Claims
- 1. A solid cleaning composition comprising:
- i) more than about 30% C.sub.14 or lower acyl esters of isethionic acid salts, the acyl chain length distribution of said esters being at least about 95% C.sub.8 -C.sub.18 ; and
- ii) at least one betaine wherein the weight ratio of said acyl esters to betaine is about 8:1 to about 2:1; and said betaine has the structure ##STR5## wherein, R is a hydrocarbon chain having a distribution of at least about 90% C.sub.5 -C.sub.17 ;
- X is H, or CH.sub.2 OH;
- Y is methyl methylene or CONHCH.sub.2 CH.sub.2 CH.sub.2 ;
- Z is COO.sup.-, or CHOHCH.sub.2 SO.sub.3 --, provided that when X, Y and Z are respectively H, CH.sub.2 and COO.sup.- in combination, R is less than 50% C.sub.15 -C.sub.17 ; and
- iii) 0 to 10% soap.
- 2. A composition according to claim 1, wherein the ratio of isethionate ester to betaine is from 8:1 to 2:1.
- 3. A composition according to claim 1, wherein the length of said acyl chain has the following distribution:
- ______________________________________ Chain Length %______________________________________ C.sub.6-10 20-25 C.sub.12 45-55 C.sub.14-18 20-40 C.sub.18 unsatured 1-15.______________________________________
- 4. A skin cleansing toilet bar composition comprising:
- i) acyl esters of isethionic acid salts as defined in claim 1 in an amount of about 30% to 70%;
- ii) at least one betaine as defined in claim 1, wherein the weight ratio of said acyl esters to betaine is about 8:1 to about 2:1;
- iii) free fatty acid in an amount of 2-40%;
- iv) fatty alcohol in an amount of about 0-10%;
- v) sodium isethionate in an amount of 2-20%;
- vi) soap in an amount of about 0-10%; and
- vii) water in an amount of about 2-20%.
- 5. A composition according to claim 4, wherein the betaine is a carboxybetaine.
- 6. A composition according to claim 4, wherein the betaine is a sulfobetaine or hydroxy sultaine.
- 7. A composition according to claim 4, wherein the betaine is an amido betaine.
- 8. A composition according to claim 7, wherein the betaine is a cocamidopropyl betaine.
- 9. A skin cleansing composition comprising:
- i) more than about 30% C.sub.14 or lower acyl esters of isethionic acid salts, the acyl chain length distribution of said esters being at least about 95% C.sub.8 -C.sub.18 ; and
- ii) at least one amido sulfosuccinate wherein the weight ratio of said acyl esters to sulfosuccinate is about 6:1 to about 2:1.
- 10. A composition according to claim 9, wherein the amido sulfosuccinate is a mono ester.
- 11. A composition according to claim 9, wherein the amido sulfosuccinate is derived from a monoethanolamide.
- 12. A composition according to claim 9, wherein the amido sulfosuccinate is a cocamido sulfosuccinate.
- 13. A composition according to claim 9, wherein the ratio of isethionate ester to amido sulfosuccinate is from 4.5:1 to 3:1.
- 14. A composition according to claim 9, wherein said acyl chain length has the following distribution:
- ______________________________________ Chain Length %______________________________________ C.sub.6-10 10-25 C.sub.12 45-55 C.sub.14-18 20-40 C.sub.18 unsatured 1-15.______________________________________
- 15. A solid skin cleansing composition comprising:
- (i) about 30-70% by wt. acyl esters of isethionic acid salts wherein more than about 30% of said acyl esters are C.sub.14 or lower and wherein the acyl chain length distribution of said acyl esters is at least about 95% C.sub.8 to C.sub.18 ;
- (ii) at least one amido sulfosuccinate wherein the weight ratio of said acyl esters to sulfosuccinate is about 6:1 to 2:1;
- (iii) free fatty acid in an amount of about 2-40%;
- (iv) fatty alcohol in an amount about 0-10%;
- (v) sodium isethionate in an amount of about 2-20%;
- (vi) soap in an amount of about 0-10%; and
- (vii) water in an amount of about 2-20%.
- 16. A skin cleansing composition comprising:
- (i) more than about 30% C.sub.14 or lower acyl esters of isethionic acid salts, the acyl chain length distribution of said esters being at least 95% C.sub.8 -C.sub.18 ;
- (ii) at least one betaine having the structure ##STR6## wherein, R is a hydrocarbon chain having a distribution of at least about 90% C.sub.5 -C.sub.17 ;
- X is H, or CH.sub.2 OH;
- Y is methyl methylene or CONHCH.sub.2 CH.sub.2 CH.sub.2 ;
- Z is COO.sup.-, or CHOHCH.sub.2 SO.sub.3 --, provided that when X, Y and Z are respectively H, CH.sub.2 and COO.sup.- in combination, R is less than 50% C.sub.15 -C.sub.17 ;
- in an amount from about 0.5 to 7.5% by weight of the composition;
- (iii) at least one amido sulfosuccinate in an amount about 1-24% by weight of the composition;
- wherein ratio of isethionate to total coactive is from about 10:1 to 2:1.
- 17. A composition according to claim 16, wherein said acyl chain length has the following distribution:
- ______________________________________ Chain Length %______________________________________ C.sub.6-10 10-25 C.sub.12 45-55 C.sub.14-16 20-40 C.sub.18 unsatured 1-15.______________________________________
- 18. A composition according to claim 16, wherein the betaine is carboxybetaine.
- 19. A composition according to claim 16, wherein the betaine is sulfobetaine or hydroxy sultaine.
- 20. A composition according to claim 16, wherein the betaine is an amido betaine.
- 21. A composition according to claim 16, wherein the betaine is cocamidopropyl betaine.
- 22. A composition according to claim 16, wherein the amido sulfosuccinate is a monoester.
- 23. A composition according to claim 16, wherein the amido sulfosuccinate is derived from monoethanolamide.
- 24. A composition according to claim 16, wherein the sulfosuccinate is a cocamido sulfosuccinate.
- 25. A skin cleansing composition comprising:
- i) more than about 30% C.sub.14 or lower acyl esters of isethionic acid salts, the acyl chain length distribution of said esters being at least about 95% C.sub.8 -C.sub.18 ; and
- ii) at least one betaine wherein the weight ratio of said acyl esters to betaine is about 8:1 to about 2:1; and said betaine has the structure ##STR7## wherein, R is a hydrocarbon chain having a distribution of at least about 90% C.sub.5 -C.sub.17 ;
- X is H, or CH.sub.2 OH;
- Y is methyl methylene or CONHCH.sub.2 CH.sub.2 CH.sub.2 ;
- Z is COO.sup.-, or CHOHCH.sub.2 SO.sub.3 --, provided that when X, Y and Z are respectively H, CH.sub.2 and COO.sup.- in combination, R is less than 50% C.sub.15 -C.sub.17 ; and
- (iii) at least one amido sulfosuccinate;
- (iv) free fatty acid in an amount of about 2-40%;
- (v) fatty alcohol in an amount of about 0-10%;
- (vi) sodium isethionate in an amount of about 2-20%;
- (vii) soap in an amount of about 0-10%; and
- (viii) water in an amount of about 2-20%.
- 26. A composition according to claim 25, wherein the sulfosuccinate is amido sulfosuccinate.
RELATED APPLICATIONS
The subject application is a continuation-in-part of U.S. Ser. No. 791,762, filed Nov. 12, 1991, and now abandoned, which in turn is a continuation-in-part of U.S. Ser. No. 477,682 to Rys et al., filed Feb. 9, 1990, and now abandoned and of U.S. Ser. No. 563,468 to Carque et al., filed Aug. 7, 1990, and now abandoned.
US Referenced Citations (18)
Foreign Referenced Citations (5)
Number |
Date |
Country |
51-1497 |
May 1976 |
JPX |
60-8398 |
Jan 1985 |
JPX |
60-161498 |
Aug 1985 |
JPX |
62-141098 |
Jun 1987 |
JPX |
63-225700 |
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JPX |
Related Publications (1)
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Number |
Date |
Country |
|
563468 |
Aug 1990 |
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Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
791762 |
Nov 1991 |
|
Parent |
477682 |
Feb 1990 |
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