Patent Application
20140203018
The invention relates to an adhesive tape system for forming a tear strip.
Tear strips are known and serve in various forms as an opening aid firstly for cigarette packs, confectionery packs, and similar packs that are wrapped in a film, and secondly for cardboard packaging such as packs of laundry detergent, for instance. In these applications the tear strip is affixed to the pack in such a way that, for opening, the tear strip is pulled and thereby the wrapping film and/or the carton is parted open at the desired point.
Traditionally in use are tear strips furnished on one side with a hotmelt-based adhesive. They are described for example in U.S. Pat. No. 3,187,982 A, in U.S. Pat. No. 3,311,032 A, or CA 749 198 A. Also in use is a tear strip furnished self-adhesively. For this, a monoaxially oriented carrier film is used which is equipped with a self-adhesive layer on one side and with a silicone release layer on the other side. Optionally there is printing below one of the two layers. Constructions of this or similar kind are known for the production of pressure-sensitive tapes, from DE 21 04 817 A, from U.S. Pat. No. 3,088,848 A, from U.S. Pat. No. 3,482,683 A, or from U.S. Pat. No. 2,956,904 A, for example. Not disclosed in those specifications is the use of such film constructions for self-adhesive tear strips. The use of self-adhesive tapes of this kind as tear strips is mentioned, however, in the journal “Packaging Review” from February 1973, page 57.
One specific embodiment of these self-adhesively furnished tear strips is described by DE 43 38 524 A1. A self-adhesive tear strip is disclosed therein that consists of a carrier film, a release layer, a layer of adhesive remote from the release layer, and optionally printing below the adhesive layer or release layer. The strip is characterized in that the carrier film consists of an oriented film, in that the release layer and adhesive layer are applied from aqueous solution, emulsion, or dispersion, and in that release layer, printing ink, and adhesive layer are applied on a machine in one operation to a film which is many times wider than the tear strip.
Customary for use as an opening aid for film packs are at least single-layer carrier films with a thickness of 15 to 60 μm that have been at least monoaxially and preferably biaxially oriented.
Self-adhesive or heat-activatable tear strips composed of polypropylene film oriented in machine direction have long been used for the tear-opening of cardboard packaging. They are offered in film thicknesses from 50 to 140 μm. Film thicknesses greater than 85 μm find use in the opening of particularly heavy cardboard packaging. More usual are tear strips in thicknesses between 60 and 90 μm.
Tear strips based on a monoaxially oriented polypropylene carrier often use, for the carrier, a specific polymer blend which is optimized in its tear-open performance, resulting in machine-direction tensile strengths of 230 to 330 N/mm2.
These polypropylene tear strips of preferably 60 to 65 μm display flawless tear-open behavior across all corrugated cardboard packaging, including card with microcorrugation. This applies irrespective of whether tearing is performed exactly in the direction of the adhered strip.
“Exactly in the direction of the adhered strip” means that in the tear-opening process, the tear strip is guided in such a way that the pulling direction never deviates from the direction mandated by the tear strip which is bonded on the carton reverse and which during the tear-open process is visible as a torn join even from the front of the carton. Only then is there a symmetrical distribution of forces in the tear strip during the tear-open process, and a uniform load on both cut edges. In practice, this ideal tearing direction is usually not observed. Deviations from this direction by up to about 30° can be expected.
A trend within the tear strip market is the deviation from a film formula optimized for tear-open performance. Reduced tear-open performance in this case is accepted willingly in order to obtain, in return, improved machine processability of the tear strip during its application.
For example, it is possible to reduce the impact modifiers to below the amount that is advisable for optimum tear-open performance, up to the point of their complete omission.
Heavy-duty solid card grades of around 1000 g/m2 can be torn open faultlessly only in the optimum tear-open direction. In the event of deviation from this direction, the unsymmetrical load on the strip may result in tears during the tear-open operation that start from the more heavily loaded edge of the strip. The frequency of the tears is influenced, for example, by inhomogeneities in the film, by microindentations in the cut edges of the film strips, by wood particles or particularly solidified particles in the card, and similar phenomena. Also possessing an influence is the speed of tearing.
For the packaging of laundry detergents, solid cards, with a basis weight of between 450 and 600 g/m2, are used to a relatively great extent, and in some cases have a wax-impregnated interlayer, but in any case are provided with a laminated-on outer layer of high-gloss cast-coated Chromolux papers. Tearing open these cards using the polypropylene tear strips can be accomplished only with a similarly poor result as for the abovementioned 1000 g/m2 solid cards.
Known from EP 0 269 967 A1 is a tear strip which has a carrier oriented in predominantly one direction and which is provided with an adhesive layer, the carrier consisting of at least one base layer which is provided with at least one tough layer that is tougher than the base layer.
Particularly preferred is a tear strip having a carrier which is oriented in predominantly one direction and which is provided with an adhesive layer, the carrier consisting of at least one base layer comprising a polypropylene-olefin copolymer and/or a polypropylene/impact modifier mixture, this base layer being provided with at least one tough, polypropylene-containing layer that comprises an impact modifier and is tougher than the base layer.
In the case of polypropylene-based tear strips it is preferred to use TPP (corresponding to monoaxially oriented polypropylene (MOPP)), since the strain must be low even under high tensile load.
High tensile loads come about firstly, in the end application, when the tear strip is pulled when the pack is being opened, through the card or through the carton and/or the film, and is intended to part these components reliably. Such loads, secondly, also come about when the tear strip is being applied to the packaging, since it is frequently applied at speeds of more than 150 m/min. Particularly at the start, in other words when the tear strip is placed onto—for example—the card, the roll, up to about 15 kg in weight, to which the tear strip has customarily been converted in the trade, is accelerated suddenly and violently. Even in ongoing operation, tensile stresses of more than 8 N are often acting on the tear strips. This rules out the use of unoriented or else biaxially oriented polypropylene.
If TPP without release is used, then unwinding, i.e., the separation of the composition from the carrier, is accompanied by splitting of the carrier, meaning that some of the fibers stretched and oriented in the machine direction are extracted from the surface of the carrier. This may adversely affect the converting operation if the coated film web, which is very much wider than the tear strip, is slit into individual tear strips and for that purpose is unwound from the stock roll. The fibers projecting from the surface of the carrier themselves hinder the operation, or else there may be tearing of the carrier web as a whole. Moreover, similar problems may occur in the course of application to the packaging, when the tear strip is being unwound.
Sales trays which serve to accommodate products packed in individual cartons currently fulfill two functions. On the one hand, the cartons are arranged in a tray which is open at the top. In the shop, this tray is offered in a visually appealing fashion to a customer, who is able to take individual cartons from the tray. The effect of the tray is that the cartons remain grouped and always in an ordered upright position.
On the other hand, the trays are intended to protect the cartons in the tray on the journey from the producer or filler to the shop. For this purpose, the product is surrounded fully by a packaging of card, which is torn open to present the contents, using a tear strip. The upper part of the carton is removed, with the lower part serving as the sales tray.
In order to evoke a visually appealing impression, the tear line must have a clean and smooth edge finish. The card of which the carton is made should not fray, and the tear must also run straight with maximum precision. The skilled person in this context refers to a “clean cut”.
For the opening of cardboard packaging in such a way that a clean cut is produced, there are primarily two solutions in existence.
The so-called Adalis system (developed by the company Adalis) consists of two adhesive tapes (guide adhesive tape=tape A and tear strip=tape B) which are installed in the carton as shown in
The adhesive tapes consist of a carrier material composed of numerous polyester filaments held together with an adhesive. The carrier material is coated with a hotmelt adhesive. The two liners and also the corrugation and the two adhesive tapes here pass through a heating tunnel, producing a laminate in accordance with
A disadvantage of this system is that the adhesive tapes used are very thick (2×200 to 250 μm) and consequently the printed image on the external, visible liner is impaired through wear at the raised points during transport and storage. Furthermore, as part of a manufacturing operation, a large number of these unmade cartons (carton blanks) and folded boxes are stacked. Since the adhesive tapes are always applied at the same point on the carton blank, this leads to an increase in thickness at this location within the stack. As a result, the stack becomes skewed, and, on exceeding a particular degree of inclination, the sheets begin to slip; the resulting stacks are unstable. Moreover, owing to the high thickness, the number of linear meters of adhesive tape, for a given width and given roll dimensions on a roll of adhesive tape, is much lower than for thinner tapes. For the corrugated packaging industry, however, a frequent necessity is to run relatively long production campaigns, meaning either that the line must be halted for changing of the rolls or that a splice must be made on the running line, an operation always associated with a high risk of tearing.
Furthermore, problems may arise during the printing of such cartons, since the different thicknesses of the print substrate produce different printing conditions in the printing operation, and this may result in an uneven printed image.
For the processor of corrugated packaging sheets with tear strips, therefore, there is an interest in using, above all, thin adhesive tapes, in order that such problems do not arise.
One variant involves slitting, and hence weakening, the carton, provided with the tear strip, in the region above the outer edges of the tear strip (known as “liner slitting”). This is shown by
The outer liner is scored superficially beforehand along the desired tear edge, so that on opening it leaves behind a clean tear edge and produces, after opening, a visually appealing display. A disadvantage of this solution is that the detriment to the outer liner causes losses of stability in the z-direction of the carton. The carton gives way preferentially at the detriment location. This phenomenon is measured using the test known as the box compression test.
A consequence of this solution, then, is to reduce the stackability of the made-up cartons.
It is an object of the invention to obtain a marked improvement over the prior art and to provide a solution with which a carton can be torn open, with clean cut edges being produced in the carton, and with the solution causing as little thickening of the carton as possible.
This object is achieved by means of an adhesive tape system as characterized more closely in the main claim. The dependent claims describe advantageous embodiments of the invention. Further encompassed by the concept of the invention are uses of the adhesive tape system of the invention, and a carton furnished with the adhesive tape system.
The invention accordingly provides an adhesive tape system particularly for opening cardboard packaging, consisting of an adhesive tape A furnished on at least one side with an adhesive coating and having a carrier, the carrier having a film and having filaments extending in the longitudinal direction of the carrier, and consisting of an adhesive tape B furnished on at least one side with an adhesive coating and having a film carrier, the adhesive tapes A and B being disposed one above the other.
A filament in the sense of this invention is a bundle of parallel, linear individual fibers/filaments. In the literature these are also often referred to as multifilament. This fiber bundle may optionally be strengthened inherently by torsion, the filaments then being said to have been spun or twisted. The fiber bundle may alternatively be strengthened inherently by entanglement using compressed air or a water jet. In the text below, in a generalizing fashion, the term filament alone is used for all of these embodiments.
The filament may be textured or smooth and locally consolidated or unconsolidated.
The filaments in question may consist of organic or inorganic materials—for example, and preferably, of glass, of carbon, of combinations of both fiber types, of aramid fibers, of polyamide, of drawn polymer fibers such as polyester fibers (such as polyethylene terephthalate), polypropylene fibers, and polyethylene fibers, and additionally the filaments may at least partly be colored, in order to give the carrier greater visual appeal. Colored glass threads or polymer threads in particular are appropriate for this purpose.
The individual filaments then consist preferably of high-strength fibers of low elongation at break.
Mixtures of the various filaments are also possible, furthermore.
The number of attached or inserted filaments is dependent primarily on the particular end use and on the desired maximum tensile force and maximum tensile force elongation of the carrier and hence of the adhesive tape, on its own nature and on the respective strength of the filaments themselves, and may therefore vary within relatively wide limits.
The filaments are preferably continuous filaments. In one advantageous embodiment, all of the filaments are continuous filaments.
The diameters of the filaments are in particular below 60 μm, more preferably between 20 and 45 μm.
The linear density of the filaments is preferably above 10 tex, more preferably above 50 tex.
It has proven advantageous, furthermore, if the linear density is not more than 300 tex, preferably not more than 200 tex, more preferably still not more than 150 tex, and even further not more than 100 tex.
In one preferred embodiment there are between 1 and 30 filaments per centimeter width in the carrier material, more particularly between 1 and 5, more particularly still between 1 and 3, and the filaments, with further preference, are distributed uniformly across the width of the film.
The number of filaments is advantageously at least 3. In further advantageous variants, there are between 3 and 30, more preferably between 3 and 20, very preferably between 3 and 10 filaments present.
It has proven advantageous, moreover, if the filaments are disposed in a ply oriented parallel to the carrier material, or at most in three plies oriented parallel to the carrier material, in a regular disposition.
The filaments in each ply are disposed in parallel alongside one another.
Reference may be made, by way of example, to DE 10 2006 023 935 A1, which discloses a filament adhesive tape of this kind.
The filaments should be firmly joined to the film. This can be done by direct incorporation or insertion of the filaments into the film, by embedment and/or by insertion during the process of manufacturing the film, for example.
Alternatively, the filaments may be joined subsequently to the film, examples including welding or laminating, optionally with a corresponding joining layer.
If the carrier is reinforced exclusively by filaments integrated in the longitudinal direction, the tapes are dubbed monofilament adhesive tapes.
According to a further advantageous embodiment, the carrier, as well as the filaments extending in the longitudinal direction (machine direction), also has filaments which, in accordance with one particularly preferred embodiment, extend in cross direction and/or in diagonal direction. These filaments may have a curved, spiral, zigzag or irregular extent.
To the skilled person here it is clear that the linear density of the filaments must not be too high. The filaments should still be tearable, and more particularly tearable by hand, of course.
In one advantageous development of the subject matter of the invention, the carrier is reinforced by an open laid filament scrim or an open woven filament fabric. In that case it is dubbed a cross-filament adhesive tape.
The carrier in this case consists of a film with a laid filament scrim or woven filament fabric on its bottom face, this scrim or fabric either being applied directly to the film or joined to the film by means of a laminating adhesive.
The adhesive is applied to the side of the film on which the filament scrim or fabric is located.
With further preference, the filament scrim or fabric has a machine-direction tensile strength of at least 50 N/cm and also an elongation at break of less than 20%, preferably less than 15%, more preferably less than 10%.
According to one further advantageous embodiment, the filament scrim or fabric is a weft inserted warp knit. One such is described in EP 1 818 437 A1, for example.
The filament scrim or fabric has a machine-direction tensile strength of preferably at least 100 N/cm, more preferably 200 N/cm, very preferably 500 N/cm.
The filaments used to form the scrim or fabric preferably have a density of 2 and 8 dtex, preferably between 4 and 8 dtex, more preferably 5 dtex.
The scrim/fabric may have been subsequently colored, or may consist of solution-dyed filaments.
According to one further advantageous embodiment of the invention, the filament count in warp direction is at least 4/cm, preferably 6 to 10/cm, more preferably 7/cm and/or the filament count in the weft is at least 1 to 10/cm, preferably 2/cm.
The laminating adhesive optionally present may be selected from the same adhesive systems as those which will be described comprehensively later on.
Shown in a lateral section in
Laminated onto a 35 μm PET film 113 is a WIWK (warp inserted warp knit) fabric made of PET (Diolen) 114, using a laminating adhesive 115.
Shown in a lateral section in
In contradistinction to the carrier of the adhesive tape from
In an alternative embodiment, the carrier consists of a film and also of a binder layer disposed between carrier film and the layer of adhesive, the binder layer comprising untwisted and unentangled individual filaments which have been inserted in the longitudinal direction and which are fully surrounded by the binder layer.
The individual filaments are preferably continuous filaments. In one advantageous embodiment, all of the individual filaments are continuous filaments.
The individual filaments are present ideally in closest spherical packing, with, therefore, no gaps or hardly any gaps between the individual filaments clad with the binder. In one preferred embodiment there are between 400 and 800 individual filaments per centimeter width in the carrier material, more particularly between 500 and 600, very preferably 550.
It has proven advantageous, furthermore, if the individual filaments are disposed regularly in one ply oriented parallel to the film, or at most in three plies oriented parallel to the film, and if the individual filaments have a linear density of 4 to 8 dtex.
In each ply these individual filaments are disposed in parallel alongside one another.
In another advantageous embodiment, the individual filaments are disposed regularly in one ply oriented parallel to the film or at most in five plies oriented parallel to the film, and if the individual filaments have a linear density of 2 to 6 dtex.
Depending on the desired end use, more than five plies of individual filaments are also possible—as the number increases, the thickness of the carrier goes up, but at the same time so does the strength.
As a result of the absence—recognized as advantageous—of twisting and entangling in the parallel arrangement oriented in the longitudinal direction, the length of the individual filaments corresponds almost exactly to the running length of the carrier, and hence to the minimum of the theoretical possible length. Accordingly, any parallel tensile force on the adhesive tape acts directly on each individual filament and at the same time is taken on, as required, by numerous individual filaments. This results in a particularly effective accommodation of force.
As a result of the absence of twisting and entangling, moreover, the individual filaments are able to respond to a nonparallel tensile loading with an individual change in length. This leads to optimum distribution of force across the width of the adhesive tape width.
The binder comprises mixtures based on SBR or acrylate. Preference is given to an aqueous, plasticizer-free, anionic dispersion of an acrylic ester copolymer containing carboxyl groups (Acronal® 500 D).
The binder in one advantageous embodiment is applied at 10 to 30, preferably 10 to 20, very preferably 15 to 17 g/m2 to the film.
For the fixing of the filaments, the binder may additionally take on tasks of a functional layer.
It may act as a primer, namely between the carrier/filament/adhesive interfaces that arise.
It may take on the tasks of a barrier layer—for example, by integration of UV absorbers, the UV protection of the adhesive.
The binder may take the form of a reactively curing binder system, thus having influence or no influence over the adhesive. At the same time, the degree of cure of the binder may be adjusted through the reactive components. Not only adjustable degrees of cure of the binder but also adjustable degrees of cohesion of the adhesive can be achieved by means of migrating crosslinkers.
Lastly, with a view to fibers and film employed, the binder may, for the purpose of achieving an optimum assembly, be modified in the respect of
The latter property is advantageous, for example, in that the color of the adhesive tape can be easily varied. In the case of a transparent film, normally the entire pressure-sensitive adhesive is colored, to give a colored adhesive tape. In accordance with the invention it is sufficient to furnish the binder with the desired color.
As a result of the use of the binder, stock material is produced that is not pressure-sensitively adhesive, and which is easy to handle and to store.
In the binder layer 102 there are in total three plies, 121, 122, and 123, of individual filaments, with the plies 121, 122, and 123 being oriented parallel to the film. Each individual filament here is completely surrounded by the binder 102.
These individual filaments are each disposed in parallel in the plies 121, 122, and 123, with the individual filaments preferably being almost in direct contact with one another.
Reference may be made, by way of example, to DE 10 2005 049 343 A1, which discloses a filament adhesive tape of this kind.
According to one preferred embodiment the film of the adhesive tape A consists
Also suitable as film material are films such as, for example, PA, PU, or PVC. The films themselves may consists in turn of a plurality of individual plies, as for example of plies coextruded to film. The film may be metalized or may be laminated with other layers such as foams), for example.
Polyolefins are preferred, although copolymers of ethylene and polar monomers such as styrene, vinyl acetate, methyl methacrylate, butyl acrylate, or acrylic acid are also included. It may be a homopolymer such as HDPE, LDPE, MDPE or a copolymer of ethylene a further olefin such as propene, butene, hexene, or octene (for example, LLDPE, VLLDE). Also suitable are polypropylenes (for example, polypropylene homopolymers, random polypropylene copolymers, or polypropylene block copolymers).
The film may be unoriented. With preference in accordance with the invention it is possible as films for monoaxially and biaxially oriented films. To be used. Monoaxially oriented polypropylene, for example, is notable for its very high tensile strength and low stretch in machine direction.
Particularly preferred are films based on polyesters such as polyethylene terephthalate.
The film preferably has a thickness of 10 μm to 100 μm, more preferably 19 to 30 μm. The film may be colored and/or transparent.
The combination of film with integrated and/or attached filaments preferably has a stretch of less than 10% under a load of 10 N/cm, and also, preferably, a basis weight of less than 350 g/m2, preferably less than 200 g/m2, very preferably less than 150 g/m2.
With further preference the film with integrated and/or attached filaments exhibits a maximum tensile force elongation of less than 25%, preferably less than 15%, more preferably less than 10%.
According to one alternative variant, the adhesive tape A may also be furnished adhesively on both sides. The adhesives in this case may be different, but they may also be identical.
It is within the concept of the invention for the carriers of the adhesive tapes A and B to be identical. Preferred, therefore, is an embodiment in which carrier of the adhesive tape A and the carrier of the adhesive tape B have a film and have filaments extending in the longitudinal direction of the carrier, with the two films being able, with further preference, to be identical. In the case of this embodiment it is additionally preferred for the two adhesive tapes to have the identical width.
The film carrier of the adhesive tape B may consist of a polyolefin film which is oriented monoaxially in the longitudinal direction and which comprises a mixture of an olefinic polymer and a polar nonolefinic polymer.
In the film the fraction of polar nonolefinic polymer in the mixture is more preferably in the range from 5 to 50 wt %, preferably 20 to 30 wt %.
To achieve high tensile strengths, high stresses at 10% strain, and high tear propagation resistance, the conditions in the drawing operation ought to be selected such that the draw ratio is the maximum technically feasible ratio for each film. In accordance with the invention the machine-direction draw ratio is preferably at least 1:4.5, more preferably at least 1:6.
A draw ratio of, for example, 1:6 indicates that a primary film segment 1 m long becomes a drawn film segment 6 m long. The draw ratio is oftentimes also termed the ratio of the linear speed prior to orientation to the linear speed after orientation. Here, it is the first definition that is used.
In one preferred version of the invention, the film has the following properties:
Strength values are calculated by dividing the width-based force values by the thickness. Where the strength values are determined on the adhesive tape, the thickness taken as a basis is not the total thickness of the adhesive tape, but only that of the carrier film.
As shown by experiments with experimental constructions from Zwick, these constructions being known to the skilled person, it is practically impossible to sever the film in the cross direction. In the sample for investigation, the film edge is impaired by an incision in cross direction. When tension is then exerted, the tear does not propagate in the cross direction but is instead diverted into the machine or longitudinal direction.
The thickness of the carrier film is preferably between 15 and 200 μm, more preferably between 30 and 140 μm, very preferably between 50 and 100 μm.
A thickness of up to 200 μm may be selected when the deviations in thickness brought about by the adhesive tape in the carton blanks or cartons for stacking one atop another are of minor importance. Preferred thicknesses are not more than 140 μm.
The olefinic polymer is a homopolymer or copolymer of olefins such as ethylene, propylene, or butylene. The term copolymer is to be understood here to include terpolymers.
The olefinic polymer comprises preferably at least 50 wt % of propylene.
Particularly suitable film raw materials are commercially available polypropylene homopolymers or polypropylene copolymers, including the block (impact) polymers and random polymers.
The melt indices of the stated polymers must be situated within the range that is suitable for flat film extrusion. This range ought to be between 0.3 and 15 g/10 min, preferably in the range of 0.8 and 5 g/10 min (measured at 230° C./2.16 kg).
The polypropylene is preferably predominantly isotactic in structure. The flexural modulus ought to be at least 1000 MPa, preferably at least 1500 MPa, very preferably at least 2000 MPa.
A polar nonolefinic polymer comprehends all polymers which
The polar nonolefinic polymer is selected preferably from the group consisting of polyesters, polyamides, polyurethanes, polyoxymethylene, polyarylene sulfides, and polyarylene oxides. Semicrystalline polymers are particularly preferred. In accordance with one particularly advantageous embodiment of the invention, polybutylene terephthalate and/or polyoxymethylene are selected as polar nonolefinic polymer.
The polyolefin with polar modification is selected preferably from the group of the copolymers of olefins with vinyl esters, methacrylic acid, and acrylic acid, more preferably ethylene-vinyl acetate copolymers and ethylene-(meth)acrylate copolymers and their esters, or from the group of the graft polymers with an unsaturated organic acid, more preferably a maleic anhydride-, methacrylic acid, or acrylic acid-grafted polyolefin, the fraction of polar-modified polyolefin in the mixture being preferably in the range from 0.2 to 10 wt %.
The polymers of the film can be used in pure form or as a blend with additives such as antioxidants, light stabilizers, antiblocking agents, lubricants, and processing assistants, fillers, dyes, pigments, blowing agents, or nucleating agents.
The film may consist of a matrix of olefinic polymer in which fibers of the polar nonolefinic polymer are embedded, said fibers preferably having a diameter of 0.01 to 50 μm, more preferably 0.1 to 20 μm.
The preferred operation for producing the film, or the adhesive tape A produced using the film, includes the following steps:
The film may be a single- or multilayer film, being preferably multilayer, more preferably of the type ABC, where B comprises the mixture described and A and C consist wholly or predominantly of polyolefinic polymer. Through coextrusion it is possible to prevent deposition during orientation of the film, and problems in the course of coating with release, primer, or adhesive.
The film may have been modified by laminating, embossing, or radiation treatment.
The film may have been given surface treatments. These are, for example, to promote adhesion, corona treatment, flame treatment, fluorine treatment, or plasma treatment, or coatings of solutions or dispersions, or liquid, radiation-curable materials. Further possible coatings are printed coatings and nonstick coatings, as for example those of crosslinked silicones, acrylates (for example, Primal® P 376 LO), polymers with vinylidene chloride or vinyl chloride as monomer, or stearyl compounds such as polyvinyl stearylcarbamate of the chromium stearate complexes (for example, Quilon® C), or reaction products of maleic anhydride copolymers and stearylamine.
In another embodiment of the invention, the film carrier of the adhesive tape B preferably consists of polyethylene, polypropylene, monoaxially or biaxially oriented polypropylene, polyester, PA, PVC, or other films; particular preference is given to MOPP.
The thickness of the carrier film of the adhesive tape B is preferably between 15 and 200 μm, more preferably between 30 and 140 μm, very preferably between 50 and 70 μm.
A thickness of up to 200 μm may be selected when the deviations in thickness brought about by the adhesive tape in the carton blanks or cartons to be stacked one atop another are of minor importance. Thicknesses of not more than 70 μm are preferred.
With further preference, the film carrier has a tensile strength of 200 N/mm2 to 300 N/mm2, more preferably 220 N/mm2 to 260 N/mm2, very preferably 240 N/mm2, and/or a stretchability of less than 35%.
The adhesive tapes A and B can be produced using all known adhesive systems. Besides adhesives based on natural or synthetic rubber, use may be made in particular of polyacrylate adhesives, preferably a pressure-sensitive acrylate hotmelt adhesive. Silicone adhesives are also possible.
The adhesives in the adhesive tapes A and B may be different. It is preferred for the same adhesive to be used in each case.
The coating thickness with adhesive lies preferably in the range from 18 to 50 g/m2, more preferably 22 to 29 g/m2 (corresponding approximately to a thickness of 18 to 50 μm, more preferably 22 to 29 μm).
The adhesive is preferably a pressure-sensitive adhesive, in other words an adhesive which even under relatively weak applied pressure allows a durable bond to virtually all substrates and which after use can be detached from the substrate again substantially without residue. At room temperature, a pressure-sensitive adhesive is permanently tacky, thus having a sufficiently low viscosity and a high touch-tack, so that it wets the surface of the respective adhesive base even under slight applied pressure. The bondability of the adhesive derives from its adhesive properties, and the redetachability from its cohesive properties.
The carriers are coated with pressure-sensitive adhesive on one or both sides, preferably one side, from solution or dispersion or in 100% form (for example, from the melt), or by coextrusion.
For optimization of the properties, the self-adhesive composition employed may have been blended with one or more additives such as tackifiers (resins), plasticizers, fillers, pigments, UV absorbers, light stabilizers, aging inhibitors, crosslinking agents, crosslinking promoters, or elastomers.
Suitable elastomers for blending are, for example, EPDM rubber or EPM rubber, polyisobutylene, butyl rubber, ethylene-vinyl acetate, hydrogenated block copolymers of dienes (for example, by hydrogenation of SBR, cSBR, BAN, NBR, SBS, SIS, or IR; such polymers are known, for example, as SEPS and SEBS), or acrylate copolymers such as ACM.
Tackifiers are, for example, hydrocarbon resins (for example, from unsaturated C5 or C7 monomers), terpene-phenolic resins, terpene resins from raw materials such as α- or γ-pinene, aromatic resins such as indene-coumarone resins, or resins of styrene or α-methylstyrene such as rosin and its derivatives, such as disproportionated, dimerized, or esterified resins, in which case glycols, glycerol or pentaerythritol may be used. Particular suitability is possessed by resins stable toward aging, with no olefinic double bond, such as hydrogenated resins, for example.
Suitable fillers and pigments are, for example, carbon black, titanium dioxide, calcium carbonate, zinc carbonate, zinc oxide, silicates, or silica.
Suitable UV absorbers, light stabilizers, and aging inhibitors for the adhesives are those as listed in this specification for the stabilizing of the film.
Suitable plasticizers are, for example, aliphatic, cycloaliphatic, and aromatic mineral oils, diesters or polyesters of phthalic acid, trimellitic acid, or adipic acid, liquid rubbers (for example nitrile rubbers or polyisoprene rubbers), liquid polymers of butene and/or isobutene, acrylic esters, polyvinyl ethers, liquid resins and plasticizer resins based on the raw materials for tackifying resins, wool wax and other waxes, or liquid silicones.
Crosslinking agents are, for example, phenolic resins or halogenated phenolic resins, melamine resins and formaldehyde resins. Suitable crosslinking promoters are, for example, maleimides, allyl esters such as triallyl cyanurate, and polyfunctional esters of acrylic and methacrylic acid.
One preferred embodiment comprises a pressure-sensitive adhesive composed of synthetic rubber, hydrocarbon resin, and antioxidant.
The adhesive may have been applied in longitudinal direction in the form of a strip with a width lower than that of the carrier film of the adhesive tape. Depending on the particular utility, it is also possible for two or more parallel strips of the adhesive to have been coated on the carrier film.
The free top face of the adhesive tapes A and B, furnished on one side with adhesive, may have been provided with a release agent, also called parting agent.
Suitable release agents encompass release systems of surfactant kind, based on long-chain alkyl groups such as stearyl sulfosuccinates or stearyl sulfosuccinamates, but also polymers, which may be selected from the group consisting of polyvinyl stearylcarbamates, polyethyleneiminestearylcarbamides, chromium complexes of C14 to C28 fatty acids, and stearyl copolymers, as are described, for example, in DE 28 45 541 A. Likewise suitable are release agents based on acrylic polymers with perfluorinated alkyl groups, silicones, or fluorosilicone compounds, based for example on poly(dimethylsiloxanes). With particular preference the release layer comprises a silicone-based polymer. Particularly preferred examples of such release-active polymers based on silicone include polyurethane- and/or polyurea-modified silicones, preferably organopolysiloxane/polyurea/polyurethane block copolymers, more preferably those as described in example 19 of EP 1 336 683 B1, very preferably anionically stabilized, polyurethane- and urea-modified silicones having a silicone weight fraction of 70% and an acid number of 30 mg KOH/g. The use of polyurethane-modified and/or urea-modified silicones has the effect that the products of the invention combine optimized aging resistance and universal writability with an optimized release behavior. In one preferred embodiment of the invention the release layer comprises 10 to 20 wt %, more preferably 13 to 18 wt %, of the release-active constituent.
The general expression “adhesive tape” for the purposes of this invention encompasses all sheetlike structures such as two-dimensionally extended films or film sections, tapes with extended length and limited width, tape sections and the like, and also, lastly, diecuts or labels.
In the simplest embodiment of the invention, the adhesive tapes A and B are laminated to one another and so form a tear-open system which may be used on film packaging, paper packaging, card packaging, or carton packs.
The invention is elucidated in more detail below with a number of figures, without thereby wishing to subject the invention to unnecessary restriction.
a shows how the disposition of the adhesive tapes to one another can be selected in any desired way. Each of the adhesive tapes 1, 2 consists of a carrier 11, 21, on each of which an adhesive 12, 22 is applied.
The adhesive tape B may be laminated by the adhesive-free side of the film carrier 21 onto the adhesive 12 of the adhesive tape A (left-hand diagram). In this case, the uncovered regions of the adhesive 12 and also the adhesive 22 of the adhesive tape B ensure the hold of the tear-open system on the selected substrate.
It would, however, also be possible for the adhesive tape B to be laminated onto the adhesive tape A in such a way that the adhesive 22 lies directly on the adhesive 11 of the adhesive tape A.
In the right-hand diagram in
b shows that the inventive concept also encompasses the embodiment wherein the adhesive tape B is disposed on the adhesive tape A such that the carriers 11, 21 finish flush at the edges.
The tear-open system of the invention also functions in this case.
A preferred embodiment is that in which the adhesive tape B is applied on the adhesive tape A with an offset, in other words offset inwardly in relation to the machine direction of the two adhesive tapes A and B. For a perpendicular projection into the plane of the adhesive tape A, therefore, the two long edges LB1, LB2 of the adhesive tape B (i.e., the edges which extend in the machine direction) always lie between the two long edges LA1, LA2 of the adhesive tape A. In
In the case of the embodiment according to
According to a preferred embodiment of the invention, therefore, the adhesive tapes A and B are disposed one above another in such a way that the two long edges LB1, LB2 of the adhesive tape B (i.e., the edges which extend in the machine direction), on vertical projection into the plane of the adhesive tape A, lie on or between the two long edges LA1, LA2 of the adhesive tape A, or at least on one of the two long edges LA1, LA2 of the adhesive tape A.
Particularly preferred are the embodiments shown in
In
In the carton 4 there is a kisscut score that produces two grip tabs 43 and 44. The kisscut score consists of two pairs of two limbs in V-shape disposition, 41, 42, 41a, and 42a, with the two limbs 41, 42, 41a, 42a of each pair not intersecting at the potential intersection point. The limbs 41, 42, 41a, 42a are punched right through the carton 4 and the adhesive tape A. Moreover, the connecting line 45 which connects the end points of the limbs 41, 42, 41a, 42a to one another is punched right through the carton 4, the adhesive tape A, and the adhesive tape B.
To open the carton 4, one of the two grip tabs 43, 44, the grip tab 43 for example, is gripped and folded upward. The fully punched-through limbs 41a, 42a produce a tear strip, whose width corresponds to the distance between the ends of limbs 41a, 42a that run toward one another. The width of the tear strip is indicated by the parallel tear lines RL. When the grip tab 43 is pulled in the direction of the arrow shown, the tear-open system parts along the lines RL. This resultant tear strip consists of the severed carton 4, the adhesive tape B, and the parted adhesive tape A.
Owing to the outstanding properties of the carrier described, the tear strip does not taper either during opening, and so the tear strip severs the entire carton.
By pulling on the other grip tab 44, likewise in the direction indicated by the arrow, a second tear strip is produced.
The tear-open system is used with further preference to join two packs (or other structures), two cartons for example, to one another temporarily. This is shown in
The tear-open possibility described comprehensively in
In one variant only the adhesive tape A is utilized to join two packs or other bodies to one another.
The adhesive tape system is preferably used as tear strip on a carton 4 consisting of an outer liner 46 and an inner liner 47, there being disposed between the liners 46 and 47 at least one corrugation 48 of card, the adhesive tape A being applied on the inside of the outer liner 46 and the adhesive tape B being applied on the outside of the inner liner 47, so that the adhesive tape B is disposed beneath the adhesive tape A. An exemplary embodiment of this use is shown in
Between the two liners 46 and 47 there is a corrugation 48, with the regions of the carton 4 that are not visible being indicated by dots.
The adhesive tape B is bonded on the outside of the inner liner 47, with the further course of the adhesive tape B being indicated with dots and dashes.
The adhesive tape A is bonded on the inside of the outer liner 46, with the further course of the adhesive tape A being indicated with dashes.
As already indicated in
The other variants of the tear-open system that are shown in
With further preference, the adhesive tape A and the adhesive tape B are applied in the form of a self-contained line on the body of the carton or in the form of two or more contained lines at different heights on the body.
The line formed by the adhesive tapes preferably lies in a plane which is oriented parallel to the base of the upright body.
The line may also surround a corner of the body in such a way that after the tear-open procedure, a tetrahedral part is removed from the rest of the body.
In one variant of the invention, the adhesive tapes do not form a self-contained line but instead take out a side wall of the carton. If the tear-open system is then removed, the last wall remains intact and is able thus to take on a hinge function, especially if the wall has a fold in the continuation of the line are. In this way a lid is formed, which can be folded open and closed via the hinge.
The adhesive tape A and the adhesive tape B are preferably applied at right angles to the corrugation of the carton.
In accordance with a further preferred embodiment, on the carton there is a kisscut score which completely severs the adhesive tape A and, preferably, the underlying carton and which serves as a grip tab for the tear strip when the carton is torn open.
The adhesive tape B lies beneath the grip tab and is preferably likewise severed by the kisscut score. When the grip tab is gripped, the adhesive tape B of the resulting tear strip is located on the underside of the grip tab.
The kisscut score also defines the later width of the tear strip.
To tear open a pack equipped with the adhesive tape system of the invention, preferably the entire width of the adhesive tape B is used, whereas only a partial region of the adhesive tape A is preferably used for the tear strip.
The width of the adhesive tape A is preferably between 10 and 50 mm, more preferably between 12 and 25 mm.
The width of the adhesive tape B is preferably between 2 and 10 mm, more preferably between 3 and 6 mm.
The width selected for the adhesive tape B is preferably lower than the width of the adhesive tape A, and more particularly is in a ratio between 1:2 and 1:4. Also possible, however, is the embodiment in which the widths of the adhesive tapes A and B are identical.
In accordance with one preferred embodiment of the invention, the tear strip formed from the adhesive tape system has a width of 2 to 10 mm, more preferably between 3 and 6 mm.
The kisscut score may be executed in the form of two limbs in a V-shape arrangement which do not contact one another at the potential intersection point.
With further preference, a diecut line joins the other two ends of the limbs, producing the form of a triangle with its apex missing. This triangle forms the grip tab on the tear strip.
In order to produce a suitable grip tab, the adhesive tape A must in some form or another be severed in the cross direction, in other words against the orientation. To define the width of the tear strip—if the tear strip is to be disposed centrally in the adhesive tape A—it is necessary for two incisions in longitudinal direction to sever the adhesive tape A. For example, the adhesive tape A could be punctured at two points whose connecting line is incised into the adhesive tape A (preferably this connecting line is aligned at right angles to the long edge). If the tear strip is to be formed in the marginal region of the adhesive tape A, a single incision is sufficient.
In this way, the preferred embodiment of the invention is produced, namely that in which the tear strip resulting from the adhesive tape A, among other components, is lower in width than the adhesive tape A.
The grip tab need not necessarily be diecut. It is also possible for the grip tab to be produced using a blade, by at least partly severing the adhesive tape A in the cross direction, and introducing, at the parting line, two notches, pointing substantially in machine direction, into the adhesive tape A, with the distance between the notches defining the width of the tear strip. The notches and the incision define a grip tab region that forms the beginning of the tear strip. In this case it should be ensured that the adhesive tape B as well is severed at the same time.
For example, the adhesive tape system described is bonded during corrugated card production on the corrugated card line. In further steps, the sheet formed after the corrugated card line is made up further into a box. On the box at least one kisscut score is made, allowing a grip tab to be extracted from the adhesive tape system for the purpose of subsequent opening of the pack. This grip tab is pulled, and the grip tab strip that forms separates the card ply located directly above it from the box during the opening process.
Further encompassed by the concept of the invention is a carton consisting of an outer liner and an inner liner, there being disposed between the liners at least one corrugation of card, furnished with an adhesive tape system of the invention, the adhesive tape A being applied on the inside of the outer liner and the adhesive tape B being applied on the outside of the inner liner, so that the adhesive tape B is disposed beneath the adhesive tape A.
Especially with a synthetic rubber-based adhesive that exhibits sufficient bond strength and high tack, the adhesive tape A displays effective bonding on a variety of paper substrates.
Owing to the specific carrier, tears therein that start from the kisscut score are propagated, surprisingly, in straight lines parallel to the machine direction (x-direction).
A further surprise is that the carrier not only does not tear further transverse to the direction of orientation, but instead reliably supports the continued tearing of the film in machine direction. This means that there is no tapering in the y-direction (in transverse direction of the strip) or else in z-direction (the direction that defines the direction of the carrier). As a result, tear continuation is possible only in the x-direction (longitudinal or machine direction). Furthermore, continuous tear propagation in the x-direction is easy to accomplish manually, in addition to the severing of the corrugated card.
Possibly there is a slight tapering or broadening in the cross direction, but preferably not more than 5 parts per million, based on the length.
The necessary strengths can be achieved with significantly reduced thicknesses of material, meaning that the overall thickness of adhesive tape can be reduced by up to 50% as compared with the Adalis system described earlier. This leads to less wear on the printing, improved stability in carton stacking, and enables greater running lengths of the adhesive tape rolls—that is, larger manufacturing campaigns can be run readily without interruption to the operation.
Likewise in particular with a synthetic rubber-based adhesive which exhibits sufficient bond strength and a high tack, adhesive tape B displays effective bonding to a variety of paper substrates.
Furthermore, the film carrier has a high tensile strength, since the adhesive tape is required to accommodate the primary load during opening of the carton, and must not tear. Furthermore, the carrier exhibits a low stretch, more particularly a stretchability of less than 35%, since otherwise it stretches too greatly under the prevailing loads.
The invention is elucidated in more detail with a number of examples, without any intention that the invention should be restricted thereby in any way whatsoever.
The measurements are conducted under test conditions of 23±1° C. and 50±5% relative humidity.
The tensile elongation behavior of the adhesive tape is determined on test specimens (rectangular test strips 100 mm long and 15 mm wide) in accordance with DIN EN 14410:2003 527-3/2/300, with a test velocity of 300 mm/min, a clamped-in length of 100 mm, and a pre-tensioning force of 0.3 N/cm, with specimens being cut to shape with sharp blades for the determination of the data.
Unless indicated otherwise, the tensile elongation behavior is tested in machine direction (MD). The force (tensile strength) is expressed in N/strip width or N/mm2, and the elongation at break in %. The test results, especially the elongation at break (breaking stretch), must be statistically ensured by means of five measurements.
For the measurement of the bond strengths, test strips 19 mm wide were adhered without bubbles to a finely abraded (emery paper with FEPA 240 grade abrasive) plate made of stainless steel, and were pressed on using a rubber-clad 2 kg roller, with a speed of 10 mlmin. The steel plate and the protruding end of the adhesive tape were then clamped into the ends of a tensile testing machine in such a way as to produce a peel angle of 180°. The adhesive tape was peeled from the steel plate at a speed of 300 mm/min. The bond strength is stated in N/cm.
The holding power indicates the bonding strength for a loading force acting parallel to the bonded tape. It is the time measured until a loaded adhesive tape shears off completely from a steel plate.
To determine the HP values, a test strip 19 mm wide is adhered to a pretreated steel plaque in such a way as to give a bond area of 19×20 mm2. By means of a clip, a 1 kg weight is suspended from the protruding end of the adhesive tape, thus transmitting a vertical tension force of 5.15 N per 1 cm tape width.
The unit of the holding power is minutes. Where there is a “>” sign before the values, this means that the measurements were discontinued after this time, since no shearing at all was apparent at that point.
This is determined in accordance with DIN 53370.
PP block copolymer, MFI 1.5 g/10 min, not nucleated, flexural modulus 1280 MPa (Dow Chemical)
PP homopolymer, MFI 6 g/10 min, flexural modulus 2150 MPa, contains an α-nucleating agent (Borealis)
PE-LLD, MFI 2 g/10 min (Dow Chemical)
PS-HI, MFI 3 g/10 min, flexural modulus 2200 MPa (Dow Chemical)
EVAL ethylene content 48 mol %, MFI 6.4 g/10 min, flexural modulus 2800 MPa (EVAL Europe)
PP-g-MA, metallocene polypropylene wax grafted with maleic anhydride (Clariant)
Hostaform C9021 natural:
POM, MFI 8 g/10 min, flexural modulus 2800 MPa (Ticona)
Celanex 2002-2 natural:
PBT, MFI 20, flexural modulus 2500 MPa (Ticona)
Advantageous embodiments of the adhesive tape of the invention are described below by means of examples, without wishing to restrict the invention unnecessarily thereby.
The adhesive tape A is 25 mm wide and consists of a 19 μm carrier film of polyethylene terephthalate which is reinforced with a weft inserted warp knit (WIWK).
The WIWK has
The WIWK is joined to the film by a laminating adhesive, the adhesive being applied at 10 g/m2.
The film is coated on the top face with 0.07 g/m2 carbamate release, and dried.
The adhesive is mixed in the melt from 42 wt % SIS elastomer, 20 wt % pentaerythritol ester of hydrogenated rosin, 37 wt % a C5 hydrocarbon resin having an R&B value of 85° C., and 1 wt % Irganox® 1010 antioxidant, and the mixture is applied to the underside of the film at 50 g/m2 at 150° C. using a nozzle.
A BS to steel of 6 N/cm and a shear strength of greater than 3000 minutes are obtained.
The elongation at break of the adhesive tape is less than 40%, the tensile strength more than 80 N/cm.
The film carrier of the adhesive tape B is produced as follows:
The raw materials are compounded and pelletized. The pellets are supplied to a single-screw extrusion system. The film carrier for the adhesive tape B is produced on this single-screw extrusion system, with a flat die having a flexible die lip, in a layer, followed by a chillroll station and a single-stage short-gap drawing system.
Dow 7C06, Celanex 2002-2 natural, and Licocene PP MA 7452 GR TP are mixed in a ratio of 15:4:1 and the mixture is extruded. The die temperature is 230° C. Chillroll temperatures and drawing roll temperatures are set so as to maximize the crystallinity of the film before and after drawing. The draw ratio is 1:5.
The film is coated on the top face with 0.05 g/m2 carbamate release, and dried.
The adhesive is mixed in the melt from 42 wt % SIS elastomer, 20 wt % pentaerythritol ester of hydrogenated rosin, 37 wt % a C5 hydrocarbon resin having an R&B value of 85° C., and 1 wt % Irganox® 1010 antioxidant, and the mixture is applied to the underside of the film, at 25 g/m2 at 150° C. using a nozzle.
A BS to steel of 6 N/cm and a shear strength of greater than 3000 minutes are obtained.
The adhesive tapes A and B are applied, as described in accordance with the invention, to a carton composed of a 2.30 double corrugation as per RAL-GZ 492 (DEUTSCHES INSTITUT FÜR GÜTESICHERUNG UND KENNZEICHNUNG E.V.).
Tearing the carton open produces a clean edge and only a slight deterioration to the outer liner.
The carrier for the adhesive tape A from example 1 is used.
The film carrier of the adhesive tape B is a MOPP film.
The film is coated on the top face with 0.05 g/m2 silicone release, and dried.
The adhesive is mixed in the melt from 42 wt % SIS elastomer, 20 wt % pentaerythritol ester of hydrogenated rosin, 37 wt % a C5 hydrocarbon resin having an R&B value of 85° C., and 1 wt % Irganox® 1010 antioxidant, and the mixture is applied to the underside of the film, at 25 g/m2 at 150° C. using a nozzle.
A BS to steel of 6 N/cm and a shear strength of greater than 3000 minutes are obtained.
The adhesive tapes A and B are applied, as described in accordance with the invention, to a carton composed of a 2.30 double corrugation as per RAL-GZ 492 (DEUTSCHES INSTITUT FÜR GÜTESICHERUNG UND KENNZEICHNUNG E.V.).
Tearing the carton open produces a clean edge and only a slight deterioration to the outer liner.
The carrier for the adhesive tape A from example 1 is used.
The film carrier for the adhesive tape B from example 1 is used, but with a width of 15 mm.
The adhesive tapes A and B are applied, as described in accordance with the invention, to a carton composed of a 1.40 single corrugation as per RAL-GZ 492 (DEUTSCHES INSTITUT FÜR GUTESICHERUNG UND KENNZEICHNUNG E.V.).
Tearing the carton open produces a clean edge and only a slight deterioration to the outer liner.
The adhesive tape A is 25 mm wide and consists of a 19 μm carrier film of polyethylene terephthalate which is reinforced with a weft inserted warp knit (WIWK).
The WIWK has
The WIWK is joined to the film by a laminating adhesive, the adhesive being applied at 10 g/m2.
The first adhesive is mixed in the melt from 42 wt % SIS elastomer, 20 wt % pentaerythritol ester of hydrogenated rosin, 37 wt % a C5 hydrocarbon resin having an R&B value of 85° C., and 1 wt % Irganox® 1010 antioxidant, and the mixture is applied to the underside of the film at 50 g/m2 at 150° C. using a nozzle.
A second adhesive, identical to the first, is likewise mixed in the melt and applied to the top face of the film, at 50 g/m2, at 150° C. using a nozzle.
A BS to steel of 6 N/cm and a shear strength of greater than 3000 minutes (top and bottom faces) are obtained.
The elongation at break of the adhesive tape is less than 40%, the tensile strength more than 80 N/cm.
The film carrier of the adhesive tape B is produced as follows:
The raw materials are compounded and pelletized. The pellets are supplied to a single-screw extrusion system. The film carrier for the adhesive tape B is produced on this single-screw extrusion system, with a flat die having a flexible die lip, in a layer, followed by a chillroll station and a single-stage short-gap drawing system.
Dow 7C06, Celanex 2002-2 natural, and Licocene PP MA 7452 GR TP are mixed in a ratio of 15:4:1 and the mixture is extruded. The die temperature is 230° C. Chillroll temperatures and drawing roll temperatures are set so as to maximize the crystallinity of the film before and after drawing. The draw ratio is 1:5.
The film is coated on the top face with 0.05 g/m2 carbamate release, and dried.
The adhesive is mixed in the melt from 42 wt % SIS elastomer, 20 wt % pentaerythritol ester of hydrogenated rosin, 37 wt % a C5 hydrocarbon resin having an R&B value of 85° C., and 1 wt % Irganox® 1010 antioxidant, and the mixture is applied to the underside of the film, at 25 g/m2 at 150° C. using a nozzle.
A BS to steel of 6 N/cm and a shear strength of greater than 3000 minutes are obtained.
The adhesive tapes A and B are applied, as described in accordance with the invention, to a carton composed of a 2.30 double corrugation as per RAL-GZ 492 (DEUTSCHES INSTITUT FÜR GÜTESICHERUNG UND KENNZEICHNUNG E.V.).
Tearing the carton open produces a clean edge and only a slight deterioration to the outer liner.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10 2011 082 882.6 | Sep 2011 | DE | national |
| 10 2011 089 331.8 | Dec 2011 | DE | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2012/066946 | 8/31/2012 | WO | 00 | 3/18/2014 |
