Patent Grant
9095168
The present application is a National Stage of International Application No. PCT/EP2010/063940, filed on Sep. 22, 2010, which claims priority to Chinese Patent Application No. 200910177791.4, filed on Sep. 22, 2009, the entire contents of which are being incorporated herein by reference.
The present invention relates to an acidified milk beverage powder and method for producing such an acidified milk beverage powder. More specifically, the present invention provides a powdered composition which can be added to water with minimal mixing to produce an acidified fruit beverage containing milk and having a smooth texture.
Attempts have been made to provide powdered compositions suitable for mixing with water, water+milk powder or milk for the manufacture of non-gelled acidified, milk containing product drinks. For example, US2008/0152777A1 provided a powdered composition that, upon mixing with water or milk, formed a non-gelled, acidified, milk-product drink without curdling of the milk protein. The composition contained 70-85% sugar, 0.15-0.4% artificial sweeteners, 7.15% citric acid, 0.6-1.6% buffering or acid bite reducing agent, 3.5-8% guar gum, 2-15% calcium fortification agent, and optional milk powder, emulsifiers, flavorants, colorants, vitamins, minerals, prebiotics, probiotic or fiber. The powdered composition was prepared by dry-blending sugars, citric acid, acid bit reducing agent, guar gum in a first step to homogeneously distribute guar gum. The remaining ingredients were added for dry-blending in a second stage. The beverage mix was prepared by mixing powder into water or milk and gentle stirring for 45 seconds to form a beverage with a pH less than 4.6. It was reported that guar gum was effective to prevent protein curdling, although it was not reported why this effect was present. Addition of fruit juice solids was reported in examples but not part of the claims.
Another patent, U.S. Pat. No. 4,530,850 provided a powdered composition that, upon mixing with milk, formed a non-gelled, acidified, milk-product drink without curdling of the milk proteins. The powdered composition contained about 1 to about 9 percent of an edible acid, about 0.5 to about 1.9 percent of an instant cold-water soluble gelatin, about 1 to about 10 percent of an edible natural or modified polysaccharide gum, about 20 to about 90 percent sweetening agents, and an effective amount of flavoring and coloring agents. The beverage was prepared by vigorously mixing (e.g. in a blender at high speed for 10 seconds or in a shaker for an unlisted time) the powdered composition into milk. It was reported that the gelatin included in the powder became attached to the casein in the milk, thereby stabilized the milk protein at lower pH; the gum was reportedly used to improve the viscosity and texture of the final beverage product. Attempts to reproduce the work reported in US2008/0152777A1 and U.S. Pat. No. 4,530,850 by the present inventors were generally unsuccessful. It is well known and has been reported by various patents, for example U.S. Pat. No. 6,652,896, that Na-CMC is effective to prevent milk protein curdling in liquid ready-to-drink beverages, when having a certain processing sequence and allowing Na-CMC and milk protein to establish in liquid conditions. No reports or positive results have been reported up to now, using Na-CMC in powdered beverages. Accordingly, there remains a need to find a suitable gum system for powdered beverage mixes containing milk, to provide a milk-containing beverage drink without protein curdling, having a smooth texture upon reconstitution with simple devices, e.g. a spoon.
At the time the consumer adds water to an acid milk powder to form a drinkable product, milk proteins coagulate by the acid compound present in the powder very rapidly. This is the technical problem to be solved (and which does not exist in currently known products on the market which are all in liquid and not powder form). Hence, the aim of the current invention is to provide an acidified milk beverage powder where upon reconstitution with a liquid, the milk proteins are not coagulated by the acid which is present in the powder mix as well.
The invention related to an acidified milk beverage powder and method for producing such acidified milk beverage powder. The present invention provides a powdered composition which can be added to water or a milk product with minimal mixing (e.g. gentle hand stirring by spoon) to produce an instant acidified milk beverage having a smooth texture.
The powdered compositions of the present invention contains sugar, concentrated fruit juices, skimmed or non-skimmed milk powder, maltodextrin, Na-Carboxymethylcellulose, and optional: acid bite reducing agents or buffering agents, flavorants, colorants, calcium fortification agent, vitamins, minerals, emulsifiers, prebiotics, probiotics, and fibers; the powdered composition of the present invention do not require and preferably do not contain any further hydrocolloids like gelatin, guar gum or thereof. The powdered composition, when added to a liquid (e.g. water, whole milk, skim milk, reconstituted skim milk powders and the like), only requires minimal mixing to obtain the desired acidified milk beverage. Preferably the milk and milk powders are pasteurized and even more preferably pasteurized using an ultra high temperature process. Specifically, the powder composition of the present invention comprises: i) 20-40 wt % fruit juice powder; ii) 50-70 wt % granular sugar; iii) 1-2 wt % organic acid granules; iv) 4-10 wt % milk powder; and v) 3-4 wt % carboxymethylcellulose powder composed of particles, wherein said particles have a diameter of 0.5 mm or less, preferably of 0.1 mm or less.
In order to solve the technical problem, we developed a powder mix wherein the CMC particles have a very fine diameter, so that the time for the CMC particles to swell when water is added to the powder mix, is considerably reduced, and it is very rapidly active to prevent flocculation. This is the first effect. The second effect, the acid particles have a big diameter, so that the swelling/dissolution of the acid when water is added to the mix, is prolonged, which therefore reduces the immediate effect of acid onto the proteins.
The two effects above are synergetic to prevent flocculation. But on top of this, the concentrations of each key ingredient is managed such that the flocculation effect is even reduced, while guaranteeing a proper texture and taste of the final product, close to what is achieved with a liquid product.
The powdered composition of the present invention can be reconstituted with a liquid (water, milk powder+water, ready-to-drink milk) and stirred with a spoon with minimal mixture to provide an acidified milk beverage in which the precipitation of casein proteins is minimized. The powdered composition is admixed dry by managing the order of addition of ingredients and following a two step mixing process: 1) dry blending granular sugar with carboxymethylcellulose powder, and 2) mixing a milk powder, a fruit juice powder and granular organic acid into the blend. No liquids are used in the preparation of the powdered compositions of the present invention. The resulting powdered composition has good dispersibility and hydration when added to the liquid. No agglomeration of the powder or homogenization within reconstitution of the powder in liquid is required. Stabilizers such as carrageenans, pectin, gelatin or other hydrocolloids are not needed and preferably are not used. Equally, acid bite reducing agents or buffering agents are not needed.
The invention relates to instant acidified beverages containing milk and methods for producing such instant acidified milk beverages. The present invention provides a powdered composition which can be added to a milk product with minimal mixing to produce an instant acidified beverage having a smooth texture. The present invention also provides a method for preparing the powdered composition.
The powdered compositions of the present invention contains sugar, concentrated fruit juices, skimmed milk powder, maltodextrin, Na-Carboxymethylcellulose, and optional: acid bite reducing agents or buffering agents, flavorants, colorants, calcium fortification agent, vitamins, minerals, emulsifiers, prebiotics, probiotics, fibers; the powdered composition of the present invention do not require and preferably do not contain any further hydrocolloids like gelatin, guar gum or thereof. The powdered composition, when added to a liquid (e.g. water, whole milk, skim milk, reconstituted skim milk powders and the like), only requires minimal mixing to obtain the desired acidified milk beverage. Preferably the milk and milk powders are pasteurized and even more preferably pasteurized using an ultra high temperature process.
Sucrose particle size is preferably uniform to avoid demixing problems in a dry mix. Particle size is preferably 0.1-1 mm and more preferably 0.3-0.8 mm. Powdered sugar enhances hygroscopicity thus leads to water uptake within shelf-life and is not preferred. Granulated sucrose between 1-2 mm or bigger, needs in cold conditions too much time and reconstitution cannot be guaranteed to be ready within 20-30 seconds. Secondly, too big sugar crystals might also lead to demixing and bad distribution of gum and other ingredients which in case of gum might lead to difficulties in solubilization of dry mix. In cases floating powder pieces of 2-5 mm can be detected which might dissolve within time but show unpleasant look and might be reason for protein flocculation if floating pieces are especially sugar with gum (thus not enough gum in system to protect protein). Result: choosing sucrose of 0.3-0.8 mm avoids difficulties of rehydration time and bad solubility.
The organic acid may be citric acid, lactic acid, malic acid, tartaric acid, and/or any combinations thereof. When citric acid is used, it is preferably a Citric Acid Anhydrous Type E330 (C6H8O7). Crystallized water in citric acid (like citric acid monohydrate (C6H8O7.H2O) might release water within shelf-life and effect the protein when powder mix is stored for several month (Total shelf-life of powder mix is given with 12-15 months). This effect can be seen but does not occur always, thus it is a factor which is preferred to be avoided.
As to the size of the organic acid particle, explanation is made taking citric acid as an example. Big citric acid crystals need stirring for a longer time to fully dissolve. If this time is not kept, the distribution is not fully uniform, leaving “pieces” of citric acid being not fully dissolved which then dissolve slowly without stirring causing in its surrounding a high “acidic” environment and might lead to flocculation of protein as Na-CMC can protect, but only to a certain extend. Secondly, if particle size of citric acid is too small, it dissolved so fast that Na-CMC has no time to coated and protect the present protein in time. Thus, minutes later, clear protein curdling can be detected visually and taste wise (enhanced grainy texture). Best particles size is thus ranging from 0.7-0.2 mm and preferably 0.7-0.4 mm.
For purpose of this invention, “minimal mixing” is intended to mean hand mixing device such as a spoon; blenders, mechanical mixing devices (e.g. rotor mixer operated by hand or electrical powder, shaker devices, and the like) are specifically not required or included in the definition of minimal mixing. Of course, as one skilled in the art will understand, the requirement that only “minimal mixing” is required to obtain the desired acidified milk containing beverage does not mean that the consumer cannot use more vigorous mixing conditions, but only that such more vigorous mixing conditions or equipment are not needed (or desired). Generally, a homogenous liquid beverage is obtained by such minimal mixing (e.g., hand mixing with a spoon) within about 40 seconds or less, and preferably within 30 seconds or less. The solubilization time depends on the temperature of milk or water used, as colder liquid extend the time of sugar solubility.
The powdered composition of the present invention is prepared by the following steps:
In the first step, dry blending granular sugar, having a particle size of 0.1-1 mm and more preferably between 0.3-0.8 mm, and Na-Carboxymethylcellulose, having a particle size of 0.5 mm or less, preferably of 0.1 mm or less and having a high rehydration capacity. Homogeneous distribution of such is highly recommended to avoid lump formation when added to water and to assure good and fast re-hydration of Na-CMC in order to protect the protein. The recommended ration of sugar to Na-CMC is 15:1 or more preferably 20:1. Mixing time should exceed 5 min before adding further ingredients.
In the second step, all ingredients except granular acid can be added mixing for another 5 min. Organic acids, such as malic acid, or more preferably citric acid is added in final mixing stage and mixed until homogeneously distributed which might take up to 2 min mixing time. The particle size of used acid is ranging between 0.2 mm to 0.7 mm, more preferably between 0.4 mm to 0.7 mm. Mixing time is related to used batch size. In present invention a typical batch size is referring to 1 kg complete mix. The composition is made of 50-60 wt % sucrose, 20-40 wt % fruit juice powders, 1-2 wt % citric acid, 0-5 wt % Non-dairy creamer having no protein, 0-1.5 wt % clouding agent, 3-4 wt % Na-CMC and 4-10 wt % milk powder, preferably 4-5 wt %. Colors, flavors, vitamins and minerals as well as buffering or acid bite reducing agents such as K-Citrate can be added upon desired and regulatory level.
Based on the above method, fruit-flavor milk beverage powders as shown in Table 1 to 3 are prepared (Example 1 to 3).
The above obtained powder was mixed with certain amount of water under gentle stirring to provide a reconstituted acidified milk beverage. After 10 minutes or even more, no flocculation was observed. The beverage gave good appearance. In addition, an evaluation of smooth texture can be given by tasting such beverage.
Additionally, comparison tests were made where Na-CMC of Example 1 was replaced with Xanthan gum, Guar gum, and Na-CMC having particle size that is out of the range as claimed by the present invention, respectively. The obtained beverage powder was reconstituted with water to provide beverage solution. Results of the comparison tests are shown in Table 4.
It can be seen from Table 4 that if the particle size of Na-CMC is too big, the flocculation of protein would occur during the reconstitution of the powder. In addition, when Na-CMC is replaced by Xanthan gum or Guar gum, the flocculation would occur after 1 to 2 minutes of stirring, resulting unsatisfied appearance of the reconstituted milk beverage.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2009 1 0177791 | Sep 2009 | CN | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2010/063940 | 9/22/2010 | WO | 00 | 5/30/2012 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2011/036163 | 3/31/2011 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 4078092 | Nishiyama | Mar 1978 | A |
| 4264638 | Sirett et al. | Apr 1981 | A |
| 20050266134 | Nagao et al. | Dec 2005 | A1 |
| 20080152777 | Cobos | Jun 2008 | A1 |
| Number | Date | Country |
|---|---|---|
| 1066121 | Nov 1979 | CA |
| 9629880 | Oct 1996 | WO |
| Entry |
|---|
| Baiqiao et al., “The stabilization mechanism of acidified mild drinks induced by carboxymethylcellulose,” vol. 87, Oct. 26, 2007, pp. 287-300—XP002612034. |
| Lueck H., et al., “Fruit juice-flavoured milk powder,” South-African Journal of Dairy Technology, vol. 6, No. 2, Jan. 1, 1974, pp. 117-121—XP009141697. |
| Number | Date | Country | |
|---|---|---|---|
| 20120321745 A1 | Dec 2012 | US |
