Claims
- 1. A process for reducing nitrogen oxides in combustion emission systems comprising the steps of:
- (a) mixing a reburning fuel with combustion emissions in a gaseous reburning zone such that the reburning zone is substantially oxygen deficient;
- (b) passing the resulting mixture of reburning fuel and combustion emissions into a first burnout zone;
- (c) introducing a first stream of burnout air into the first burnout zone such that the carbon monoxide concentration in the first burnout zone is reduced to a level below about 0.5 percent;
- (d) advancing the resulting mixture from the first burnout zone to a second burnout zone having a temperature in the range from about 1300.degree. F. to about 1900.degree. F.; and
- (e) introducing a second stream of burnout air into the second burnout zone, said second stream of burnout air including a reducing agent capable of providing a source of nitrogenous reducing species thereby reducing the nitrogen oxides in the combustion emissions.
- 2. A process for reducing nitrogen oxides in combustion emission system as defined in claim 1, wherein the substantially oxygen deficient reburning zone has a stoichiometry in the range from about 0.7 to about 1.0.
- 3. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reburning zone has a temperature in the range from about 2200.degree. F. to about 3000.degree. F.
- 4. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reburning fuel mixed with the combustion emissions includes natural gas.
- 5. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the first burnout zone has a stoichiometry in the range from about 1.0 to about 1.2.
- 6. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the first burnout zone has a temperature in the range from about 1300.degree. F. to about 3000.degree. F.
- 7. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the first burnout zone has a temperature in the range from about 1300.degree. F. to about 2600.degree. F.
- 8. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the carbon monoxide concentration in the first burnout zone is reduced to a level below about 0.5 percent.
- 9. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the second burnout zone has a stoichiometry in the range from about 1.0 to about 2.0.
- 10. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the second burnout zone has a temperature in the range from about 300.degree. F. to about 1900.degree. F.
- 11. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent included with the second stream of burnout air includes ammonium sulfate.
- 12. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent included with the second stream of burnout air includes cyanuric acid.
- 13. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent included with the second stream of burnout air includes urea.
- 14. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent included with the second stream of burnout air includes ammonia gas.
- 15. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent included with the second stream of burnout air includes aqueous ammonium solution.
- 16. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is aqueous ammonium sulfate solution.
- 17. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is cyanuric acid.
- 18. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is urea.
- 19. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is ammonia gas.
- 20. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is aqueous ammonium solution.
- 21. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is ammonium formate.
- 22. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is aqueous ammonium formate.
- 23. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is ammonium carbonate.
- 24. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is aqueous ammonium carbonate.
- 25. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is ammonium bicarbonate.
- 26. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is aqueous ammonium bicarbonate.
- 27. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is ammonium sulfate.
- 28. A process for reducing nitrogen oxides in combustion emission systems as defined in claim 1, wherein the reducing agent is aqueous ammonium sulfate.
RELATED APPLICATION
This application is a continuation-in-part of copending patent application Serial No. 07/598,879, filed Oct. 17, 1990, now abandoned, in the names of William Randall Seeker, Shih L. Chen and John C. Kramlich, and entitled "ADVANCED REBURNING FOR NO.sub.x CONTROL," which is incorporated herein by specific reference.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
4851201 |
Heap et al. |
Jul 1989 |
|
4861567 |
Heap et al. |
Aug 1989 |
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
598879 |
Oct 1990 |
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