The present application is a National Phase entry of PCT Application No. PCT/GB2016/052831, filed Sep. 14, 2016, which claims priority from GB Patent Application No. 1517092.1, filed Sep. 28, 2015, each of which is hereby fully incorporated herein by reference.
The present disclosure relates to aerosol provision cartridges and systems such as nicotine provision systems (e.g. e-cigarettes) comprising coated metallic components. The present disclosure also relates to the use of coated metallic components to stabilize and/or improve the aerosol.
Aerosol provision systems such as e-cigarettes generally contain, amongst other parts, an aerosol provision cartridge which comprises a reservoir of a source liquid, typically including nicotine, from which an aerosol is generated, e.g. through vaporization or other means. The aerosol provision cartridge may also comprise an aerosol generating component, such as a heater, which is fluidly connected to the source liquid contained in the reservoir. When a user inhales on the device, the aerosol generating component is activated to vaporize an amount of the source liquid. More particularly, such devices are usually provided with one or more air inlet holes located away from a mouthpiece of the system. When a user sucks on the mouthpiece, air is drawn in through the inlet holes and past the aerosol generating component. There is a flow path connecting between the aerosol generating component and an opening in the mouthpiece so that air drawn past the aerosol generating component continues along the flow path to the mouthpiece opening, carrying some of the aerosol produced from the aerosol generating component with it. The aerosol-carrying air exits the aerosol provision system through the mouthpiece opening for inhalation by the user.
Typical aerosol generating components comprise a heater. The source liquid is generally arranged within the system such that it can access the aerosol generating component. For example, it may be that the aerosol generating component is a wire which is heated during use of the device. As a result of the contact between the source liquid and the wire, when the wire is hearted during use the source liquid is vaporized and subsequently condenses into an aerosol which is then inhaled by the user. The means by which the source liquid can contact the wire may vary. It is not uncommon for the source liquid to be stored in a wadding or other type of holding matrix. This wadding or matrix can either itself directly contact the heating wire or, alternatively, it may be that a further “wick” is in contact with both the wadding and the heating wire. This wick serves to draw the source liquid from the wadding to the heating wire during use.
Other types of systems do not employ wadding to hold the source liquid. Instead, in these systems the source liquid is held freely in a tank or other storage region and is directly fed to the heating wire (which may itself include a wicking core to assist in holding the source liquid in proximity to the wire).
Typically, the aerosol generating component is contained within an aerosol generating region. In some instances, this aerosol generating region is a chamber. The primary characteristics of such a region are that it should provide sufficient space to house the aerosol generating component, as well as to allow for the desired degree of airflow past the aerosol generating component and on to the mouthpiece outlet. Whilst it is desired that substantially all of the vapor that is generated in the aerosol generating region is entrained in the airflow travelling past the aerosol generating component, this does not always occur. For example, in some instances vapor produced in the aerosol generating region can condense and remain within that region. In other words, not all of the vapor produced is entrained in the through-flowing airflow. The result of this is that condensate can accumulate within the aerosol generating region. As a result of the aerosol generating region being provided with an inlet to allow for the ingress of air so as to allow for formation of the aerosol, the aerosol generating region is typically not liquid impermeable—in other words, the aerosol generating region is generally not sealed and as a result any condensate which has accumulated in the aerosol generating region may migrate to other parts of the aerosol provision cartridge. Depending on the composition of the liquid source, this may or may not present certain issues. For example, if the condensate produced from the aerosol generating component contains compounds that are reactive with other components of the aerosol provision cartridge outside of the aerosol generating region, it may be that the acceptability of the aerosol delivered to the user deteriorates over time as a result of the reaction products from the condensate reacting with the other components within the cartridge becoming entrained in the airflow through the device and thus into the resulting aerosol.
Therefore, it would be desirable to provide an aerosol provision cartridge which is able to provide a consistently acceptable aerosol to a user.
In a first aspect there is provided an aerosol provision cartridge for use with an aerosol provision system, said cartridge comprising: a liquid storage region in fluid communication with an aerosol generating region; and one or more metallic components, located substantially outside of the aerosol generating region and liquid storage region, wherein at least one of the said metallic components has a coating comprising silver and/or gold.
In a further aspect there is provided an aerosol provision cartridge for use with an aerosol provision system, said cartridge comprising: a liquid storage region comprising a source liquid, said source liquid comprising nicotine and at least one acid; an aerosol generating region in fluid communication with the liquid storage region; and one or more metallic components, located substantially outside of the aerosol generating region and liquid storage region, wherein at least one of the said metallic components has a coating comprising silver and/or gold.
In a further aspect there is provided an aerosol provision cartridge for use with an aerosol provision system, said cartridge comprising: a liquid storage region in fluid communication with an aerosol generating region; said aerosol generating region configured to be substantially liquid-free; and one or more metallic components, located substantially outside of the aerosol generating region and liquid storage region, wherein at least one of the said metallic components has a coating comprising silver and/or gold.
It has surprisingly been found that aerosols produced from cartridges and systems of the present disclosure are more acceptable to consumers.
In a further aspect there is provided the use of a metallic component having a coating comprising gold and/or silver in an aerosol provision cartridge to stabilize and/or improve the acceptability of the aerosol to a user.
In a further aspect there is provided a method of preventing the deterioration of the sensorial attributes of an aerosol produced from an aerosol provision cartridge comprising utilizing in the construction of the cartridge a metallic component having a coating comprising gold and/or silver.
In a further aspect there is provided an aerosol provision system comprising an aerosol provision cartridge as defined herein, and an aerosol provision device comprising a power source and an input means.
The approach described herein is not restricted to specific embodiments such as set out below, but includes and contemplates any appropriate combinations of features presented herein. For example, an electronic aerosol provision system may be provided in accordance with the approach described herein which includes any one or more of the various features described below as appropriate.
Various embodiments will now be described in detail by way of example only with reference to the following drawings:
Aspects and features of certain examples and embodiments are discussed/described herein. Some aspects and features of certain examples and embodiments may be implemented conventionally and these are not discussed/described in detail in the interests of brevity. It will thus be appreciated that aspects and features of apparatus and methods discussed herein which are not described in detail may be implemented in accordance with any conventional techniques for implementing such aspects and features.
As described above, the present disclosure relates to an aerosol provision cartridge which may form part of an aerosol provision system, such as an e-cigarette. Throughout the following description the term “e-cigarette” is sometimes used; however, this term may be used interchangeably with aerosol (vapor) provision system, or vapor provision device. Further, term “aerosol provision cartridge” may also be referred to as cartomizer, clearomizer or tank, as such terms are common in the field of aerosol provision systems such as e-cigarettes.
The liquid storage region for the source liquid may comprise a foam matrix or any other structure, such as a wadding, within a housing for retaining the source liquid until such time that it is required to be delivered to the aerosol generating component. Alternatively, the liquid storage region may simply be a reservoir which an amount of “free liquid” contained therein. The liquid storage region may be “closed” or “open”. In other words, where the liquid storage region is “closed”, the user is not able to re-fill the liquid storage region with liquid once it has been depleted without dismantling or otherwise breaking the device in a manner which is not envisaged by the manufacturer. Where the liquid storage region is “open” it is configured to be re-filled by the user. This “open” configuration can generally be achieved by using a mouthpiece or other component that seals the liquid storage region, but which can be removed (via a screw thread, etc.) such that access to the liquid storage region is provided.
The aerosol generating component includes a heater for vaporizing the source liquid to form the aerosol. The aerosol generating component may further include a wick or similar facility to transport a small amount of the source liquid from the storage region to a heating location on or adjacent the heater.
The body 20 includes a re-chargeable cell or battery to provide power for the e-cigarette 10 and a circuit board for generally controlling the e-cigarette 10. In use, when the heater receives power from the battery, as controlled by the circuit board, the heater vaporizes the source liquid at the heating location to generate the aerosol, and this is then inhaled by a user through the opening in the mouthpiece 35. The aerosol is carried to the mouthpiece 35 along an air channel that connects the aerosol generating region to the mouthpiece 35 opening as a user inhales on the mouthpiece 35.
In this particular example, the body 20 and cartomizer 30 are detachable from one another by separating in a direction parallel to the longitudinal axis LA, as shown in
In connection with this, in order to allow for connection with the body 20 (both mechanically and electrically) the cartomizer 30 generally contains one or more metallic components. For example, these components may be screw thread rings, electrodes, or intermediate supporting members (all not shown). When assembled, such metallic components allow for the cartomizer 30 to be connected to the body 20 in a manner which supports the aerosol generating component in the aerosol generating region, allows for the provision of electrical current to the aerosol generating component, and allows for airflow to travel into the aerosol generating region so that it may collect the vapor/aerosol produced therein and deliver it to the user.
The e-cigarette 10 is provided with one or more holes (not shown in
When a user inhales through the mouthpiece 35, air is drawn into this air passage through the one or more air inlet holes, which are suitably located on the outside of the e-cigarette 10. This airflow (or the resulting change in pressure) is detected by a pressure sensor (as an example of an input means) that in turn activates the aerosol generating component (heater in this case) to vaporize a portion of the source liquid to generate the aerosol. The airflow passes through the air passage, and combines with the aerosol in the region around the aerosol generating region, and the resulting aerosol then travels along the air channel connecting from the aerosol generating region to the mouthpiece 35 to be inhaled by a user. The cartomizer 30 may be detached from the body 20 and disposed of when the supply of source liquid is exhausted (and replaced with another cartomizer if so desired). Alternatively, the cartomizer 30 may be refillable.
It will be appreciated the e-cigarette 10 shown in
As shown in
The body 20 further includes a cap 225 to seal and protect the far (distal) end of the e-cigarette 10. There is an air inlet hole provided in or adjacent to the cap 225 to allow air to enter the body 20 and flow past the sensor unit 215 when a user inhales on the mouthpiece 35. This airflow therefore allows the sensor unit 215 to detect the user inhalation and so activate the aerosol generating component of the e-cigarette 10.
At the opposite end of the body 20 from the cap 225 is the connector 25B for joining the body 20 to the cartomizer 30. The connector 25B provides mechanical and electrical connectivity between the body 20 and the cartomizer 30. The connector 25B includes a body connector 240, which is metallic (silver-plated in some embodiments) to serve as one terminal for electrical connection (positive or negative) to the cartomizer 30. The connector 25B further includes an electrical contact 250 to provide a second terminal for electrical connection to the cartomizer 30 of opposite polarity to the first terminal, namely body connector 240. The electrical contact 250 is mounted on a coil spring 255. When the body 20 is attached to the cartomizer 30, the connector 25A on the cartomizer 30 pushes against the electrical contact 250 in such a manner as to compress the coil spring in an axial direction, i.e. in a direction parallel to (co-aligned with) the longitudinal axis LA. In view of the resilient nature of the spring 255, this compression biases the spring 255 to expand, which has the effect of pushing the electrical contact 250 firmly against connector 25A, thereby helping to ensure good electrical connectivity between the body 20 and the cartomizer 30. The body connector 240 and the electrical contact 250 are separated by a trestle 260, which is made of a non-conductor (such as plastic) to provide good insulation between the two electrical terminals. The trestle 260 is shaped to assist with the mutual mechanical engagement of connectors 25A and 25B. It may be that when the sensor 215 is located at the opposite end of the body 20 relative to the cap 225, the body 20 includes one or more air inlet holes provided in or adjacent to connector 25B to allow air to enter the body 20 and flow past the sensor unit 215 when a user inhales on the mouthpiece 35.
The cartomizer 30 includes an air passage 355 extending along the central (longitudinal) axis of the cartomizer 30 from the mouthpiece 35 to the connector 25A for joining the cartomizer to the body 20.
A liquid storage region 360 is provided around the air passage 335. This storage region 360 may be implemented, for example, by providing cotton or foam soaked in source liquid. Alternatively, it may be a simple reservoir which contains the source liquid in a free state, i.e. not held within a wadding, matrix or the like. The cartomizer 30 also includes a heater 365 for heating liquid from the storage region 360 to generate an aerosol to flow through air passage 355 and out through an opening in the mouthpiece 35 in response to a user inhaling on the e-cigarette 10. The heater 365 is powered through lines 366 and 367, which are in turn connected to opposing polarities (positive and negative, or vice versa) of the battery 210 via connector 25A (the details of the wiring between the power lines 366 and 367 and connector 25A are omitted from
The connector 25A includes an inner electrode 375, which may be made of a metal suitable for conducting electrical current. When the cartomizer 30 is connected to the body 20, the inner electrode 375 contacts the electrical contact 250 of the body 20 to provide a first electrical path between the cartomizer 30 and the body 20. In particular, as the connectors 25A and 25B are engaged, the inner electrode 375 pushes against the electrical contact 250 so as to compress the coil spring 255, thereby helping to ensure good electrical contact between the inner electrode 375 and the electrical contact 250.
The inner electrode 375 is surrounded by an insulating ring 372, which may be made of plastic, rubber, silicone, or any other suitable material. The insulating ring 372 is surrounded by the cartomizer connector 370, which may be made of a suitable metal which is able to conduct electricity. When the cartomizer 30 is connected to the body 20, the cartomizer connector 370 contacts the body connector 240 of the body 20 to provide a second electrical path between the cartomizer 30 and the body 20. In other words, the inner electrode 375 and the cartomizer connector 370 serve as positive and negative terminals (or vice versa) for supplying power from the battery 210 in the body 20 to the heater 365 in the cartomizer via supply lines 366 and 367 as appropriate.
In one embodiment, the connector 25A is a metallic component having a coating comprising silver and/or gold. In one embodiment, the inner electrode 375 is a metallic component having a coating comprising silver and/or gold. In one embodiment, the cartomizer connector 370 is a metallic component having a coating comprising silver and/or gold. In one embodiment, one or more of the connector 25A, the inner electrode 375, and the cartomizer connector 370 are metallic components having a coating comprising silver and/or gold.
In one embodiment, one, two, three, four, five, six, or every metallic component of the aerosol provision cartridge which is upstream of the aerosol generating chamber (relative to the airflow entering said chamber) and which is outside of the liquid storage region and aerosol generating region has a coating comprising gold and/or silver.
In one embodiment, every metallic component of the aerosol provision cartridge which is upstream of the aerosol generating chamber (relative to the airflow entering said chamber) and which is outside of the liquid storage region and aerosol generating region has a coating comprising gold and/or silver.
In one embodiment, every metallic component of the aerosol provision cartridge outside of the liquid storage region and aerosol generating region has a coating comprising gold and/or silver.
In one embodiment, it may be desirable to ensure that any metallic components that are in contact with airflow through the device are coated with a coating comprising gold and/or silver. In one embodiment, the surface of one or more of metallic components of the aerosol provision cartridge which is in contact with the airflow through the device is coated with a coating comprising gold and/or silver.
In another embodiment, it may be desirable to ensure that one or more metallic components are in contact with the airflow through the aerosol provision cartridge, and are located upstream of an aerosol generating component and entirely outside of a liquid storage region, wherein at least one of the metallic components has a coating comprising at least one of silver or gold.
The cartomizer connector 370 is provided with two lugs or tabs 380A, 380B, which extend in opposite directions away from the longitudinal axis of the e-cigarette 10. These tabs 380A, 380B are used to provide a bayonet fitting in conjunction with the body connector 240 for connecting the cartomizer 30 to the body 20. This bayonet fitting provides a secure and robust connection between the cartomizer 30 and the body 20, so that the cartomizer 30 and body 20 are held in a fixed position relative to one another, without wobble or flexing, and the likelihood of any accidental disconnection is very small. At the same time, the bayonet fitting provides simple and rapid connection and disconnection by an insertion followed by a rotation for connection, and a rotation (in the reverse direction) followed by withdrawal for disconnection. It will be appreciated that other embodiments may use a different form of connection between the body 20 and the cartomizer 30, such as a snap fit or a screw connection.
The body connector 240 extends from this external housing 201 of the body 20. The body connector as shown in
As mentioned above, the cap 225 is provided with an air inlet hole to allow air to flow past sensor 215 when a user inhales on the mouthpiece 35. However, the majority of air that enters the device when a user inhales flows through collar 290 and body connector 240 as indicated by the two arrows in
The liquid storage region component 502 comprises a liquid storage body 506 defining a liquid storage region. The liquid storage region comprises a source liquid from which an aerosol is to be generated. The base of the liquid storage component is open and cooperates with membrane 601 and optionally also liquid distributing component 602. Thus, it will be appreciated that both membrane 601 and component 602 may be dimensioned to be received within the opening of the liquid storage component 502, and they may further form an interference fit with the inner wall of the liquid storage component 502.
The membrane 601 is positioned between the liquid storage region and an aerosol generating region of the system (not shown in
In this regard, the presence of the membrane typically results in a reduced “flow” of liquid compared to the “direct flow” that is seen in other systems of the prior art. The particular construction of the membrane need not be particularly limited, provided that it allows for the source liquid contained within the liquid store to be transferred to the aerosol generating region. It is also generally preferred if the membrane has a degree of heat resistance. In one embodiment, the membrane is formed from a porous material. In one embodiment, the membrane is formed from a porous ceramic material. In one embodiment, the membrane is formed from ceramic fibers. In this regard, ceramic fibers are known to be heat resistant and yet also provide a degree of porosity owing to their structure. Ceramic fibers may also be known as “high-temperature insulation wool” (HTIW). High-temperature insulation wool is an accumulation of fibers of different lengths and diameters, produced synthetically from mineral raw materials. The raw mineral materials are typically melted and then processed into fibers which are then formed into the final material. Different types of HTIW may be available, such as alkaline earth silicate wool, alumina silicate wool, and poly-silicate wool. Alumino silicate wool, also known as “refractory ceramic fiber” (RCF), are amorphous fibers produced by melting a combination of Al2O3 and SiO2, usually in a weight ratio of about 50:50. In one embodiment, the membrane is formed from an alumina silicate wool. In one embodiment, the alumina silicate wool has a Al2O3 content of from 48 to 54% and a SiO2 content of from 46 to 52%. Other raw materials, such as Fe2O3 may also be present in minor amounts. The skilled person is aware of the various considerations for producing high temperature insulation wool. In this regard, a suitable high temperature insulation wool may be obtained from Zibo Dingrong High-Temperature Materials Co., Ltd, Zibo City, Shandong Province, China.
The dimensions of the membrane itself are not particularly limited. Typically, the thickness of the membrane may be in the range 0.1 mm to 2 mm. In one embodiment, the thickness of the membrane may be in the range 0.1 to 1 mm. In one embodiment, the thickness of the membrane may be in the range 0.5 to 1.5 mm. In one embodiment, the thickness of the membrane may be in the range 0.5 to 1 mm.
The shape of the membrane may not be particularly limited. Typically, the membrane has a shape which conforms to the general cross-sectional shape of the liquid storage region. For example, as shown in
However, it may in some circumstances be non-planar where such a configuration is necessary. For example, it may be that the membrane is tubular with the source liquid being stored in a storage region radially outward of the membrane, with the aerosol generating region, including aerosol generating component, being disposed radially inwardly of the tubular membrane.
In some embodiments, at the interface between the aerosol generating region and the liquid storage region, there may be a membrane support (not shown). This membrane support is generally rigid and serves to support the membrane from its underside (the side projecting towards the aerosol generating region). The membrane support is typically metal, and in some cases is produced from stainless steel. The grade of stainless steel used for the membrane support is not particularly limited, and it may be selected from 304L, 316L etc. The membrane support typically spans the liquid provision region of the membrane. In other words, where the membrane is generally circular, the membrane support spans substantially the entire diameter of the membrane. In this regard, the membrane support is typically “I” shaped in that it has a central linear section capped by two substantially linear bars formed at substantially right angles to the central linear section.
The aerosol generating region comprises an aerosol generating component, such as a heater. In some embodiments, the heater takes the form of a wire 701, which may also be coiled. The coiled wire may have a wick 801 running through the longitudinal axis formed by the turns of the coil. This wick may then contact the membrane at point “C” shown for example in
As discussed above, a liquid distribution component 602 may optionally be present in the system between the membrane and the liquid storage region. The liquid distribution component 602 may have the function of providing more controlled wetting of the membrane. Thus, the component 602 has one or more through holes 603 which allow for the source liquid to flow from the liquid storage region onto the membrane. The membrane and the liquid distribution component may generally be disposed such that their central point is in-line with the central longitudinal axis of the system. In this regard, such a configuration (showing the membrane only) is shown in
The reservoir body 506 is generally in the form of a circular cylinder with a flat face 508 running longitudinally along one side. The reservoir body 506 may be formed in accordance with conventional techniques, for example comprising a molded plastics material.
The housing component 510 is generally tubular and circularly symmetric. The housing component 510 comprises a main housing component 512 and a mouthpiece component 514. These may be formed separately or integrally. The main housing component 512 and mouthpiece component 514 may be formed in accordance with conventional techniques, for example comprising extruded aluminum or molded plastic. The main housing component 512 comprises a generally cylindrical tube having an interior dimension conforming to the exterior dimension of the liquid storage component 502. Thus the liquid storage component 502 can be received within the housing component 510 in a close-fitting arrangement, as schematically represented in
As can be seen from the schematic representation in
As discussed briefly above,
The aerosol provision system 500 may also comprise components that correspond substantially to those described earlier with respect to e-cigarette 10. In this regard, aerosol provision system 500 may additionally comprise a screw component and an inner electrode. In one embodiment, the screw component is a metallic component having a coating comprising silver and/or gold. In one embodiment, the inner electrode is a metallic component having a coating comprising silver and/or gold. In one embodiment, both the screw component and the inner electrode are metallic components independently having a coating comprising gold and/or silver.
In one embodiment, the screw component is located outside of the aerosol generating region. In one embodiment, the inner electrode is located outside of the aerosol generating region.
In one embodiment, one, two, three, four, five, six, or every metallic component of the aerosol provision cartridge which is upstream of the aerosol generating chamber (relative to the airflow entering said chamber) and which is outside of the liquid storage region and aerosol generating region has a coating comprising gold and/or silver.
In one embodiment, every metallic component of the aerosol provision cartridge which is upstream of the aerosol generating chamber (relative to the airflow entering said chamber) and which is outside of the liquid storage region and aerosol generating region has a coating comprising gold and/or silver.
In one embodiment, every metallic component of the aerosol provision cartridge outside of the liquid storage region and aerosol generating region has a coating comprising gold and/or silver.
The coated metallic components referred to herein generally have a coating comprising gold and/or silver. In the context of the present invention, a “coating” refers to a outer layer of coating material that may extend over the entire surface of the base metallic component. Alternatively, the coating may not extend over the entire surface of the base metallic component, and instead be limited to discrete areas. Although the term “coating” is used in the present invention, the term “plating” is deemed to be equivalent.
Coating such components has surprisingly led to aerosols that are more acceptable to users. This is explained with further reference to the examples below. Generally, the coating used to coat the metallic components referred to herein comprise at least one of gold and/or silver. In one embodiment, one or more metallic components can comprise more than one metallic component coated with the same coating, or alternatively, the one or more metallic components can comprise more than one metallic component coated with a different coating. In one embodiment, the metallic components referred to herein have a coating comprising at least gold. In one embodiment, the metallic components referred to herein have a coating comprising at least silver. In one embodiment, the metallic components referred to herein have a coating comprising a gold alloy. In one embodiment, the coating comprises gold in an amount of about 99% w/w, with reference to the weight of the coating. In one embodiment, the coating comprises gold in an amount of greater than 99% w/w, with reference to the weight of the coating. In one embodiment, the coating comprises gold in an amount of about 99.7% w/w, with reference to the weight of the coating. In one embodiment, the coating comprises gold in an amount of about 99.9% w/w, with reference to the weight of the coating. Suitable gold containing coatings (also referred to as platings) are defined under standards such as Mil-G-45204, ASTM B488 or AMS 2422. Suitable silver containing coatings (also referred to as platings) are defined under standards such as QQ-S-365, ASTM B700, AMS 2410, AMS 2411 and AMS 2412.
The thickness of the coating on the metallic components must be such that the base metal of the metallic component is not exposed. In one embodiment, the coating on the metallic component(s) is at least 0.001 mm thick. In one embodiment, the coating on the metallic component(s) is at least 0.002 mm thick. In one embodiment, the coating on the metallic component(s) is at least 0.003 mm thick. In one embodiment, the coating on the metallic component(s) is at least 0.004 mm thick. In one embodiment, the coating on the metallic component(s) is at least 0.005 mm thick. In one embodiment, the coating on the metallic component(s) is from 0.001 mm to about 0.005 mm thick. In one embodiment, the coating on the metallic component(s) is from 0.001 mm to about 0.004 mm thick. In one embodiment, the coating on the metallic component(s) is from 0.001 mm to about 0.003 mm thick. In one embodiment, the coating on the metallic component(s) is from 0.001 mm to about 0.002 mm thick. In one embodiment, the coating on the metallic component(s) is from 0.002 mm to about 0.005 mm thick. In one embodiment, the coating on the metallic component(s) is from 0.003 mm to about 0.005 mm thick. In one embodiment, the coating on the metallic component(s) is from 0.004 mm to about 0.005 mm thick. In one embodiment, the coating on the metallic component(s) is about 0.004 mm thick.
The metallic components of the invention are typically brass or stainless steel. In one embodiment, the coated metallic components are brass, coated with a coating comprising gold and/or silver.
In one embodiment, the source liquid comprises nicotine and benzoic acid, and the metallic components are brass, coated with a coating comprising gold.
The general operating principles of the aerosol provision system 500 schematically represented in
In some embodiments, the source liquid comprises nicotine, a carrier and one or more acids. The carrier of the source liquid may be any suitable solvent such that the source liquid can be vaporized for use. In one aspect the solvent is selected from glycerol, propylene glycol (PG) and mixtures thereof. In one aspect the solvent is at least glycerol. In one aspect the solvent consists essentially of glycerol. In one aspect the solvent consists of glycerol. In one aspect the solvent is at least propylene glycol. In one aspect the solvent consists essentially of propylene glycol. In one aspect the solvent consists of propylene glycol. In one aspect the solvent is at least a mixture of propylene glycol and glycerol. In one aspect the solvent consists essentially of a mixture of propylene glycol and glycerol. In one aspect the solvent consists of a mixture of propylene glycol and glycerol.
The carrier of the source liquid may be present in any suitable amount. In one aspect the carrier is present in an amount of 1 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 5 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 10 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 20 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 30 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 40 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 50 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 60 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 70 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 80 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 90 to 98 wt % based on the source liquid. In one aspect the carrier is present in an amount of 1 to 90 wt % based on the source liquid. In one aspect the carrier is present in an amount of 5 to 90 wt % based on the source liquid. In one aspect the carrier is present in an amount of 10 to 90 wt % based on the source liquid. In one aspect the carrier is present in an amount of 20 to 90 wt % based on the source liquid. In one aspect the carrier is present in an amount of 30 to 90 wt % based on the source liquid. In one aspect the carrier is present in an amount of 40 to 90 wt % based on the source liquid. In one aspect the carrier is present in an amount of 50 to 90 wt % based on the source liquid. In one aspect the carrier is present in an amount of 60 to 90 wt % based on the source liquid. In one aspect the carrier is present in an amount of 70 to 90 wt % based on the source liquid. In one aspect the carrier is present in an amount of 80 to 90 wt % based on the source liquid.
In one aspect the source liquid further comprises water. The water may be present in any suitable amount. In one aspect water is present in an amount of 1 to 50 wt % based on the source liquid. In one aspect water is present in an amount of 5 to 50 wt % based on the source liquid. In one aspect water is present in an amount of 10 to 50 wt % based on the source liquid. In one aspect water is present in an amount of 20 to 50 wt % based on the source liquid. In one aspect water is present in an amount of 1 to 40 wt % based on the source liquid. In one aspect water is present in an amount of 5 to 40 wt % based on the source liquid. In one aspect water is present in an amount of 10 to 40 wt % based on the source liquid. In one aspect water is present in an amount of 20 to 40 wt % based on the source liquid. In one aspect water is present in an amount of 1 to 30 wt % based on the source liquid. In one aspect water is present in an amount of 5 to 30 wt % based on the source liquid. In one aspect water is present in an amount of 10 to 30 wt % based on the source liquid. In one aspect water is present in an amount of 20 to 30 wt % based on the source liquid.
In one aspect the combined amount of carrier and water in the source liquid is from 1 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 5 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 10 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 20 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 30 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 40 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 50 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 60 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 70 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 80 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 90 to 98 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 1 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 5 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 10 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 20 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 30 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 40 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 50 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 60 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 70 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 80 to 90 wt % based on the source liquid. In one aspect the combined amount of carrier and water in the source liquid is 90 to 90 wt % based on the source liquid.
The source liquid comprises an acid, such as an organic acid. In one aspect the organic acid is a carboxylic acid. The carboxylic acid may be any suitable carboxylic acid. In one aspect the organic acid is a mono-carboxylic acid. In one aspect the organic acid is selected from the group consisting of acetic acid, lactic acid, benzoic acid, levulinic acid, formic acid, citric acid, pyruvic acid, succinic acid, tartaric acid, oleic acid, sorbic acid, propionic acid, phenylacetic acid, and mixtures thereof. In one embodiment, the source liquid comprises benzoic acid. In one embodiment, the source liquid comprises levulinic acid.
In one embodiment, the total content of acid present in the source liquid is no greater than 1 mole equivalents based on the nicotine. In one embodiment, the total content of acid present in the source liquid is no greater than 0.9 mole equivalents based on the nicotine. In one embodiment, the total content of acid present in the source liquid is no greater than 0.8 mole equivalents based on the nicotine. In one embodiment, the total content of acid present in the source liquid is no greater than 0.7 mole equivalents based on the nicotine. In one embodiment, the total content of acid present in the source liquid is no greater than 0.6 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is no greater than 0.55 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is no greater than 0.5 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is no greater than 0.45 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is no greater than 0.4 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is no greater than 0.35 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is no greater than 0.3 mole equivalents based on the nicotine.
In one aspect the total content of acid present in the source liquid is from 0.1 to 0.6 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is from 0.1 to 0.5 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is from 0.2 to 0.6 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is from 0.1 to 0.4 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is from 0.3 to 0.6 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is from 0.2 to 0.5 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is from 0.3 to 0.5 mole equivalents based on the nicotine. In one aspect the total content of acid present in the source liquid is from 0.2 to 0.4 mole equivalents based on the nicotine.
Nicotine may be provided at any suitable amount depending on the desired dosage when inhaled by the user. In one aspect nicotine is present in an amount of no greater than 6 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.4 to 6 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.8 to 6 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1 to 6 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1.8 to 6 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.4 to 5 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.8 to 5 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1 to 5 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1.8 to 5 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of no greater than 4 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.4 to 4 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.8 to 4 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1 to 4 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1.8 to 4 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of no greater than 3 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.4 to 3 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.8 to 3 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1 to 3 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1.8 to 3 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of no greater than 1.8 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.4 to 1.8 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.5 to 1.8 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.8 to 1.8 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1 to 1.8 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of less than 1.8 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.4 to less than 1.8 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.5 to less than 1.8 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 0.8 to less than 1.8 wt % based on the total weight of the source liquid. In one aspect nicotine is present in an amount of from 1 to less than 1.8 wt % based on the total weight of the source liquid.
The source liquid may comprise a number of other components such as flavorings. The amounts of these components can generally be varied depending on the desired profile of the source liquid. In some embodiments, the flavorings are dissolved in propylene glycol and so the “flavoring” component may be understood as a combination of the PG and the active flavoring compounds. Typical flavoring components may include menthol, and other active compounds providing other sensory flavors such as cherry, smokey, etc.
The acid is typically present in the source liquid as a source of protons with which to protonate the nicotine present in the source liquid. In this regard, nicotine generally exists as a free base in which neither of its nitrogen atoms are “protonated”. The inclusion of an acid in the source liquid provides a source of protons which can protonate the nicotine.
In a further aspect, there is provided an aerosol provision cartridge for use with an aerosol provision system, said cartridge comprising: a liquid storage region in fluid communication with an aerosol generating region; said aerosol generating region configured to be substantially liquid-free; and one or more metallic components, located substantially outside of the aerosol generating region and liquid storage region, wherein at least one of the said metallic components has a coating comprising silver and/or gold.
In this regard, the term an “said aerosol generating region configured to be substantially liquid-free” means that the aerosol generating region is a chamber which is substantially free of liquid during use. In other words, whilst small amounts of condensate may form in the aerosol generating region/chamber, it is intended that in normal use this part of the cartridge will not be a reservoir or store for liquid that is to be vaporized.
In one embodiment, there are no metallic components in the aerosol generating region/chamber, other than the aerosol generating component.
In a further aspect there is provided the use of a metallic component having a coating comprising gold and/or silver in an aerosol provision cartridge to stabilize and/or improve the acceptability of the aerosol to a user. In this regard, the metallic component having a coating comprising gold and/or silver is as defined with respect to the aerosol provision cartridge defined above.
In a further aspect there is provided a method of preventing the deterioration of the sensorial attributes of an aerosol produced from an aerosol provision cartridge comprising utilizing in the construction of the cartridge a metallic component having a coating comprising gold and/or silver. In this regard, the metallic component having a coating comprising gold and/or silver is as defined with respect to the aerosol provision cartridge defined above.
In a further aspect there is provided an aerosol provision system comprising an aerosol provision cartridge as defined herein, and an aerosol provision device comprising a power source and an input means. The aerosol provision device may be as defined above with regard to, for example, the body 20 described with reference to the embodiment of
Thus, described above are examples of aerosol provision systems that can help ameliorate the issues discussed above with regard to the generation of degradation products. The following examples serve to illustrate the surprising benefits of the present system.
An assessment was made of an aerosol provision system comprising metallic components having various coatings. An aerosol provision system (ePen, www.govype.com) was modified such that metallic components of the aerosol provision cartridge which were outside of the aerosol generating region/chamber and liquid storage region were coated with a range of coatings. The coatings assessed contained:
Multiple cartridges were prepared for each example and the liquid storage region of each aerosol provision cartridge was filled with a source liquid comprising nicotine, water, glycerol and an organic acid as set out in Table 1. Thus, for each experiment, Sample 1 contained no organic acid, whereas Samples 2 and 3 contained 0.3 molar equivalents and 0.75 molar equivalents of acid respectively, relative to the nicotine in the source liquid.
Each sample was stored for 14 days at ambient temperature. Additionally, replicates where prepared and stored under “accelerated” conditions of elevated temperatures as follows:
Prior to user assessment of the aerosol, an analysis was carried out of the trace metals (if any) present in the aerosol. The samples comprising metallic components with nickel, gold and silver containing coatings did not lead to unacceptable levels of metals being identified in the aerosol. The samples comprising metallic components with tin containing components had unacceptable levels of metals in the aerosol and were not used in the user assessment of the aerosol.
For the user assessment, six users were asked to rate the aerosol in terms of preference on a scale of 1 to 4, a lower score indicating a higher preference. Their preferences were recorded and the average reference provided.
As can be seen from
In order to address various issues and advance the art, this disclosure shows by way of illustration various embodiments in which the claimed invention(s) may be practiced. The advantages and features of the disclosure are of a representative sample of embodiments only, and are not exhaustive and/or exclusive. They are presented only to assist in understanding and to teach the claimed invention(s). It is to be understood that advantages, embodiments, examples, functions, features, structures, and/or other aspects of the disclosure are not to be considered limitations on the disclosure as defined by the claims or limitations on equivalents to the claims, and that other embodiments may be utilized and modifications may be made without departing from the scope of the claims. Various embodiments may suitably comprise, consist of, or consist essentially of, various combinations of the disclosed elements, components, features, parts, steps, means, etc. other than those specifically described herein, and it will thus be appreciated that features of the dependent claims may be combined with features of the independent claims in combinations other than those explicitly set out in the claims. The disclosure may include other inventions not presently claimed, but which may be claimed in future.
Number | Date | Country | Kind |
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1517361 | Oct 2015 | GB | national |
Filing Document | Filing Date | Country | Kind |
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PCT/GB2016/053051 | 9/30/2016 | WO |
Publishing Document | Publishing Date | Country | Kind |
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WO2017/055866 | 4/6/2017 | WO | A |
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Number | Date | Country | |
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20180279679 A1 | Oct 2018 | US |