Claims
- 1. A method of restoring a carious tooth, comprising:
- applying to the wall surface of a cavity in a carious tooth an adhesive composition which comprises 100 parts by weight of a polymerizable monomer comprising (a) 1.5 to 50 parts by weight of a compound represented by one of formulas I and II: ##STR155## where R.sub.1 and R.sub.1 ' each stand for hydrogen or a methyl group, R.sub.2 stands for a divalent organic residue having 4 to 40 carbon atoms, X.sub.1 and X.sub.2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R.sub.3 stands for a group of the formula ##STR156## having 6 to 40 carbon atoms, where R.sub.4 and R.sub.4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom, or a hydroxyl, amino or carboxyl group, and b is an integer of 0 to 3, a plurality of R.sub.4 ' being the same or different, at least one of R.sub.4 and R.sub.4 ' having at least three carbon atoms, and Z stands for --O--, --COO-- or --NH--, and (b) 50 to 98.5 parts by weight of a vinyl monomer copolymerizable with said compound, and 0.01 to 20 parts by weight of a curing agent; and
- filling said cavity with a dental filling composition comprising a polymerizable monomer, a filler and a curing agent.
- 2. A method as set forth in claim 1, wherein said compound is a compound represented by formula I.
- 3. A method as set forth in claim 2, wherein R.sub.2 stands for (a) a hydrocarbon group having 4 to 30 carbon atoms which is unsubstituted or substituted by a halogen atom or a hydroxyl, amino or carboxyl group, or (b) a group having 4 to 30 carbon atoms, and comprising two to seven hydrocarbon groups bonded to one another by a linkage selected from the group consisting of ether, thioether, ester, thioester, thiocarbonyl, amide, urethane, carbonyl and sulfonyl linkages, each of said two to seven hydrocarbon group having 1 to 29 carbon atoms, being unsubstituted or substituted by a halogen atom, or a hydroxyl, amino or carboxyl group, wherein at least one of said two to seven hydrocarbon groups having at least three carbon atoms.
- 4. A method as set forth in claim 3, wherein R.sub.2 is represented by the formula --R.sub.5 --Y--R.sub.5 ')--.sub.c where R.sub.5 and R.sub.5 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom, or a hydroxyl, amino or carboxyl group, at least one of R.sub.5 and R.sub.5 ' having at least three carbon atoms, Y stands for ##STR157## and c is an integer of 1 to 6, a plurality of R.sub.5 ' being the same or different.
- 5. A method as set forth in claim 3, wherein R.sub.2 is represented by the formula ##STR158## where Y and and Y' each stand for ##STR159## d is an integer of 0 to 3, and R.sub.6 and R.sub.6 ' each stand for a hydrocarbon group having 1 to 27 carbon atoms, which is unsubstituted or substituted by a halogen atom or a hydroxyl, amino or carboxyl group.
- 6. A method as set forth in claim 3, wherein X.sub.1 and X.sub.2 both stand for --O--, and a is 1.
- 7. A method as set forth in claim 4, wherein X.sub.1 and X.sub.2 both stand for --O--, and a is 1.
- 8. A method as set forth in claim 5, wherein X.sub.1 and X.sub.2 both stand for --O--, and a is 1.
- 9. A method as set forth in claim 6, wherein R.sub.2 is represented by the formula ##STR160## where R.sub.7 and R.sub.7 ' each stand for a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms, which is unsubstituted or substituted by a halogen atom.
- 10. A method as set forth in claim 6, wherein R.sub.2 is represented by the formula ##STR161## where R.sub.8 stands for hydrogen or a methyl group, and R.sub.9 stands for a hydrocarbon group having 3 to 28 carbon atoms, which is unsubstituted or substituted by a halogen atom.
- 11. A method as set forth in claim 6, wherein R.sub.2 is represented by the formula ##STR162## where R.sub.10 stands for a hydrocarbon group having 1 to 12 carbon atoms, which is unsubstituted or substituted by a halogen atom, and e is 0 or 1.
- 12. A method as set forth in claim 6, wherein R.sub.2 is represented by the formula --CH.sub.2 --.sub.f where f is an integer of 4 to 20.
- 13. A method as set forth in claim 6, wherein R.sub.2 is represented by the formula ##STR163## where h is an integer of 1 to 5, and i is an integer of 0 to 3.
- 14. A method as set forth in claim 6, wherein R.sub.2 is represented by the formula ##STR164##
- 15. A method as set forth in claim 6, wherein R.sub.2 is represented by the formula ##STR165## where R.sub.11 stands for a hydrocarbon group having 2 to 6 carbon atoms, which is unsubstituted or substituted by a halogen atom.
- 16. A method as set forth in claim 6, wherein R.sub.2 is represented by the formula: ##STR166##
- 17. A method as set forth in claim 10, wherein R.sub.2 is represented by the formula ##STR167## where g is an integer of 1 to 20, or the formula ##STR168##
- 18. A method as set forth in claim 12, wherein R.sub.2 is represented by the formula --CH.sub.2 --.sub.j where j is an integer of 5 to 12.
- 19. A method as set forth in claim 14, wherein R.sub.2 is represented by the formula ##STR169##
- 20. A method as set forth in any of claims 9 to 19, wherein R.sub.1 stands for a methyl group.
- 21. A method as set forth in claim 7, wherein R.sub.2 is represented by the formula ##STR170## where R.sub.12 stands for a hydrocarbon group having 1 to 12 carbon atoms, which is unsubstituted or substituted by a halogen atom.
- 22. A method as set forth in claim 21, wherein Y stands for --O-- or --COO--.
- 23. A method as set forth in claim 7, wherein R.sub.2 is represented by the formula ##STR171## where R.sub.13 and R.sub.13 ' each stand for a hydrocarbon group having 1 to 6 carbon atoms, which is unsubstituted or substituted by a halogen atom.
- 24. A method as set forth in claim 7, wherein R.sub.2 is represented by the formula: ##STR172## where R.sub.14 and R.sub.14 ' each stand for hydrogen or a methyl group, and k and k' are both a real number greater than 1, and up to and including 3.
- 25. A method as set forth in claim 7, wherein R.sub.2 is represented by the formula ##STR173## where r and r' are both an integer of 2 to 6.
- 26. A method as set forth in claim 23, wherein R.sub.2 is represented by the formula: ##STR174##
- 27. A method as set forth in claim 23, wherein R.sub.2 is represented by the formula: ##STR175##
- 28. A method as set forth in claim 23, wherein R.sub.2 is represented by the formula: ##STR176## where l is 3 or 4.
- 29. A method as set forth in any of claims 21 to 28, wherein R.sub.1 stands for a methyl group.
- 30. A method as set forth in claim 8, wherein R.sub.2 is represented by the formula: ##STR177## where R.sub.6 and R.sub.6 ' are as defined above, m is 0 or 1, and n is an integer of 0 to 3.
- 31. A method as set forth in claim 30, wherein at least one of R.sub.6 and R.sub.6 ' is an aromatic hydrocarbon group.
- 32. A method as set forth in claim 30 or 31, wherein R.sub.1 is a methyl group.
- 33. A method as set forth in claim 1, wherein said compound is a compound represented by formula II.
- 34. A method as set forth in claim 33, wherein R.sub.4 is represented by the formula --CH.sub.2 CHCH.sub.2 --.
- 35. A method as set forth in claim 1, wherein said vinyl monomer is a monomer selected from the group consisting of (meth)acrylate monomers, styrene monomers and vinyl acetate.
- 36. A method as set forth in claim 35, wherein said (meth)acrylate monomers are mono- to tetrafunctional (meth)acrylates having 1 to 66 carbon atoms.
- 37. A method as set forth in claim 35, wherein said styrene monomers are represented by the formula ##STR178## where Q stands for a halogen atom, or a hydrocarbon group having 1 to 6 carbon atoms.
- 38. A method as set forth in claim 1, wherein said adhesive composition further contains a volatile organic solvent having a boiling point up to 150.degree. C. at 760 Torr, said solvent having a proportion by weight which is a maximum of 300 times greater than that of said polymerizable monomer.
- 39. A method as set forth in claim 1, wherein said curing agent is an agent of the redox type.
- 40. A method as set forth in claim 39, wherein said curing agent is a ternary agent composed of (a) a salt of an organic sulfinic acid, (b) an amine or a salt thereof, and (c) a peroxide.
- 41. A method of restoring a tooth cavity, comprising filling said cavity with an adhesive composition which comprises 100 parts by weight of a polymerizable monomer comprising (a) 1.5 to 50 parts by weight of a compound represented by one of formulas I and II: ##STR179## where R.sub.1 and R.sub.1 ' each stand for hydrogen or a methyl group, R.sub.2 stands for a divalent organic residue having 4 to 40 carbon atoms, X.sub.1 and X.sub.2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R.sub.3 stands for a group of the formula ##STR180## having 6 to 40 carbon atoms, where R.sub.4 and R.sub.4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom or a hydroxyl, amino or carboxyl group, b is an integer of 0 to 3, and Z stands for --O--, --COO-- or --NH--, a plurality of R.sub.4 ' being the same or different, at least one of R.sub.4 and R.sub.4 ' having at least three carbon atoms, and (b) 50 to 98.5 parts by weight of a vinyl monomer copolymerizable with said compound; 20 to 500 parts by weight of a filler; and 0.01 to 20 parts by weight of a curing agent.
- 42. A method as set forth in claim 41, wherein said compound is a compound represented by formula I.
- 43. A method as set forth in claim 42, wherein R.sub.2 stands for (a) a hydrocarbon group having 4 to 30 carbon atoms, which is unsubstituted or substituted by a halogen atom, or a hydroxyl, amino or carboxyl group, or (b) a group having 4 to 30 carbon atoms, and composed of two to seven hydrocarbon groups bonded to one another by a linkage selected from the group consisting of ether, thioether, ester, thioester, thiocarbonyl, amide, urethane, carbonyl and sulfonyl linkages, each of said two to seven hydrocarbon groups having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom, or a hydroxyl, amino or carboxyl group, at least one of said two to seven hydrocarbon groups having at least three carbon atoms.
- 44. A method as set forth in claim 43, wherein R.sub.2 is represented by the formula --R.sub.5 --Y--R.sub.5 '--.sub.c where R.sub.5 and R.sub.5 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom, or a hydroxyl, amino or carboxyl group, at least one of R.sub.5 and R.sub.5 ' having at least three carbon atoms, Y stands for ##STR181## and c is an integer of 1 to 6, a plurality of R.sub.5 ' being the same or different.
- 45. A method as set forth in claim 43, wherein R.sub.2 is represented by the formula ##STR182## where Y and Y' each stand for ##STR183## d is an integer of 0 to 3, and R.sub.6 and R.sub.6 ' each stand for a hydrocarbon group having 1 to 27 carbon atoms which is unsubstituted or substituted by a halogen atom, or a hydroxyl, amino or carboxyl group.
- 46. A method as set forth in claim 43, wherein both X.sub.1 and X.sub.2 stand for --O--, and a is 1.
- 47. A method as set forth in claim 44, wherein both X.sub.1 and X.sub.2 stand for --O--, and a is 1.
- 48. A method as set forth in claim 45, wherein both X.sub.1 and X.sub.2 stand for --O--, and a is 1.
- 49. A method as set forth in claim 46, wherein R.sub.2 is represented by the formula ##STR184## where R.sub.7 and R.sub.7 ' each stand for a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms, which is unsubstituted or substituted by a hydrogen or halogen atom.
- 50. A method as set forth in claim 46, wherein R.sub.2 is represented by the formula ##STR185## where R.sub.8 stands for hydrogen or a methyl group, and R.sub.9 stands for a hydrocarbon group having 3 to 28 carbon atoms, which is unsubstituted or substituted by a halogen atom.
- 51. A method as set forth in claim 46, wherein R.sub.2 is represented by the formula ##STR186## where R.sub.10 stands for a hydrocarbon group having 1 to 12 carbon atoms, which is unsubstituted or substituted by a halogen atom, and e is 0 or 1.
- 52. A method as set forth in claim 46, wherein R.sub.2 is represented by the formula --CH.sub.2 --.sub.f where f is an integer of 4 to 20.
- 53. A method as set forth in claim 46, wherein R.sub.2 is represented by the formula ##STR187## where h is an integer of 1 to 5, and i is an integer of 0 to 3.
- 54. A method as set forth in claim 46, wherein R.sub.2 is represented by the formula ##STR188##
- 55. A method as set forth in claim 46, wherein R.sub.2 is represented by the formula ##STR189## where R.sub.11 stands for a hydrocarbon group having 2 to 6 carbon atoms, which is unsubstituted or substituted by a halogen atom.
- 56. A method as set forth in claim 46, wherein R.sub.2 is represented by the formula: ##STR190##
- 57. A method as set forth in claim 50, wherein R.sub.2 is represented by the formula ##STR191## where g is an integer of 1 to 20, or the formula ##STR192##
- 58. A method as set forth in claim 52, wherein R.sub.2 is represented by the formula --CH.sub.2 --.sub.j where j is an integer of 5 to 12.
- 59. A method as set forth in claim 54, wherein R.sub.2 is represented by the formula ##STR193##
- 60. A method as set forth in any of claims 49 to 59, wherein R.sub.1 stands for a methyl group.
- 61. A method as set forth in claim 47, wherein R.sub.2 is represented by the formula ##STR194## where R.sub.12 stands for a hydrocarbon group having 1 to 12 carbon atoms, which is unsubstituted or substituted by a halogen atom.
- 62. A method as set forth in claim 61, where in Y stands for --O-- or --COO--.
- 63. A method as set forth in claim 47, wherein R.sub.2 is represented by the formula ##STR195## where R.sub.13 and R.sub.13 ' each stand for a hydrocarbon group having 1 to 6 carbon atoms, which is unsubstituted or substituted by a halogen atom.
- 64. A method as set forth in claim 47, wherein R.sub.2 is represented by the formula: ##STR196## where R.sub.14 and R.sub.14 ' stand for hydrogen or a methyl group, and k and k' are both a real number greater than 1, and up to and including 3.
- 65. A method as set forth in claim 47, where R.sub.2 is represented by the formula ##STR197## where r and r' are an integer of 2 to 6.
- 66. A method as set forth in claim 63, wherein R.sub.2 is represented by the formula: ##STR198##
- 67. A method as set forth in claim 63, wherein R.sub.2 is represented by formula: ##STR199##
- 68. A method as set forth in claim 63, wherein R.sub.2 is represented by the formula: ##STR200## where l is 3 or 4.
- 69. A method as set forth in any of claims 61 to 68, wherein R.sub.1 stands for a methyl group.
- 70. A method as set forth in claim 48, wherein R.sub.2 is represented by the formula: ##STR201## where R.sub.6 and R.sub.6 ' are as defined above, m is 0 or 1, and n is an integer of 0 to 3.
- 71. A method as set forth in claim 70, wherein at least one of R.sub.6 and R.sub.6 ' is an aromatic hydrocarbon group.
- 72. A method as set forth in claim 70 or 71, wherein R.sub.1 is a methyl group.
- 73. A method as set forth in claim 41, wherein said compound is a compound represented by formula II.
- 74. A method as set forth in claim 73, wherein R.sub.4 is represented by the formula --CH.sub.2 CHCH.sub.2 --.
- 75. A method as set forth in claim 41, wherein said vinyl monomer is a monomer selected from the group consisting of (meth)acrylate monomers, styrene monomers and vinyl acetate.
- 76. A method as set forth in claim 75, wherein said (meth)acrylate momomers are mono- to tetrafunctional (meth)acrylates having 1 to 66 carbon atoms.
- 77. A method as set forth in claim 75, wherein said styrene monomers are represented by the formula ##STR202## where Q stands for a halogen atom, or a hydrocarbon group having 1 to 6 carbon atoms.
- 78. A method as set forth in claim 41, wherein said filler is a silanated inorganic filler, or an organic-inorganic composite filler.
- 79. A method as set forth in claim 41, wherein said curing agent is an agent of the redox type.
- 80. A method as set forth in claim 79, wherein said curing agent is a ternary agent composed of (a) a salt of an organic sulfinic acid, (b) an amine or a salt thereof, and (c) a peroxide.
- 81. A method of restoring a carious tooth, comprising:
- applying to the wall surface of a cavity in a carious tooth an adhesive composition which comprises 100 parts by weight of a polymerizable monomer comprising (a) 51 to 100 parts by weight of a compound represented by one of formulas I and II: ##STR203## where R.sub.1 and R.sub.1 ' each stand for hydrogen or a methyl group, R.sub.2 stands for a divalent organic residue having 4 to 40 carbon atoms, X.sub.1 and X.sub.2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R.sub.3 stands for a group of the formula ##STR204## having 6 to 40 carbon atoms, where R.sub.4 and R.sub.4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom or hydroxyl, amino or carboxyl group, and b is an integer of 0 to 3, a plurality of R.sub.4 ' being the same or different, at least one of R.sub.4 and R.sub.4 ' having at least three carbon atoms, and Z stands for --O--, --COO-- or --NH--, and (b) 0 to 49 parts by weight of a vinyl monomer copolymerizable with said compound, and 0.01 to 20 parts by weight of a curing agent; and
- filling said cavity with a dental filling composition comprising a polymerizable monomer, a filler and a curing agent.
- 82. A method of restoring a tooth cavity, comprising filling said cavity with an adhesive composition which comprises 100 parts by weight of a polymerizable monomer comprising (a) 51 to 100 parts by weight of a compound represented by one of formulas I and II: ##STR205## where R.sub.1 and R.sub.1 ' each stand for hydrogen or a methyl group, R.sub.2 stands for a divalent organic residue having 4 to 40 carbon atoms, X.sub.1 and X.sub.2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R.sub.3 stands for a group of the formula ##STR206## having 6 to 40 carbon atoms, where R.sub.4 and R.sub.4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom or a hydroxyl, amino or carboxyl group, b is an integer of 0 to 3, and Z stands for --O--, --COO-- or --NH--, a plurality of R.sub.4 ' being the same or different, at least one of R.sub.4 and R.sub.4 ' having at least three carbon atoms, and Z stands for --O--, --COO-- or --NH--, and (b) 0 to 49 parts by weight of a vinyl monomer copolymerizable with said compoound; 20 to 500 parts by weight of a filler; and 0.01 to 20 parts by weight of a curing agent.
- 83. A method for dental treatment which comprises bonding either a tooth and a dental restorative material or dental restorative materials to each other by employing an adhesive composition which comprises 100 parts by weight of a polymerizable monomer comprising (a) 1.5 to 50 parts by weight of a compound represented by one of formulas I or II: ##STR207## wherein R.sub.1 and R.sub.1 ' each stand for hydrogen or a methyl group, R.sub.2 stands for a divalent organic residue having 4 to 40 carbon atoms, X.sub.1 and X.sub.2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R.sub.3 stands for a group of the formula ##STR208## having 6 to 40 carbon atoms, where R.sub.4 and R.sub.4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom or a hydroxyl, amino or carboxyl group, b is an integer of 0 to 3, and Z stands for --O--, --COO-- or --NH--, a plurality of R.sub.4 ' being the same or different, at least one of R.sub.4 and R.sub.4 ' having at least 3 carbon atoms, and (b) 50-98.5 parts by weight of a vinyl monomer copolymerizable with said compound; 20 to 500 parts by weight of a filler; and 0.01 to 20 parts by weight of a curing agent.
- 84. A method for dental treatment which comprises bonding either a tooth and a dental restorative material or dental restorative materials to each other by employing an adhesive composition which comprises 100 parts by weight of a polymerizable monomer comprising (a) 51 to 100 parts by weight of a compound represented by one of formulas I or II: ##STR209## where R.sub.1 and R.sub.1 ' each stand for hydrogen or a methyl group, R.sub.2 stands for a divalent organic residue having 4 to 40 carbon atoms, X.sub.1 and X.sub.2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R.sub.3 stands for a group of the formula ##STR210## having 6 to 40 carbon atoms, where R.sub.4 and R.sub.4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom or hydroxyl, amino or carboxyl group, b is an integer of 0 to 3, and Z stands for --O--, --COO-- or --NH--, a plurality of R.sub.4 ' being the same or different, at least one R.sub.4 and R.sub.4 ' having at least 3 carbon atoms, and Z stands for --O--, --COO-- or --NH--, and (b) 0 to 49 parts by weight of a vinyl monomer copolymerizable with said compound; 20-500 parts by weight of a filler; and 0.01 to 20 parts by weight of a curing agent.
- 85. A method for protecting teeth against dental caries which comprises coating the tooth surface using a pit and a fissure sealant composition having adhesion to tooth which comprises 100 parts by weight of a polymerizable monomer comprising (a) 1.5 to 50 parts by weight of a compound represented by one of formulas I or II: ##STR211## where R.sub.1 and R.sub.1 ' each stand for hydrogen or a methyl group, R.sub.2 stands for a divalent organic residue having 4 to 40 carbon atoms, X.sub.1 and X.sub.2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R.sub.3 stands for a group of the formula ##STR212## having 6 to 40 carbon atoms, where R.sub.4 and R.sub.4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom, or a hydroxyl, amino or carboxyl group, b is an integer of 0 to 3, a plurality of R.sub.4 ' being the same or different, at least one of R.sub.4 and R.sub.4 ' having at least 3 carbon atoms, and Z stands for --O--, --COO-- or --NH--, and (b) 50-98.5 parts by weight of a vinyl monomer copolymerizable with said compound, and 0.01 to 20 parts by weight of a curing agent.
- 86. A method protecting teeth against dental caries which comprises coating the tooth surface using a pit and fissure sealant composition having adhesion to tooth which comprises 100 parts by weight of a polymerizable monomer comprising (a) 51 to 100 parts by weight of a compound represented by one of formulas I or II: ##STR213## where R.sub.1 and R.sub.1 ' each stand for hydrogen or a methyl group, R.sub.2 stands for a divalent organic residue having 4 to 40 carbon atoms, X.sub.1 and X.sub.2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R.sub.3 stands for a group of the formula ##STR214## having 6 to 40 carbon atoms, where R.sub.4 and R.sub.4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, which is unsubstituted or substituted by a halogen atom or hydroxyl, amino or carboxyl group, and b is an integer of 0 to 3, a plurality of R.sub.4 ' being the same or different, at least one of R.sub.4 and R.sub.4 ' having at least 3 carbon atoms, and Z stands for --O--, --COO-- or --NH--, and (b) 0 to 49 parts by weight of a vinyl monomer copolymerizable with said compound, and 0.01 to 20 parts by weight of a curing agent.
Priority Claims (6)
Number |
Date |
Country |
Kind |
56-119536 |
Jul 1981 |
JPX |
|
56-119537 |
Jul 1981 |
JPX |
|
56-120371 |
Jul 1981 |
JPX |
|
57-13038 |
Jan 1982 |
JPX |
|
57-74830 |
May 1982 |
JPX |
|
58-4476 |
Jan 1983 |
JPX |
|
Parent Case Info
This application is a continuation of Ser. No. 398,437, filed on July 14, 1982, now abandoned.
US Referenced Citations (6)
Non-Patent Literature Citations (2)
Entry |
E. Masuhara, "Substitutes for Hard Tissues", Chemical Reviews, No. 21, (1978), pp. 97-110. |
D. Beech, "Adhesion in the Oral Environment: Biophysical and Biochemical Considerations", International Dental Journal, vol. 28, No. 3, (1978), pp. 338-347. |
Continuations (1)
|
Number |
Date |
Country |
Parent |
398437 |
Jul 1982 |
|