Additive manufacturing system having adjustable nozzle configuration

Information

  • Patent Grant
  • 10828829
  • Patent Number
    10,828,829
  • Date Filed
    Monday, October 30, 2017
    7 years ago
  • Date Issued
    Tuesday, November 10, 2020
    4 years ago
Abstract
A print head is disclosed for use with an additive manufacturing system. The print head may include a matrix reservoir, and a nozzle base connected to an end of the matrix reservoir. The nozzle base may have a plurality of attachment features formed within an exposed surface. The print head may further include a plurality of available dies separately connectable to the nozzle base via the plurality of attachment features. Attachment of the plurality of available dies to the nozzle base may establish fluid communication with the matrix reservoir.
Description
TECHNICAL FIELD

The present disclosure relates generally to a manufacturing system and, more particularly, to an additive manufacturing system having an adjustable nozzle configuration.


BACKGROUND

Extrusion manufacturing is a known process for producing continuous structures. During extrusion manufacturing, a liquid matrix (e.g., a thermoset resin or a heated thermoplastic) is pushed through a die having a desired cross-sectional shape and size. The material, upon exiting the die, cures and hardens into a final form. In some applications, UV light and/or ultrasonic vibrations are used to speed the cure of the liquid matrix as it exits the die. The structures produced by the extrusion manufacturing process can have any continuous length, with a straight or curved profile, a consistent cross-sectional shape, and excellent surface finish. Although extrusion manufacturing can be an efficient way to continuously manufacture structures, the resulting structures may lack the strength required for some applications.


Pultrusion manufacturing is a known process for producing high-strength structures. During pultrusion manufacturing, individual fiber strands, braids of strands, and/or woven fabrics are coated with or otherwise impregnated with a liquid matrix (e.g., a thermoset resin or a heated thermoplastic) and pulled through a stationary die where the liquid matrix cures and hardens into a final form. As with extrusion manufacturing, UV light and/or ultrasonic vibrations are used in some pultrusion applications to speed the cure of the liquid matrix as it exits the die. The structures produced by the pultrusion manufacturing process have many of the same attributes of extruded structures, as well as increased strength due to the integrated fibers. Although pultrusion manufacturing can be an efficient way to continuously manufacture high-strength structures, the resulting structures may lack the form (shape, size, and/or precision) and/or diversity required for some applications.


The disclosed system is directed at addressing one or more of the problems set forth above and/or other problems of the prior art.


SUMMARY

In one aspect, the present disclosure is directed to a die for a print head of an additive manufacturing system. The die may include a plurality of wall blocks pre-assembled to form an open-ended enclosure. The die may also include at least one orifice block located inside the open-ended enclosure.


In another aspect, the present disclosure is directed to a print head for an additive manufacturing system. The print head may include a matrix reservoir, and a nozzle base connected to an end of the matrix reservoir. The nozzle base may have a plurality of attachment features formed within an exposed surface. The print head may further include a plurality of available dies separately connectable to the nozzle base via the plurality of attachment features. Attachment of the plurality of available dies to the nozzle base may establish fluid communication with the matrix reservoir.


In yet another aspect, the present disclosure is directed to another print head for an additive manufacturing system. This print head may include a matrix reservoir, and a nozzle base connected to an end of the matrix reservoir. The nozzle base may have a plurality of attachment features formed within an exposed surface. The print head may also include a plurality of wall blocks separately connectable to the nozzle base via the plurality of attachment features to form an open-ended enclosure, and at least one orifice block connectable to the nozzle base via at least one of the plurality of attachment features at a location inside the open-ended enclosure. Attachment of the at least one orifice block to the nozzle base may establish fluid communication with the matrix reservoir.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a diagrammatic illustration of an exemplary disclosed manufacturing system;



FIGS. 2 and 3 are diagrammatic illustrations of an exemplary disclosed head that may be utilized with the manufacturing system of FIG. 1; and



FIGS. 4 and 5 are diagrammatic illustrations of exemplary nozzle configurations that may be used in conjunction with the head of FIGS. 2 and 3.





DETAILED DESCRIPTION


FIG. 1 illustrates an exemplary system 10, which may be used to continuously manufacture a composite structure 12 having any desired cross-sectional shape (e.g., circular, polygonal, etc.). System 10 may include at least a support 14 and a head 16. Head 16 may be coupled to and moved by support 14. In the disclosed embodiment of FIG. 1, support 14 is a robotic arm capable of moving head 16 in multiple directions during fabrication of structure 12, such that a resulting longitudinal axis of structure 12 is three-dimensional. It is contemplated, however, that support 14 could alternatively be an overhead gantry or a hybrid gantry/arm also capable of moving head 16 in multiple directions during fabrication of structure 12. Although support 14 is shown as being capable of multi-axis movements, it is contemplated that any other type of support 14 capable of moving head 16 in the same or in a different manner could also be utilized, if desired. In some embodiments, a drive may mechanically couple head 16 to support 14, and may include components that cooperate to move and/or supply power or materials to head 16.


Head 16 may be configured to receive or otherwise contain a matrix material. The matrix material may include any type of matrix material (e.g., a liquid resin, such as a zero volatile organic compound resin; a powdered metal; etc.) that is curable. Exemplary matrixes include thermosets, single- or multi-part epoxy resins, polyester resins, cationic epoxies, acrylated epoxies, urethanes, esters, thermoplastics, photopolymers, polyepoxides, thiols, alkenes, thiol-enes, and more. In one embodiment, the matrix material inside head 16 may be pressurized, for example by an external device (e.g., an extruder or another type of pump—not shown) that is fluidly connected to head 16 via a corresponding conduit (not shown). In another embodiment, however, the pressure may be generated completely inside of head 16 by a similar type of device. In yet other embodiments, the matrix material may be gravity-fed through and/or mixed within head 16. In some instances, the matrix material inside head 16 may need to be kept cool and/or dark to inhibit premature curing; while in other instances, the matrix material may need to be kept warm for the same reason. In either situation, head 16 may be specially configured (e.g., insulated, chilled, and/or warmed) to provide for these needs.


The matrix material may be used to coat, encase, or otherwise surround any number of continuous reinforcements (e.g., separate fibers, tows, rovings, ribbons, and/or sheets of material) and, together with the reinforcements, make up at least a portion (e.g., a wall) of composite structure 12. The reinforcements may be stored within (e.g., on separate internal spools—not shown) or otherwise passed through head 16 (e.g., fed from external spools). When multiple reinforcements are simultaneously used, the reinforcements may be of the same type and have the same diameter and cross-sectional shape (e.g., circular, square, flat, etc.), or of a different type with different diameters and/or cross-sectional shapes. The reinforcements may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, optical tubes, etc. It should be noted that the term “reinforcement” is meant to encompass both structural and non-structural types of continuous materials that can be at least partially encased in the matrix material discharging from head 16.


The reinforcements may be exposed to (e.g., coated with) the matrix material while the reinforcements are inside head 16, while the reinforcements are being passed to head 16 (e.g., as a pre-preg material), and/or while the reinforcements are discharging from head 16, as desired. The matrix material, dry reinforcements, and/or reinforcements that are already exposed to the matrix material (e.g., wetted reinforcements) may be transported into head 16 in any manner apparent to one skilled in the art.


The matrix material and reinforcement may be discharged from head 16 via at least two different modes of operation. In a first mode of operation, the matrix material and reinforcement are extruded (e.g., pushed under pressure and/or mechanical force) from head 16, as head 16 is moved by support 14 to create the 3-dimensional shape of structure 12. In a second mode of operation, at least the reinforcement is pulled from head 16, such that a tensile stress is created in the reinforcement during discharge. In this mode of operation, the matrix material may cling to the reinforcement and thereby also be pulled from head 16 along with the reinforcement, and/or the matrix material may be discharged from head 16 under pressure along with the pulled reinforcement. In the second mode of operation, where the matrix material is being pulled from head 16, the resulting tension in the reinforcement may increase a strength of structure 12, while also allowing for a greater length of unsupported material to have a straighter trajectory (i.e., the tension may act against the force of gravity to provide free-standing support for structure 12).


The reinforcement may be pulled from head 16 as a result of head 16 moving away from an anchor point 18. In particular, at the start of structure-formation, a length of matrix-impregnated reinforcement may be pulled and/or pushed from head 16, deposited onto anchor point 18, and cured, such that the discharged material adheres to anchor point 18. Thereafter, head 16 may be moved away from anchor point 18, and the relative movement may cause the reinforcement to be pulled from head 16. It should be noted that the movement of the reinforcement through head 16 could be assisted (e.g., via internal feed mechanisms), if desired. However, the discharge rate of the reinforcement from head 16 may primarily be the result of relative movement between head 16 and anchor point 18, such that tension is created within the reinforcement. It is contemplated that anchor point 18 could be moved away from head 16 instead of or in addition to head 16 being moved away from anchor point 18.


One or more cure enhancers (e.g., one or more light sources, an ultrasonic emitter, a laser, a heater, a catalyst dispenser, a microwave generator, etc.) 20 may be mounted proximate (e.g., within, on, and/or trailing from) head 16 and configured to enhance a cure rate and/or quality of the matrix material as it is discharged from head 16. Cure enhancer 20 may be controlled to selectively expose internal and/or external surfaces of structure 12 to energy (e.g., light energy, electromagnetic radiation, vibrations, heat, a chemical catalyst or hardener, etc.) during the formation of structure 12. The energy may increase a rate of chemical reaction occurring within the matrix material, sinter the material, harden the material, or otherwise cause the material to cure as it discharges from head 16.


A controller 22 may be provided and communicatively coupled with support 14, head 16, and any number and type of cure enhancers 20. Controller 22 may embody a single processor or multiple processors that include a means for controlling an operation of system 10. Controller 22 may include one or more general- or special-purpose processors or microprocessors. Controller 22 may further include or be associated with a memory for storing data such as, for example, design limits, performance characteristics, operational instructions, matrix characteristics, reinforcement characteristics, characteristics of structure 12, and corresponding parameters of each component of system 10. Various other known circuits may be associated with controller 22, including power supply circuitry, signal-conditioning circuitry, solenoid/motor driver circuitry, communication circuitry, and other appropriate circuitry. Moreover, controller 22 may be capable of communicating with other components of system 10 via wired and/or wireless transmission.


One or more maps may be stored in the memory of controller 22 and used during fabrication of structure 12. Each of these maps may include a collection of data in the form of models, lookup tables, graphs, and/or equations. In the disclosed embodiment, the maps are used by controller 22 to determine desired characteristics of cure enhancers 20, the associated matrix, and/or the associated reinforcements at different locations within structure 12. The characteristics may include, among others, a type, quantity, and/or configuration of reinforcement and/or matrix to be discharged at a particular location within structure 12, and/or an amount, intensity, shape, and/or location of desired compacting and curing. Controller 22 may then correlate operation of support 14 (e.g., the location and/or orientation of head 16) and/or the discharge of material from head 16 (a type of material, desired performance of the material, cross-linking requirements of the material, a discharge rate, etc.) with the operation of cure enhancers 20 such that structure 12 is produced in a desired manner.


An exemplary head 16 is disclosed in detail in FIGS. 2 and 3. As can be seen in these figures, head 16 may be modular and configured to change configuration in a plug-and-play manner (e.g., like interlocking building blocks), such that structures 12 of varying cross-sectional shapes and sizes may be produced. Head 16 may include, among other things, a matrix reservoir 24 that is connectable to a distal end of support 14, and a configurable nozzle 26 that is operatively and fluidly connected to receive matrix only and/or matrix-coated reinforcements from an end of matrix reservoir 24 opposite support 14.


Nozzle 26 may have a base 28 that includes any number of attachment features (e.g., posts and holes, latches and catches, etc.) 30 distributed across an exposed end face. One or more functional blocks may be removably attachable to base 28 via features 30. These functional blocks may include, among others, wall blocks 32, orifice blocks 34, and cure blocks 36. Wall blocks 32 may have one or more walls (e.g., straight-line walls, angled walls, segmented walls, L-shaped walls, tilted walls, curved walls, etc.) that can be oriented to direct flows of matrix only and/or matrix-coated reinforcements during extrusion from nozzle 26. Multiple wall blocks 32 may be arranged to form an open-ended enclosure, which can be used to channel and/or shape the flows in a particular manner. One or more orifice blocks 34 may be connected to base 28 at a location inside of the enclosure formed by wall blocks 32, and used as gates or valves that allow the flows of matrix or matrix-coated fibers to pass from matrix reservoir 24 into or through the enclosure. Cure blocks 36 may host one or more cure enhancers 20, and are typically connected to base 28 at an outer periphery of the enclosure formed by wall blocks 32. It is contemplated, however, that cure blocks 36 could additionally or alternatively be located inside of the enclosure, if desired.


It is contemplated attachment features 30 may all be the same and used with all of the functional blocks, or different and dedicated to the use of only particular functional blocks. For example, each attachment feature 30 may include a centralized one-way port (e.g., a reed valve) that is selectively opened (e.g., pushed inward, pulled outward, twisted open, etc.) when a corresponding orifice block 34 is coupled therewith, as well as electrical leads (e.g., a negative lead at a lower surface of base 28, and a positive lead that protrudes away and is insulated from the lower surface) that provide power to cure blocks 36 upon establishment of the appropriate connection. Alternatively, some features 30 may include only the one-way port, while other features may include only the electrical leads. Wall blocks 32 may be connected to any available feature 30.


Wall blocks 32, orifice blocks 34, and/or cure blocks 36, when arranged in a particular manner, may constitute a die 38 (see FIG. 3) that produces a particular cross-sectional shape and/or size within structure 12. It is contemplated that these functional blocks could be pre-assembled into unique dies 38, if desired, and thereafter connected as an integral unit to base 28. In this manner, a first die 38 may be pulled away from base 28 and easily replaced with an alternative die 38 via a simplified process, if desired. Likewise, multiple relatively simple dies 38 could be connected to base 28 at the same time (see FIG. 4) and cooperate to produce a more complex die assembly of connected channels. This may allow for a large number of differently shaped structures 12 to be manufactured with the same head 16, without requiring an extensive collection of nozzles 26.



FIGS. 4 and 5 illustrate different examples of how functional blocks 32-36 and/or dies 38 can be arranged to produce different structures 12 having complex cross-sectional shapes and sizes. It should be noted that features 30 are not shown in FIGS. 4 and 5, for purposes of clarity. FIG. 4 illustrates a complex shape consisting of three separate dies 38 forming three separate enclosures. The enclosure of each die 38 is made from multiple separate wall blocks 32, some of which are straight and others of which are curved. It should be noted that functional blocks of different sizes may be intermingled, if desired. One or more orifice blocks 34 are located inside of each of the enclosures, and multiple cure blocks 36 are positioned around the perimeter of each enclosure. FIG. 5 illustrates a complex shape consisting of wall blocks 32 forming a generally four-sided enclosure that can be used to fabricate a molding (e.g., crown molding). Three orifice blocks 34 are located inside of the enclosure, and five cure blocks 36 are positioned around the enclosure. Any number and shape of cooperating functional blocks 32-36 and/or dies 38 may be used to fabricate a single structure 12.


INDUSTRIAL APPLICABILITY

The disclosed system may be used to continuously manufacture composite structures having any desired cross-sectional size, shape, length, density, and/or strength. The composite structures may include any number of different reinforcements of the same or different types, diameters, shapes, configurations, and consists, each coated with a common matrix material. In addition, the disclosed heads may allow cooperative fabrication of complex structures via a variety of configurable nozzles. Operation of system 10 will now be described in detail.


At a start of a manufacturing event, information regarding a desired structure 12 may be loaded into system 10 (e.g., into controller 22 that is responsible for regulating operations of support 14 and/or head 16). This information may include, among other things, a size (e.g., diameter, wall thickness, length, etc.), a contour (e.g., a trajectory), surface features (e.g., ridge size, location, thickness, length; flange size, location, thickness, length; etc.), connection geometry (e.g., locations and sizes of couplings, tees, splices, etc.), desired weave patterns, weave transition locations, location-specific matrix stipulations, location-specific reinforcement stipulations, density stipulations, etc. It should be noted that this information may alternatively or additionally be loaded into system 10 at different times and/or continuously during the manufacturing event, if desired. Based on the component information, one or more functional blocks 32-36 or pre-assembled dies 38 may then be connected base 28 of nozzle 26. It is contemplated that this assembly may be completed manually, or automatically (e.g., by controller 22 causing support 14 to move head 16 to a configuration area having the functional blocks 32-36 and/or dies 38 set out and prepared in a manner that would allow hands free connection), as desired.


Different reinforcements and/or matrix materials may be selectively installed and/or continuously supplied into system 10. Installation of the reinforcements may be performed by passing the reinforcements down through matrix reservoir 24, and then threading the reinforcements through orifice block(s) 34 of nozzle 26. Installation of the matrix material may include filling matrix reservoir 24 and/or coupling of an extruder (not shown) to matrix reservoir 24.


Head 16 may then be moved by support 14 under the regulation of controller 22 to cause matrix-coated reinforcements to be placed against or on a corresponding anchor point 18. Cure enhancers 20 located within cure blocks 36 may then be selectively activated to cause hardening of the matrix material surrounding the reinforcements, thereby bonding the reinforcements to anchor point 18.


The component information may then be used to control operation of systems 10 and 12. For example, the reinforcements may be pulled and/or pushed from head 16 (along with the matrix material), while support 14 selectively moves head 16 in a desired manner during curing, such that an axis of the resulting structure 12 follows a desired trajectory (e.g., a free-space, unsupported, 3-D trajectory). As the separate reinforcements are pulled through head 16, the reinforcements may pass through orifice block(s) 34 and into any associated enclosure formed by wall block(s) 32. The composite material may then take the shape of the enclosure, and be discharged as the cross-section of structure 12. Once structure 12 has grown to a desired length, structure 12 may be disconnected (e.g., severed) from head 16 in any desired manner.


It will be apparent to those skilled in the art that various modifications and variations can be made to the disclosed systems and head. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the disclosed systems and heads. It is intended that the specification and examples be considered as exemplary only, with a true scope being indicated by the following claims and their equivalents.

Claims
  • 1. A die for a print head of an additive manufacturing system, the die comprising: a nozzle base;a plurality of wall blocks separately connectable to the nozzle base in a plurality of available configurations to form an open-ended enclosure configured to shape material discharging from the print head; andat least one orifice block connectable to the base at a location inside the open-ended enclosure and configured to discharge the material into the open-ended enclosure.
  • 2. The die of claim 1, further including at least one cure block located at a periphery of the open-ended enclosure and configured to expose the material after discharge to energy that causes the material to cure.
  • 3. The die of claim 2, wherein at least one of a location and a number of the at least one cure block is adjustable.
  • 4. The die of claim 2, wherein the at least one cure block hosts at least one cure enhancer configured to enhance curing of a matrix discharging from the print head.
  • 5. The die of claim 4, wherein the at least one cure enhancer is a UV light.
  • 6. The die of claim 1, wherein the one of the plurality of available configurations of the open-ended enclosure is adjustable via movement of the plurality of separate wall blocks relative to the base.
  • 7. The die of claim 1, wherein at least one of a location and a number of the at least one orifice block is adjustable.
  • 8. The die of claim 1, wherein the plurality of wall blocks and the at least one orifice block each includes an attachment feature configured to removably engage a corresponding attachment feature of the base.
  • 9. A print head of an additive manufacturing system, the print head comprising: a matrix reservoir;a nozzle base fluidly connected to an end of the matrix reservoir and having a plurality of attachment features formed within an exposed surface;a plurality of wall blocks separately connectable to the nozzle base via the plurality of attachment features in a plurality of different configurations, the plurality of wall blocks arranged to form an open-ended enclosure together that shapes material discharging from the print head.
  • 10. The print head of claim 9, further including at least one orifice block located inside the open-ended enclosure and configured to discharge the material, wherein attachment of the at least one orifice block to the nozzle base establishes fluid communication with the matrix reservoir.
  • 11. The print head of claim 10, further including at least one cure block mounted on the nozzle base in a plurality of adjustable configurations at a periphery of the open-ended enclosure and configured to expose the material after discharge to energy that causes the material to cure.
  • 12. The print head of claim 11, wherein mechanical attachment of the at least one cure block to the nozzle base establishes at least one electrical connection.
  • 13. The print head of claim 9, wherein the the open-ended enclosure is connectable to the nozzle base at different locations.
  • 14. The print head of claim 9, wherein multiple open-ended enclosures may be connected to the nozzle base at the same time to form a multi-part die assembly.
  • 15. A print head of an additive manufacturing system, the print head comprising: a matrix reservoir;a nozzle base connected to an end of the matrix reservoir and having a plurality of attachment features formed within an exposed surface; anda plurality of wall blocks separately connectable to the nozzle base in a plurality of different configurations via the plurality of attachment features to form an open-ended enclosure that shapes material as it discharges from the print head; andat least one orifice block connectable to the nozzle base via at least one of the plurality of attachment features at a location inside the open-ended enclosure, wherein attachment of the at least one orifice block to the nozzle base establishes fluid communication with the matrix reservoir.
  • 16. The print head of claim 15, further including at least one cure block connectable to the nozzle base via at least one of the plurality of attachment features at a periphery of the open-ended enclosure.
  • 17. The print head of claim 16, wherein attachment of the at least one cure block to the nozzle base establishes at least one electrical connection.
  • 18. The print head of claim 16, wherein at least one of the following is adjustable: a location of the at least one cure block;a number of the at least one cure block;a configuration of the open-ended enclosure;a location of the at least one orifice block; anda number of the at least one orifice block.
  • 19. The print head of claim 16, wherein the at least one cure block hosts at least one cure enhancer configured to expose the material after discharge to energy to enhance curing of a matrix discharging from the print head.
  • 20. The print head of claim 19, wherein the at least one cure enhancer is a UV light.
RELATED APPLICATIONS

This application is based on and claims the benefit of priority from U.S. Provisional Application No. 62/417,709 that was filed on Nov. 4, 2016, the contents of which are expressly incorporated herein by reference.

US Referenced Citations (185)
Number Name Date Kind
3286305 Seckel Nov 1966 A
3809514 Nunez May 1974 A
3984271 Gilbu Oct 1976 A
3993726 Moyer Nov 1976 A
4643940 Shaw et al. Feb 1987 A
4671761 Adrian et al. Jun 1987 A
4822548 Hempel Apr 1989 A
4851065 Curtz Jul 1989 A
5002712 Goldmann et al. Mar 1991 A
5037691 Medney et al. Aug 1991 A
5296335 Thomas et al. Mar 1994 A
5340433 Crump Aug 1994 A
5746967 Hoy et al. May 1998 A
5866058 Batchelder et al. Feb 1999 A
5936861 Jang et al. Aug 1999 A
6153034 Lipsker Nov 2000 A
6459069 Rabinovich Oct 2002 B1
6501554 Hackney et al. Dec 2002 B1
6799081 Hale et al. Sep 2004 B1
6803003 Rigali et al. Oct 2004 B2
6934600 Jang et al. Aug 2005 B2
7039485 Engelbart et al. May 2006 B2
7555404 Brennan et al. Jun 2009 B2
7795349 Bredt et al. Sep 2010 B2
8221669 Batchelder et al. Jul 2012 B2
8962717 Roth et al. Feb 2015 B2
9126365 Mark et al. Sep 2015 B1
9126367 Mark et al. Sep 2015 B1
9149988 Mark et al. Oct 2015 B2
9156205 Mark et al. Oct 2015 B2
9186846 Mark et al. Nov 2015 B1
9186848 Mark et al. Nov 2015 B2
9327452 Mark et al. May 2016 B2
9327453 Mark et al. May 2016 B2
9370896 Mark Jun 2016 B2
9381702 Hollander Jul 2016 B2
9457521 Johnston et al. Oct 2016 B2
9458955 Hammer et al. Oct 2016 B2
9527248 Hollander Dec 2016 B2
9539762 Durand et al. Jan 2017 B2
9579851 Mark et al. Feb 2017 B2
9688028 Mark et al. Jun 2017 B2
9694544 Mark et al. Jul 2017 B2
9764378 Peters et al. Sep 2017 B2
9770876 Farmer et al. Sep 2017 B2
9782926 Witzel et al. Oct 2017 B2
10293554 Hakkaku May 2019 B2
20020009935 Hsiao et al. Jan 2002 A1
20020062909 Jang et al. May 2002 A1
20020113331 Zhang et al. Aug 2002 A1
20020165304 Mulligan et al. Nov 2002 A1
20030011106 Osaki Jan 2003 A1
20030044539 Oswald Mar 2003 A1
20030056870 Comb et al. Mar 2003 A1
20030160970 Basu et al. Aug 2003 A1
20030186042 Dunlap et al. Oct 2003 A1
20030236588 Jang et al. Dec 2003 A1
20050006803 Owens Jan 2005 A1
20050061422 Martin Mar 2005 A1
20050104257 Gu et al. May 2005 A1
20050109451 Hauber et al. May 2005 A1
20050230029 Vaidyanathan et al. Oct 2005 A1
20070003650 Schroeder Jan 2007 A1
20070228592 Dunn et al. Oct 2007 A1
20080176092 Owens Jul 2008 A1
20090095410 Oldani Apr 2009 A1
20100283809 Bastani et al. Nov 2010 A1
20110032301 Fienup et al. Feb 2011 A1
20110143108 Fruth et al. Jun 2011 A1
20110298877 Blessing Dec 2011 A1
20120060468 Dushku et al. Mar 2012 A1
20120159785 Pyles et al. Jun 2012 A1
20120212540 Dietl Aug 2012 A1
20120231225 Mikulak et al. Sep 2012 A1
20120247655 Erb et al. Oct 2012 A1
20130164498 Langone et al. Jun 2013 A1
20130209600 Tow Aug 2013 A1
20130233471 Kappesser et al. Sep 2013 A1
20130292039 Peters et al. Nov 2013 A1
20130337256 Farmer et al. Dec 2013 A1
20130337265 Farmer Dec 2013 A1
20140034214 Boyer et al. Feb 2014 A1
20140044822 Mulliken Feb 2014 A1
20140061974 Tyler Mar 2014 A1
20140159284 Leavitt Jun 2014 A1
20140232035 Bheda Aug 2014 A1
20140242208 Elsworthy Aug 2014 A1
20140268604 Wicker et al. Sep 2014 A1
20140291886 Mark et al. Oct 2014 A1
20150136455 Fleming May 2015 A1
20160012935 Rothfuss Jan 2016 A1
20160031155 Tyler Feb 2016 A1
20160046082 Fuerstenberg Feb 2016 A1
20160052208 Debora et al. Feb 2016 A1
20160082641 Bogucki et al. Mar 2016 A1
20160082659 Hickman et al. Mar 2016 A1
20160107379 Mark et al. Apr 2016 A1
20160114532 Schirtzinger et al. Apr 2016 A1
20160136885 Nielsen-Cole et al. May 2016 A1
20160144565 Mark et al. May 2016 A1
20160144566 Mark et al. May 2016 A1
20160192741 Mark Jul 2016 A1
20160200047 Mark et al. Jul 2016 A1
20160243762 Fleming et al. Aug 2016 A1
20160263806 Gardiner Sep 2016 A1
20160263822 Boyd Sep 2016 A1
20160263823 Espiau et al. Sep 2016 A1
20160271876 Lower Sep 2016 A1
20160297104 Guillemette et al. Oct 2016 A1
20160311165 Mark et al. Oct 2016 A1
20160325491 Sweeney et al. Nov 2016 A1
20160332369 Shah et al. Nov 2016 A1
20160339633 Stolyarov et al. Nov 2016 A1
20160346998 Mark et al. Dec 2016 A1
20160361869 Mark et al. Dec 2016 A1
20160368213 Mark Dec 2016 A1
20160368255 Witte et al. Dec 2016 A1
20170007359 Kopelman et al. Jan 2017 A1
20170007360 Kopelman et al. Jan 2017 A1
20170007361 Boronkay et al. Jan 2017 A1
20170007362 Chen et al. Jan 2017 A1
20170007363 Boronkay Jan 2017 A1
20170007365 Kopelman et al. Jan 2017 A1
20170007366 Kopelman et al. Jan 2017 A1
20170007367 Li et al. Jan 2017 A1
20170007368 Boronkay Jan 2017 A1
20170007386 Mason et al. Jan 2017 A1
20170008333 Mason et al. Jan 2017 A1
20170015059 Lewicki Jan 2017 A1
20170015060 Lewicki et al. Jan 2017 A1
20170021565 Deaville Jan 2017 A1
20170028434 Evans et al. Feb 2017 A1
20170028588 Evans et al. Feb 2017 A1
20170028617 Evans et al. Feb 2017 A1
20170028619 Evans et al. Feb 2017 A1
20170028620 Evans et al. Feb 2017 A1
20170028621 Evans et al. Feb 2017 A1
20170028623 Evans et al. Feb 2017 A1
20170028624 Evans et al. Feb 2017 A1
20170028625 Evans et al. Feb 2017 A1
20170028627 Evans et al. Feb 2017 A1
20170028628 Evans et al. Feb 2017 A1
20170028633 Evans et al. Feb 2017 A1
20170028634 Evans et al. Feb 2017 A1
20170028635 Evans et al. Feb 2017 A1
20170028636 Evans et al. Feb 2017 A1
20170028637 Evans et al. Feb 2017 A1
20170028638 Evans et al. Feb 2017 A1
20170028639 Evans et al. Feb 2017 A1
20170028644 Evans et al. Feb 2017 A1
20170030207 Kittleson Feb 2017 A1
20170036403 Ruff et al. Feb 2017 A1
20170050340 Hollander Feb 2017 A1
20170057164 Hemphill et al. Mar 2017 A1
20170057165 Waldrop et al. Mar 2017 A1
20170057167 Tooren et al. Mar 2017 A1
20170057181 Waldrop et al. Mar 2017 A1
20170064840 Espalin et al. Mar 2017 A1
20170066187 Mark et al. Mar 2017 A1
20170087768 Bheda Mar 2017 A1
20170106565 Braley et al. Apr 2017 A1
20170120519 Mark May 2017 A1
20170129170 Kim et al. May 2017 A1
20170129171 Gardner et al. May 2017 A1
20170129176 Waafti et al. May 2017 A1
20170129182 Sauti et al. May 2017 A1
20170129186 Sauti et al. May 2017 A1
20170144375 Waldrop et al. May 2017 A1
20170151728 Kunc et al. Jun 2017 A1
20170157828 Mandel et al. Jun 2017 A1
20170157831 Mandel et al. Jun 2017 A1
20170157844 Mandel et al. Jun 2017 A1
20170157851 Nardiello et al. Jun 2017 A1
20170165908 Pattinson et al. Jun 2017 A1
20170173868 Mark Jun 2017 A1
20170182712 Scribner et al. Jun 2017 A1
20170210074 Ueda et al. Jul 2017 A1
20170217088 Boyd et al. Aug 2017 A1
20170232674 Mark Aug 2017 A1
20170259502 Chapiro et al. Sep 2017 A1
20170259507 Hocker Sep 2017 A1
20170266876 Hocker Sep 2017 A1
20170274585 Armijo et al. Sep 2017 A1
20170284876 Moorlag et al. Oct 2017 A1
20190084219 Brusilovski Mar 2019 A1
Foreign Referenced Citations (29)
Number Date Country
4102257 Jul 1992 DE
2589481 Jan 2016 EP
3219474 Sep 2017 EP
100995983 Nov 2010 KR
101172859 Aug 2012 KR
2013017284 Feb 2013 WO
2015163862 Oct 2015 WO
2016088042 Jun 2016 WO
2016088048 Jun 2016 WO
2016110444 Jul 2016 WO
2016159259 Oct 2016 WO
2016196382 Dec 2016 WO
2017006178 Jan 2017 WO
2017006324 Jan 2017 WO
2017051202 Mar 2017 WO
2017081253 May 2017 WO
2017085649 May 2017 WO
2017087663 May 2017 WO
2017108758 Jun 2017 WO
2017122941 Jul 2017 WO
2017122942 Jul 2017 WO
2017122943 Jul 2017 WO
2017123726 Jul 2017 WO
2017124085 Jul 2017 WO
2017126476 Jul 2017 WO
2017126477 Jul 2017 WO
2017137851 Aug 2017 WO
2017142867 Aug 2017 WO
2017150186 Sep 2017 WO
Non-Patent Literature Citations (14)
Entry
A. Di. Pietro & Paul Compston, Resin Hardness and Interlaminar Shear Strength of a Glass-Fibre/Vinylester Composite Cured with High Intensity Ultraviolet (UV) Light, Journal of Materials Science, vol. 44, pp. 4188-4190 (Apr. 2009).
A. Endruweit, M. S. Johnson, & A. C. Long, Curing of Composite Components by Ultraviolet Radiation: A Review, Polymer Composites, pp. 119-128 (Apr. 2006).
C. Fragassa, & G. Minak, Standard Characterization for Mechanical Properties of Photopolymer Resins for Rapid Prototyping, 1st Symposium on Multidisciplinary Studies of Design in Mechanical Engineering, Bertinoro, Italy (Jun. 25-28, 2008).
Hyouk Ryeol Choi and Se-gon Roh, In-pipe Robot with Active Steering Capability for Moving Inside of Pipelines, Bioinspiration and Robotics: Walking and Climbing Robots, Sep. 2007, p. 544, I-Tech, Vienna, Austria.
Kenneth C. Kennedy II & Robert P. Kusy, UV-Cured Pultrusion Processing of Glass-Reinforced Polymer Composites, Journal of Vinyl and Additive Technology, vol. 1, Issue 3, pp. 182-186 (Sep. 1995).
M. Martin-Gallego et al., Epoxy-Graphene UV-Cured Nanocomposites, Polymer, vol. 52, Issue 21, pp. 4664-4669 (Sep. 2011).
P. Compston, J. Schiemer, & A. Cvetanovska, Mechanical Properties and Styrene Emission Levels of a UV-Cured Glass-Fibre/Vinylester Composite, Composite Structures, vol. 86, pp. 22-26 (Mar. 2008).
S Kumar & J.-P. Kruth, Composites by Rapid Prototyping Technology, Materials and Design, (Feb. 2009).
S. L. Fan, F. Y. C. Boey, & M. J. M. Abadie, UV Curing of a Liquid Based Bismaleimide-Containing Polymer System, eXPRESS Polymer Letters, vol. 1, No. 6, pp. 397-405 (2007).
T. M. Llewelly-Jones, Bruce W. Drinkwater, and Richard S. Trask; 3D Printed Components With Ultrasonically Arranged Microscale Structure, Smart Materials and Structures, 2016, pp. 1-6, vol. 25, IOP Publishing Ltd., UK.
Vincent J. Lopata et al., Electron-Beam-Curable Epoxy Resins for the Manufacture of High-Performance Composites, Radiation Physics and Chemistry, vol. 56, pp. 405-415 (1999).
Yugang Duan et al., Effects of Compaction and UV Exposure on Performance of Acrylate/Glass-Fiber Composites Cured Layer by Layer, Journal of Applied Polymer Science, vol. 123, Issue 6, pp. 3799-3805 (May 15, 2012).
3D Chocolate Printer, by Kira, Sep. 19, 2015. Available at http://www.3ders.org/articles/20150919-childhood-fantasy-come-true-a-3d-chocolate-printer-made-from-lego.html, retrieved on Dec. 23, 2013.
International Search Report dated Jan. 22, 2018 for PCT/US17/59442 to CC3D LLC Filed Nov. 1, 2017.
Related Publications (1)
Number Date Country
20180126642 A1 May 2018 US
Provisional Applications (1)
Number Date Country
62417709 Nov 2016 US