Patent Application
20120128280
The present disclosure generally relates to bushings, and more particularly relates to an adhesive film for bushings.
Sliding bearing composite materials consisting of a load bearing substrate and a friction reducing layer overlay are generally known.
Sliding bearing composite materials can be used to form a variety of bearings, such as plain bearing bushing used, for example, by the automotive industry. Such plain bearing bushings can be used for door, hood, and engine compartment hinges, seats, steering columns, flywheels, balancer shaft bearings, etc. Additionally, plain bearing bushings formed from the sliding bearing composite materials can also be used in non-automotive applications.
One method of enhancing the adhesion between a load bearing substrate and the friction reducing layer is to apply a surface treatment to the load bearing substrate, such as chromate or a chromic acid treated phosphate. However, surface treatment can include the use of toxic compounds such as hexavalent chromium. Thus, there is an ongoing need for improved bearings that do not rely upon surface treatments such as chromate.
In an exemplary embodiment, a bushing can include a load bearing substrate having a first major surface, an adhesive film overlying the first major surface, and a friction reducing layer overlying the adhesive layer. The adhesive film can include an adhesive layer and a fluoropolymer layer.
In another exemplary embodiment, a composite can include a metal substrate having a first major surface, an adhesive film overlying the first major surface, and a friction reducing layer overlying the adhesive layer. The adhesive film can include an adhesive layer and an fluoropolymer layer. The adhesive layer can have a thickness of not greater than about 7.5 microns.
In yet another embodiment, a method can include extruding an adhesive film comprising an adhesive layer and a fluoropolymer layer. The method can further include laminating a friction reducing layer to a load bearing substrate with the adhesive film therebetween to form a composite, and shaping the composite to form a bushing.
The present disclosure may be better understood, and its numerous features and advantages made apparent to those skilled in the art by referencing the accompanying drawings.
The use of the same reference symbols in different drawings indicates similar or identical items.
In an exemplary embodiment, a bushing can include a load bearing substrate having a first major surface, an adhesive film overlying the first major surface, and a friction reducing layer overlying the adhesive layer. The adhesive film can include a first adhesive layer and a fluoropolymer layer. In a particular embodiment, the adhesive film can include a second adhesive layer with the fluoropolymer layer between the two adhesive layers. The bushing can provide a sliding engagement between two components and reduce surface wear of the two components.
A friction reducing layer 104 can be applied to the load bearing substrate 102 with an adhesive film 106. The friction reducing layer 104 can include a polymer. Examples of polymers that can be used in friction reducing layer 104 include fluoropolymer, polyacetal, polybutylene terephthalate, polyimide, polyetherimide, polyetheretherketone (PEEK), polyethylene, polysulfone, polyamide, polyphenylene oxide, polyphenylene sulfide (PPS), polyurethane, polyester, or any combination thereof. Examples of fluoropolymers can include polytetrafluoroethylene (PTFE), fluorinated ethylene-propylene (FEP), polyvinylidenfluoride (PVDF), polychlorotrifluoroethylene (PCTFE), ethylene chlorotrifluoroethylene (ECTFE), perfluoroalkoxypolymer (PFA), or any combination thereof. In a particular embodiment, the friction reducing layer 104 can include PTFE, such as, cast, paste extruded, or skived PTFE. In an embodiment, the friction reducing layer 104 can have a coefficient of friction of not greater than about 0.4, such as not greater than about 0.2, even not greater than about 0.15.
Additionally, friction reducing layer 104 can include fillers, such as a friction reducing filler. Examples of fillers that can be used in the friction reducing layer 102 include glass fibers, carbon fibers, silicon, graphite, PEEK, molybdenum disulfide, aromatic polyester, carbon particles, bronze, fluoropolymer, thermoplastic fillers, silicon carbide, aluminum oxide, polyamidimide (PAI), PPS, polyphenylene sulfone (PPSO2), aromatic polyesters including liquid crystal polymers (LCP), and mineral particles such as wollastonite and barium sulfate, or any combination thereof. An LCP is a partially oriented aromatic polyester capable of forming highly oriented regions while in the liquid phase. Fillers can be in the form of beads, fibers, powder, mesh, or any combination thereof.
Adhesive film 106 can include an adhesive layer 108 and a fluoropolymer layer 110. In a particular embodiment, the adhesive film 104 can be in direct contact with the load bearing substrate 102.
The adhesive layer 108 can include a modified fluoropolymer. The modified fluoropolymer can include a functional group, such as a carboxy group, a carboxy anhydride group, a carboxylic halide group, an ester group, a carbonate group, an epoxy group, a sulfate group, a phosphate group, an amide group, a silyl group, or any combination thereof. In a particular embodiment, the functional group can include maleic anhydride, acrylic acid, or another suitable material. Additionally, fluoropolymer layer 110 can include a melt processible fluoropolymer, such as ETFE, ethylene fluorinated ethylene-propylene (EFEP) terpolymer, polychlorotrifluoroethylene (PCTFE), ethylene chlorotrifluoroethylene (ECTFE), or any combination thereof. In an embodiment, the polymer of the adhesive layer 108 can be a modified variant of the fluoropolymer in the fluoropolymer layer 110. For example, the fluoropolymer layer 110 can include ETFE and the adhesive layer 108 can include a modified ETFE, such as a maleic anhydride modified ETFE or other modified ETFE.
In an embodiment, the adhesive film 106 can have a thickness of about 25 microns to about 75 microns, such as about 30 microns to about 50 microns. Further, the first adhesive layer can have a thickness of about 1 micron to about 7.5 microns, such as about 1.5 microns to about 5 microns. Additionally, the fluoropolymer layer can have a thickness of about 20 microns to about 70 microns, such as about 24 microns to about 45 microns. The ratio of the thickness of the adhesive layer 108 to the thickness of the fluoropolymer layer 110 can be not less than about 1:20, such as not less than about 1:15, even not less than about 1:10. In a particular embodiment, the ratio of the thickness of the adhesive layer to the thickness of the fluoropolymer layer can be not greater than 1:2, such as not greater than 1:4.
In an alternative embodiment illustrated in
Turning to the method of forming the bushing, an adhesive film can be formed by coextruding an adhesive layer and a fluoropolymer layer. Coextruding the adhesive layer and the fluoropolymer layer can include extruding onto a casting drum.
A friction reducing layer, such as a skived fluoropolymer, can be laminated to a load bearing substrate with the adhesive film to form a laminate sheet having the adhesive film between the friction reducing layer and the load bearing substrate. In a particular embodiment, a surface of the friction reducing layer can be etched to enhance bonding between the friction reducing layer and the adhesive film. The laminate sheet can be cut into strips or blanks that can be formed into the bushing. The blanks can be formed into the bushing, such as by rolling and flanging the laminate to form a semi-finished bushing of a desired shape.
In an embodiment, the bushing can have a cylindrically shaped portion. In another embodiment, the bushing can have a conical shape. Further, the bushing can have a flanged portion on one or more ends. Additionally, the friction reducing layer can be on an inner surface of the bushing or on an outer surface of the bushing.
In a particular example, the bushing can be used in a hinge. For example,
In another example, the bushing can be used in a headset. For example,
Particular embodiments of the above bushing provide advantageous technical features. In particular, Applicants use of an adhesive film with a modified polymer adhesive, such as modified ETFE, can result in improved adhesion between the friction reducing layer and the load bearing substrate without the use of a surface treatment including chromate or chromic acid. As a result, manufacturing of the bushing can have a reduced impact on the environment and reduced cost for disposal of toxic chemicals.
Note that not all of the activities described above in the general description or the examples are required, that a portion of a specific activity may not be required, and that one or more further activities may be performed in addition to those described. Still further, the order in which activities are listed are not necessarily the order in which they are performed.
In the foregoing specification, the concepts have been described with reference to specific embodiments. However, one of ordinary skill in the art appreciates that various modifications and changes can be made without departing from the scope of the invention as set forth in the claims below. Accordingly, the specification and figures are to be regarded in an illustrative rather than a restrictive sense, and all such modifications are intended to be included within the scope of invention.
As used herein, the terms “comprises,” “comprising,” “includes,” “including,” “has,” “having” or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a process, method, article, or apparatus that comprises a list of features is not necessarily limited only to those features but may include other features not expressly listed or inherent to such process, method, article, or apparatus. Further, unless expressly stated to the contrary, “or” refers to an inclusive-or and not to an exclusive-or. For example, a condition A or B is satisfied by any one of the following: A is true (or present) and B is false (or not present), A is false (or not present) and B is true (or present), and both A and B are true (or present).
Also, the use of “a” or “an” are employed to describe elements and components described herein. This is done merely for convenience and to give a general sense of the scope of the invention. This description should be read to include one or at least one and the singular also includes the plural unless it is obvious that it is meant otherwise.
Benefits, other advantages, and solutions to problems have been described above with regard to specific embodiments. However, the benefits, advantages, solutions to problems, and any feature(s) that may cause any benefit, advantage, or solution to occur or become more pronounced are not to be construed as a critical, required, or essential feature of any or all the claims.
After reading the specification, skilled artisans will appreciate that certain features are, for clarity, described herein in the context of separate embodiments, may also be provided in combination in a single embodiment. Conversely, various features that are, for brevity, described in the context of a single embodiment, may also be provided separately or in any subcombination. Further, references to values stated in ranges include each and every value within that range.
The present application claims priority from U.S. Provisional Patent Application No. 61/415,463, filed Nov. 19, 2010, entitled “ADHESIVE FILM FOR BUSHINGS,” naming inventors Paul W. Ortiz and Julia DiCorleto Gibson, which application is incorporated by reference herein in its entirety.
| Number | Date | Country | |
|---|---|---|---|
| 61415463 | Nov 2010 | US |
