AIR CONDITIONER

Information

  • Patent Application
  • 20200363112
  • Publication Number
    20200363112
  • Date Filed
    June 26, 2020
    4 years ago
  • Date Published
    November 19, 2020
    4 years ago
Abstract
In an air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, high efficiency is achieved. In the air conditioner (1), a compressor (100, 200) can be driven without interposing a power conversion device between an AC power source (90, 190) and a motor (70, 170). Thus, it is possible to provide the air conditioner (1) that is environmentally friendly and has a relatively inexpensive configuration.
Description
TECHNICAL FIELD

The present invention relates to an air conditioner that uses refrigerant with a low global warming potential (GWP).


BACKGROUND ART

In recent years, use of refrigerant with a low GWP (hereinafter referred to as low-GWP refrigerant) in air conditioners has been considered from the viewpoint of environmental protection. A dominant example of low-GWP refrigerant is a refrigerant mixture containing 1,2-difluoroethylene.


SUMMARY OF THE INVENTION
Technical Problem

However, the related art giving consideration from the aspect of increasing the efficiency of air conditioners using the foregoing refrigerant is rarely found. For example, in the case of applying the foregoing refrigerant to the air conditioner disclosed in PTL 1 (Japanese Unexamined Patent Application Publication No. 2013-124848), there is an issue of how to achieve high efficiency.


Solution to Problem

An air conditioner according to a first aspect includes a compressor that compresses a refrigerant mixture containing at least 1,2-difluoroethylene, a motor that drives the compressor, and a connection unit that causes power to be supplied from an alternating-current (AC) power source to the motor without frequency conversion.


In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, it is possible to provide the air conditioner that is environmentally friendly and has a relatively inexpensive configuration.


An air conditioner according to a second aspect is the air conditioner according to the first aspect, in which the connection unit directly applies an AC voltage of the AC power source between at least two terminals of the motor.


An air conditioner according to a third aspect is the air conditioner according to the first aspect or the second aspect, in which the AC power source is a single-phase power source.


An air conditioner according to a fourth aspect is the air conditioner according to any one of the first aspect to the third aspect, in which one terminal of the motor is connected in series to an activation circuit.


An air conditioner according to a fifth aspect is the air conditioner according to the fourth aspect, in which the activation circuit is a circuit in which a positive temperature coefficient thermistor and an operation capacitor are connected in parallel to each other.


In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, after the compressor has been activated, the PTC thermistor self-heats and the resistance value thereof increases, and switching to an operation circuit substantially by the operation capacitor occurs. Thus, the compressor enters a state of being capable of outputting a rated torque at appropriate timing.


An air conditioner according to a sixth aspect is the air conditioner according to the first aspect or the second aspect, in which the AC power source is a three-phase power source.


This air conditioner does not require an activation circuit and thus the cost is relatively low.


An air conditioner according to a seventh aspect is the air conditioner according to any one of the first aspect to the sixth aspect, in which the motor is an induction motor.


In this air conditioner, the motor is capable of high output with relatively low cost, and thus the efficiency of the air conditioner can be increased.

    • An air conditioner according to a eighth aspect is the air conditioner according to any of the first through seventh aspects, wherein, the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).


In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) and a coefficient of performance (COP) equal to those of R410A is used.

    • An air conditioner according to a ninth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AA′, A′B, BD, DC′, C′C, CO, and OA that connect the following 7 points:


      point A (68.6, 0.0, 31.4),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point D (0.0, 80.4, 19.6),


      point C′ (19.5, 70.5, 10.0),


      point C (32.9, 67.1, 0.0), and


      point O (100.0, 0.0, 0.0),


      or on the above line segments (excluding the points on the line segments BD, CO, and OA);
    • the line segment AA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),
    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),
    • the line segment DC′ is represented by coordinates (x, 0.0082x2−0.6671x+80.4, −0.0082x2−0.3329x+19.6),
    • the line segment C′C is represented by coordinates (x, 0.0067x2−0.6034x+79.729, −0.0067x2−0.3966x+20.271), and
    • the line segments BD, CO, and OA are straight lines.
    • An air conditioner according to a tenth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments GI, IA, AA′, A′B, BD, DC′, C′C, and CG that connect the following 8 points:


      point G (72.0, 28.0, 0.0),


      point I (72.0, 0.0, 28.0),


      point A (68.6, 0.0, 31.4),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point D (0.0, 80.4, 19.6),


      point C′ (19.5, 70.5, 10.0), and


      point C (32.9, 67.1, 0.0),


      or on the above line segments (excluding the points on the line segments IA, BD, and CG);
    • the line segment AA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),
    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),
    • the line segment DC′ is represented by coordinates (x, 0.0082x2−0.6671x+80.4, −0.0082x2−0.3329x+19.6),
    • the line segment C′C is represented by coordinates (x, 0.0067x2−0.6034x+79.729, −0.0067x2−0.3966x+20.271), and
    • the line segments GI, IA, BD, and CG are straight lines.
    • An air conditioner according to a eleventh aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PN, NK, KA′, A′B, BD, DC′, C′C, and CJ that connect the following 9


      points:


      point J (47.1, 52.9, 0.0),


      point P (55.8, 42.0, 2.2),


      point N (68.6, 16.3, 15.1),


      point K (61.3, 5.4, 33.3),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point D (0.0, 80.4, 19.6),


      point C′ (19.5, 70.5, 10.0), and


      point C (32.9, 67.1, 0.0),


      or on the above line segments (excluding the points on the line segments BD and CJ);
    • the line segment PN is represented by coordinates (x, −0.1135x2+12.112x−280.43, 0.1135x2−13.112x+380.43),
    • the line segment NK is represented by coordinates (x, 0.2421x2−29.955x+931.91, −0.2421x2+28.955x−831.91),
    • the line segment KA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),
    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),
    • the line segment DC′ is represented by coordinates (x, 0.0082x2−0.6671x+80.4, −0.0082x2−0.3329x+19.6),
    • the line segment C′C is represented by coordinates (x, 0.0067x2−0.6034x+79.729, −0.0067x2−0.3966x+20.271), and
    • the line segments JP, BD, and CG are straight lines.
    • An air conditioner according to a twelfth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PL, LM, MA′, A′B, BD, DC′, C′C, and CJ that connect the following 9


      points:


      point J (47.1, 52.9, 0.0),


      point P (55.8, 42.0, 2.2),


      point L (63.1, 31.9, 5.0),


      point M (60.3, 6.2, 33.5),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point D (0.0, 80.4, 19.6),


      point C′ (19.5, 70.5, 10.0), and


      point C (32.9, 67.1, 0.0),


      or on the above line segments (excluding the points on the line segments BD and CJ);
    • the line segment PL is represented by coordinates (x, −0.1135x2+12.112x−280.43, 0.1135x2−13.112x+380.43)
    • the line segment MA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),
    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),
    • the line segment DC′ is represented by coordinates (x, 0.0082x2−0.6671x+80.4, −0.0082x2−0.3329x+19.6),
    • the line segment C′C is represented by coordinates (x, 0.0067x2−0.6034x+79.729, −0.0067x2−0.3966x+20.271), and
    • the line segments JP, LM, BD, and CG are straight lines.
    • An air conditioner according to a thirteenth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LM, MA′, A′B, BF, FT, and TP that connect the following 7 points:


      point P (55.8, 42.0, 2.2),


      point L (63.1, 31.9, 5.0),


      point M (60.3, 6.2, 33.5),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point F (0.0, 61.8, 38.2), and


      point T (35.8, 44.9, 19.3),


      or on the above line segments (excluding the points on the line segment BF);
    • the line segment PL is represented by coordinates (x, −0.1135x2+12.112x−280.43, 0.1135x2−13.112x+380.43),
    • the line segment MA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),
    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),
    • the line segment FT is represented by coordinates (x, 0.0078x2−0.7501x+61.8, −0.0078x2−0.2499x+38.2),
    • the line segment TP is represented by coordinates (x, 0.00672x2−0.7607x+63.525, −0.00672x2−0.2393x+36.475), and
    • the line segments LM and BF are straight lines.
    • An air conditioner according to a fourteenth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LQ, QR, and RP that connect the following 4 points:


      point P (55.8, 42.0, 2.2),


      point L (63.1, 31.9, 5.0),


      point Q (62.8, 29.6, 7.6), and


      point R (49.8, 42.3, 7.9),


      or on the above line segments;
    • the line segment PL is represented by coordinates (x, −0.1135x2+12.112x−280.43, 0.1135x2−13.112x+380.43),
    • the line segment RP is represented by coordinates (x, 0.00672x2−0.7607x+63.525, −0.00672x2−0.2393x+36.475), and
    • the line segments LQ and QR are straight lines.
    • An air conditioner according to a fifth aspect is the air conditioner according to the eighth aspect, wherein, when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments SM, MA′, A′B, BF, FT, and TS that connect the following 6 points:


      point S (62.6, 28.3, 9.1),


      point M (60.3, 6.2, 33.5),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point F (0.0, 61.8, 38.2), and


      point T (35.8, 44.9, 19.3),


      or on the above line segments,
    • the line segment MA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),
    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),
    • the line segment FT is represented by coordinates (x, 0.0078x2−0.7501x+61.8, −0.0078x2−0.2499x+38.2),
    • the line segment TS is represented by coordinates (x, −0.0017x2−0.7869x+70.888, −0.0017x2−0.2131x+29.112), and
    • the line segments SM and BF are straight lines.
    • An air conditioner according to a sixth aspect is the air conditioner according to any of the 1 through seventh aspects, wherein, the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)) and trifluoroethylene (HFO-1123) in a total amount of 99.5 mass % or more based on the entire refrigerant, and
    • the refrigerant comprises 62.0 mass % to 72.0 mass % of HFO-1132(E) based on the entire refrigerant.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) and a coefficient of performance (COP) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.
    • An air conditioner according to a seventeenth aspect is the air conditioner according to any of the first through seventh aspects, wherein, the refrigerant comprises HFO-1132(E) and HFO-1123 in a total amount of 99.5 mass % or more based on the entire refrigerant, and
    • the refrigerant comprises 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire refrigerant.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) and a coefficient of performance (COP) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.
    • An air conditioner according to a eighteenth aspect is the air conditioner according to any of the first through seventh aspects, wherein, the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32),


      wherein
    • when the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum in the refrigerant is respectively represented by x, y, z, and a,
    • if 0<a≤11.1, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines GI, IA, AB, BD′, D′C, and CG that connect the following 6 points:


      point G (0.026a2−1.7478a+72.0, −0.026a2+0.7478a+28.0, 0.0),


      point I (0.026a2−1.7478a+72.0, 0.0, −0.026a2+0.7478a+28.0),


      point A (0.0134a2−1.9681a+68.6, 0.0, −0.0134a2+0.9681a+31.4),


      point B (0.0, 0.0144a2−1.6377a+58.7, −0.0144a2+0.6377a+41.3),


      point D′ (0.0, 0.0224a2+0.968a+75.4, −0.0224a2−1.968a+24.6), and


      point C (−0.2304a2−0.4062a+32.9, 0.2304a2−0.5938a+67.1, 0.0),


      or on the straight lines GI, AB, and D′C (excluding point G, point I, point A, point B, point D′, and point C);
    • if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:


      point G (0.02a2−1.6013a+71.105, −0.02a2+0.6013a+28.895, 0.0),


      point I (0.02a2−1.6013a+71.105, 0.0, −0.02a2+0.6013a+28.895),


      point A (0.0112a2−1.9337a+68.484, 0.0, −0.0112a2+0.9337a+31.516),


      point B (0.0, 0.0075a2−1.5156a+58.199, −0.0075a2+0.5156a+41.801), and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);
    • if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:


      point G (0.0135a2−1.4068a+69.727, −0.0135a2+0.4068a+30.273, 0.0),


      point I (0.0135a2−1.4068a+69.727, 0.0, −0.0135a2+0.4068a+30.273),


      point A (0.0107a2−1.9142a+68.305, 0.0, −0.0107a2+0.9142a+31.695),


      point B (0.0, 0.009a2−1.6045a+59.318, −0.009a2+0.6045a+40.682), and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);
    • if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:


      point G (0.0111a2−1.3152a+68.986, −0.0111a2+0.3152a+31.014, 0.0),


      point I (0.0111a2−1.3152a+68.986, 0.0, −0.0111a2+0.3152a+31.014),


      point A (0.0103a2−1.9225a+68.793, 0.0, −0.0103a2+0.9225a+31.207),


      point B (0.0, 0.0046a2−1.41a+57.286, −0.0046a2+0.41a+42.714), and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W); and
    • if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:


      point G (0.0061a2−0.9918a+63.902, −0.0061a2−0.0082a+36.098, 0.0),


      point I (0.0061a2−0.9918a+63.902, 0.0, −0.0061a2−0.0082a+36.098),


      point A (0.0085a2−1.8102a+67.1, 0.0, −0.0085a2+0.8102a+32.9),


      point B (0.0, 0.0012a2−1.1659a+52.95, −0.0012a2+0.1659a+47.05), and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W).
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) and a coefficient of performance (COP) equal to those of R410A is used.
    • An air conditioner according to a nineteenth aspect is the air conditioner according to any of the first through seventh aspects, wherein, the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32),


      wherein
    • when the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum in the refrigerant is respectively represented by x, y, z, and a,
    • if 0<a≤11.1, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines JK′, K′B, BD′, D′C, and CJ that connect the following 5 points:


      point J (0.0049a2−0.9645a+47.1, −0.0049a2−0.0355a+52.9, 0.0),


      point K′ (0.0514a2−2.4353a+61.7, −0.0323a2+0.4122a+5.9, −0.0191a2+1.0231a+32.4),


      point B (0.0, 0.0144a2−1.6377a+58.7, −0.0144a2+0.6377a+41.3),


      point D′ (0.0, 0.0224a2+0.968a+75.4, −0.0224a2−1.968a+24.6), and


      point C (−0.2304a2−0.4062a+32.9, 0.2304a2−0.5938a+67.1, 0.0),


      or on the straight lines JK′, K′B, and D′C (excluding point J, point B, point D′, and point C);
    • if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:


      point J (0.0243a2−1.4161a+49.725, −0.0243a2+0.4161a+50.275, 0.0),


      point K′ (0.0341a2−2.1977a+61.187, −0.0236a2+0.34a+5.636, −0.0105a2+0.8577a+33.177),


      point B (0.0, 0.0075a2−1.5156a+58.199, −0.0075a2+0.5156a+41.801), and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines JK′ and K′B (excluding point J, point B, and point W);
    • if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:


      point J (0.0246a2−1.4476a+50.184, −0.0246a2+0.4476a+49.816, 0.0),


      point K′ (0.0196a2−1.7863a+58.515, −0.0079a2−0.1136a+8.702, −0.0117a2+0.8999a+32.783),


      point B (0.0, 0.009a2−1.6045a+59.318, −0.009a2+0.6045a+40.682), and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines JK′ and K′B (excluding point J, point B, and point W);
    • if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′A, AB, BW, and WJ that connect the following 5 points:


      point J (0.0183a2−1.1399a+46.493, −0.0183a2+0.1399a+53.507, 0.0),


      point K′ (−0.0051a2+0.0929a+25.95, 0.0, 0.0051a2−1.0929a+74.05),


      point A (0.0103a2−1.9225a+68.793, 0.0, −0.0103a2+0.9225a+31.207),


      point B (0.0, 0.0046a2−1.41a+57.286, −0.0046a2+0.41a+42.714), and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines JK′, K′A, and AB (excluding point J, point B, and point W); and
    • if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′A, AB, BW, and WJ that connect the following 5 points:


      point J (−0.0134a2+1.0956a+7.13, 0.0134a2−2.0956a+92.87, 0.0),


      point K′ (−1.892a+29.443, 0.0, 0.892a+70.557),


      point A (0.0085a2−1.8102a+67.1, 0.0, −0.0085a2+0.8102a+32.9),


      point B (0.0, 0.0012a2−1.1659a+52.95, −0.0012a2+0.1659a+47.05), and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines JK′, K′A, and AB (excluding point J, point B, and point W).
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) and a coefficient of performance (COP) equal to those of R410A is used.
    • An air conditioner according to a twentieth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),


      wherein
    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments IJ, JN, NE, and EI that connect the following 4 points:


      point I (72.0, 0.0, 28.0),


      point J (48.5, 18.3, 33.2),


      point N (27.7, 18.2, 54.1), and


      point E (58.3, 0.0, 41.7),


      or on these line segments (excluding the points on the line segment EI;
    • the line segment IJ is represented by coordinates (0.0236y2−1.7616y+72.0, y, −0.0236y2+0.7616y+28.0);
    • the line segment NE is represented by coordinates (0.012y2−1.9003y+58.3, y, −0.012y2+0.9003y+41.7); and
    • the line segments JN and EI are straight lines.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.
    • An air conditioner according to a twenty-first aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), R32, and R1234yf,


      wherein
    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments MM′, M′N, NV, VG, and GM that connect the following 5 points:


      point M (52.6, 0.0, 47.4),


      point M′ (39.2, 5.0, 55.8),


      point N (27.7, 18.2, 54.1),


      point V (11.0, 18.1, 70.9), and


      point G (39.6, 0.0, 60.4),


      or on these line segments (excluding the points on the line segment GM);
    • the line segment MM′ is represented by coordinates (0.132y2−3.34y+52.6, y, −0.132y2+2.34y+47.4);
    • the line segment M′N is represented by coordinates (0.0596y2−2.2541y+48.98, y, −0.0596y2+1.2541y+51.02);
    • the line segment VG is represented by coordinates (0.0123y2−1.8033y+39.6, y, −0.0123y2+0.8033y+60.4); and
    • the line segments NV and GM are straight lines.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.
    • An air conditioner according to a twenty-second aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), R32, and R1234yf,


      wherein
    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ON, NU, and UO that connect the following 3 points:


      point O (22.6, 36.8, 40.6),


      point N (27.7, 18.2, 54.1), and


      point U (3.9, 36.7, 59.4),


      or on these line segments;
    • the line segment ON is represented by coordinates (0.0072y2−0.6701y+37.512, y, −0.0072y2−0.3299y+62.488);
    • the line segment NU is represented by coordinates (0.0083y2−1.7403y+56.635, y, −0.0083y2+0.7403y+43.365); and
    • the line segment UO is a straight line.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.
    • An air conditioner according to a twenty-third aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), R32, and R1234yf,


      wherein
    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments QR, RT, TL, LK, and KQ that connect the following 5 points:


      point Q (44.6, 23.0, 32.4),


      point R (25.5, 36.8, 37.7),


      point T (8.6, 51.6, 39.8),


      point L (28.9, 51.7, 19.4), and


      point K (35.6, 36.8, 27.6),


      or on these line segments;
    • the line segment QR is represented by coordinates (0.0099y2−1.975y+84.765, y, −0.0099y2+0.975y+15.235);
    • the line segment RT is represented by coordinates (0.0082y2−1.8683y+83.126, y, −0.0082y2+0.8683y+16.874);
    • the line segment LK is represented by coordinates (0.0049y2−0.8842y+61.488, y, −0.0049y2−0.1158y+38.512);
    • the line segment KQ is represented by coordinates (0.0095y2−1.2222y+67.676, y, −0.0095y2+0.2222y+32.324); and
    • the line segment TL is a straight line.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.
    • An air conditioner according to a twenty-fourth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), R32, and R1234yf,


      wherein
    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:


      point P (20.5, 51.7, 27.8),


      point S (21.9, 39.7, 38.4), and


      point T (8.6, 51.6, 39.8),


      or on these line segments;
    • the line segment PS is represented by coordinates (0.0064y2−0.7103y+40.1, y, −0.0064y2−0.2897y+59.9);
    • the line segment ST is represented by coordinates (0.0082y2−1.8683y+83.126, y, −0.0082y2+0.8683y+16.874); and
    • the line segment TP is a straight line.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, a refrigeration capacity (may also be referred to as a cooling capacity or a capacity) equal to those of R410A and classified with lower flammability (Class 2L) in the standard of The American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) is used.
    • An air conditioner according to a fifth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),


      wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments IK, KB′, B′H, HR, RG, and GI that connect the following 6 points:


      point I (72.0, 28.0, 0.0),


      point K (48.4, 33.2, 18.4),


      point B′ (0.0, 81.6, 18.4),


      point H (0.0, 84.2, 15.8),


      point R (23.1, 67.4, 9.5), and


      point G (38.5, 61.5, 0.0),


      or on these line segments (excluding the points on the line segments B′H and GI);
    • the line segment IK is represented by coordinates (0.025z2−1.7429z+72.00, −0.025z2+0.7429z+28.0, z),
    • the line segment HR is represented by coordinates (−0.3123z2+4.234z+11.06, 0.3123z2−5.234z+88.94, z),
    • the line segment RG is represented by coordinates (−0.0491z2−1.1544z+38.5, 0.0491z2+0.1544z+61.5, z), and
    • the line segments KB′ and GI are straight lines.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, and a coefficient of performance (COP) equal to that of R410A is used.
    • An air conditioner according to a twenty-sixth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,


      wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments IJ, JR, RG, and GI that connect the following 4 points:


      point I (72.0, 28.0, 0.0),


      point J (57.7, 32.8, 9.5),


      point R (23.1, 67.4, 9.5), and


      point G (38.5, 61.5, 0.0),


      or on these line segments (excluding the points on the line segment GI);
    • the line segment IJ is represented by coordinates (0.025z2−1.7429z+72.0, −0.025z2+0.7429z+28.0, z),
    • the line segment RG is represented by coordinates (−0.0491z2−1.1544z+38.5, 0.0491z2+0.1544z+61.5, z), and
    • the line segments JR and GI are straight lines.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, and a coefficient of performance (COP) equal to that of R410A is used.
    • An air conditioner according to a twenty-seventh aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,


      wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MP, PB′, B′H, HR, RG, and GM that connect the following 6 points:


      point M (47.1, 52.9, 0.0),


      point P (31.8, 49.8, 18.4),


      point B′ (0.0, 81.6, 18.4),


      point H (0.0, 84.2, 15.8),


      point R (23.1, 67.4, 9.5), and


      point G (38.5, 61.5, 0.0),


      or on these line segments (excluding the points on the line segments B′H and GM);
    • the line segment MP is represented by coordinates (0.0083z2−0.984z+47.1, −0.0083z2−0.016z+52.9, z),
    • the line segment HR is represented by coordinates (−0.3123z2+4.234z+11.06, 0.3123z2−5.234z+88.94, z),
    • the line segment RG is represented by coordinates (−0.0491z2−1.1544z+38.5, 0.0491z2+0.1544z+61.5, z), and
    • the line segments PB′ and GM are straight lines.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, and a coefficient of performance (COP) equal to that of R410A is used.
    • An air conditioner according to a twenty-eighth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,


      wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MN, NR, RG, and GM that connect the following 4 points:


      point M (47.1, 52.9, 0.0),


      point N (38.5, 52.1, 9.5),


      point R (23.1, 67.4, 9.5), and


      point G (38.5, 61.5, 0.0),


      or on these line segments (excluding the points on the line segment GM);
    • the line segment MN is represented by coordinates (0.0083z2−0.984z+47.1, −0.0083z2−0.016z+52.9, z),
    • the line segment RG is represented by coordinates (−0.0491z2−1.1544z+38.5, 0.0491z2+0.1544z+61.5, z), and
    • the line segments JR and GI are straight lines.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, and a coefficient of performance (COP) equal to that of R410A is used.
    • An air conditioner according to a twenty-ninth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,


      wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:


      point P (31.8, 49.8, 18.4),


      point S (25.4, 56.2, 18.4), and


      point T (34.8, 51.0, 14.2),


      or on these line segments;
    • the line segment ST is represented by coordinates (−0.0982z2+0.9622z+40.931, 0.0982z2−1.9622z+59.069, z),
    • the line segment TP is represented by coordinates (0.0083z2−0.984z+47.1, −0.0083z2−0.016z+52.9, z), and
    • the line segment PS is a straight line.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, and a coefficient of performance (COP) equal to that of R410A is used.
    • An air conditioner according to a thirtieth aspect is the air conditioner according to any of the first through seventh aspects, wherein the refrigerant comprises HFO-1132(E), HFO-1123, and R32,


      wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments QB″, B″D, DU, and UQ that connect the following 4 points:


      point Q (28.6, 34.4, 37.0),


      point B″ (0.0, 63.0, 37.0),


      point D (0.0, 67.0, 33.0), and


      point U (28.7, 41.2, 30.1),


      or on these line segments (excluding the points on the line segment B″D);
    • the line segment DU is represented by coordinates (−3.4962z2+210.71z−3146.1, 3.4962z2−211.71z+3246.1, z),
    • the line segment UQ is represented by coordinates (0.0135z2−0.9181z+44.133, −0.0135z2−0.0819z+55.867, z), and
    • the line segments QB″ and B″D are straight lines.
    • In the air conditioner that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor can be driven without interposing a power conversion device between the AC power source and the motor. Thus, the air conditioner that is environmentally friendly and has a relatively inexpensive configuration can also be achieved when a refrigerant having a sufficiently low GWP, and a coefficient of performance (COP) equal to that of R410A is used.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a schematic view of an instrument used for a flammability test.



FIG. 2 is a diagram showing points A to T and line segments that connect these points in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass %.



FIG. 3 is a diagram showing points A to C, D′, G, I, J, and K′, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass %.



FIG. 4 is a diagram showing points A to C, D′, G, I, J, and K′, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 92.9 mass % (the content of R32 is 7.1 mass %).



FIG. 5 is a diagram showing points A to C, D′, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 88.9 mass % (the content of R32 is 11.1 mass %).



FIG. 6 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 85.5 mass % (the content of R32 is 14.5 mass %).



FIG. 7 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 81.8 mass % (the content of R32 is 18.2 mass %).



FIG. 8 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 78.1 mass % (the content of R32 is 21.9 mass %).



FIG. 9 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 73.3 mass % (the content of R32 is 26.7 mass %).



FIG. 10 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 70.7 mass % (the content of R32 is 29.3 mass %).



FIG. 11 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 63.3 mass % (the content of R32 is 36.7 mass %).



FIG. 12 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 55.9 mass % (the content of R32 is 44.1 mass %).



FIG. 13 is a diagram showing points A, B, G, I, J, K′, and W, and line segments that connect these points to each other in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 52.2 mass % (the content of R32 is 47.8 mass %).



FIG. 14 is a view showing points A to C, E, G, and I to W; and line segments that connect points A to C, E, G, and I to W in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass %.



FIG. 15 is a view showing points A to U; and line segments that connect the points in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass %.



FIG. 16 is a configuration diagram of an air conditioner according to one embodiment of the present disclosure.



FIG. 17 is an operation circuit diagram of a motor of a compressor.



FIG. 18 is an operation circuit diagram of a motor of a compressor in an air conditioner according to a modification example.





DESCRIPTION OF EMBODIMENTS
(1) Definition of Terms





    • In the present specification, the term “refrigerant” includes at least compounds that are specified in ISO 817 (International Organization for Standardization), and that are given a refrigerant number (ASHRAE number) representing the type of refrigerant with “R” at the beginning; and further includes refrigerants that have properties equivalent to those of such refrigerants, even though a refrigerant number is not yet given. Refrigerants are broadly divided into fluorocarbon compounds and non-fluorocarbon compounds in terms of the structure of the compounds. Fluorocarbon compounds include chlorofluorocarbons (CFC), hydrochlorofluorocarbons (HCFC), and hydrofluorocarbons (HFC). Non-fluorocarbon compounds include propane (R290), propylene (R1270), butane (R600), isobutane (R600a), carbon dioxide (R744), ammonia (R717), and the like.

    • In the present specification, the phrase “composition comprising a refrigerant” at least includes (1) a refrigerant itself (including a mixture of refrigerants), (2) a composition that further comprises other components and that can be mixed with at least a refrigeration oil to obtain a working fluid for a refrigerating machine, and (3) a working fluid for a refrigerating machine containing a refrigeration oil. In the present specification, of these three embodiments, the composition (2) is referred to as a “refrigerant composition” so as to distinguish it from a refrigerant itself (including a mixture of refrigerants). Further, the working fluid for a refrigerating machine (3) is referred to as a “refrigeration oil-containing working fluid” so as to distinguish it from the “refrigerant composition.”

    • In the present specification, when the term “alternative” is used in a context in which the first refrigerant is replaced with the second refrigerant, the first type of “alternative” means that equipment designed for operation using the first refrigerant can be operated using the second refrigerant under optimum conditions, optionally with changes of only a few parts (at least one of the following: refrigeration oil, gasket, packing, expansion valve, dryer, and other parts) and equipment adjustment. In other words, this type of alternative means that the same equipment is operated with an alternative refrigerant. Embodiments of this type of “alternative” include “drop-in alternative,” “nearly drop-in alternative,” and “retrofit,” in the order in which the extent of changes and adjustment necessary for replacing the first refrigerant with the second refrigerant is smaller.

    • The term “alternative” also includes a second type of “alternative,” which means that equipment designed for operation using the second refrigerant is operated for the same use as the existing use with the first refrigerant by using the second refrigerant. This type of alternative means that the same use is achieved with an alternative refrigerant.

    • In the present specification, the term “refrigerating machine” refers to machines in general that draw heat from an object or space to make its temperature lower than the temperature of ambient air, and maintain a low temperature. In other words, refrigerating machines refer to conversion machines that gain energy from the outside to do work, and that perform energy conversion, in order to transfer heat from where the temperature is lower to where the temperature is higher.

    • In the present specification, a refrigerant having a “WCF lower flammability” means that the most flammable composition (worst case of formulation for flammability: WCF) has a burning velocity of 10 cm/s or less according to the US ANSI/ASHRAE Standard 34-2013. Further, in the present specification, a refrigerant having “ASHRAE lower flammability” means that the burning velocity of WCF is 10 cm/s or less, that the most flammable fraction composition (worst case of fractionation for flammability: WCFF), which is specified by performing a leakage test during storage, shipping, or use based on ANSI/ASHRAE 34-2013 using WCF, has a burning velocity of 10 cm/s or less, and that flammability classification according to the US ANSI/ASHRAE Standard 34-2013 is determined to classified as be “Class 2L.”

    • In the present specification, a refrigerant having an “RCL of x % or more” means that the refrigerant has a refrigerant concentration limit (RCL), calculated in accordance with the US ANSI/ASHRAE Standard 34-2013, of x % or more. RCL refers to a concentration limit in the air in consideration of safety factors. RCL is an index for reducing the risk of acute toxicity, suffocation, and flammability in a closed space where humans are present. RCL is determined in accordance with the ASHRAE Standard. More specifically, RCL is the lowest concentration among the acute toxicity exposure limit (ATEL), the oxygen deprivation limit (ODL), and the flammable concentration limit (FCL), which are respectively calculated in accordance with sections 7.1.1, 7.1.2, and 7.1.3 of the ASHRAE Standard.

    • In the present specification, temperature glide refers to an absolute value of the difference between the initial temperature and the end temperature in the phase change process of a composition containing the refrigerant of the present disclosure in the heat exchanger of a refrigerant system.





(2) Refrigerant
(2-1) Refrigerant Component

Any one of various refrigerants such as refrigerant A, refrigerant B, refrigerant C, refrigerant D, and refrigerant E, details of these refrigerant are to be mentioned later, can be used as the refrigerant.


(2-2) Use of Refrigerant

The refrigerant according to the present disclosure can be preferably used as a working fluid in a refrigerating machine.


The composition according to the present disclosure is suitable for use as an alternative refrigerant for HFC refrigerant such as R410A, R407C and R404 etc, or HCFC refrigerant such as R22 etc.


(3) Refrigerant Composition





    • The refrigerant composition according to the present disclosure comprises at least the refrigerant according to the present disclosure, and can be used for the same use as the refrigerant according to the present disclosure. Moreover, the refrigerant composition according to the present disclosure can be further mixed with at least a refrigeration oil to thereby obtain a working fluid for a refrigerating machine.

    • The refrigerant composition according to the present disclosure further comprises at least one other component in addition to the refrigerant according to the present disclosure. The refrigerant composition according to the present disclosure may comprise at least one of the following other components, if necessary. As described above, when the refrigerant composition according to the present disclosure is used as a working fluid in a refrigerating machine, it is generally used as a mixture with at least a refrigeration oil. Therefore, it is preferable that the refrigerant composition according to the present disclosure does not substantially comprise a refrigeration oil. Specifically, in the refrigerant composition according to the present disclosure, the content of the refrigeration oil based on the entire refrigerant composition is preferably 0 to 1 mass %, and more preferably 0 to 0.1 mass %.





(3-1) Water





    • The refrigerant composition according to the present disclosure may contain a small amount of water. The water content of the refrigerant composition is preferably 0.1 mass % or less based on the entire refrigerant. A small amount of water contained in the refrigerant composition stabilizes double bonds in the molecules of unsaturated fluorocarbon compounds that can be present in the refrigerant, and makes it less likely that the unsaturated fluorocarbon compounds will be oxidized, thus increasing the stability of the refrigerant composition.





(3-2) Tracer





    • A tracer is added to the refrigerant composition according to the present disclosure at a detectable concentration such that when the refrigerant composition has been diluted, contaminated, or undergone other changes, the tracer can trace the changes.

    • The refrigerant composition according to the present disclosure may comprise a single tracer, or two or more tracers.

    • The tracer is not limited, and can be suitably selected from commonly used tracers. Preferably, a compound that cannot be an impurity inevitably mixed in the refrigerant of the present disclosure is selected as the tracer.

    • Examples of tracers include hydrofluorocarbons, hydrochlorofluorocarbons, chlorofluorocarbons, hydrochlorocarbons, fluorocarbons, deuterated hydrocarbons, deuterated hydrofluorocarbons, perfluorocarbons, fluoroethers, brominated compounds, iodinated compounds, alcohols, aldehydes, ketones, and nitrous oxide (N2O). The tracer is particularly preferably a hydrofluorocarbon, a hydrochlorofluorocarbon, a chlorofluorocarbon, a fluorocarbon, a hydrochlorocarbon, a fluorocarbon, or a fluoroether.

    • The following compounds are preferable as the tracer.


      FC-14 (tetrafluoromethane, CF4)


      HCC-40 (chloromethane, CH3Cl)


      HFC-23 (trifluoromethane, CHF3)


      HFC-41 (fluoromethane, CH3Cl)


      HFC-125 (pentafluoroethane, CF3CHF2)


      HFC-134a (1,1,1,2-tetrafluoroethane, CF3CH2F)


      HFC-134 (1,1,2,2-tetrafluoroethane, CHF2CHF2)


      HFC-143a (1,1,1-trifluoroethane, CF3CH3)


      HFC-143 (1,1,2-trifluoroethane, CHF2CH2F)


      HFC-152a (1,1-difluoroethane, CHF2CH3)


      HFC-152 (1,2-difluoroethane, CH2FCH2F)


      HFC-161 (fluoroethane, CH3CH2F)


      HFC-245fa (1,1,1,3,3-pentafluoropropane, CF3CH2CHF2)


      HFC-236fa (1,1,1,3,3,3-hexafluoropropane, CF3CH2CF3)


      HFC-236ea (1,1,1,2,3,3-hexafluoropropane, CF3CHFCHF2)


      HFC-227ea (1,1,1,2,3,3,3-heptafluoropropane, CF3CHFCF3)


      HCFC-22 (chlorodifluoromethane, CHClF2)


      HCFC-31 (chlorofluoromethane, CH2ClF)


      CFC-1113 (chlorotrifluoroethylene, CF2═CClF)


      HFE-125 (trifluoromethyl-difluoromethyl ether, CF3OCHF2)


      HFE-134a (trifluoromethyl-fluoromethyl ether, CF3OCH2F)


      HFE-143a (trifluoromethyl-methyl ether, CF3OCH3)


      HFE-227ea (trifluoromethyl-tetrafluoroethyl ether, CF3OCHFCF3)


      HFE-236fa (trifluoromethyl-trifluoroethyl ether, CF3OCH2CF3)





The tracer compound may be present in the refrigerant composition at a total concentration of about 10 parts per million (ppm) to about 1000 ppm. Preferably, the tracer compound is present in the refrigerant composition at a total concentration of about 30 ppm to about 500 ppm, and most preferably, the tracer compound is present at a total concentration of about 50 ppm to about 300 ppm.


(3-3) Ultraviolet Fluorescent Dye





    • The refrigerant composition according to the present disclosure may comprise a single ultraviolet fluorescent dye, or two or more ultraviolet fluorescent dyes.

    • The ultraviolet fluorescent dye is not limited, and can be suitably selected from commonly used ultraviolet fluorescent dyes.

    • Examples of ultraviolet fluorescent dyes include naphthalimide, coumarin, anthracene, phenanthrene, xanthene, thioxanthene, naphthoxanthene, fluorescein, and derivatives thereof. The ultraviolet fluorescent dye is particularly preferably either naphthalimide or coumarin, or both.





(3-4) Stabilizer





    • The refrigerant composition according to the present disclosure may comprise a single stabilizer, or two or more stabilizers.

    • The stabilizer is not limited, and can be suitably selected from commonly used stabilizers.

    • Examples of stabilizers include nitro compounds, ethers, and amines.

    • Examples of nitro compounds include aliphatic nitro compounds, such as nitromethane and nitroethane; and aromatic nitro compounds, such as nitro benzene and nitro styrene.

    • Examples of ethers include 1,4-dioxane.

    • Examples of amines include 2,2,3,3,3-pentafluoropropylamine and diphenylamine.

    • Examples of stabilizers also include butylhydroxyxylene and benzotriazole.

    • The content of the stabilizer is not limited. Generally, the content of the stabilizer is preferably 0.01 to 5 mass %, and more preferably 0.05 to 2 mass %, based on the entire refrigerant.





(3-5) Polymerization Inhibitor





    • The refrigerant composition according to the present disclosure may comprise a single polymerization inhibitor, or two or more polymerization inhibitors.

    • The polymerization inhibitor is not limited, and can be suitably selected from commonly used polymerization inhibitors.

    • Examples of polymerization inhibitors include 4-methoxy-1-naphthol, hydroquinone, hydroquinone methyl ether, dim ethyl-t-butylphenol, 2,6-di-tert-butyl-p-cresol, and benzotriazole.

    • The content of the polymerization inhibitor is not limited. Generally, the content of the polymerization inhibitor is preferably 0.01 to 5 mass %, and more preferably 0.05 to 2 mass %, based on the entire refrigerant.





(4) Refrigeration Oil—Containing Working Fluid





    • The refrigeration oil-containing working fluid according to the present disclosure comprises at least the refrigerant or refrigerant composition according to the present disclosure and a refrigeration oil, for use as a working fluid in a refrigerating machine. Specifically, the refrigeration oil-containing working fluid according to the present disclosure is obtained by mixing a refrigeration oil used in a compressor of a refrigerating machine with the refrigerant or the refrigerant composition. The refrigeration oil-containing working fluid generally comprises 10 to 50 mass % of refrigeration oil.





(4-1) Refrigeration Oil





    • The refrigeration oil is not limited, and can be suitably selected from commonly used refrigeration oils. In this case, refrigeration oils that are superior in the action of increasing the miscibility with the mixture and the stability of the mixture, for example, are suitably selected as necessary.

    • The base oil of the refrigeration oil is preferably, for example, at least one member selected from the group consisting of polyalkylene glycols (PAG), polyol esters (POE), and polyvinyl ethers (PVE).

    • The refrigeration oil may further contain additives in addition to the base oil. The additive may be at least one member selected from the group consisting of antioxidants, extreme-pressure agents, acid scavengers, oxygen scavengers, copper deactivators, rust inhibitors, oil agents, and antifoaming agents.

    • A refrigeration oil with a kinematic viscosity of 5 to 400 cSt at 40° C. is preferable from the standpoint of lubrication.

    • The refrigeration oil-containing working fluid according to the present disclosure may further optionally contain at least one additive. Examples of additives include compatibilizing agents described below.





(4-2) Compatibilizing Agent





    • The refrigeration oil-containing working fluid according to the present disclosure may comprise a single compatibilizing agent, or two or more compatibilizing agents.

    • The compatibilizing agent is not limited, and can be suitably selected from commonly used compatibilizing agents.

    • Examples of compatibilizing agents include polyoxyalkylene glycol ethers, amides, nitriles, ketones, chlorocarbons, esters, lactones, aryl ethers, fluoroethers, and 1,1,1-trifluoroalkanes. The compatibilizing agent is particularly preferably a polyoxyalkylene glycol ether.





(5) Various Refrigerants

Hereinafter, the refrigerants A to E, which are the refrigerants used in the present embodiment, will be described in detail.


In addition, each description of the following refrigerant A, refrigerant B, refrigerant C, refrigerant D, and refrigerant E is each independent. The alphabet which shows a point or a line segment, the number of an Examples, and the number of a comparative examples are all independent of each other among the refrigerant A, the refrigerant B, the refrigerant C, the refrigerant D, and the refrigerant E. For example, the first embodiment of the refrigerant A and the first embodiment of the refrigerant B are different embodiment from each other.


(5-1) Refrigerant A





    • The refrigerant A according to the present disclosure is a mixed refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).

    • The refrigerant A according to the present disclosure has various properties that are desirable as an R410A-alternative refrigerant, i.e., a refrigerating capacity and a coefficient of performance that are equivalent to those of R410A, and a sufficiently low GWP.

    • The refrigerant A according to the present disclosure is a composition comprising HFO-1132(E) and R1234yf, and optionally further comprising HFO-1123, and may further satisfy the following requirements. This refrigerant also has various properties desirable as an alternative refrigerant for R410A; i.e., it has a refrigerating capacity and a coefficient of performance that are equivalent to those of R410A, and a sufficiently low GWP.





Requirements





    • Preferable refrigerant A is as follows:

    • When the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AA′, A′B, BD, DC′, C′C, CO, and OA that connect the following 7 points:


      point A (68.6, 0.0, 31.4),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point D (0.0, 80.4, 19.6),


      point C′ (19.5, 70.5, 10.0),


      point C (32.9, 67.1, 0.0), and


      point O (100.0, 0.0, 0.0),


      or on the above line segments (excluding the points on the line CO);

    • the line segment AA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),

    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3,

    • the line segment DC′ is represented by coordinates (x, 0.0082x2−0.6671x+80.4, −0.0082x2−0.3329x+19.6),

    • the line segment C′C is represented by coordinates (x, 0.0067x2−0.6034x+79.729, −0.0067x2−0.3966x+20.271), and

    • the line segments BD, CO, and OA are straight lines.

    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 92.5% or more relative to that of R410A.

    • When the mass % of HFO-1132(E), HFO-1123, and R1234yf, based on their sum in the refrigerant A according to the present disclosure is respectively represented by x, y, and z, the refrigerant is preferably a refrigerant wherein coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within a figure surrounded by line segments GI, IA, AA′, A′B, BD, DC′, C′C, and CG that connect the following 8 points:


      point G (72.0, 28.0, 0.0),


      point I (72.0, 0.0, 28.0),


      point A (68.6, 0.0, 31.4),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point D (0.0, 80.4, 19.6),


      point C′ (19.5, 70.5, 10.0), and


      point C (32.9, 67.1, 0.0),


      or on the above line segments (excluding the points on the line segment CG);

    • the line segment AA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),

    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),

    • the line segment DC′ is represented by coordinates (x, 0.0082x2−0.6671x+80.4, −0.0082x2−0.3329x+19.6),

    • the line segment C′C is represented by coordinates (x, 0.0067x2−0.6034x+79.729, −0.0067x2−0.3966x+20.271), and

    • the line segments GI, IA, BD, and CG are straight lines.

    • When the requirements above are satisfied, the refrigerant A according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 92.5% or more relative to that of R410A; furthermore, the refrigerant A has a WCF lower flammability according to the ASHRAE Standard (the WCF composition has a burning velocity of 10 cm/s or less).

    • When the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant according to the present disclosure is respectively represented by x, y, and z, the refrigerant is preferably a refrigerant wherein coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PN, NK, KA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:


      point J (47.1, 52.9, 0.0),


      point P (55.8, 42.0, 2.2),


      point N (68.6, 16.3, 15.1),


      point K (61.3, 5.4, 33.3),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point D (0.0, 80.4, 19.6),


      point C′ (19.5, 70.5, 10.0), and


      point C (32.9, 67.1, 0.0),


      or on the above line segments (excluding the points on the line segment CJ);

    • the line segment PN is represented by coordinates (x, −0.1135x2+12.112x−280.43, 0.1135x2−13.112x+380.43),

    • the line segment NK is represented by coordinates (x, 0.2421x2−29.955x+931.91, −0.2421x2+28.955x−831.91),

    • the line segment KA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),

    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),

    • the line segment DC′ is represented by coordinates (x, 0.0082x2−0.6671x+80.4, −0.0082x2−0.3329x+19.6),

    • the line segment C′C is represented by coordinates (x, 0.0067x2−0.6034x+79.729, −0.0067x2−0.3966x+20.271), and

    • the line segments JP, BD, and CG are straight lines.

    • When the requirements above are satisfied, the refrigerant A according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 92.5% or more relative to that of R410A; furthermore, the refrigerant exhibits a lower flammability (Class 2L) according to the ASHRAE Standard (the WCF composition and the WCFF composition have a burning velocity of 10 cm/s or less).

    • When the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant according to the present disclosure is respectively represented by x, y, and z, the refrigerant is preferably a refrigerant wherein coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PL, LM, MA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:


      point J (47.1, 52.9, 0.0),


      point P (55.8, 42.0, 2.2),


      point L (63.1, 31.9, 5.0),


      point M (60.3, 6.2, 33.5),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point D (0.0, 80.4, 19.6),


      point C′ (19.5, 70.5, 10.0), and


      point (32.9, 67.1, 0.0),


      or on the above line segments (excluding the points on the line segment CJ);

    • the line segment PL is represented by coordinates (x, −0.1135x2+12.112x−280.43, 0.1135x2−13.112x+380.43),

    • the line segment MA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),

    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),

    • the line segment DC′ is represented by coordinates (x, 0.0082x2−0.6671x+80.4, −0.0082x2−0.3329x+19.6),

    • the line segment C′C is represented by coordinates (x, 0.0067x2−0.6034x+79.729, −0.0067x2−0.3966x+20.271), and

    • the line segments JP, LM, BD, and CG are straight lines.





When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 92.5% or more relative to that of R410A; furthermore, the refrigerant has an RCL of 40 g/m3 or more.

    • When the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant A according to the present disclosure is respectively represented by x, y, and z, the refrigerant is preferably a refrigerant wherein coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LM, MA′, A′B, BF, FT, and TP that connect the following 7 points:


      point P (55.8, 42.0, 2.2),


      point L (63.1, 31.9, 5.0),


      point M (60.3, 6.2, 33.5),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point F (0.0, 61.8, 38.2), and


      point T (35.8, 44.9, 19.3),


      or on the above line segments (excluding the points on the line segment BF);
    • the line segment PL is represented by coordinates (x, −0.1135x2+12.112x−280.43, 0.1135x2−13.112x+380.43),
    • the line segment MA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),
    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),
    • the line segment FT is represented by coordinates (x, 0.0078x2−0.7501x+61.8, −0.0078x2−0.2499x+38.2),
    • the line segment TP is represented by coordinates (x, 0.00672x2−0.7607x+63.525, −0.00672x2−0.2393x+36.475), and
    • the line segments LM and BF are straight lines.
    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 95% or more relative to that of R410A; furthermore, the refrigerant has an RCL of 40 g/m3 or more.
    • The refrigerant A according to the present disclosure is preferably a refrigerant wherein when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LQ, QR, and RP that connect the following 4 points:


      point P (55.8, 42.0, 2.2),


      point L (63.1, 31.9, 5.0),


      point Q (62.8, 29.6, 7.6), and


      point R (49.8, 42.3, 7.9),


      or on the above line segments;
    • the line segment PL is represented by coordinates (x, −0.1135x2+12.112x−280.43, 0.1135x2−13.112x+380.43),
    • the line segment RP is represented by coordinates (x, 0.00672x2−0.7607x+63.525, −0.00672x2−0.2393x+36.475), and
    • the line segments LQ and QR are straight lines.
    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP of 95% or more relative to that of R410A, and an RCL of 40 g/m3 or more, furthermore, the refrigerant has a condensation temperature glide of 1° C. or less.
    • The refrigerant A according to the present disclosure is preferably a refrigerant wherein when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments SM, MA′, A′B, BF, FT, and TS that connect the following 6 points:


      point S (62.6, 28.3, 9.1),


      point M (60.3, 6.2, 33.5),


      point A′(30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point F (0.0, 61.8, 38.2), and


      point T (35.8, 44.9, 19.3),


      or on the above line segments,
    • the line segment MA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),
    • the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),
    • the line segment FT is represented by coordinates (x, 0.0078x2−0.7501x+61.8, −0.0078x2−0.2499x+38.2),
    • the line segment TS is represented by coordinates (x, −0.0017x2−0.7869x+70.888, −0.0017x2−0.2131x+29.112), and
    • the line segments SM and BF are straight lines.
    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to that of R410A, a COP of 95% or more relative to that of R410A, and an RCL of 40 g/m3 or more furthermore, the refrigerant has a discharge pressure of 105% or more relative to that of R410A.
    • The refrigerant A according to the present disclosure is preferably a refrigerant wherein when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments Od, dg, gh, and hO that connect the following 4 points:


      point d (87.6, 0.0, 12.4),


      point g (18.2, 55.1, 26.7),


      point h (56.7, 43.3, 0.0), and


      point o (100.0, 0.0, 0.0),


      or on the line segments Od, dg, gh, and hO (excluding the points 0 and h);
    • the line segment dg is represented by coordinates (0.0047y2−1.5177y+87.598, y, −0.0047y2+0.5177y+12.402),
    • the line segment gh is represented by coordinates (−0.0134z2−1.0825z+56.692, 0.0134z2+0.0825z+43.308, z), and
    • the line segments hO and Od are straight lines.
    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to that of R410A, and a COP ratio of 92.5% or more relative to that of R410A.
    • The refrigerant A according to the present disclosure is preferably a refrigerant wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R1234yf, based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments lg, gh, hi, and il that connect the following 4 points:


      point l (72.5, 10.2, 17.3),


      point g (18.2, 55.1, 26.7),


      point h (56.7, 43.3, 0.0), and


      point i (72.5, 27.5, 0.0) or


      on the line segments lg, gh, and il (excluding the points h and i);
    • the line segment lg is represented by coordinates (0.0047y2−1.5177y+87.598, y, −0.0047y2+0.5177y+12.402),
    • the line gh is represented by coordinates (−0.0134z2−1.0825z+56.692, 0.0134z2+0.0825z+43.308, z), and
    • the line segments hi and il are straight lines.
    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to that of R410A, and a COP ratio of 92.5% or more relative to that of R410A; furthermore, the refrigerant has a lower flammability (Class 2L) according to the ASHRAE Standard.
    • The refrigerant A according to the present disclosure is preferably a refrigerant wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments Od, de, ef, and fO that connect the following 4 points:


      point d (87.6, 0.0, 12.4),


      point e (31.1, 42.9, 26.0),


      point f (65.5, 34.5, 0.0), and


      point O (100.0, 0.0, 0.0),


      or on the line segments Od, de, and ef (excluding the points 0 and f);
    • the line segment de is represented by coordinates (0.0047y2−1.5177y+87.598, y, −0.0047y2+0.5177y+12.402),
    • the line segment ef is represented by coordinates (−0.0064z2−1.1565z+65.501, 0.0064z2+0.1565z+34.499, z), and
    • the line segments fO and Od are straight lines.
    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 93.5% or more relative to that of R410A, and a COP ratio of 93.5% or more relative to that of R410A.
    • The refrigerant A according to the present disclosure is preferably a refrigerant wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z,
    • coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments le, ef, fi, and il that connect the following 4 points:


      point l (72.5, 10.2, 17.3),


      point e (31.1, 42.9, 26.0),


      point f (65.5, 34.5, 0.0), and


      point i (72.5, 27.5, 0.0),


      or on the line segments le, ef, and il (excluding the points f and i);
    • the line segment le is represented by coordinates (0.0047y2−1.5177y+87.598, y, −0.0047y2+0.5177y+12.402),
    • the line segment ef is represented by coordinates (−0.0134z2−1.0825z+56.692, 0.0134z2+0.0825z+43.308, z), and
    • the line segments fi and il are straight lines.
    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 93.5% or more relative to that of R410A, and a COP ratio of 93.5% or more relative to that of R410A; furthermore, the refrigerant has a lower flammability (Class 2L) according to the ASHRAE Standard.
    • The refrigerant A according to the present disclosure is preferably a refrigerant wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z,
    • coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments Oa, ab, bc, and cO that connect the following 4 points:


      point a (93.4, 0.0, 6.6),


      point b (55.6, 26.6, 17.8),


      point c (77.6, 22.4, 0.0), and


      point O (100.0, 0.0, 0.0),


      or on the line segments Oa, ab, and bc (excluding the points 0 and c);
    • the line segment ab is represented by coordinates (0.0052y2−1.5588y+93.385, y, −0.0052y2+0.5588y+6.615),
    • the line segment bc is represented by coordinates (−0.0032z2−1.1791z+77.593, 0.0032z2+0.1791z+22.407, z), and
    • the line segments cO and Oa are straight lines.
    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 95% or more relative to that of R410A, and a COP ratio of 95% or more relative to that of R410A.
    • The refrigerant A according to the present disclosure is preferably a refrigerant wherein
    • when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z,
    • coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments kb, bj, and jk that connect the following 3 points:


      point k (72.5, 14.1, 13.4),


      point b (55.6, 26.6, 17.8), and


      point j (72.5, 23.2, 4.3),


      or on the line segments kb, bj, and jk;
    • the line segment kb is represented by coordinates


      (0.0052y2−1.5588y+93.385, y, and −0.0052y2+0.5588y+6.615),
    • the line segment bj is represented by coordinates


      (−0.0032z2−1.1791z+77.593, 0.0032z2+0.1791z+22.407, z), and
    • the line segment jk is a straight line.
    • When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 95% or more relative to that of R410A, and a COP ratio of 95% or more relative to that of R410A; furthermore, the refrigerant has a lower flammability (Class 2L) according to the ASHRAE Standard.
    • The refrigerant according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E), HFO-1123, and R1234yf, as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E), HFO-1123, and R1234yf in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and still more preferably 99.9 mass % or more, based on the entire refrigerant.
    • The refrigerant according to the present disclosure may comprise HFO-1132(E), HFO-1123, and R1234yf in a total amount of 99.5 mass % or more, 99.75 mass % or more, or 99.9 mass % or more, based on the entire refrigerant.
    • Additional refrigerants are not particularly limited and can be widely selected. The mixed refrigerant may contain one additional refrigerant, or two or more additional refrigerants.


(Examples of Refrigerant A)





    • The present disclosure is described in more detail below with reference to Examples of refrigerant A. However, refrigerant A is not limited to the Examples.

    • The GWP of R1234yf and a composition consisting of a mixed refrigerant R410A (R32=50%/R125=50%) was evaluated based on the values stated in the Intergovernmental Panel on Climate Change (IPCC), fourth report. The GWP of HFO-1132(E), which was not stated therein, was assumed to be 1 from HFO-1132a (GWP=1 or less) and HFO-1123 (GWP=0.3, described in WO2015/141678). The refrigerating capacity of R410A and compositions each comprising a mixture of HFO-1132(E), HFO-1123, and R1234yf was determined by performing theoretical refrigeration cycle calculations for the mixed refrigerants using the National Institute of Science and Technology (NIST) and Reference Fluid Thermodynamic and Transport Properties Database (Refprop 9.0) under the following conditions.

    • Further, the RCL of the mixture was calculated with the LFL of HFO-1132(E) being 4.7 vol. %, the LFL of HFO-1123 being 10 vol. %, and the LFL of R1234yf being 6.2 vol. %, in accordance with the ASHRAE Standard 34-2013.


      Evaporating temperature: 5° C.


      Condensation temperature: 45° C.


      Degree of superheating: 5 K


      Degree of subcooling: 5 K


      Compressor efficiency: 70%

    • Tables 1 to 34 show these values together with the GWP of each mixed refrigerant.




















TABLE 1








Comp.
Comp.

Example

Comp.




Comp.
Ex. 2
Ex. 3
Example
2
Example
Ex. 4


Item
Unit
Ex. 1
O
A
1
A′
3
B























HFO-1132(E)
mass %
R410A
100.0
68.6
49.0
30.6
14.1
0.0


HFO-1123
mass %

0.0
0.0
14.9
30.0
44.8
58.7


R1234yf
mass %

0.0
31.4
36.1
39.4
41.1
41.3


GWP

2088
1
2
2
2
2
2


COP ratio
% (relative
100
99.7
100.0
98.6
97.3
96.3
95.5



to 410A)


Refrigerating
% (relative
100
98.3
85.0
85.0
85.0
85.0
85.0


capacity ratio
to 410A)


Condensation
° C.
0.1
0.00
1.98
3.36
4.46
5.15
5.35


glide


Discharge
% (relative
100.0
99.3
87.1
88.9
90.6
92.1
93.2


pressure
to 410A)


RCL
g/m3

30.7
37.5
44.0
52.7
64.0
78.6

























TABLE 2







Comp.

Example

Comp.
Comp.
Example
Comp.




Ex. 5
Example
5
Example
Ex. 6
Ex. 7
7
Ex. 8


Item
Unit
C
4
C′
6
D
E
E′
F
























HFO-1132(E)
mass %
32.9
26.6
19.5
10.9
0.0
58.0
23.4
0.0


HFO-1123
mass %
67.1
68.4
70.5
74.1
80.4
42.0
48.5
61.8


R1234yf
mass %
0.0
5.0
10.0
15.0
19.6
0.0
28.1
38.2


GWP

1
1
1
1
2
1
2
2


COP ratio
% (relative
92.5
92.5
92.5
92.5
92.5
95.0
95.0
95.0



to 410A)


Refrigerating
% (relative
107.4
105.2
102.9
100.5
97.9
105.0
92.5
86.9


capacity ratio
to 410A)


Condensation
° C.
0.16
0.52
0.94
1.42
1.90
0.42
3.16
4.80


glide


Discharge
% (relative
119.5
117.4
115.3
113.0
115.9
112.7
101.0
95.8


pressure
to 410A)


RCL
g/m3
53.5
57.1
62.0
69.1
81.3
41.9
46.3
79.0























TABLE 3







Comp.
Example
Example
Example
Example
Example




Ex. 9
8
9
10
11
12


Item
Unit
J
P
L
N
N′
K






















HFO-1132(E)
mass %
47.1
55.8
63.1
68.6
65.0
61.3


HFO-1123
mass %
52.9
42.0
31.9
16.3
7.7
5.4


R1234yf
mass %
0.0
2.2
5.0
15.1
27.3
33.3


GWP

1
1
1
1
2
2


COP ratio
% (relative
93.8
95.0
96.1
97.9
99.1
99.5



to 410A)


Refrigerating
% (relative
106.2
104.1
101.6
95.0
88.2
85.0


capacity ratio
to 410A)


Condensation
° C.
0.31
0.57
0.81
1.41
2.11
2.51


glide


Discharge
% (relative
115.8
111.9
107.8
99.0
91.2
87.7


pressure
to 410A)


RCL
g/m3
46.2
42.6
40.0
38.0
38.7
39.7
























TABLE 4







Example
Example
Example
Example
Example
Example
Example




13
14
15
16
17
18
19


Item
Unit
L
M
Q
R
S
S′
T























HFO-1132(E)
mass %
63.1
60.3
62.8
49.8
62.6
50.0
35.8


HFO-1123
mass %
31.9
6.2
29.6
42.3
28.3
35.8
44.9


R1234yf
mass %
5.0
33.5
7.6
7.9
9.1
14.2
19.3


GWP

1
2
1
1
1
1
2


COP ratio
% (relative
96.1
99.4
96.4
95.0
96.6
95.8
95.0



to 410A)


Refrigerating
% (relative
101.6
85.0
100.2
101.7
99.4
98.1
96.7


capacity ratio
to 410A)


Condensation
° C.
0.81
2.58
1.00
1.00
1.10
1.55
2.07


glide


Discharge
% (relative
107.8
87.9
106.0
109.6
105.0
105.0
105.0


pressure
to 410A)


RCL
g/m3
40.0
40.0
40.0
44.8
40.0
44.4
50.8




















TABLE 5







Comp.
Example
Example




Ex. 10
20
21


Item
Unit
G
H
I



















HFO-1132(E)
mass %
72.0
72.0
72.0


HFO-1123
mass %
28.0
14.0
0.0


R1234yf
mass %
0.0
14.0
28.0


GWP

1
1
2


COP ratio
% (relative
96.6
98.2
99.9



to 410A)


Refrigerating
% (relative
103.1
95.1
86.6


capacity ratio
to 410A)


Condensation glide
° C.
0.46
1.27
1.71


Discharge pressure
% (relative
108.4
98.7
88.6



to 410A)


RCL
g/m3
37.4
37.0
36.6

























TABLE 6







Comp.
Comp.
Example
Example
Example
Example
Example
Comp.


Item
Unit
Ex. 11
Ex. 12
22
23
24
25
26
Ex. 13
























HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0


HFO-1123
mass %
85.0
75.0
65.0
55.0
45.0
35.0
25.0
15.0


R1234yf
mass %
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0


GWP

1
1
1
1
1
1
1
1


COP ratio
% (relative
91.4
92.0
92.8
93.7
94.7
95.8
96.9
98.0



to 410A)


Refrigerating
% (relative
105.7
105.5
105.0
104.3
103.3
102.0
100.6
99.1


capacity ratio
to 410A)


Condensation
° C.
0.40
0.46
0.55
0.66
0.75
0.80
0.79
0.67


glide


Discharge
% (relative
120.1
118.7
116.7
114.3
111.6
108.7
105.6
102.5


pressure
to 410A)


RCL
g/m3
71.0
61.9
54.9
49.3
44.8
41.0
37.8
35.1

























TABLE 7







Comp.
Example
Example
Example
Example
Example
Example
Comp.


Item
Unit
Ex. 14
27
28
29
30
31
32
Ex. 15
























HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0


HFO-1123
mass %
80.0
70.0
60.0
50.0
40.0
30.0
20.0
10.0


R1234yf
mass %
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0


GWP

1
1
1
1
1
1
1
1


COP ratio
% (relative
91.9
92.5
93.3
94.3
95.3
96.4
97.5
98.6



to 410A)


Refrigerating
% (relative
103.2
102.9
102.4
101.5
100.5
99.2
97.8
96.2


capacity ratio
to 410A)


Condensation
° C.
0.87
0.94
1.03
1.12
1.18
1.18
1.09
0.88


glide


Discharge
% (relative
116.7
115.2
113.2
110.8
108.1
105.2
102.1
99.0


pressure
to 410A)


RCL
g/m3
70.5
61.6
54.6
49.1
44.6
40.8
37.7
35.0

























TABLE 8







Comp.
Example
Example
Example
Example
Example
Example
Comp.


Item
Unit
Ex. 16
33
34
35
36
37
38
Ex. 17
























HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0


HFO-1123
mass %
75.0
65.0
55.0
45.0
35.0
25.0
15.0
5.0


R1234yf
mass %
15.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0


GWP

1
1
1
1
1
1
1
1


COP ratio
% (relative
92.4
93.1
93.9
94.8
95.9
97.0
98.1
99.2



to 410A)


Refrigerating
% (relative
100.5
100.2
99.6
98.7
97.7
96.4
94.9
93.2


capacity ratio
to 410A)


Condensation
° C.
1.41
1.49
1.56
1.62
1.63
1.55
1.37
1.05


glide


Discharge
% (relative
113.1
111.6
109.6
107.2
104.5
101.6
98.6
95.5


pressure
to 410A)


RCL
g/m3
70.0
61.2
54.4
48.9
44.4
40.7
37.5
34.8
























TABLE 9







Example
Example
Example
Example
Example
Example
Example


Item
Unit
39
40
41
42
43
44
45























HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0


HFO-1123
mass %
70.0
60.0
50.0
40.0
30.0
20.0
10.0


R1234yf
mass %
20.0
20.0
20.0
20.0
20.0
20.0
20.0


GWP

2
2
2
2
2
2
2


COP ratio
% (relative
93.0
93.7
94.5
95.5
96.5
97.6
98.7



to 410A)


Refrigerating
% (relative
97.7
97.4
96.8
95.9
94.7
93.4
91.9


capacity ratio
to 410A)


Condensation
° C.
2.03
2.09
2.13
2.14
2.07
1.91
1.61


glide


Discharge
% (relative
109.4
107.9
105.9
103.5
100.8
98.0
95.0


pressure
to 410A)


RCL
g/m3
69.6
60.9
54.1
48.7
44.2
40.5
37.4
























TABLE 10







Example
Example
Example
Example
Example
Example
Example


Item
Unit
46
47
48
49
50
51
52























HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0


HFO-1123
mass %
65.0
55.0
45.0
35.0
25.0
15.0
5.0


R1234yf
mass %
25.0
25.0
25.0
25.0
25.0
25.0
25.0


GWP

2
2
2
2
2
2
2


COP ratio
% (relative
93.6
94.3
95.2
96.1
97.2
98.2
99.3



to 410A)


Refrigerating
% (relative
94.8
94.5
93.8
92.9
91.8
90.4
88.8


capacity ratio
to 410A)


Condensation
° C.
2.71
2.74
2.73
2.66
2.50
2.22
1.78


glide


Discharge
% (relative
105.5
104.0
102.1
99.7
97.1
94.3
91.4


pressure
to 410A)


RCL
g/m3
69.1
60.5
53.8
48.4
44.0
40.4
37.3























TABLE 11







Example
Example
Example
Example
Example
Example


Item
Unit
53
54
55
56
57
58






















HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0
60.0


HFO-1123
mass %
60.0
50.0
40.0
30.0
20.0
10.0


R1234yf
mass %
30.0
30.0
30.0
30.0
30.0
30.0


GWP

2
2
2
2
2
2


COP ratio
% (relative
94.3
95.0
95.9
96.8
97.8
98.9



to 410A)


Refrigerating
% (relative
91.9
91.5
90.8
89.9
88.7
87.3


capacity ratio
to 410A)


Condensation
° C.
3.46
3.43
3.35
3.18
2.90
2.47


glide


Discharge
% (relative
101.6
100.1
98.2
95.9
93.3
90.6


pressure
to 410A)


RCL
g/m3
68.7
60.2
53.5
48.2
43.9
40.2























TABLE 12







Example
Example
Example
Example
Example
Comp.


Item
Unit
59
60
61
62
63
Ex. 18






















HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0
60.0


HFO-1123
mass %
55.0
45.0
35.0
25.0
15.0
5.0


R1234yf
mass %
35.0
35.0
35.0
35.0
35.0
35.0


GWP

2
2
2
2
2
2


COP ratio
% (relative
95.0
95.8
96.6
97.5
98.5
99.6



to 410A)


Refrigerating
% (relative
88.9
88.5
87.8
86.8
85.6
84.1


capacity ratio
to 410A)


Condensation
° C.
4.24
4.15
3.96
3.67
3.24
2.64


glide


Discharge
% (relative
97.6
96.1
94.2
92.0
89.5
86.8


pressure
to 410A)


RCL
g/m3
68.2
59.8
53.2
48.0
43.7
40.1






















TABLE 13







Example
Example
Comp.
Comp.
Comp.


Item
Unit
64
65
Ex. 19
Ex. 20
Ex. 21





















HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0


HFO-1123
mass %
50.0
40.0
30.0
20.0
10.0


R1234yf
mass %
40.0
40.0
40.0
40.0
40.0


GWP

2
2
2
2
2


COP ratio
% (relative
95.9
96.6
97.4
98.3
99.2



to 410A)


Refrigerating
% (relative
85.8
85.4
84.7
83.6
82.4


capacity ratio
to 410A)


Condensation
° C.
5.05
4.85
4.55
4.10
3.50


glide


Discharge
% (relative
93.5
92.1
90.3
88.1
85.6


pressure
to 410A)


RCL
g/m3
67.8
59.5
53.0
47.8
43.5

























TABLE 14







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
66
67
68
69
70
71
72
73
























HFO-1132(E)
mass %
54.0
56.0
58.0
62.0
52.0
54.0
56.0
58.0


HFO-1123
mass %
41.0
39.0
37.0
33.0
41.0
39.0
37.0
35.0


R1234yf
mass %
5.0
5.0
5.0
5.0
7.0
7.0
7.0
7.0


GWP

1
1
1
1
1
1
1
1


COP ratio
% (relative
95.1
95.3
95.6
96.0
95.1
95.4
95.6
95.8



to 410A)


Refrigerating
% (relative
102.8
102.6
102.3
101.8
101.9
101.7
101.5
101.2


capacity ratio
to 410A)


Condensation
° C.
0.78
0.79
0.80
0.81
0.93
0.94
0.95
0.95


glide


Discharge
% (relative
110.5
109.9
109.3
108.1
109.7
109.1
108.5
107.9


pressure
to 410A)


RCL
g/m3
43.2
42.4
41.7
40.3
43.9
43.1
42.4
41.6

























TABLE 15







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
74
75
76
77
78
79
80
81
























HFO-1132(E)
mass %
60.0
62.0
61.0
58.0
60.0
62.0
52.0
54.0


HFO-1123
mass %
33.0
31.0
29.0
30.0
28.0
26.0
34.0
32.0


R1234yf
mass %
7.0
7.0
10.0
12.0
12.0
12.0
14.0
14.0


GWP

1
1
1
1
1
1
1
1


COP ratio
% (relative
96.0
96.2
96.5
96.4
96.6
96.8
96.0
96.2



to 410A)


Refrigerating
% (relative
100.9
100.7
99.1
98.4
98.1
97.8
98.0
97.7


capacity ratio
to 410A)


Condensation
° C.
0.95
0.95
1.18
1.34
1.33
1.32
1.53
1.53


glide


Discharge
% (relative
107.3
106.7
104.9
104.4
103.8
103.2
104.7
104.1


pressure
to 410A)


RCL
g/m3
40.9
40.3
40.5
41.5
40.8
40.1
43.6
42.9

























TABLE 16







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
82
83
84
85
86
87
88
89
























HFO-1132(E)
mass %
56.0
58.0
60.0
48.0
50.0
52.0
54.0
56.0


HFO-1123
mass %
30.0
28.0
26.0
36.0
34.0
32.0
30.0
28.0


R1234yf
mass %
14.0
14.0
14.0
16.0
16.0
16.0
16.0
16.0


GWP

1
1
1
1
1
1
1
1


COP ratio
% (relative
96.4
96.6
96.9
95.8
96.0
96.2
96.4
96.7



to 410A)


Refrigerating
% (relative
97.5
97.2
96.9
97.3
97.1
96.8
96.6
96.3


capacity ratio
to 410A)


Condensation
° C.
1.51
1.50
1.48
1.72
1.72
1.71
1.69
1.67


glide


Discharge
% (relative
103.5
102.9
102.3
104.3
103.8
103.2
102.7
102.1


pressure
to 410A)


RCL
g/m3
42.1
41.4
40.7
45.2
44.4
43.6
42.8
42.1

























TABLE 17







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
90
91
92
93
94
95
96
97
























HFO-1132(E)
mass %
58.0
60.0
42.0
44.0
46.0
48.0
50.0
52.0


HFO-1123
mass %
26.0
24.0
40.0
38.0
36.0
34.0
32.0
30.0


R1234yf
mass %
16.0
16.0
18.0
18.0
18.0
18.0
18.0
18.0


GWP

1
1
2
2
2
2
2
2


COP ratio
% (relative
96.9
97.1
95.4
95.6
95.8
96.0
96.3
96.5



to 410A)


Refrigerating
% (relative
96.1
95.8
96.8
96.6
96.4
96.2
95.9
95.7


capacity ratio
to 410A)


Condensation
° C.
1.65
1.63
1.93
1.92
1.92
1.91
1.89
1.88


glide


Discharge
% (relative
101.5
100.9
104.5
103.9
103.4
102.9
102.3
101.8


pressure
to 410A)


RCL
g/m3
41.4
40.7
47.8
46.9
46.0
45.1
44.3
43.5

























TABLE 18







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
98
99
100
101
102
103
104
105
























HFO-1132(E)
mass %
54.0
56.0
58.0
60.0
36.0
38.0
42.0
44.0


HFO-1123
mass %
28.0
26.0
24.0
22.0
44.0
42.0
38.0
36.0


R1234yf
mass %
18.0
18.0
18.0
18.0
20.0
20.0
20.0
20.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
96.7
96.9
97.1
97.3
95.1
95.3
95.7
95.9



to 410A)


Refrigerating
% (relative
95.4
95.2
94.9
94.6
96.3
96.1
95.7
95.4


capacity ratio
to 410A)


Condensation
° C.
1.86
1.83
1.80
1.77
2.14
2.14
2.13
2.12


glide


Discharge
% (relative
101.2
100.6
100.0
99.5
104.5
104.0
103.0
102.5


pressure
to 410A)


RCL
g/m3
42.7
42.0
41.3
40.6
50.7
49.7
47.7
46.8

























TABLE 19







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
106
107
108
109
110
111
112
113
























HFO-1132(E)
mass %
46.0
48.0
52.0
54.0
56.0
58.0
34.0
36.0


HFO-1123
mass %
34.0
32.0
28.0
26.0
24.0
22.0
44.0
42.0


R1234yf
mass %
20.0
20.0
20.0
20.0
20.0
20.0
22.0
22.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
96.1
96.3
96.7
96.9
97.2
97.4
95.1
95.3



to 410A)


Refrigerating
% (relative
95.2
95.0
94.5
94.2
94.0
93.7
95.3
95.1


capacity ratio
to 410A)


Condensation
° C.
2.11
2.09
2.05
2.02
1.99
1.95
2.37
2.36


glide


Discharge
% (relative
101.9
101.4
100.3
99.7
99.2
98.6
103.4
103.0


pressure
to 410A)


RCL
g/m3
45.9
45.0
43.4
42.7
41.9
41.2
51.7
50.6

























TABLE 20







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
114
115
116
117
118
119
120
121
























HFO-1132(E)
mass %
38.0
40.0
42.0
44.0
46.0
48.0
50.0
52.0


HFO-1123
mass %
40.0
38.0
36.0
34.0
32.0
30.0
28.0
26.0


R1234yf
mass %
22.0
22.0
22.0
22.0
22.0
22.0
22.0
22.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
95.5
95.7
95.9
96.1
96.4
96.6
96.8
97.0



to 410A)


Refrigerating
% (relative
94.9
94.7
94.5
94.3
94.0
93.8
93.6
93.3


capacity ratio
to 410A)


Condensation
° C.
2.36
2.35
2.33
2.32
2.30
2.27
2.25
2.21


glide


Discharge
% (relative
102.5
102.0
101.5
101.0
100.4
99.9
99.4
98.8


pressure
to 410A)


RCL
g/m3
49.6
48.6
47.6
46.7
45.8
45.0
44.1
43.4

























TABLE 21







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
122
123
124
125
126
127
128
129
























HFO-1132(E)
mass %
54.0
56.0
58.0
60.0
32.0
34.0
36.0
38.0


HFO-1123
mass %
24.0
22.0
20.0
18.0
44.0
42.0
40.0
38.0


R1234yf
mass %
22.0
22.0
22.0
22.0
24.0
24.0
24.0
24.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
97.2
97.4
97.6
97.9
95.2
95.4
95.6
95.8



to 410A)


Refrigerating
% (relative
93.0
92.8
92.5
92.2
94.3
94.1
93.9
93.7


capacity ratio
to 410A)


Condensation
° C.
2.18
2.14
2.09
2.04
2.61
2.60
2.59
2.58


glide


Discharge
% (relative
98.2
97.7
97.1
96.5
102.4
101.9
101.5
101.0


pressure
to 410A)


RCL
g/m3
42.6
41.9
41.2
40.5
52.7
51.6
50.5
49.5

























TABLE 22







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
130
131
132
133
134
135
136
137
























HFO-1132(E)
mass %
40.0
42.0
44.0
46.0
48.0
50.0
52.0
54.0


HFO-1123
mass %
36.0
34.0
32.0
30.0
28.0
26.0
24.0
22.0


R1234yf
mass %
24.0
24.0
24.0
24.0
24.0
24.0
24.0
24.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
96.0
96.2
96.4
96.6
96.8
97.0
97.2
97.5



to 410A)


Refrigerating
% (relative
93.5
93.3
93.1
92.8
92.6
92.4
92.1
91.8


capacity ratio
to 410A)


Condensation
° C.
2.56
2.54
2.51
2.49
2.45
2.42
2.38
2.33


glide


Discharge
% (relative
100.5
100.0
99.5
98.9
98.4
97.9
97.3
96.8


pressure
to 410A)


RCL
g/m3
48.5
47.5
46.6
45.7
44.9
44.1
43.3
42.5

























TABLE 23







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
138
139
140
141
142
143
144
145
























HFO-1132(E)
mass %
56.0
58.0
60.0
30.0
32.0
34.0
36.0
38.0


HFO-1123
mass %
20.0
18.0
16.0
44.0
42.0
40.0
38.0
36.0


R1234yf
mass %
24.0
24.0
24.0
26.0
26.0
26.0
26.0
26.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
97.7
97.9
98.1
95.3
95.5
95.7
95.9
96.1



to 410A)


Refrigerating
% (relative
91.6
91.3
91.0
93.2
93.1
92.9
92.7
92.5


capacity ratio
to 410A)


Condensation
° C.
2.28
2.22
2.16
2.86
2.85
2.83
2.81
2.79


glide


Discharge
% (relative
96.2
95.6
95.1
101.3
100.8
100.4
99.9
99.4


pressure
to 410A)


RCL
g/m3
41.8
41.1
40.4
53.7
52.6
51.5
50.4
49.4

























TABLE 24







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
146
147
148
149
150
151
152
153
























HFO-1132(E)
mass %
40.0
42.0
44.0
46.0
48.0
50.0
52.0
54.0


HFO-1123
mass %
34.0
32.0
30.0
28.0
26.0
24.0
22.0
20.0


R1234yf
mass %
26.0
26.0
26.0
26.0
26.0
26.0
26.0
26.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
96.3
96.5
96.7
96.9
97.1
97.3
97.5
97.7



to 410A)


Refrigerating
% (relative
92.3
92.1
91.9
91.6
91.4
91.2
90.9
90.6


capacity ratio
to 410A)


Condensation
° C.
2.77
2.74
2.71
2.67
2.63
2.59
2.53
2.48


glide


Discharge
% (relative
99.0
98.5
97.9
97.4
96.9
96.4
95.8
95.3


pressure
to 410A)


RCL
g/m3
48.4
47.4
46.5
45.7
44.8
44.0
43.2
42.5

























TABLE 25







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
154
155
156
157
158
159
160
161
























HFO-1132(E)
mass %
56.0
58.0
60.0
30.0
32.0
34.0
36.0
38.0


HFO-1123
mass %
18.0
16.0
14.0
42.0
40.0
38.0
36.0
34.0


R1234yf
mass %
26.0
26.0
26.0
28.0
28.0
28.0
28.0
28.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
97.9
98.2
98.4
95.6
95.8
96.0
96.2
96.3



to 410A)


Refrigerating
% (relative
90.3
90.1
89.8
92.1
91.9
91.7
91.5
91.3


capacity ratio
to 410A)


Condensation
° C.
2.42
2.35
2.27
3.10
3.09
3.06
3.04
3.01


glide


Discharge
% (relative
94.7
94.1
93.6
99.7
99.3
98.8
98.4
97.9


pressure
to 410A)


RCL
g/m3
41.7
41.0
40.3
53.6
52.5
51.4
50.3
49.3

























TABLE 26







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
162
163
164
165
166
167
168
169
























HFO-1132(E)
mass %
40.0
42.0
44.0
46.0
48.0
50.0
52.0
54.0


HFO-1123
mass %
32.0
30.0
28.0
26.0
24.0
22.0
20.0
18.0


R1234yf
mass %
28.0
28.0
28.0
28.0
28.0
28.0
28.0
28.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
96.5
96.7
96.9
97.2
97.4
97.6
97.8
98.0



to 410A)


Refrigerating
% (relative
91.1
90.9
90.7
90.4
90.2
89.9
89.7
89.4


capacity ratio
to 410A)


Condensation
° C.
2.98
2.94
2.90
2.85
2.80
2.75
2.68
2.62


glide


Discharge
% (relative
97.4
96.9
96.4
95.9
95.4
94.9
94.3
93.8


pressure
to 410A)


RCL
g/m3
48.3
47.4
46.4
45.6
44.7
43.9
43.1
42.4

























TABLE 27







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
170
171
172
173
174
175
176
177
























HFO-1132(E)
mass %
56.0
58.0
60.0
32.0
34.0
36.0
38.0
42.0


HFO-1123
mass %
16.0
14.0
12.0
38.0
36.0
34.0
32.0
28.0


R1234yf
mass %
28.0
28.0
28.0
30.0
30.0
30.0
30.0
30.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
98.2
98.4
98.6
96.1
96.2
96.4
96.6
97.0



to 410A)


Refrigerating
% (relative
89.1
88.8
88.5
90.7
90.5
90.3
90.1
89.7


capacity ratio
to 410A)


Condensation
° C.
2.54
2.46
2.38
3.32
3.30
3.26
3.22
3.14


glide


Discharge
% (relative
93.2
92.6
92.1
97.7
97.3
96.8
96.4
95.4


pressure
to 410A)


RCL
g/m3
41.7
41.0
40.3
52.4
51.3
50.2
49.2
47.3

























TABLE 28







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
178
179
180
181
182
183
184
185
























HFO-1132(E)
mass %
44.0
46.0
48.0
50.0
52.0
54.0
56.0
58.0


HFO-1123
mass %
26.0
24.0
22.0
20.0
18.0
16.0
14.0
12.0


R1234yf
mass %
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
97.2
97.4
97.6
97.8
98.0
98.3
98.5
98.7



to 410A)


Refrigerating
% (relative
89.4
89.2
89.0
88.7
88.4
88.2
87.9
87.6


capacity ratio
to 410A)


Condensation
° C.
3.08
3.03
2.97
2.90
2.83
2.75
2.66
2.57


glide


Discharge
% (relative
94.9
94.4
93.9
93.3
92.8
92.3
91.7
91.1


pressure
to 410A)


RCL
g/m3
46.4
45.5
44.7
43.9
43.1
42.3
41.6
40.9

























TABLE 29







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
186
187
188
189
190
191
192
193
























HFO-1132(E)
mass %
30.0
32.0
34.0
36.0
38.0
40.0
42.0
44.0


HFO-1123
mass %
38.0
36.0
34.0
32.0
30.0
28.0
26.0
24.0


R1234yf
mass %
32.0
32.0
32.0
32.0
32.0
32.0
32.0
32.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
96.2
96.3
96.5
96.7
96.9
97.1
97.3
97.5



to 410A)


Refrigerating
% (relative
89.6
89.5
89.3
89.1
88.9
88.7
88.4
88.2


capacity ratio
to 410A)


Condensation
° C.
3.60
3.56
3.52
3.48
3.43
3.38
3.33
3.26


glide


Discharge
% (relative
96.6
96.2
95.7
95.3
94.8
94.3
93.9
93.4


pressure
to 410A)


RCL
g/m3
53.4
52.3
51.2
50.1
49.1
48.1
47.2
46.3

























TABLE 30







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
194
195
196
197
198
199
200
201
























HFO-1132(E)
mass %
46.0
48.0
50.0
52.0
54.0
56.0
58.0
60.0


HFO-1123
mass %
22.0
20.0
18.0
16.0
14.0
12.0
10.0
8.0


R1234yf
mass %
32.0
32.0
32.0
32.0
32.0
32.0
32.0
32.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
97.7
97.9
98.1
98.3
98.5
98.7
98.9
99.2



to 410A)


Refrigerating
% (relative
88.0
87.7
87.5
87.2
86.9
86.6
86.3
86.0


capacity ratio
to 410A)


Condensation
° C.
3.20
3.12
3.04
2.96
2.87
2.77
2.66
2.55


glide


Discharge
% (relative
92.8
92.3
91.8
91.3
90.7
90.2
89.6
89.1


pressure
to 410A)


RCL
g/m3
45.4
44.6
43.8
43.0
42.3
41.5
40.8
40.2

























TABLE 31







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
202
203
204
205
206
207
208
209
























HFO-1132(E)
mass %
30.0
32.0
34.0
36.0
38.0
40.0
42.0
44.0


HFO-1123
mass %
36.0
34.0
32.0
30.0
28.0
26.0
24.0
22.0


R1234yf
mass %
34.0
34.0
34.0
34.0
34.0
34.0
34.0
34.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
96.5
96.6
96.8
97.0
97.2
97.4
97.6
97.8



to 410A)


Refrigerating
% (relative
88.4
88.2
88.0
87.8
87.6
87.4
87.2
87.0


capacity ratio
to 410A)


Condensation
° C.
3.84
3.80
3.75
3.70
3.64
3.58
3.51
3.43


glide


Discharge
% (relative
95.0
94.6
94.2
93.7
93.3
92.8
92.3
91.8


pressure
to 410A)


RCL
g/m3
53.3
52.2
51.1
50.0
49.0
48.0
47.1
46.2

























TABLE 32







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
210
211
212
213
214
215
216
217
























HFO-1132(E)
mass %
46.0
48.0
50.0
52.0
54.0
30.0
32.0
34.0


HFO-1123
mass %
20.0
18.0
16.0
14.0
12.0
34.0
32.0
30.0


R1234yf
mass %
34.0
34.0
34.0
34.0
34.0
36.0
36.0
36.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
98.0
98.2
98.4
98.6
98.8
96.8
96.9
97.1



to 410A)


Refrigerating
% (relative
86.7
86.5
86.2
85.9
85.6
87.2
87.0
86.8


capacity ratio
to 410A)


Condensation
° C.
3.36
3.27
3.18
3.08
2.97
4.08
4.03
3.97


glide


Discharge
% (relative
91.3
90.8
90.3
89.7
89.2
93.4
93.0
92.6


pressure
to 410A)


RCL
g/m3
45.3
44.5
43.7
42.9
42.2
53.2
52.1
51.0

























TABLE 33







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
218
219
220
221
222
223
224
225
























HFO-1132(E)
mass %
36.0
38.0
40.0
42.0
44.0
46.0
30.0
32.0


HFO-1123
mass %
28.0
26.0
24.0
22.0
20.0
18.0
32.0
30.0


R1234yf
mass %
36.0
36.0
36.0
36.0
36.0
36.0
38.0
38.0


GWP

2
2
2
2
2
2
2
2


COP ratio
% (relative
97.3
97.5
97.7
97.9
98.1
98.3
97.1
97.2



to 410A)


Refrigerating
% (relative
86.6
86.4
86.2
85.9
85.7
85.5
85.9
85.7


capacity ratio
to 410A)


Condensation
° C.
3.91
3.84
3.76
3.68
3.60
3.50
4.32
4.25


glide


Discharge
% (relative
92.1
91.7
91.2
90.7
90.3
89.8
91.9
91.4


pressure
to 410A)


RCL
g/m3
49.9
48.9
47.9
47.0
46.1
45.3
53.1
52.0





















TABLE 34









Example
Example



Item
Unit
226
227





















HFO-1132(E)
mass %
34.0
36.0



HFO-1123
mass %
28.0
26.0



R1234yf
mass %
38.0
38.0



GWP

2
2



COP ratio
% (relative
97.4
97.6




to 410A)



Refrigerating
% (relative
85.6
85.3



capacity ratio
to 410A)



Condensation glide
° C.
4.18
4.11



Discharge pressure
% (relative
91.0
90.6




to 410A)



RCL
g/m3
50.9
49.8












    • These results indicate that under the condition that the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AA′, A′B, BD, DC′, C′C, CO, and OA that connect the following 7 points:


      point A (68.6, 0.0, 31.4),


      point A′(30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point D (0.0, 80.4, 19.6),


      point C′ (19.5, 70.5, 10.0),


      point C (32.9, 67.1, 0.0), and


      point O (100.0, 0.0, 0.0),


      or on the above line segments (excluding the points on the line segment CO);


      the line segment AA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),


      the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3,


      the line segment DC′ is represented by coordinates (x, 0.0082x2−0.6671x+80.4, −0.0082x2−0.3329x+19.6),


      the line segment C′C is represented by coordinates (x, 0.0067x2−0.6034x+79.729, −0.0067x2−0.3966x+20.271), and


      the line segments BD, CO, and OA are straight lines,


      the refrigerant has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 92.5% or more relative to that of R410A.

    • The point on the line segment AA′ was determined by obtaining an approximate curve connecting point A, Example 1, and point A′ by the least square method.

    • The point on the line segment A′B was determined by obtaining an approximate curve connecting point A′, Example 3, and point B by the least square method.

    • The point on the line segment DC′ was determined by obtaining an approximate curve connecting point D, Example 6, and point C′ by the least square method.

    • The point on the line segment C′C was determined by obtaining an approximate curve connecting point C′, Example 4, and point C by the least square method.

    • Likewise, the results indicate that when coordinates (x,y,z) are within the range of a figure surrounded by line segments AA′, A′B, BF, FT, TE, EO, and OA that connect the following 7 points:


      point A (68.6, 0.0, 31.4),


      point A′ (30.6, 30.0, 39.4),


      point B (0.0, 58.7, 41.3),


      point F (0.0, 61.8, 38.2),


      point T (35.8, 44.9, 19.3),


      point E (58.0, 42.0, 0.0) and


      point O (100.0, 0.0, 0.0),


      or on the above line segments (excluding the points on the line EO);


      the line segment AA′ is represented by coordinates (x, 0.0016x2−0.9473x+57.497, −0.0016x2−0.0527x+42.503),


      the line segment A′B is represented by coordinates (x, 0.0029x2−1.0268x+58.7, −0.0029x2+0.0268x+41.3),


      the line segment FT is represented by coordinates (x, 0.0078x2−0.7501x+61.8, −0.0078x2−0.2499x+38.2), and


      the line segment TE is represented by coordinates (x, 0.0067x2−0.7607x+63.525, −0.0067x2−0.2393x+36.475), and


      the line segments BF, FO, and OA are straight lines,


      the refrigerant has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP of 95% or more relative to that of R410A.

    • The point on the line segment FT was determined by obtaining an approximate curve connecting three points, i.e., points T, E′, and F, by the least square method.

    • The point on the line segment TE was determined by obtaining an approximate curve connecting three points, i.e., points E, R, and T, by the least square method.

    • The results in Tables 1 to 34 clearly indicate that in a ternary composition diagram of the mixed refrigerant of HFO-1132(E), HFO-1123, and R1234yf in which the sum of these components is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on or below the line segment LM connecting point L (63.1, 31.9, 5.0) and point M (60.3, 6.2, 33.5), the refrigerant has an RCL of 40 g/m3 or more.

    • The results in Tables 1 to 34 clearly indicate that in a ternary composition diagram of the mixed refrigerant of HFO-1132(E), HFO-1123 and R1234yf in which their sum is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on the line segment QR connecting point Q (62.8, 29.6, 7.6) and point R (49.8, 42.3, 7.9) or on the left side of the line segment, the refrigerant has a temperature glide of 1° C. or less.

    • The results in Tables 1 to 34 clearly indicate that in a ternary composition diagram of the mixed refrigerant of HFO-1132(E), HFO-1123, and R1234yf in which their sum is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on the line segment ST connecting point S (62.6, 28.3, 9.1) and point T (35.8, 44.9, 19.3) or on the right side of the line segment, the refrigerant has a discharge pressure of 105% or less relative to that of 410A.

    • In these compositions, R1234yf contributes to reducing flammability, and suppressing deterioration of polymerization etc. Therefore, the composition preferably contains R1234yf.

    • Further, the burning velocity of these mixed refrigerants whose mixed formulations were adjusted to WCF concentrations was measured according to the ANSI/ASHRAE Standard 34-2013. Compositions having a burning velocity of 10 cm/s or less were determined to be classified as “Class 2L (lower flammability).”

    • A burning velocity test was performed using the apparatus shown in FIG. 1 in the following manner. In FIG. 1, reference numeral 901 refers to a sample cell, 902 refers to a high-speed camera, 903 refers to a xenon lamp, 904 refers to a collimating lens, 905 refers to a collimating lens, and 906 refers to a ring filter. First, the mixed refrigerants used had a purity of 99.5% or more, and were degassed by repeating a cycle of freezing, pumping, and thawing until no traces of air were observed on the vacuum gauge. The burning velocity was measured by the closed method. The initial temperature was ambient temperature. Ignition was performed by generating an electric spark between the electrodes in the center of a sample cell. The duration of the discharge was 1.0 to 9.9 ms, and the ignition energy was typically about 0.1 to 1.0 J. The spread of the flame was visualized using schlieren photographs. A cylindrical container (inner diameter: 155 mm, length: 198 mm) equipped with two light transmission acrylic windows was used as the sample cell, and a xenon lamp was used as the light source. Schlieren images of the flame were recorded by a high-speed digital video camera at a frame rate of 600 fps and stored on a PC.

    • Each WCFF concentration was obtained by using the WCF concentration as the initial concentration and performing a leak simulation using NIST Standard Reference Database REFLEAK Version 4.0.

    • Tables 35 and 36 show the results.
















TABLE 35





Item
Unit
G
H
I




















WCF
HFO-1132(E)
mass %
72.0
72.0
72.0



HFO-1123
mass %
28.0
9.6
0.0



R1234yf
mass %
0.0
18.4
28.0











Burning velocity (WCF)
cm/s
10
10
10























TABLE 36





Item
Unit
J
P
L
N
N′
K























WCF
HFO-1132(E)
mass %
47.1
55.8
63.1
68.6
65.0
61.3



HFO-1123
mass %
52.9
42.0
31.9
16.3
7.7
5.4



R1234yf
mass %
0.0
2.2
5.0
15.1
27.3
33.3













Leak condition that results in WCFF
Storage/
Storage/
Storage/
Storage/
Storage/
Storage/



Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°
Shipping, −40°



C., 92%
C., 90%
C., 90%
C., 66%
C., 12%
C., 0%



release,
release,
release,
release,
release,
release,



liquid phase
liquid phase
gas phase
gas phase
gas phase
gas phase



side
side
side
side
side
side















WCFF
HFO-1132(E)
mass %
72.0
72.0
72.0
72.0
72.0
72.0



HFO-1123
mass %
28.0
17.8
17.4
13.6
12.3
9.8



R1234yf
mass %
0.0
10.2
10.6
14.4
15.7
18.2














Burning velocity (WCF)
cm/s
8 or
8 or
8 or
9
9
8 or




less
less
less


less


Burning velocity (WCFF)
cm/s
10
10
10
10
10
10











    • The results in Table 35 clearly indicate that when a mixed refrigerant of HFO-1132(E), HFO-1123, and R1234yf contains HFO-1132(E) in a proportion of 72.0 mass % or less based on their sum, the refrigerant can be determined to have a WCF lower flammability.

    • The results in Tables 36 clearly indicate that in a ternary composition diagram of a mixed refrigerant of HFO-1132(E), HFO-1123, and R1234yf in which their sum is 100 mass %, and a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base,


      when coordinates (x,y,z) are on or below the line segments JP, PN, and NK connecting the following 6 points:


      point J (47.1, 52.9, 0.0),


      point P (55.8, 42.0, 2.2),


      point L (63.1, 31.9, 5.0)


      point N (68.6, 16.3, 15.1)


      point N′ (65.0, 7.7, 27.3) and


      point K (61.3, 5.4, 33.3),


      the refrigerant can be determined to have a WCF lower flammability, and a WCFF lower flammability.


      In the diagram, the line segment PN is represented by coordinates (x, −0.1135x2+12.112x−280.43, 0.1135x2−13.112x+380.43),


      and the line segment NK is represented by coordinates (x, 0.2421x2−29.955x+931.91, −0.2421x2+28.955x−831.91).

    • The point on the line segment PN was determined by obtaining an approximate curve connecting three points, i.e., points P, L, and N, by the least square method.

    • The point on the line segment NK was determined by obtaining an approximate curve connecting three points, i.e., points N, N′, and K, by the least square method.





(5-2) Refrigerant B





    • The refrigerant B according to the present disclosure is

    • a mixed refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)) and trifluoroethylene (HFO-1123) in a total amount of 99.5 mass % or more based on the entire refrigerant, and the refrigerant comprising 62.0 mass % to 72.0 mass % or 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire refrigerant, or

    • a mixed refrigerant comprising HFO-1132(E) and HFO-1123 in a total amount of 99.5 mass % or more based on the entire refrigerant, and the refrigerant comprising 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire refrigerant.

    • The refrigerant B according to the present disclosure has various properties that are desirable as an R410A-alternative refrigerant, i.e., (1) a coefficient of performance equivalent to that of R410A, (2) a refrigerating capacity equivalent to that of R410A, (3) a sufficiently low GWP, and (4) a lower flammability (Class 2L) according to the ASHRAE standard.

    • When the refrigerant B according to the present disclosure is a mixed refrigerant comprising 72.0 mass % or less of HFO-1132(E), it has WCF lower flammability. When the refrigerant B according to the present disclosure is a composition comprising 47.1% or less of HFO-1132(E), it has WCF lower flammability and WCFF lower flammability, and is determined to be “Class 2L,” which is a lower flammable refrigerant according to the ASHRAE standard, and which is further easier to handle.

    • When the refrigerant B according to the present disclosure comprises 62.0 mass % or more of HFO-1132(E), it becomes superior with a coefficient of performance of 95% or more relative to that of R410A, the polymerization reaction of HFO-1132(E) and/or HFO-1123 is further suppressed, and the stability is further improved. When the refrigerant B according to the present disclosure comprises 45.1 mass % or more of HFO-1132(E), it becomes superior with a coefficient of performance of 93% or more relative to that of R410A, the polymerization reaction of HFO-1132(E) and/or HFO-1123 is further suppressed, and the stability is further improved.

    • The refrigerant B according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E) and HFO-1123, as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E) and HFO-1123 in a total amount of 99.75 mass % or more, and more preferably 99.9 mass % or more, based on the entire refrigerant.

    • Such additional refrigerants are not limited, and can be selected from a wide range of refrigerants. The mixed refrigerant may comprise a single additional refrigerant, or two or more additional refrigerants.





(Examples of Refrigerant B)





    • The present disclosure is described in more detail below with reference to Examples of refrigerant B. However, the refrigerant B is not limited to the Examples.

    • Mixed refrigerants were prepared by mixing HFO-1132(E) and HFO-1123 at mass % based on their sum shown in Tables 37 and 38.

    • The GWP of compositions each comprising a mixture of R410A (R32=50%/R125=50%) was evaluated based on the values stated in the Intergovernmental Panel on Climate Change (IPCC), fourth report. The GWP of HFO-1132(E), which was not stated therein, was assumed to be 1 from HFO-1132a (GWP=1 or less) and HFO-1123 (GWP=0.3, described in WO2015/141678). The refrigerating capacity of compositions each comprising R410A and a mixture of HFO-1132(E) and HFO-1123 was determined by performing theoretical refrigeration cycle calculations for the mixed refrigerants using the National Institute of Science and Technology (NIST) and Reference Fluid Thermodynamic and Transport Properties Database (Refprop 9.0) under the following conditions.


      Evaporating temperature: 5° C.


      Condensation temperature: 45° C.


      Superheating temperature: 5 K


      Subcooling temperature: 5 K


      Compressor efficiency: 70%

    • The composition of each mixture was defined as WCF. A leak simulation was performed using NIST Standard Reference Data Base Refleak Version 4.0 under the conditions of Equipment, Storage, Shipping, Leak, and Recharge according to the ASHRAE Standard 34-2013. The most flammable fraction was defined as WCFF.

    • Tables 1 and 2 show GWP, COP, and refrigerating capacity, which were calculated based on these results. The COP and refrigerating capacity are ratios relative to R410A.

    • The coefficient of performance (COP) was determined by the following formula.








COP=(refrigerating capacity or heating capacity)/power consumption

    • For the flammability, the burning velocity was measured according to the ANSI/ASHRAE Standard 34-2013. Both WCF and WCFF having a burning velocity of 10 cm/s or less were determined to be “Class 2L (lower flammability).”
    • A burning velocity test was performed using the apparatus shown in FIG. 1 in the following manner. First, the mixed refrigerants used had a purity of 99.5% or more, and were degassed by repeating a cycle of freezing, pumping, and thawing until no traces of air were observed on the vacuum gauge. The burning velocity was measured by the closed method. The initial temperature was ambient temperature. Ignition was performed by generating an electric spark between the electrodes in the center of a sample cell. The duration of the discharge was 1.0 to 9.9 ms, and the ignition energy was typically about 0.1 to 1.0 J. The spread of the flame was visualized using schlieren photographs. A cylindrical container (inner diameter: 155 mm, length: 198 mm) equipped with two light transmission acrylic windows was used as the sample cell, and a xenon lamp was used as the light source. Schlieren images of the flame were recorded by a high-speed digital video camera at a frame rate of 600 fps and stored on a PC.



















TABLE 37







Comparative
Comparative











Example 1
Example 2
Comparative
Example
Example
Example
Example
Example
Comparative


Item
Unit
R410A
HFO-1132E
Example 3
1
2
3
4
5
Example 4

























HFO-1132E
mass %

100
80
72
70
68
65
62
60


(WCF)


HFO-1123
mass %

0
20
28
30
32
35
38
40


(WCF)


GWP

2088
1
1
1
1
1
1
1
1


COP ratio
%
100
99.7
97.5
96.6
96.3
96.1
95.8
95.4
95.2



(relative



to R410A)


Refrigerating
%
100
98.3
101.9
103.1
103.4
103.8
104.1
104.5
104.8


capacity
(relative


ratio
to R410A)


Discharge
Mpa
2.73
2.71
2.89
2.96
2.98
3.00
3.02
3.04
3.06


pressure


Burning
cm/sec
Non-flammable
20
13
10
9
9
8
8 or
8 or


velocity








less
less


(WCF)


























TABLE 38















Comparative




Comparative
Comparative
Example
Example
Example
Comparative
Comparative
Comparative
Example 10


Item
Unit
Example 5
Example 6
7
8
9
Example 7
Example 8
Example 9
HFO-1123

























HFO-1132E
mass %
50
48
47.1
46.1
45.1
43
40
25
0


(WCF)


HFO-1123
mass %
50
52
52.9
53.9
54.9
57
60
75
100


(WCF)


GWP

1
1
1
1
1
1
1
1
1


COP ratio
%
94.1
93.9
93.8
93.7
93.6
93.4
93.1
91.9
90.6



(relative



to R410A)


Refrigerating
%
105.9
106.1
106.2
106.3
106.4
106.6
106.9
107.9
108.0


capacity
(relative


ratio
to R410A)


Discharge
Mpa
3.14
3.16
3.16
3.17
3.18
3.20
3.21
3.31
3.39


pressure
















Leakage test
Storage/
Storage/
Storage/
Storage/
Storage/
Storage/
Storage/
Storage/



conditions (WCFF)
Shipp-
Shipp-
Shipp-
Shipp-
Shipp-
Shipp-
Shipp-
Shipp-



ing −40°
ing −40°
ing −40°
ing −40°
ing −40°
ing −40°
ing −40°
ing −40°



C., 92%
C., 92%
C., 92%
C., 92%
C., 92%
C., 92%
C., 92%
C., 90%



release,
release,
release,
release,
release,
release,
release,
release,



liquid
liquid
liquid
liquid
liquid
liquid
liquid
liquid



phase
phase
phase
phase
phase
phase
phase
phase



side
side
side
side
side
side
side
side

















HFO-1132E
mass %
74
73
72
71
70
67
63
38



(WCFF)


HFO-1123
mass %
26
27
28
29
30
33
37
62


(WCFF)


Burning
cm/sec
8 or
8 or
8 or
8 or
8 or
8 or
8 or
8 or
5


velocity

less
less
less
less
less
less
less
less


(WCF)


Burning
cm/sec
11
10.5
10.0
9.5
9.5
8.5
8 or
8 or


velocity







less
less


(WCFF)
















ASHRAE flammability
2
2
2L
2L
2L
2L
2L
2L
2L


classification











    • The compositions each comprising 62.0 mass % to 72.0 mass % of HFO-1132(E) based on the entire composition are stable while having a low GWP (GWP=1), and they ensure WCF lower flammability. Further, surprisingly, they can ensure performance equivalent to that of R410A. Moreover, compositions each comprising 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire composition are stable while having a low GWP (GWP=1), and they ensure WCFF lower flammability. Further, surprisingly, they can ensure performance equivalent to that of R410A.





(5-3) Refrigerant C





    • The refrigerant C according to the present disclosure is a composition comprising trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32), and satisfies the following requirements. The refrigerant C according to the present disclosure has various properties that are desirable as an alternative refrigerant for R410A; i.e. it has a coefficient of performance and a refrigerating capacity that are equivalent to those of R410A, and a sufficiently low GWP.





Requirements





    • Preferable refrigerant C is as follows:

    • When the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum is respectively represented by x, y, z, and a,

    • if 0<a≤11.1, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines GI, IA, AB, BD′, D′C, and CG that connect the following 6 points:


      point G (0.026a2−1.7478a+72.0, −0.026a2+0.7478a+28.0, 0.0),


      point I (0.026a2−1.7478a+72.0, 0.0, −0.026a2+0.7478a+28.0),


      point A (0.0134a2−1.9681a+68.6, 0.0, −0.0134a2+0.9681a+31.4),


      point B (0.0, 0.0144a2−1.6377a+58.7, −0.0144a2+0.6377a+41.3),


      point D′ (0.0, 0.0224a2+0.968a+75.4, −0.0224a2−1.968a+24.6), and


      point C (−0.2304a2−0.4062a+32.9, 0.2304a2−0.5938a+67.1, 0.0),


      or on the straight lines GI, AB, and D′C (excluding point G, point I, point A, point B,


      point D′, and point C);

    • if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:


      point G (0.02a2−1.6013a+71.105, −0.02a2+0.6013a+28.895, 0.0),


      point I (0.02a2−1.6013a+71.105, 0.0, −0.02a2+0.6013a+28.895),


      point A (0.0112a2−1.9337a+68.484, 0.0, −0.0112a2+0.9337a+31.516),


      point B (0.0, 0.0075a2−1.5156a+58.199, −0.0075a2+0.5156a+41.801) and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);

    • if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:


      point G (0.0135a2−1.4068a+69.727, −0.0135a2+0.4068a+30.273, 0.0),


      point I (0.0135a2−1.4068a+69.727, 0.0, −0.0135a2+0.4068a+30.273),


      point A (0.0107a2−1.9142a+68.305, 0.0, −0.0107a2+0.9142a+31.695),


      point B (0.0, 0.009a2−1.6045a+59.318, −0.009a2+0.6045a+40.682) and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W);

    • if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:


      point G (0.0111a2−1.3152a+68.986, −0.0111a2+0.3152a+31.014, 0.0),


      point I (0.0111a2−1.3152a+68.986, 0.0, −0.0111a2+0.3152a+31.014),


      point A (0.0103a2−1.9225a+68.793, 0.0, −0.0103a2+0.9225a+31.207),


      point B (0.0, 0.0046a2−1.41a+57.286, −0.0046a2+0.41a+42.714) and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W); and

    • if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines GI, IA, AB, BW, and WG that connect the following 5 points:


      point G (0.0061a2−0.9918a+63.902, −0.0061a2−0.0082a+36.098, 0.0),


      point I (0.0061a2−0.9918a+63.902, 0.0, −0.0061a2−0.0082a+36.098),


      point A (0.0085a2−1.8102a+67.1, 0.0, −0.0085a2+0.8102a+32.9),


      point B (0.0, 0.0012a2−1.1659a+52.95, −0.0012a2+0.1659a+47.05) and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines GI and AB (excluding point G, point I, point A, point B, and point W). When the refrigerant according to the present disclosure satisfies the above requirements, it has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP ratio of 92.5% or more relative to that of R410A, and further ensures a WCF lower flammability.

    • The refrigerant C according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum is respectively represented by x, y, and z,

    • if 0<a≤11.1, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines JK′, K′B, BD′, D′C, and CJ that connect the following 5 points:


      point J (0.0049a2−0.9645a+47.1, −0.0049a2−0.0355a+52.9, 0.0),


      point K′ (0.0514a2−2.4353a+61.7, −0.0323a2+0.4122a+5.9, −0.0191a2+1.0231a+32.4),


      point B (0.0, 0.0144a2−1.6377a+58.7, −0.0144a2+0.6377a+41.3),


      point D′ (0.0, 0.0224a2+0.968a+75.4, −0.0224a2−1.968a+24.6), and


      point C (−0.2304a2−0.4062a+32.9, 0.2304a2−0.5938a+67.1, 0.0),


      or on the straight lines JK′, K′B, and D′C (excluding point J, point B, point D′, and point C);

    • if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:


      point J (0.0243a2−1.4161a+49.725, −0.0243a2+0.4161a+50.275, 0.0),


      point K′ (0.0341a2−2.1977a+61.187, −0.0236a2+0.34a+5.636, −0.0105a2+0.8577a+33.177),


      point B (0.0, 0.0075a2−1.5156a+58.199, −0.0075a2+0.5156a+41.801) and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines JK′ and K′B (excluding point J, point B, and point W);

    • if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′B, BW, and WJ that connect the following 4 points:


      point J (0.0246a2−1.4476a+50.184, −0.0246a2+0.4476a+49.816, 0.0),


      point K′ (0.0196a2−1.7863a+58.515, −0.0079a2−0.1136a+8.702, −0.0117a2+0.8999a+32.783),


      point B (0.0, 0.009a2−1.6045a+59.318, −0.009a2+0.6045a+40.682) and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines JK′ and K′B (excluding point J, point B, and point W);

    • if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′A, AB, BW, and WJ that connect the following 5 points:


      point J (0.0183a2−1.1399a+46.493, −0.0183a2+0.1399a+53.507, 0.0),


      point K′ (−0.0051a2+0.0929a+25.95, 0.0, 0.0051a2−1.0929a+74.05),


      point A (0.0103a2−1.9225a+68.793, 0.0, −0.0103a2+0.9225a+31.207),


      point B (0.0, 0.0046a2−1.41a+57.286, −0.0046a2+0.41a+42.714) and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines JK′, K′A, and AB (excluding point J, point B, and point W); and

    • if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines JK′, K′A, AB, BW, and WJ that connect the following 5 points:


      point J (−0.0134a2+1.0956a+7.13, 0.0134a2−2.0956a+92.87, 0.0),


      point K′ (−1.892a+29.443, 0.0, 0.892a+70.557),


      point A (0.0085a2−1.8102a+67.1, 0.0, −0.0085a2+0.8102a+32.9),


      point B (0.0, 0.0012a2−1.1659a+52.95, −0.0012a2+0.1659a+47.05) and


      point W (0.0, 100.0−a, 0.0),


      or on the straight lines JK′, K′A, and AB (excluding point J, point B, and point W). When the refrigerant according to the present disclosure satisfies the above requirements, it has a refrigerating capacity ratio of 85% or more relative to that of R410A, and a COP ratio of 92.5% or more relative to that of R410A. Additionally, the refrigerant has a WCF lower flammability and a WCFF lower flammability, and is classified as “Class 2L,” which is a lower flammable refrigerant according to the ASHRAE standard.

    • When the refrigerant C according to the present disclosure further contains R32 in addition to HFO-1132 (E), HFO-1123, and R1234yf, the refrigerant may be a refrigerant wherein when the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum is respectively represented by x, y, z, and a,

    • if 0<a≤10.0, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % are within the range of a figure surrounded by straight lines that connect the following 4 points:


      point a (0.02a2−2.46a+93.4, 0, −0.02a2+2.46a+6.6),


      point b′ (−0.008a2−1.38a+56, 0.018a2−0.53a+26.3, −0.01a2+1.91a+17.7),


      point c (−0.016a2+1.02a+77.6, 0.016a2−1.02a+22.4, 0), and


      point o (100.0−a, 0.0, 0.0)


      or on the straight lines oa, ab′, and b′c (excluding point o and point c);

    • if 10.0<a≤16.5, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines that connect the following 4 points:


      point a (0.0244a2−2.5695a+94.056, 0, −0.0244a2+2.5695a+5.944),


      point b′ (0.1161a2−1.9959a+59.749, 0.014a2−0.3399a+24.8, −0.1301a2+2.3358a+15.451),


      point c (−0.0161a2+1.02a+77.6, 0.0161a2−1.02a+22.4, 0), and


      point o (100.0−a, 0.0, 0.0),


      or on the straight lines oa, ab′, and b′c (excluding point o and point c); or

    • if 16.5<a≤21.8, coordinates (x,y,z) in the ternary composition diagram are within the range of a figure surrounded by straight lines that connect the following 4 points:


      point a (0.0161a2−2.3535a+92.742, 0, −0.0161a2+2.3535a+7.258),


      point b′ (−0.0435a2−0.0435a+50.406, 0.0304a2+1.8991a−0.0661, 0.0739a2−1.8556a+49.6601),


      point c (−0.0161a2+0.9959a+77.851, 0.0161a2−0.9959a+22.149, 0), and


      point o (100.0−a, 0.0, 0.0),


      or on the straight lines oa, ab′, and b′c (excluding point o and point c). Note that when point b in the ternary composition diagram is defined as a point where a refrigerating capacity ratio of 95% relative to that of R410A and a COP ratio of 95% relative to that of R410A are both achieved, point b′ is the intersection of straight line ab and an approximate line formed by connecting the points where the COP ratio relative to that of R410A is 95%. When the refrigerant according to the present disclosure meets the above requirements, the refrigerant has a refrigerating capacity ratio of 95% or more relative to that of R410A, and a COP ratio of 95% or more relative to that of R410A.

    • The refrigerant C according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E), HFO-1123, R1234yf, and R32 as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E), HFO-1123, R1234yf, and R32 in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and still more preferably 99.9 mass % or more, based on the entire refrigerant.

    • The refrigerant C according to the present disclosure may comprise HFO-1132(E), HFO-1123, R1234yf, and R32 in a total amount of 99.5 mass % or more, 99.75 mass % or more, or 99.9 mass % or more, based on the entire refrigerant.

    • Additional refrigerants are not particularly limited and can be widely selected. The mixed refrigerant may contain one additional refrigerant, or two or more additional refrigerants.





(Examples of Refrigerant C)





    • The present disclosure is described in more detail below with reference to Examples of refrigerant C. However, the refrigerant C is not limited to the Examples.

    • Mixed refrigerants were prepared by mixing HFO-1132(E), HFO-1123, R1234yf, and R32 at mass % based on their sum shown in Tables 39 to 96.

    • The GWP of compositions each comprising a mixture of R410A (R32=50%/R125=50%) was evaluated based on the values stated in the Intergovernmental Panel on Climate Change (IPCC), fourth report. The GWP of HFO-1132(E), which was not stated therein, was assumed to be 1 from HFO-1132a (GWP=1 or less) and HFO-1123 (GWP=0.3, described in WO2015/141678). The refrigerating capacity of compositions each comprising R410A and a mixture of HFO-1132(E) and HFO-1123 was determined by performing theoretical refrigeration cycle calculations for the mixed refrigerants using the National Institute of Science and Technology (NIST) and Reference Fluid Thermodynamic and Transport Properties Database (Refprop 9.0) under the following conditions.

    • For each of these mixed refrigerants, the COP ratio and the refrigerating capacity ratio relative to those of R410 were obtained. Calculation was conducted under the following conditions.

    • Evaporating temperature: 5° C.

    • Condensation temperature: 45° C.

    • Superheating temperature: 5 K

    • Subcooling temperature: 5 K

    • Compressor efficiency: 70%

    • Tables 39 to 96 show the resulting values together with the GWP of each mixed refrigerant. The COP and refrigerating capacity are ratios relative to R410A.

    • The coefficient of performance (COP) was determined by the following formula.








COP=(refrigerating capacity or heating capacity)/power consumption



















TABLE 39








Comp.
Comp.
Comp.
Comp.
Comp.
Comp.
Comp.
Ex.




Comp.
Ex. 2
Ex. 3
Ex. 4
Ex. 5
Ex. 6
Ex. 7
Ex. 8
1


Item
Unit
Ex. 1
A
B
C
D′
G
I
J
K′

























HFO-1132(E)
Mass %
R410A
68.6
0.0
32.9
0.0
72.0
72.0
47.1
61.7


HFO-1123
Mass %

0.0
58.7
67.1
75.4
28.0
0.0
52.9
5.9


R1234yf
Mass %

31.4
41.3
0.0
24.6
0.0
28.0
0.0
32.4


R32
Mass %

0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0


GWP

2088
2
2
1
2
1
2
1
2



% (relative


COP ratio
to R410A)
100
100.0
95.5
92.5
93.1
96.6
99.9
93.8
99.4


Refrigerating
% (relative


capacity ratio
to R410A)
100
85.0
85.0
107.4
95.0
103.1
86.6
106.2
85.5

























TABLE 40







Comp.
Comp.
Comp.
Comp.
Comp.
Comp.
Comp.
Ex.




Ex. 9
Ex. 10
Ex. 11
Ex. 12
Ex. 13
Ex. 14
Ex. 15
2


Item
Unit
A
B
C
D′
G
I
J
K′
























HFO-1132(E)
Mass %
55.3
0.0
18.4
0.0
60.9
60.9
40.5
47.0


HFO-1123
Mass %
0.0
47.8
74.5
83.4
32.0
0.0
52.4
7.2


R1234yf
Mass %
37.6
45.1
0.0
9.5
0.0
32.0
0.0
38.7


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

50
50
49
49
49
50
49
50


COP ratio
% (relative
99.8
96.9
92.5
92.5
95.9
99.6
94.0
99.2



to R410A)


Refrigerating
% (relative
85.0
85.0
110.5
106.0
106.5
87.7
108.9
85.5


capacity ratio
to R410A)
























TABLE 41







Comp.
Comp.
Comp.
Comp.
Comp.
Comp.
Ex.




Ex. 16
Ex. 17
Ex. 18
Ex. 19
Ex. 20
Ex. 21
3


Item
Unit
A
B
C = D′
G
I
J
K′























HFO-1132(E)
Mass %
48.4
0.0
0.0
55.8
55.8
37.0
41.0


HFO-1123
Mass %
0.0
42.3
88.9
33.1
0.0
51.9
6.5


R1234yf
Mass %
40.5
46.6
0.0
0.0
33.1
0.0
41.4


R32
Mass %
11.1
11.1
11.1
11.1
11.1
11.1
11.1


GWP

77
77
76
76
77
76
77


COP ratio
% (relative
99.8
97.6
92.5
95.8
99.5
94.2
99.3



to R410A)


Refrigerating
% (relative
85.0
85.0
112.0
108.0
88.6
110.2
85.4


capacity ratio
to R410A)























TABLE 42







Comp.
Comp.
Comp.
Comp.
Comp.
Ex.




Ex. 22
Ex. 23
Ex. 24
Ex. 25
Ex. 26
4


Item
Unit
A
B
G
I
J
K′






















HFO-1132(E)
Mass %
42.8
0.0
52.1
52.1
34.3
36.5


HFO-1123
Mass %
0.0
37.8
33.4
0.0
51.2
5.6


R1234yf
Mass %
42.7
47.7
0.0
33.4
0.0
43.4


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5


GWP

100
100
99
100
99
100


COP ratio
% (relative
99.9
98.1
95.8
99.5
94.4
99.5



to R410A)


Refrigerating
% (relative
85.0
85.0
109.1
89.6
111.1
85.3


capacity ratio
to R410A)























TABLE 43







Comp.
Comp.
Comp.
Comp.
Comp.
Ex.




Ex. 27
Ex. 28
Ex. 29
Ex. 30
Ex. 31
5


Item
Unit
A
B
G
I
J
K′






















HFO-1132(E)
Mass %
37.0
0.0
48.6
48.6
32.0
32.5


HFO-1123
Mass %
0.0
33.1
33.2
0.0
49.8
4.0


R1234yf
Mass %
44.8
48.7
0.0
33.2
0.0
45.3


R32
Mass %
18.2
18.2
18.2
18.2
18.2
18.2


GWP

125
125
124
125
124
125


COP ratio
% (relative
100.0
98.6
95.9
99.4
94.7
99.8



to R410A)


Refrigerating
% (relative
85.0
85.0
110.1
90.8
111.9
85.2


capacity ratio
to R410A)























TABLE 44







Comp.
Comp.
Comp.
Comp.
Comp.
Ex.




Ex. 32
Ex. 33
Ex. 34
Ex. 35
Ex. 36
6


Item
Unit
A
B
G
I
J
K′






















HFO-1132(E)
Mass %
31.5
0.0
45.4
45.4
30.3
28.8


HFO-1123
Mass %
0.0
28.5
32.7
0.0
47.8
2.4


R1234yf
Mass %
46.6
49.6
0.0
32.7
0.0
46.9


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9


GWP

150
150
149
150
149
150


COP ratio
% (relative
100.2
99.1
96.0
99.4
95.1
100.0



to R410A)


Refrigerating
% (relative
85.0
85.0
111.0
92.1
112.6
85.1


capacity ratio
to R410A)























TABLE 45







Comp.
Comp.
Comp.
Comp.
Comp.
Comp.




Ex. 37
Ex. 38
Ex. 39
Ex. 40
Ex. 41
Ex. 42


Item
Unit
A
B
G
I
J
K′






















HFO-1132(E)
Mass %
24.8
0.0
41.8
41.8
29.1
24.8


HFO-1123
Mass %
0.0
22.9
31.5
0.0
44.2
0.0


R1234yf
Mass %
48.5
50.4
0.0
31.5
0.0
48.5


R32
Mass %
26.7
26.7
26.7
26.7
26.7
26.7


GWP

182
182
181
182
181
182


COP ratio
% (relative
100.4
99.8
96.3
99.4
95.6
100.4



to R410A)


Refrigerating
% (relative
85.0
85.0
111.9
93.8
113.2
85.0


capacity ratio
to R410A)























TABLE 46







Comp.
Comp.
Comp.
Comp.
Comp.
Comp.




Ex. 43
Ex. 44
Ex. 45
Ex. 46
Ex. 47
Ex. 48


Item
Unit
A
B
G
I
J
K′






















HFO-1132(E)
Mass %
21.3
0.0
40.0
40.0
28.8
24.3


HFO-1123
Mass %
0.0
19.9
30.7
0.0
41.9
0.0


R1234yf
Mass %
49.4
50.8
0.0
30.7
0.0
46.4


R32
Mass %
29.3
29.3
29.3
29.3
29.3
29.3


GWP

200
200
198
199
198
200


COP ratio
% (relative
100.6
100.1
96.6
99.5
96.1
100.4



to R410A)


Refrigerating
% (relative
85.0
85.0
112.4
94.8
113.6
86.7


capacity ratio
to R410A)























TABLE 47







Comp.
Comp.
Comp.
Comp.
Comp.
Comp.




Ex. 49
Ex. 50
Ex. 51
Ex. 52
Ex. 53
Ex. 54


Item
Unit
A
B
G
I
J
K′






















HFO-1132(E)
Mass %
12.1
0.0
35.7
35.7
29.3
22.5


HFO-1123
Mass %
0.0
11.7
27.6
0.0
34.0
0.0


R1234yf
Mass %
51.2
51.6
0.0
27.6
0.0
40.8


R32
Mass %
36.7
36.7
36.7
36.7
36.7
36.7


GWP

250
250
248
249
248
250


COP ratio
% (relative
101.2
101.0
96.4
99.6
97.0
100.4



to R410A)


Refrigerating
% (relative
85.0
85.0
113.2
97.6
113.9
90.9


capacity ratio
to R410A)























TABLE 48







Comp.
Comp.
Comp.
Comp.
Comp.
Comp.




Ex. 55
Ex. 56
Ex. 57
Ex. 58
Ex. 59
Ex. 60


Item
Unit
A
B
G
I
J
K′






















HFO-1132(E)
Mass %
3.8
0.0
32.0
32.0
29.4
21.1


HFO-1123
Mass %
0.0
3.9
23.9
0.0
26.5
0.0


R1234yf
Mass %
52.1
52.0
0.0
23.9
0.0
34.8


R32
Mass %
44.1
44.1
44.1
44.1
44.1
44.1


GWP

300
300
298
299
298
299


COP ratio
% (relative
101.8
101.8
97.9
99.8
97.8
100.5



to R410A)


Refrigerating
% (relative
85.0
85.0
113.7
100.4
113.9
94.9


capacity ratio
to R410A)






















TABLE 49







Comp.
Comp.
Comp.
Comp.
Comp.




Ex. 61
Ex. 62
Ex. 63
Ex. 64
Ex. 65


Item
Unit
A = B
G
I
J
K′





















HFO-
Mass %
0.0
30.4
30.4
28.9
20.4


1132(E)


HFO-1123
Mass %
0.0
21.8
0.0
23.3
0.0


R1234yf
Mass %
52.2
0.0
21.8
0.0
31.8


R32
Mass %
47.8
47.8
47.8
47.8
47.8


GWP

325
323
324
323
324


COP ratio
%
102.1
98.2
100.0
98.2
100.6



(relative



to R410A)


Refrigerating
%
85.0
113.8
101.8
113.9
96.8


capacity
(relative


ratio
to R410A)

























TABLE 50







Comp.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
Ex. 66
7
8
9
10
11
12
13
























HFO-1132(E)
Mass %
5.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0


HFO-1123
Mass %
82.9
77.9
72.9
67.9
62.9
57.9
52.9
47.9


R1234yf
Mass %
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

49
49
49
49
49
49
49
49


COP ratio
% (relative
92.4
92.6
92.8
93.1
93.4
93.7
94.1
94.5



to R410A)


Refrigerating
% (relative
108.4
108.3
108.2
107.9
107.6
107.2
106.8
106.3


capacity ratio
to R410A)

























TABLE 51







Ex.
Ex.
Ex.
Ex.
Comp.
Ex.
Ex.
Ex.


Item
Unit
14
15
16
17
Ex. 67
18
19
20
























HFO-1132(E)
Mass %
45.0
50.0
55.0
60.0
65.0
10.0
15.0
20.0


HFO-1123
Mass %
42.9
37.9
32.9
27.9
22.9
72.9
67.9
62.9


R1234yf
Mass %
5.0
5.0
5.0
5.0
5.0
10.0
10.0
10.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

49
49
49
49
49
49
49
49


COP ratio
% (relative
95.0
95.4
95.9
96.4
96.9
93.0
93.3
93.6



to R410A)


Refrigerating
% (relative
105.8
105.2
104.5
103.9
103.1
105.7
105.5
105.2


capacity ratio
to R410A)

























TABLE 52







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
21
22
23
24
25
26
27
28
























HFO-1132(E)
Mass %
25.0
30.0
35.0
40.0
45.0
50.0
55.0
60.0


HFO-1123
Mass %
57.9
52.9
47.9
42.9
37.9
32.9
27.9
22.9


R1234yf
Mass %
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

49
49
49
49
49
49
49
49


COP ratio
% (relative
93.9
94.2
94.6
95.0
95.5
96.0
96.4
96.9



to R410A)


Refrigerating
% (relative
104.9
104.5
104.1
103.6
103.0
102.4
101.7
101.0


capacity ratio
to R410A)

























TABLE 53







Comp.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
Ex. 68
29
30
31
32
33
34
35
























HFO-1132(E)
Mass %
65.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0


HFO-1123
Mass %
17.9
67.9
62.9
57.9
52.9
47.9
42.9
37.9


R1234yf
Mass %
10.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

49
49
49
49
49
49
49
49


COP ratio
% (relative
97.4
93.5
93.8
94.1
94.4
94.8
95.2
95.6



to R410A)


Refrigerating
% (relative
100.3
102.9
102.7
102.5
102.1
101.7
101.2
100.7


capacity ratio
to R410A)

























TABLE 54







Ex.
Ex.
Ex.
Ex.
Comp.
Ex.
Ex.
Ex.


Item
Unit
36
37
38
39
Ex. 69
40
41
42
























HFO-1132(E)
Mass %
45.0
50.0
55.0
60.0
65.0
10.0
15.0
20.0


HFO-1123
Mass %
32.9
27.9
22.9
17.9
12.9
62.9
57.9
52.9


R1234yf
Mass %
15.0
15.0
15.0
15.0
15.0
20.0
20.0
20.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

49
49
49
49
49
49
49
49


COP ratio
% (relative
96.0
96.5
97.0
97.5
98.0
94.0
94.3
94.6



to R410A)


Refrigerating
% (relative
100.1
99.5
98.9
98.1
97.4
100.1
99.9
99.6


capacity ratio
to R410A)

























TABLE 55







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
43
44
45
46
47
48
49
50
























HFO-1132(E)
Mass %
25.0
30.0
35.0
40.0
45.0
50.0
55.0
60.0


HFO-1123
Mass %
47.9
42.9
37.9
32.9
27.9
22.9
17.9
12.9


R1234yf
Mass %
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

49
49
49
49
49
49
49
49


COP ratio
% (relative
95.0
95.3
95.7
96.2
96.6
97.1
97.6
98.1



to R410A)


Refrigerating
% (relative
99.2
98.8
98.3
97.8
97.2
96.6
95.9
95.2


capacity ratio
to R410A)

























TABLE 56







Comp.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
Ex. 70
51
52
53
54
55
56
57
























HFO-1132(E)
Mass %
65.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0


HFO-1123
Mass %
7.9
57.9
52.9
47.9
42.9
37.9
32.9
27.9


R1234yf
Mass %
20.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

49
50
50
50
50
50
50
50


COP ratio
% (relative
98.6
94.6
94.9
95.2
95.5
95.9
96.3
96.8



to R410A)


Refrigerating
% (relative
94.4
97.1
96.9
96.7
96.3
95.9
95.4
94.8


capacity ratio
to R410A)

























TABLE 57







Ex.
Ex.
Ex.
Ex.
Comp.
Ex.
Ex.
Ex.


Item
Unit
58
59
60
61
Ex. 71
62
63
64
























HFO-1132(E)
Mass %
45.0
50.0
55.0
60.0
65.0
10.0
15.0
20.0


HFO-1123
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


R1234yf
Mass %
25.0
25.0
25.0
25.0
25.0
30.0
30.0
30.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

50
50
50
50
50
50
50
50


COP ratio
% (relative
97.2
97.7
98.2
98.7
99.2
95.2
95.5
95.8



to R410A)


Refrigerating
% (relative
94.2
93.6
92.9
92.2
91.4
94.2
93.9
93.7


capacity ratio
to R410A)

























TABLE 58







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
65
66
67
68
69
70
71
72
























HFO-1132(E)
Mass %
25.0
30.0
35.0
40.0
45.0
50.0
55.0
60.0


HFO-1123
Mass %
37.9
32.9
27.9
22.9
17.9
12.9
7.9
2.9


R1234yf
Mass %
30.0
30.0
30.0
30.0
30.0
30.0
30.0
30.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

50
50
50
50
50
50
50
50


COP ratio
% (relative
96.2
96.6
97.0
97.4
97.9
98.3
98.8
99.3



to R410A)


Refrigerating
% (relative
93.3
92.9
92.4
91.8
91.2
90.5
89.8
89.1


capacity ratio
to R410A)

























TABLE 59







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
73
74
75
76
77
78
79
80
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0


HFO-1123
Mass %
47.9
42.9
37.9
32.9
27.9
22.9
17.9
12.9


R1234yf
Mass %
35.0
35.0
35.0
35.0
35.0
35.0
35.0
35.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

50
50
50
50
50
50
50
50


COP ratio
% (relative
95.9
96.2
96.5
96.9
97.2
97.7
98.1
98.5



to R410A)


Refrigerating
% (relative
91.1
90.9
90.6
90.2
89.8
89.3
88.7
88.1


capacity ratio
to R410A)

























TABLE 60







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
81
82
83
84
85
86
87
88
























HFO-1132(E)
Mass %
50.0
55.0
10.0
15.0
20.0
25.0
30.0
35.0


HFO-1123
Mass %
7.9
2.9
42.9
37.9
32.9
27.9
22.9
17.9


R1234yf
Mass %
35.0
35.0
40.0
40.0
40.0
40.0
40.0
40.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

50
50
50
50
50
50
50
50


COP ratio
% (relative
99.0
99.4
96.6
96.9
97.2
97.6
98.0
98.4



to R410A)


Refrigerating
% (relative
87.4
86.7
88.0
87.8
87.5
87.1
86.6
86.1


capacity ratio
to R410A)

























TABLE 61







Comp.
Comp.
Comp.
Comp.
Comp.
Comp.
Comp.
Comp.


Item
Unit
Ex. 72
Ex. 73
Ex. 74
Ex. 75
Ex. 76
Ex. 77
Ex. 78
Ex. 79
























HFO-1132(E)
Mass %
40.0
45.0
50.0
10.0
15.0
20.0
25.0
30.0


HFO-1123
Mass %
12.9
7.9
2.9
37.9
32.9
27.9
22.9
17.9


R1234yf
Mass %
40.0
40.0
40.0
45.0
45.0
45.0
45.0
45.0


R32
Mass %
7.1
7.1
7.1
7.1
7.1
7.1
7.1
7.1


GWP

50
50
50
50
50
50
50
50


COP ratio
% (relative
98.8
99.2
99.6
97.4
97.7
98.0
98.3
98.7



to R410A)


Refrigerating
% (relative
85.5
84.9
84.2
84.9
84.6
84.3
83.9
83.5


capacity ratio
to R410A)




















TABLE 62







Comp.
Comp.
Comp.


Item
Unit
Ex. 80
Ex. 81
Ex. 82



















HFO-1132(E)
Mass %
35.0
40.0
45.0


HFO-1123
Mass %
12.9
7.9
2.9


R1234yf
Mass %
45.0
45.0
45.0


R32
Mass %
7.1
7.1
7.1


GWP

50
50
50


COP ratio
% (relative
99.1
99.5
99.9



to R410A)


Refrigerating
% (relative
82.9
82.3
81.7


capacity ratio
to R410A)

























TABLE 63







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
89
90
91
92
93
94
95
96
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0


HFO-1123
Mass %
70.5
65.5
60.5
55.5
50.5
45.5
40.5
35.5


R1234yf
Mass %
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

99
99
99
99
99
99
99
99


COP ratio
% (relative
93.7
93.9
94.1
94.4
94.7
95.0
95.4
95.8



to R410A)


Refrigerating
% (relative
110.2
110.0
109.7
109.3
108.9
108.4
107.9
107.3


capacity ratio
to R410A)

























TABLE 64







Ex.
Comp.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
97
Ex. 83
98
99
100
101
102
103
























HFO-1132(E)
Mass %
50.0
55.0
10.0
15.0
20.0
25.0
30.0
35.0


HFO-1123
Mass %
30.5
25.5
65.5
60.5
55.5
50.5
45.5
40.5


R1234yf
Mass %
5.0
5.0
10.0
10.0
10.0
10.0
10.0
10.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

99
99
99
99
99
99
99
99


COP ratio
% (relative
96.2
96.6
94.2
94.4
94.6
94.9
95.2
95.5



to R410A)


Refrigerating
% (relative
106.6
106.0
107.5
107.3
107.0
106.6
106.1
105.6


capacity ratio
to R410A)

























TABLE 65







Ex.
Ex.
Ex.
Comp.
Ex.
Ex.
Ex.
Ex.


Item
Unit
104
105
106
Ex. 84
107
108
109
110
























HFO-1132(E)
Mass %
40.0
45.0
50.0
55.0
10.0
15.0
20.0
25.0


HFO-1123
Mass %
35.5
30.5
25.5
20.5
60.5
55.5
50.5
45.5


R1234yf
Mass %
10.0
10.0
10.0
10.0
15.0
15.0
15.0
15.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

99
99
99
99
99
99
99
99


COP ratio
% (relative
95.9
96.3
96.7
97.1
94.6
94.8
95.1
95.4



to R410A)


Refrigerating
% (relative
105.1
104.5
103.8
103.1
104.7
104.5
104.1
103.7


capacity ratio
to R410A)

























TABLE 66







Ex.
Ex.
Ex.
Ex.
Ex.
Comp.
Ex.
Ex.


Item
Unit
111
112
113
114
115
Ex. 85
116
117
























HFO-1132(E)
Mass %
30.0
35.0
40.0
45.0
50.0
55.0
10.0
15.0


HFO-1123
Mass %
40.5
35.5
30.5
25.5
20.5
15.5
55.5
50.5


R1234yf
Mass %
15.0
15.0
15.0
15.0
15.0
15.0
20.0
20.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

99
99
99
99
99
99
99
99


COP ratio
% (relative
95.7
96.0
96.4
96.8
97.2
97.6
95.1
95.3



to R410A)


Refrigerating
% (relative
103.3
102.8
102.2
101.6
101.0
100.3
101.8
101.6


capacity ratio
to R410A)

























TABLE 67







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Comp.


Item
Unit
118
119
120
121
122
123
124
Ex. 86
























HFO-1132(E)
Mass %
20.0
25.0
30.0
35.0
40.0
45.0
50.0
55.0


HFO-1123
Mass %
45.5
40.5
35.5
30.5
25.5
20.5
15.5
10.5


R1234yf
Mass %
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

99
99
99
99
99
99
99
99


COP ratio
% (relative
95.6
95.9
96.2
96.5
96.9
97.3
97.7
98.2



to R410A)


Refrigerating
% (relative
101.2
100.8
100.4
99.9
99.3
98.7
98.0
97.3


capacity ratio
to R410A)

























TABLE 68







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
125
126
127
128
129
130
131
132
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0


HFO-1123
Mass %
50.5
45.5
40.5
35.5
30.5
25.5
20.5
15.5


R1234yf
Mass %
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

99
99
99
99
99
99
99
99


COP ratio
% (relative
95.6
95.9
96.1
96.4
96.7
97.1
97.5
97.9



to R410A)


Refrigerating
% (relative to
98.9
98.6
98.3
97.9
97.4
96.9
96.3
95.7


capacity ratio
R410A)

























TABLE 69







Ex.
Comp.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
133
Ex. 87
134
135
136
137
138
139
























HFO-1132(E)
Mass %
50.0
55.0
10.0
15.0
20.0
25.0
30.0
35.0


HFO-1123
Mass %
10.5
5.5
45.5
40.5
35.5
30.5
25.5
20.5


R1234yf
Mass %
25.0
25.0
30.0
30.0
30.0
30.0
30.0
30.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

99
99
100
100
100
100
100
100


COP ratio
% (relative
98.3
98.7
96.2
96.4
96.7
97.0
97.3
97.7



to R410A)


Refrigerating
% (relative
95.0
94.3
95.8
95.6
95.2
94.8
94.4
93.8


capacity ratio
to R410A)

























TABLE 70







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
140
141
142
143
144
145
146
147
























HFO-1132(E)
Mass %
40.0
45.0
50.0
10.0
15.0
20.0
25.0
30.0


HFO-1123
Mass %
15.5
10.5
5.5
40.5
35.5
30.5
25.5
20.5


R1234yf
Mass %
30.0
30.0
30.0
35.0
35.0
35.0
35.0
35.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

100
100
100
100
100
100
100
100


COP ratio
% (relative
98.1
98.5
98.9
96.8
97.0
97.3
97.6
97.9



to R410A)


Refrigerating
% (relative
93.3
92.6
92.0
92.8
92.5
92.2
91.8
91.3


capacity ratio
to R410A)

























TABLE 71







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
148
149
150
151
152
153
154
155
























HFO-1132(E)
Mass %
35.0
40.0
45.0
10.0
15.0
20.0
25.0
30.0


HFO-1123
Mass %
15.5
10.5
5.5
35.5
30.5
25.5
20.5
15.5


R1234yf
Mass %
35.0
35.0
35.0
40.0
40.0
40.0
40.0
40.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

100
100
100
100
100
100
100
100


COP ratio
% (relative
98.3
98.7
99.1
97.4
97.7
98.0
98.3
98.6



to R410A)


Refrigerating
% (relative
90.8
90.2
89.6
89.6
89.4
89.0
88.6
88.2


capacity ratio
to R410A)

























TABLE 72







Ex.
Ex.
Ex.
Ex.
Ex.
Comp.
Comp.
Comp.


Item
Unit
156
157
158
159
160
Ex. 88
Ex. 89
Ex. 90
























HFO-1132(E)
Mass %
35.0
40.0
10.0
15.0
20.0
25.0
30.0
35.0


HFO-1123
Mass %
10.5
5.5
30.5
25.5
20.5
15.5
10.5
5.5


R1234yf
Mass %
40.0
40.0
45.0
45.0
45.0
45.0
45.0
45.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5
14.5
14.5
14.5


GWP

100
100
100
100
100
100
100
100


COP ratio
% (relative
98.9
99.3
98.1
98.4
98.7
98.9
99.3
99.6



to R410A)


Refrigerating
% (relative
87.6
87.1
86.5
86.2
85.9
85.5
85.0
84.5


capacity ratio
to R410A)






















TABLE 73







Comp.
Comp.
Comp.
Comp.
Comp.


Item
Unit
Ex. 91
Ex. 92
Ex. 93
Ex. 94
Ex. 95





















HFO-
Mass %
10.0
15.0
20.0
25.0
30.0


1132(E)


HFO-1123
Mass %
25.5
20.5
15.5
10.5
5.5


R1234yf
Mass %
50.0
50.0
50.0
50.0
50.0


R32
Mass %
14.5
14.5
14.5
14.5
14.5


GWP

100
100
100
100
100


COP ratio
% (relative
98.9
99.1
99.4
99.7
100.0



to R410A)


Refrigerating
% (relative
83.3
83.0
82.7
82.2
81.8


capacity ratio
to R410A)

























TABLE 74







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
161
162
163
164
165
166
167
168
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0


HFO-1123
Mass %
63.1
58.1
53.1
48.1
43.1
38.1
33.1
28.1


R1234yf
Mass %
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9


GWP

149
149
149
149
149
149
149
149


COP ratio
% (relative
94.8
95.0
95.2
95.4
95.7
95.9
96.2
96.6



to R410A)


Refrigerating
% (relative
111.5
111.2
110.9
110.5
110.0
109.5
108.9
108.3


capacity ratio
to R410A)

























TABLE 75







Comp.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
Ex. 96
169
170
171
172
173
174
175
























HFO-1132(E)
Mass %
50.0
10.0
15.0
20.0
25.0
30.0
35.0
40.0


HFO-1123
Mass %
23.1
58.1
53.1
48.1
43.1
38.1
33.1
28.1


R1234yf
Mass %
5.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9


GWP

149
149
149
149
149
149
149
149


COP ratio
% (relative
96.9
95.3
95.4
95.6
95.8
96.1
96.4
96.7



to R410A)


Refrigerating
% (relative
107.7
108.7
108.5
108.1
107.7
107.2
106.7
106.1


capacity ratio
to R410A)

























TABLE 76







Ex.
Comp.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
176
Ex. 97
177
178
179
180
181
182
























HFO-1132(E)
Mass %
45.0
50.0
10.0
15.0
20.0
25.0
30.0
35.0


HFO-1123
Mass %
23.1
18.1
53.1
48.1
43.1
38.1
33.1
28.1


R1234yf
Mass %
10.0
10.0
15.0
15.0
15.0
15.0
15.0
15.0


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9


GWP

149
149
149
149
149
149
149
149


COP ratio
% (relative
97.0
97.4
95.7
95.9
96.1
96.3
96.6
96.9



to R410A)


Refrigerating
% (relative
105.5
104.9
105.9
105.6
105.3
104.8
104.4
103.8


capacity ratio
to R410A)

























TABLE 77







Ex.
Ex.
Comp.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
183
184
Ex. 98
185
186
187
188
189
























HFO-1132(E)
Mass %
40.0
45.0
50.0
10.0
15.0
20.0
25.0
30.0


HFO-1123
Mass %
23.1
18.1
13.1
48.1
43.1
38.1
33.1
28.1


R1234yf
Mass %
15.0
15.0
15.0
20.0
20.0
20.0
20.0
20.0


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9


GWP

149
149
149
149
149
149
149
149


COP ratio
% (relative
97.2
97.5
97.9
96.1
96.3
96.5
96.8
97.1



to R410A)


Refrigerating
% (relative
103.3
102.6
102.0
103.0
102.7
102.3
101.9
101.4


capacity ratio
to R410A)

























TABLE 78







Ex.
Ex.
Ex.
Comp.
Ex.
Ex.
Ex.
Ex.


Item
Unit
190
191
192
Ex. 99
193
194
195
196
























HFO-1132(E)
Mass %
35.0
40.0
45.0
50.0
10.0
15.0
20.0
25.0


HFO-1123
Mass %
23.1
18.1
13.1
8.1
43.1
38.1
33.1
28.1


R1234yf
Mass %
20.0
20.0
20.0
20.0
25.0
25.0
25.0
25.0


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9


GWP

149
149
149
149
149
149
149
149


COP ratio
% (relative
97.4
97.7
98.0
98.4
96.6
96.8
97.0
97.3



to R410A)


Refrigerating
% (relative
100.9
100.3
99.7
99.1
100.0
99.7
99.4
98.9


capacity ratio
to R410A)

























TABLE 79







Ex.
Ex.
Ex.
Ex.
Comp.
Ex.
Ex.
Ex.


Item
Unit
197
198
199
200
Ex. 100
201
202
203
























HFO-1132(E)
Mass %
30.0
35.0
40.0
45.0
50.0
10.0
15.0
20.0


HFO-1123
Mass %
23.1
18.1
13.1
8.1
3.1
38.1
33.1
28.1


R1234yf
Mass %
25.0
25.0
25.0
25.0
25.0
30.0
30.0
30.0


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9


GWP

149
149
149
149
149
150
150
150


COP ratio
% (relative
97.6
97.9
98.2
98.5
98.9
97.1
97.3
97.6



to R410A)


Refrigerating
% (relative
98.5
97.9
97.4
96.8
96.1
97.0
96.7
96.3


capacity ratio
to R410A)

























TABLE 80







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
204
205
206
207
208
209
210
211
























HFO-1132(E)
Mass %
25.0
30.0
35.0
40.0
45.0
10.0
15.0
20.0


HFO-1123
Mass %
23.1
18.1
13.1
8.1
3.1
33.1
28.1
23.1


R1234yf
Mass %
30.0
30.0
30.0
30.0
30.0
35.0
35.0
35.0


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9


GWP

150
150
150
150
150
150
150
150


COP ratio
% (relative
97.8
98.1
98.4
98.7
99.1
97.7
97.9
98.1



to R410A)


Refrigerating
% (relative
95.9
95.4
94.9
94.4
93.8
93.9
93.6
93.3


capacity ratio
to R410A)

























TABLE 81







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
212
213
214
215
216
217
218
219
























HFO-1132(E)
Mass %
25.0
30.0
35.0
40.0
10.0
15.0
20.0
25.0


HFO-1123
Mass %
18.1
13.1
8.1
3.1
28.1
23.1
18.1
13.1


R1234yf
Mass %
35.0
35.0
35.0
35.0
40.0
40.0
40.0
40.0


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9


GWP

150
150
150
150
150
150
150
150


COP ratio
% (relative
98.4
98.7
99.0
99.3
98.3
98.5
98.7
99.0



to R410A)


Refrigerating
% (relative
92.9
92.4
91.9
91.3
90.8
90.5
90.2
89.7


capacity ratio
to R410A)

























TABLE 82







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Comp.


Item
Unit
220
221
222
223
224
225
226
Ex. 101
























HFO-1132(E)
Mass %
30.0
35.0
10.0
15.0
20.0
25.0
30.0
10.0


HFO-1123
Mass %
8.1
3.1
23.1
18.1
13.1
8.1
3.1
18.1


R1234yf
Mass %
40.0
40.0
45.0
45.0
45.0
45.0
45.0
50.0


R32
Mass %
21.9
21.9
21.9
21.9
21.9
21.9
21.9
21.9


GWP

150
150
150
150
150
150
150
150


COP ratio
% (relative
99.3
99.6
98.9
99.1
99.3
99.6
99.9
99.6



to R410A)


Refrigerating
% (relative
89.3
88.8
87.6
87.3
87.0
86.6
86.2
84.4


capacity ratio
to R410A)




















TABLE 83







Comp.
Comp.
Comp.


Item
Unit
Ex. 102
Ex. 103
Ex. 104



















HFO-1132(E)
Mass %
15.0
20.0
25.0


HFO-1123
Mass %
13.1
8.1
3.1


R1234yf
Mass %
50.0
50.0
50.0


R32
Mass %
21.9
21.9
21.9


GWP

150
150
150


COP ratio
% (relative
99.8
100.0
100.2



to R410A)


Refrigerating
% (relative
84.1
83.8
83.4


capacity ratio
to R410A)

























TABLE 84







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Comp.


Item
Unit
227
228
229
230
231
232
233
Ex. 105
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0


HFO-1123
Mass %
55.7
50.7
45.7
40.7
35.7
30.7
25.7
20.7


R1234yf
Mass %
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0


R32
Mass %
29.3
29.3
29.3
29.3
29.3
29.3
29.3
29.3


GWP

199
199
199
199
199
199
199
199


COP ratio
% (relative
95.9
96.0
96.2
96.3
96.6
96.8
97.1
97.3



to R410A)


Refrigerating
% (relative
112.2
111.9
111.6
111.2
110.7
110.2
109.6
109.0


capacity ratio
to R410A)

























TABLE 85







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Comp.


Item
Unit
234
235
236
237
238
239
240
Ex. 106
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0


HFO-1123
Mass %
50.7
45.7
40.7
35.7
30.7
25.7
20.7
15.7


R1234yf
Mass %
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0


R32
Mass %
29.3
29.3
29.3
29.3
29.3
29.3
29.3
29.3


GWP

199
199
199
199
199
199
199
199


COP ratio
% (relative
96.3
96.4
96.6
96.8
97.0
97.2
97.5
97.8



to R410A)


Refrigerating
% (relative
109.4
109.2
108.8
108.4
107.9
107.4
106.8
106.2


capacity ratio
to R410A)

























TABLE 86







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Comp.


Item
Unit
241
242
243
244
245
246
247
Ex. 107
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0


HFO-1123
Mass %
45.7
40.7
35.7
30.7
25.7
20.7
15.7
10.7


R1234yf
Mass %
15.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0


R32
Mass %
29.3
29.3
29.3
29.3
29.3
29.3
29.3
29.3


GWP

199
199
199
199
199
199
199
199


COP ratio
% (relative
96.7
96.8
97.0
97.2
97.4
97.7
97.9
98.2



to R410A)


Refrigerating
% (relative
106.6
106.3
106.0
105.5
105.1
104.5
104.0
103.4


capacity ratio
to R410A)

























TABLE 87







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Comp.


Item
Unit
248
249
250
251
252
253
254
Ex. 108
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
40.0
45.0


HFO-1123
Mass %
40.7
35.7
30.7
25.7
20.7
15.7
10.7
5.7


R1234yf
Mass %
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0


R32
Mass %
29.3
29.3
29.3
29.3
29.3
29.3
29.3
29.3


GWP

199
199
199
199
199
199
199
199


COP ratio
% (relative
97.1
97.3
97.5
97.7
97.9
98.1
98.4
98.7



to R410A)


Refrigerating
% (relative
103.7
103.4
103.0
102.6
102.2
101.6
101.1
100.5


capacity ratio
to R410A)

























TABLE 88







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
255
256
257
258
259
260
261
262
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
40.0
10.0


HFO-1123
Mass %
35.7
30.7
25.7
20.7
15.7
10.7
5.7
30.7


R1234yf
Mass %
25.0
25.0
25.0
25.0
25.0
25.0
25.0
30.0


R32
Mass %
29.3
29.3
29.3
29.3
29.3
29.3
29.3
29.3


GWP

199
199
199
199
199
199
199
199


COP ratio
% (relative
97.6
97.7
97.9
98.1
98.4
98.6
98.9
98.1



to R410A)


Refrigerating
% (relative
100.7
100.4
100.1
99.7
99.2
98.7
98.2
97.7


capacity ratio
to R410A)

























TABLE 89







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
263
264
265
266
267
268
269
270
























HFO-1132(E)
Mass %
15.0
20.0
25.0
30.0
35.0
10.0
15.0
20.0


HFO-1123
Mass %
25.7
20.7
15.7
10.7
5.7
25.7
20.7
15.7


R1234yf
Mass %
30.0
30.0
30.0
30.0
30.0
35.0
35.0
35.0


R32
Mass %
29.3
29.3
29.3
29.3
29.3
29.3
29.3
29.3


GWP

199
199
199
199
199
200
200
200


COP ratio
% (relative
98.2
98.4
98.6
98.9
99.1
98.6
98.7
98.9



to R410A)


Refrigerating
% (relative
97.4
97.1
96.7
96.2
95.7
94.7
94.4
94.0


capacity ratio
to R410A)

























TABLE 90







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
271
272
273
274
275
276
277
278
























HFO-1132(E)
Mass %
25.0
30.0
10.0
15.0
20.0
25.0
10.0
15.0


HFO-1123
Mass %
10.7
5.7
20.7
15.7
10.7
5.7
15.7
10.7


R1234yf
Mass %
35.0
35.0
40.0
40.0
40.0
40.0
45.0
45.0


R32
Mass %
29.3
29.3
29.3
29.3
29.3
29.3
29.3
29.3


GWP

200
200
200
200
200
200
200
200


COP ratio
% (relative
99.2
99.4
99.1
99.3
99.5
99.7
99.7
99.8



to R410A)


Refrigerating
% (relative
93.6
93.2
91.5
91.3
90.9
90.6
88.4
88.1


capacity ratio
to R410A)





















TABLE 91







Ex.
Ex.
Comp.
Comp.


Item
Unit
279
280
Ex. 109
Ex. 110




















HFO-1132(E)
Mass %
20.0
10.0
15.0
10.0


HFO-1123
Mass %
5.7
10.7
5.7
5.7


R1234yf
Mass %
45.0
50.0
50.0
55.0


R32
Mass %
29.3
29.3
29.3
29.3


GWP

200
200
200
200


COP ratio
% (relative
100.1
100.3
100.4
100.9



to R410A)


Refrigerating
% (relative
87.8
85.2
85.0
82.0


capacity ratio
to R410A)

























TABLE 92







Ex.
Ex.
Ex.
Ex.
Ex.
Comp.
Ex.
Ex.


Item
Unit
281
282
283
284
285
Ex. 111
286
287
























HFO-1132(E)
Mass %
10.0
15.0
20.0
25.0
30.0
35.0
10.0
15.0


HFO-1123
Mass %
40.9
35.9
30.9
25.9
20.9
15.9
35.9
30.9


R1234yf
Mass %
5.0
5.0
5.0
5.0
5.0
5.0
10.0
10.0


R32
Mass %
44.1
44.1
44.1
44.1
44.1
44.1
44.1
44.1


GWP

298
298
298
298
298
298
299
299


COP ratio
% (relative
97.8
97.9
97.9
98.1
98.2
98.4
98.2
98.2



to R410A)


Refrigerating
% (relative
112.5
112.3
111.9
111.6
111.2
110.7
109.8
109.5


capacity ratio
to R410A)

























TABLE 93







Ex.
Ex.
Ex.
Comp.
Ex.
Ex.
Ex.
Ex.


Item
Unit
288
289
290
Ex. 112
291
292
293
294
























HFO-1132(E)
Mass %
20.0
25.0
30.0
35.0
10.0
15.0
20.0
25.0


HFO-1123
Mass %
25.9
20.9
15.9
10.9
30.9
25.9
20.9
15.9


R1234yf
Mass %
10.0
10.0
10.0
10.0
15.0
15.0
15.0
15.0


R32
Mass %
44.1
44.1
44.1
44.1
44.1
44.1
44.1
44.1


GWP

299
299
299
299
299
299
299
299


COP ratio
% (relative
98.3
98.5
98.6
98.8
98.6
98.6
98.7
98.9



to R410A)


Refrigerating
% (relative
109.2
108.8
108.4
108.0
107.0
106.7
106.4
106.0


capacity ratio
to R410A)

























TABLE 94







Ex.
Comp.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
295
Ex. 113
296
297
298
299
300
301
























HFO-1132(E)
Mass %
30.0
35.0
10.0
15.0
20.0
25.0
30.0
10.0


HFO-1123
Mass %
10.9
5.9
25.9
20.9
15.9
10.9
5.9
20.9


R1234yf
Mass %
15.0
15.0
20.0
20.0
20.0
20.0
20.0
25.0


R32
Mass %
44.1
44.1
44.1
44.1
44.1
44.1
44.1
44.1


GWP

299
299
299
299
299
299
299
299


COP ratio
% (relative
99.0
99.2
99.0
99.0
99.2
99.3
99.4
99.4



to R410A)


Refrigerating
% (relative
105.6
105.2
104.1
103.9
103.6
103.2
102.8
101.2


capacity ratio
to R410A)

























TABLE 95







Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.
Ex.


Item
Unit
302
303
304
305
306
307
308
309
























HFO-1132(E)
Mass %
15.0
20.0
25.0
10.0
15.0
20.0
10.0
15.0


HFO-1123
Mass %
15.9
10.9
5.9
15.9
10.9
5.9
10.9
5.9


R1234yf
Mass %
25.0
25.0
25.0
30.0
30.0
30.0
35.0
35.0


R32
Mass %
44.1
44.1
44.1
44.1
44.1
44.1
44.1
44.1


GWP

299
299
299
299
299
299
299
299


COP ratio
% (relative
99.5
99.6
99.7
99.8
99.9
100.0
100.3
100.4



to R410A)


Refrigerating
% (relative
101.0
100.7
100.3
98.3
98.0
97.8
95.3
95.1


capacity ratio
to R410A)




















TABLE 96









Ex.



Item
Unit
400




















HFO-1132(E)
Mass %
10.0



HFO-1123
Mass %
5.9



R1234yf
Mass %
40.0



R32
Mass %
44.1



GWP

299



COP ratio
% (relative
100.7




to R410A)



Refrigerating
% (relative
92.3



capacity ratio
to R410A)












    • The above results indicate that the refrigerating capacity ratio relative to R410A is 85% or more in the following cases:

    • When the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum is respectively represented by x, y, z, and a, in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass %, a straight line connecting a point (0.0, 100.0−a, 0.0) and a point (0.0, 0.0, 100.0−a) is the base, and the point (0.0, 100.0−a, 0.0) is on the left side, if 0<a≤11.1, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0134a2−1.9681a+68.6, 0.0, −0.0134a2+0.9681a+31.4) and point B (0.0, 0.0144a2−1.6377a+58.7, −0.0144a2+0.6377a+41.3);

    • if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0112a2−1.9337a+68.484, 0.0, −0.0112a2+0.9337a+31.516) and point B (0.0, 0.0075a2−1.5156a+58.199, −0.0075a2+0.5156a+41.801);

    • if 18.2a<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0107a2−1.9142a+68.305, 0.0, −0.0107a2+0.9142a+31.695) and point B (0.0, 0.009a2−1.6045a+59.318, −0.009a2+0.6045a+40.682);

    • if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0103a2−1.9225a+68.793, 0.0, −0.0103a2+0.9225a+31.207) and point B (0.0, 0.0046a2−1.41a+57.286, −0.0046a2+0.41a+42.714); and

    • if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are on, or on the left side of, a straight line AB that connects point A (0.0085a2−1.8102a+67.1, 0.0, −0.0085a2+0.8102a+32.9) and point B (0.0, 0.0012a2−1.1659a+52.95, −0.0012a2+0.1659a+47.05).

    • Actual points having a refrigerating capacity ratio of 85% or more form a curved line that connects point A and point B in FIG. 3, and that extends toward the 1234yf side. Accordingly, when coordinates are on, or on the left side of, the straight line AB, the refrigerating capacity ratio relative to R410A is 85% or more.

    • Similarly, it was also found that in the ternary composition diagram, if 0<a≤11.1, when coordinates (x,y,z) are on, or on the left side of, a straight line D′C that connects point D′ (0.0, 0.0224a2+0.968a+75.4, −0.0224a2−1.968a+24.6) and point C (−0.2304a2−0.4062a+32.9, 0.2304a2−0.5938a+67.1, 0.0); or if 11.1<a≤46.7, when coordinates are in the entire region, the COP ratio relative to that of R410A is 92.5% or more.

    • In FIG. 3, the COP ratio of 92.5% or more forms a curved line CD. In FIG. 3, an approximate line formed by connecting three points: point C (32.9, 67.1, 0.0) and points (26.6, 68.4, 5) (19.5, 70.5, 10) where the COP ratio is 92.5% when the concentration of R1234yf is 5 mass % and 10 mass was obtained, and a straight line that connects point C and point D′ (0, 75.4, 24.6), which is the intersection of the approximate line and a point where the concentration of HFO-1132(E) is 0.0 mass % was defined as a line segment D′C. In FIG. 4, point D′(0, 83.4, 9.5) was similarly obtained from an approximate curve formed by connecting point C (18.4, 74.5, 0) and points (13.9, 76.5, 2.5) (8.7, 79.2, 5) where the COP ratio is 92.5%, and a straight line that connects point C and point D′ was defined as the straight line D′C.

    • The composition of each mixture was defined as WCF. A leak simulation was performed using NIST Standard Reference Database REFLEAK Version 4.0 under the conditions of Equipment, Storage, Shipping, Leak, and Recharge according to the ASHRAE Standard 34-2013. The most flammable fraction was defined as WCFF.

    • For the flammability, the burning velocity was measured according to the ANSI/ASHRAE Standard 34-2013. Both WCF and WCFF having a burning velocity of 10 cm/s or less were determined to be classified as “Class 2L (lower flammability).”

    • A burning velocity test was performed using the apparatus shown in FIG. 1 in the following manner. First, the mixed refrigerants used had a purity of 99.5% or more, and were degassed by repeating a cycle of freezing, pumping, and thawing until no traces of air were observed on the vacuum gauge. The burning velocity was measured by the closed method. The initial temperature was ambient temperature. Ignition was performed by generating an electric spark between the electrodes in the center of a sample cell. The duration of the discharge was 1.0 to 9.9 ms, and the ignition energy was typically about 0.1 to 1.0 J. The spread of the flame was visualized using schlieren photographs. A cylindrical container (inner diameter: 155 mm, length: 198 mm) equipped with two light transmission acrylic windows was used as the sample cell, and a xenon lamp was used as the light source. Schlieren images of the flame were recorded by a high-speed digital video camera at a frame rate of 600 fps and stored on a PC.

    • The results are shown in Tables 97 to 104.


















TABLE 97






Comp.
Comp.
Comp.
Comp.
Comp.
Comp.


Item
Ex. 6
Ex. 13
Ex. 19
Ex. 24
Ex. 29
Ex. 34























WCF
HFO-1132(E)
Mass %
72.0
60.9
55.8
52.1
48.6
45.4



HFO-1123
Mass %
28.0
32.0
33.1
33.4
33.2
32.7



R1234yf
Mass %
0.0
0.0
0.0
0
0
0



R32
Mass %
0.0
7.1
11.1
14.5
18.2
21.9














Burning velocity (WCF)
cm/s
10
10
10
10
10
10





















TABLE 98






Comp.
Comp.
Comp.
Comp.
Comp.


Item
Ex. 39
Ex. 45
Ex. 51
Ex. 57
Ex. 62






















WCF
HFO-1132(E)
Mass %
41.8
40
35.7
32
30.4



HFO-1123
Mass %
31.5
30.7
23.6
23.9
21.8



R1234yf
Mass %
0
0
0
0
0



R32
Mass %
26.7
29.3
36.7
44.1
47.8













Burning velocity (WCF)
cm/s
10
10
10
10
10






















TABLE 99






Comp.
Comp.
Comp.
Comp.
Comp.
Comp.


Item
Ex. 7
Ex. 14
Ex. 20
Ex. 25
Ex. 30
Ex. 35























WCF
HFO-1132(E)
Mass %
72.0
60.9
55.8
52.1
48.6
45.4



HFO-1123
Mass %
0.0
0.0
0.0
0
0
0



R1234yf
Mass %
28.0
32.0
33.1
33.4
33.2
32.7



R32
Mass %
0.0
7.1
11.1
14.5
18.2
21.9














Burning velocity (WCF)
cm/s
10
10
10
10
10
10





















TABLE 100






Comp.
Comp.
Comp.
Comp.
Comp.


Item
Ex. 40
Ex. 46
Ex. 52
Ex. 58
Ex. 63






















WCF
HFO-1132(E)
Mass %
41.8
40
35.7
32
30.4



HFO-1123
Mass %
0
0
0
0
0



R1234yf
Mass %
31.5
30.7
23.6
23.9
21.8



R32
Mass %
26.7
29.3
36.7
44.1
47.8













Burning velocity (WCF)
cm/s
10
10
10
10
10






















TABLE 101






Comp.
Comp.
Comp.
Comp.
Comp.
Comp.


Item
Ex. 8
Ex. 15
Ex. 21
Ex. 26
Ex. 31
Ex. 36























WCF
HFO-1132(E)
Mass %
47.1
40.5
37.0
34.3
32.0
30.3



HFO-1123
Mass %
52.9
52.4
51.9
51.2
49.8
47.8



R1234yf
Mass %
0.0
0.0
0.0
0.0
0.0
0.0



R32
Mass %
0.0
7.1
11.1
14.5
18.2
21.9













Leak condition that results in WCFF
Storage/
Storage/
Storage/
Storage/
Storage/
Storage/



Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°



C., 92%
C., 92%
C., 92%
C., 92%
C., 92%
C., 92%



release,
release,
release,
release,
release,
release,



liquid
liquid
liquid
liquid
liquid
liquid



phase side
phase side
phase side
phase side
phase side
phase side















WCFF
HFO-1132(E)
Mass %
72.0
62.4
56.2
50.6
45.1
40.0



HFO-1123
Mass %
28.0
31.6
33.0
33.4
32.5
30.5



R1234yf
Mass %
0.0
0.0
0.0
20.4
0.0
0.0



R32
Mass %
0.0
50.9
10.8
16.0
22.4
29.5














Burning velocity (WCF)
cm/s
8 or
8 or
8 or
8 or
8 or
8 or




less
less
less
less
less
less


Burning velocity (WCFF)
cm/s
10
10
10
10
10
10





















TABLE 102






Comp.
Comp.
Comp.
Comp.
Comp.


Item
Ex. 41
Ex. 47
Ex. 53
Ex. 59
Ex. 64






















WCF
HFO-1132(E)
Mass %
29.1
28.8
29.3
29.4
28.9



HFO-1123
Mass %
44.2
41.9
34.0
26.5
23.3



R1234yf
Mass %
0.0
0.0
0.0
0.0
0.0



R32
Mass %
26.7
29.3
36.7
44.1
47.8












Leak condition that results in WCFF
Storage/
Storage/
Storage/
Storage/
Storage/



Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°



C., 92%
C., 92%
C., 92%
C., 90%
C., 86%



release,
release,
release,
release,
release,



liquid
liquid
liquid
gas
gas



phase side
phase side
phase side
phase side
phase side














WCFF
HFO-1132(E)
Mass %
34.6
32.2
27.7
28.3
27.5



HFO-1123
Mass %
26.5
23.9
17.5
18.2
16.7



R1234yf
Mass %
0.0
0.0
0.0
0.0
0.0



R32
Mass %
38.9
43.9
54.8
53.5
55.8













Burning velocity (WCF)
cm/s
8 or less
8 or less
8.3
9.3
9.6


Burning velocity (WCFF)
cm/s
10
10
10
10
10






















TABLE 103






Comp.
Comp.
Comp.
Comp.
Comp.
Comp.


Item
Ex. 9
Ex. 16
Ex. 22
Ex. 27
Ex. 32
Ex. 37























WCF
HFO-1132(E)
Mass %
61.7
47.0
41.0
36.5
32.5
28.8



HFO-1123
Mass %
5.9
7.2
6.5
5.6
4.0
2.4



R1234yf
Mass %
32.4
38.7
41.4
43.4
45.3
46.9



R32
Mass %
0.0
7.1
11.1
14.5
18.2
21.9













Leak condition that results in WCFF
Storage/
Storage/
Storage/
Storage/
Storage/
Storage/



Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°



C., 0%
C., 0%
C., 0%
C., 92%
C., 0%
C., 0%



release,
release,
release,
release,
release,
release,



gas
gas
gas
liquid
gas
gas



phase side
phase side
phase side
phase side
phase side
phase side















WCFF
HFO-1132(E)
Mass %
72.0
56.2
50.4
46.0
42.4
39.1



HFO-1123
Mass %
10.5
12.6
11.4
10.1
7.4
4.4



R1234yf
Mass %
17.5
20.4
21.8
22.9
24.3
25.7



R32
Mass %
0.0
10.8
16.3
21.0
25.9
30.8














Burning velocity (WCF)
cm/s
8 or less
8 or less
8 or less
8 or less
8 or less
8 or less


Burning velocity (WCFF)
cm/s
10
10
10
10
10
10





















TABLE 104






Comp.
Comp.
Comp.
Comp.
Comp.


Item
Ex. 42
Ex. 48
Ex. 54
Ex. 60
Ex. 65






















WCF
HFO-1132(E)
Mass %
24.8
24.3
22.5
21.1
20.4



HFO-1123
Mass %
0.0
0.0
0.0
0.0
0.0



R1234yf
Mass %
48.5
46.4
40.8
34.8
31.8



R32
Mass %
26.7
29.3
36.7
44.1
47.8












Leak condition that results in WCFF
Storage/
Storage/
Storage/
Storage/
Storage/



Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°
Shipping −40°



C., 0%
C., 0%
C., 0%
C., 0%
C., 0%



release,
release,
release,
release,
release,



gas
gas
gas
gas
gas



phase side
phase side
phase side
phase side
phase side














WCFF
HFO-1132(E)
Mass %
35.3
34.3
31.3
29.1
28.1



HFO-1123
Mass %
0.0
0.0
0.0
0.0
0.0



R1234yf
Mass %
27.4
26.2
23.1
19.8
18.2



R32
Mass %
37.3
39.6
45.6
51.1
53.7













Burning velocity (WCF)
cm/s
8 or less
8 or less
8 or less
8 or less
8 or less


Burning velocity (WCFF)
cm/s
10
10
10
10
10











    • The results in Tables 97 to 100 indicate that the refrigerant has a WCF lower flammability in the following cases:

    • When the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum in the mixed refrigerant of HFO-1132(E), HFO-1123, R1234yf, and R32 is respectively represented by x, y, z, and a, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % and a straight line connecting a point (0.0, 100.0−a, 0.0) and a point (0.0, 0.0, 100.0−a) is the base, if 0<a≤11.1, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line GI that connects point G (0.026a2−1.7478a+72.0, −0.026a2+0.7478a+28.0, 0.0) and point I (0.026a2−1.7478a+72.0, 0.0, −0.026a2+0.7478a+28.0);


      if 11.1<a≤18.2, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line GI that connects point G (0.02a2−1.6013a+71.105, −0.02a2+0.6013a+28.895, 0.0) and point I (0.02a2−1.6013a+71.105, 0.0, −0.02a2+0.6013a+28.895); if 18.2<a≤26.7, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line GI that connects point G (0.0135a2−1.4068a+69.727, −0.0135a2+0.4068a+30.273, 0.0) and point I (0.0135a2−1.4068a+69.727, 0.0, −0.0135a2+0.4068a+30.273); if 26.7<a≤36.7, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line GI that connects point G (0.0111a2−1.3152a+68.986, −0.0111a2+0.3152a+31.014, 0.0) and point I (0.0111a2−1.3152a+68.986, 0.0, −0.0111a2+0.3152a+31.014); and if 36.7<a≤46.7, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line GI that connects point G (0.0061a2−0.9918a+63.902, −0.0061a2−0.0082a+36.098, 0.0) and point I (0.0061a2−0.9918a+63.902, 0.0, −0.0061a2−0.0082a+36.098).

    • Three points corresponding to point G (Table 105) and point I (Table 106) were individually obtained in each of the following five ranges by calculation, and their approximate expressions were obtained.















TABLE 105







Item
11.1 ≥ R32 > 0
18.2 ≥ R32 ≥ 11.1
26.7 ≥ R32 ≥ 18.2



















R32
0
7.1
11.1
11.1
14.5
18.2
18.2
21.9
26.7


HFO-1132(E)
72.0
60.9
55.8
55.8
52.1
48.6
48.6
45.4
41.8


HFO-1123
28.0
32.0
33.1
33.1
33.4
33.2
33.2
32.7
31.5


R1234yf
0
0
0
0
0
0
0
0
0










R32
a
a
a


HFO-1132(E)
  0.026a2 − 1.7478a + 72.0
  0.02a2 − 1.6013a + 71.105
 0.0135a2 − 1.4068a + 69.727


Approximate


expression


HFO-1123
−0.026a2 + 0..7478a + 28.0
−0.02a2 + 0..6013a + 28.895
−0.0135a2 + 0.4068a + 30.273


Approximate


expression


R1234yf
0
0
0


Approximate


expression














Item
36.7 ≥ R32 ≥ 26.7
46.7 ≥ R32 ≥ 36.7



















R32
26.7
29.3
36.7
36.7
44.1
47.8



HFO-1132(E)
41.8
40.0
35.7
35.7
32.0
30.4



HFO-1123
31.5
30.7
27.6
27.6
23.9
21.8



R1234yf
0
0
0
0
0
0











R32
a
a



HFO-1132(E)
 0.0111a2 − 1.3152a + 68.986
 0.0061a2 − 0.9918a + 63.902



Approximate



expression



HFO-1123
−0.0111a2 + 0.3152a + 31.014
−0.0061a2 − 0.0082a + 36.098



Approximate



expression



R1234yf
0
0



Approximate



expression




















TABLE 106







Item
11.1 ≥ R32 > 0
18.2 ≥ R32 ≥ 11.1
26.7 ≥ R32 ≥ 18.2



















R32
0
7.1
11.1
11.1
14.5
18.2
18.2
21.9
26.7


HFO-1132(E)
72.0
60.9
55.8
55.8
52.1
48.6
48.6
45.4
41.8


HFO-1123
0
0
0
0
0
0
0
0
0


R1234yf
28.0
32.0
33.1
33.1
33.4
33.2
33.2
32.7
31.5










R32
a
a
a


HFO-1132(E)
 0.026a2 − 1.7478a + 72.0
 0.02a2 − 1.6013a + 71.105
 0.0135a2 − 1.4068a + 69.727


Approximate


expression


HFO-1123
0
0
0


Approximate


expression


R1234yf
−0.026a2 + 0.7478a + 28.0
−0.02a2 + 0.6013a + 28.895
−0.0135a2 + 0.4068a + 30.273


Approximate


expression














Item
36.7 ≥ R32 ≥ 26.7
46.7 ≥ R32 ≥ 36.7



















R32
26.7
29.3
36.7
36.7
44.1
47.8



HFO-1132(E)
41.8
40.0
35.7
35.7
32.0
30.4



HFO-1123
0
0
0
0
0
0



R1234yf
31.5
30.7
23.6
23.6
23.5
21.8











R32
x
x



HFO-1132(E)
 0.0111a2 − 1.3152a + 68.986
 0.0061a2 − 0.9918a + 63.902



Approximate



expression



HFO-1123
0
0



Approximate



expression



R1234yf
−0.0111a2 + 0.3152a + 31.014
−0.0061a2 − 0.0082a + 36.098



Approximate



expression












    • The results in Tables 101 to 104 indicate that the refrigerant is determined to have a WCFF lower flammability, and the flammability classification according to the ASHRAE Standard is “2L (flammability)” in the following cases:

    • When the mass % of HFO-1132(E), HFO-1123, R1234yf, and R32 based on their sum in the mixed refrigerant of HFO-1132(E), HFO-1123, R1234yf, and R32 is respectively represented by x, y, z, and a, in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is (100−a) mass % and a straight line connecting a point (0.0, 100.0−a, 0.0) and a point (0.0, 0.0, 100.0−a) is the base, if 0<a≤11.1, coordinates (x,y,z) in the ternary composition diagram are on or below a straight line JK′ that connects point J (0.0049a2−0.9645a+47.1, −0.0049a2−0.0355a+52.9, 0.0) and point K′(0.0514a2−2.4353a+61.7, −0.0323a2+0.4122a+5.9, −0.0191a2+1.0231a+32.4); if 11.1<a≤18.2, coordinates are on a straight line JK′ that connects point J (0.0243a2−1.4161a+49.725, −0.0243a2+0.4161a+50.275, 0.0) and point K′(0.0341a2−2.1977a+61.187, −0.0236a2+0.34a+5.636, −0.0105a2+0.8577a+33.177); if 18.2<a≤26.7, coordinates are on or below a straight line JK′ that connects point J (0.0246a2−1.4476a+50.184, −0.0246a2+0.4476a+49.816, 0.0) and point K′ (0.0196a2−1.7863a+58.515, −0.0079a2−0.1136a+8.702, −0.0117a2+0.8999a+32.783); if 26.7<a≤36.7, coordinates are on or below a straight line JK′ that connects point J (0.0183a2−1.1399a+46.493, −0.0183a2+0.1399a+53.507, 0.0) and point K′ (−0.0051a2+0.0929a+25.95, 0.0, 0.0051a2−1.0929a+74.05); and if 36.7<a≤46.7, coordinates are on or below a straight line JK′ that connects point J (−0.0134a2+1.0956a+7.13, 0.0134a2−2.0956a+92.87, 0.0) and point K′(−1.892a+29.443, 0.0, 0.892a+70.557).

    • Actual points having a WCFF lower flammability form a curved line that connects point J and point K′ (on the straight line AB) in FIG. 3 and extends toward the HFO-1132(E) side. Accordingly, when coordinates are on or below the straight line JK′, WCFF lower flammability is achieved.

    • Three points corresponding to point J (Table 107) and point K′ (Table 108) were individually obtained in each of the following five ranges by calculation, and their approximate expressions were obtained.















TABLE 107







Item
11.1 ≥ R32 > 0
18.2 ≥ R32 ≥ 11.1
26.7 ≥ R32 ≥ 18.2



















R32
0
7.1
11.1
11.1
14.5
18.2
18.2
21.9
26.7


HFO-1132(E)
47.1
40.5
37
37.0
34.3
32.0
32.0
30.3
29.1


HFO-1123
52.9
52.4
51.9
51.9
51.2
49.8
49.8
47.8
44.2


R1234yf
0
0
0
0
0
0
0
0
0










R32
a
a
a


HFO-1132(E)
 0.0049a2 − 0.9645a + 47.1
 0.0243a2 − 1.4161a + 49.725
 0.0246a2 − 1.4476a + 50.184


Approximate


expression


HFO-1123
−0.0049a2 − 0.0355a + 52.9
−0.0243a2 + 0.4161a + 50.275
−0.0246a2 + 0.4476a + 49.816


Approximate


expression


R1234yf
0
0
0


Approximate


expression














Item
36.7 ≥ R32 ≥ 26.7
47.8 ≥ R32 ≥ 36.7



















R32
26.7
29.3
36.7
36.7
44.1
47.8



HFO-1132(E)
29.1
28.8
29.3
29.3
29.4
28.9



HFO-1123
44.2
41.9
34.0
34.0
26.5
23.3



R1234yf
0
0
0
0
0
0











R32
a
a



HFO-1132(E)
 0.0183a2 − 1.1399a + 46.493
−0.0134a2 + 1.0956a + 7.13



Approximate



expression



HFO-1123
−0.0183a2 + 0.1399a + 53.507
 0.0134a2 − 2.0956a + 92.87



Approximate



expression



R1234yf
0
0



Approximate



expression




















TABLE 108







Item
11.1 ≥ R32 > 0
18.2 ≥ R32 ≥ 11.1
26.7 ≥ R32 ≥ 18.2



















R32
0
7.1
11.1
11.1
14.5
18.2
18.2
21.9
26.7


HFO-1132(E)
61.7
47.0
41.0
41.0
36.5
32.5
32.5
28.8
24.8


HFO-1123
5.9
7.2
6.5
6.5
5.6
4.0
4.0
2.4
0


R1234yf
32.4
38.7
41.4
41.4
43.4
45.3
45.3
46.9
48.5










R32
x
x
x


HFO-1132(E)
 0.0514a2 − 2.4353a + 61.7
 0.0341a2 − 2.1977a + 61.187
 0.0196a2 − 1.7863a + 58.515


Approximate


expression


HFO-1123
−0.0323a2 + 0.4122a + 5.9 
−0.0236a2 + 0.34a + 5.636 
−0.0079a2 − 0.1136a + 8.702 


Approximate


expression


R1234yf
−0.0191a2 + 1.0231a + 32.4
−0.0105a2 + 0.8577a + 33.177
−0.0117a2 + 0.8999a + 32.783


Approximate


expression














Item
36.7 ≥ R32 ≥ 26.7
46.7 ≥ R32 ≥ 36.7



















R32
26.7
29.3
36.7
36.7
44.1
47.8



HFO-1132(E)
24.8
24.3
22.5
22.5
21.1
20.4



HFO-1123
0
0
0
0
0
0



R1234yf
48.5
46.4
40.8
40.8
34.8
31.8











R32
x
x



HFO-1132(E)
−0.0051a2 + 0.0929a + 25.95
−1.892a + 29.443



Approximate



expression



HFO-1123
0
0



Approximate



expression



R1234yf
 0.0051a2 − 1.0929a + 74.05
 0.892a + 70.557



Approximate



expression













    • FIGS. 3 to 13 show compositions whose R32 content a (mass %) is 0 mass %, 7.1 mass %, 11.1 mass %, 14.5 mass %, 18.2 mass %, 21.9 mass %, 26.7 mass %, 29.3 mass %, 36.7 mass %, 44.1 mass %, and 47.8 mass %, respectively.

    • Points A, B, C, and D′ were obtained in the following manner according to approximate calculation.

    • Point A is a point where the content of HFO-1123 is 0 mass %, and a refrigerating capacity ratio of 85% relative to that of R410A is achieved. Three points corresponding to point A were obtained in each of the following five ranges by calculation, and their approximate expressions were obtained (Table 109).















TABLE 109







Item
11.1 ≥ R32 > 0
18.2 ≥ R32 ≥ 11.1
26.7 ≥ R32 ≥ 18.2



















R32
0
7.1
11.1
11.1
14.5
18.2
18.2
21.9
26.7


HFO-1132(E)
68.6
55.3
48.4
48.4
42.8
37
37
31.5
24.8


HFO-1123
0
0
0
0
0
0
0
0
0


R1234yf
31.4
37.6
40.5
40.5
42.7
44.8
44.8
46.6
48.5










R32
a
a
a


HFO-1132(E)
 0.0134a2 − 1.9681a + 68.6
 0.0112a2 − 1.9337a + 68.484
 0.0107a2 − 1.9142a + 68.305


Approximate


expression


HFO-1123
0
0
0


Approximate


expression


R1234yf
−0.0134a2 + 0.9681a + 31.4
−0.0112a2 + 0.9337a + 31.516
−0.0107a2 + 0.9142a + 31.695


Approximate


expression














Item
36.7 ≥ R32 ≥ 26.7
46.7 ≥ R32 ≥ 36.7



















R32
26.7
29.3
36.7
36.7
44.1
47.8



HFO-1132(E)
24.8
21.3
12.1
12.1
3.8
0



HFO-1123
0
0
0
0
0
0



R1234yf
48.5
49.4
51.2
51.2
52.1
52.2











R32
a
a



HFO-1132(E)
 0.0103a2 − 1.9225a + 68.793
 0.0085a2 − 1.8102a + 67.1



Approximate



expression



HFO-1123
0
0



Approximate



expression



R1234yf
−0.0103a2 + 0.9225a + 31..207
−0.0085a2 + 0.8102a + 32.9



Approximate



expression












    • Point B is a point where the content of HFO-1132(E) is 0 mass %, and a refrigerating capacity ratio of 85% relative to that of R410A is achieved.

    • Three points corresponding to point B were obtained in each of the following five ranges by calculation, and their approximate expressions were obtained (Table 110).















TABLE 110







Item
11.1 ≥ R32 > 0
18.2 ≥ R32 ≥ 11.1
26.7 ≥ R32 ≥ 18.2



















R32
0
7.1
11.1
11.1
14.5
18.2
18.2
21.9
26.7


HFO-1132(E)
0
0
0
0
0
0
0
0
0


HFO-1123
58.7
47.8
42.3
42.3
37.8
33.1
33.1
28.5
22.9


R1234yf
41.3
45.1
46.6
46.6
47.7
48.7
48.7
49.6
50.4










R32
a
a
a


HFO-1132(E)
0
0
0


Approximate


expression


HFO-1123
 0.0144a2 − 1.6377a + 58.7
 0.0075a2 − 1.5156a + 58.199
 0.009a2 − 1.6045a + 59.318


Approximate


expression


R1234yf
−0.0144a2 + 0.6377a + 41.3
−0.0075a2 + 0.5156a + 41.801
−0.009a2 + 0.6045a + 40.682


Approximate


expression














Item
36.7 ≥ R32 ≥ 26.7
46.7 ≥ R32 ≥ 36.7



















R32
26.7
29.3
36.7
36.7
44.1
47.8



HFO-1132(E)
0
0
0
0
0
0



HFO-1123
22.9
19.9
11.7
11.8
3.9
0



R1234yf
50.4
50.8
51.6
51.5
52.0
52.2











R32
a
a



HFO-1132(E)
0
0



Approximate



expression



HFO-1123
 0.0046a2 − 1.41a + 57.286
 0.0012a2 − 1.1659a + 52.95



Approximate



expression



R1234yf
−0.0046a2 + 0.41a + 42.714
−0.0012a2 + 0.1659a + 47.05



Approximate



expression












    • Point D′ is a point where the content of HFO-1132(E) is 0 mass %, and a COP ratio of 95.5% relative to that of R410A is achieved.

    • Three points corresponding to point D′ were obtained in each of the following by calculation, and their approximate expressions were obtained (Table 111).















TABLE 111







Item
11.1 ≥ R32 > 0





















R32
0
7.1
11.1



HFO-1132(E)
0
0
0



HFO-1123
75.4
83.4
88.9



R1234yf
24.6
9.5
0










R32
a



HFO-1132(E)
0



Approximate



expression



HFO-1123
 0.0224a2 + 0.968a + 75.4



Approximate



expression



R1234yf
−0.0224a2 − 1.968a + 24.6



Approximate



expression












    • Point C is a point where the content of R1234yf is 0 mass %, and a COP ratio of 95.5% relative to that of R410A is achieved.

    • Three points corresponding to point C were obtained in each of the following by calculation, and their approximate expressions were obtained (Table 112).















TABLE 112







Item
11.1 ≥ R32 > 0





















R32
0
7.1
11.1



HFO-1132(E)
32.9
18.4
0



HFO-1123
67.1
74.5
88.9



R1234yf
0
0
0










R32
a



HFO-1132(E)
−0.2304a2 − 0.4062a + 32.9



Approximate



expression



HFO-1123
 0.2304a2 − 0.5938a + 67.1



Approximate



expression



R1234yf
0



Approximate



expression










(5-4) Refrigerant D





    • The refrigerant D according to the present disclosure is a mixed refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).

    • The refrigerant D according to the present disclosure has various properties that are desirable as an R410A-alternative refrigerant; i.e., a refrigerating capacity equivalent to that of R410A, a sufficiently low GWP, and a lower flammability (Class 2L) according to the ASHRAE standard.

    • The refrigerant D according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments IJ, JN, NE, and EI that connect the following 4 points:


      point I (72.0, 0.0, 28.0),


      point J (48.5, 18.3, 33.2),


      point N (27.7, 18.2, 54.1), and


      point E (58.3, 0.0, 41.7),


      or on these line segments (excluding the points on the line segment EI);

    • the line segment IJ is represented by coordinates (0.0236y2−1.7616y+72.0, y, −0.0236y2+0.7616y+28.0);

    • the line segment NE is represented by coordinates (0.012y2−1.9003y+58.3, y, −0.012y2+0.9003y+41.7); and

    • the line segments JN and EI are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 80% or more relative to R410A, a GWP of 125 or less, and a WCF lower flammability.

    • The refrigerant D according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments MM′, M′N, NV, VG, and GM that connect the following 5 points:


      point M (52.6, 0.0, 47.4),


      point M′ (39.2, 5.0, 55.8),


      point N (27.7, 18.2, 54.1),


      point V (11.0, 18.1, 70.9), and


      point G (39.6, 0.0, 60.4),


      or on these line segments (excluding the points on the line segment GM);

    • the line segment MM′ is represented by coordinates (0.132y2−3.34y+52.6, y, −0.132y2+2.34y+47.4);

    • the line segment M′N is represented by coordinates (0.0596y2−2.2541y+48.98, y, −0.0596y2+1.2541y+51.02);

    • the line segment VG is represented by coordinates (0.0123y2−1.8033y+39.6, y, −0.0123y2+0.8033y+60.4); and

    • the line segments NV and GM are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 70% or more relative to R410A, a GWP of 125 or less, and an ASHRAE lower flammability.

    • The refrigerant D according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ON, NU, and UO that connect the following 3 points:


      point O (22.6, 36.8, 40.6),


      point N (27.7, 18.2, 54.1), and


      point U (3.9, 36.7, 59.4),


      or on these line segments;

    • the line segment ON is represented by coordinates (0.0072y2−0.6701y+37.512, y, −0.0072y2−0.3299y+62.488);

    • the line segment NU is represented by coordinates (0.0083y2−1.7403y+56.635, y, −0.0083y2+0.7403y+43.365); and

    • the line segment UO is a straight line. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 80% or more relative to R410A, a GWP of 250 or less, and an ASHRAE lower flammability.

    • The refrigerant D according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments QR, RT, TL, LK, and KQ that connect the following 5 points:


      point Q (44.6, 23.0, 32.4),


      point R (25.5, 36.8, 37.7),


      point T (8.6, 51.6, 39.8),


      point L (28.9, 51.7, 19.4), and


      point K (35.6, 36.8, 27.6),


      or on these line segments;

    • the line segment QR is represented by coordinates (0.0099y2−1.975y+84.765, y, −0.0099y2+0.975y+15.235);

    • the line segment RT is represented by coordinates (0.0082y2−1.8683y+83.126, y, −0.0082y2+0.8683y+16.874);

    • the line segment LK is represented by coordinates (0.0049y2−0.8842y+61.488, y, −0.0049y2−0.1158y+38.512);

    • the line segment KQ is represented by coordinates (0.0095y2−1.2222y+67.676, y, −0.0095y2+0.2222y+32.324); and

    • the line segment TL is a straight line. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to R410A, a GWP of 350 or less, and a WCF lower flammability.

    • The refrigerant D according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:


      point P (20.5, 51.7, 27.8),


      point S (21.9, 39.7, 38.4), and


      point T (8.6, 51.6, 39.8),


      or on these line segments;

    • the line segment PS is represented by coordinates (0.0064y2−0.7103y+40.1, y, −0.0064y2−0.2897y+59.9);

    • the line segment ST is represented by coordinates (0.0082y2−1.8683y+83.126, y, −0.0082y2+0.8683y+16.874); and

    • the line segment TP is a straight line. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to R410A, a GWP of 350 or less, and an ASHRAE lower flammability.

    • The refrigerant D according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ac, cf, fd, and da that connect the following 4 points:


      point a (71.1, 0.0, 28.9),


      point c (36.5, 18.2, 45.3),


      point f (47.6, 18.3, 34.1), and


      point d (72.0, 0.0, 28.0),


      or on these line segments;

    • the line segment ac is represented by coordinates (0.0181y2−2.2288y+71.096, y, −0.0181y2+1.2288y+28.904);

    • the line segment fd is represented by coordinates (0.02y2−1.7y+72, y, −0.02y2+0.7y+28); and

    • the line segments cf and da are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to R410A, a GWP of 125 or less, and a lower flammability (Class 2L) according to the ASHRAE standard.

    • The refrigerant D according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ab, be, ed, and da that connect the following 4 points:


      point a (71.1, 0.0, 28.9),


      point b (42.6, 14.5, 42.9),


      point e (51.4, 14.6, 34.0), and


      point d (72.0, 0.0, 28.0),


      or on these line segments;

    • the line segment ab is represented by coordinates (0.0181y2−2.2288y+71.096, y, −0.0181y2+1.2288y+28.904);

    • the line segment ed is represented by coordinates (0.02y2−1.7y+72, y, −0.02y2+0.7y+28); and

    • the line segments be and da are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 85% or more relative to R410A, a GWP of 100 or less, and a lower flammability (Class 2L) according to the ASHRAE standard.

    • The refrigerant D according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments gi, ij, and jg that connect the following 3 points:


      point g (77.5, 6.9, 15.6),


      point i (55.1, 18.3, 26.6), and


      point j (77.5. 18.4, 4.1),


      or on these line segments;

    • the line segment gi is represented by coordinates (0.02y2−2.4583y+93.396, y, −0.02y2+1.4583y+6.604); and

    • the line segments ij and jg are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 95% or more relative to R410A and a GWP of 100 or less, undergoes fewer or no changes such as polymerization or decomposition, and also has excellent stability.

    • The refrigerant D according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments gh, hk, and kg that connect the following 3 points:


      point g (77.5, 6.9, 15.6),


      point h (61.8, 14.6, 23.6), and


      point k (77.5, 14.6, 7.9),


      or on these line segments;

    • the line segment gh is represented by coordinates (0.02y2−2.4583y+93.396, y, −0.02y2+1.4583y+6.604); and

    • the line segments hk and kg are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a refrigerating capacity ratio of 95% or more relative to R410A and a GWP of 100 or less, undergoes fewer or no changes such as polymerization or decomposition, and also has excellent stability.

    • The refrigerant D according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E), R32, and R1234yf, as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E), R32, and R1234yf in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and still more preferably 99.9 mass % or more based on the entire refrigerant.

    • Such additional refrigerants are not limited, and can be selected from a wide range of refrigerants. The mixed refrigerant may comprise a single additional refrigerant, or two or more additional refrigerants.





(Examples of Refrigerant D)





    • The present disclosure is described in more detail below with reference to Examples of refrigerant D. However, the refrigerant D is not limited to the Examples.

    • The composition of each mixed refrigerant of HFO-1132(E), R32, and R1234yf was defined as WCF. A leak simulation was performed using the NIST Standard Reference Database REFLEAK Version 4.0 under the conditions of Equipment, Storage, Shipping, Leak, and Recharge according to the ASHRAE Standard 34-2013. The most flammable fraction was defined as WCFF.

    • A burning velocity test was performed using the apparatus shown in FIG. 1 in the following manner. First, the mixed refrigerants used had a purity of 99.5% or more, and were degassed by repeating a cycle of freezing, pumping, and thawing until no traces of air were observed on the vacuum gauge. The burning velocity was measured by the closed method. The initial temperature was ambient temperature. Ignition was performed by generating an electric spark between the electrodes in the center of a sample cell. The duration of the discharge was 1.0 to 9.9 ms, and the ignition energy was typically about 0.1 to 1.0 J. The spread of the flame was visualized using schlieren photographs. A cylindrical container (inner diameter: 155 mm, length: 198 mm) equipped with two light transmission acrylic windows was used as the sample cell, and a xenon lamp was used as the light source. Schlieren images of the flame were recorded by a high-speed digital video camera at a frame rate of 600 fps and stored on a PC. Tables 113 to 115 show the results.




















TABLE 113







Comparative

Example

Example

Example




Example 13
Example
12
Example
14
Example
16


Item
Unit
I
11
J
13
K
15
L
























WCF
HFO-1132(E)
Mass %
72
57.2
48.5
41.2
35.6
32
28.9



R32
Mass %
0
10
18.3
27.6
36.8
44.2
51.7



R1234yf
Mass %
28
32.8
33.2
31.2
27.6
23.8
19.4















Burning Velocity (WCF)
cm/s
10
10
10
10
10
10
10























TABLE 114







Comparative

Example

Example





Example 14
Example
19
Example
21
Example


Item
Unit
M
18
W
20
N
22























WCF
HFO-1132(E)
Mass %
52.6
39.2
32.4
29.3
27.7
24.6



R32
Mass %
0.0
5.0
10.0
14.5
18.2
27.6



R1234yf
Mass %
47.4
55.8
57.6
56.2
54.1
47.8













Leak condition that results in WCFF
Storage,
Storage,
Storage,
Storage,
Storage,
Storage,



Shipping, −40°
Shipping, −40°
Shipping, −40°
Shipping, −40°
Shipping, −40°
Shipping, −40°



C., 0%
C., 0%
C., 0%
C., 0%
C., 0%
C., 0%



release, on
release, on
release, on
release, on
release, on
release, on



the gas
the gas
the gas
the gas
the gas
the gas



phase side
phase side
phase side
phase side
phase side
phase side















WCF
HFO-1132(E)
Mass %
72.0
57.8
48.7
43.6
40.6
34.9



R32
Mass %
0.0
9.5
17.9
24.2
28.7
38.1



R1234yf
Mass %
28.0
32.7
33.4
32.2
30.7
27.0














Burning Velocity (WCF)
cm/s
8 or less
8 or less
8 or less
8 or less
8 or less
8 or less


Burning Velocity (WCFF)
cm/s
10
10
10
10
10
10




















TABLE 115







Example

Example




23
Example
25


Item
Unit
O
24
P




















WCF
HFO-1132(E)
Mass %
22.6
21.2
20.5



HFO-1123
Mass %
36.8
44.2
51.7



R1234yf
Mass %
40.6
34.6
27.8










Leak condition that results in WCFF
Storage,
Storage,
Storage,



Shipping,
Shipping,
Shipping,



−40° C., 0%
−40° C., 0%
−40° C., 0%



release, on
release, on
release, on



the gas
the gas
the gas



phase side
phase side
phase side












WCFF
HFO-1132(E)
Mass %
31.4
29.2
27.1



HFO-1123
Mass %
45.7
51.1
56.4



R1234yf
Mass %
23.0
19.7
16.5











Burning Velocity (WCF)
cm/s
8 or less
8 or less
8 or less


Burning Velocity (WCFF)
cm/s
10  
10  
10  











    • The results indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in the ternary composition diagram shown in FIG. 14 in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are on the line segment that connects point I, point J, point K, and point L, or below these line segments, the refrigerant has a WCF lower flammability.

    • The results also indicate that when coordinates (x,y,z) in the ternary composition diagram shown in FIG. 14 are on the line segments that connect point M, point M′, point W, point J, point N, and point P, or below these line segments, the refrigerant has an ASHRAE lower flammability.

    • Mixed refrigerants were prepared by mixing HFO-1132(E), R32, and R1234yf in amounts (mass %) shown in Tables 116 to 144 based on the sum of HFO-1132(E), R32, and R1234yf. The coefficient of performance (COP) ratio and the refrigerating capacity ratio relative to R410 of the mixed refrigerants shown in Tables 116 to 144 were determined. The conditions for calculation were as described below.

    • Evaporating temperature: 5° C.

    • Condensation temperature: 45° C.

    • Degree of superheating: 5 K

    • Degree of subcooling: 5 K

    • Compressor efficiency: 70%

    • Tables 116 to 144 show these values together with the GWP of each mixed refrigerant.




















TABLE 116








Comparative
Comparative
Comparative
Comparative
Comparative
Comparative




Comparative
Example 2
Example 3
Example 4
Example 5
Example 6
Example 7


Item
Unit
Example 1
A
B
A′
B′
A″
B″























HFO-1132(E)
Mass %
R410A
81.6
0.0
63.1
0.0
48.2
0.0


R32
Mass %

18.4
18.1
36.9
36.7
51.8
51.5


R1234yf
Mass %

0.0
81.9
0.0
63.3
0.0
48.5


GWP

2088 
125
125
250
250
350
350


COP Ratio
% (relative
100
98.7
103.6
98.7
102.3
99.2
102.2



to R410A)


Refrigerating
% (relative
100
105.3
62.5
109.9
77.5
112.1
87.3


Capacity Ratio
to R410A)
























TABLE 117







Comparative

Comparative

Example

Example




Example 8
Comparative
Example 10
Example
2
Example
4


Item
Unit
C
Example 9
C′
1
R
3
T























HFO-1132(E)
Mass %
85.5
66.1
52.1
37.8
25.5
16.6
8.6


R32
Mass %
0.0
10.0
18.2
27.6
36.8
44.2
51.6


R1234yf
Mass %
14.5
23.9
29.7
34.6
37.7
39.2
39.8


GWP

1
69
125
188
250
300
350


COP Ratio
% (relative
99.8
99.3
99.3
99.6
100.2
100.8
101.4



to R410A)


Refrigerating
% (relative
92.5
92.5
92.5
92.5
92.5
92.5
92.5


Capacity Ratio
to R410A)

























TABLE 118







Comparative

Example

Example
Comparative

Example




Example 11
Example
6
Example
8
Example 12
Example
10


Item
Unit
E
5
N
7
U
G
9
V
























HFO-1132(E)
Mass %
58.3
40.5
27.7
14.9
3.9
39.6
22.8
11.0


R32
Mass %
0.0
10.0
18.2
27.6
36.7
0.0
10.0
18.1


R1234yf
Mass %
41.7
49.5
54.1
57.5
59.4
60.4
67.2
70.9


GWP

2
70
125
189
250
3
70
125


COP Ratio
% (relative
100.3
100.3
100.7
101.2
101.9
101.4
101.8
102.3



to R410A)


Refrigerating
% (relative
80.0
80.0
80.0
80.0
80.0
70.0
70.0
70.0


Capacity Ratio
to R410A)

























TABLE 119







Comparative

Example

Example

Example
Example




Example 13
Example
12
Example
14
Example
16
17


Item
Unit
I
11
J
13
K
15
L
Q
























HFO-1132(E)
Mass %
72.0
57.2
48.5
41.2
35.6
32.0
28.9
44.6


R32
Mass %
0.0
10.0
18.3
27.6
36.8
44.2
51.7
23.0


R1234yf
Mass %
28.0
32.8
33.2
31.2
27.6
23.8
19.4
32.4


GWP

2
69
125
188
250
300
350
157


COP Ratio
% (relative
99.9
99.5
99.4
99.5
99.6
99.8
100.1
99.4



to R410A)


Refrigerating
% (relative
86.6
88.4
90.9
94.2
97.7
100.5
103.3
92.5


Capacity Ratio
to R410A)























TABLE 120







Comparative

Example

Example





Example 14
Example
19
Example
21
Example


Item
Unit
M
18
W
20
N
22






















HFO-1132(E)
Mass %
52.6
39.2
32.4
29.3
27.7
24.5


R32
Mass %
0.0
5.0
10.0
14.5
18.2
27.6


R1234yf
Mass %
47.4
55.8
57.6
56.2
54.1
47.9


GWP

2
36
70
100
125
188


COP Ratio
% (relative
100.5
100.9
100.9
100.8
100.7
100.4



to R410A)


Refrigerating
% (relative
77.1
74.8
75.6
77.8
80.0
85.5


Capacity Ratio
to R410A)





















TABLE 121







Example

Example
Example




23
Example
25
26


Item
Unit
O
24
P
S




















HFO-1132(E)
Mass %
22.6
21.2
20.5
21.9


R32
Mass %
36.8
44.2
51.7
39.7


R1234yf
Mass %
40.6
34.6
27.8
38.4


GWP

250
300
350
270


COP Ratio
% (relative
100.4
100.5
100.6
100.4



to R410A)


Refrigerating
% (relative
91.0
95.0
99.1
92.5


Capacity Ratio
to R410A)

























TABLE 122







Comparative
Comparative
Comparative
Comparative
Example
Example
Comparative
Comparative


Item
Unit
Example 15
Example 16
Example 17
Example 18
27
28
Example 19
Example 20
























HFO-1132(E)
Mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0


R32
Mass %
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0


R1234yf
Mass %
85.0
75.0
65.0
55.0
45.0
35.0
25.0
15.0


GWP

37
37
37
36
36
36
35
35


COP Ratio
% (relative
103.4
102.6
101.6
100.8
100.2
99.8
99.6
99.4



to R410A)


Refrigerating
% (relative
56.4
63.3
69.5
75.2
80.5
85.4
90.1
94.4


Capacity Ratio
to R410A)

























TABLE 123







Comparative
Comparative
Example
Comparative
Example
Comparative
Comparative
Comparative


Item
Unit
Example 21
Example 22
29
Example 23
30
Example 24
Example 25
Example 26
























HFO-1132(E)
Mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0


R32
Mass %
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0


R1234yf
Mass %
80.0
70.0
60.0
50.0
40.0
30.0
20.0
10.0


GWP

71
71
70
70
70
69
69
69


COP Ratio
% (relative
103.1
102.1
101.1
100.4
99.8
99.5
99.2
99.1



to R410A)


Refrigerating
% (relative
61.8
68.3
74.3
79.7
84.9
89.7
94.2
98.4


Capacity Ratio
to R410A)

























TABLE 124







Comparative
Example
Comparative
Example
Example
Comparative
Comparative
Comparative


Item
Unit
Example 27
31
Example 28
32
33
Example 29
Example 30
Example 31
























HFO-1132(E)
Mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0


R32
Mass %
15.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0


R1234yf
Mass %
75.0
65.0
55.0
45.0
35.0
25.0
15.0
5.0


GWP

104
104
104
103
103
103
103
102


COP Ratio
% (relative
102.7
101.6
100.7
100.0
99.5
99.2
99.0
98.9



to R410A)


Refrigerating
% (relative
66.6
72.9
78.6
84.0
89.0
93.7
98.1
102.2


Capacity Ratio
to R410A)

























TABLE 125







Comparative
Comparative
Comparative
Comparative
Comparative
Comparative
Comparative
Comparative


Item
Unit
Example 32
Example 33
Example 34
Example 35
Example 36
Example 37
Example 38
Example 39
























HFO-1132(E)
Mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0
10.0


R32
Mass %
20.0
20.0
20.0
20.0
20.0
20.0
20.0
25.0


R1234yf
Mass %
70.0
60.0
50.0
40.0
30.0
20.0
10.0
65.0


GWP

138
138
137
137
137
136
136
171


COP Ratio
% (relative
102.3
101.2
100.4
99.7
99.3
99.0
98.8
101.9



to R410A)


Refrigerating
% (relative
71.0
77.1
82.7
88.0
92.9
97.5
101.7
75.0


Capacity Ratio
to R410A)

























TABLE 126







Example
Comparative
Comparative
Comparative
Comparative
Comparative
Comparative
Example


Item
Unit
34
Example 40
Example 41
Example 42
Example 43
Example 44
Example 45
35
























HFO-1132(E)
Mass %
20.0
30.0
40.0
50.0
60.0
70.0
10.0
20.0


R32
Mass %
25.0
25.0
25.0
25.0
25.0
25.0
30.0
30.0


R1234yf
Mass %
55.0
45.0
35.0
25.0
15.0
5.0
60.0
50.0


GWP

171
171
171
170
170
170
205
205


COP Ratio
% (relative
100.9
100.1
99.6
99.2
98.9
98.7
101.6
100.7



to R410A)


Refrigerating
% (relative
81.0
86.6
91.7
96.5
101.0
105.2
78.9
84.8


Capacity Ratio
to R410A)

























TABLE 127







Comparative
Comparative
Comparative
Comparative
Example
Example
Example
Comparative


Item
Unit
Example 46
Example 47
Example 48
Example 49
36
37
38
Example 50
























HFO-1132(E)
Mass %
30.0
40.0
50.0
60.0
10.0
20.0
30.0
40.0


R32
Mass %
30.0
30.0
30.0
30.0
35.0
35.0
35.0
35.0


R1234yf
Mass %
40.0
30.0
20.0
10.0
55.0
45.0
35.0
25.0


GWP

204
204
204
204
239
238
238
238


COP Ratio
% (relative
100.0
99.5
99.1
98.8
101.4
100.6
99.9
99.4



to R410A)


Refrigerating
% (relative
90.2
95.3
100.0
104.4
82.5
88.3
93.7
98.6


Capacity Ratio
to R410A)

























TABLE 128







Comparative
Comparative
Comparative
Comparative
Example
Comparative
Comparative
Comparative


Item
Unit
Example 51
Example 52
Example 53
Example 54
39
Example 55
Example 56
Example 57
























HFO-1132(E)
Mass %
50.0
60.0
10.0
20.0
30.0
40.0
50.0
10.0


R32
Mass %
35.0
35.0
40.0
40.0
40.0
40.0
40.0
45.0


R1234yf
Mass %
15.0
5.0
50.0
40.0
30.0
20.0
10.0
45.0


GWP

237
237
272
272
272
271
271
306


COP Ratio
% (relative
99.0
98.8
101.3
100.6
99.9
99.4
99.0
101.3



to R410A)


Refrigerating
% (relative
103.2
107.5
86.0
91.7
96.9
101.8
106.3
89.3


Capacity Ratio
to R410A)

























TABLE 129







Example
Example
Comparative
Comparative
Comparative
Example
Comparative
Comparative


Item
Unit
40
41
Example 58
Example 59
Example 60
42
Example 61
Example 62
























HFO-1132(E)
Mass %
20.0
30.0
40.0
50.0
10.0
20.0
30.0
40.0


R32
Mass %
45.0
45.0
45.0
45.0
50.0
50.0
50.0
50.0


R1234yf
Mass %
35.0
25.0
15.0
5.0
40.0
30.0
20.0
10.0


GWP

305
305
305
304
339
339
339
338


COP Ratio
% (relative
100.6
100.0
99.5
99.1
101.3
100.6
100.0
99.5



to R410A)


Refrigerating
% (relative
94.9
100.0
104.7
109.2
92.4
97.8
102.9
107.5


Capacity Ratio
to R410A)

























TABLE 130







Comparative
Comparative
Comparative
Comparative
Example
Example
Example
Example


Item
Unit
Example 63
Example 64
Example 65
Example 66
43
44
45
46
























HFO-1132(E)
Mass %
10.0
20.0
30.0
40.0
56.0
59.0
62.0
65.0


R32
Mass %
55.0
55.0
55.0
55.0
3.0
3.0
3.0
3.0


R1234yf
Mass %
35.0
25.0
15.0
5.0
41.0
38.0
35.0
32.0


GWP

373
372
372
372
22
22
22
22


COP Ratio
% (relative
101.4
100.7
100.1
99.6
100.1
100.0
99.9
99.8



to R410A)


Refrigerating
% (relative
95.3
100.6
105.6
110.2
81.7
83.2
84.6
86.0


Capacity Ratio
to R410A)

























TABLE 131







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
47
48
49
50
51
52
53
54
























HFO-1132(E)
Mass %
49.0
52.0
55.0
58.0
61.0
43.0
46.0
49.0


R32
Mass %
6.0
6.0
6.0
6.0
6.0
9.0
9.0
9.0


R1234yf
Mass %
45.0
42.0
39.0
36.0
33.0
48.0
45.0
42.0


GWP

43
43
43
43
42
63
63
63


COP Ratio
% (relative
100.2
100.0
99.9
99.8
99.7
100.3
100.1
99.9



to R410A)


Refrigerating
% (relative
80.9
82.4
83.9
85.4
86.8
80.4
82.0
83.5


Capacity Ratio
to R410A)

























TABLE 132







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
55
56
57
58
59
60
61
62
























HFO-1132(E)
Mass %
52.0
55.0
58.0
38.0
41.0
44.0
47.0
50.0


R32
Mass %
9.0
9.0
9.0
12.0
12.0
12.0
12.0
12.0


R1234yf
Mass %
39.0
36.0
33.0
50.0
47.0
44.0
41.0
38.0


GWP

63
63
63
83
83
83
83
83


COP Ratio
% (relative
99.8
99.7
99.6
100.3
100.1
100.0
99.8
99.7



to R410A)


Refrigerating
% (relative
85.0
86.5
87.9
80.4
82.0
83.5
85.1
86.6


Capacity Ratio
to R410A)

























TABLE 133







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
63
64
65
66
67
68
69
70
























HFO-1132(E)
Mass %
53.0
33.0
36.0
39.0
42.0
45.0
48.0
51.0


R32
Mass %
12.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0


R1234yf
Mass %
35.0
52.0
49.0
46.0
43.0
40.0
37.0
34.0


GWP

83
104
104
103
103
103
103
103


COP Ratio
% (relative
99.6
100.5
100.3
100.1
99.9
99.7
99.6
99.5



to R410A)


Refrigerating
% (relative
88.0
80.3
81.9
83.5
85.0
86.5
88.0
89.5


Capacity Ratio
to R410A)

























TABLE 134







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
71
72
73
74
75
76
77
78
























HFO-1132(E)
Mass %
29.0
32.0
35.0
38.0
41.0
44.0
47.0
36.0


R32
Mass %
18.0
18.0
18.0
18.0
18.0
18.0
18.0
3.0


R1234yf
Mass %
53.0
50.0
47.0
44.0
41.0
38.0
35.0
61.0


GWP

124
124
124
124
124
123
123
23


COP Ratio
% (relative
100.6
100.3
100.1
99.9
99.8
99.6
99.5
101.3



to R410A)


Refrigerating
% (relative
80.6
82.2
83.8
85.4
86.9
88.4
89.9
71.0


Capacity Ratio
to R410A)

























TABLE 135







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
79
80
81
82
83
84
85
86
























HFO-1132(E)
Mass %
39.0
42.0
30.0
33.0
36.0
26.0
29.0
32.0


R32
Mass %
3.0
3.0
6.0
6.0
6.0
9.0
9.0
9.0


R1234yf
Mass %
58.0
55.0
64.0
61.0
58.0
65.0
62.0
59.0


GWP

23
23
43
43
43
64
64
63


COP Ratio
% (relative
101.1
100.9
101.5
101.3
101.0
101.6
101.3
101.1



to R410A)


Refrigerating
% (relative
72.7
74.4
70.5
72.2
73.9
71.0
72.8
74.5


Capacity Ratio
to R410A)

























TABLE 136







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
87
88
89
90
91
92
93
94
























HFO-1132(E)
Mass %
21.0
24.0
27.0
30.0
16.0
19.0
22.0
25.0


R32
Mass %
12.0
12.0
12.0
12.0
15.0
15.0
15.0
15.0


R1234yf
Mass %
67.0
64.0
61.0
58.0
69.0
66.0
63.0
60.0


GWP

84
84
84
84
104
104
104
104


COP Ratio
% (relative
101.8
101.5
101.2
101.0
102.1
101.8
101.4
101.2



to R410A)


Refrigerating
% (relative
70.8
72.6
74.3
76.0
70.4
72.3
74.0
75.8


Capacity Ratio
to R410A)

























TABLE 137







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
95
96
97
98
99
100
101
102
























HFO-1132(E)
Mass %
28.0
12.0
15.0
18.0
21.0
24.0
27.0
25.0


R32
Mass %
15.0
18.0
18.0
18.0
18.0
18.0
18.0
21.0


R1234yf
Mass %
57.0
70.0
67.0
64.0
61.0
58.0
55.0
54.0


GWP

104
124
124
124
124
124
124
144


COP Ratio
% (relative
100.9
102.2
101.9
101.6
101.3
101.0
100.7
100.7



to R410A)


Refrigerating
% (relative
77.5
70.5
72.4
74.2
76.0
77.7
79.4
80.7


Capacity Ratio
to R410A)

























TABLE 138







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
103
104
105
106
107
108
109
110
























HFO-1132(E)
Mass %
21.0
24.0
17.0
20.0
23.0
13.0
16.0
19.0


R32
Mass %
24.0
24.0
27.0
27.0
27.0
30.0
30.0
30.0


R1234yf
Mass %
55.0
52.0
56.0
53.0
50.0
57.0
54.0
51.0


GWP

164
164
185
185
184
205
205
205


COP Ratio
% (relative
100.9
100.6
101.1
100.8
100.6
101.3
101.0
100.8



to R410A)


Refrigerating
% (relative
80.8
82.5
80.8
82.5
84.2
80.7
82.5
84.2


Capacity Ratio
to R410A)

























TABLE 139







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
111
112
113
114
115
116
117
118
























HFO-1132(E)
Mass %
22.0
9.0
12.0
15.0
18.0
21.0
8.0
12.0


R32
Mass %
30.0
33.0
33.0
33.0
33.0
33.0
36.0
36.0


R1234yf
Mass %
48.0
58.0
55.0
52.0
49.0
46.0
56.0
52.0


GWP

205
225
225
225
225
225
245
245


COP Ratio
% (relative
100.5
101.6
101.3
101.0
100.8
100.5
101.6
101.2



to R410A)


Refrigerating
% (relative
85.9
80.5
82.3
84.1
85.8
87.5
82.0
84.4


Capacity Ratio
to R410A)

























TABLE 140







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
119
120
121
122
123
124
125
126
























HFO-1132(E)
Mass %
15.0
18.0
21.0
42.0
39.0
34.0
37.0
30.0


R32
Mass %
36.0
36.0
36.0
25.0
28.0
31.0
31.0
34.0


R1234yf
Mass %
49.0
46.0
43.0
33.0
33.0
35.0
32.0
36.0


GWP

245
245
245
170
191
211
211
231


COP Ratio
% (relative
101.0
100.7
100.5
99.5
99.5
99.8
99.6
99.9



to R410A)


Refrigerating
% (relative
86.2
87.9
89.6
92.7
93.4
93.0
94.5
93.0


Capacity Ratio
to R410A)

























TABLE 141







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
127
128
129
130
131
132
133
134
























HFO-1132(E)
Mass %
33.0
36.0
24.0
27.0
30.0
33.0
23.0
26.0


R32
Mass %
34.0
34.0
37.0
37.0
37.0
37.0
40.0
40.0


R1234yf
Mass %
33.0
30.0
39.0
36.0
33.0
30.0
37.0
34.0


GWP

231
231
252
251
251
251
272
272


COP Ratio
% (relative
99.8
99.6
100.3
100.1
99.9
99.8
100.4
100.2



to R410A)


Refrigerating
% (relative
94.5
96.0
91.9
93.4
95.0
96.5
93.3
94.9


Capacity Ratio
to R410A)

























TABLE 142







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
135
136
137
138
139
140
141
142
























HFO-1132(E)
Mass %
29.0
32.0
19.0
22.0
25.0
28.0
31.0
18.0


R32
Mass %
40.0
40.0
43.0
43.0
43.0
43.0
43.0
46.0


R1234yf
Mass %
31.0
28.0
38.0
35.0
32.0
29.0
26.0
36.0


GWP

272
271
292
292
292
292
292
312


COP Ratio
% (relative
100.0
99.8
100.6
100.4
100.2
100.1
99.9
100.7



to R410A)


Refrigerating
% (relative
96.4
97.9
93.1
94.7
96.2
97.8
99.3
94.4


Capacity Ratio
to R410A)

























TABLE 143







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
143
144
145
146
147
148
149
150
























HFO-1132(E)
Mass %
21.0
23.0
26.0
29.0
13.0
16.0
19.0
22.0


R32
Mass %
46.0
46.0
46.0
46.0
49.0
49.0
49.0
49.0


R1234yf
Mass %
33.0
31.0
28.0
25.0
38.0
35.0
32.0
29.0


GWP

312
312
312
312
332
332
332
332


COP Ratio
% (relative
100.5
100.4
100.2
100.0
101.1
100.9
100.7
100.5



to R410A)


Refrigerating
% (relative
96.0
97.0
98.6
100.1
93.5
95.1
96.7
98.3


Capacity Ratio
to R410A)





















TABLE 144









Example
Example



Item
Unit
151
152





















HFO-1132(E)
Mass %
25.0
28.0



R32
Mass %
49.0
49.0



R1234yf
Mass %
26.0
23.0



GWP

332
332



COP Ratio
% (relative
100.3
100.1




to R410A)



Refrigerating
% (relative
99.8
101.3



Capacity Ratio
to R410A)












    • The results also indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments IJ, JN, NE, and EI that connect the following 4 points:


      point I (72.0, 0.0, 28.0),


      point J (48.5, 18.3, 33.2),


      point N (27.7, 18.2, 54.1), and


      point E (58.3, 0.0, 41.7),


      or on these line segments (excluding the points on the line segment EI),

    • the line segment IJ is represented by coordinates (0.0236y2−1.7616y+72.0, y, −0.0236y2+0.7616y+28.0),

    • the line segment NE is represented by coordinates (0.012y2−1.9003y+58.3, y, −0.012y2+0.9003y+41.7), and

    • the line segments JN and EI are straight lines, the refrigerant D has a refrigerating capacity ratio of 80% or more relative to R410A, a GWP of 125 or less, and a WCF lower flammability.

    • The results also indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments MM′, M′N, NV, VG, and GM that connect the following 5 points:


      point M (52.6, 0.0, 47.4),


      point M′ (39.2, 5.0, 55.8),


      point N (27.7, 18.2, 54.1),


      point V (11.0, 18.1, 70.9), and


      point G (39.6, 0.0, 60.4),


      or on these line segments (excluding the points on the line segment GM),

    • the line segment MM′ is represented by coordinates (0.132y2−3.34y+52.6, y, −0.132y2+2.34y+47.4),

    • the line segment M′N is represented by coordinates (0.0596y2−2.2541y+48.98, y, −0.0596y2+1.2541y+51.02),

    • the line segment VG is represented by coordinates (0.0123y2−1.8033y+39.6, y, −0.0123y2+0.8033y+60.4), and

    • the line segments NV and GM are straight lines, the refrigerant D according to the present disclosure has a refrigerating capacity ratio of 70% or more relative to R410A, a GWP of 125 or less, and an ASHRAE lower flammability.

    • The results also indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments ON, NU, and UO that connect the following 3 points:


      point O (22.6, 36.8, 40.6),


      point N (27.7, 18.2, 54.1), and


      point U (3.9, 36.7, 59.4),


      or on these line segments,

    • the line segment ON is represented by coordinates (0.0072y2−0.6701y+37.512, y, −0.0072y2−0.3299y+62.488),

    • the line segment NU is represented by coordinates (0.0083y2−1.7403y+56.635, y, −0.0083y2+0.7403y+43.365), and

    • the line segment UO is a straight line, the refrigerant D according to the present disclosure has a refrigerating capacity ratio of 80% or more relative to R410A, a GWP of 250 or less, and an ASHRAE lower flammability.

    • The results also indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments QR, RT, TL, LK, and KQ that connect the following 5 points:


      point Q (44.6, 23.0, 32.4),


      point R (25.5, 36.8, 37.7),


      point T (8.6, 51.6, 39.8),


      point L (28.9, 51.7, 19.4), and


      point K (35.6, 36.8, 27.6),


      or on these line segments,

    • the line segment QR is represented by coordinates (0.0099y2−1.975y+84.765, y, −0.0099y2+0.975y+15.235),

    • the line segment RT is represented by coordinates (0.0082y2−1.8683y+83.126, y, −0.0082y2+0.8683y+16.874),

    • the line segment LK is represented by coordinates (0.0049y2−0.8842y+61.488, y, −0.0049y2−0.1158y+38.512),

    • the line segment KQ is represented by coordinates (0.0095y2−1.2222y+67.676, y, −0.0095y2+0.2222y+32.324), and

    • the line segment TL is a straight line, the refrigerant D according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to R410A, a GWP of 350 or less, and a WCF lower flammability.





The results further indicate that under the condition that the mass % of HFO-1132(E), R32, and R1234yf based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), R32, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:


point P (20.5, 51.7, 27.8),


point S (21.9, 39.7, 38.4), and


point T (8.6, 51.6, 39.8),


or on these line segments,

    • the line segment PS is represented by coordinates (0.0064y2−0.7103y+40.1, y, −0.0064y2−0.2897y+59.9),
    • the line segment ST is represented by coordinates (0.0082y2−1.8683y+83.126, y, −0.0082y2+0.8683y+16.874), and
    • the line segment TP is a straight line, the refrigerant D according to the present disclosure has a refrigerating capacity ratio of 92.5% or more relative to R410A, a GWP of 350 or less, and an ASHRAE lower flammability.


(5-5) Refrigerant E





    • The refrigerant E according to the present disclosure is a mixed refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32).

    • The refrigerant E according to the present disclosure has various properties that are desirable as an R410A-alternative refrigerant, i.e., a coefficient of performance equivalent to that of R410A and a sufficiently low GWP.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments IK, KB′, B′H, HR, RG, and GI that connect the following 6 points:


      point I (72.0, 28.0, 0.0),


      point K (48.4, 33.2, 18.4),


      point B′ (0.0, 81.6, 18.4),


      point H (0.0, 84.2, 15.8),


      point R (23.1, 67.4, 9.5), and


      point G (38.5, 61.5, 0.0),


      or on these line segments (excluding the points on the line segments B′H and GI);

    • the line segment IK is represented by coordinates (0.025z2−1.7429z+72.00, −0.025z2+0.7429z+28.0, z),

    • the line segment HR is represented by coordinates (−0.3123z2+4.234z+11.06, 0.3123z2−5.234z+88.94, z),

    • the line segment RG is represented by coordinates (−0.0491z2−1.1544z+38.5, 0.0491z2+0.1544z+61.5, z), and

    • the line segments KB′ and GI are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has WCF lower flammability, a COP ratio of 93% or more relative to that of R410A, and a GWP of 125 or less.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments IJ, JR, RG, and GI that connect the following 4 points:


      point I (72.0, 28.0, 0.0),


      point J (57.7, 32.8, 9.5),


      point R (23.1, 67.4, 9.5), and


      point G (38.5, 61.5, 0.0),


      or on these line segments (excluding the points on the line segment GI);

    • the line segment IJ is represented by coordinates (0.025z2−1.7429z+72.0, −0.025z2+0.7429z+28.0, z),

    • the line segment RG is represented by coordinates (−0.0491z2−1.1544z+38.5, 0.0491z2+0.1544z+61.5, z), and

    • the line segments JR and GI are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has WCF lower flammability, a COP ratio of 93% or more relative to that of R410A, and a GWP of 125 or less.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MP, PB′, B′H, HR, RG, and GM that connect the following 6 points:


      point M (47.1, 52.9, 0.0),


      point P (31.8, 49.8, 18.4),


      point B′ (0.0, 81.6, 18.4),


      point H (0.0, 84.2, 15.8),


      point R (23.1, 67.4, 9.5), and


      point G (38.5, 61.5, 0.0),


      or on these line segments (excluding the points on the line segments B′H and GM);

    • the line segment MP is represented by coordinates (0.0083z2−0.984z+47.1, −0.0083z2−0.016z+52.9, z),

    • the line segment HR is represented by coordinates (−0.3123z2+4.234z+11.06, 0.3123z2−5.234z+88.94, z),

    • the line segment RG is represented by coordinates (−0.0491z2−1.1544z+38.5, 0.0491z2+0.1544z+61.5, z), and

    • the line segments PB′ and GM are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has ASHRAE lower flammability, a COP ratio of 93% or more relative to that of R410A, and a GWP of 125 or less.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments MN, NR, RG, and GM that connect the following 4 points:


      point M (47.1, 52.9, 0.0),


      point N (38.5, 52.1, 9.5),


      point R (23.1, 67.4, 9.5), and


      point G (38.5, 61.5, 0.0),


      or on these line segments (excluding the points on the line segment GM);

    • the line segment MN is represented by coordinates (0.0083z2−0.984z+47.1, −0.0083z2−0.016z+52.9, z),

    • the line segment RG is represented by coordinates (−0.0491z2−1.1544z+38.5, 0.0491z2+0.1544z+61.5, z),

    • the line segments NR and GM are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has ASHRAE lower flammability, a COP ratio of 93% or more relative to that of R410A, and a GWP of 65 or less.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments PS, ST, and TP that connect the following 3 points:


      point P (31.8, 49.8, 18.4),


      point S (25.4, 56.2, 18.4), and


      point T (34.8, 51.0, 14.2),


      or on these line segments;

    • the line segment ST is represented by coordinates (−0.0982z2+0.9622z+40.931, 0.0982z2−1.9622z+59.069, z),

    • the line segment TP is represented by coordinates (0.0083z2−0.984z+47.1, −0.0083z2−0.016z+52.9, z), and

    • the line segment PS is a straight line. When the requirements above are satisfied, the refrigerant according to the present disclosure has ASHRAE lower flammability, a COP ratio of 94.5% or more relative to that of R410A, and a GWP of 125 or less.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments QB″, B″D, DU, and UQ that connect the following 4 points:


      point Q (28.6, 34.4, 37.0),


      point B″ (0.0, 63.0, 37.0),


      point D (0.0, 67.0, 33.0), and


      point U (28.7, 41.2, 30.1),


      or on these line segments (excluding the points on the line segment B″D);

    • the line segment DU is represented by coordinates (−3.4962z2+210.71z−3146.1, 3.4962z2−211.71z+3246.1, z),

    • the line segment UQ is represented by coordinates (0.0135z2−0.9181z+44.133, −0.0135z2−0.0819z+55.867, z), and

    • the line segments QB″ and B″D are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has ASHRAE lower flammability, a COP ratio of 96% or more relative to that of R410A, and a GWP of 250 or less.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments Oc′, c′d′, d′e′, e′a′, and a′O that connect the following 5 points:


      point O (100.0, 0.0, 0.0),


      point c′ (56.7, 43.3, 0.0),


      point d′ (52.2, 38.3, 9.5),


      point e′ (41.8, 39.8, 18.4), and


      point a′ (81.6, 0.0, 18.4),


      or on the line segments c′d′, d′e′, and e′a′ (excluding the points c′ and a′);

    • the line segment c′d′ is represented by coordinates (−0.0297z2−0.1915z+56.7, 0.0297z2+1.1915z+43.3, z),

    • the line segment d′e′ is represented by coordinates (−0.0535z2+0.3229z+53.957, 0.0535z2+0.6771z+46.043, z), and

    • the line segments Oc′, e′a′, and a′O are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP ratio of 92.5% or more relative to that of R410A, and a GWP of 125 or less.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments Oc, cd, de, ea′, and a′O that connect the following 5 points:


      point O (100.0, 0.0, 0.0),


      point c (77.7, 22.3, 0.0),


      point d (76.3, 14.2, 9.5),


      point e (72.2, 9.4, 18.4), and


      point a′ (81.6, 0.0, 18.4),


      or on the line segments cd, de, and ea′ (excluding the points c and a′);

    • the line segment cde is represented by coordinates (−0.017z2+0.0148z+77.684, 0.017z2+0.9852z+22.316, z), and

    • the line segments Oc, ea′, and a′O are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP ratio of 95% or more relative to that of R410A, and a GWP of 125 or less.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments Oc′, c′d′, d′a, and aO that connect the following 5 points:


      point O (100.0, 0.0, 0.0),


      point c′ (56.7, 43.3, 0.0),


      point d′ (52.2, 38.3, 9.5), and


      point a (90.5, 0.0, 9.5),


      or on the line segments c′d′ and d′a (excluding the points c′ and a);

    • the line segment c′d′ is represented by coordinates (−0.0297z2−0.1915z+56.7, 0.0297z2+1.1915z+43.3, z), and

    • the line segments Oc′, d′a, and aO are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP ratio of 93.5% or more relative to that of R410A, and a GWP of 65 or less.

    • The refrigerant E according to the present disclosure is preferably a refrigerant wherein

    • when the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass % are within the range of a figure surrounded by line segments Oc, cd, da, and aO that connect the following 4 points:


      point O (100.0, 0.0, 0.0),


      point c (77.7, 22.3, 0.0),


      point d (76.3, 14.2, 9.5), and


      point a (90.5, 0.0, 9.5),


      or on the line segments cd and da (excluding the points c and a);

    • the line segment cd is represented by coordinates (−0.017z2+0.0148z+77.684, 0.017z2+0.9852z+22.316, z), and

    • the line segments Oc, da, and aO are straight lines. When the requirements above are satisfied, the refrigerant according to the present disclosure has a COP ratio of 95% or more relative to that of R410A, and a GWP of 65 or less.

    • The refrigerant E according to the present disclosure may further comprise other additional refrigerants in addition to HFO-1132(E), HFO-1123, and R32, as long as the above properties and effects are not impaired. In this respect, the refrigerant according to the present disclosure preferably comprises HFO-1132(E), HFO-1123, and R32 in a total amount of 99.5 mass % or more, more preferably 99.75 mass % or more, and even more preferably 99.9 mass % or more, based on the entire refrigerant.

    • Such additional refrigerants are not limited, and can be selected from a wide range of refrigerants. The mixed refrigerant may comprise a single additional refrigerant, or two or more additional refrigerants.





(Examples of Refrigerant E)





    • The present disclosure is described in more detail below with reference to Examples of refrigerant E. However, the refrigerant E is not limited to the Examples.

    • Mixed refrigerants were prepared by mixing HFO-1132(E), HFO-1123, and R32 at mass % based on their sum shown in Tables 145 and 146.

    • The composition of each mixture was defined as WCF. A leak simulation was performed using National Institute of Science and Technology (NIST) Standard Reference Data Base Refleak Version 4.0 under the conditions for equipment, storage, shipping, leak, and recharge according to the ASHRAE Standard 34-2013. The most flammable fraction was defined as WCFF.

    • For each mixed refrigerant, the burning velocity was measured according to the ANSI/ASHRAE Standard 34-2013. When the burning velocities of the WCF composition and the WCFF composition are 10 cm/s or less, the flammability of such a refrigerant is classified as Class 2L (lower flammability) in the ASHRAE flammability classification.

    • A burning velocity test was performed using the apparatus shown in FIG. 1 in the following manner. First, the mixed refrigerants used had a purity of 99.5% or more, and were degassed by repeating a cycle of freezing, pumping, and thawing until no traces of air were observed on the vacuum gauge. The burning velocity was measured by the closed method. The initial temperature was ambient temperature. Ignition was performed by generating an electric spark between the electrodes in the center of a sample cell. The duration of the discharge was 1.0 to 9.9 ms, and the ignition energy was typically about 0.1 to 1.0 J. The spread of the flame was visualized using schlieren photographs. A cylindrical container (inner diameter: 155 mm, length: 198 mm) equipped with two light transmission acrylic windows was used as the sample cell, and a xenon lamp was used as the light source. Schlieren images of the flame were recorded by a high-speed digital video camera at a frame rate of 600 fps and stored on a PC.

    • Tables 145 and 146 show the results.

















TABLE 145





Item
Unit
I
J
K
L





















WCF
HFO-1132(E)
mass %
72.0
57.7
48.4
35.5



HFO-1123
mass %
28.0
32.8
33.2
27.5



R32
mass %
0.0
9.5
18.4
37.0












Burning velocity (WCF)
cm/s
10
10
10
10























TABLE 146





Item
Unit
M
N
T
P
U
Q























WCF
HFO-1132(E)
mass %
47.1
38.5
34.8
31.8
28.7
28.6



HFO-1123
mass %
52.9
52.1
51.0
49.8
41.2
34.4



R32
mass %
0.0
9.5
14.2
18.4
30.1
37.0













Leak condition that results in WCFF
Storage,
Storage,
Storage,
Storage,
Storage,
Storage,



Shipping, −40°
Shipping, −40°
Shipping, −40°
Shipping, −40°
Shipping, −40°
Shipping, −40°



C., 92%,
C., 92%,
C., 92%,
C., 92%,
C., 92%,
C., 92%,



release, on
release, on
release, on
release, on
release, on
release, on



the liquid
the liquid
the liquid
the liquid
the liquid
the liquid



phase side
phase side
phase side
phase side
phase side
phase side















WCFF
HFO-1132(E)
mass %
72.0
58.9
51.5
44.6
31.4
27.1



HFO-1123
mass %
28.0
32.4
33.1
32.6
23.2
18.3



R32
mass %
0.0
8.7
15.4
22.8
45.4
54.6














Burning velocity (WCF)
cm/s
8 or less
8 or less
8 or less
8 or less
8 or less
8 or less


Burning velocity (WCFF)
cm/s
10
10
10
10
10
10











    • The results in Table 1 indicate that in a ternary composition diagram of a mixed refrigerant of HFO-1132(E), HFO-1123, and R32 in which their sum is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on or below line segments IK and KL that connect the following 3 points:


      point I (72.0, 28.0, 0.0),


      point K (48.4, 33.2, 18.4), and


      point L (35.5, 27.5, 37.0);


      the line segment IK is represented by coordinates


      (0.025z2−1.7429z+72.00, −0.025z2+0.7429z+28.00, z), and


      the line segment KL is represented by coordinates


      (0.0098z2−1.238z+67.852, −0.0098z2+0.238z+32.148, z),


      it can be determined that the refrigerant has WCF lower flammability.

    • For the points on the line segment IK, an approximate curve (x=0.025z2−1.7429z+72.00) was obtained from three points, i.e., I (72.0, 28.0, 0.0), J (57.7, 32.8, 9.5), and K (48.4, 33.2, 18.4) by using the least-square method to determine coordinates (x=0.025z2−1.7429z+72.00, y=100−z−x=−0.00922z2+0.2114z+32.443, z).

    • Likewise, for the points on the line segment KL, an approximate curve was determined from three points, i.e., K (48.4, 33.2, 18.4), Example 10 (41.1, 31.2, 27.7), and L (35.5, 27.5, 37.0) by using the least-square method to determine coordinates.

    • The results in Table 146 indicate that in a ternary composition diagram of a mixed refrigerant of HFO-1132(E), HFO-1123, and R32 in which their sum is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, the point (0.0, 100.0, 0.0) is on the left side, and the point (0.0, 0.0, 100.0) is on the right side, when coordinates (x,y,z) are on or below line segments MP and PQ that connect the following 3 points:


      point M (47.1, 52.9, 0.0),


      point P (31.8, 49.8, 18.4), and


      point Q (28.6, 34.4, 37.0),


      it can be determined that the refrigerant has ASHRAE lower flammability.

    • In the above, the line segment MP is represented by coordinates (0.0083z2−0.984z+47.1, −0.0083z2−0.016z+52.9, z), and the line segment PQ is represented by coordinates


      (0.0135z2−0.9181z+44.133, −0.0135z2−0.0819z+55.867, z).

    • For the points on the line segment MP, an approximate curve was obtained from three points, i.e., points M, N, and P, by using the least-square method to determine coordinates. For the points on the line segment PQ, an approximate curve was obtained from three points, i.e., points P, U, and Q, by using the least-square method to determine coordinates.

    • The GWP of compositions each comprising a mixture of R410A (R32=50%/R125=50%) was evaluated based on the values stated in the Intergovernmental Panel on Climate Change (IPCC), fourth report. The GWP of HFO-1132(E), which was not stated therein, was assumed to be 1 from HFO-1132a (GWP=1 or less) and HFO-1123 (GWP=0.3, described in WO2015/141678). The refrigerating capacity of compositions each comprising R410A and a mixture of HFO-1132(E) and HFO-1123 was determined by performing theoretical refrigeration cycle calculations for the mixed refrigerants using the National Institute of Science and Technology (NIST) and Reference Fluid Thermodynamic and Transport Properties Database (Refprop 9.0) under the following conditions.

    • The COP ratio and the refrigerating capacity (which may be referred to as “cooling capacity” or “capacity”) ratio relative to those of R410 of the mixed refrigerants were determined. The conditions for calculation were as described below.


      Evaporating temperature: 5° C.


      Condensation temperature: 45° C.


      Degree of superheating: 5K


      Degree of subcooling: 5K


      Compressor efficiency: 70%

    • Tables 147 to 166 show these values together with the GWP of each mixed refrigerant.




















TABLE 147








Comparative
Comparative
Comparative
Comparative
Comparative
Comparative




Comparative
Example 2
Example 3
Example 4
Example 5
Example 6
Example 7


Item
Unit
Example 1
A
B
A′
B′
A″
B″























HFO-1132(E)
mass %
R410A
90.5
0.0
81.6
0.0
63.0
0.0


HFO-1123
mass %

0.0
90.5
0.0
81.6
0.0
63.0


R32
mass %

9.5
9.5
18.4
18.4
37.0
37.0


GWP

2088 
65
65
125
125
250
250


COP ratio
% (relative
100
99.1
92.0
98.7
93.4
98.7
96.1



to R410A)


Refrigerating
% (relative
100
102.2
111.6
105.3
113.7
110.0
115.4


capacity ratio
to R410A)























TABLE 148







Comparative
Comparative

Example

Comparative




Example 8
Example 9
Comparative
1
Example
Example 11


Item
Unit
O
C
Example 10
U
2
D






















HFO-1132(E)
mass %
100.0
50.0
41.1
28.7
15.2
0.0


HFO-1123
mass %
0.0
31.6
34.6
41.2
52.7
67.0


R32
mass %
0.0
18.4
24.3
30.1
32.1
33.0


GWP

1
125
165
204
217
228


COP ratio
% (relative
99.7
96.0
96.0
96.0
96.0
96.0



to R410A)


Refrigerating
% (relative
98.3
109.9
111.7
113.5
114.8
115.4


capacity ratio
to R410A)






















TABLE 149







Comparative

Example
Example
Comparative




Example 12
Comparative
3
4
Example 14


Item
Unit
E
Example 13
T
S
F





















HFO-1132(E)
mass %
53.4
43.4
34.8
25.4
0.0


HFO-1123
mass %
46.6
47.1
51.0
56.2
74.1


R32
mass %
0.0
9.5
14.2
18.4
25.9


GWP

1
65
97
125
176


COP ratio
% (relative
94.5
94.5
94.5
94.5
94.5



to R410A)


Refrigerating
% (relative
105.6
109.2
110.8
112.3
114.8


capacity ratio
to R410A)






















TABLE 150







Comparative



Comparative




Example 15

Example 6

Example 16


Item
Unit
G
Example 5
R
Example 7
H





















HFO-1132(E)
mass %
38.5
31.5
23.1
16.9
0.0


HFO-1123
mass %
61.5
63.5
67.4
71.1
84.2


R32
mass %
0.0
5.0
9.5
12.0
15.8


GWP

1
35
65
82
107


COP ratio
% (relative to
93.0
93.0
93.0
93.0
93.0



R410A)


Refrigerating
% (relative to
107.0
109.1
110.9
111.9
113.2


capacity ratio
R410A)






















TABLE 151







Comparative
Example
Example

Comparative




Example 17
8
9
Comparative
Example 19


Item
Unit
I
J
K
Example 18
L





















HFO-1132(E)
mass %
72.0
57.7
48.4
41.1
35.5


HFO-1123
mass %
28.0
32.8
33.2
31.2
27.5


R32
mass %
0.0
9.5
18.4
27.7
37.0


GWP

1
65
125
188
250


COP ratio
% (relative
96.6
95.8
95.9
96.4
97.1



to R410A)


Refrigerating
% (relative
103.1
107.4
110.1
112.1
113.2


capacity ratio
to R410A)





















TABLE 152







Comparative
Example
Example
Example




Example 20
10
11
12


Item
Unit
M
N
P
Q




















HFO-1132(E)
mass %
47.1
38.5
31.8
28.6


HFO-1123
mass %
52.9
52.1
49.8
34.4


R32
mass %
0.0
9.5
18.4
37.0


GWP

1
65
125
250


COP ratio
% (relative
93.9
94.1
94.7
96.9



to R410A)


Refrigerating
% (relative
106.2
109.7
112.0
114.1


capacity ratio
to R410A)

























TABLE 153







Comparative
Comparative
Comparative
Example
Example
Example
Comparative
Comparative


Item
Unit
Example 22
Example 23
Example 24
14
15
16
Example 25
Example 26
























HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0


HFO-1123
mass %
85.0
75.0
65.0
55.0
45.0
35.0
25.0
15.0


R32
mass %
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0


GWP

35
35
35
35
35
35
35
35


COP ratio
% (relative
91.7
92.2
92.9
93.7
94.6
95.6
96.7
97.7



to R410A)


Refrigerating
% (relative
110.1
109.8
109.2
108.4
107.4
106.1
104.7
103.1


capacity ratio
to R410A)

























TABLE 154







Comparative
Comparative
Comparative
Example
Example
Example
Comparative
Comparative


Item
Unit
Example 27
Example 28
Example 29
17
18
19
Example 30
Example 31
























HFO-1132(E)
mass %
90.0
10.0
20.0
30.0
40.0
50.0
60.0
70.0


HFO-1123
mass %
5.0
80.0
70.0
60.0
50.0
40.0
30.0
20.0


R32
mass %
5.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0


GWP

35
68
68
68
68
68
68
68


COP ratio
% (relative
98.8
92.4
92.9
93.5
94.3
95.1
96.1
97.0



to R410A)


Refrigerating
% (relative
101.4
111.7
111.3
110.6
109.6
108.5
107.2
105.7


capacity ratio
to R410A)

























TABLE 155







Comparative
Example
Example
Example
Example
Example
Comparative
Comparative


Item
Unit
Example 32
20
21
22
23
24
Example 33
Example 34
























HFO-1132(E)
mass %
80.0
10.0
20.0
30.0
40.0
50.0
60.0
70.0


HFO-1123
mass %
10.0
75.0
65.0
55.0
45.0
35.0
25.0
15.0


R32
mass %
10.0
15.0
15.0
15.0
15.0
15.0
15.0
15.0


GWP

68
102
102
102
102
102
102
102


COP ratio
% (relative
98.0
93.1
93.6
94.2
94.9
95.6
96.5
97.4



to R410A)


Refrigerating
% (relative
104.1
112.9
112.4
111.6
110.6
109.4
108.1
106.6


capacity ratio
to R410A)

























TABLE 156







Comparative
Comparative
Comparative
Comparative
Comparative
Comparative
Comparative
Comparative


Item
Unit
Example 35
Example 36
Example 37
Example 38
Example 39
Example 40
Example 41
Example 42
























HFO-1132(E)
mass %
80.0
10.0
20.0
30.0
40.0
50.0
60.0
70.0


HFO-1123
mass %
5.0
70.0
60.0
50.0
40.0
30.0
20.0
10.0


R32
mass %
15.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0


GWP

102
136
136
136
136
136
136
136


COP ratio
% (relative
98.3
93.9
94.3
94.8
95.4
96.2
97.0
97.8



to R410A)


Refrigerating
% (relative
105.0
113.8
113.2
112.4
111.4
110.2
108.8
107.3


capacity ratio
to R410A)

























TABLE 157







Comparative
Comparative
Comparative
Comparative
Comparative
Comparative
Comparative
Comparative


Item
Unit
Example 43
Example 44
Example 45
Example 46
Example 47
Example 48
Example 49
Example 50
























HFO-1132(E)
mass %
10.0
20.0
30.0
40.0
50.0
60.0
70.0
10.0


HFO-1123
mass %
65.0
55.0
45.0
35.0
25.0
15.0
5.0
60.0


R32
mass %
25.0
25.0
25.0
25.0
25.0
25.0
25.0
30.0


GWP

170
170
170
170
170
170
170
203


COP ratio
% (relative
94.6
94.9
95.4
96.0
96.7
97.4
98.2
95.3



to R410A)


Refrigerating
% (relative
114.4
113.8
113.0
111.9
110.7
109.4
107.9
114.8


capacity ratio
to R410A)

























TABLE 158







Comparative
Comparative
Comparative
Comparative
Comparative
Example
Example
Comparative


Item
Unit
Example 51
Example 52
Example 53
Example 54
Example 55
25
26
Example 56
























HFO-1132(E)
mass %
20.0
30.0
40.0
50.0
60.0
10.0
20.0
30.0


HFO-1123
mass %
50.0
40.0
30.0
20.0
10.0
55.0
45.0
35.0


R32
mass %
30.0
30.0
30.0
30.0
30.0
35.0
35.0
35.0


GWP

203
203
203
203
203
237
237
237


COP ratio
% (relative
95.6
96.0
96.6
97.2
97.9
96.0
96.3
96.6



to R410A)


Refrigerating
% (relative
114.2
113.4
112.4
111.2
109.8
115.1
114.5
113.6


capacity ratio
to R410A)

























TABLE 159







Comparative
Comparative
Comparative
Comparative
Comparative
Comparative
Comparative
Comparative


Item
Unit
Example 57
Example 58
Example 59
Example 60
Example 61
Example 62
Example 63
Example 64
























HFO-1132(E)
mass %
40.0
50.0
60.0
10.0
20.0
30.0
40.0
50.0


HFO-1123
mass %
25.0
15.0
5.0
50.0
40.0
30.0
20.0
10.0


R32
mass %
35.0
35.0
35.0
40.0
40.0
40.0
40.0
40.0


GWP

237
237
237
271
271
271
271
271


COP ratio
% (relative
97.1
97.7
98.3
96.6
96.9
97.2
97.7
98.2



to R410A)


Refrigerating
% (relative
112.6
111.5
110.2
115.1
114.6
113.8
112.8
111.7


capacity ratio
to R410A)

























TABLE 160







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
27
28
29
30
31
32
33
34
























HFO-1132(E)
mass %
38.0
40.0
42.0
44.0
35.0
37.0
39.0
41.0


HFO-1123
mass %
60.0
58.0
56.0
54.0
61.0
59.0
57.0
55.0


R32
mass %
2.0
2.0
2.0
2.0
4.0
4.0
4.0
4.0


GWP

14
14
14
14
28
28
28
28


COP ratio
% (relative
93.2
93.4
93.6
93.7
93.2
93.3
93.5
93.7



to R410A)


Refrigerating
% (relative
107.7
107.5
107.3
107.2
108.6
108.4
108.2
108.0


capacity ratio
to R410A)

























TABLE 161







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
35
36
37
38
39
40
41
42
























HFO-1132(E)
mass %
43.0
31.0
33.0
35.0
37.0
39.0
41.0
27.0


HFO-1123
mass %
53.0
63.0
61.0
59.0
57.0
55.0
53.0
65.0


R32
mass %
4.0
6.0
6.0
6.0
6.0
6.0
6.0
8.0


GWP

28
41
41
41
41
41
41
55


COP ratio
% (relative
93.9
93.1
93.2
93.4
93.6
93.7
93.9
93.0



to R410A)


Refrigerating
% (relative
107.8
109.5
109.3
109.1
109.0
108.8
108.6
110.3


capacity ratio
to R410A)

























TABLE 162







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
43
44
45
46
47
48
49
50
























HFO-1132(E)
mass %
29.0
31.0
33.0
35.0
37.0
39.0
32.0
32.0


HFO-1123
mass %
63.0
61.0
59.0
57.0
55.0
53.0
51.0
50.0


R32
mass %
8.0
8.0
8.0
8.0
8.0
8.0
17.0
18.0


GWP

55
55
55
55
55
55
116
122


COP ratio
% (relative
93.2
93.3
93.5
93.6
93.8
94.0
94.5
94.7



to R410A)


Refrigerating
% (relative
110.1
110.0
109.8
109.6
109.5
109.3
111.8
111.9


capacity ratio
to R410A)

























TABLE 163







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
51
52
53
54
55
56
57
58
























HFO-1132(E)
mass %
30.0
27.0
21.0
23.0
25.0
27.0
11.0
13.0


HFO-1123
mass %
52.0
42.0
46.0
44.0
42.0
40.0
54.0
52.0


R32
mass %
18.0
31.0
33.0
33.0
33.0
33.0
35.0
35.0


GWP

122
210
223
223
223
223
237
237


COP ratio
% (relative
94.5
96.0
96.0
96.1
96.2
96.3
96.0
96.0



to R410A)


Refrigerating
% (relative
112.1
113.7
114.3
114.2
114.0
113.8
115.0
114.9


capacity ratio
to R410A)

























TABLE 164







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
59
60
61
62
63
64
65
66
























HFO-1132(E)
mass %
15.0
17.0
19.0
21.0
23.0
25.0
27.0
11.0


HFO-1123
mass %
50.0
48.0
46.0
44.0
42.0
40.0
38.0
52.0


R32
mass %
35.0
35.0
35.0
35.0
35.0
35.0
35.0
37.0


GWP

237
237
237
237
237
237
237
250


COP ratio
% (relative
96.1
96.2
96.2
96.3
96.4
96.4
96.5
96.2



to R410A)


Refrigerating
% (relative
114.8
114.7
114.5
114.4
114.2
114.1
113.9
115.1


capacity ratio
to R410A)

























TABLE 165







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
67
68
69
70
71
72
73
74
























HFO-1132(E)
mass %
13.0
15.0
17.0
15.0
17.0
19.0
21.0
23.0


HFO-1123
mass %
50.0
48.0
46.0
50.0
48.0
46.0
44.0
42.0


R32
mass %
37.0
37.0
37.0
0.0
0.0
0.0
0.0
0.0


GWP

250
250
250
237
237
237
237
237


COP ratio
% (relative
96.3
96.4
96.4
96.1
96.2
96.2
96.3
96.4



to R410A)


Refrigerating
% (relative
115.0
114.9
114.7
114.8
114.7
114.5
114.4
114.2


capacity ratio
to R410A)

























TABLE 166







Example
Example
Example
Example
Example
Example
Example
Example


Item
Unit
75
76
77
78
79
80
81
82
























HFO-1132(E)
mass %
25.0
27.0
11.0
19.0
21.0
23.0
25.0
27.0


HFO-1123
mass %
40.0
38.0
52.0
44.0
42.0
40.0
38.0
36.0


R32
mass %
0.0
0.0
0.0
37.0
37.0
37.0
37.0
37.0


GWP

237
237
250
250
250
250
250
250


COP ratio
% (relative
96.4
96.5
96.2
96.5
96.5
96.6
96.7
96.8



to R410A)


Refrigerating
% (relative
114.1
113.9
115.1
114.6
114.5
114.3
114.1
114.0


capacity ratio
to R410A)











    • The above results indicate that under the condition that the mass % of HFO-1132(E), HFO-1123, and R32 based on their sum is respectively represented by x, y, and z, when coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R32 is 100 mass %, a line segment connecting a point (0.0, 100.0, 0.0) and a point (0.0, 0.0, 100.0) is the base, and the point (0.0, 100.0, 0.0) is on the left side are within the range of a figure surrounded by line segments that connect the following 4 points:


      point O (100.0, 0.0, 0.0),


      point A″ (63.0, 0.0, 37.0),


      point B″ (0.0, 63.0, 37.0), and


      point (0.0, 100.0, 0.0),


      or on these line segments,


      the refrigerant has a GWP of 250 or less.

    • The results also indicate that when coordinates (x,y,z) are within the range of a figure surrounded by line segments that connect the following 4 points:


      point O (100.0, 0.0, 0.0),


      point A′ (81.6, 0.0, 18.4),


      point B′ (0.0, 81.6, 18.4), and


      point (0.0, 100.0, 0.0),


      or on these line segments,


      the refrigerant has a GWP of 125 or less.

    • The results also indicate that when coordinates (x,y,z) are within the range of a figure surrounded by line segments that connect the following 4 points:


      point O (100.0, 0.0, 0.0),


      point A (90.5, 0.0, 9.5),


      point B (0.0, 90.5, 9.5), and


      point (0.0, 100.0, 0.0),


      or on these line segments,


      the refrigerant has a GWP of 65 or less.

    • The results also indicate that when coordinates (x,y,z) are on the left side of line segments that connect the following 3 points:


      point C (50.0, 31.6, 18.4),


      point U (28.7, 41.2, 30.1), and


      point D (52.2, 38.3, 9.5),


      or on these line segments,


      the refrigerant has a COP ratio of 96% or more relative to that of R410A.

    • In the above, the line segment CU is represented by coordinates (−0.0538z2+0.7888z+53.701, 0.0538z2−1.7888z+46.299, z), and the line segment UD is represented by coordinates


      (−3.4962z2+210.71z−3146.1, 3.4962z2−211.71z+3246.1, z).

    • The points on the line segment CU are determined from three points, i.e., point C, Comparative Example 10, and point U, by using the least-square method.

    • The points on the line segment UD are determined from three points, i.e., point U, Example 2, and point D, by using the least-square method.

    • The results also indicate that when coordinates (x,y,z) are on the left side of line segments that connect the following 3 points:


      point E (55.2, 44.8, 0.0),


      point T (34.8, 51.0, 14.2), and


      point F (0.0, 76.7, 23.3),


      or on these line segments,


      the refrigerant has a COP ratio of 94.5% or more relative to that of R410A.





In the above, the line segment ET is represented by coordinates (−0.0547z2−0.5327z+53.4, 0.0547z2−0.4673z+46.6, z), and the line segment TF is represented by coordinates


(−0.0982z2+0.9622z+40.931, 0.0982z2−1.9622z+59.069, z).

    • The points on the line segment ET are determined from three points, i.e., point E, Example 2, and point T, by using the least-square method.
    • The points on the line segment TF are determined from three points, i.e., points T, S, and F, by using the least-square method.
    • The results also indicate that when coordinates (x,y,z) are on the left side of line segments that connect the following 3 points:


      point G (0.0, 76.7, 23.3),


      point R (21.0, 69.5, 9.5), and


      point H (0.0, 85.9, 14.1),


      or on these line segments,


      the refrigerant has a COP ratio of 93% or more relative to that of R410A.
    • In the above, the line segment GR is represented by coordinates (−0.0491z2−1.1544z+38.5, 0.0491z2+0.1544z+61.5, z), and the line segment RH is represented by coordinates


      (−0.3123z2+4.234z+11.06, 0.3123z2−5.234z+88.94, z).
    • The points on the line segment GR are determined from three points, i.e., point G, Example 5, and point R, by using the least-square method.
    • The points on the line segment RH are determined from three points, i.e., point R, Example 7, and point H, by using the least-square method.
    • In contrast, as shown in, for example, Comparative Examples 8, 9, 13, 15, 17, and 18, when R32 is not contained, the concentrations of HFO-1132(E) and HFO-1123, which have a double bond, become relatively high; this undesirably leads to deterioration, such as decomposition, or polymerization in the refrigerant compound.


(6) Specific Embodiment


FIG. 16 is a configuration diagram of an air conditioner 1 according to a first embodiment of the present disclosure. In FIG. 16, the air conditioner 1 is constituted by a utilization unit 2 and a heat source unit 3.


(6-1) Configuration of Air Conditioner 1

The air conditioner 1 has a refrigerant circuit 11 in which a compressor 100, a four-way switching valve 16, a heat-source-side heat exchanger 17, an expansion valve 18 serving as a decompression mechanism, and a utilization-side heat exchanger 13 are connected in a loop shape by refrigerant pipes.


In this embodiment, the refrigerant circuit 11 is filled with refrigerant for performing a vapor compression refrigeration cycle. The refrigerant is a refrigerant mixture containing 1,2-difluoroethylene, and any one of the above-described refrigerant A to refrigerant E can be used. The refrigerant circuit 11 is filled with refrigerating machine oil together with the refrigerant mixture.


(6-1-1) Utilization Unit 2

In the refrigerant circuit 11, the utilization-side heat exchanger 13 belongs to the utilization unit 2. In addition, a utilization-side fan 14 is mounted in the utilization unit 2. The utilization-side fan 14 generates an air flow to the utilization-side heat exchanger 13.


A utilization-side communicator 35 and a utilization-side microcomputer 41 are mounted in the utilization unit 2. The utilization-side communicator 35 is connected to the utilization-side microcomputer 41.


The utilization-side communicator 35 is used by the utilization unit 2 to communicate with the heat source unit 3. The utilization-side microcomputer 41 is supplied with a control voltage even during a standby state in which the air conditioner 1 is not operating. Thus, the utilization-side microcomputer 41 is constantly activated.


(6-1-2) Heat Source Unit 3

In the refrigerant circuit 11, the compressor 100, the four-way switching valve 16, the heat-source-side heat exchanger 17, and the expansion valve 18 belong to the heat source unit 3. In addition, a heat-source-side fan 19 is mounted in the heat source unit 3. The heat-source-side fan 19 generates an air flow to the heat-source-side heat exchanger 17.


In addition, a connection unit 30, a heat-source-side communicator 36, and a heat-source-side microcomputer 42 are mounted in the heat source unit 3. The connection unit 30 and the heat-source-side communicator 36 are connected to the heat-source-side microcomputer 42.


(6-2) Configuration of connection unit 30



FIG. 17 is an operation circuit diagram of a motor 70 of the compressor 100. In FIG. 17, the connection unit 30 is a circuit that causes power to be supplied from an alternating-current (AC) power source 90 to the motor 70 of the compressor 100 without frequency conversion.


The motor 70 is an induction motor and includes a squirrel-cage rotor 71, and a stator 72 having a main winding 727 and an auxiliary winding 728. The squirrel-cage rotor 71 rotates following a rotating magnetic field generated by the stator 72.


The compressor 100 has an M terminal, an S terminal, and a C terminal. The M terminal and the C terminal are connected by the main winding 727. The S terminal and the C terminal are connected by the auxiliary winding 728.


The AC power source 90 and the compressor 100 are connected by power supply lines 901 and 902 that supply an AC voltage to the compressor 100. The power supply line 901 is connected to the C terminal via a thermostat 26.


The thermostat 26 detects a temperature of a room equipped with the air conditioner 1. The thermostat 26 opens the contact thereof when the room temperature is within a set temperature range and closes the contact when the room temperature is out of the set temperature range.


The power supply line 902 branches off into a first branch line 902A and a second branch line 902B. The first branch line 902A is connected to the M terminal, and the second branch line 902B is connected to the S terminal via an activation circuit 20.


The activation circuit 20 is a circuit in which a positive temperature coefficient (PTC) thermistor 21 and an operation capacitor 22 are connected in parallel to each other.


In this embodiment, the thermostat 26 connected to the power supply line 901 and the activation circuit 20 connected to the power supply line 902 are referred to as the connection unit 30.


(6-3) Operation

In the operation circuit of the compressor 100 having the above-described configuration, turning on of the AC power source 90 causes a current to flow through the auxiliary winding 728 via the PTC thermistor 21 and the motor 70 to be activated.


After the motor 70 has been activated, the PTC thermistor 21 self-heats by using the current flowing therethrough, and the resistance value thereof increases. As a result, the operation capacitor 22, instead of the PTC thermistor 21, is connected to the auxiliary winding 728, and the state shifts to a stable operation state.


(6-4) Features

(6-4-1)


In the air conditioner 1 that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor 100 can be driven without interposing a power conversion device between the AC power source 90 and the motor 70. Thus, it is possible to provide the air conditioner 1 that is environmentally friendly and has a relatively inexpensive configuration.


(6-4-2)


In the air conditioner 1 that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the connection between the auxiliary winding 728 and the activation circuit 20, which is a parallel circuit of the PTC thermistor 21 and the operation capacitor 22, makes it possible to achieve a large activation torque of the motor 70 of the compressor 100.


After the compressor 100 has been activated, the PTC thermistor 21 self-heats and the resistance value thereof increases, the state changes to a state where the operation capacitor 22 and the auxiliary winding 728 are substantially connected to each other, and the compressor 100 is operated at a constant rotation rate (power source frequency). Thus, the compressor 100 enters a state of being capable of outputting a rated torque. As described above, in the air conditioner 1, switching of connection to the operation capacitor 22 is performed at appropriate timing, and thus the efficiency of the compressor 100 can be increased.


(6-4-3)


The motor 70 is an induction motor and is capable of high output with relatively low cost, and thus the efficiency of the air conditioner 1 can be increased.


(6-5) Modification Example


FIG. 18 is an operation circuit diagram of a motor 170 of a compressor 200 in the air conditioner 1 according to a modification example. In FIG. 18, the motor 170 is a three-phase induction motor and is connected to a three-phase AC power source 190 via a connection unit 130.


The connection unit 130 is a relay having contacts 130u, 130v, and 130w. The contact 130u opens or closes a power supply line 903 between an R terminal of the three-phase AC power source 190 and a U-phase winding Lu of the motor 170. The contact 130v opens or closes a power supply line 904 between an S terminal of the three-phase AC power source 190 and a V-phase winding Lv of the motor 170. The contact 130w opens or closes a power supply line 905 between a T terminal of the three-phase AC power source 190 and a W-phase winding Lw of the motor 170.


AC voltages are supplied from the R terminal, the S terminal, and the T terminal of the three-phase AC power source 190 to the corresponding U-phase winding Lu, the V-phase winding Lv, and the W-phase winding Lw of the motor 170. The AC voltage supplied to the V-phase winding Lv of the motor 170 has a phase difference of 120 degrees with respect to the AC voltage supplied to the U-phase winding Lu. Also, the AC voltage supplied to the W-phase winding Lw of the motor 170 has a phase difference of 120 degrees with respect to the AC voltage supplied to the V-phase winding Lv.


Thus, only the supply of AC voltages from the three-phase AC power source 190 to the motor 170 causes a rotating magnetic field to be generated in the stator 172, and the rotor 171 rotates following the rotating magnetic field. As a result, the compressor 200 is operated at a constant rotation rate (power source frequency). Thus, the operation circuit of the motor 170 does not require the activation circuit 20 according to the foregoing embodiment, and only a relay circuit of the connection unit 130 is used.


(6-6) Features of Modification Example

(6-6-1)


In the air conditioner 1 that uses a refrigerant mixture containing at least 1,2-difluoroethylene, the compressor 200 can be driven without interposing a power conversion device between the three-phase AC power source 190 and the motor 170. Thus, it is possible to provide the air conditioner 1 that is environmentally friendly and has a relatively inexpensive configuration.


(6-6-2)


The motor 170 is an induction motor and is capable of high output with relatively low cost, and thus the efficiency of the air conditioner 1 can be increased.


An embodiment of the present disclosure has been described above. It is to be understood that various changes of the embodiment and details are possible without deviating from the gist and scope of the present disclosure described in the claims.


REFERENCE SIGNS LIST






    • 1: air conditioner


    • 20: activation circuit


    • 21: positive temperature coefficient thermistor


    • 22: operation capacitor


    • 30: connection unit


    • 70: motor


    • 90: single-phase AC power source


    • 100: compressor


    • 130: connection unit


    • 170: motor


    • 190: three-phase AC power source


    • 200: compressor





CITATION LIST
Patent Literature

PTL 1: Japanese Unexamined Patent Application Publication No. 2013-124848

Claims
  • 1. An air conditioner comprising: a compressor that compresses a refrigerant containing at least 1,2-difluoroethylene;a motor that drives the compressor; anda connection unit that causes power to be supplied from an alternating-current (AC) power source to the motor without frequency conversion.
  • 2. The air conditioner according to claim 1, wherein the connection unit directly applies an AC voltage of the AC power source between at least two terminals of the motor.
  • 3. The air conditioner according to claim 1, wherein the AC power source is a single-phase power source.
  • 4. The air conditioner according to claim 1, wherein one terminal of the motor is connected in series to an activation circuit.
  • 5. The air conditioner according to claim 4, wherein the activation circuit is a circuit in which a positive temperature coefficient thermistor and an operation capacitor are connected in parallel to each other.
  • 6. The air conditioner according to claim 1, wherein the AC power source is a three-phase power source.
  • 7. The air conditioner according to claim 1, wherein the motor is an induction motor.
  • 8. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).
  • 9. The air conditioner according to claim 8, whereinwhen the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments AA′, A′B, BD, DC′, C′C, CO, and OA that connect the following 7 points:
  • 10. The air conditioner according to claim 8, whereinwhen the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments GI, IA, AA′, A′B, BD, DC′, C′C, and CG that connect the following 8 points:
  • 11. The air conditioner according to claim 8, whereinwhen the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PN, NK, KA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:
  • 12. The air conditioner according to claim 8, whereinwhen the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments JP, PL, LM, MA′, A′B, BD, DC′, C′C, and CJ that connect the following 9 points:
  • 13. The air conditioner according to claim 8, whereinwhen the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LM, MA′, A′B, BF, FT, and TP that connect the following 7 points:
  • 14. The air conditioner according to claim 8, whereinwhen the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments PL, LQ, QR, and RP that connect the following 4 points:
  • 15. The air conditioner according to claim 8, whereinwhen the mass % of HFO-1132(E), HFO-1123, and R1234yf based on their sum in the refrigerant is respectively represented by x, y, and z, coordinates (x,y,z) in a ternary composition diagram in which the sum of HFO-1132(E), HFO-1123, and R1234yf is 100 mass % are within the range of a figure surrounded by line segments SM, MA′, A′B, BF, FT, and TS that connect the following 6 points:
  • 16. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)) and trifluoroethylene (HFO-1123) in a total amount of 99.5 mass % or more based on the entire refrigerant, andthe refrigerant comprises 62.0 mass % to 72.0 mass % of HFO-1132(E) based on the entire refrigerant.
  • 17. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)) and trifluoroethylene (HFO-1123) HFO 1132(E) and HFO 1123 in a total amount of 99.5 mass % or more based on the entire refrigerant, andthe refrigerant comprises 45.1 mass % to 47.1 mass % of HFO-1132(E) based on the entire refrigerant.
  • 18. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32),
  • 19. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), 2,3,3,3-tetrafluoro-1-propene (R1234yf), and difluoromethane (R32),
  • 20. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),
  • 21. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),
  • 22. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),
  • 23. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),
  • 24. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), and 2,3,3,3-tetrafluoro-1-propene (R1234yf),
  • 25. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),
  • 26. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),
  • 27. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),
  • 28. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),
  • 29. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),
  • 30. The air conditioner according to claim 1, whereinthe refrigerant comprises trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and difluoromethane (R32),
Priority Claims (9)
Number Date Country Kind
2017-242183 Dec 2017 JP national
2017-242185 Dec 2017 JP national
2017-242186 Dec 2017 JP national
2017-242187 Dec 2017 JP national
PCT/JP2018/037483 Oct 2018 JP national
PCT/JP2018/038746 Oct 2018 JP national
PCT/JP2018/038747 Oct 2018 JP national
PCT/JP2018/038748 Oct 2018 JP national
PCT/JP2018/038749 Oct 2018 JP national
Continuation in Parts (1)
Number Date Country
Parent 16772961 US
Child 16913454 US