrasives. In one embodiment, the powder is in the form of a multiplicity of binder precursor particles comprising a radiation curable component. In other embodiments, the powder comprises at least one metal salt of a fatty acid and optionally an organic component that may be a thermoplastic macromolecule, a radiation curable component, and/or a thermally curable macromolecule. In either embodiment, the powder exists as a solid under the desired dry coating conditions, but is easily melted at relatively low temperatures and then solidified also at reasonably low processing temperatures. The principles of the present invention can be applied to form make coats, size coats, and/or supersize coats, as desired.

The present invention offers several advantages. Firstly, because melting and curing occur at relatively low temperatures, abrasive articles prepared in accordance with the present invention can be used with a wider range of other components, for example, backing materials, that otherwise would be damaged at higher temperatures. The ability to use lower processing temperatures also means that the present invention has lower energy demands, making the invention more efficient and economical in terms of energy costs. Additionally, the powder coatings can be applied at 100% solids with no solvent whatsoever. Therefore, emission controls, solvent handling procedures, solvent drying, solvent recovery, solvent disposal, drying ovens, energy costs associated with solvents, and the significant costs thereof, are entirely avoided. Powder coating is a noncontact coating method. Unlike many solvent coating techniques, for example, roll coating or the like, powder coating methods are noncontact and, therefore, avoid the kind of coating contact that might otherwise disrupt coated abrasive particles. This advantage is most noticeable when applying size and supersize coats over underlying make coat and abrasive particles. Powder coating methods are versatile and can be applied to a broad range of materials.

The use of dry powder particles comprising a radiation curable component and/or a metal salt of a fatty acid is particularly advantageous in that excellent control is provided over the curing process. Specifically, one can precisely control not only when cure begins, but the rate of cure as well. Thus, the premature crosslinking problems associated with conventional thermosetting powders is avoided. The result is that a binder derived from binder particles and/or powders of the present invention tends to bond more strongly to abrasive particles and is more consistently fully fused prior to curing, making manufacture much easier. As another advantage, the binder particles of the present invention comprising a radiation curable component can be formed using low molecular weight, radiation curable materials that have relatively low viscosity when melted, providing much better flow and fusing characteristics than thermally curable, resinous counterparts.

In one aspect, the present invention relates to an abrasive article comprising a plurality of abrasive particles incorporated into a bond system, wherein at least a portion of the bond system comprises a cured binder matrix derived from ingredients comprising a plurality of solid, binder precursor particles, said binder precursor particles comprising a radiation curable component that is fluidly flowable at a temperature in the range from about 35° C. to about 180° C.

In another aspect, the present invention relates to a method of forming an abrasive article, comprising the steps of (a) incorporating a plurality of abrasive particles into a bond system; and (b) deriving at least a portion of the bond system from a plurality of solid, binder precursor particles, said binder precursor particles comprising a radiation curable component that is fluidly flowable at a temperature in the range from about 35° C. to about 180° C.

In still yet another aspect, the present invention provides a powder, comprising a radiation curable component that is a solid at temperatures below about 35° C. and is fluidly flowable at a temperature in the range from about 35° C. to about 180° C.

The present invention also provides a fusible powder, comprising 100 parts by weight of a metal salt of a fatty acid and 0 to 35 parts by weight of a fusible organic component.

The present invention also relates to a method of forming a supersize coating on an underlying abrasive layer of an abrasive article. A fusible powder is dry coated onto the abrasive layer, wherein the fusible powder comprises at least one metal salt of a fatty acid. The fusible powder is liquefied to form a supersize melt layer. The supersize melt layer is solidified, whereby the supersize coating is formed.

As used herein, the term “cured binder matrix” refers to a matrix comprising a crosslinked, polymer network in which chemical linkages exist between polymer chains. A preferred cured binder matrix is generally insoluble in solvents in which the corresponding, crosslinkable binder precursor(s) is readily soluble. The term “binder precursor” refers to monomeric, oligomeric, and/or polymeric materials having pendant functionality allowing the precursors to be crosslinked to form the corresponding cured binder matrix.

If desired, the cured binder matrix of the present invention may be in the form of an interpenetrating polymer network (IPN) in which the binder matrix includes separately crosslinked, but entangled networks of polymer chains. As another option, the cured binder matrix may be in the form of a semi-IPN comprising uncrosslinked components, for example, thermoplastic oligomers or polymers that generally do not participate in crosslinking reactions, but nonetheless are entangled in the network of crosslinked polymer chains.

As used herein, the term “macromolecule” shall refer to an oligomer, a polymer, and combinations thereof.

BRIEF DESCRIPTION OF THE DRAWINGS

The above mentioned and other advantages of the present invention, and the manner of attaining them, will become more apparent and the invention itself will be better understood by reference to the following description of the embodiments of the invention taken in conjunction with the accompanying drawings, wherein:

FIG. 1 is a sectional side view of a coated abrasive article according to one embodiment of the present invention.

FIG. 2 schematically shows a reaction scheme for making one kind of radiation curable monomer suitable in the practice of the present invention.

FIG. 3 is a preferred embodiment of radiation curable monomer prepared using the reaction scheme of FIG. 2 .

FIG. 4 schematically shows a reaction scheme for making another class of radiation curable monomer suitable in the practice of the present invention.

FIG. 5 is a preferred embodiment of radiation curable monomer prepared using the reaction scheme of FIG. 4 .

FIG. 6 is a preferred embodiment of another radiation curable monomer of the present invention.

FIG. 7 schematically shows a reaction scheme for making the class of radiation curable monomers including the monomer of FIG. 6 .

FIG. 8A is a preferred embodiment of another radiation curable monomer of the present invention.

FIG. 8B is a cyanate ester novolak oligomer suitable in the practice of the present invention.

FIG. 9 shows a general formula for a metal salt of a fatty acid suitable in the practice of the present invention.

FIG. 10 shows the formula for one embodiment of a radiation curable novolak type phenolic oligomer suitable in the practice of the present invention.

FIG. 11 shows a formula for one type of a radiation curable epoxy oligomer suitable in the practice of the present invention.

FIG. 12 is a schematic representation of an apparatus for making a coated abrasive of the present invention having make, size and supersize coatings.

DETAILED DESCRIPTION OF THE PRESENTLY PREFERRED EMBODIMENTS

The radiation curable, fusible binder precursor particles of the present invention may be incorporated into a wide range of different kinds of abrasive articles with beneficial results. For purposes of illustration, the radiation curable, fusible binder precursor particles will be described with respect to the particular flexible, coated abrasive article 10 illustrated in FIG. 1 . The embodiments of the present invention described in connection with FIG. 1 are not intended to be exhaustive or to limit the invention to the precise forms disclosed in the following detailed description. Rather the embodiments are chosen and described so that others skilled in the art may appreciate and understand the principles and practices of the present invention.

Abrasive article 10 generally includes backing 12 and abrasive layer 14 bonded to backing 12 . Backing 12 may be any suitable backing and typically may be comprised of paper, vulcanized rubber, a polymeric film (primed or unprimed), a woven or nonwoven fibrous material, composites of these, and the like. Backings made from paper typically may have a basis weight in the range from 25 g/m 2 to 300 g/m 2 or more. Backings made from paper or fibrous materials optionally may be treated with a presize, backsize, and/or saturant coating in accordance with conventional practices. Specific materials suitable for use as backing 12 are well known in the art and have been described, for example, in U.S. Pat. Nos. 5,436,063; 4,991,362; and 2,958,593, incorporated herein by reference.

Abrasive coating 14 includes a plurality of abrasive particles 16 functionally distributed in bond system 18 generally comprising make coat 20 , size coat 22 , and optional supersize coat 24 . Abrasive particles 16 may comprise any suitable abrasive material or combination of materials having abrading capabilities. Abrasive particles 16 preferably comprise at least one material having a Mohs hardness of at least about 8, more preferably at least about 9. Examples of such materials include fused aluminum oxide, heat treated aluminum oxide, white fused aluminum oxide, black silicon carbide, green silicon carbide, titanium diboride, boron carbide, tungsten carbide, titanium carbide, diamond, silica, iron oxide, chromia, ceria, zirconia, titania, silicates, tin oxide, cubic boron nitride, garnet, fused alumina zirconia, sol gel abrasive particles, combinations of these, and the like. As an option, abrasive particles 16 may include a surface coating to enhance the performance of the particles in accordance with conventional practices. In some instances, the surface coating can be formed from a material, such as a silane coupling agent, that increases adhesion between abrasive particles 16 and the binders used in make coat 20 , size coat 22 , and/or supersize coat 24 .

Abrasive particles 16 can be present in any suitable size(s) and shape(s). For example, with respect to size, preferred abrasive particles 16 typically have an average size in the range from about 0.1 micrometers to 2500 micrometers, more preferably from about 1 micrometer to 1300 micrometers. Abrasive particles 16 may also have any shape suitable for carrying out abrading operations. Examples of such shapes include rods, triangles, pyramids, cones, solid spheres, hollow spheres, combinations of these, and the like. Abrasive particles 16 may be present in substantially nonagglomerated form or, alternatively, may be in the form of abrasive agglomerates in which individual particles are adhered together. Examples of abrasive agglomerates are described in U.S. Pat. No. 4,652,275 and U.S. Pat. No. 4,799,939, which patents are incorporated herein by reference.

Make coat 20 helps adhere abrasive particles 16 to backing 12 . Size coat 22 is applied over make coat 20 and abrasive particles 16 in order to reinforce particles 16 . Optional supersize coat 24 may be included over size coat 22 in order to prevent or reduce the accumulation of swarf (the material abraded from a workpiece) among abrasive particles 16 during abrading operations. Swarf accumulation might otherwise dramatically reduce the cutting ability of abrasive article 10 over time. Alternatively, supersize coat 24 may also be included over size coat 22 in order to incorporate grinding aids into abrasive article 10 . Supersize coatings are further described in European Patent Publication No. 486, 308, which is incorporated herein by reference.

In the practice of the present invention, at least portions of one or more of make coat 20 , size coat 22 , and/or supersize coat 24 constituting bond system 18 comprise a cured binder matrix derived from the binder precursor particles of the present invention. The binder precursor particles of the present invention generally include a radiation curable component that may be formed from any one or more radiation curable, fusible materials that can be dry coated in particulate form, then liquefied to convert the precursor material into a fluid, melt layer, and then cured by exposure to a suitable source of curing energy to convert the fluid melt layer into a thermoset, solid, cured binder matrix component of bond system 18 .

In the practice of the present invention, “radiation curable” refers to functionality directly or indirectly pendant from a monomer, oligomer, or polymer backbone (as the case may be) that participate in crosslinking reactions upon exposure to a suitable source of curing energy. Such functionality generally includes not only groups that crosslink via a cationic mechanism upon radiation exposure but also groups that crosslink via a free radical mechanism. Representative examples of radiation crosslinkable groups suitable in the practice of the present invention include epoxy groups, (meth)acrylate groups, olefinic carbon-carbon double bonds, allyloxy groups, alpha-methyl styrene groups, (meth)acrylamide groups, cyanate ester groups, vinyl ethers groups, combinations of these, and the like.

The energy source used for achieving crosslinking of the radiation curable functionality may be actinic (for example, radiation having a wavelength in the ultraviolet or visible region of the spectrum), accelerated particles (for example, electron beam radiation), thermal (for example, heat or infrared radiation), or the like. Preferably, the energy is actinic radiation or accelerated particles, because such energy provides excellent control over the initiation and rate of crosslinking. Additionally, actinic radiation and accelerated particles can be used for curing at relatively low temperatures. This avoids degrading components of abrasive article 10 that might be sensitive to the relatively high temperatures that might be required to initiate crosslinking of the radiation curable groups when using thermal curing techniques. Suitable sources of actinic radiation include a mercury lamp, a xenon lamp, a carbon arc lamp, a tungsten filament lamp, sunlight, and the like. Ultraviolet radiation, especially from a medium pressure mercury arc lamp, is most preferred.

The amount of curing energy to be used for curing depends upon a number of factors, such as the amount and the type of reactants involved, the energy source, web speed, the distance from the energy source, and the thickness of the bond layer to be cured. Generally, the rate of curing tends to increase with increased energy intensity. The rate of curing also may tend to increase with increasing amounts of photocatalyst and/or photoinitiator being present in the composition. As general guidelines, actinic radiation typically involves a total energy exposure from about 0.1 to about 10 J/cm 2 , and electron beam radiation typically involves a total energy exposure in the range from less than 1 Megarad to 100 Megarads or more, preferably 1 to 10 Mrads. Exposure times may be from less than about 1 second up to 10 minutes or more. Radiation exposure may occur in air or in an inert atmosphere such as nitrogen.

The particle size of the binder precursor particles of the present invention is not particularly limited so long as the particles can be adequately fused and then cured to form desired portions of bond system 18 with the desired level of uniformity and performance. If the particles are too big, it is more difficult to control the uniformity of coating thickness. Larger particles are also not as free flowing as smaller particles. Therefore, particles with a smaller average particle size such that the particles are in the form of a free flowing powder are preferred. However, extremely small particles may pose a safety hazard. Additionally, control over coating thickness also may become more difficult when using extremely small particles. Accordingly, as general guidelines, preferred binder precursor particles generally have an average particle size of less than about 500 micrometers, preferably less than about 125 micrometers, and more preferably 10 to 90 micrometers. In the practice of the present invention, the average particle size of the particles may be determined by laser diffraction using an instrument commercially available under the trade designation “HORIBA LA-910” from Horiba Ltd.

In preferred embodiments of the invention, the radiation curable component of the fusible binder precursor particles comprises one or more radiation curable monomers, oligomers, and/or polymers that, at least in combination, exist as a solid at about room temperature, for example, 20° C. to about 25° C., to facilitate dry coating under ambient conditions, but then melt or otherwise become fluidly flowable at moderate temperatures in the range from about 35° C. to about 180° C., preferably 40° C. to about 140° C., to facilitate fusing and curing without resort to higher temperatures that might otherwise damage other components of abrasive article 10 . The term “monomer” as used herein refers to a single, one unit molecule capable of combination with itself or other monomers to form oligomers or polymers. The term “oligomer” refers to a compound that is a combination of 2 to 20 monomer units. The term “polymer” refers to a compound that is a combination of 21 or more monomer units.

Of course, in alternative, less preferred embodiments of the invention, the radiation curable component may exist as a solid only at relatively cool temperatures below ambient conditions. However, such embodiments would involve carrying out dry coating at correspondingly cool temperatures to ensure that the radiation curable component was solid during dry coating. Similarly, in other alternative embodiments of the invention, the radiation curable component may exist as a solid up to higher temperatures above about 180° C. However, such embodiments would involve carrying out melting and curing at correspondingly higher temperatures as well, which could damage other, temperature sensitive components of abrasive article 10 .

Generally, any radiation curable monomer, oligomer, and/or polymer, or combinations thereof, that is solid under the desired dry coating conditions and that may be melted under the desired melt processing conditions may be incorporated into the radiation curable component. Accordingly, the present invention is not intended to be limited to specific kinds of radiation curable monomers, oligomers, and polymers so long as these processing conditions are satisfied. However, particularly preferred radiation curable components that have excellent flow characteristics when liquefied generally comprise at least one polyfunctional, radiation curable monomer and at least one polyfunctional, radiation curable macromolecule (that is, an oligomer or polymer, preferably an oligomer), wherein at least one of the monomer and/or the macromolecule has a solid to nonsolid phase transition at a sufficiently high temperature such that the combination of the monomer and macromolecule is a solid below about 35° C., but is liquefied at a temperature in the range from about 35° C. to about 180° C., preferably 40° C. to about 140° C. More preferably, it is the monomer that is a solid, by itself, and the macromolecule, by itself, may or may not be a solid under the noted temperature ranges. In the practice of the present invention, radiation curable components comprising one or more monomers and one or more oligomers are preferred over embodiments including polymers. Blends of oligomers and monomers tend to have lower viscosity and better flow characteristics at lower temperatures, thus easing melting and fusing of the particles during processing.

For example, representative embodiments of radiation curable components suitable in the practice of the present invention include the following components:

Embodiment Compounds
1          a solid, radiation curable, polyfunctional monomer having a
           melting point in the range from 35° C. to 180° C.
2          a solid, radiation curable, polyfunctional macromolecule
           having a glass transition temperature in the range from
           35° C. to 180° C.
3          a solid blend including 10 to 90 parts by weight of a solid,
           radiation curable, polyfunctional monomer and 10 to 90
           parts by weight of a solid, radiation curable, polyfunctional
           macromolecule
4          a solid blend including 10 to 90 parts by weight of a solid,
           radiation curable, polyfunctional monomer and 10 to 90
           parts by weight of a liquid, radiation curable, polyfunctional
           macromolecule
5          a solid blend including 10 to 80 parts by weight of a liquid,
           radiation curable, polyfunctional monomer and 10 to 80
           parts by weight of a solid, radiation curable, polyfunctional
           macromolecule
6          a solid blend comprising 0.1 to 10 parts by weight of a
           liquid, radiation curable, polyfunctional monomer and 100
           parts by weight of a metal salt of a fatty acid (make coat
           and/or size coat)
7          a solid blend comprising 0 to 30 parts by weight of a liquid,
           radiation curable, polyfunctional macromolecule and 100
           parts by weight of a metal salt of a fatty acid (supersize
           coat)
8          a solid blend comprising 100 parts by weight of a solid,
           radiation curable, polyfunctional monomer and 0.1 to 10
           parts by weight of a metal salt of a fatty acid (make coat
           and/or size coat)
9          a solid blend comprising 0 to 30 parts by weight of a solid,
           radiation curable, polyfunctional macromolecule and 100
           parts by weight of a metal salt of a fatty acid (supersize
           coat)

With respect to the monomer, the solid to nonsolid phase transition is typically the melting point of the monomer. With respect to the macromolecule, the solid to nonsolid phase transition is typically the glass transition temperature of the macromolecule. In the practice of the present invention, glass transition temperature, Tg, is determined using differential scanning calorimetry (DSC) techniques. The term “polyfunctional” with respect to the monomer or macromolecule means that the material comprises, on average, more than 1 radiation curable group, preferably two or more radiation curable groups, per molecule. Polyfunctional monomers, oligomers, and polymers cure quickly into a crosslinked network due to the multiple radiation curable groups available on each molecule. Further, polyfunctional materials are preferred in this invention to encourage and promote polymeric network formation in order to provide bond system 18 with toughness and resilience.

Preferred monomers, oligomers, and polymers of the present invention are aromatic and/or heterocyclic. Aromatic and/or heterocyclic materials generally tend to be thermally stable when melt processed and also tend to have melting point and/or Tg characteristics in the preferred temperature ranges noted above. As an option, at least one of the monomer and the macromolecule, preferably the macromolecule, further comprises OH, that is, hydroxyl, functionality. While not wishing to be bound by theory, it is believed that the OH functionality helps promote adhesion between abrasive particles 16 and the corresponding portion of bond system 18 . Preferably, the macromolecule includes, on average, 0.1 to 1 OH groups per monomeric unit incorporated into the macromolecule.

For purposes of illustration, representative examples of suitable radiation curable monomers, oligomers, and polymers will now be described.

One representative class of polyfunctional, radiation curable, aromatic monomers and/or oligomers is shown in FIG. 2 . FIG. 2 schematically shows reaction scheme 30 by which hydroxyl functional (meth)acrylate reactant 32 reacts with dicarboxylic acid reactant 34 to form radiation curable, poly(meth)acrylate functional polyester monomer 36 . The moiety W of reactant 34 desirably comprises an aromatic moiety for the reasons described above. The moiety Z is any suitable divalent linking group. Any kinds of hydroxyl functional (meth)acrylate reactant 32 and such aromatic dicarboxylic acid reactant 34 may be reacted together so long as the resultant radiation curable component is a solid under the desired dry coating conditions and has a melting point in the desired processing range. Examples of hydroxyl functional (meth)acrylate reactant 32 include hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxybutyl acrylate, hydroxybutyl methacrylate, combinations of these, and the like. Examples of aromatic dicarboxylic acid reactant 34 include terephthalic acid, isophthalic acid, phthalic acid, combinations of these, and the like. Although reactant 34 is shown as a dicarboxylic acid, an acid dihalide, diester, or the like could be used instead. The moiety X in monomer 36 is a divalent linking group typically identical to Z. R is hydrogen or a lower alkyl group of 1 to 4 carbon atoms, preferably —H or —CH 3 .

FIG. 3 shows a particularly preferred embodiment of a radiation curable monomer 38 prepared in accordance with the reaction scheme of FIG. 2 . Radiation curable monomer 38 has a melting point of 97° C. The radiation curable monomers 36 and 38 of FIGS. 2 and 3 , and methods of making such monomers are further described in U.S. Pat. No. 5,523,152, incorporated herein by reference.

Another representative class of monomers in the form of radiation curable vinyl ether monomer 40 suitable in the practice of the present invention is shown as the product in FIG. 4 of a reaction between diisocyanate reactant 42 and hydroxyl functional vinyl ether reactant 44 . The moiety W′ desirably includes an aromatic moiety in the backbone for the reasons described above, and Z′ is a suitable divalent linking group. R is as defined above in FIG. 2 . Any kinds of hydroxyl functional vinyl ether reactant 44 and diisocyante reactant 42 may be reacted together so long as the resultant radiation curable component is a solid under the desired dry coating conditions and has a melting point in the desired processing range. Examples of hydroxyl functional vinyl ether reactant 44 include 4-hydroxybutyl vinyl ether (HO CH 2 CH 2 CH 2 CH 2 OCH=CH 2 ) and the like. Examples of diisocyanate reactant 42 include diphenylmethane-4, 4-diisocyanate, toluene diisocyanate, combinations of these, and the like. The reaction scheme of FIG. 4 may also be carried out using a compound such as a hydroxyl functional (meth)acrylate in place of hydroxyl functional vinyl ether reactant 44 .

FIG. 5 shows a particularly preferred embodiment of a radiation curable vinyl ether monomer 50 prepared in accordance with the reaction scheme of FIG. 4 . Radiation curable vinyl ether monomer 50 has a melting point of 60-65° C.

FIG. 6 shows another example of a suitable radiation curable, aromatic monomer 60 commonly referred to in the art as tris (2-hydroxyethyl) isocyanurate triacrylate, or “TATHEIC” for short. This monomer has a melting point in the range from 35° C. to 40° C. The TATHEIC monomer is generally formed by reaction scheme 70 of FIG. 7 in which hydroxyl functional isocyanurate 72 is reacted with carboxylic acid 74 to form acrylated isocyanurate 76 . The X″ moiety may be any suitable divalent linking group such as —CH 2 CH 2 — or the like. The acrylate form is shown in FIG. 6 , but monomer 60 could be a methacrylate or the like as well.

FIG. 8A shows another example of a radiation curable, aromatic monomer in the form of an aromatic cyanate ester 80 . This monomer has a melting point of 78° C. to 80° C. This and similar monomers have been described in U.S. Pat. No. 4,028,393. Other cyanate esters are described in U.S. Pat. Nos. 5,215,860; 5,294,517; and 5,387,492, the cyanate ester descriptions incorporated by reference herein.

Other examples of radiation curable monomers that may be incorporated into the radiation curable component of the present invention include, for example, ethylene glycol diacrylate, ethylene glycol dimethacrylate, hexanediol diacrylate, hexanediol dimethacrylate, triethylene glycol diacrylate, triethylene glycol dimethacrylate, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, ethoxylated trimethylolpropane triacrylate, ethoxylated trimethylolpropane trimethacrylate, glycerol triacrylate, glycerol trimethacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate, pentaerythritol tetracrylate, pentaerythritol tetramethacrylate, neopentylglycol diacrylate, and neopentylglycol dimethacrylate. Mixtures and combinations of different types of polyfunctional (meth)acrylates also can be used. Although some of these other monomer examples might not be solids under ambient conditions by themselves, blends of these monomers with other radiation curable ingredients may nonetheless provide particles having the desired solid characteristics.

Preferred radiation curable oligomers of the present invention generally have a number average molecular weight in the range from about 400 to 5000, preferably about 800 to about 2500 and either are solid at ambient conditions, or if not solid under ambient conditions, nonetheless form solid blends in combination with other ingredients of the radiation curable component. In addition to radiation curable functionality, preferred oligomers of the present invention also preferably include pendant hydroxyl functionality and are aromatic.

One preferred class of radiation curable, hydroxyl functional, aromatic oligomers found to be suitable in the practice of the present invention includes the class of radiation curable, novolak-type phenolic oligomers. A representative radiation curable, aromatic novolak-type phenolic oligomer 90 having pendant cyanate ester functionality is shown in FIG. 8B , wherein n has a value in the range from about 3 to about 20, preferably 3 to 10. Another representative, radiation curable oligomer 100 having pendant acrylamide functionality and hydroxyl functionality (a combination of functionality that is particularly beneficial when incorporated into a make coat formulation) is shown in FIG. 10 , wherein n has an average value in the range from about 3 to 20, preferably 3 to 10. In a particularly preferred embodiment, n has an average value of about 3 to 5. Interestingly, the resultant oligomer for which the average value of n is about 3 to 5 tends to have a taffy-like consistency under ambient conditions. Advantageously, however, such oligomer readily forms solid particles when combined with other solid, radiation curable monomers, oligomers, and polymers to facilitate dry coating, but flows easily when heated after dry coating, facilitating formation of uniform, fused binder matrices. The class of radiation curable, novolak-type phenolic oligomers, including the particular oligomer 100 shown in FIG. 10 has been described generally in U.S. Pat. Nos. 4,903,440 and 5,236,472, incorporated herein by reference.

Another preferred class of radiation curable, hydroxyl functional, aromatic oligomers found to be suitable in the practice of the present invention includes the class of epoxy oligomers obtained, for example, by chain extending bisphenol A up to a suitable molecular weight and then functionalizing the resultant oligomer with radiation curable functionality. For example, FIG. 11 illustrates such an epoxy oligomer 110 which has been reacted with an acrylic acid to provide radiation curable functionality. Preferably, n of FIG. 11 has a value such that oligomer 110 has a number average molecular weight in the range from about 800 to 5000, preferably about 1000 to 1200. Such materials typically are viscous liquids under ambient conditions but nonetheless form solid powders when blended with other solid materials such as solid monomers, solid macromolecules, and/or calcium and/or zinc stearate. Accordingly, such materials also can be easily dry coated in solid form under ambient conditions, but then demonstrate excellent flow characteristics upon heating to facilitate formation of binder matrices having desired performance characteristics. Indeed, any oligomer that has this dual liquid/solid behavior under ambient conditions would be particularly advantageous with respect to achieving such processing advantages. Acrylate oligomers according to FIG. 11 are available under the trade designations “RSX29522” and “EBECRYL 3720”, respectively, from UCB Chemicals Corp., Smyrna, Ga.

Of course, the oligomers suitable in the practice of the present invention are not limited solely to the preferred novolak-type phenolic oligomers or epoxy oligomers described above. For instance, other radiation curable oligomers that are solid at room temperature, or that form solids at room temperature in blends with other ingredients, include polyether oligomers such as polyethylene glycol 200 diacrylate having the trade designation “SR259” and polyethylene glycol 400 diacrylate having the trade designation “SR344,” both being commercially available from Sartomer Co., Exton, Pa.; and acrylated epoxies available under the trade designations “CMD 3500,” “CMD 3600,” and “CMD 3700,” from Radcure Specialties.

A wide variety of radiation curable polymers also can be beneficially incorporated into the radiation curable component, although polymers tend to be more viscous and do not flow as easily upon heating as compared to monomers and oligomers. Representative radiation curable polymers of the present invention comprise vinyl ether functionality, cyanate ester functionality, (meth)acrylate functionality, (meth)acrylamide functionality, cyanate ester functionality, epoxy functionality, combinations thereof, and the like. Representative examples of polymers that may be functionalized with one or more of these radiation curable groups include polyamides, phenolic resins, epoxy resins, polyurethanes, vinyl copolymers, polycarbonates, polyesters, polyethers, polysulfones, polyimides, combinations of these, and the like.

For example, in one embodiment, the radiation curable polymer may be an epoxy functional resin having at least one oxirane ring polymerizable by a ring opening reaction. These materials generally have, on the average, at least two epoxy groups per molecule (preferably more than two epoxy groups per molecule). The polymeric epoxides include linear polymers having terminal epoxy groups (for example, a diglycidyl ether of a polyoxyalkylene glycol), polymers having skeletal oxirane units (for example, polybutadiene polyepoxide), and polymers having pendent epoxy groups (for example, a glycidyl methacrylate polymer or copolymer). The number average molecular weight of the epoxy functional resin most typically may vary from about 1000 to about 5000 or more.

Another useful class of epoxy functional macromolecules includes those which contain cyclohexene oxide groups derived from monomers such as the epoxycyclohexanecarboxylates, typified by 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, 3,4-epoxy-2-methylcyclohexylmethyl-3,4-epoxy-2-methylcyclohexane carboxylate, and bis(3,4-epoxy-6-methylcyclohexylmethyl) adipate. For a more detailed list of useful epoxides of this nature, reference may be made to U.S. Pat. No. 3,117,099, incorporated herein by reference.

Further epoxy functional macromolecules which are particularly useful in the practice of this invention include resins incorporating glycidyl ether monomers of the formula

where R′ is alkyl or aryl and n is an integer of 1 to 6. Examples are the glycidyl ethers of polyhydric phenols obtained by reacting a polyhydric phenol with an excess of chlorohydrin such as epichlorohydrin, for example, the diglycidyl ether of 2,2-bis-2,3-epoxypropoxyphenol propane. Further examples of epoxides of this type are described in U.S. Pat. No. 3,018,262, incorporated herein by reference.

There are also several commercially available epoxy macromolecules that can be used in this invention. In particular, epoxides which are readily available include octadecylene oxide, epichlorohydrin, styrene oxide, vinyl cyclohexene oxide, glycidol, glycidyl-methacrylate, diglycidyl ether of Bisphenol A (for example, those available under the trade designations “EPON 828,” “EPON 1004,” and “EPON 1001F” from Shell Chemical Co., and “DER-332” and “DER-334,” from Dow Chemical Co.), diglycidyl ether of Bisphenol F (for example, “ARALDITE GY281” from Ciba-Geigy), vinylcyclohexene dioxide (for example, having the trade designation “ERL 4206” from Union Carbide Corp.), 3,4-epoxycyclohexyl-methyl-3,4-epoxycyclohexene carboxylate (for example, having the trade designation “ERL-4221” from Union Carbide Corp.), 2-(3,4-epoxycyclohexyl-5,5-spiro-3,4-epoxy) cyclohexane-metadioxane (for example, having the trade designation “ERL-4234” from Union Carbide Corp.), bis(3,4-epoxy-cyclohexyl) adipate (for example, having the trade designation “ERL-4299” from Union Carbide Corp.), dipentene dioxide (for example, having the trade designation “ERL-4269” from Union Carbide Corp.), epoxidized polybutadiene (for example, having the trade designation “OXIRON 2001” from FMC Corp.), silicone resin containing epoxy functionality, epoxy silanes, for example, beta-3,4-epoxycyclohexylethyltri-methoxy silane and gamma-glycidoxypropyltrimethoxy silane, commercially available from Union Carbide, flame retardant epoxy resins (for example, having the trade designation “DER-542,” a brominated bisphenol type epoxy resin available from Dow Chemical Co.), 1,4-butanediol diglycidyl ether (for example, having the trade designation “ARALDITE RD-2” from Ciba-Geigy), hydrogenated bisphenol A-epichlorohydrin based epoxy resins (for example having the trade designation “EPONEX 1510” from Shell Chemical Co.), and polyglycidyl ether of phenol-formaldehyde novolak (for example, having the trade designation “DEN-431” and “DEN-438” from Dow Chemical Co.).

It is also within the scope of this invention to use an epoxy functional macromolecule that has both epoxy and (meth)acrylate functionality. For example, one such resin having such dual functionality is described in U.S. Pat. No. 4,751,138 (Tumey et al.), which is incorporated herein by reference.

In addition to the radiation curable component, the binder precursor particles of the present invention may also include a thermoplastic resin in order to adjust the properties of the particles and/or the resultant cured binder matrix. For example, thermoplastic resins can be incorporated into the particles in order to adjust flow properties of the particles upon being melted, to allow the melt layer to display pressure sensitive adhesive properties so that abrasive particles more aggressively adhere to the melt layer prior to curing (desirable for a make coat), to adjust the flexibility characteristics of the resultant cured binder matrix, combinations of these objectives, and the like. Just a few examples of the many different kinds of thermoplastic polymers useful in the present invention include polyester, polyurethane, polyamide, combinations of these, and the like. When used, the binder precursor particles may include up to 30 parts by weight of a thermoplastic component per 100 parts by weight of the radiation curable component.

In alternative embodiments of the present invention, rather than using binder precursor particles as described above to form supersize coat 24 , at least a portion of supersize coat 24 can be made from a fusible powder comprising at least one metal salt of a fatty acid. Advantageously, metal salts of a fatty acid function as an antiloading agent, a binder component, and/or a flow control agent, when incorporated into supersize coat 24 . Although not required, the fusible powder may also include a binder comprising one or more monomers and/or macromolecules that may be thermoplastic, thermally curable, and/or radiation curable as described above in connection with the binder precursor particles. In typical embodiments, the fusible powder comprises 70 to 95 parts by weight of at least one metal salt of a fatty acid and 0 to 30 parts by weight of the binder.

The metal salts of a fatty acid ester suitable for use in the fusible powder generally may be represented by formula 90 shown in FIG. 9 wherein R′ is a saturated or unsaturated moiety, preferably an alkyl group having at least 10, preferably 12 to 30, carbon atoms, M is a metal cation having a valence of n, wherein n typically is 1 to 3. Specific examples of compounds according to formula 90 of FIG. 9 include lithium stearate, zinc stearate, calcium stearate, magnesium stearate combinations of these, and the like. The metal salt of a fatty acid preferably is calcium stearate, zinc stearate, or a combination thereof wherein the weight ratio of calcium stearate to zinc stearate is in the range from 1:1 to 9:1. The use of a powder comprising a combination of calcium and zinc stearates also provides an excellent way to control the melting characteristics of the powder. For example, if it is desired to increase the melting temperature of the powder, the amount of calcium stearate being used can be increased relative to the amount of zinc stearate. Conversely, if it is desired to lower the melting temperature of the powder, the amount of zinc stearate being used can be increased relative to the amount of calcium stearate. Calcium stearate is unique in that this material never truly melts. However, in fine powder form, for example, a powder having an average particle size of less than about 125 micrometers, calcium stearate can be used by itself, or in combination with other materials, to provide powders that readily flow when heated at moderately low processing temperatures.

Uniquely, solid embodiments of metal salts of fatty acids, for example, the metal stearates, may be blended with liquid monomers, oligomers, and/or polymers to form blends that, nonetheless, are solid and can be ground to form fine powders. Such powders have excellent viscosity, fusing, and flow characteristics when melt processed at reasonably low melt processing temperatures. Embodiments demonstrating this advantage of the invention will be described further below in the examples.

Optimally, the fusible powder of the present invention may include one or more fatty acids. Advantageously, the presence of a fatty acid makes it easier to melt process the fusible powder at reasonably low processing temperatures, for example, 35° C. to 180° C. For example, a preferred embodiment of a fusible powder of the present invention might include calcium stearate (a metal salt of a fatty acid) as a major component. A fusible powder including just calcium stearate by itself tends to be difficult to melt process, because calcium stearate never truly melts. However, if a fatty acid is incorporated into the fusible powder along with calcium stearate, the resultant blend can be readily melt processed at convenient temperatures.

Generally, preferred embodiments of the present invention include a sufficient amount of a fatty acid so that the fusible powder can be melt processed at the desired temperature, for example a temperature in the range from 35° C. to 180° C. Preferred fusible powders of the present invention incorporate up to 30, preferably about 10, parts by weight of one or more fatty acids per 70 to 100, preferably about 90, parts by weight of the metal salt of a fatty acid. Although any fatty acid can be used in the present invention, a preferred fatty acid is the corresponding acid form of the metal salt of a fatty acid being used. For instance, stearic acid is a preferred fatty acid when the metal salt of a fatty acid is a stearate, for example, zinc stearate or calcium stearate.

The binder precursor particles and/or fusible powder of the present invention may also include one or more grinding aids. Useful examples of classes of grinding aids include waxes, organic halide compounds, halide salts, metals, and alloys of metals. Organic halide compounds typically break down during abrading and release a halogen acid or a gaseous halide compound. Examples of organic halides include chlorinated waxes, such as tetrachloronapthalene, pentachloronapthalene, and polyvinyl chloride. Chlorinated waxes can also be considered to be waxes. Examples of halide salts include sodium chloride (NaCl), potassium chloride (KCl), potassium fluoroborate (KBF 4 ), ammonium cryolite (NH4) 3 AlF 6 ), cryolite (Na 3 AlF 6 ),and magnesium chloride (MgCl 2 ). Examples of metals include tin, lead, bismuth, cobalt, antimony, cadmium, iron, and titanium. Other grinding aids include sulfur and organic sulfur compounds, graphite, and metallic sulfides. Combinations of grinding aids can be used. The preferred grinding aid for stainless steel is potassium fluoroborate. The preferred grinding aid for mild steel is cryolite. The ratio of the fusible organic component to grinding aid ranges from 0 to 95, preferably ranges from about 10 to about 85, more preferably about 15 to about 60, parts by weight of a fusible organic component to about 5 to 100, preferably about 15 to about 85, more preferably about 40 to about 85, parts by weight grinding aid.

The binder precursor particles and/or fusible powder of the present invention additionally may comprise one or more optional additives, such as, plasticizers, other antiloading agents (that is, materials useful for reducing or preventing swarf accumulation), grinding aids, surface modification agents, fillers, flow agents, curing agents, hydroxyl containing additives, tackifiers, grinding aids, expanding agents, fibers, antistatic agents, lubricants, pigments, dyes, UV stabilizers, fungicides, bacteriocides, and the like. These additional kinds of additives may be incorporated into the binder precursor particles in according to conventional practices.

Selecting a suitable composition of the binder precursor particles and/or fusible powder for a particular application will depend, to a large extent, upon the portion of bond system 18 into which the particles will be incorporated. Different compositions may be more desirable depending upon whether the binder precursor particles are to be incorporated into make coat 20 , size coat 22 , and/or supersize coat 24 . Further, not all binder precursor particles to be incorporated into bond system 18 need be the same. Binder precursor particles of one composition, for instance, may be incorporated into make coat 20 and size coat 22 , while binder precursor particles of a second composition are incorporated into supersize coat 24 .

In one embodiment of the present invention suitable for use in make coat 20 and/or size coat 22 , a preferred binder precursor particle composition (Make/Size Composition I) comprises 100 parts by weight of a radiation curable binder component, about 1 to 5 parts by weight of a flow control agent, and about 0.5 to 5 parts by weight of a photoinitiator or photocatalyst. The preferred radiation curable binder component comprises a (i) solid, radiation curable monomer and (ii) a solid radiation curable oligomer and/or polymer, wherein the weight ratio of the monomer to the oligomer/polymer is in the range from 1:10 to 10:1, preferably 1:4 to 4:1, more preferably about 1:1. Preferred examples of the solid monomer include the monomer of FIG. 3 , the cyanate ester of FIG. 8 , and the TATHEIC monomer of FIG. 6 . Preferred examples of the solid oligomer/polymer include the epoxy functional resin commercially available under the trade designation “EPON 1001F” from Shell Chemical Co. and the acrylate functional oligomer available under the trade designation “RSX 29522” from UCB Chemicals Corp. Preferred flow control agents include waxes and acrylic copolymers commercially available under the trade designation Modarez MFP-V from Synthron, Inc., metal stearates such as zinc stearate and/or calcium stearate, combinations of these, and the like. These ingredients may be melt blended together, cooled, and then ground into a free flowing powder of the desired average particle size.

In an alternative embodiment of the present invention suitable for forming make coat 20 and size coat 22 , a composition (Make/Size Composition II) identical to Make/Size Composition I is used, except that a liquid oligomer and/or polymer is substituted for the solid oligomer/polymer. Most preferably, the liquid oligomer or polymer is highly viscous. “Highly viscous” means that the material is a liquid at 25° C. and has a weight average molecular weight of at least about 5000, preferably at least about 8000, more preferably at least about 10,000. Preferred examples of highly viscous oligomers and polymers include the oligomer of FIG. 10 in which n is about 5, as well as the acrylate functional resin of FIG. 11 .

For another embodiment of the present invention suitable for use in supersize coat 24 , a preferred binder precursor particle composition (Supersize Composition I) comprises 75 to 95 parts by weight of a solid metal salt of a fatty acid, about 5 to 25 parts by weight of a liquid, radiation curable monomer, oligomer and/or polymer, and about 1 to 5 parts by weight of a photoinitiator or photocatalyst. Notwithstanding the liquid character of the radiation curable monomer, oligomer, and/or polymer, the ingredients can be melt blended, cooled, and then ground to form a free flowing, solid powder. Preferred metal salts of a fatty acid include zinc stearate, calcium stearate, and combinations of these. Preferred liquid materials include acrylate functional epoxy oligomers available under the trade designations “EBECRYL 3720 and 302”, acrylate functional polyester available under the trade designation “EBECRYL 450”, acrylate functional polyurethanes available under the trade designation “EBECRYL 8804 and 270”, ethoxylated trimethylol propane triacrylate, and the novolak-type phenolic oligomer of FIG. 10 , wherein n is about 5.

For another embodiment of the present invention suitable for use in supersize coat 24 , a preferred binder precursor particle composition (Supersize Composition II) is identical to Supersize Composition I except that one or more solid radiation curable monomers, oligomers, and/or polymers is substituted for the liquid radiation curable materials. Preferred examples of the solid radiation curable material include the monomer of FIG. 3 , the cyanate ester of FIG. 8 , and the TATHEIC monomer of FIG. 6 . Preferred examples of the solid oligomer/polymer include the epoxy functional resin commercially available under the trade designation “EPON 1001F” and the acrylate functional oligomer available under the trade designation “RSX 29522”.

For another embodiment of the present invention suitable for use in supersize coat 24 , a preferred binder precursor particle composition (Supersize Composition III) comprises 70 to 95 parts by weight of a metal salt of a fatty acid as described above, 5 to 30 parts by weight of a thermoplastic resin, and optionally 5 to 30 parts by weight of a solid or liquid radiation curable component as described above. Preferred examples of thermoplastic resins include polyamides, polyesters, ethylene vinyl acetate copolymers, combinations of these, and the like. A particularly preferred resin is available from Union Camp Chemical Product Division under the trade designation “UNIREZ 2221”.

For another embodiment of the present invention suitable for use in supersize coat 24 , a preferred binder precursor particle composition (Supersize Composition IV) comprises 70 to 95 parts by weight of the metal salt of a fatty acid as described above and 5 to 20 parts by weight of a thermosetting resin other than a radiation curable resin. Preferred examples of the thermosetting resin include phenol-formaldehyde resins (that is, novolak type phenolic resins and powdered resole resins) such as the resin available under the trade designation “VARCUM 29517” from the Durez Division of the Occidental Chemical Corp. (“Oxychem”), and urea-formaldehyde resins such as the resin available under the trade designation “AEROLITE UP4145” from Dynochem UK, Ltd.; and the EPON™ 1001F epoxy resin.

The binder precursor particles and/or fusible powder of the present invention are easily made by a process in which all of the ingredients to be incorporated into the particles or powder, as the case may be, are first blended together to form a homogeneous, solid admixture. Blending can be accomplished by dry blending the ingredients together in powder form, but more preferably is accomplished by melt processing in which at least the radiation curable ingredients of the particles are liquefied during blending. Typically, melt processing occurs at a temperature above the glass transition temperatures and/or melting points of at least some of the radiation curable ingredients, while nonetheless occurring at a sufficiently low temperature to avoid premature crosslinking of the binder components. The melt processing temperature is also below temperatures that might degrade any temperature sensitive ingredients of the particles. The particular technique used to accomplish melt processing and blending is not critical, and any convenient technique can be used. As one example, processing the ingredients through an extruder to form a solid, blended extrudate is suitable, so long as extruder temperature is carefully monitored to avoid premature crosslinking of, and degradation to, the ingredients.

After the solid blend is formed, the resultant solid can then be milled, for example, ground, into particles of the desired particle size. The type of milling technique is not critical and representative examples include cryogenic grinding, hammer milling (either cold or at room temperature), using a mortar and pestle, using a coffee grinder, ball milling, and the like. Hammer milling at room temperature is presently preferred.

Depending upon the composition of the particles, the dry particles can then be used, without use of any solvent whatsoever, to form the binder matrix component of make coat 20 , size coat 22 , and/or supersize coat 24 , as desired. Generally, the particles may be applied to an underlying surface of abrasive article 10 using any convenient dry coating technique such as drop coating, electrostatic spraying, electrostatic fluidized bed coating, hot melt spraying, and the like. After coating, the particles are liquefied, preferably by heating, in a manner such that the particles fusibly flow together to form a uniform, fluid melt layer. The melt layer can then be exposed to a suitable source of energy in order to cure the melt layer so that a thermoset, solid, binder matrix is formed. In the case of forming make coat 20 , abrasive particles 16 to be incorporated may be codeposited with the dry binder precursor particles if desired. Alternatively, it is also possible to sequentially and separately apply the binder precursor particles and abrasive particles 16 in any order. For example, the binder precursor particles can be dry coated and liquefied first, after which abrasive particles 16 are coated into the melt layer prior to curing. In order to promote the adhesion of make coat 20 to backing 12 , it may be desirable to modify, for example, prime, the surface of backing 12 to which make coat 20 is applied. Appropriate surface modifications include corona discharge, ultraviolet light exposure, electron beam exposure, flame discharge and scuffing.

With reference to abrasive article 10 of FIG. 1 , FIG. 12 is a schematic representation of an apparatus 200 suitable for forming abrasive article 10 . For purposes of illustrating the versatility of the present invention, FIG. 12 shows forming each of make coat 20 , size coat 22 , and supersize coat 24 of abrasive article 10 from binder precursor particles of the present invention. However, it is to be understood that the present invention is not limited to the illustrated application in which the entirety of bond system 18 is formed from the binder precursor particles, but rather is applicable to circumstances in which any one or more portions of bond system 18 is derived from such binder precursor particles.

FIG. 12 shows backing 202 being transported from supply roll 204 to take-up roll 206 . Typically, backing 202 may be transported at a speed in the range from 0.1 m/min to as much as 100 m/min or more. During transit between supply roll 204 and take up roll 206 , backing 202 is supported upon suitable number of guide rollers 208 as backing 202 passes through coating stations 210 , 212 , and 214 . Make coat 20 , size coat 22 , and supersize coat 24 are applied at stations 210 , 212 , and 214 , respectively. Firstly, at station 210 , binder precursor particles 216 corresponding to the binder matrix of make coat 20 are drop coated onto backing 202 from dry coating apparatus 220 . Backing 202 then passes through oven 224 in which particles 216 are heated to form a liquefied make coat melt layer. Abrasive particles 16 are then electrostatically coated into the make coat melt layer from mineral coater 226 . The coated backing then passes ultraviolet light source 228 , where the make coat melt layer is exposed to ultraviolet radiation to crosslink and cure the make coat. The crosslinked make coat now firmly bonds abrasive particles 16 to backing 202 .

Next, the coated backing 202 passes through station 212 to form size coat 22 . Binder precursor particles 230 corresponding to the binder matrix of size coat 22 are drop coated onto make coat 20 from dry coating apparatus 232 . The coated backing 202 then passes through oven 234 in which particles 230 are heated to form a liquefied size coat melt layer. The coated backing then passes ultraviolet light source 238 , where the size coat melt layer is exposed to ultraviolet radiation to crosslink and cure the size coat. The crosslinked size coat now helps reinforce the attachment of abrasive particles 16 to backing 202 .

Next, the coated backing 202 passes through station 214 to form supersize coat 24 . Binder precursor particles 240 corresponding to the binder matrix of supersize coat 24 are drop coated onto size coat 22 from dry coating apparatus 242 . The coated backing 202 then passes through oven 244 in which particles 240 are heated to form a liquefied supersize coat melt layer. The coated backing 202 then passes ultraviolet light source 248 , where the supersize coat melt layer is exposed to ultraviolet radiation to crosslink and cure the supersize coat. The crosslinked supersize coat now helps provide abrasive article 10 with desired performance characteristics, for example, anti-loading capabilities if supersize coat 24 incorporates an antiloading agent.

The finished abrasive article 10 is then stored on take-up roll 206 , after which abrasive article may be cut into a plurality of sheets, discs or the like, depending upon the desired application. Of course, instead of being directly stored on take-up roll 206 , abrasive article 10 may be transported directly to a cutting apparatus to form sheets or discs, after which the sheets or discs may be stored, packaged for distribution, used, or the like. The invention will be more fully understood with reference to the following nonlimiting examples in which all parts, percentages, ratios, and so forth, are by weight unless otherwise indicated.

Abbreviations for the materials defined in the above detailed description and used in the following samples are shown in the following schedule.

Thermoplastic
DS1227                           High molecular weight polyester commercially available
                                 from Creanova, Piscataway, NJ under the trade designation
                                 “DYNAPOL S1227”
Elvax 310                        Ethylene vinyl acetate copolymer commercially available
                                 from E. I. Du Pont de Nemours and Company Inc.,
                                 Willmington, DE
Unirez 2221                      Dimer acid hot melt polyamide commercially available
                                 f30rom Union Camp, Chemical Products Division,
                                 Jacksonville, FL
Thermosetting Resins
DZ1                              Novolak type powdered phenolic resin commercially
                                 available from OxyChem, Occidental Chemical
                                 Corporation, Durez Engineering Materials, Dallas, TX
                                 under the trade designation “Durez 12687”
DZ2                              Novolak type powdered phenolic resin commercially
                                 available from OxyChem, Occidental Chemical
                                 Corporation, Durez Engineering Materials, Dallas, TX
                                 under the trade designation “Durez 12608”
VM1                              Novolak type powdered phenolic resin commercially
                                 available from OxyChem, Occidental Chemical
                                 Corporation, Durez Engineering Materials, Dallas, TX
                                 under the trade designation “Varcum 29517”
UF1                              Powdered urea-formaldehyde resin available from
                                 Dynochem UK Ltd, Cambridge, UK. under the trade
                                 designation “Aerolite UP 4145”
UF2                              Urea-formaldehyde liquid resin commercially available
                                 from Borden Chemical Inc., Louisville, KY under the trade
                                 designation “Durite Al-3029 R”
Radiation Curable or thermally curable epoxy resins
EP1                              Bisphenol A epoxy resin commercially available from Shell
                                 Chemical, Houston, TX under the trade designation “EPON
                                 828” (epoxy equivalent weight of 185-192 g/eq.)
EP2                              Bisphenol A epoxy resin commercially available from Shell
                                 Chemical, Houston, TX under the trade designation “EPON
                                 828” (epoxy equivalent weight of 185-192 g/eq.)
ERL 4221                         Cycloaliphatic epoxy resin commercially available from
                                 Union Carbide Chemicals and Plastics Company Inc.,
                                 Danbury, CT
Radiation Curable Monomers Oligomers and Polymers
EB1                              Bisphenol A epoxy acrylate commercially available from
                                 UCB Chemicals Corp., Smyrna, GA under the trade
                                 designation “Ebecryl 3720”
EB2                              Fatty acid modified epoxy acrylate commercially available
                                 from UCB Chemicals Corp., Smyrna, GA under the trade
                                 designation “Ebecryl 3702”
EB3                              Polyester hexa-acrylate commercially available from UCB
                                 Chemicals Corp., Smyrna, GA under the trade designation
                                 “Ebecryl 450”
RSX 29522                        Experimental solid acrylated epoxy oligomer obtained from
                                 UCB Chemicals Corp, Smyrna, GA
TRPGDA                           Tripropylene glycol diacrylate commercially available from
                                 Sartomer Co., Exton, PA under the trade designation
                                 “SR306”
TMPTA                            Trimethylol propane triacrylate commercially available from
                                 Sartomer Co., Exton, PA under the trade designation
                                 “SR35 1”
AMN                              Acrylamidomethyl novolak resin in U.S. Pat. No. 4,903,440
                                 and 5,236,472
PDAP                             p-Di(acryloyloxyethyl)terephthalate, prepared as described
                                 below at IIA
PAN                              O-Acrylated novolak resin, prepared as described below at
                                 IIA
PT 60                            Cyanate ester novolak commercially available from Lonza
                                 Inc., Fair Lawn, NJ under the tradename “Primaset PT 60”
Metal salts of fatty acids/Antiloading agents
ZnSt2                            Zinc stearate commercially available from Witco Chemical
                                 Corporation, Memphis, TN under the tradename
                                 “Lubrazinc W”
CaSt2                            Calcium stearate commercially available from Witco
                                 Chemical Corporation, Memphis, TN under the tradename
                                 “Calcium Stearate Extra Dense G”
LiSt                             Lithium stearate commercially available from Witco
                                 Chemical Corporation, Memphis, TN under the tradename
                                 “Lithium Stearate 304”
StA                              Stearic acid commercially available from Aldrich Chemical
                                 of Milwaukee, WI
Grinding Aids
KBF4                             Potassium Fluoroborate commercially available from
                                 Aerotech USA Inc., under the trade designation
                                 “POTASSIUM FLUOROBORATE SPEC. 102.”
Abrasive particles
P180 AlO                         Grade P180 aluminum oxide particles, commercially
                                 available from Triebacher Schleifmittel AG, Villach,
                                 Austria
P400 SiC                         Grade P400 silicon carbide particles, commercially
                                 available from Triebacher Schleifmittel AG, Villach,
                                 Austria
P80 CUB                          Grade P80 ceramic aluminum oxide particles, commercially
                                 available from Minnesota Mining and Manufacturing
                                 Company, St. Paul, MN
P80 AO                           Grade P80 aluminum oxide particles, commercially
                                 available from Triebacher Schleifmittel AG, Villach,
                                 Austria
50 AZ                            Grade 50 ceramic aluminum oxide particle commercially
                                 available from Norton, WHERE
Hydroxyl containing materials
CHDM                             Cyclohexanedimethanol commercially available from
                                 Eastman Chemical Company, Kingsport, CT
SD 7280                          Novolak type powdered phenolic resin (uncatalyzed)
                                 commercially available from Borden Chemical Inc.,
                                 Louisville, KY
Initiators/Catalysts
“KB1”                            2,2-Dimethoxy-1,2-diphenyl-1-ethanone commercially
                                 available from Sartomer Co., Exton, PA under the trade
                                 designation “KB1”
IRG1                             2,2-Dimethoxy-1,2-diphenyl-1-ethanone commercially
                                 available from Ciba Speciality Chemicals, under the trade
                                 designation “IRGACURE 651”
COM                              Eta                                                                        6                                                                    -[xylenes (mixed isomers)]eta                                                                        5
                                 cyclopentadienyliron(1+)hexafluoroantimonate(1−) (acts as
                                 a photocatalyst) as described in U.S. Pat. Nos. 5,059,701;
                                 5,191,101 and 5,252,694
AMOX                             Di-t-amyloxalate (acts as an accelerator) as described in
                                 U.S. Pat. Nos. 5,252,694 and 5,436,063
IMID                             2-Ethyl-4-methylimidazole, commercially available from
                                 Aldrich Chemical, Milwaukee, WI
PTSOH                            p-Toloune sulfonic acid, commercially available from
                                 Aldrich Chemical Milwaukee, WI
ACL                              Aluminum chloride, commercially available from Aldrich
                                 Chemical, Milwaukee, WI
Fillers
FLDSP                            Feldspar, commercially available from K-T Feldstar
                                 Corporation, GA under the trade designation “Minspar 3”
CRY                              Cryolite commercially available from TR International
                                 Trading Company Inc., Houston, TX under the trade
                                 designation “RTNC CRYOLITE”
CaCO                                                                        3 Calcium carbonate
FEO                              Iron oxide
Flow control agents
MOD                              Powder coating flow agent commercially available from
                                 Sythron Inc, Moganton, NC under the trade designation
                                 “Modarez MFP-V”
CAB-O-SIL                        Hydrophobic treated amorphous fumed silica, commercially
                                 available from Cabot Corportation, Tuscola, IL, under the
                                 trade designation “CAB-O-SIL TS-720”
Solvents
Ethyl                            Ethyl acetate is commercially available from Aldrich
Acetate                          Chemical, Milwaukee, WI

EXAMPLE I

Preparation of Abrasive Articles Comprsing a Backing Layer and Abrasive Coating Compromising a Supersize Coat

A. Preparation of Abrasive Articles Comprising a Backing Layer and an Abrasive Coating

1. Abrasive Article A

These abrasive articles used a backing that was a 95 g/m 2 paper backing C90233 EX commercially available from Kimberly-Clark, Neenah, Wis. For each, a make coat precursor was prepared from DS1227 (20.7 parts), EP1 (30.5 parts), EP2 (33.7 parts), CHDM (2.9 parts), COM (0.6 part), KB1 (1.0 part) and AMOX (0.6 parts). The batch was prepared by melting DS1227 and EP2 together at 140° C., mixing, then adding EP1 and CHDM. Then, TMPTA (4.5 parts) was added with mixing at 100° C. To this sample was added COM, AMOX, and KB1 followed by mixing at 100° C. The make coat precursor was applied at 125° C. by means of a knife coater to the paper backing at a weight of about 20 g/m 2 . The sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb immediately before P180 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85 g/m 2 . The intermediate product was thermally cured for 15 minutes at a temperature of 100° C.

A size coat precursor was roll coated over the abrasive grains at a weight of about 50 g/m 2 . The size coat precursor included a 100% solids blend of EP1 (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KB1 (1 part), and COM (1 part). The sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb followed by a thermal cure for 10 minutes at 100° C.

2. Abrasvie Article B

Abrasive article B was prepared by the same methodology as described above using the formulations shown in Table 1.

3. Comparative Samples B, D, F, H, J, K, N, P, BB, DD, FF, HH, JJ

Abrasive articles used a backing that was a 95 g/m 2 paper backing C90233 EX commercially available from Kimberly-Clark, Neenah, Wis. For each, a make coat precursor was prepared from DS1227 (20.7 parts), EP1 (30.5 parts), EP2 (33.7 parts), CHDM (2.9 parts), COM (0.6 part), KB1 (1.0 part) and AMOX (0.6 parts). The batch was prepared by melting DS1227 and EP2 together at 140° C., mixing, then adding EP1 and CHDM. Then, TMPTA (4.5 parts) was added with mixing at 100° C. To this sample was added COM, AMOX, and KB1 followed by mixing at 100° C. Make coat precursors were applied at 125° C. by means of a knife coater to the paper backing at a weight of about 20 g/m 2 . The sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb immediately before P180 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85 g/m 2 . The intermediate product was thermally cured for 15 minutes at a temperature of 100° C.

A size coat precursor was roll coated over the abrasive grains at a weight of about 50 g/m 2 . The size coat precursor included a 100% solids blend of EP1 (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KB1 (1 part), and COM (1 part). The samples were then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb followed by a thermal cure for 10 minutes at 100° C. The sample was supersized at a weight of about 35 g/m 2 with a calcium stearate solution (50% solids aqueous calcium stearate/acrylic binder solution) available from Witco Chemical Corporation, Memphis, Tenn.

4. Comparative Sample L

Comparative Article L was prepared by the same methodology as described above for Abrasive Article A using the formulations shown in Table 1.

5. Comparative Samples A, C, G, I, O, AA, CC

Comparative Articles A, C, G, I, O, AA, CC are commercially available from Minnesota Mining and Manufacturing Company, St. Paul, Minn. under trade designation “216U P180 Fre-Cut Production Paper A Weight”.

TABLE 1
Formulation of Abrasive Articles
			Comparative Abrasive
			Articles B, D, F,, H, J, K, N,	Comparative Abrasive
	Abrasive Article A	Abrasive Article B	P, BB, DD, FF, HH, JJ	Article L
Backing type	a Paper, C90233 EX	a Paper, S-44165	a Paper, 90233 EX	a Paper, S-44165
Backing wt. (g/m 2 )	95	70	95	20
Make resin type	DS1227 (20.7 parts),	DS1227 (20.7 parts), EP1 (30.5	DS1227 (20.7 parts), EP1 (30.5	DS1227 (20.7 parts), EP1 (30.5
	EP1 (30.5 parts), EP2	parts), EP2 (33.7 parts), CHDM	parts), EP2 (33.7 parts), CHDM	parts), EP2 (33.7 parts), CHDM
	(33.7 parts), CHDM	(2.9 parts), COM (0.6 part),	(2.9 parts), COM (0.6 part),	(2.9 parts), COM (0.6 part),
	(2.9 parts), COM (0.6	KB1 (1.0 part) and AMOX (0.6	KB1 (1.0 part) and AMOX	KB 1 (1.0 part) and AMOX
	part), KB1 (1.0 part)	parts).	(0.6 parts).	(0.6 parts).
	and AMOX (0.6
	parts).
Make resin wt. (g/m 2 )	20	12.5	20	12.5
Mineral Type	P180 AO	P400 SiC	P180 AO	P400 SiC
Mineral Wt. (g/m 2 )	85	40	85	40
Size resin Type	EP1/ERL 4221/SR321	EP1/ERL 4221/TMTPA	EP1/ERL 4221/TMTPA	EP1/ERL 4221/TMTPA
	(40/30/30)	(40/30/30)	(40/30/30)	(40/30/30)
Size Resin wt. (g/m 2 )	50	35	50	35
Supersize coating	none	none	Calcium Stearate/acrylic binder	Calcium Stearate/acrylic binder
type			solution (50% solids)	solution (50% solids)
Supersize wt. (g/m 2 )			35	20

B. Preparation of Binder Percursor Particles For Use in a Supersize Coat

Samples of binder precursor particles according to the present invention were prepared from the formulations in Table 2. To make each sample, the ingredients were either (1) melt blended together, solidified, and ground into a powder or (2) dry blend mixed and ground into powders. The samples were ground into fine powders by mortar and pestle or hammer mill, unless otherwise indicated. A few examples are given below to illustrate the methodology.

1. Preparation of binder precursor particles comprising a combination of ZnSt2/CaSt2/EB1/IRG1 (45/45/10/1)

A 0.5 L.jar was charged with 45 g of ZnSt2, 45 g of CaSt2 and 10 g of EB1. The materials were melted at 120-160° C., mixed, and 1 g of IRG1 was added. The material was cooled, and the resultant solid was ground into a fine powder.

2. Preparation of binder precursor particles comprising a combination of ZnSt2/UF1 (80/20)

A 0.5 L.jar was charged with 80 g of ZnSt2 and 20 g of UF1. The solids were dry blended in a grinder.

3. Preparation of binder precursor particles comprising a combination of ZnSt2/CaSt2/EP2/IMID (50/50/14/1)

A 0.5 L.jar was charged with 50 g of ZnSt2, 50 g of CaSt2 and 14 g of EP2, The materials were melted at 120-140° C., mixed, and 1 g of IMID was added. The material was cooled, and the resultant solid was ground into a fine powder.

TABLE 2
Binder Precursor Particles Formulations
	Metal Salt of	Weight of	Radiation/	Weight Radiation/
	Fatty	Metal Salt	Thermally	Thermally
	Acid/Fatty	of Fatty	Curable	Curable
Sample No.	Acid	Acid (g)	Component	Component (g)*
Sample 1,	ZnSt2	No binder	None	0
15 & 37
Sample 2,	ZnSt2	88	EB1	12
16 & 38A
Sample 3	ZnSt2	85	EB3	15
Sample 4	ZnSt2	85	EB1	15
Sample 5	ZnSt2	85	EB1	7.5
			EB3	7.5
Sample 6	ZnSt2	70	EB1	7.5
			Elvax 310	7.5
Sample 7	ZnSt2	95	EB1	5
Sample 8	ZnSt2	95	EB2	5
Sample 9	ZnSt2	95	EB3	5
Sample 10 &	CaSt2	90	EB1	10
12
Sample 11	CaSt2	100	None	0
Sample 13	CaSt2	90	EB3	10
Sample 14	CaSt2	90	EB1	10
Sample 17	CaSt2	25	TRPGDA	31
Sample 18	ZnSt2	25	TRPGDA	57
Sample 19	CaSt2	25	TRPGDA	44
Sample 20	ZnSt2	25	TRPGDA	45
Sample 21	LiSt	25	TRPGDA	68
a Sample	50% CaSt2	73.6	EB1	23.4
22 & 26	50% ZnSt2
b Sample	50% CaSt2	73.6	EB1	23.4
23 & 27	50% ZnSt2
a Sample	75% CaSt2	73.6	EB1	23.4
24, 28 & 29	25% ZnSt2
b Sample	75% CaSt2	73.6	EB1	23.4
25 & 30	25% ZnSt2
Sample 31 &	73% CaSt2	89	EB1	10
32	27% StA
Sample 33 &	80% CaSt2	89	EB1	10
34	20% StA
Sample 35 &	90% CaSt2	89	EB1	10
36	10% StA
Sample 38B	50% CaSt2	80	PDAP	14
	50% ZnSt2
Sample 38C	50% CaSt2	90	RSX 29522	10
	50% ZnSt2
Sample 38D	50% CaSt2	90	Et-TMPTA	10
	50% ZnSt2
Sample 38E	100% ZnSt2	90	UP4145	10
Sample 38F	100% ZnSt2	90	V1	10
Sample 38G	50% CaSt2	100	EP2	14
	50% ZnSt2
Sample 38H	100% CaSt2	90	Unirez 2221	10
a Particle size of powder was 45-90 um.
b Particle size of powder was 0-45 um.

C. Preparation of Abrasive Articles Comprising Supersize Coat

Binder precursor particle samples 1 - 38 H were dry coated onto Abrasive Articles A and/or B (see Table 3), melted, and then solidified to form supersize coats according to the following procedures. The details of the resultant abrasive articles are disclosed in Table 3.

The binder precursors samples 2 - 15 , 16 , 22 - 36 , and 38 A- 38 B were respectively coated onto Abrasive Article A or B. Specifically, the binder precursor particles were powder coated at about 7.0 to 23 g/m 2 onto the abrasive articles by drop coating with a mesh sifter, spray coating with a fluidized or electrostatic fluidized spray gun, or coating with an electrostatic fluidized bed coater. The binder precursor particles were then melted by placing the abrasive article in an oven at a temperature of from about 120° to about 165° C. for about 5-15 minutes. The resultant melt layer was then cured by passing the abrasive article through a UV lamp (1 pass at 7.6 m/min. with 157 w/cm bulb). Adhesive sheeting was attached to the backside of the abrasive article and 10.2 cm or 15.2 cm discs were died out of the abrasive articles. The discs were used for Schiefer or Off hand DA testing, described below.

Supersize coat samples formed from binder precursor particles 1 15 , 37 and 38 H, respectively, were prepared identically to samples 2 - 14 , 16 , 22 - 36 , and 38 A, except that the materials were not cured after removing the resultant melt layer form the oven. Adhesive sheeting was attached to the backside of the abrasive article and 10.2 cm or 15.2 cm discs were died out of the abrasive articles. The discs were used for Schiefer or Offhand DA testing, describe below.

Supersize coat samples formed from binder precursor particles 38 B-G, respectively, were prepared identically to samples 2 - 14 , 16 22 - 36 , and 38 A except that the amount of time that the samples were placed in the oven was extended to 30-90 minutes to thermally cure the resultant melt layer. Adhesive sheeting was attached to the backside of the abrasive articles and 10.2 cm or 15.2 cm discs were died out of the abrasive articles. The discs were used for Schiefer tests, described below.

Supersize coat samples formed from binder precursor particles 17 - 21 , respectively, were prepared identically to samples 2 - 14 , 16 22 - 36 , and 38 A except that, prior to powder coating, a composition comprising 50 g of radiation curable monomer (TRPGDA), 50 g of ethyl acetate and 1 g of initiator (IRG1) were combined and placed in a spray bottle. The solution was sprayed onto 15.2 cm×20.3 cm sections of Abrasive Article A and allowed to air dry. About 8 g/m 2 were then applied to the corresponding abrasive article by electrostatic fluidizing spray gun. The abrasive article was then placed in an oven at a temperature in the range of from about 120° to about 165° C. to melt the particles. Finally, the resultant melt layer was cured by passing the abrasive article through a UV lamp (1 pass at 7.6 m/min. with a 157 w/cm bulb). Adhesive sheeting was attached to the backside of the abrasive article and 10.2 cm or 15.2 cm discs were died out of the abrasive articles. The discs were used in testing, described below.

TABLE 3
Samples of Abrasive Articles Powder Coated with Supersize Coat
	Supersize Coat	Abrasive
Sample No.	Weight (g/m 2 )	Article	Powder Coat Method
Sample 1-2	21.9	A	Drop coating
Sample 3	20.7	A	Drop coating
Sample 4-6	21.9	A	Drop coating
Sample 7	22.6	A	Drop coating
Sample 8-9	21.3	A	Drop coating
Sample 10	21.3	A	Drop coating
Sample 11	22.3	A	Drop coating
Sample 12-14	22.6	A	Drop coating
Sample 15	7.4	A	Electrostatic fluidized
			spraying
Sample 16	16.8	A	Electrostatic fluidized
			spraying
Sample 17-21	8.1	A	Electrostatic fluidized
			spraying
Sample 22	17.4	A	Electrostatic fluidized bed
			coating
Sample 23	19.2	A	Electrostatic fluidized bed
			coating
Sample 24	16.1	A	Electrostatic fluidized bed
			coating
Sample 25	22.3	A	Electrostatic fluidized bed
			coating
Sample 26	8.7	B	Electrostatic fluidized bed
			coating
Sample 27	7.4	B	Electrostatic fluidized bed
			coating
Sample 28	12.4	B	Electrostatic fluidized bed
			coating
Sample 29	NA	B	Electrostatic fluidized bed
			coating
Sample 30	8.7	B	Electrostatic fluidized bed
			coating
Sample 31-36	22.6	A	Drop Coating
Sample 37-38	22.6	A	Drop Coating
Sample 38B	22.6	A	Drop Coating
Sample 38C	22.6	A	Drop Coating
Sample 38D	16.1	A	Drop Coating
Sample 38E	16.1	A	Drop Coating
Sample 38F	16.1	A	Drop Coating
Sample 39G	16.1	A	Drop Coating
Sample 39H	16.1	A	Drop Coating

D. Evaluation of Abrasive Articles Comprising a Supersize Coat

1. Test Procedures

a. Schiefer Testing Procedure

Each 10.2 cm diameter disc of the abrasive articles of each Sample 1 - 38 H and Comparative Samples A-O and AA-JJ(See Tables 4-7) was secured to a foam back-up pad by means of a pressure sensitive adhesive. Each coated abrasive disc and back-up pad assembly was installed on a Schiefer testing machine, and the coated abrasive disc was used to abrade a cellulose acetate butyrate polymer of predetermined weight. The load was 4.5 kg. The test was considered complete after 500 revolution cycles of the coated abrasive disc. The cellulose acetate butyrate polymer was then weighed, and the amount of cellulose acetate butyrate polymer removed was recorded. The results of the test procedures are tabulated hereinbelow with the appropriate Comparative Samples. Briefly, the results illustrated below in Tables 4-7 illustrated that supersize coats derived from radiation curable binder precursor particles, thermal curable binder precursor particles and thermoplastic binder precursor particles exhibited superior performance to conventional aqueous calcium stearate/acrylic binder supersize coats. In addition to the superior performance, these binder precursor particles for supersize coats have environmental and processing advantages over conventional supersize coats prepared from solvent-containing solutions.

TABLE 4A
Schiefer Testing of Samples 1-6 and Comparative Samples A and B
		Comparative
		Ranking Relative	Comparative Ranking
Sample No.	Cut (g)	to A	Relative to B
Comparative A	3.324	100	106
Comparative B	3.150	95	100
Sample 1	3.362	101	107
Sample 2	3.052	92	97
Sample 3	3.218	97	102
Sample 4	3.024	91	96
Sample 5	2.818	85	89
Sample 6	2.803	84	89

TABLE 4B
Schiefer Testing of Samples 7-11 and Comparative Samples C and D
		Comparative
		Ranking Relative	Comparative Ranking
Sample No.	Cut (g)	to C	Relative to D
Comparative C	3.195	100	115
Comparative D	2.776	87	100
Sample 7	2.846	89	102
Sample 8	3.208	100	116
Sample 9	3.118	98	112
Sample 10	3.391	106	122
Sample 11	3.421	107	123

TABLE 4C
Schiefer Testing of Samples 12-14 and Comparative Samples E and F
		Comparative
		Ranking Relative	Comparative Ranking
Sample No.	Cut (g)	to E	Relative to F
Comparative E	3.016	100	91
Comparative F	3.317	110	100
Sample 12	3.495	116	105
Sample 13	3.392	112	102
Sample 14	3.596	119	108

TABLE 5A
Schiefer Testing of Samples 15-16 and Comparative Samples G and H
		Comparative
		Ranking Relative	Comparative Ranking
Sample No.	Cut (g)	to G	Relative to H
Comparative G	2.849	100	90
Comparative H	3.176	111	100
Sample 15	3.060	107	96
Sample 16	2.824	99	90

TABLE 5B
Schiefer Testing of Samples 17-21 and Comparative Samples I and J
		Comparative
		Ranking Relative	Comparative Ranking
Sample No.	Cut (g)	to I	Relative to J
Comparative I	3.173	100	96
Comparative J	3.291	104	100
Sample 17	2.901	91	88
Sample 18	2.349	74	71
Sample 19	3.046	96	92
Sample 20	2.345	74	71
Sample 21	2.157	68	65

TABLE 6
Schiefer Testing for Samples 22-30 and Comparative Samples K and L
	Sample No	Cut (g)
			Comparative Ranking
			Relative to K
	Comparative K	2.990	100
	Sample 22	3.183	106
	Sample 23	3.159	105
	Sample 24	3.632	121
	Sample 25	3.641	122
			Comparative Ranking
			Relative to L
	Comparative L	1.000	100
	Sample 26	1.196	120
	Sample 27	0.955	96
	Sample 28	1.237	124
	Sample 29	1.242	124
	Sample 30	1.191	119

TABLE 7A
Schiefer Testing for Samples 31-36 and Comparative Sample N
			Comparative Ranking
	Sample No.	Cut (g)	Relative to N
	Comparative N.	2.469	100
	Sample 31	2.741	111
	Sample 32	2.472	100
	Sample 33	3.142	127
	Sample 34	3.347	136
	Sample 35	3.218	130
	Sample 36	3.597	145

TABLE 7B
Schiefer Testing for Samples 38B-38D and Comparative
Sample BB, DD and FF
Sample No.	Cut (g)
		Comparative Ranking Relative to BB.
Comparative BB	2.916	100
Sample 38B	3.408	117
		Comparative Ranking Relative to DD
Comparative DD	2.932	100
Sample 38C	3.236	110
		Comparative Ranking Relative to FF
Comparative FF	2.756	100
Sample 38D	3.219	117

TABLE 7C
Schiefer Testing for Samples 38E-38H and Comparative
Samples HH, JJ and AA
Sample No.	Cut (g)
		Comparative Ranking Relative to HH.
Comparative HH	2.720	100
Sample 38E	3.013	111
Sample 38F	2.936	108
		Comparative Ranking Relative to AA
Comparative AA	2.346	100
Sample 38G	2.764	118
		Comparative Ranking Relative to JJ
Comparative KK	3.323	100
Sample 38H	3.717	112

2. Offhand DA Test Method

A paint panel, that is, a steel substrate with an e-coat, primer, base coat, and clear coat typically used in automotive paints, was abraded in each case with coated abrasives made in accordance with the invention and with coated abrasives as comparative examples. Each coated abrasive had a diameter of 15.2 cm and was attached to a random orbital sander (available under the trade designation “DAQ”, from National Detroit, Inc., Rockford, Ill.). The abrading pressure was about 0.2 kg/cm 2 , while the sander operated at about 60 PSI@TOOL (413 kPa). The painted panels were purchased from ACT Company of Hillsdale, Mich. The cut in grams was computed in each case by weighing the primer-coated substrate before abrading and after abrading for a predetermined time, for example, 1 or 3 minutes. The DA test data for Samples 37 , 38 A, and Comparative Samples O and P are shown in Table 8.

TABLE 8
DA Testing (3 min.) for Samples 37, 38A and Comparative
Sample O and P
		Ranking Relative	Ranking Relative to
		to Comparative	Comparative
Sample No.	Cut	Abrasive Article O	Abrasive Article P
Comparative O	11.7	100	101
Comparative P	11.6	99	100
Example 37	10.15	87	88
Example 38A	11.75	100	101

EXAMPLE II

Preparation of Abrasive Articles Comprising a Backing Layer and Abrasive Coating Comprising a Size Coat

A. Preparation of Abrasive Articles Comprising a Backing Layer and Abrasive (Table 9)

1. Abrasive Article C

These abrasive articles used a backing that was a 95 g/m 2 paper backing C90233 EX commercially available from Kimberly-Clark, Neenah, Wis. To make each, a make coat precursor was prepared from DS1227 (20.7 parts), EP1 (30.5 parts), EP2 (33.7 parts), CHDM (2.9 parts), COM (0.6 part), KB1 (1.0 part) and AMOX (0.6 parts). The batch was prepared by melting DS1227 and EP2 together at 140° C., mixing, and then adding EP1 and CHDM and mixing. Then, TMPTA (4.5 parts) was added with mixing at 100° C. To this sample was added COM, AMOX, and KB1 followed by mixing at 100° C. The make coat precursor was applied at 125° C. by means of a knife coater to the paper backing at a weight of about 20 g/m 2 . The sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb immediately before P180 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85 g/m 2 . The intermediate product was thermally cured for 15 minutes at a temperature of 100° C.

2. Abrasive Article D

An abrasive article used a 5 mil thick polyester backing that can be obtained commercially from Minnesota Mining and Manufacturing Company, St. Paul, Minn. A make coat precursor comprising an aqueous solution of UF2, a 75% solid aqueous resole phenolic resin with a formaldehyde/phenol ratio of approximately 1.1-3.0/1 and a pH of 9, ACL and PTSOH (85/15/2/1) was roll coated onto the backing at an approximate weight of 40 g/m 2 . Next, a blend of P180 and AlO/CUB abrasive particles ( 50 - 90 / 10 - 50 ) was electrostatically projected into the make coat precursor at a weight of about 155 g/m 2 . The make resin was cured in an oven at 100° C. for 60 minutes.

3. Comparative Samples Q and R

These abrasive articles used a backing that was a 95 g/m 2 paper backing C90233 EX commercially available from Kimberly-Clark, Neenah, Wis. To make each article, a make coat precursor was prepared from DS1227 (20.7 parts), EP1 (30.5 parts), EP2 (33.7 parts), CHDM (2.9 parts), COM (0.6 part), KB1 (1.0 part) and AMOX (0.6 parts). The batch was prepared by melting DS1227 and EP2 together at 140° C., mixing, and then adding EP1 and CHDM. Then, TMPTA (4.5 parts) was added with mixing at 100° C. To this sample was added COM, AMOX, and KB1 followed by mixing at 100° C. Make coat precursors were applied at 125° C. by means of a knife coater to the paper backing at a weight of about 20 g/m 2 . The sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb immediately before P180 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85 g/m 2 . The intermediate product was thermally cured for 15 minutes at a temperature of 100° C.

A size coat precursor was roll coated over the abrasive grains at a weight of about 50 g/m 2 . The size coat precursor included a 100% solids blend of EP1 (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KB1 (1 part), and COM (1 part). The samples were then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb followed by a thermal cure for 10 minutes at 100° C.

4. Comparative Abrasive Articles S,T,U,V

An abrasive article used a 5 mil thick polyester backing with a backing that can be obtained commercially from Minnesota Mining and Manufacturing Company, Paul, Minn. A make coat precursor comprising an aqueous solution ofUF2, a 75% solid aqueous resole phenolic resin with a with a formaldehyde/phenol ratio of approximately 1.1-3.)/1 and pH of 9, ACL, and PTSOH (85/15/2/1) was roll coated onto the backing at an approximate weight of 40 g/m 2 . Next, a blend of P180 and AlO/CUB abrasive particles ( 50 - 90 / 10 - 50 ) was electrostatically projected into the make coat precursor at a weight of about 155 g/m 2 . The make resin was cured in an oven at 93 C. for 30 minutes. Next, a size coat precursor comprising a 75% solids aqueous solution of resole phenolic resin with a formaldehyde/phenol ratio of approximately 1.1-3.0/1, pH of 9 and feldspar (70/35) was coated onto the make coat at an approximate weight of 200 g/m 2 . The size resin was cured by placing the sample in an oven at 100-110° C. for 1-2 hours.

The formulations for Abrasive Articles C and D and Comparative Abrasive Articles Q-V are shown below in Table 9.

TABLE 9
Formulation of Abrasive Articles
			Comparative	Comparative
	Abrasive	Abrasive	Abrasive	Abrasive
	Article C	Article D	Articles Q, R	Articles S,T,U,V
Backing	a C90233 EX	b polyester	a C90233 EX	b polyester film
type		film
Backing	95	5 mil	95	5 mil
wt. (g/m 2 )
Make	DS1227	UF2/Resole	DS1227	UF2/Resole
resin	(20.7 parts),	phenolic	(20.7 parts),	phenolic
type	EP1 (30.5	resin/ACL/	EP1 (30.5	resin/ACL/PTSO
	parts), EP2	PTSO	parts), EP2	H (85/15/12/1)
	(33.7 parts),	H (85/15/	(33.7 parts),
	CHDM	12/1)	CHDM
	(2.9 parts),		(2.9 parts),
	COM (0.6		COM (0.6
	part), KB1		part), KB1
	(1.0 part)		(1.0 part)
	and AMOX		and AMOX
	(0.6 parts).		(0.6 parts).
Make	20	40	20	40
resin
wt. (g/m 2 )
Mineral	P180 AO	P180	P18O AO	P180 AO/CUB
Type		AO/CUB		(50-90/10-50)
		(50-90/
		10-50)
Mineral	85	155	85	155
Wt. (g/m 2 )
Size resin	none		EP1/ERL	Resole Phenolic
Type			4221/	resin filled with
			TMPTA	35% FLSPR
			(40/30/30)
Size Resin	none		50	200
wt. (g/m 2 )
a Commercially available from Kimberly-Clark, Neenah, WI
b Commercially available from Minnesota Mining and Manufacturing Company, St. Paul, MN

B. Preparation of Radiation Curable Binders

1. p-Di(acryloyloxyethyl)Terephthalate (PDAP)

To a 2 liter, 3-necked round bottomed flask equipped with a dropping addition funnel, thermometer, ice bath and paddle stirrer was added 500 ml of dry tetrahydrofuran (THF), 103 g (1.02 mol) of triethylamine and 117 g (1 mol) of 2-Hydroxyethylacrylate. Stirring was begun. To the dropping addition funnel was added a solution of 102.5 g (0.5 mol, plus slight excess) terephthaloyl chloride in 500 ml of dry THF. This solution was added to the reaction vessel contents such that the temperature of the contents did not exceed 30° C. When the addition was completed, the reaction was stirred for an hour longer at ambient temperature and filtered through a sintered Buchner-type funnel. The formed triethylamine hydrochloride was rinsed thoroughly with dry THF, and discarded. The THF solution was concentrated on a rotoevaporator, using a 60° C. water bath, until the volume of solvent was reduced by approximately one half. Then, the concentrate was quenched with twice its volume in heptane and triturated. The solid product quickly precipitated. The pasty solid was cooled to ambient temperature and filtered. The cake was rinsed with additional heptane and spread out to dry in a glass cake pan. Isolated yield: 85-90% of theoretical. The product was found to have a T m of about 97° C., by DSC. Thin layer chromatography showed the product to be pure, as evidenced by a single spot (elution solvent of 10% methanol/90% chloroform, using F254 silica gel coated glass plates). The infrared spectrum showed a characteristic ester peak at 1722 cm −1 .

2. O-Acrylated Novolak (PAN)

To a 1 liter, 3-necked round bottomed flask equipped with a paddle stirrer, thermometer, ice bath and a dropping addition funnel was added 200 g of Borden SD-7280 phenolic novolak resin, followed by 400 ml of dry tetrahydrofuran (THF). Stirring was begun. When solution was obtained, 52.6 g (0.52 mol) of triethylamine was added. The contents of the flask were cooled to 10° C. To the dropping addition funnel were added 45.3 g (0.5 mol) of acryloyl chloride. This acid chloride was added to the novolak solution over 30 minutes, at such a rate that allowed the temperature of the contents to rise to ambient. The triethylamine hydrochloride readily formed. The contents were stirred for an additional 2 hours at ambient temperature, then filtered. The filter cake was rinsed with dry THF and concentrated to a viscous, resinous-like syrup on a rotoevaporator, while heating the concentrate to 70° C. The resinous product was transferred to a glass jar, with gentle heating of the flask walls to aid in its flow. NMR analysis of this resin showed some traces of triethylamine hydrochloride still present, and approximately 10 weight percent of THF. The main product showed approximately 0.2 mol of acrylate ester per ring of phenol. The novolak had a calculated formaldehyde to phenol ratio of about 0.8

3. Acrylamidomethyl novolak (AMN)

AMN was prepared as described in U.S. Pat. Nos. 4,903,440 and 5,236,472.

C. Preparation of Radiation Curable Binder Precursor Particles For Use in Size Coat (See Table 10 For Formulation Summary)

1. Preparation of binder precursor particles comprising a combination of AMN/PDAP/CAB-O-SIL/IRG1 (50/50/0.2/2)

A 0.5 L.jar was charged with 100 g of AMN (a viscous liquid), 100 g of PDAP and 0.4 g of CAB-O-SIL. The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 4 g of IRG1 was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.

2. Preparation of binder precursor particles comprising of a combination of PAN/PDAP/IRG1/MOD (50/50/2/0.2)

A 0.25 L jar was charged with 25 g of a viscous liquid, PAN, and 25 g of PDAP. The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 1 g. of IRG1 and 0.1 g of MOD was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder. The addition of liquid nitrogen to the cooling solid aided in grinding.

3. Preparation of binder precursor particles comprising a combination of AMN/PDAP/CRY/IRG1(50/50/100/2)

A 0.5 L jar was charged with 50 g of AMN (a viscous liquid), 50 g of PDAP, and 100 g of CRY The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 2 g of IRG1 was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder.

4. Preparation of binder precursor particles comprising a combination of EP1/EP2/SD 7280/COM (20/60/20/1)

A 0.5 L jar was charged with 20 g of EP1, 60 g of EP2, and 20 g of SD 7280. The sample was heated to 120° C. for 60 minutes and mixed. Next, 1 g of COM was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder.

5. Preparation of binder precursor particles comprising a combination of EP1/EP2/SD 7280/CRY/COM (20/60/20/100/2)

A 0.5 L jar was charged with 20 g of EP1 (a viscous liquid), 60 g of EP2, 20 g of SD 7280 and 100 g of CRY. The sample was heated to 120° C. for 60 minutes and mixed. Next, 2 g of COM was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.

6. Preparation of binder precursor particles comprising a combination of PT60/COM (100/1)

A 0.5 L jar was charged with 100 g of PT-60 and heated to 90° C. 1 g of COM was added, and the resultant solid was cooled to room temperature. The solid was ground into a fine powder with a grinder.

7. Preparation of binder precursor particles comprising a combination PT60/CRY/IRG1 (50/50/1)

A 0.5 L jar was charged with 50 g of 100/1 PT60/COM solid. Next 50 g of CRY was added. The two solids were mixed and ground into a fine powder with a grinder.

8. Preparation of binder precursor particles comprising a combination EP2/PDAP/IRG1/COM (70/30/1/1)

A 0.5 L. jar was charged with 70 g EP1 (a solid embodiment), and 30 g PDAP. The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 1 g of IRG1 and 1 g of COM was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.

9. Preparation of binder precursor particles comprising a combination EP2/PDAP (70/30/4/2/1/1)

A 0.5 L. jar was charged with 70 g of (EP2), as solid, 30 g of (PDAP), 4 g of CaSt2, and 2 g of ZnSt2. The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 1 g of IRG1 and 1 g of COM was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.

TABLE 10
Binder Precursor Particle Formulations
Sample No. Formulation
Sample 39  AMN/PDAP/CAB-O-SIL/IRG1 (50/50/0.2/2)
Sample 40  PAN/PDAP/IRG1/MOD (50/50/2/0.2)
Sample 41  AMN/PDAP/CRY/IRG1 (50/50/100/2)
Sample 42  EP1/EP2/SD 7280/COM (20/60/20/1)
Sample 43  EP1/EP2/SD 7280/CRY/COM (20/60/20/100/2)
Sample 44  PT60/COM (100/1)
Sample 45  PT60/CRY/COM (100/100/1)
Sample 46  EP2/PDAP/IRG1/COM (70/30/1/1)
Sample 47  EP2/PDAP (70/30/4/2/1/1)
Sample 48  EP1/EP2/SD 7280/COM (38.5/38.5/23/1)
Sample 49  DZ1
Sample 50  DZ2

D. Preparation of Abrasive Articles Comprising a Size Coat

Binder precursor particles sample 39 - 50 were coated onto one or more of Abrasive Articles C and D to form size coats according to the following procedure.

The binder precursor particle samples 39 - 46 and 48 were coated onto Abrasive Article D, while binder precursor particle sample 45 and 47 were coated onto Abrasive Article C. Specifically, the binder precursor particles were powder coated onto the abrasive articles at 30 to 160 g/m 2 by drop coating with a mesh sifter. The binder precursor particles were then melted by placing the abrasive article in an oven at a temperature in the range from about 120° C. to about 165° C. for 5-15 minutes. The size coat was then cured by passing the abrasive through a UV lamp (1 pass at 7.6 m/min. with a 157 w/cm bulb). Samples 46 and 47 were placed in an oven for 10 minutes at 100° C. Adhesive sheeting was attached to the abrasive articles and 10.2 cm discs were died out of the abrasive articles.

The binder precursor particle samples 49 and 50 were coated onto Abrasive Article C. Specifically, the binder precursor particles were powder coated onto the abrasive articles by drop coating with a mesh sifter. The abrasive samples were placed in an oven at a temperature in the range from about 105° C. to about 140° C. for about 2 hours. Adhesive sheeting was attached to the abrasive articles and 10.2 cm discs were died out of the abrasive articles.

The details of the resultant abrasive articles are disclosed in Table 11, hereinbelow. All discs were used for Schiefer testing, described below.

TABLE 11
Abrasive Articles Comprising Size Coat
	Size Coat		Powder Coat
Sample No.	Weight (g/m 2 )	Abrasive Article	Method
Sample 39	120	D	Drop Coat
Sample 40	120	D	Drop Coat
Sample 41	171	D	Drop Coat
Sample 42	123	D	Drop Coat
Sample 43	165	D	Drop Coat
Sample 44	123	D	Drop Coat
Sample 45	160	D	Drop Coat
Sample 46A	58.1	C	Drop Coat
Sample 46B	42.0	C	Drop Coat
Sample 47A	61.3	C	Drop Coat
Sample 47B	45.2	C	Drop Coat
Sample 48	123	D	Drop Coat
Sample 49A	42.0	C	Drop Coat
Sample 49B	40.4	C	Drop Coat
Sample 50A	42.0	C	Drop Coat
Sample 50B	32.3	C	Drop Coat

E. Evaluation of Abrasive Articles Comprising a Size Coat

1. Schiefer Test Procedure

Each 10.2 cm diameter disc of the abrasive articles of each Sample 39 - 50 and Comparative Samples R-V (See Table 11) was secured to a foam back-up pad by means of a pressure sensitive adhesive. Each coated abrasive disc and back-up pad assembly were installed on a Schiefer testing machine, and the coated abrasive disc was used to abrade a properly sized cellulose acetate butyrate polymer of predetermined weight. The load was 4.5 kg. The test was considered completed after 500 revolution cycles of the coated abrasive disc. The cellulose acetate butyrate polymer was then weighed, and the amount of cellulose acetate butyrate polymer removed was recorded. The results of the test procedure are tabulated hereinbelow along with results for the appropriate Comparative Samples. Briefly, the results illustrated in Tables 12-15 illustrated that size coats derived from radiation curable binder precursor particles exhibited superior performance to conventional phenolic size coats. In addition to the superior performance, these binder precursor particles for size coats have environmental and processing advantages over conventional coatings. Tables 12A, 12B, and 13 show the results of Scheifer Testing for Samples 39 - 50 B and Comparative Samples Q-V.

TABLE 12A
Schiefer Testing for Samples 39-45, 48 and Comparative
Samples S, T, U, V
Sample No.	Cut (g)
		Comparative Ranking Relative to S
Comparative S	2.964	100
Sample 41	3.252	110
Sample 39	3.211	108
		Comparative Ranking Relative to T
Comparative T	3.216	100
Sample 44	3.699	115
Sample 45	3.663	114
		Comparative Ranking Relative to U
Comparative U	3.421	100
Sample 42	3.776	109
Sample 48	3.831	110
		Comparative Ranking Relative to V
Comparative V	3.556	100
Sample 43	4.029	113
Sample 40	2.204	62

TABLE 12B
Schiefer Testing for Samples 46-47 and Comparative Samples R
Sample No.	Cut (g)	Comparative Ranking Relative to R
Comparative Q	1.117	100
Sample 46A	0.689	58
Sample 46B	0.674	57
Sample 47A	1.425	121
Sample 47B	1.465	124

TABLE 13
Schiefer Testing for Samples and Comparative Samples Q
Sample No.	Cut (g)	Comparative Ranking Relative to Q
Comparative R	1.223	100
Sample 49A	1.126	92
Sample 49B	1.289	105
Sample 50A	1.005	82
Sample 50B	0.793	65

EXAMPLE III

Preparation of Abrasive Article Comprising a Backing Layer and an Abrasive Coating Comprising a Make Coat

A. Preparation of Abrasive Articles Comprising a Backing Layer and Abrasive

1. Comparative Abrasive Article W

Abrasive articles used a backing that was a 95 g/m 2 paper backing C90233 EX commercially available from Kimberly-Clark, Neenah, Wis. A make coat precursor was prepared from DS1227 (20.7 parts), EP1 (30.5 parts), EP2 (33.7 parts), CHDM (2.9 parts), COM (0.6 part), KB1 (1.0 part) and AMOX (0.6 parts). The batch was prepared by melting DS1227 and EP2 together at 140° C., mixing, and then adding EP1 and CHDM followed by further mixing. Then, TMPTA (4.5 parts) was added with mixing at 100° C. To this sample was added COM, AMOX, and KB1 followed by mixing at 100° C. The make coat precursor was applied at 125° C. by means of a knife coater to the paper backing at a weight of about 30 g/m 2 . The sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb immediately before P180 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85 g/m 2 . The intermediate product was thermally cured for 15 minutes at a temperature of 100° C.

A size coat precursor was roll coated over the abrasive grains at a wet weight of about 50 g/m 2 . The size coat precursor included a 100% solids blend of EP1 (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KB1 (1 part), and COM (1 part). The sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb followed by a thermal cure for 10 minutes at 100° C.

B. Preparation of Binder Precursors Particles For Use in a Make Coat

1. Preparation of binder precursor particles comprising a combination of PDAP/IRG1 (100/1)

A 0.5 L. jar was charged with 100 g of PDAP. The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 1 g. of IRG1 was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.

2. Preparation of binder precursor particles comprising a combination of AMN/PDAP/IRG1 (70/30/1)

A 0.5 L. jar was charged with 70 g of AMN (a viscous liquid) and 30 g of PDAP. The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 1 g of IRG1 was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.

3. Preparation of binder precursor particles comprising a combination of PAN/PDAP/IRG1 (50/50/1)

A 8 oz. jar was charged with 25 g of, a viscous liquid PAN and 25 g of PDAP. The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 1 g. of IRGACURE 651 was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.

4. Preparation of binder precursor particles comprising a combination of EP2/PDAP/IRG1/COM/(70/30/1/1)

A 0.5 L. jar was charged with 70 g EP2, a solid, and 30 g of PDAP. The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 1 g of IRG1 and 1 g of COM was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder

TABLE 14
Binder Precursor Particle Formulations
Sample No. Formulations
Sample 51A PDAP/IRG1 (100/10)
Sample 51B PDAP/IRG1 (100/10)
Sample 52A AMN/PDAP (70/30/1)
Sample 52B AMN/PDAP (70/30/1)
Sample 53A EP2/PDAP/COM/IRG1 (70/30/1/1)
Sample 53B EP2/PDAP/COM/IRG1 (70/30/1/1)
Sample 54A PAN/PDAP/IRG1 (50/50/1)
Sample 54B PAN/PDAP/IRG1 (50/50/1)

C. Preparation of Abrasvive Articles Comprising a Make Coat

Binder precursor particle samples 51 - 54 were drop coated onto paper backing EX C90233 which is commercially available from Kimberly-Clark, Neenah, Wis. The specific make weights can be found in Table 15. Next, the binder precursor particles were melted onto the backing in an oven at 100-140° C., and P180 AO mineral was drop coated onto the make coat at a weight of 115 g/m 2 . The sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb.

A size coat precursor was roll coated over the abrasive grains at a wet weight of about 100 g/m 2 . The size coat precursor included a 100% solids blend of EP1 (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KB1 (1 part), and COM (1 part). The sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm “D” bulb followed by a thermal cure for 10 minutes at 100° C.

TABLE 15
Abrasive Articles Comprising a Make Coat
Sample No. Make Coat (g/m                                                                        2                                                                    )
Sample 51A 16.8
Sample 51B 14.9
Sample 52A 20
Sample 52B 15.0
Sample 53A 17.1
Sample 53B 16.8
Sample 54A 17.2
Sample 54B 16.9

D. Evaluation of Abrasive Articles Comprising a Make Coat

1. Test Procedures

a. Schiefer Testing Procedure

The coated abrasive article for each example was converted into a 10.2 cm diameter disc and secured to a foam back-up pad by means of a pressure sensitive adhesive. The coated abrasive disc and back-up pad assembly were installed on a Schiefer testing machine, and the coated abrasive disc was used to abrade a cellulose acetate butyrate polymer. The load was 4.5 kg. The endpoint of the test was 500 revolutions or cycles of the coated abrasive disc. The amount of cellulose acetate butyrate polymer removed is recorded. As illustrated in Table 16, radiation curable binder precursor particles show utility as make coats, especially when the oligomeric material has hydroxyl functionality, for example, AMN and EP2.

TABLE 16
Schiefer Testing
Abrasive Articles Comprising A Make Coat
			Ranking Relative to
	Sample No	Cut (g)	Comparative Abrasive Article W
	Comparative W	1.042	100
	Sample 51A	0.036	3
	Sample 51B	0.423	41
	Sample 52A	0.840	81
	Sample 52B	0.787	76
	Sample 53A	0.862	83
	Sample 53B	0.946	91
	Sample 54A	0.386	37
	Sample 54B	0.630	60

EXAMPLE IV

Preparation of Abrasive Article Comprising a Backing Layer and Abrasive Coating Comprising a Grinding Aid Supersize Coat

A. Preparation of Abrasive Articles Comprising a Backing Layer and Abrasive

1. Abrasive Article E

Abrasive articles used a backing that was a 1080 g/m 2 fiber disk (17.8 cm diameter disc) commercially available from Kimberly-Clark, Neenah, Wis. For each, a make coat precursor was prepared from a 75% solids aqueous solution of a phenolic resole (formaldehyde/phenolic ratio of 1.1-3.0/1, pH of about 9), CaCO 2 and FEO (50/50/2). The make coat precursor was applied to the backing with a paint brush. Next, grade 50 AZ mineral was electrostatically projected into the make coat precursor at a weight of about 685 g/m 2 . The intermediate product was thermally cured for 45 minutes at a temperature of 90° C.

A size coat precursor was applied with a paint brush at a weight of 405 g/m 2 . The size coat precursor was prepared from a 75% solids aqueous solution of a phenolic resole (formaldehyde/phenolic ratio of 1.1-3.0/1, pH of about 9), CRY, and FEO (50/60/2) The sample was cured thermally for 6 hours at 115° C.

2. Comparative Sample X

Abrasive articles used a backing that was a 1080 g/m 2 fiber disk (17.8 cm diameter disc) commercially available from Kimberly-Clark, Neenah, Wis. A make coat precursor was prepared from a 75% solids aqueous solution of a phenolic resole (formaldehyde/phenolic ratio of 1.1-3.0/1, pH of about 9), CaCO 2 and FEO (50/50/2). The make coat precursor was applied to the backing with a paint brush. Next, grade 50 AZ mineral was electrostatically projected into the make coat precursor at a weight of about 685 g/m 2 . The intermediate product was thermally cured for 45 minutes at a temperature of 90° C.

A size coat precursor was applied with a paint brush at a weight of 405 g/m 2 . The size coat precursor was prepared from a 75% solids aqueous solution of a phenolic resole (formaldehyde/phenolic ratio of 1.1-3.0/1, pH of about 9), CRY, and FEO (50/60/2) The sample was cured thermally for 6 hours at 115° C.

B. Preparation of Binder Precursor Particles For Use Grinding Aid Supersize Coat

1. Preparation of binder precursor particles comprising a combination of PDAP/KBF4/ZnSt2/IRG1 (30/60/10/1) (Table 17)

A 0.5 L. jar was charged with 30 g of PDAP, 60 g of KBF4, and 10 g of ZnSt2. The sample was heated to 110-115° C. for 30 minutes and mixed. Next, 1 g. of IRG1 was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.

TABLE 17
Binder Precursor Particle Formulation
Sample No. Formulations
Sample 55  PDAP/KBF4/ZnSt2/IRG1 (30/60/10/1)

C. Preparation of Abrasive Articles Comprising a Grinding Supersize Coat

Binder precursor particle sample 55 were drop coated with a mesh sifter onto Abrasive Article E. The specific supersize weights can be found in Table 18. Next, the binder precursor particles were melted onto the abrasive article in an oven at 100-140° C., The samples were then irradiated (1 pass at 18.3 m/min) with one 400 W/cm “D” bulb.

TABLE 18
Abrasive Article Comprising a Supersize Coat
Sample No. Supersize Coat (g/m                                                                        2                                                                    )
Sample 55  153

D. Evaluation of Abrasive Articles Comprising a Grinding Aid Supersize Coat

1. Swing Arm Flat Test

Abrasive article samples (17.8 cm diameter discs and 2.2 cm center diameter hole and 0.76 mm thickness) were attached to a backup pad and secured to the Swing Arm tester with a metal screw fastener. A 4130 steel workpiece (35 cm diameter) was weighed and secured to the Swing Arm tester with a metal fastener. The pressure was 4.0 kg. The endpoint of the test was 8 min at 350 rpm. The amount of steel removed was recorded.

As illustrated in Table 19, radiation curable binder precursor particles show utility as grinding aid supersize coats.

TABLE 19
Flat Testing of Sample 55 and Comparative X
			Ranking Relative to
	Sample No	Cut (g)	Comparative Abrasive Article X
	Comparative W	128	100
	Sample 55	134	105

Numerous characteristics, advantages, and embodiments of the invention have been described in detail in the foregoing description with reference to the accompanying drawings. However, the disclosure is illustrative only and the invention is not intended to be limited to the precise embodiments illustrated. Various changes and modifications may be made in the invention by one skilled in the art without departing from the scope or spirit of the invention.

Claims

1. A method of forming an abrasive article, comprising the steps of:(a) incorporating a plurality of abrasive particles into a bond system to form a particulate mixture, wherein at least a portion of the bond system is derived from a solventless solid binder precursor, said binder precursor comprises a radiation curable component that is flowable at a temperature in the range of about 35° C. to about 180° C.; (b) depositing the particulate mixture onto an underlying surface of the abrasive article; (c) liquefying the binder precursor to form a melt layer on the underlying surface; and (d) solidifying the melt layer to bond the abrasive particles to the underlying surface.

2. A method of forming an abrasive article comprising the steps of:(a) depositing a bond system onto an underlying surface of the abrasive article, wherein at least a portion of the bond system is derived from a solventless solid binder precursor, said binder precursor comprising a radiation curable component that is flowable at a temperature in the range of about 35° C. to about 180° C.; (b) liquefying the binder precursor to form a melt layer on the underlying surface; (c) depositing a plurality of abrasive particles onto the melt layer; and (d) solidifying the melt layer to bond the abrasive particles to the underlying surface.

3. The method of claim 2 further comprising the steps of:(i) dry coating a fusible powder onto the abrasive layer, wherein at least a portion of the fusible powder is derived from a solventless binder precursor, said binder precursor comprising a radiation curable component that is flowable at a temperature in the range of about 35° C. to about 180° C.; (ii) liquefying the fusible powder to form a size melt layer; and (iii) solidifying the size melt layer to form a size coat.

4. The method of claim 3 further comprising the step of applying a supersize coating precursor over the size coat, wherein at least a portion of the supersize precursor is derived from a solventless binder precursor, said binder precursor comprising a radiation curable component that is flowable at a temperature in the range of about 35° C. to about 180° C.

5. An abrasive article comprising a plurality of abrasive particles incorporated into a bond system, wherein at least a portion of the bond system comprises a cured binder derived from a solventless, solid binder precursor, said binder precursor comprising a radiation curable component that is flowable at a temperature in the range from about 35° C. to about 180° C.

6. The abrasive article of claim 5, wherein the radiation curable component comprises at least one radiation curable binder precursor having a backbone containing an aromatic or heterocyclic moiety.

7. The abrasive article of claim 5, wherein the radiation curable component comprises at least one radiation curable binder precursor including a plurality of radiation curable groups and a plurality of OH groups.

8. The abrasive article of claim 5, wherein the radiation curable component comprises (i) at least one polyfunctional, radiation curable monomer, and (ii) at least one polyfunctional, radiation curable macromolecule selected from an oligomer, a polymer, or a combination of at least one oligomer and at least one polymer, wherein the weight ratio of the monomer to the macromolecule is in the range from about 1:10 to about 10:1.

9. The abrasive article of claim 8, wherein at least one of the monomer or macromolecule is a solid at temperatures below about 35° C.

10. The abrasive article of claim 8, wherein the monomer and macromolecule are both solids at temperatures below about 35° C.

11. The abrasive article of claim 8, wherein the monomer is a solid at temperatures below about 35° C. and the macromolecule is a liquid at least under ambient conditions.

12. The abrasive article of claim 8, wherein the monomer is selected from a reaction product of a dicarboxylic acid and a reactant comprising hydroxy and radiation curable functionality, a reaction product of a hydroxyl functional isocyanurate and a carboxylic acid, a reaction product of a diisocyanate and a reactant comprising hydroxy and radiation curable functionality, a cyanate ester, a vinyl ether, or combinations thereof.

13. The abrasive article of claim 8, wherein the oligomer is selected from the group consisting of a novolak phenolic oligomer functionalized with a plurality of radiation curable groups, a chain-extended bisphenol A epoxy oligomer functionalized with a plurality of radiation curable groups, an epoxy functional oligomer, a novolak oligomer functionalized with cyanate ester functionality and combinations thereof.

14. The abrasive article of claim 5, wherein the radiation curable component comprises a radiation curable, polyfunctional monomer and a radiation curable, polyfunctional oligomer, wherein each of said monomer and oligomer independently has a melting point such that a blend of the monomer and oligomer is a solid at a temperature below about 35° C. and such that said blend is a melt at a temperature above about 35° C., wherein the weight ratio of the monomeric component to the oligomeric component is in the range from about 1:10 to 10:1.

15. The abrasive article of claim 5, wherein the radiation curable component comprises a monomer of the formula: wherein W is a divalent aromatic moiety, X is divalent linking group, and R is selected from hydrogen or a lower alkyl group of 1 to 4 carbon atoms.

16. The abrasive article of claim 5, wherein the radiation curable component comprises a monomer of the formula: wherein W′ is a divalent, aromatic moiety, Z′ is a divalent linking group, and R is hydrogen or a lower alkyl group of 1 to 4 carbon atoms.

17. The abrasive article of claim 5, wherein the radiation curable component comprises a monomer of the formula: wherein X″ is a divalent linking group.

18. The abrasive article of claim 5, wherein the radiation curable component comprises an oligomer of the formula: wherein n has an average value in the range from about 3 to about 20.

19. The abrasive article of claim 5, wherein the radiation curable component comprises an oligomer of the formula: wherein n has an average value in the range from about 3 to about 20.

20. The abrasive article of claim 5, wherein the radiation curable component comprises an oligomer of the formula: wherein n has a value such that the oligomer has a number average molecular weight in the range from about 800 to about 5000.

21. The method of claim 2, wherein the bond system comprises a polymeric make coat binder, wherein at least a portion of the make coat binder is derived from the binder precursor.

22. The method of claim 2, wherein the liquefying step comprises heating the powder to a temperature in the range from about 40° C. to about 140° C.

23. The method of claim 2, wherein the radiation curable component comprises at least one compound having a backbone containing an aromatic or heterocyclic moiety.

24. The method of claim 2, wherein the radiation curable component comprises at least one radiation curable macromolecule including a plurality of radiation curable groups and a plurality of OH groups.

25. The method of claim 2, wherein the radiation curable component comprises at least one polyfunctional, radiation curable monomer and at least one polyfunctional, radiation curable macromolecule selected from an oligomer, a polymer, or a combination of at least one oligomer and at least one polymer, wherein the weight ratio of the monomer to the macromolecule is in the range from about 1:10 to about 10:1.

26. The method of claim 25, wherein at least one of the monomer or macromolecule is a solid at temperatures below about 35° C.

27. The method of claim 25, wherein the monomer and macromolecule are both solids at temperatures below about 35° C.

28. The method of claim 25, wherein the monomer is a solid at temperatures below about 35° C. and the macromolecule is a liquid at least under ambient conditions.

29. The method of claim 25, wherein the monomer is selected from a reaction product of a dicarboxylic acid and a reactant comprising hydroxy and radiation curable functionality, a reaction product of a hydroxyl functional isocyanurate and a carboxylic acid, a reaction product of a diisocyanate and a reactant comprising hydroxy and radiation curable functionality, a cyanate ester, a vinyl ether or combinations thereof.

30. The method of claim 25, wherein the oligomer is selected from the group consisting of a novolak phenolic oligomer functionalized with a plurality of radiation curable groups, a chain-extended bisphenol A epoxy oligomer functionalized with a plurality of radiation curable groups, an epoxy functional oligomer, a novolak oligomer functionalized with cyanate ester functionality and combinations thereof.

31. The method of claim 2, wherein the radiation curable component comprises a radiation curable, polyfunctional monomer and a radiation curable, polyfunctional oligomer, wherein each of said monomer and oligomer independently has a melting point such that a blend of the monomer and oligomer is a solid at a temperature below about 35° C. and such that said blend is a melt at a temperature above about 35° C., wherein the weight ratio of the monomeric component to the oligomeric component is in the range from about 1:10 to 10:1.

32. The method of claim 2, wherein the radiation curable component comprises a monomer of the formula: wherein W is a divalent aromatic moiety, X is divalent linking group, and R is selected from hydrogen or a lower alkyl group of 1 to 4 carbon atoms.

33. The method of claim 2, wherein the radiation curable component comprises a monomer of the formula: wherein W′ is a divalent, aromatic moiety, Z′ is a divalent linking group, and R is hydrogen or a lower alkyl group of 1 to 4 carbon atoms.

34. The method of claim 2, wherein the radiation curable component comprises a monomer of the formula: wherein X″ is a divalent linking group.

35. The method of claim 2, wherein the radiation curable component comprises an oligomer of the formula: wherein n has an average value in the range from about 3 to about 20.

36. The method of claim 2, wherein the radiation curable component comprises an oligomer of the formula: wherein n has an average value in the range from about 3 to about 20.

37. The method of claim 2, wherein the radiation curable component comprises an oligomer of the formula: wherein n has a value such that the oligomer has a number average molecular weight in the range from about 800 to about 5000.

38. The method of claim 4, wherein the radiation curable component comprises a metal salt of a fatty acid.

39. A method of forming a supersize coating on an underlying abrasive layer of an abrasive article, comprising:(a) dry coating a fusible powder onto the abrasive layer, wherein the fusible powder comprises at least one metal salt of a fatty acid; (b) liquefying the fusible powder to form a supersize melt layer; and (c) solidifying the supersize melt layer, whereby the supersize coating is formed.

40. The method of claim 39, wherein the fusible powder further comprises 0 to 30 parts by weight of a radiation curable binder precursor per 100 parts by weight of the metal salt of a fatty acid.

41. The method of claim 39, wherein the fusible powder further comprises 0 to 30 parts by weight of a thermoplastic macromolecule per 100 parts by weight of the metal salt of a fatty acid.

42. The method of claim 39, wherein the fusible powder further comprises 0 to 30 parts by weight of a thermosetting macromolecule per 100 parts by weight of the metal salt of a fatty acid.

43. The method of claim 40, wherein step (b) comprises heating the fusible powder at a melt processing temperature in the range from about 35° C. to about 140° C.

44. The method of claim 40, wherein step (c) comprises irradiating the melt layer with radiation.

45. The method of claim 39, wherein the fusible powder comprises calcium stearate and zinc stearate, wherein the weight ratio of the calcium stearate to the zinc stearate is in the range from 1:1 to 9:1.

46. A method of forming a peripheral coating on an underlying abrasive layer of an abrasive article, comprising:(a) dry coating a fusible powder onto the abrasive layer, wherein the fusible powder comprises at least one grinding aid; (b) liquefying the fusible powder to form a peripheral melt layer; and (c) solidifying the peripheral melt layer, whereby the peripheral coating is formed.

47. The method of claim 46 wherein the grinding aid is an organic halide, a halide salt, a metal, a metal alloy, or combinations thereof.

48. The abrasive article of claim 5, wherein the solventless solid binder precursor is a powder.