Claims
- 1. In a vapor phase process for the preparation of unsaturated hydrocarbon monoolefins and diolefins comprising oxidative dehydrogenation of stream of C.sub.3 to C.sub.9 hydrocarbon compounds to produce a product stream comprising 3.5 to 80 mol percent of unsaturated hydrocarbon product and of about or from 0.0001 to 2.5 mol percent acetylenic compound impurity, about or from 0.0005 to 2.5 mol percent carbonyl compounds and 5 to 93 mol percent non-condensable gases, wherein the improvement comprises contacting said product stream in vapor phase at a temperature in the range of 250.degree. to 900.degree. C. and containing less than 5 mol percent free oxygen with a solid catalyst for reducing said acetylenic compounds in said product stream, said catalyst consisting essentially of a mixture of oxides, carbonates or hydroxides of Fe and Ni, Fe being present as the major metal component and Ni being present in the range of about 0.25 to 20 weight percent based on total catalyst, an alkaline earth metal oxide, carbonate or hydroxide of Mg, Ca, Sr or Ba, and about 0.5 to 30 weight percent of an alkali metal oxide, carbonate or hydroxide of Li, Na, K or Rb determined as metal and based on the other metallic elements, and recovering said stream having the amount of acetylenic compounds therein reduced.
- 2. The process according to claim 1 wherein said hydrocarbons have 4 to 6 carbon atoms.
- 3. The process according to claim 1 wherein the major amount of hydrocarbons in said product stream comprises n-butene and butadiene.
Parent Case Info
This is a division of application Ser. No. 84,295 filed Oct. 12, 1979, now U.S. Pat. No. 4,513,159, which is a continuation of Ser. No. 540,336, filed Jan. 13, 1975 and now abandoned, which was a division of Ser. No. 443,752, filed Feb. 19, 1974 and now abandoned.
US Referenced Citations (11)
Divisions (2)
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Number |
Date |
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84295 |
Oct 1979 |
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Parent |
443752 |
Feb 1974 |
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Continuations (1)
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540336 |
Jan 1975 |
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