Absorbent sheet having regenerated cellulose microfiber network

Abstract
An absorbent paper sheet for tissue or towel includes from about 99 percent to about 70 percent by weight of cellulosic papermaking fiber and from about 1 percent to about 30 percent by weight fibrillated regenerated cellulose microfiber which was regenerated form a cellulosic dope utilizing a tertiary amine N-oxide solvent or an ionic liquid. Fibrillation of the microfiber is controlled such that it has a reduced coarseness and a reduced freeness as compared with unfibrillated regenerated cellulose microfiber from which it is made and provides at least one of the following attributes to the absorbent sheet: (a) the absorbent sheet exhibits an elevated SAT value and an elevated wet tensile value as compared with a like sheet prepared without fibrillated regenerated cellulose microfiber; (b) the absorbent sheet exhibits an elevated wet/dry CD tensile ratio as compared with a like sheet prepared without fibrillated regenerated cellulose microfiber; (c) the absorbent sheet exhibits a lower GM Break Modulus than a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber; or (d) the absorbent sheet exhibits an elevated bulk as compared with a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber. In some embodiments, the pulp is pre-treated with debonder to enhance the wet/dry CD tensile ratio of the sheet.
Description

BRIEF DESCRIPTION OF DRAWINGS

The invention is described in detail below with reference to the Figures wherein:



FIG. 1 is a photomicrograph showing creped tissue with 20% regenerated cellulose microfiber;



FIG. 2 is a photomicrograph of 1.5 denier unrefined regenerated cellulose fiber having a coarseness of 16.7 mg/100 m;



FIG. 3 is a photomicrograph of 14 mesh refined regenerated cellulose fiber;



FIG. 4 is a photomicrograph of 200 mesh refined regenerated cellulose fiber;



FIGS. 5-9 are photomicrographs at increasing magnification of fibrillated regenerated cellulose microfiber which passed through a 200 mesh screen of a Bauer-McNett classifier;



FIGS. 10-15 are graphical representations of physical properties of hand sheets incorporating regenerated cellulose microfiber, wherein FIG. 10 is a graph of hand sheet bulk versus tensile (breaking length), FIG. 11 is a plot of roughness versus tensile, FIG. 12 is a plot of opacity versus tensile, FIG. 13 is a plot of modulus versus tensile, FIG. 14 is a plot of hand sheet tear versus tensile and FIG. 15 is a plot of hand sheet bulk versus ZDT bonding;



FIG. 16 is a photomicrograph at 250 magnification of a softwood hand sheet without fibrillated regenerated cellulose fiber;



FIG. 17 is a photomicrograph at 250 magnification of a softwood hand sheet incorporating 20% fibrillated regenerated cellulose microfiber;



FIG. 18 is a schematic diagram of a wet press paper machine which may be used in the practice of the present invention;



FIG. 19 is a plot of softness (panel) versus two-ply GM tensile for 12 lb/ream tissue base sheet with southern furnish and regenerated cellulose microfiber prepared by a CWP process;



FIG. 20 is a plot of panel softness versus tensile-for various tissue. sheets;



FIG. 21 is a plot of bulk versus tensile for creped CWP base sheet.



FIG. 22 is a plot of MD stretch versus CD stretch for CWP tissue base sheet;



FIG. 23 is a plot of GM Break Modulus versus GM tensile for tissue base sheet;



FIG. 24 is a plot of tensile change versus percent microfiber for tissue and towel base sheet;



FIG. 25 is a plot of basis weight versus tensile for tissue base sheet;



FIG. 26 is a plot of basis weight versus tensile for CWP base sheet;



FIG. 27 is a plot of two-ply SAT versus CD wet tensile;



FIG. 28 is a plot of CD wet tensile versus CD dry tensile for CWP base sheet;



FIG. 29 is a scanning electron micrograph (SEM) of creped tissue without microfiber;



FIG. 30 is a photomicrograph of creped tissue with 20 percent microfiber;



FIG. 31 is a plot of Wet Breaking Length versus Dry Breaking Length for various products, showing the effects of regenerated cellulose microfiber and debonder on product tensiles;



FIG. 32 is a plot of GM Break Modulus versus Breaking Length, showing the effect of regenerated cellulose microfiber and debonder on product stiffness;



FIG. 33 is a plot of Bulk versus Breaking Length showing the effect of regenerated cellulose microfiber and debonder or product bulk;



FIG. 34 is a flow diagram illustrating fiber pre-treatment prior to feeding the furnish to a papermachine; and



FIG. 35 is a plot of TAPPI opacity vs. basis weight showing that regenerated cellulose microfiber greatly increases the opacity of tissue base sheet prepared with recycle furnish.


Claims
  • 1. An absorbent paper sheet for tissue or towel comprising from about 99 percent to about 70 percent by weight of cellulosic, pulp-derived papermaking fiber and from about 1 percent to about 30 percent by weight fibrillated regenerated cellulose microfiber having a CSF value of less than 175 ml, and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides, the pulp-derived papermaking fiber being arranged in a fibrous matrix and the regenerated cellulose microfiber being sized and distributed in the fiber matrix to form a microfiber network therein, and wherein fibrillation of the microfiber is controlled such that it has a reduced coarseness and a reduced freeness as compared with unfibrillated microfiber from which it is made, such that the microfiber network provides at least one of the following attributes to the absorbent sheet: (a) the absorbent sheet exhibits an elevated SAT value and an elevated wet tensile value as compared with a like sheet prepared without fibrillated regenerated cellulose microfiber;(b) the absorbent sheet exhibits an elevated wet/dry CD tensile ratio as compared with a like sheet prepared without fibrillated regenerated cellulose microfiber;(c) the absorbent sheet exhibits a lower GM Break Modulus than a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber; or(d) the absorbent sheet exhibits an elevated bulk as compared with a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber.
  • 2. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits an elevated SAT value and an elevated wet tensile value as compared with a like sheet prepared without fibrillated regenerated cellulose microfiber.
  • 3. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits an elevated wet/dry CD tensile ratio as compared with a like sheet prepared without fibrillated regenerated cellulose microfiber.
  • 4. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits a wet/dry CD tensile ratio at least 25 percent higher than that of a like sheet prepared without fibrillated regenerated cellulose microfiber.
  • 5. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits a wet/dry CD tensile ratio at least 50 percent higher than that of a like sheet prepared without fibrillated regenerated cellulose microfiber.
  • 6. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits a wet/dry CD tensile ratio at least 100 percent higher than that of a like sheet prepared without fibrillated regenerated cellulose microfiber.
  • 7. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits an elevated opacity value as compared with a like sheet prepared without fibrillated regenerated cellulose microfiber.
  • 8. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits a lower GM Break Modulus than a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber.
  • 9. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits a GM Break Modulus at least 20 percent lower than a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber.
  • 10. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits an elevated bulk as compared with a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber.
  • 11. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits a specific bulk at least 5% higher than a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber.
  • 12. The absorbent sheet according to claim 1, wherein the absorbent sheet exhibits a specific bulk at least 10% higher than a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber.
  • 13. The absorbent sheet according to claim 1, comprising from about 5 percent by weight to about 15 percent by weight fibrillated regenerated cellulose microfiber.
  • 14. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber has a CSF value of less than 150 ml.
  • 15. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber has a CSF value of less than 100 ml.
  • 16. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber has a CSF value of less than 50 ml.
  • 17. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber has a CSF value of less than 25 ml.
  • 18. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber has a CSF value of 0 ml.
  • 19. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber has a number average diameter of less than about 2.0 microns.
  • 20. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber has a number average diameter of from about 0.1 to about 2 microns.
  • 21. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber has a coarseness value of less than about 0.5 mg/100 m.
  • 22. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber has a coarseness value of from about 0.001 mg/100 m to about 0.2 mg/100 m.
  • 23. The absorbent sheet according to claim 1, having a basis weight of from about 5 lbs per 3,000 square foot ream to about 40 lbs per 3,000 square foot ream.
  • 24. The absorbent sheet according to claim 1, having a basis weight of from about 15 lbs per 3,000 square foot ream to about 35 lbs per 3,000 square foot ream.
  • 25. The absorbent sheet according to claim 1, wherein the pulp-derived papermaking fiber comprises predominantly softwood fiber.
  • 26. The absorbent sheet according to claim 1, wherein the pulp-derived papermaking fiber comprises predominantly southern softwood Kraft fiber and at least 20 percent by weight hardwood fiber.
  • 27. An absorbent paper sheet for tissue or towel comprising from about 99 percent to about 70 percent by weight of a pulp-derived papermaking fiber and from about 1 percent to about 30 percent by weight fibrillated regenerated cellulose microfiber having a CSF value of less than 100 ml, wherein the absorbent sheet has an absorbency of at least about 4 g/g.
  • 28. The absorbent sheet according to claim 27, wherein the absorbent sheet has an absorbency of at least about 4.5 g/g.
  • 29. The absorbent sheet according to claim 27, wherein the absorbent sheet has an absorbency of at least about 5 g/g.
  • 30. The absorbent sheet according to claim 27, wherein the absorbent sheet has an absorbency of at least about 7.5 g/g.
  • 31. The absorbent sheet according to claim 27, wherein the absorbent sheet has an absorbency of from about 6 g/g to about 9.5 g/g.
  • 32. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber is prepared from a cellulosic dope comprising cellulose dissolved in a tertiary amine N-oxide.
  • 33. The absorbent sheet according to claim 1, wherein the fibrillated regenerated cellulose microfiber is prepared from a cellulosic dope comprising cellulose dissolved in an ionic liquid.
  • 34. An absorbent paper sheet for tissue or towel comprising from about 99 percent to about 70 percent by weight of pulp-derived papermaking fiber and from about 1 to about 30 percent by weight of fibrillated regenerated cellulose microfiber having a CSF value of less than 100 ml, wherein the fibrillated regenerated cellulose microfiber has a fiber count greater than 50 million fibers/gram and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides.
  • 35. The absorbent paper sheet for tissue or towel according to claim 34, wherein the fibrillated regenerated cellulose microfiber has a weight average diameter of less than 2 microns, a weight average length of less than 500 microns and a fiber count of greater than 400 million fibers/gram.
  • 36. The absorbent paper sheet for tissue or towel according to claim 34, wherein the fibrillated regenerated cellulose microfiber has a weight average diameter of less than 1 micron, a weight average length of less than 400 microns and a fiber count of greater than 2 billion fibers/gram.
  • 37. The absorbent paper sheet for tissue or towel according to claim 34, wherein the fibrillated regenerated cellulose microfiber has a weight average diameter of less than 0.5 microns, a weight average length of less than 300 microns and a fiber count of greater than 10 billion fibers/gram.
  • 38. The absorbent paper sheet for tissue or towel according to claim 34, wherein the fibrillated regenerated cellulose microfiber has a weight average diameter of less than 0.25 microns, a weight average length of less than 200 microns and a fiber count of greater than 50 billion fibers/gram.
  • 39. The absorbent paper sheet for tissue or towel according to claim 34, wherein the fibrillated regenerated cellulose microfiber has a fiber count greater than 200 billion fibers/gram.
  • 40. An absorbent sheet for tissue comprising at least about 75 percent by weight pulp-derived papermaking fiber wherein hardwood fiber is the predominant pulp-derived papermaking fiber (exclusive of regenerated cellulose content) and from about 1 percent to about 25 percent by weight fibrillated regenerated cellulose microfiber having a CSF value of less than 100 ml and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides.
  • 41. The absorbent sheet for tissue according to claim 40, having a basis weight of less than about 15 lbs per 3,000 square foot ream.
  • 42. The absorbent sheet for tissue according to claim 40, having a basis weight of from about 7 lbs per 3000 square foot ream to about 13 lbs per 3000 square foot ream.
  • 43. The absorbent sheet for tissue according to claim 40, comprising at least about 75 percent by weight of a mixture of hardwood and softwood pulp-derived papermaking fiber.
  • 44. The absorbent sheet for tissue according to claim 40, wherein the hardwood fiber is southern hardwood Kraft fiber.
  • 45. The absorbent sheet for tissue according to claim 40, wherein the pulp-derived papermaking fiber comprises at least about 20 percent by weight pulp-derived fiber of softwood fiber.
  • 46. The absorbent sheet for tissue according to claim 40, wherein the tissue sheet exhibits elevated GM tensile strength as compared with a like sheet made without fibrillated regenerated cellulose microfiber.
  • 47. The absorbent sheet for tissue according to claim 40, wherein the tissue sheet exhibits a GM tensile strength at least about 20 percent higher than a like sheet of like basis weight made without fibrillated regenerated cellulose microfiber.
  • 48. The absorbent sheet for tissue according to claim 40, wherein the tissue sheet exhibits a GM tensile strength at least about 30 percent higher than a like sheet of like basis weight made without fibrillated regenerated cellulose microfiber.
  • 49. The absorbent sheet for tissue according to claim 40, wherein the tissue sheet exhibits a GM tensile strength at least about 40 percent higher than a like sheet of like basis weight made without fibrillated regenerated cellulose microfiber.
  • 50. The absorbent sheet for tissue according to claim 40, wherein the tissue sheet exhibits increased MD and CD stretch as compared with a like sheet made without fibrillated regenerated cellulose microfiber.
  • 51. The absorbent sheet for tissue according to claim 40, wherein the tissue sheet exhibits a CD stretch of at least 5 percent.
  • 52. A base sheet for tissue comprising pulp-derived papermaking fiber which is predominantly hardwood fiber and from about 5 to about 30 percent by weight fibrillated regenerated cellulose microfiber, wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides and wherein further the base sheet exhibits at least about 20% more GM tensile than a like sheet of like basis weight and like softness prepared without fibrillated regenerated cellulose fiber.
  • 53. The base sheet for tissue according to claim 52, wherein the sheet has a basis weight of from about 4 to about 12 lbs per 3000 square foot ream.
  • 54. The base sheet for tissue according to claim 52, wherein the sheet has a basis weight of from about 5 to about 8 lbs per 3000 square foot ream.
  • 55. The base sheet for tissue according to claim 52, wherein the sheet has a basis weight of from about 5 to about 7 lbs per 3000 square foot ream.
  • 56. A base sheet for tissue comprising pulp-derived papermaking fiber which is predominantly hardwood fiber, the base sheet exhibiting a GM tensile of greater than 300 g/3″ and a basis weight of from about 4 lbs per 3000 square foot ream to about 10 lbs per 3000 square foot ream, said base sheet including from about 1 to about 30 percent by weight fibrillated fibrillated regenerated cellulose microfiber having more than 400 million fibrils per gram wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides.
  • 57. An absorbent cellulosic sheet, comprising: (a) cellulosic pulp-derived papermaking fibers in an amount of from about 70% up to about 98% by weight; and(b) fibrillated regenerated cellulose fibers in an amount of from about 30% to about 2% by weight, wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,
  • 58. The absorbent cellulosic sheet of claim 57, wherein the number average fibril width is less than about 2 μm.
  • 59. The absorbent cellulosic sheet of claim 57, wherein the number average fibril width is less than about 1 μm.
  • 60. The absorbent cellulosic sheet of claim 57, wherein the number average fibril width is less than about 0.5 μm.
  • 61. The absorbent cellulosic sheet of claim 57, wherein the number average fiber length of the fibrillated regenerated cellulose fibers is less than about 500 micrometers.
  • 62. The absorbent cellulosic sheet of claim 57, wherein the number average fiber length of the fibrillated regenerated cellulose fibers is less than about 250 micrometers.
  • 63. The absorbent cellulosic sheet of claim 57, wherein the number average fiber length of the fibrillated regenerated cellulose fibers is less than about 150 micrometers.
  • 64. The absorbent cellulosic sheet of claim 57, wherein the number average fiber length of the fibrillated regenerated cellulose fibers is less than about 100 micrometers.
  • 65. The absorbent cellulosic sheet of claim 57, wherein the number average fiber length of the fibrillated regenerated cellulose fibers is less than about 75 micrometers.
  • 66. An absorbent cellulosic sheet, comprising: (a) cellulosic pulp-derived papermaking fibers in an amount of from about 70% up to about 98% by weight; and(b) fibrillated regenerated cellulose fibers in an amount of from about 30% to about 2% by weight, and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,
  • 67. The absorbent cellulosic sheet of claim 66, wherein the number average fiber length of the fibrillated regenerated cellulose fibers is less than about 250 micrometers.
  • 68. The absorbent cellulosic sheet of claim 66, wherein the number average fiber length of the fibrillated regenerated cellulose fibers is less than about 150 micrometers.
  • 69. The absorbent cellulosic sheet of claim 66, wherein the number average fiber length of the fibrillated regenerated cellulose fibers is less than about 100 micrometers.
  • 70. The absorbent cellulosic sheet of claim 66, wherein the number average fiber length of the fibrillated regenerated cellulose fibers is less than about 75 micrometers.
  • 71. An absorbent cellulosic sheet, comprising: (a) cellulosic pulp-derived papermaking fibers in an amount of from about 70% up to about 99% by weight, the southern softwood content of the cellulosic pulp-derived papermaking fibers in the absorbent cellulosic sheet being at least about 60% by weight of the pulp-derived papermaking fiber; and(b) fibrillated regenerated cellulose fibers in an amount of from about 30% to about 1% by weight, and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,
  • 72. The absorbent cellulosic sheet of claim 71, exhibiting a TAPPI opacity of more than 55 opacity units.
  • 73. The absorbent cellulosic sheet of claim 71, exhibiting a TAPPI opacity of more than 60 opacity units.
  • 74. The absorbent cellulosic sheet of claim 71, exhibiting a TAPPI opacity of more than 63 opacity units.
  • 75. The absorbent cellulosic sheet of claim 71, wherein the sheet has a basis weight of less than 8 lbs/3000 square feet ream and exhibits a normalized TAPPI opacity of greater than 6 TAPPI opacity units/lb/3000 square foot ream.
  • 76. The absorbent cellulosic sheet of claim 75, wherein the sheet has a basis weight of less than 8 lbs/3000 square feet ream and exhibits a normalized TAPPI opacity of greater than 6.5 TAPPI opacity units/lb/3000 square foot ream.
  • 77. The absorbent cellulosic sheet of claim 75, wherein the fiber in the sheet consists predominantly of secondary fiber and fibrillated regenerated cellulose fiber.
  • 78. The absorbent cellulosic sheet of claim 71, wherein the sheet has a basis weight of from about 9 lbs/3000 square feet ream to about 11 lbs/3000 square feet ream and exhibits a normalized TAPPI opacity of greater than 5 TAPPI opacity units/lb/3000 square feet ream.
  • 79. The absorbent cellulosic sheet of claim 78, wherein the fiber in the sheet consists predominantly of secondary fiber and fibrillated regenerated cellulose fiber.
  • 80. An absorbent cellulosic sheet, comprising: (a) cellulosic pulp-derived papermaking fibers in an amount of from about 70% up to about 99% by weight, the southern softwood content of the cellulosic pulp-derived papermaking fibers in the absorbent cellulosic sheet being at least about 60% by weight of the pulp-derived papermaking fiber; and(b) fibrillated regenerated cellulose fibers in an amount of from about 30% to about 1% by weight, and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,
  • 81. An absorbent cellulosic sheet, comprising: (a) cellulosic pulp-derived papermaking fibers in an amount of from about 70% up to about 99% by weight, the southern softwood content of the cellulosic pulp-derived papermaking fibers in the absorbent cellulosic sheet being at least about 60% by weight of the pulp-derived papermaking fiber; and(b) fibrillated lyocell fibers in an amount of from about 30% to about 1% by weight, and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,
  • 82. The absorbent cellulosic sheet of claim 81, exhibiting a fiber population of greater than 50 million fibers/g.
  • 83. The absorbent cellulosic sheet of claim 81, exhibiting a fiber population of greater than 100 million fibers/g.
  • 84. The absorbent cellulosic sheet of claim 81, exhibiting a fiber population of greater than 500 million fibers/g.
  • 85. The absorbent cellulosic sheet of claim 81, exhibiting a fiber population of greater than 10 billion fibers/g.
  • 86. An absorbent cellulosic sheet, comprising: (a) cellulosic pulp-derived papermaking fibers in an amount of from about 70% up to about 99% by weight, the southern softwood content of the cellulosic pulp-derived papermaking fibers in the absorbent cellulosic sheet being at least about 60% by weight of the pulp-derived papermaking fiber; and(b) fibrillated regenerated cellulose fibers in an amount of from about 30% to about 1% by weight, and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,
  • 87. The absorbent cellulosic sheet of claim 86, exhibiting a fiber population of greater than 50 million fibers/g.
  • 88. The absorbent cellulosic sheet of claim 87, exhibiting a fiber population of greater than 100 million fibers/g.
  • 89. The absorbent cellulosic sheet of claim 88, exhibiting a fiber population of greater than 500 million fibers/g.
  • 90. The absorbent cellulosic sheet of claim 89, exhibiting a fiber population of greater than 10 billion fibers/g.
  • 91. The absorbent sheet according to claim 86, having a breaking length of at least 0.92 km.
  • 92. The absorbent sheet according to claim 86, having a breaking length of at least 0.95 km.
  • 93. The absorbent sheet according to claim 86, having a breaking length of at least 0.97 km.
  • 94. An absorbent cellulosic sheet, comprising: (a) cellulosic pulp-derived papermaking fibers in an amount of from about 70% up to about 99% by weight, the southern softwood content of the cellulosic pulp-derived papermaking fibers in the absorbent cellulosic sheet being at least about 60% by weight of the pulp-derived papermaking fiber; and(b) fibrillated regenerated cellulose fibers in an amount of from about 30% to about 1% by weight, and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,
  • 95. The absorbent cellulosic sheet of claim 94, exhibiting a breaking length of at least 0.92 km.
  • 96. The absorbent cellulosic sheet of claim 94, exhibiting a breaking length of at least 0.95 km.
  • 97. The absorbent cellulosic sheet of claim 94, exhibiting a breaking length of at least 0.97 km.
  • 98. An absorbent cellulosic sheet, comprising: (a) cellulosic pulp-derived papermaking fibers in an amount of from about 70% up to about 99% by weight, the southern softwood content of the cellulosic pulp-derived papermaking fibers in the absorbent cellulosic sheet being at least about 60% by weight of the pulp-derived papermaking fiber; and(b) fibrillated regenerated cellulose fibers in an amount of from about 30% to about 1% by weight, and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,
  • 99. The absorbent cellulosic sheet of claim 98, exhibiting a breaking length of at least 0.92 km.
  • 100. The absorbent cellulosic sheet of claim 98, exhibiting a breaking length of at least 0.95 km.
  • 101. The absorbent cellulosic sheet of claim 98, exhibiting a breaking length of at least 0.97 km.
  • 102. An absorbent cellulosic sheet, comprising: (a) cellulosic pulp-derived papermaking fiber in an amount of from about 70% up to about 99% by weight, at least a portion of the pulp-derived papermaking fiber being pretreated with a debonder composition prior to being formed into the sheet; and(b) fibrillated regenerated cellulose fibers in an amount of from about 30% to about 1% by weight, and wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,
  • 103. The absorbent cellulosic sheet according to claim 102, wherein the sheet has a wet/dry CD tensile ratio of between about 35% and about 60%.
  • 104. The absorbent cellulosic sheet according to claim 102, wherein the sheet has a wet/dry CD tensile ratio of at least about 40%.
  • 105. The absorbent cellulosic sheet according to claim 102, wherein the sheet has a wet/dry CD tensile ratio of at least about 45%.
  • 106. The absorbent cellulosic sheet according to claim 102, wherein the absorbent sheet further comprises a dry strength resin.
  • 107. The absorbent cellulosic sheet according to claim 102, wherein the dry strength resin is carboxymethyl cellulose.
  • 108. The absorbent cellulosic sheet according to claim 102, wherein the absorbent sheet further comprises a wet strength resin.
  • 109. The absorbent cellulosic sheet according to claim 102, wherein the wet strength resin is a polyamidamine-epihalohydrin resin.
  • 110. The absorbent cellullosic sheet according to claim 102, wherein the debonder composition comprises a nonionic amphiphilic compound and a quaternary ammonium surfactant.
  • 111. The absorbent cellulosic sheet according to claim 102, wherein the debonder composition comprises a quaternary ammonium surfactant selected from the group consisting of: (a) a dialkyldimethyl-ammonium salt of the formula:
  • 112. The absorbent cellulosic sheet according to claim 102, wherein the debonder comprises a nonionic surfactant selected from PEG diols and PEG mono or diesters of fatty acids, and PEG mono or diethers of fatty alcohols.
  • 113. The absorbent cellulosic sheet according to claim 102, wherein the debonder composition comprises a quaternary ammonium surfactant and a nonionic surfactant.
  • 114. The absorbent cellulosic sheet according to claim 102, wherein the debonder comprises an ion-paired mixture of an anionic surfactant and a cationic amphiphilic compound.
  • 115. The absorbent cellulosic sheet according to claim 102, wherein at least 50% by weight of the pulp-derived papermaking fiber is pretreated with the debonder composition.
  • 116. The absorbent cellulosic sheet according to claim 102, wherein at least 75% by weight of the pulp-derived papermaking fiber is pretreated with the debonder composition.
  • 117. The absorbent cellulosic sheet according to claim 102, wherein 100% by weight of the pulp-derived papermaking fiber is pretreated with the debonder composition.
  • 118. A method of making absorbent cellulosic sheet comprising: (a) preparing an aqueous furnish with a fiber mixture including from about 99 percent to about 70 percent of a pulp-derived papermaking fiber, the fiber mixture also including from about 1 to 30 percent by weight of fibrillated regenerated cellulose microfibers having a CSF value of less than 175 ml wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,(b) depositing the aqueous furnish on a foraminous support to form a nascent web and at least partially dewatering the nascent web; and(c) drying the web to provide absorbent sheet.
  • 119. The method of making absorbent sheet according to claim 118, wherein the aqueous furnish has a consistency of 2 percent or less.
  • 120. The method of making absorbent sheet according to claim 118, wherein the aqueous furnish has a consistency of 1 percent or less.
  • 121. The method of making absorbent sheet according to claim 118, wherein the nascent web is compactively dewatered with a papermaking felt.
  • 122. The method of making absorbent sheet according to claim 118, wherein the compactively dewatered web is applied to a Yankee dryer and creped therefrom.
  • 123. The method of making absorbent sheet according to claim 118, wherein the compactively dewatered web is applied to a rotating cylinder and fabric-creped therefrom.
  • 124. The method of making absorbent sheet according to claim 118, wherein the nascent web is at least partially dewatered by through drying.
  • 125. The method of making absorbent sheet according to claim 118, wherein the nascent web is at least partially dewatered by impingement air drying.
  • 126. The method of making absorbent sheet according to claim 118, wherein said fiber mixture includes southern softwood Kraft and southern hardwood Kraft.
  • 127. A method of making base sheet for tissue comprising: (a) preparing an aqueous furnish comprising southern hardwood fiber and fibrillated regenerated cellulose microfiber having a CSF value of less than 100 ml and a fibril count of more than 400 million fibrils per gram wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,(b) depositing the aqueous furnish on a foraminous support to form a nascent web and at least partially dewatering the nascent web; and(c) drying the web to provide absorbent sheet.
  • 128. The method of making base sheet for tissue according to claim 127, wherein the fibrillated regenerated cellulose fiber has a fibril count of more than 1 billion fibrils per gram.
  • 129. The method of making base sheet for tissue according to claim 127, wherein the fibrillated regenerated cellulose fiber has a fibril count of more than 100 billion fibrils per gram.
  • 130. A method of making absorbent cellulosic sheet comprising: (a) preparing an aqueous furnish with a fiber mixture including from about 99 percent to about 70 percent of a pulp-derived papermaking fiber, the fiber mixture also including from about 1 to 30 percent by weight of fibrillated regenerated cellulose microfibers having a CSF value of less than 175 ml wherein the regenerated cellulose is prepared from a cellulosic dope of dissolved cellulose comprising a solvent selected from ionic liquids and tertiary amine N-oxides,(b) pretreating at least a portion of the fiber mixture with a debonder composition;(c) depositing the debonder-treated aqueous furnish on a foraminous support to form a nascent web and at least partially dewatering the nascent web; and(d) drying the web to provide absorbent sheet;
  • 131. The method according to claim 130, wherein the pulp-derived papermaking fiber is treated with debonder concurrently with pulping of the fiber.
  • 132. The method according to claim 130, further comprising refining the pulp-derived papermaking fiber.
  • 133. The method according to claim 132, wherein the pulp-derived papermaking fiber is treated with the debonder composition prior to refining the pulp-derived papermaking fiber.
  • 134. The method according to claim 130, further comprising adding a dry strength resin to the finish.
  • 135. The method according to claim 130, further comprising adding a wet strength resin to the furnish.
  • 136. The method according to claim 130, wherein the pulp-derived fiber is pretreated with the debonder composition in an amount from about 1 pound of debonder composition per ton of pulp-derived fiber to about 50 lbs of debonder composition per ton of pulp-derived fiber.
  • 137. The method according to claim 130, wherein the pulp-derived fiber is pretreated with the debonder composition in an amount from about 5 pounds of debonder composition per ton of pulp-derived fiber to about 30 lbs of debonder composition per ton of pulp-derived fiber.
  • 138. The method according to claim 130, wherein the pulp-derived fiber is pretreated with the debonder composition in an amount from about 10 pounds of debonder composition per ton of pulp-derived fiber to about 20 lbs of debonder composition per ton of pulp-derived fiber.
  • 139. The method according to claim 130, wherein the pulp-derived papermaking fiber is pretreated with debonder prior to mixing it with the fibrillated regenerated cellulose microfiber.
  • 140. The method according to claim 130, wherein the pulp-derived papermaking fiber is pretreated with debonder composition for at least 20 minutes prior to depositing the furnish on the foraminous support to form the nascent web.
  • 141. The method according to claim 130, wherein the pulp-derived papermaking fiber is pretreated with debonder composition upstream of a machine chest and prior to depositing the furnish on the foraminous support to form the nascent web.
  • 142. The method according to claim 130, wherein the pulp-derived papermaking fiber is pretreated with debonder composition in a pulper and diluted prior to depositing the furnish on the foraminous support to form the nascent web.
  • 143. The method according to claim 130, wherein the pulp-derived papermaking fiber is pretreated with debonder at a consistency of at greater than 2 percent.
  • 144. The method according to claim 130, wherein the aqueous furnish is treated with debonder at a consistency of greater than 3 percent.
  • 145. The method according to claim 130, wherein the pulp-derived papermaking fiber is treated with debonder at a consistency of greater than 4 percent.
  • 146. The method according to claim 130, wherein the pulp-derived papermaking fiber is treated with debonder at a consistency between about 3 and about 8 percent.
Provisional Applications (4)
Number Date Country
60784228 Mar 2006 US
60850467 Oct 2006 US
60850681 Oct 2006 US
60881310 Jan 2007 US