Additive manufacturing system implementing anchor curing

Information

  • Patent Grant
  • 10857726
  • Patent Number
    10,857,726
  • Date Filed
    Tuesday, December 19, 2017
    6 years ago
  • Date Issued
    Tuesday, December 8, 2020
    3 years ago
Abstract
A system for additively manufacturing a composite structure is disclosed. The system may include a print head configured to discharge a matrix-coated reinforcement, and a support configured to move the print head in multiple dimensions during discharging of the matrix-coated reinforcement. The system may further include at least one cure enhancer located offboard the print head, and a controller in communication with the support and the at least one cure enhancer. The controller may be configured to selectively activate the at least one cure enhancer to expose the matrix-coated reinforcement to a cure energy during discharging of the matrix-coated reinforcement.
Description
TECHNICAL FIELD

The present disclosure relates generally to a manufacturing system and, more particularly, to an additive manufacturing system implementing anchor curing.


BACKGROUND

Traditional additive manufacturing is a process of creating three-dimensional parts by depositing overlapping layers of material under the guided control of a computer. A common form of additive manufacturing is known as fused deposition modeling (FDM). Using FDM, a thermoplastic is passed through and liquified within a heated print head. The print head is moved in a predefined trajectory (a.k.a., a tool path) as the material discharges from the print head, such that the material is laid down in a particular pattern and shape of overlapping 2-dimensional layers. The material, after exiting the print head, cools and hardens into a final form. A strength of the final form is primarily due to properties of the particular thermoplastic supplied to the print head and a 3-dimensional shape formed by the stack of 2-dimensional layers.


A recently developed improvement over traditional FDM manufacturing involves the use of continuous fibers embedded within material discharging from the print head (a.k.a., Continuous Fiber 3D Printing—CF3D™). In particular, a matrix is supplied to the print head and discharged (e.g., extruded and/or pultruded) along with one or more continuous fibers also passing through the same head at the same time. The matrix can be a traditional thermoplastic, a powdered metal, a liquid matrix (e.g., a UV curable and/or two-part resin), or a combination of any of these and other known matrixes. Upon exiting the print head, a cure enhancer (e.g., a UV light, an ultrasonic emitter, a heat source, a catalyst supply, etc.) is activated to initiate and/or complete curing of the matrix. This curing occurs almost immediately, allowing for unsupported structures to be fabricated in free space. And when fibers, particularly continuous fibers, are embedded within the structure, a strength of the structure may be multiplied beyond the matrix-dependent strength. An example of this technology is disclosed in U.S. Pat. No. 9,511,543 that issued to Tyler on Dec. 6, 2016 (“the '543 patent”).


In some applications, the cure enhancers described above are mounted directly to the print head. In these applications, when discharging relatively opaque fibers, such as carbon fibers, high-density fibers, high-concentrations of fibers, large-diameter fibers, etc., light from the cure enhancers can be blocked by the fibers during an anchoring procedure occurring at a start of a fabrication event. This can lead to the need for manual intervention and/or result in a delayed fabrication start and weak anchoring.


The disclosed system is directed to addressing one or more of the problems set forth above and/or other problems of the prior art.


SUMMARY

In one aspect, the present disclosure is directed to a system for additively manufacturing a composite structure. The system may include a print head configured to discharge a matrix-coated reinforcement, and a support configured to move the print head in multiple dimensions during discharging of the matrix-coated reinforcement. The system may further include at least one cure enhancer located offboard the print head, and a controller in communication with the support and the at least one cure enhancer. The controller may be configured to selectively activate the at least one cure enhancer to expose the matrix-coated reinforcement to a cure energy during discharging of the matrix-coated reinforcement.


In another aspect, the present disclosure is directed to another system for additively manufacturing a composite structure. This system may include a print head configured to discharge a matrix-coated reinforcement, and at least one onboard cure enhancer operatively mounted to the print head. The system may further include a support configured to move the print head in multiple dimensions during discharging of the matrix-coated reinforcement, and at least one offboard cure enhancer located offboard the print head. The system may also include a controller in communication with the support, the at least one onboard cure enhancer, and the at least one offboard cure enhancer. The controller may be configured to selectively activate the at least one onboard cure enhancer and the at least one offboard cure enhancer to expose the matrix-coated reinforcement to a cure energy during discharging of the matrix-coated reinforcement based on a proximity of the print head.


In yet another aspect, the present disclosure is directed to a method of additively manufacturing a composite structure. The method may include discharging from a print head a matrix-coated reinforcement, and moving the print head in multiple dimensions during discharging of the matrix-coated reinforcement. The method may further include selectively exposing the matrix-coated reinforcement to a cure energy from offboard the print head during discharging of the matrix-coated reinforcement.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a diagrammatic illustration of an exemplary disclosed manufacturing system.





DETAILED DESCRIPTION


FIG. 1 illustrates an exemplary system 10, which may be used to continuously manufacture a composite structure 12 having any desired cross-sectional shape (e.g., circular, polygonal, etc.). System 10 may include at least a support 14 and a head 16. Head 16 may have a body 18 that is coupled to and moved by support 14, and a nozzle 20 located at an opposing discharge end of body 18. In the disclosed embodiment of FIG. 1, support 14 is a robotic arm capable of moving head 16 in multiple directions during fabrication of structure 12, such that a resulting longitudinal axis of structure 12 is three-dimensional. It is contemplated, however, that support 14 could alternatively be an overhead gantry or a hybrid gantry/arm also capable of moving head 16 in multiple directions during fabrication of structure 12. Although support 14 is shown as being capable of 6-axis movements, it is contemplated that any other type of support 14 capable of moving head 16 in the same or in a different manner could also be utilized, if desired. In some embodiments, a drive may mechanically couple head 16 to support 14, and may include components that cooperate to move and/or supply power or materials to head 16.


Body 18 may be configured to receive or otherwise contain a matrix. The matrix may include any type of material (e.g., a liquid resin, such as a zero-volatile organic compound resin; a powdered metal; etc.) that is curable. Exemplary resins include thermosets, single- or multi-part epoxy resins, polyester resins, cationic epoxies, acrylated epoxies, urethanes, esters, thermoplastics, photopolymers, polyepoxides, thiols, alkenes, thiol-enes, and more. In one embodiment, the matrix inside body 18 is pressurized, for example by an external device (e.g., an extruder or another type of pump—not shown) that is fluidly connected to head 16 via a corresponding conduit (not shown). In another embodiment, however, the pressure is generated completely inside of body 18 by a similar type of device. In yet other embodiments, the matrix is gravity-fed through and/or mixed within body 18. In some instances, the matrix may need to be kept cool and/or dark inside body 18 to inhibit premature curing; while in other instances, the matrix may need to be kept warm for the same reason. In either situation, body 18 may be specially configured (e.g., insulated, chilled, and/or warmed) to provide for these needs.


The matrix may be used to coat, encase, or otherwise surround any number of continuous reinforcements (e.g., separate fibers, tows, rovings, and/or sheets of material) and, together with the reinforcements, make up at least a portion (e.g., a wall) of composite structure 12. The reinforcements may be stored within (e.g., on separate internal spools—not shown) or otherwise passed through body 18 (e.g., fed from external spools—not shown). When multiple reinforcements are simultaneously used, the reinforcements may be of the same type and have the same diameter and cross-sectional shape (e.g., circular, square, flat, etc.), or of a different type with different diameters and/or cross-sectional shapes. The reinforcements may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, optical tubes, etc. It should be noted that the term “reinforcement” is meant to encompass both structural and non-structural types of continuous materials that can be at least partially encased in the matrix discharging from nozzle 20.


The reinforcements may be exposed to (e.g., at least partially coated with) the matrix while the reinforcements are passing through body 18. The matrix, dry reinforcements, and/or reinforcements that are already exposed to the matrix (a.k.a., wetted reinforcements) may be transported into body 18 in any manner apparent to one skilled in the art.


The matrix and reinforcement may be discharged from nozzle 20 as a track of composite material via at least two different modes of operation. In a first mode of operation, the matrix and reinforcement are extruded (e.g., pushed under pressure and/or mechanical force) from nozzle 20, as head 16 is moved by support 14 to create the 3-dimensional shape of structure 12. In a second mode of operation, at least the reinforcement is pulled from nozzle 20, such that a tensile stress is created in the reinforcement during discharge. In this mode of operation, the matrix may cling to the reinforcement and thereby also be pulled from nozzle 20 along with the reinforcement, and/or the matrix may be discharged from nozzle 20 under pressure along with the pulled reinforcement. In the second mode of operation, where the composite material is being pulled from nozzle 20, a residual tension in the reinforcement may increase a strength of structure 12, while also allowing for a greater length of unsupported material to have a straighter trajectory (i.e., the tension may act against the force of gravity to provide free-standing support for structure 12).


The reinforcement may be pulled from nozzle 20 as a result of head 16 moving away from an anchor point 22. In particular, at the start of structure-formation, a length of matrix-impregnated reinforcement may be pulled and/or pushed from nozzle 20, deposited onto anchor point 22, and cured, such that the discharged material adheres to anchor point 22. Thereafter, head 16 may be moved away from anchor point 22, and the relative movement may cause the reinforcement to be pulled from nozzle 20. It should be noted that the movement of reinforcement through body 18 could be assisted (e.g., via one or more internal and/or external feed mechanisms—not shown), if desired. However, the discharge rate of reinforcement from nozzle 20 may primarily be the result of relative movement between head 16 and anchor point 22, such that tension is created and maintained within the reinforcement. It is contemplated that anchor point 22 could be moved away from head 16 instead of or in addition to head 16 being moved away from anchor point 22. Anchor points 22 may extend from a build chamber (e.g., from a print bed or wall) 24 and/or from structure 12 itself. In fact, build chamber may 24, itself, function as an anchor point 22, if desired.


One or more cure enhancers (e.g., a UV light, an ultrasonic emitter, a laser, a heater, a catalyst dispenser, etc.) 26 may be selectively used to enhance a cure rate and/or quality of the matrix as it is discharged from head 16. Cure enhancer 26 may be controlled to selectively expose internal and/or external surfaces of structure 12 to energy (e.g., UV light, electromagnetic radiation, vibrations, heat, a chemical catalyst, hardener, or initiator, etc.) during the formation of structure 12. The energy may increase a rate of chemical reaction occurring within the matrix, sinter the material, harden the material, or otherwise cause the material to cure as it discharges from head 16.


Any number of cure enhancers 26 may be cooperatively energized to produce a desired cure effect within structure 12. In one embodiment, multiple cure enhancers 26 are mounted proximate (e.g., within, on, and/or trailing from) head 16 (e.g., at a base of body 18, inside of body 18, outside of body 18, or otherwise adjacent nozzle 20) and energized continuously during discharge of material from nozzle 20. In another embodiment, at least one cure enhancer 26 is located offboard head 16 and associated with each (e.g., located on, inside of, adjacent to, etc.) anchor point 22. These offboard cure enhancer(s) may be used only during an initial step of a build process to help ensure proper adhesion to anchor point 22. In yet another embodiment, one or more additional offboard cure enhancers 26 are associated with build chamber 24, in which structure 12 is being fabricated. Specifically, one or more cure enhancers 26 may be mounted on, inside of, or behind a floor, wall, and/or ceiling of build chamber 24. For example, the associated surface of build chamber 24 may be generally transparent, and cure enhancer(s) 24 may be located at a side opposite print head 16, such that cure energy passes through the surface. In this embodiment, cure enhancers 26 may be selectively activated at any time during the build process (e.g., simultaneously and continuously throughout the process, or sequentially and temporarily based on a known or tracked proximity of head 16 during controlled movements by support 14) to help ensure a desired level of cure within structure 12. It is contemplated that any combination of head-mounted, anchor-mounted, and/or chamber-mounted cure enhancers 26 may be used at any time during fabrication of structure 12. Each of these cure enhancers 26 may generate an equal amount of cure energy of the same type and having the same characteristics (e.g., angle, focus, intensity, wavelength, direction, etc.), or different amounts of cure energy of differing types and having different characteristics.


A controller 28 may be provided and communicatively coupled with support 14, head 16, and any number and type of cure enhancers 26. Controller 28 may embody a single processor or multiple processors that include a means for controlling an operation of system 10. Controller 28 may include one or more general- or special-purpose processors or microprocessors. Controller 28 may further include or be associated with a memory for storing data such as, for example, design limits, performance characteristics, operational instructions, matrix characteristics, reinforcement characteristics, characteristics of structure 12, and corresponding parameters of each component of system 10. Various other known circuits may be associated with controller 28, including power supply circuitry, signal-conditioning circuitry, solenoid/motor driver circuitry, communication circuitry, and other appropriate circuitry. Moreover, controller 28 may be capable of communicating with other components of system 10 via wired and/or wireless transmission.


One or more maps may be stored in the memory of controller 28 and used during fabrication of structure 12. Each of these maps may include a collection of data in the form of lookup tables, graphs, and/or equations. In the disclosed embodiment, the maps are used by controller 28 to determine desired characteristics of cure enhancers 26, the associated matrix, and/or the associated reinforcements at different locations within structure 12. The characteristics may include, among others, a type, quantity, and/or configuration of reinforcement and/or matrix to be discharged at a particular location within structure 12, and/or an amount, shape, timing, and/or location of desired curing. Controller 28 may then correlate operation of support 14 (e.g., the location and/or orientation of head 16) and/or the discharge of material from nozzle 20 (a type of material, desired performance of the material, cross-linking requirements of the material, a discharge rate, etc.) with the operation of cure enhancers 26 such that structure 12 is produced in a desired manner.


INDUSTRIAL APPLICABILITY

The disclosed system may be used to continuously manufacture composite structures having any desired cross-sectional shape, length, density, and/or strength. The composite structures may include any number of different reinforcements of the same or different types, diameters, shapes, configurations, and consists, and/or any number of different matrixes. Operation of system 10 will now be described in detail.


At a start of a manufacturing event, information regarding a desired structure 12 may be loaded into system 10 (e.g., into controller 28 that is responsible for regulating operation of support 14, cure enhancer(s) 26, and/or any other associated components). This information may include, among other things, a size (e.g., diameter, wall thickness, length, etc.), a contour (e.g., a trajectory), surface features (e.g., ridge size, location, thickness, length; flange size, location, thickness, length; etc.), connection geometry (e.g., locations and sizes of couplings, tees, splices, etc.), location-specific matrix stipulations, location-specific reinforcement stipulations, desired cure rates, cure locations, cure shapes, cure amounts, etc. It should be noted that this information may alternatively or additionally be loaded into system 10 at different times and/or continuously during the manufacturing event, if desired.


Based on the component information, a specific cure enhancer configuration may be connected to head 16 (e.g., to the discharge end of body 18), to anchor point(s) 22, and/or various surfaces of build chamber 24, and one or more different (e.g., different sizes, shapes, and/or types of) reinforcements and/or matrixes may be selectively installed within system 10 and/or continuously supplied into nozzle 20. The corresponding reinforcements (e.g., prepreg or dry fibers, tows, ribbons, or sheets) may be passed through nozzle 20, and thereafter connected to a pulling machine (not shown) and/or to a mounting fixture (e.g., to anchor point 22). Installation of the matrix may include filling body 18 and/or coupling of an extruder (not shown) to head 16.


Head 16 may be moved by support 14 under the regulation of controller 28 to cause matrix-coated reinforcements to be placed against or on a corresponding anchor point 22. Any combination of cure enhancers 26 (e.g., the offboard cure enhancers 26 mounted to a particular anchor point 22 and/or the onboard cure enhancers 26 of head 16) may then be selectively activated (e.g., turned on by controller 28) to cause hardening of the matrix surrounding the reinforcements, thereby bonding the reinforcements to anchor point 22.


The component information may then be used to control operation of system 10. For example, the reinforcements may be pulled through body 18, submerged within the matrix, and then discharged from nozzle 20. Controller 28 selectively cause support 14 to move head 16 in a desired manner at this time, such that an axis of the resulting structure 12 follows a desired trajectory (e.g., a free-space, unsupported, 3-D trajectory). In addition, cure enhancers 26 associated with head 16 and/or build chamber 24 may be selectively activated by controller 28 during material discharge to initiate, speed up, or complete hardening of the matrix. As controller 28 causes support 14 to move head 16 about build chamber 24 during material discharging, various chamber-mounted cure enhancers 26 (e.g., those cure enhancers 26 closest to head 16 at any given time) may be selectively activated to provide a desired level of cure within the material.


It will be apparent to those skilled in the art that various modifications and variations can be made to the disclosed systems and head. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the disclosed systems and heads. It is intended that the specification and examples be considered as exemplary only, with a true scope being indicated by the following claims and their equivalents.

Claims
  • 1. A method of additively manufacturing a composite structure, comprising: discharging from a print head a matrix-coated reinforcement;moving the print head in multiple dimensions during discharging of the matrix-coated reinforcement; andexposing the matrix-coated reinforcement to a cure energy during discharging of the matrix-coated reinforcement by activating one or more of a plurality of cure energy sources located offboard the print head, wherein said activation of the one or more plurality of cure energy sources located offboard of the print head is based on a proximity of the print head discharging the matrix-coated reinforcement to a respective one or more of the plurality of cure energy sources.
  • 2. The method of claim 1, wherein: discharging from the print head the matrix-coated reinforcement includes discharging the matrix-coated reinforcement into a print chamber; andactivating the one or more of the plurality of cure energy sources includes activating the one or more of the plurality of cure energy sources at a surface of the print chamber.
  • 3. The method of claim 1, wherein: discharging from the print head the matrix-coated reinforcement includes discharging the matrix-coated reinforcement into a print chamber; andactivating the one or more of the plurality of cure energy sources includes directing the cure energy through a surface of the print chamber.
  • 4. The method of claim 1, wherein: discharging from the print head the matrix-coated reinforcement includes discharging the matrix-coated reinforcement onto an anchor point that extends inward from a print chamber wall, and moving the print head away from the anchor point to cause the matrix-coated reinforcement to be pulled from the print head; andactivating the one or more of the plurality of cure energy sources located offboard the print head includes exposing the matrix-coated reinforcement to cure energy from the anchor point.
  • 5. The method of claim 1, further selectively exposing the matrix-coated reinforcement to a cure energy from onboard the print head.
  • 6. The method of claim 5, wherein selectively exposing the matrix-coated reinforcement to the cure energy from onboard the print head includes selectively activating a cure source having a different energy characteristic from the cure energy to which the matrix-coated reinforcement is exposed to from offboard the print head.
  • 7. A method of additively manufacturing a composite structure, comprising: discharging from a print head a composite material that hardens when exposed to a cure energy;moving the print head during discharging; andactivating one or more of a plurality of available cure energy sources located off board of the print head, wherein said activation is based on a proximity of the print head, during discharging of the composite material, to the one or more of the plurality of energy cure sources located off board of the printhead.
  • 8. The method of claim 7, wherein activating the one or more of the plurality of available cure energy sources includes activating a stationary source.
  • 9. The method of claim 8, wherein: discharging from the print head includes discharging into a print chamber; andactivating the one or more of the plurality of available cure energy sources includes selectively exposing the composite material to the cure energy from a surface of the print chamber.
  • 10. The method of claim 8, wherein: discharging from the print head includes discharging into a print chamber; andactivating the one or more of the plurality of available cure energy sources includes directing light through the surface of the print chamber.
  • 11. The method of claim 8, wherein: discharging from the print head includes discharging onto an anchor point that extends inward from a print chamber wall, and moving the print head away from the anchor point to cause the composite material to be pulled from the print head; andactivating the one or more of the plurality of available cure energy sources includes selectively exposing the composite material to the cure energy from the anchor point.
  • 12. The method of claim 11, wherein: discharging from the print head includes discharging into a print chamber; andactivating the one or more of the plurality of available cure energy sources further includes selectively exposing the composite material to the cure energy from a surface of the print chamber.
  • 13. The method of claim 8, further including selectively exposing the composite material to additional cure energy from onboard the print head.
  • 14. The method of claim 13, wherein selectively exposing the composite material to additional cure energy from onboard the print head includes selectively exposing the composite material to a cure energy having a characteristic different from the cure energy to which the material is exposed from offboard the print head.
  • 15. The method of claim 14, wherein at least one of the cure energy and the additional cure energy is light energy.
RELATED APPLICATIONS

This application is based on and claims the benefit of priority from U.S. Provisional Application No. 62/449,899 that was filed on Jan. 24, 2017, the contents of which are expressly incorporated herein by reference.

US Referenced Citations (187)
Number Name Date Kind
3286305 Seckel Nov 1966 A
3809514 Nunez May 1974 A
3984271 Gilbu Oct 1976 A
3993726 Moyer Nov 1976 A
4643940 Shaw et al. Feb 1987 A
4671761 Adrian et al. Jun 1987 A
4822548 Hempel Apr 1989 A
4851065 Curtz Jul 1989 A
5002712 Goldmann et al. Mar 1991 A
5037691 Medney et al. Aug 1991 A
5134569 Masters Jul 1992 A
5204124 Secretan Apr 1993 A
5296335 Thomas et al. Mar 1994 A
5340433 Crump Aug 1994 A
5534101 Keyworth Jul 1996 A
5746967 Hoy et al. May 1998 A
5866058 Batchelder et al. Feb 1999 A
5936861 Jang et al. Aug 1999 A
6153034 Lipsker Nov 2000 A
6459069 Rabinovich Oct 2002 B1
6501554 Hackney et al. Dec 2002 B1
6799081 Hale et al. Sep 2004 B1
6803003 Rigali et al. Oct 2004 B2
6934600 Jang et al. Aug 2005 B2
7039485 Engelbart et al. May 2006 B2
7555404 Brennan et al. Jun 2009 B2
7795349 Bredt et al. Sep 2010 B2
8221669 Batchelder et al. Jul 2012 B2
8962717 Roth et al. Feb 2015 B2
9126365 Mark et al. Sep 2015 B1
9126367 Mark et al. Sep 2015 B1
9149988 Mark et al. Oct 2015 B2
9156205 Mark et al. Oct 2015 B2
9186846 Mark et al. Nov 2015 B1
9186848 Mark et al. Nov 2015 B2
9327452 Mark et al. May 2016 B2
9327453 Mark et al. May 2016 B2
9370896 Mark Jun 2016 B2
9381702 Hollander Jul 2016 B2
9457521 Johnston et al. Oct 2016 B2
9458955 Hammer et al. Oct 2016 B2
9527248 Hollander Dec 2016 B2
9539762 Durand et al. Jan 2017 B2
9579851 Mark et al. Feb 2017 B2
9688028 Mark et al. Jun 2017 B2
9694544 Mark et al. Jul 2017 B2
9764378 Peters et al. Sep 2017 B2
9770876 Farmer et al. Sep 2017 B2
9782926 Witzel et al. Oct 2017 B2
20020009935 Hsiao et al. Jan 2002 A1
20020062909 Jang et al. May 2002 A1
20020113331 Zhang et al. Aug 2002 A1
20020127345 Rheinberger et al. Sep 2002 A1
20020165304 Mulligan et al. Nov 2002 A1
20030044539 Oswald Mar 2003 A1
20030056870 Comb et al. Mar 2003 A1
20030160970 Basu et al. Aug 2003 A1
20030186042 Dunlap et al. Oct 2003 A1
20030236588 Jang et al. Dec 2003 A1
20050006803 Owens Jan 2005 A1
20050061422 Martin Mar 2005 A1
20050104257 Gu et al. May 2005 A1
20050109451 Hauber et al. May 2005 A1
20050230029 Vaidyanathan et al. Oct 2005 A1
20070003650 Schroeder Jan 2007 A1
20070228592 Dunn et al. Oct 2007 A1
20080176092 Owens Jul 2008 A1
20090095410 Oldani Apr 2009 A1
20110032301 Fienup et al. Feb 2011 A1
20110143108 Fruth et al. Jun 2011 A1
20120060468 Dushku et al. Mar 2012 A1
20120159785 Pyles et al. Jun 2012 A1
20120231225 Mikulak et al. Sep 2012 A1
20120247655 Erb et al. Oct 2012 A1
20130164498 Langone et al. Jun 2013 A1
20130209600 Tow Aug 2013 A1
20130233471 Kappesser et al. Sep 2013 A1
20130292039 Peters et al. Nov 2013 A1
20130337256 Farmer et al. Dec 2013 A1
20130337265 Farmer Dec 2013 A1
20140034214 Boyer et al. Feb 2014 A1
20140036455 Napadensky Feb 2014 A1
20140061974 Tyler Mar 2014 A1
20140159284 Leavitt Jun 2014 A1
20140232035 Bheda Aug 2014 A1
20140268604 Wicker et al. Sep 2014 A1
20140291886 Mark et al. Oct 2014 A1
20150136455 Fleming May 2015 A1
20150165691 Mark Jun 2015 A1
20150217517 Karpas Aug 2015 A1
20160012935 Rothfuss Jan 2016 A1
20160031155 Tyler Feb 2016 A1
20160046082 Fuerstenberg Feb 2016 A1
20160052208 Debora et al. Feb 2016 A1
20160067928 Mark et al. Mar 2016 A1
20160082641 Bogucki et al. Mar 2016 A1
20160082659 Hickman et al. Mar 2016 A1
20160107379 Mark et al. Apr 2016 A1
20160114532 Schirtzinger et al. Apr 2016 A1
20160136885 Nielsen-Cole et al. May 2016 A1
20160144565 Mark et al. May 2016 A1
20160144566 Mark et al. May 2016 A1
20160192741 Mark Jul 2016 A1
20160200047 Mark et al. Jul 2016 A1
20160243762 Fleming et al. Aug 2016 A1
20160263806 Gardiner Sep 2016 A1
20160263822 Boyd, IV Sep 2016 A1
20160263823 Espiau et al. Sep 2016 A1
20160271876 Lower Sep 2016 A1
20160297104 Guillemette et al. Oct 2016 A1
20160311165 Mark et al. Oct 2016 A1
20160325491 Sweeney et al. Nov 2016 A1
20160332369 Shah et al. Nov 2016 A1
20160339633 Stolyarov et al. Nov 2016 A1
20160346998 Mark et al. Dec 2016 A1
20160361869 Mark et al. Dec 2016 A1
20160368213 Mark Dec 2016 A1
20160368255 Witte et al. Dec 2016 A1
20170007359 Kopelman et al. Jan 2017 A1
20170007360 Kopelman et al. Jan 2017 A1
20170007361 Boronkay et al. Jan 2017 A1
20170007362 Chen et al. Jan 2017 A1
20170007363 Boronkay Jan 2017 A1
20170007365 Kopelman et al. Jan 2017 A1
20170007366 Kopelman et al. Jan 2017 A1
20170007367 Li et al. Jan 2017 A1
20170007368 Boronkay Jan 2017 A1
20170007386 Mason et al. Jan 2017 A1
20170008333 Mason et al. Jan 2017 A1
20170014950 Okada Jan 2017 A1
20170015059 Lewicki Jan 2017 A1
20170015060 Lewicki et al. Jan 2017 A1
20170021565 Deaville Jan 2017 A1
20170028434 Evans et al. Feb 2017 A1
20170028588 Evans et al. Feb 2017 A1
20170028617 Evans et al. Feb 2017 A1
20170028619 Evans et al. Feb 2017 A1
20170028620 Evans et al. Feb 2017 A1
20170028621 Evans et al. Feb 2017 A1
20170028623 Evans et al. Feb 2017 A1
20170028624 Evans et al. Feb 2017 A1
20170028625 Evans et al. Feb 2017 A1
20170028627 Evans et al. Feb 2017 A1
20170028628 Evans et al. Feb 2017 A1
20170028633 Evans et al. Feb 2017 A1
20170028634 Evans et al. Feb 2017 A1
20170028635 Evans et al. Feb 2017 A1
20170028636 Evans et al. Feb 2017 A1
20170028637 Evans et al. Feb 2017 A1
20170028638 Evans et al. Feb 2017 A1
20170028639 Evans et al. Feb 2017 A1
20170028644 Evans et al. Feb 2017 A1
20170030207 Kittleson Feb 2017 A1
20170036403 Ruff et al. Feb 2017 A1
20170050340 Hollander Feb 2017 A1
20170057164 Hemphill et al. Mar 2017 A1
20170057165 Waldrop, III et al. Mar 2017 A1
20170057167 Tooren et al. Mar 2017 A1
20170057181 Waldrop, III et al. Mar 2017 A1
20170064840 Espalin et al. Mar 2017 A1
20170066187 Mark et al. Mar 2017 A1
20170087768 Bheda Mar 2017 A1
20170106565 Braley et al. Apr 2017 A1
20170120519 Mark May 2017 A1
20170129170 Kim et al. May 2017 A1
20170129171 Gardner et al. May 2017 A1
20170129176 Waatti et al. May 2017 A1
20170129182 Sauti et al. May 2017 A1
20170129186 Sauti et al. May 2017 A1
20170144375 Waldrop, III et al. May 2017 A1
20170151728 Kunc et al. Jun 2017 A1
20170157828 Mandel et al. Jun 2017 A1
20170157831 Mandel et al. Jun 2017 A1
20170157844 Mandel et al. Jun 2017 A1
20170157851 Nardiello et al. Jun 2017 A1
20170165908 Pattinson et al. Jun 2017 A1
20170173868 Mark Jun 2017 A1
20170182712 Scribner et al. Jun 2017 A1
20170210074 Ueda et al. Jul 2017 A1
20170217088 Boyd et al. Aug 2017 A1
20170232674 Mark Aug 2017 A1
20170259502 Chapiro et al. Sep 2017 A1
20170259507 Hocker Sep 2017 A1
20170266876 Hocker Sep 2017 A1
20170274585 Armijo et al. Sep 2017 A1
20170284876 Moorlag et al. Oct 2017 A1
20180154588 Wilenski Jun 2018 A1
Foreign Referenced Citations (30)
Number Date Country
4102257 Jul 1992 DE
102015002967 Oct 2016 DE
2447046 May 2012 EP
2589481 Jan 2016 EP
3219474 Sep 2017 EP
100995983 Nov 2010 KR
101172859 Aug 2012 KR
2013017284 Feb 2013 WO
2016088042 Jun 2016 WO
2016088048 Jun 2016 WO
2016110444 Jul 2016 WO
2016159259 Oct 2016 WO
2016196382 Dec 2016 WO
2017006178 Jan 2017 WO
2017006324 Jan 2017 WO
2017051202 Mar 2017 WO
2017081253 May 2017 WO
2017085649 May 2017 WO
2017087663 May 2017 WO
2017108758 Jun 2017 WO
2017122941 Jul 2017 WO
2017122942 Jul 2017 WO
2017122943 Jul 2017 WO
2017123726 Jul 2017 WO
2017124085 Jul 2017 WO
2017126476 Jul 2017 WO
2017126477 Jul 2017 WO
2017137851 Aug 2017 WO
2017142867 Aug 2017 WO
2017150186 Sep 2017 WO
Non-Patent Literature Citations (13)
Entry
A. Di. Pietro & Paul Compston, Resin Hardness and Interlaminar Shear Strength of a Glass-Fibre/Vinylester Composite Cured with High Intensity Ultraviolet (UV) Light, Journal of Materials Science, vol. 44, pp. 4188-4190 (Apr. 2009).
A. Endruweit, M. S. Johnson, & A. C. Long, Curing of Composite Components by Ultraviolet Radiation: A Review, Polymer Composites, pp. 119-128 (Apr, 2006).
C. Fragassa, & G. Minak, Standard Characterization for Mechanical Properties of Photopolymer Resins for Rapid Prototyping, 1st Symposium on Multidisciplinary Studies of Design in Mechanical Engineering, Bertinoro, Italy (Jun. 25-28, 2008).
Hyouk Ryeol CHOI and Se-gon ROH, In-pipe Robot with Active Steering Capability for Moving Inside of Pipelines, Bioinspiration and Robotics: Walking and Climbing Robots, Sep. 2007, p. 544, I-Tech, Vienna, Austria.
Kenneth C. Kennedy II & Robert P. Kusy, UV-Cured Pultrusion Processing of Glass-Reinforced Polymer Composites, Journal of Vinyl and Additive Technology, vol. 1, Issue 3, pp. 182-186 (Sep. 1995).
M. Martin-Gallego et al., Epoxy-Graphene UV-Cured Nanocomposites, Polymer, vol. 52, Issue 21, pp. 4664-4669 (Sep. 2011).
P. Compston, J, Schiemer, & A. Cvetanovska, Mechanical Properties and Styrene Emission Levels of a UV-Cured Glass-Fibre/Vinylester Composite, Composite Structures, vol. 86, pp, 22-26 (Mar. 2008).
S Kumar & J.-P. Kruth, Composites by Rapid Prototyping Technology, Materials and Design, (Feb. 2009).
S. L. Fan, F. Y. C. Boey, & M. J. M. Abadie, UV Curing of a Liquid Based Bismaleimide-Containing Polymer System, eXPRESS Polymer Letters, vol. 1, No. 6, pp. 397-405 (2007).
T.M. Llewelly-Jones, Bruce W. Drinkwater, and Richard S. Trask; 3D Printed Components With Ultrasonically Arranged Microscale Structure, Smart Materials and Structures, 2016, pp. 1-6, vol. 25, IOP Publishing Ltd., UK.
Vincent J. Lopata et al., Electron-Beam-Curable Epoxy Resins for the Manufacture of High-Performance Composites, Radiation Physics and Chemistry, vol. 56, pp. 405-415 (1999).
Yugang Duan et al., Effects of Compaction and UV Exposure on Performance of Acrylate/Glass-Fiber Composites Cured Layer by Layer, Journal of Applied Polymer Science, vol. 123, Issue 6, pp. 3799-805 (May 15, 2012).
International Search Report dated Feb. 20, 2018 for PCT/US2017/068019 to CC3D LLC Filed Dec. 21, 2017.
Related Publications (1)
Number Date Country
20180207862 A1 Jul 2018 US
Provisional Applications (1)
Number Date Country
62449899 Jan 2017 US