The present invention is targeted to solving the serious pollution problems originating from the generation of electric power from plants which burn coal that may be forced to shut down by virtue of their being uneconomical to be retrofitted with expensive pollution controls; see Exhibit 1. The pollutants from coal-burning power stations comprise SO2, NOx, Hg, Particulate Matter, Ash, and CO2. This invention offers a unique and comprehensive solution which makes possible the prevention of the ill-effects currently caused to health and environment while at the same time would also prevent the closure of these badly needed power generation facilities that provide some 50% of the electricity generated in this country whose citizens so heavily depend on. In addition to the herein comprehensive solution, it will be disclosed in the specification that follows, the putting of all six pollutants mentioned above into beneficial use while avoiding the discharge of said pollutants into the atmosphere.
The renowned Clean Air Task Force (CATF), whose main office is in Boston, Mass., with several branches, issued in September 2010 a Report titled “The Toll From Coal” and subtitled “An Updated Assessment of Death and Disease from America's Dirtiest Energy Source.” The first paragraph of the Report's Executive Summary states the following:
The main object of the present invention is to avoid the burning of coal in boilers of existing electric power stations by efficiently processing the coal upstream of the boilers in an environmentally closed system while producing clean gases that are utilized to generate clean, low-cost power as well as valuable by-products.
Another object of the instant invention is to prevent layoffs from shutting down coal-burning power generating facilities and, instead, create many additional well-paying jobs.
Therefore another object of the present invention is to capitalize on existing infrastructure in the power stations that is quite costly to replace.
Yet another object of the instant invention is to create energy security by providing ample capacity to prevent black-outs.
Further another object of the present invention is to provide one comprehensive solution that will control SO2, NOx, Hg, Particulate Matter, Ash, and CO2, from coal.
Still another object of the instant invention is to eliminate the need for pulverizing the coal, as pulverization is notorious in producing fine particulate matter that is injurious to health.
Further still another object of the present invention is to increase the availability of boilers currently used in coal-burning power stations, by avoiding the burning of coal altogether in boilers, which currently demand frequent maintenance caused by deposits within the boilers as a result of combusting coal in the boilers.
Further yet another object of the present invention is to generate clean electric power more efficiently while still using existing boilers to raise steam that can serve as the steam cycle of a hybrid, efficient combined cycle power generation.
It is therefore another object of the instant invention to increase capacity of power generation with low capital investment.
It is yet another object of the instant invention to increase the net profit of power producers using clean gases made from coal, which will enable such producers to offer attractive power costs to the consumer.
Other objects of this invention will appear from the following detailed description and appended claims. Reference is made to the accompanying drawings forming a part of this specification wherein like reference characters designate corresponding parts in the various figures.
Reference is made to
Pyrolyzer 10 is made up of charger 20, pyrolyzing chamber 21, radiant zone 22, downcomer 23, and flow control valve 24, from which bifurcated pipe 25 forms a delivery pipe assembly, with pipe 26 connecting downcomer 23 thence to char gasifier 11 by way of control valve 28, and pipe 27 connecting downcomer 23 to char quencher 12 by way of control valve 29. It is to be noted that gasifier 11 serves to perform three functions; namely, the conversion of hot incandescent residual char into a raw lean gas, the reduction of CO2 into 2CO (a fuel or chemical feedstock), and the conversion of coal ash (a polluter) into inert slag.
Gasifier 11 comprises vessel 30, which is equipped with injection points at different levels for a gas containing oxygen, such as air, to react with hot char to produce a lean fuel gas; gasifier 11 possesses at its bottom discharge cooler 31 that is equipped with a lean gas exit port 32; cooler 31 serves to solidify molten slag produced in gasifier 11 into an inert grit. Below cooler 31, lockhopper 33 is provided, which is controlled by upper valve 34 and by lower valve 34 that controls the discharge of the solidified, inert slag into collection tank 35. At about mid-point of gasifier 11, a special manifold marked by numeral 36 serves for the injection of flue gases containing CO2 for reducing the CO2 into 2CO that serves as a feedstock. Char quencher 12 comprises vessel 37, which is equipped with multi-level manifolds, like manifold 38, that gradually cool the char below ignition point prior to being periodically discharged to the atmosphere by means of valve 39.
The equipment to feed the run-of-mine coal and the char, marked by numeral 19, comprises skip 40 which elevates the run-of-mine coal from ground level to conveyor 42 and skip 41 which elevates the char (fuel) from ground level to conveyor 43, which in turn conveyor 42 discharges to feeder 44 and conveyor 43 discharges to feeder 45. A secondary surge hopper marked by numeral 68 serves to feed polluted boiler ash from coal combustion that had been stored in ponds (Exhibit 2) and classified as hazardous material. In feeding such hazardous material into gasifier 11, such ash is caused to mix with the ash from the freshly fed char from pyrolyzer 10 into slagging gasifier 11, thus providing a way of converting the old, hazardous ash and the newly formed ash into inert slag.
Gas cleanup 13 is made up of three vessels, marked by numerals 46, 47, and 48. Vessel 46 cracks and simultaneously desulfurizes the H2 rich gas (volatile matter) from pyrolyzer 10; vessel 47 cleans the lean fuel gas made up of nitrogen (N2) and carbon monoxide (CO) gas from gasifier 11; and vessel 48 serves to regenerate the spent sorbent while producing elemental sulfur directly and additional lean fuel gas. All three vessels are equipped with feeders denoted by numeral 49. Vessel 48 interconnects with vessels 46 and 47 via the inverted Y-pipe that is marked by numeral 50, which is equipped with diversion valves 51. Gas cleanup 13 is equipped with pneumatic transporters 52 to convey the spent sorbent from vessels 46 and 47 to regenerator 48.
Cyanogen make-up equipment 16 comprises reactor 53 “A” and reactor 53 “B” with gas temperature moderator denoted by numeral 54 being upstream of reactors “A” and “B,” and chiller-liquefier which is denoted by numeral 55, being downstream of reactors 53A and 53B. A separator marked by numeral 56 is provided to segregate the liquefied cyanogen from the unreacted gases which are directed (not shown) to pyrolyzer 10, or recycled back to either reactor 53A or 53B.
Downstream of separator 56, oxamide maker 17 is located. It consists of reactor 57, settling tank 58, filter press 59, drier 60, and stacker 61. Pump 62 is provided to separator 56, to pump the liquefied cyanogen to evaporator 63, and pump 64 serves to circulate the liquid catalyst to the top of reactor 57; a heater denoted by numeral 65 serves to adjust the temperature of the liquid catalyst.
The mercury removal systems marked by numeral 18A and 18B (also known as mercury traps) consist of activated carbon beds, comprising beds “a” and “b,” with the practice being when bed “a” is in absorption of mercury, bed “b” is in stand-by mode, and when bed “b” is in absorption, while bed “a” is in stand-by mode. A baghouse marked by numeral 91 is provided downstream of each mercury trap. A preferred configuration of mercury capture is described hereinafter in
The electric power generation system in this invention, marked by numeral 15, is preferably fueled with a clean, lean gas (fuel gas) fed from cleanup vessel 47 and comprises combustion turbine numeral 66 connected to existing boiler 67 which serves as both—a heat recovery steam generator and steam turbine by advantageously making use of the very valuable coal-burning boiler 67, by jointly forming a combined cycle configuration by making use of combustion turbine 66; such configuration provides a most efficient way of generating power while still salvaging the existing coal-burning boiler but without combusting coal in it, to raise steam by means of hot exhaust from combustion turbine 66. If the supply of the hot exhaust is inadequate, clean lean gas (2CO+N2) is fed to the boiler by means of duct 87 as clean supplemental fuel. Instead of discharging the flue gas (N2+CO2) from boiler 67 into the atmosphere, the flue gas is compressed by means of compressor 88 and fed to gasifier 11 for reduction of the CO2 to 2CO3 by means of duct 89, which ties to manifold 36 of gasifier 11, thus providing a completely closed-to-the-atmosphere system.
For additional clarification, pyrolyzer 10 is illustrated in a vertical, frontal section taken along the longitudinal axis of
Referring now to
The coal is heated peripherally by means of injection nozzles disposed through shell 77 and refractory 75, one of which being marked by numeral 80, with such nozzles being supplied with a gas containing oxygen furnished by manifold 79, thus providing direct, pressurized, bi-directional, efficient heating that increases the release of the volatile matter from the coal annulus to such an extent that virtually all the oils in the coal are recovered in tar-free vapor form.
In the instant invention, wherein a core of char is surrounded by an annulus of coal and the char is combusted, thus minimizing the combustion of coal, the yield of H2 rich raw gas (raw syngas) is markedly increased, this being an important and beneficial factor, as a H2 rich syngas is quite valuable to be used to produce chemicals and transportation fuels such as methanol/gasoline and dimethyl ether, a clean fuel, as a substitute for dirty diesel. To achieve this objective, numeral 21 is the pyrolyzing chamber, numeral 20 is the charger, numeral 81 is the feed hopper, numeral 69 is the ram, numeral 70 is the mandrel, numeral 71 is the injection lance, numeral 82 is the nozzle at the tip of lance 71, and numeral 83 is one of the several nozzles disposed at the side of lance 71, numeral 72 is the char fuel, numeral 73 is the charged coal, and numeral 75 is the refractory/insulation which is configured as a monolithic structure that is reinforced with metallic needles such as stainless steel needles, marked by numeral 84 (shown in SECTION A-A), somewhat similar to imbedding steel wire in reinforced concrete; this structure is cast in place against shell 77.
In the case of heating the material peripherally directly by combusting char (not shown), oxygen is introduced through shell 77 by means of injectors, one such injector being marked by numeral 80 supplied by manifold 79. When combustion takes place peripherally around the coal annulus, it is possible to also charge char around the perimeter of the coal annulus by providing an additional mandrel that circumscribes ram 69 to form a ring of char around the periphery of the coal. In so doing, the combustion effected by injectors, such as injector 80, consumes the ring of char, instead of combusting the coal, as the objective is to maximize the production of H2 rich gas, which after cleanup, is a very valuable feedstock.
In the case of heating the material peripherally indirectly, numeral 74 represents the manifold for distributing hot heating gas into a plurality of small-diameter flues installed in refractory/insulation 75, one such flue being marked by numeral 76 carrying hot gases that heat refractory 75, which in turn heats indirectly the coal marked my numeral 78 shown in Section A-A. It is to be noted that towards the exit end of pyrolyzing chamber 21, the coal has been completely devolatilized, yielding a residue consisting of hot incandescent char.
Referring to
Beds “a” and “b” get charged from the top with activated carbon, with flow control valves 111 and 109, respectively; beds “a’ and “b” get discharged from the bottom, with flow control valves 102 and 104, respectively. Upstream of valves 102 and 104, feeders 107 and 105 are situated in such a way that feeder 107 is upstream of valve 102, and feeder 105 is upstream of value 104. Upstream of flow control valves 111 and 109, common feeder 114 is disposed to enable the feed of fresh activated carbon to either bed “a” or bed “b,” with common feeder 114 forming the lower portion of surge hopper 113, which serves as storage for fresh activated carbon; surge hopper 113 receives activated carbon by means of skip hoist 112, which elevates the activated carbon from ground level.
To regenerate the saturated (mercurized) carbon from beds “a” and “b,” valves 102 and 104 discharge the mercurized carbon into the charging chamber of miniature pyrolyzer 92 by way of manifold 99, within which the mercurized carbon is heated indirectly, causing the vaporization of the mercury which is directed from pyrolyzer 92 to condenser 93 where the recovered mercury is cooled and collected in liquid form in tank 94. The feed of the mercurized carbon through pyrolyzer 92 is effected by a ram pusher marked by numeral 98, and the de-mercurized carbon is discharged from pyrolyzer 92 by means of lockhopper having an upper valve marked by numeral 95 and a lower valve marked by numeral 96, while the de-mercurized carbon is noted by numeral 97.
Downstream of beds “a” and “b,” two baghouses are disposed and respectively marked by numerals 91A and 91B, with baghouse 91A serving to clean particulate matter entrained in de-mercurized H2 rich gas stream 118, and baghouse 91 B serving to clean particulate matter entrained in de-mercurized fuel gas stream 119. Subsequent to the removal of particulate matter from stream 118, the cleaned, de-mercurized H2 rich gas is raised in pressure by means of compressor 115, forming stream 116 which is directed to plant 90 (shown in
Referring to
To describe the operation of this invention based on extensive test work that had taken place and referenced hereinafter begins with using unprepared, crushed run-of-mine coal preferably of three inches and under that is directly fed into a battery of pyrolyzers, where the cracking of asphalt in highly hot radiant zone 22 results in a tar-free volatile matter containing a hydrogen rich, non-condensable raw syngas together with vaporized light liquids and incandescent char. The syngas and vaporized light liquids are desulfurized and upgraded in the first hot gas cleanup 46 (shown in
The test work performed in the Applicant's pilot in cooperation with Sun refining proved that the method described herein, which uses CaO as sorbent, produced light liquids from cracking residuum (heavy bitumen) from its Philadelphia Refinery against CaO as sorbent. Such light liquids were referred to by Sun as “excellent feedstocks and can be separated by a simple distillation process into valuable intermediates”; see Exhibit 3, page 1 of 2.
Data that was produced by way of the tests (see Exhibit 3, page 2 of 2) showed that the Ramsbottom Carbon (by weight percentage) of the residuum was converted from 18.2% to 1.24% in test Run #3, to 0.59% in test Run #4, and to 0.31% in test Run #5. Further, for the Pour Point temperature in ° F., the residuum was 145° F., and in tests #3, #4, and #5, the temperature was reduced to −20° F. Also, the INITIAL BOILING POINT of the residuum dropped from 802° F.: in test #3 to 108° F., in test #4 to 154° F., and in test #5 to 135° F. This data show that the method herein described—which is based on the replication of the test work performed, except at commercial scale—should produce outstanding results in producing light liquids from bituminous coal. It is also important to disclose herein that the syngas (Rich Gas Sample—Test Run #3) produced in Mole % as follows: H2—57.3%; CH4—36.6%; N2—3%; C2H4—1.8%; CO 1.6%; and CO2—only 0.7%.
Additional work with respect to residual char after pyrolysis, tests were conducted in 1997 at Applicant's Process Development Unit (Exhibit 4) making metallurgical coke from coal; the coke (char) produced was tested for various properties including residual volatile matter after pyrolysis. In testing the coke made from Bethlehem Steel's coal, the residual volatile matter in the coke was 0.58%, and with coke made from U.S. Steel's three coals, the residual volatile matter in the coke was 0.55% from Blue Tag Coal, 0.48% from Low-Vol coal, and 0.70% from White Tag coal; see Exhibit 5. In the tests conducted, whether the feedstock was heavy oil (bitumen) or coal, these feedstocks were pyrolyzed in sealed tubes in which cracking of tars took place as proposed herein; in the case of sulfur removal, the gas produced had no H2S, as reported in Exhibit 3, page 1 of 2. Elemental sulfur was produced directly during regeneration (see Exhibit 6), and the chemistry for such results were published in The Making, Shaping and Treating of Steel, 11th edition; see Exhibit 7.
As referenced above, there are six pollutants as a result of combusting coal in existing coal-fired boilers to raise steam which is fed into steam turbines to generate electric power. These pollutants consist of: SO2, NOx, Hg, Particulate Matter, Ash, and CO2. The comprehensive solution of the instant invention is to convert all the six pollutants into valuable products instead of wastes being discharged into the atmosphere or buried in landfills or some geologic formation which is costly, inefficient, and must be continuously monitored.
The herein invention addresses these six pollutants into products as follows:
In conclusion, based on the test work done and the herein description, the objectives listed towards the beginning of this disclosure are achievable. It is submitted herein that the instant method and apparatus provide major improvements over the conventional practice of using pulverized coal that is combusted in boilers. The details of construction mentioned above are for the purpose of description and not limitation, since other configurations are possible without departing from the spirit of the invention. Further, other materials besides coal can be processed in the apparatus herein described.