The present invention relates to absorbent articles, e. g. disposable absorbent articles, such as diapers, incontinent briefs, training pants and the like.
Infants and other incontinent individuals wear absorbent articles such as diapers to receive and contain urine and other body exudates. In general, absorbent articles function contain the discharged materials and/or to isolate these materials from the body of the wearer and from the wearer's garments and surroundings. Accordingly, it is desirable to completely eliminate or at least minimize leakage from the absorbent article.
In an effort to control leakage from absorbent articles and enhance containment of waste material, absorbent articles have been provided with elastic features, such as elastic waist and/or leg features. Despite such improvement such absorbent articles still show a tendency towards leakage. For example, it has been observed that absorbent articles having elastic waist features have a tendency to sag or gap away from the body of the wearer during wear or the waist feature has a tendency to roll down or in, all of which can lead to leakage about the wearer in the waist regions.
Containment flaps and moisture responsive members have also been proposed and/or utilized in absorbent articles. For example, U.S. Pat. No. 5,935,118 discloses an absorbent article includes a garment shell and at least one liquid containment beam formed of an absorbent material and bonded along an attachment edge to the garment shell so that the containment beam can lie against the garment shell and also pivot about an axis defined by the attachment edge, wherein the containment beam, for example, may swell upon absorbing liquid and thereafter form a physical barrier to inhibit liquid movement within the absorbent article. U.S. Pat. No. 7,314,967, for example, discloses a disposable absorbent article having first longitudinal edge, a second longitudinal edge, a front waist edge, and a rear waist edge, the disposable article comprising: a backsheet; a topsheet bonded to the backsheet; an absorbent core disposed between the topsheet and the backsheet; and a first moisture responsive member containing e. g. an absorbent gelling material and attached to the disposable absorbent article along at least one of the first longitudinal edge, the second longitudinal edge, the front waist edge, and the rear waist edge of the disposable absorbent article outboard of the absorbent core, wherein the first moisture responsive member provides contact with a portion of a wearer's body such that when the moisture responsive member is wetted by moisture from the wearer's body, the first moisture responsive member expands against the portion of the wearer's body to form a seal between the first moisture responsive member and the portion of the wearer's body.
Such absorbent articles still have an undesirable tendency towards leakage. In particular it has been found that for such absorbent articles including a containment flap or moisture responsive member outboard of the absorbent core, leakage often results from discharged liquid and materials, in particular in the case of discharge of large amounts of liquids and materials in a short period of time, running over the containment flap and/or the moisture responsive member before absorbent material of the flap or member has a chance to expand and thus before the flap or member has a chance to form a barrier or seal.
Therefore, there exists a need for an absorbent article to have improved leakage characteristics in particular an absorbent article that can provide maximum leakage protection when the leakage protection is needed the most, such as situations where there is excessive discharge of liquid and materials in a short period of time.
It is has been found that by providing one or more liquid conducting members extending from the central region of the absorbent article, which includes the absorbent core, to a liquid response barrier member comprising absorbent material, such as a containment flap or moisture responsive member, located outboard of the absorbent core in a peripheral region of the absorbent article, the absorbent material of the liquid response barrier member expands as a result of liquid absorbance and thus the liquid response barrier member forms a barrier or a seal before the overall level of discharged liquid and material within the absorbent article reaches the fluid response barrier member. In this manner, the formation of a barrier or seal before the amount of the discharged liquid and material in the absorbent article reaches a critical level is facilitated, and accordingly once the amount of the discharged liquid and material reaches a critical level the formed barrier or seal facilitates containment of discharged liquid and material within the absorbent article and thereby minimizing leakage.
Accordingly, the present invention provides an absorbent article having a central region and a peripheral region, the absorbent article comprising:
Favorably, the first end of the at least one elongate liquid conducting member positioned in the central region or directly adjacent to the outer periphery of the central region and the second end or a portion including the second end (“second end portion”) of the at least one elongate liquid conducting member is positioned adjacent or in proximity to the at least one elongate liquid response barrier member such that fluid that is conducted along the at least one elongate liquid conducting member is communicated to the absorbent material of the at least one elongate liquid response barrier member.
The at least one elongate liquid conducting member may be disposed either between the topsheet and the backsheet or on the interior surface of the absorbent article, for example onto the topsheet of the article, which allows for flexibility in the design of absorbent article as well as in the manufacture thereof. Alternatively, the liquid conducting member may be disposed between the topsheet and the absorbent core of the absorbent article.
It has been found advantageous to use liquid conducting members which comprise a fluid control film having at least one microstructure-bearing surface with a plurality of channels therein that permit transport of liquid between a central portion and the at least one elongate liquid response barrier member. Such elongate liquid conducting members may favorably comprise a cap layer to enclose the channels along at least a portion of the length of the liquid conducting member, for example to enhance the creation of discrete channels and/or to minimize or prevent liquid from being transferred over the sides of the liquid conducting members along its length onto the topsheet in the peripheral region.
Further scope of applicability and advantages of the present invention will become apparent from the detailed description given hereinafter. However, it should be understood that the detailed description and specific examples, while indicating preferred embodiments of the invention, are given by way of illustration only, since various changes and modifications within the spirit and scope of the invention will become apparent to those skilled in the art from this detailed description.
The present invention will become more fully understood from the detailed description given hereinbelow and the accompanying drawings which are given by way of illustration only, and thus, are not limiting of the present invention, and wherein:
Corresponding parts are marked with the same reference symbols in all figures.
With reference to the
Referring to
The absorbent article includes an elongate liquid response barrier member provided on an interior surface of the absorbent article (for example attached to the topsheet) in the peripheral region, and thus outboard of the absorbent core, and positioned along an outer edge of the absorbent article, either adjacent to or spaced apart from said outer edge. In the embodiments illustrated in
The elongate liquid response barrier member comprises absorbent material. And in use the absorbent material expands upon absorbing liquid (e. g. as urine) and upon expansion of the absorbent material the elongate liquid response barrier member forms a barrier or a seal between the at least one elongate liquid response barrier member and a respective portion of the body of a wearer of the absorbent article.
In addition, the absorbent article includes at least one elongate liquid conducting member extending from the central region of the absorbent article to the at least one elongate liquid response barrier member. In the exemplary embodiments illustrated in
One end of the elongate liquid conducting member may be positioned either directly adjacent to the outer periphery of the central region or in the central region. It has been found to be advantageous to the position the first end of the elongate liquid conducting member within the central region to facilitate the conduct of the fluid from the central portion to the liquid response barrier member in a timely manner. Favorably the positioning of the first end of the elongate liquid conducting member can be optimized having regard to the particular absorbent article under consideration, for example its construction, absorbency capabilities as well as what is considered to amount to a critical level of discharge fluid and material in terms of potential imminent leakage. For example, in a disposable diaper, discharged fluid and material reaching a level of about one-half up the rear portion of the diaper would typically be considered as critical and in such as case it would be desirable to dispose the first end of the elongate liquid conducting member within the central portion at position lower than said critical level. In the exemplary embodiments shown in
Elongate liquid conducting members favorably comprise a fluid control film having at least one microstructure-bearing surface with a plurality of channels therein that permit transport of liquid. Suitable fluid control films for use in the present invention are described in U.S. Pat. Nos. 5,514,120 and 5,728,446 and described generally in the following. The microreplicated channels of the fluid control films described in U.S. Pat. Nos. 5,514,120 and 5,728,446 are precisely replicated from a predetermined pattern and form a series of individual open capillary channels that extend along a major surface. (“Microreplication” means the production of a microstructured surface through a process where the structured surface features retain an individual feature fidelity during manufacture). These microreplicated channels formed in films are favorably uniform and regular along substantially each channel length and from channel to channel and advantageously provide more effective liquid flow than is achieved with webs, foam, or fibrous material, such as tows and nonwovens.
Desirably fluid control films used in the present invention are capable of spontaneously and uniformly transporting liquids along the axis of the film channels. Two general factors that influence the ability of fluid control films to spontaneously transport liquids (e. g., water, urine or vaginal secretions) are (i) the geometry or topography of the surface (capillarity, shape of the channels) and (ii) the nature of the film surface (e. g., surface energy). To achieve the desired amount of fluid transport capability the designer may adjust the structure or topography of the fluid control film and/or adjust the surface energy of the fluid control film surface. In order for a closed channel wick made from a fluid control film to function it preferably is sufficiently hydrophilic to allow the desired fluid to wet the surface. Generally, to facilitate spontaneous wicking in open channels, the fluid must wet the surface of the fluid control film, and the contact angle be equal to or less than 90 degrees minus one-half the notch angle.
The channels of fluid control films can be of any geometry that provides desired liquid transport, and preferably one which is readily replicated. The geometry of the channels may change over their length. Furthermore, the number of channels may vary, for example, the number may be 1 to 150, preferably 10 to 100, more preferred 20 to 80 channels.
Fluid control films can be formed from any thermoplastic materials suitable for casting, or embossing including, for example, polyolefins, polyesters, polyamides, poly (vinyl chloride), polyether esters, polyimides, polyesteramide, polyacrylates, polyvinylacetate, hydrolyzed derivatives of polyvinylacetate, etc. Polyolefins are preferred, particularly polyethylene or polypropylene, blends and/or copolymers thereof, and copolymers of propylene and/or ethylene with minor proportions of other monomers, such as vinyl acetate or acrylates such as methyl and butylacrylate. Polyolefins are preferred because of their excellent physical properties, ease of processing, and typically lower cost than other thermoplastic materials having similar characteristics. Polyolefins readily replicate the surface of a casting or embossing roll. They are tough, durable and hold their shape well, thus making such films easy to handle after the casting or embossing process. Hydrophilic polyurethanes are also preferred for their physical properties and inherently high surface energy. Alternatively, fluid control films can be cast from thermosets (curable resin materials) such as polyurethanes, acrylates, epoxies and silicones, and cured by exposure to heat or UV or E-beam radiation, or moisture. These materials may contain various additives including surface energy modifiers (such as surfactants and hydrophilic polymers), plasticizers, antioxidants, pigments, release agents, antistatic agents and the like.
The surface properties, e. g. the hydrophilicity, may vary over the length of the material such that the hydrophilicity increases or decreases from one end to another to form a gradient.
Generally, the susceptibility of a solid surface to be wet out by a liquid is characterized by the contact angle that the liquid makes with the solid surface after being deposited on the horizontally disposed surface and allowed to stabilize thereon. It is sometimes referred to as the “static equilibrium contact angle”, sometimes referred to herein merely as “contact angle”. As shown in
Depending on the nature of the microreplicated film material itself, and the nature of the fluid being transported, one may desire to adjust or modify the surface of the film in order to ensure sufficient capillary forces. For example, the surface of the fluid control film may be modified in order to ensure it is sufficiently hydrophilic. Here body liquids that will come into contact with the fluid control films are aqueous. Thus, if films made of a polyolefin, for example, are to be used as fluid control films, they generally must be modified, e. g., by surface treatment, application of surface coatings or agents, or incorporation of selected agents, such that the surface is rendered hydrophilic so as to exhibit a contact angle of 90 or less, thereby enhancing the wetting and liquid transport properties of the fluid control film. Suitable methods of making the surface hydrophilic include: (i) incorporation of a surfactant; (ii) incorporation or surface coating with a hydrophilic polymer; and (iii) treatment with a hydrophilic silane.
Other methods are also envisioned.
The fluid control films may have a variety of topographies. Preferred fluid control films are comprised of a plurality of channels with V-shaped or rectangular cross-sections, and combinations of these, as well as structures that have secondary channels, i. e., channels within channels. For open channels, the desired surface energy of the microstructured surface of V-channeled fluid control films is such that:
Theta<(90−Alpha/2),
wherein Theta is the contact angle of the liquid with the film and Alpha (α) is the average included angle of the secondary V-channel notches. (See, e. g.,
Any suitable known method may be utilized to achieve a hydrophilic surface on fluid control films. Surface treatments may be employed such as topical application of a surfactant, plasma treatment, vacuum deposition, polymerization of hydrophilic monomers, grafting hydrophilic moieties onto the film surface, corona or flame treatment, etc. Alternatively, a surfactant or other suitable agent may be blended with the resin as an internal additive at the time of film extrusion. It is typically preferred to incorporate a surfactant in the polymeric composition from which the fluid control film is made rather than rely upon topical application of a surfactant coating. Topically applied coatings tend to fill in, i. e., blunt, the notches of the channels, thereby interfering with the desired liquid flow to which the invention is directed. An illustrative example of a surfactant that can be incorporated in polyethylene fluid control films is TRITON™ X-100, an octylphenoxypolyethoxyethanol nonionic surfactant, e. g., used at between about 0.1 and 0.5 weight percent. An illustrative method for surface modification of the films is the topical application of a 1 percent aqueous solution of the reaction product comprising 90 weight percent or more of:
wherein n=8 (97 percent), n=7 (3 percent), and 10 weight percent or less of CH2CH3 CnF2n+1 S02NsH
wherein n=8 (97 percent), n=7 (3 percent). Preparation of such agents is disclosed in U.S. Pat. No. 2,915,554 (Ahlbrecht et al.).
As discussed above, a surfactant or mixture of surfactants may be applied to the surface of the fluid control film or impregnated into the article in order to adjust the properties of the fluid control film or article. For example, it may be desired to make the surface of the fluid control film more hydrophilic than the film would be without such a component.
Desirably the favorable fluid transport properties are retained throughout the life of the product into which the fluid control film is incorporated. In order to ensure the surfactant is available throughout the life of the fluid control film the surfactant preferably is available in sufficient quantity in the article throughout the life of the article or is immobilized at the surface of the fluid control film. For example, a hydroxyl functional surfactant can be immobilized to a fluid control film by functionalizing the surfactant with a di- or tri-alkoxy silane functional group. The surfactant could then be applied to the surface of the fluid control film or impregnated into the article with the article subsequently exposed to moisture. The moisture would result in hydrolysis and subsequent condensation to a polysiloxane. Hydroxy functional surfactants (especially 1,2 diol surfactants) may also be immobilized by association with borate ion. Suitable surfactants include anionic, cationic, and non-ionic surfactants, however, nonionic surfactants may be preferred due to their relatively low irritation potential. Polyethoxylated and polyglucoside surfactants are particularly preferred including polyethoxylated alkyl, aralkyl, and alkenyl alcohols, ethylene oxide and propylene oxide copolymers such as “Pluronic” and “Tetronic”, alkylpolyglucosides, polyglyceryl esters, and the like. Other suitable surfactants are disclosed in Ser. No. 08/576,255.
As discussed above, a hydrophilic polymer or mixture of polymers may be applied to the surface of the fluid control film or impregnated into the article in order to adjust the properties of the fluid control film. In order to ensure the hydrophilic polymer is available throughout the life of the fluid control film the polymer preferably is available in sufficient quantity in the article throughout the life of the article or is immobilized at the surface of the fluid control film. Alternatively, a hydrophilic monomer may be added to the article and polymerized in situ to form an interpenetrating polymer network. For example, a hydrophilic acrylate and initiator could be added and polymerized by heat or actinic radiation.
Suitable hydrophilic polymers include: homo and copolymers of ethylene oxide; hydrophilic polymers incorporating vinyl unsaturated monomers such as vinylpyrrolidone, carboxylic acid, sulfonic acid, or phosphonic acid functional acrylates such as acrylic acid, hydroxy functional acrylates such as hydroxyethylacrylate, vinyl acetate and its hydrolyzed derivatives (e. g. polyvinylalcohol), acrylamides, polyethoxylated acrylates, and the like; hydrophilic modified celluloses, as well as polysaccharides such as starch and modified starches, dextran, and the like.
As discussed above, a hydrophilic silane or mixture of silanes may be applied to the surface of the fluid control film or impregnated into the film in order to adjust the properties of the fluid control film. Suitable silanes include the anionic silanes disclosed in U.S. Pat. No. 5,585,186, as well as non-ionic or cationic hydrophilic silanes. Cationic silanes may be advantageous in that certain of these silanes are also believed to have antimicrobial properties.
As previously mentioned the channels of fluid control films can be of any geometry that provides desired liquid transport. Fluid control films can have primary channels on both major surfaces, however it has been found that fluid control films having primary channels on only one major surface (e. g. as shown in
As shown in
As shown in
With reference to
The primary channel included angle is not critical except in that it should not be so wide that the primary channel is ineffective in channeling liquid. Generally, the primary channel maximum width is less than 3000 microns and preferably less than 1500 microns. The included angle of a V-channel shaped primary channel will generally be from about 10 degrees to 120 degrees, preferably 30 to 90 degrees. If the included angle of the primary channel is too narrow, the primary channel may not have sufficient width at its base so that it is capable of accommodating an adequate number of secondary channels. Generally, it is preferred that the included angle of the primary channel be greater than the included angle of the secondary channels so as to accommodate the two or more secondary channels at the base of the primary channel. Generally, the secondary channels have an included angle at least 20 percent smaller than the included angle of the primary channel (for V-shaped primary channels).
With reference to
As illustrated in
The depth of one of the secondary channels (603, 623) (the height of the top of the secondary peaks 606 over the notches 605) is uniform over the length of the fluid control films, and is typically at least 5 microns. The depth of the secondary channels (603, 623) is generally 0.5 to 80 percent of the depth of the primary channels, preferably 5 to 50 percent. The spacing of the notches (605, 625) on either side of a peak 6 is also preferably uniform over the length of the fluid control film. Preferably the primary and/or secondary channel depth and width varies by less than 20 percent, preferably less than 10 percent for each channel over a given length of the fluid control film. Variation in the secondary channel depth and shape above this range has a substantial adverse impact on the rate and uniformity of liquid transport along the fluid control film. Generally, the primary and secondary channels are continuous and undisturbed.
The structured surface can also be provided with a very low profile. Thus, elongate liquid conducting members comprising are contemplated where the structured polymeric layer of the fluid control film has a thickness of less than 5000 micrometers, and possibly less than 1500 micrometers. To do this, the channels may be defined by peaks that have a height of approximately 5 to 1200 micrometers and that have a peak distance of about 10 to 2000 micrometers.
Suitable channels in fluid control films used in the liquid conducting members of the present invention may be of any suitable geometry but are generally rectangular (typically having depths of 50 to 3000 micron and widths of 50 to 3000 micron or “V” channel patterns (typically having depths of about 50 to 3000 micron and heights of 50 to 3000 micron) with an included angle of generally 20 to 120 degrees and preferably about 45 degrees. The presently preferred structure has a nested construction wherein the master channels are 200 micron deep and repeat every 225 micron with three equally spaced channels in the base each 40 micron deep. Compound channels are also possible and often preferably such as rectangular channels that contain smaller rectangular or V channels within.
Elongate liquid conducting members may comprise layers of two or more fluid control films. As indicated above, elongate liquid conducting members comprising a fluid control film may favorably comprise a cap layer to enclose the channels, at least in part along the length of the liquid conducting member, for example to enhance creation of discrete channel and more particularly to minimize or prevent fluid from being transferred over the sides of the liquid conducting members along its length for example onto the topsheet in the peripheral region. A cap layer may be juxtaposed against the structured surface, in particular onto the highest peaks or plateaus of the structure. A cap layer may be bonded to some or all the highest peaks or plateaus of the structured surface. This can be done thermally or by using conventional adhesives that are compatible with the cap layer material and the polymeric structured layer. Bonds may be provided entirely along the peaks or plateaus to the cap layer or the bonds may be spot welds or bonds that may be placed thereon in an ordered or random pattern. Cap layer preferably is made from a polymeric material such as the polymers described for the structured polymeric layer. Polymers may be chosen such that the cap layer can be secured to the structured surface without using an adhesive. Such a polymer could be chosen such that the cap layer becomes securely welded to the structured surface by applying heat, for example, as from an ultrasonic welding operation. Optionally, dependent on the overall absorbent article construction, a cap layer may comprise a material such as a spunlaced, spunbond, blown microfiber or carded nonwoven.
Sidewalls may be arranged surrounding the liquid conducting members in part or entirely. These sidewalls may form a U-shaped profile. Such profiles may be closed on one end of the liquid conducting members.
Returning to the exemplary embodiment of
In reference to
The elongate liquid response barrier member 30 has a longitudinal attachment edge portion 32 near the outer edge, here the rear waist edge 13, of the absorbent article. The liquid response barrier member is attached along the longitudinal attachment edge portion to the interior surface of the absorbent article, in particular to the topsheet. (As typical in the art the topsheet 10 is bonded to the backsheet 11 is the peripheral region of the absorbent article). Absorbent material 31 is disposed in the free portion 33 (i. e. unattached portion) of the liquid response barrier member 30. The free portion 33 of the elongate liquid response barrier member 30 can lie towards the topsheet, and in this exemplary embodiment lie resting on the second end portion 45 of liquid conducting member 40. The free portion 33 of the elongate liquid response barrier member 30 can also pivot about an axis defined by the attachment edge portion 32. As shown in this exemplary embodiment, the absorbent material may be provided in a sheath 34 made of a liquid permeable material. The sheath may comprise a woven or a nonwoven web adapted to readily take in and transport liquid (for example having hydrophilic properties) as well as being extensible. The liquid response barrier member may optionally be provided with an outer liquid impermeable layer 35, distant to the liquid conducting member and near to the wearer of the article in use. Any liquid impermeable material may be used, favorably a soft material and a material is also adapted to expand. The portion of the liquid permeable sheath 34 resting on the liquid conducting member 40 is in fluid communication with the conducting member and thus liquid can be communicated from the liquid conducting member 40 to the absorbent material 31 over that portion of liquid permeable sheath.
Referring to
For both exemplary variants shown in
The second end 42 of the liquid conducting member is positioned 40 to abut the absorbent material 31 and thus the absorbent material is in direct fluid communication with the channels of the fluid control film of the liquid conducting member 30 (see e. g.
For both exemplary variants shown in
Returning to
Absorbent material of the liquid response barrier member may comprise super absorbents such as those described in U.S. Pat. No. 7,314,967. Absorbent material of the liquid response barrier member may comprise absorbent gelling material (such as Gelling Elastic Material produced by The Procter and Gamble Corp; Gelling adhesive material manufactured by H. B. Fuller of St. Paul, Minn., USA, under the designation HydroLock, or superporous hydrogels manufactured by Akina West of Lafayette, Ind., USA, under the designation Aquagel) or a fluid stable aggregates, or any combinations thereof.
The absorbent gelling material (“AGM”) includes a variety of water-insoluble, but water-swellable polymers capable of absorbing large quantities of fluids. Such polymer materials are generally known in the art and include all those well-known polymers used or deemed useful in the context of disposable absorbent article technology. Particularly the AGMs disclosed in EP-A-752 892 or those disclosed in the textbook entitled “Modem Super Absorbent Technology” by F. L. Buchholz and A. T. Graham, published by Wiley VCH, New York, 1998 are useful. AGM particles may be of numerous shapes. The term “particles” refers to granules, fibers, flakes, spheres, powders, platelets, and other shapes and forms known to person skilled in the art of AGMs. The particles can be in the form of granules, beads, that have a particle size from about 10 μ]m to about 1000 μm, or even from about 100 μm to about 1000 μm, or even from about 150 μm to about 850 μm and or even from about 150 μm to about 500 μm. In another embodiment, the AGMs can be in the shape of fibers, i. e. elongated, acicular AGM particles. In another embodiment, the AGM may be pre-wetted such that the AGM is already in a gel like state. The fibers can also be in the form of a long filament that can be woven into a sheet. The AGM may be in sheet form and disposed on the second end portion of the liquid conducting member or the topsheet. Alternatively, the AGM may be printed or glued to the cover layer, in particular to the liquid impermeable cover layer using any suitable bonding or printing process that is well known in the art.
Fluid stable aggregates (“FSA's”) can be used to make up absorbent polymeric macrostructures. Exemplary FSA's structures suitable for use are described in U.S. Pat. No. 5,536,264 entitled “Absorbent Composites Comprising a Porous Macrostructure of Absorbent Gelling Particles and A Substrate” issued to Hsueh et al. on Jul. 16, 1996; U.S. Pat. No. 6,224,961 entitled “Absorbent Macrostructure Made From Mixtures of Different Hydrogel-Forming Absorbent Polymers for Improved Fluid Handling Capability” issued to Hsueh et al. on May 1, 2001; U.S. Pat. No. 5,428,076 entitled “Flexible, Porous, Absorbent, Polymeric Macrostructures and Methods of Making the Same” issued to Roe on Jun. 27, 1995; U.S. Pat. No. 5,372,766 entitled “Flexible, Porous, Absorbent, Polymeric Macrostructures and Methods of Making the Same” issued to Roe on Dec. 13, 1994; U.S. Pat. No. 5,324,561 entitled “Porous, Absorbent, Macrostructures of Bonded Particles Surface Crosslinked with Cationic Amino-Epichlorohydrin Adducts” issued to Rezai et al. on Jun. 28, 1994; U.S. Pat. No. 5,124,188 entitled “Porous, Absorbent, Polymeric Macrostructures and Methods of Making the Same” issued to Roe et al. on Jun. 23, 1992; and U.S. Pat. No. 5,102,597 entitled “Porous, Absorbent, Polymeric Macrostructures and Methods of Making the Same” issued to Roe et al. on Apr. 7, 1992.
Any suitable liquid impermeable material known in the art may be used in a liquid impermeable layer or cover layer of the liquid response barrier member. For example, a liquid impermeable layer or cover layer may comprise an elastomeric material which includes those materials manufactured by Kraton Polymers Inc. of Houston, Tex., USA, and sold under trade names Kraton D and Kraton G.
Any suitable liquid permeable material known in the art may be used in a liquid permeable layer or sheath of the liquid response barrier member. As an example, the liquid permeable layer or sheath may comprise a carded nonwoven material that is made of bi-component fibers of a polyethylene (PE) and a polypropylene (PP) where the ratio of PE/PP is about 50/50 (e. g. obtainable from Chisso Corp., Moriyama, Japan). Alternatively, the liquid permeable sheath may comprise a spunbonded nonwoven material that is made of bi-component fibers of a polyethylene (PE) and a polypropylene (PP) with a ratio of PE/PP of about 80/20 (e. g. obtainable from Mitsui Petrochemical Industries, Ltd., Tokyo, Japan).
Exemplary embodiments of this invention are discussed and reference has been made to some possible variations within the scope of this invention. These and other variations and modifications in the invention will be apparent to those skilled in the art without departing from the scope of the invention, and it should be understood that this invention is not limited to the exemplary embodiments set forth herein. Accordingly, the invention is to be limited only by the claims provided below and equivalents thereof.
Number | Date | Country | Kind |
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1806839.5 | Apr 2018 | GB | national |
Filing Document | Filing Date | Country | Kind |
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PCT/IB2019/053454 | 4/26/2019 | WO | 00 |