Patent Grant
6929985
The present invention concerns an air filter for use in a clean room used, for example, in factories or research laboratories relevant to the field of semiconductors, foodstuffs and biotechnology, a method of manufacturing thereof, a local facility and a clean room equipped with the air filter.
In clean rooms used heretofore, for example, in factories or research laboratories in the relevant field of semiconductors, foodstuffs, medicines and biotechnology, dry air filters for trapping air-born particles are disposed to air introduction paths and air passing therethrough is introduced into the clean room.
Air filters used at present in clean rooms include ULPA (abbreviation for Ultra Low Penetration Air.) using glass fibers for the filter medium and HEPA (abbreviation for High Efficiency Particle Air), and such filters are excellent filters in view of removal of dusts and, for example, ULPA filters can remove fine particles even of 0.1 μm. Further, non-glass type filters using fluoro resin or quartz fibers instead of the glass fibers for the filter medium have also been developed so as not to release inorganic substances from the air filters.
Recently, with the increase of integration degree of semiconductors, diffusing of gaseous organic substances as well as dusts in the clean room air have considered to be the cause of the defective. That is, it has been pointed out that organic substances are adsorbed on the surface of semiconductor substrates (silicon wafers) in clean rooms, to deteriorate device characteristics (for example, Fujii, “Gaseous Contaminants and Current Situation for Countermeasure of Removal”, Air Cleaning,, Vol. 32, No. 3, p 43 (1994), published from the Foundation of Japan Air Cleaning Society).
Further, it has been well-known that an n-type semiconductor is obtained by doping P (phosphorus) and a p-type semiconductor is obtained by doping B (boron, into a silicon-wafer in semiconductor manufacturing steps but, if phosphorus compounds or boron compounds are present in the clean room air., these may possibly cause unnecessary doping, so that it is necessary to remove such ingredients from the clean room air.
The present invention has been accomplished to solve the problems described above and it is an object thereof to provide an air filter for trapping air-born particles that can eliminate the presence of gaseous organic substances, for example, in clean rooms semiconductor production apparatus or the like, a method of manufacturing an air filter therefor, a treatment agent constituting the air filter, a method of manufacturing, a filter medium, a clean r6om and a local facility such as a semiconductor production apparatus in which gaseous organic substances are not present, as well as a clean room and a local facility in which phosphorus compounds and boron compounds are not present.
The present inventors have made earnest studies for attaining the foregoing-object and, as a result, have accomplished the present invention based on the finding that presence of gaseous organic substances in a clean room and a local facility such as a semiconductor production apparatus is mainly caused by air filters disposed to air introduction paths and gaskets intervened for attaching the air filters to openings, for example, of a ceiling.
That is, it has been found by the study of the present inventors that gaseous organic substances such as cyclosiloxanes, carboxylic acid esters, phosphoric acid esters, hydrocarbons, and phenols are released from the existent air, filters described above and that such organic substances are released from treatment agents impregnated between each of fibers upon forming the fibers into a cloth-like filter medium (including a binder for binding fibers, a water repellent for improving dust trapping effect and a plasticizer or an antioxidant), silicone oils deposited to fibers in a case where the filter medium is glass fibers (this is a reinforcing material upon spinning glass fibers which serves also as a water repellent of the filter medium) and sealing materials for bonding a filter medium and a frame. Further, it has also been found that organic substances are detected at a high ratio also from rubber materials used so far as gaskets.
Specifically, it has been found that the ingredient of the conventional water repellent (non-silicone type) in the treatment agent is liquid paraffins (aliphatic hydrocarbon having 12 to 18, carbon atoms) which contain a plasticizer or an antioxidant of relatively low molecular weight.
Further, while the sealing material comprising a polyurethane or epoxy type resin as the main ingredient is used, it has been found that isocyanates of the main agent left after the curing reaction become organic contaminations in a case of a two component polyurethane resin, while amine compounds used as a curing agent become organic contaminations in a case of a two component epoxy resin. It has also been found that conventional sealing materials contain plasticizers and antioxidants of relatively low molecular weight.
Based on the findings described above, the present invention provides an air filter comprising a filter medium formed of fibers treated with a treatment agent into a cloth-like shape, a frame for containing the filter medium and a sealing material for tightly sealing a portion between the frame and the filter medium for trapping air-born particles, wherein at least one of the filter medium and the sealing material does not release gaseous organic substances during use.
Further, the present invention provides an air filter satisfying one of the following definitions (a)-(c) and (e)-(g) for the treatment agent and the sealing material.
(a) The main ingredient of a non-silicone type water repellent contained in the treatment agent Is at least one of an aliphatic hydrocarbon having 20 carbon atoms or more and a higher alcohol having 18 carbon atoms or more.
(b) The main ingredient of the plasticizer contained in the treatment agent is at least one of carboxylic acid esters, polyester and epoxy type compound having 400 or more molecular weight.
(c) The main ingredient of the antioxidant contained in the treatment agent is a phenolic compound having 300 or more molecular weight.
(e) The main ingredient of the plasticizer contained in the sealing material is at least one of carboxylic acid esters, polyesters and epoxy type compounds having 400 or more molecular weight.
(f) The main ingredient of the antioxidant contained in the sealing material is a phenolic compound having 300 or more molecular weight.
(g) The main-ingredient of the lubricant contained in the sealing material is at least one of an aliphatic hydrocarbon having 20 carbon atoms or more and a higher alcohol having 18 carbon atoms or more.
Further, the present invention provides a method of manufacturing an air filter which comprises selectively using the plasticizer and the antioxidant defined in (b), (c), (e) and (f) for the treatment agent and the sealing agent described above.
Now, if the main ingredient of the non-silicone type water repellent in (a) and the main ingredient of the lubricant in (g) are an aliphatic hydrocarbon having 19 carbon atoms or less and a higher alcohol having 17 carbon atoms or less, the gaseous substances are present in the clean room air being entrained by air passing through the air filter in a usual clean room, which is controlled at a temperature of 23° C. and at a humidity of 30-40% and in which the flow rate of air passing through the air filter is about. 0.3 to 0.4 m/s, but such gaseous substances are not present in the clean room air when an aliphatic hydrocarbon having 20 carbon atoms or more and a higher alcohol 18 having carbon atoms or more is used.
Further, if the main ingredient of the plasticizer in (b) and (e) is dibutyl phthalate (molecular weight 278), dioctyl phthalate (molecular weight 391) or di-2-ethylhexyl adipate (.molecular weight 371) having 400 or more molecular weight, the gaseous substances are present in the clean room air being entrained by air passing through the air filter in the usual clean room, but the-gaseous substances are not present in the clean room air if those having 400 or more molecular weight are used.
Further, if the main ingredient of the antioxidant in (c) and (f) is 2,6-di-t-butyl-p-cresol (molecular weight. 220.4) having 300 or more molecular weight, the gaseous substances are present in the clean room air being entrained by air passing through the air filter in the usual clean room, but the gaseous substances are not present in the clean room air if those having 400 or more molecular weight are used.
As actual examples of (a) and (g), there can be mentioned at least one of microcrystalline wax, natural wax, synthesis paraffin, polyolefin wax, branched alcohol of 18, 20 and 24 carbon number and oleyl alcohol.
As actual examples of (b) and (e), there can be mentioned isononyl phthalate (molecular weight: 418), octyldecyl phthalate (molecular weight: 419), diisodecyl phthalate (molecular weight: 447), lauryl phthalate (molecular weight:
501), myristylyl phthalate (molecular weight: 530), di-2-ethylhexyl azelate (molecular weight: 413), di-2-ethylhexyl sebacate (molecular weight: 427), tris-2 ethylhexyl trimellitate (molecular weight: 547), trioctyl trimellitate (molecular weight: 547), trinonyl trimellitate (molecular weight: 570), tridecyl trimellitate (molecular weight: 612), polyesters obtained by polycondensation of adipic acid, azelaic acid, sebacic acid or phthalic acid and glycol or glycerine (molecular weight: 2,000-8,000), epoxy fatty acid ester (molecular weight: 400-500) and epoxidized oil (molecular weight about 1,000).
As actual examples of (c) and (f), there can be mentioned stearyl-β-(3,5-di-t-butyl-4-hydrbxyphenyl) propionate (molecular weight: 520.9), 2,2′-methylene-bis (4-methyl-6-t-butylphenol) (molecular weight: 340.5), 2,2′methylene-bis′ (4-ethyl-6-t-butylphenol) (molecular weight 368.54), 4,4′-thiobis (3-methyl-B-t-butylphenol) (molecular weight: 358-5), 4,4′-butylidene-bis (3-methyl-6-t-butyl-phenol) (molecular weight: 382.6), 1,1,3-tris (2-methyl-4-hydroxy-5-t-butylphenyl) butane (molecular weight: 544.8), 1,3,5-trimethyl-2,-4,6-tris (3,5-di-t-butyl-4-hydroxybenzyl) benzene (molecular weight: 775.2), tetrakis (methylene-3(3′5′-.di-t-butyl-4′-hydroxyphenyl) propionate methane (molecular weight: 1177.7), bis (3,3′-bis W-hydroxy-3′-t-butylphenyl) butiric acid) glycol ester (molecular weight: 1177.7) and tocophenol (molecular weight: 794.4).
Further, the present inventors have found that as the molecular weight of the organic substance is greater, the volatility is lowered and the adsorption property is increased, but the adsorption amount to the silicon wafer is decreased and restricted if the molecular weight increases to more than a predetermined amount and, that the predetermined amount is different depending on the molecular structure, and definitions for the numerical values in (a)-(c) and (e)-(g) described above were determined based on the result of experiment.conducted for a number of targeted materials respectively.
The air filter according to the present invention may be such one as satisfying at least one of the definitions (a)-(c) and (e)-(g) described above, but those satisfying all of them are preferred since no gaseous organic substances are not released from all of the constituent materials of the air filter.
Specifically, preferred are those in which the main ingredient of the non-silicone type water repellent is microcrystalline wax, the main ingredient of the plasticizer contained in the non-silicone series water repellent is tri-2-ethylhexyl trimellitate, the main ingredient of the antiox 1 dant contained in the non-silicone type water repellent is 2,2′-methylene-bis (4-ethyl-6-t-butylphenol), the main ingredient of the plasticizer contained in the sealing material is di-2-ethylhexyl sebacate, the main ingredient of the antioxidant contained in the sealing material is 2,2′methylene-bis (4-ethyl-6-t-butylphenol) and the main ingredient of the lubricant contained in the sealing material is synthesis paraffin.
Further, the present invention provides an air filter which satisfies at least one of the definitions (a)-(c) and (e)-(d) described above, in which the main ingredient of the sealing material is a two component polyurethane resin formed by reaction between a main agent comprising a polyisocyanate and a curing agent, and the equivalent amount of active hydrogen in the curing agent is more than the equivalent amount of the isocyanate as the main agent and which contains no phosphoric acid ester. In the air filter, since the isocyanates of the main agent do not remain after the curing reaction of the sealing material, isocyanates and diamines caused by reaction of the isocyanate with water in the air are not formed, and since phosphoric acid ester is not released, release of gaseous organic substances from the sealing material is further suppressed.
The present invention further provides an air filter which satisfies at least one of the definitions (a).-(c) and (e)-(g) described above and in which the main ingredient for the sealing material is a two component epoxy resin formed by the reaction between the main ingredient and the curing agent, and the curing agent is acidic or neutral. In the air filter, since a basic amine compound as the curing agent of the sealing material is not contained in the air filter, release of the gaseous organic substances from the sealing material is further suppressed.
The present invention further provides an air filter which satisfies at least one of the definitions (a)-(c) and (e)-(g) described above and in which the main ingredient of the sealing material is a two component epoxy resin formed by the reaction between the main agent and the curing agent is of an amine type and the residual amine is reduced. As the means for reducing the residual amine, there can be mentioned blending and curing such that the amine equivalent is slightly lower than the epoxy equivalent thereby leaving no residual amine after curing, or heating of the resin after curing thereby volatiling the residual amine.
Further, the present invention provides an air filter which satisfies at least one of the definitions (a)-(c) and (e)-(g) described above and in which the filter medium is formed into a cloth-like shape by treating silicone-oil deposited glass fibers with a treatment agent and the silicone oil does not contain cyclosiloxanes having 10 silicon atom or less. Since cyclosiloxanes having 10 silicon atoms or lessare adsorbed extremely easily to the silicon wafer, this filter is suitable, particularly, to an air filter used for a clean room for use in semiconductor production.
Further, the present invention provides a method of manufacturing an air filter including a first step of depositing an silicone oil to glass fibers and a second step of treating the glass fibers with a treatment agent after the first step thereby forming a cloth-like filter medium, which comprises subjecting the glass fibers after the first step to a heat treatment in, a clean air stream, thereby sufficiently removing siloxanes having 10 silicon atoms or less from the silicone oil deposited to the glass fibers and then applying a treatment by a treatment agent not releasing gaseous organic substances.
This is one of methods for manufacturing the air filter, in which siloxanes having 10 silicon atoms or less contained in the silicone oil can be removed sufficiently by putting the glass fibers deposited with the silicon oil in a tightly closed vessel and heating, for example, at 120° C. for several hours.
Further, the present invention provides a method of manufacturing an air filter including a first step of depositing a silicon oil to glass filters and a second step of treating the glass fibers with a treatment agent, after the first step into a cloth-like filter medium which comprises using those removed with cyclosiloxane having 10 silicon atoms or less as the silicone oil used in the first step and treating them by a treatment agent not forming gaseous organic substances.
This is one of methods for manufacturing the air filter, and siloxanes having 10 silicon atoms or less contained in the silicone oil can be eliminated sufficiently by removing low boiling ingredients by heating, for example, at 200° C. in a vacuum state (for example, at vacuum degree of 5 mHg).
Further, the present invention provides a clean room equipped one of air filters each described above.
Further, the present invention provides a local facility equipped with one of air filters each described above. The local facility means, for example, a clean booth disposed to a place where cleanness is intended to be increased locally, or a production facility requiring a predetermined cleanness, for example, a semiconductor production apparatus.
Further, the present invention provides a clean room, in which walls and floors are fabricated with building materials releasing gaseous organic substances in an amount of 50 μg per 1 g or less measured by a purge & trap method, and one of the air filters described above is attached by interposing, between the air filter and an opening used for attachment, a, gasket not releasing gaseous organic substances in an amount of 50 μg per 1 g or less measured by the purge & trap method.
When the walls and the floors of the clean room and the gaskets for attaching the air filters are constituted with materials releasing gaseous organic substances in an amount of 50 μg per 1 g or less measured by the purge & trap method, the clean room can be reliably put to a state in which the organic substances are not released in a usual operation state.
If the clean room is used, for example, in a semiconductor production factory, it is possible that the organic substances are scarcely adsorbed to the silicone wafer.
The purge & trap method is a method of passing an inert gas at a predetermined temperature (a temperature at which all the organic ingredients can be volatile) to a predetermined amount of a material, evaporating all the gaseous organic ingredients contained in the specimen, trapping them and quantitatively determining the amount of the gaseous organic substances released from the trapped ingredient.
For the wall materials among the building materials releasing the gaseous organic substances in an amount of 50 μg per 1 g or less, a method of dry sealing a partition system by a fire proof material previously proposed by the present Applicant (refer to Patent Laid-Open Sho 62-86248, Utility Model Laid-Open Sho 62-56614 and Utility Model Laid-Open Sho 62-124102) can be adopted and the surface material of the free access floor may be made of inorganic material such as stainless steel for the floor material. The amount of gaseous organic substances released from the wall materials and the floor materials is about 1.0 μg per 1 g.
Further, the present invention provides a treatment agent for impregnation into fibers in order to form the fibers into a cloth-like shape as a filter medium used for the air filter, which satisfies one of the definitions (a)-(c) described above. The treatment agent can suppress the amount of gaseous organic substances released from the air filter manufactured by using them.
As the treatment agent, those satisfying all the definitions (a)-(c) described above are preferred since gaseous organic substances are not released from the main constituent materials.
Further, the present invention provides a method of manufacturing a filter medium which selectively uses those defined with (b), (c) described above as the plasticizer and the antioxidant contained in the treatment agent impregnated in the filter medium. According to this method, a filter medium with less releasing amount of the gaseous organic substances can be manufactured.
The present inventors have further found that the presence of the phosphorus compounds or boron compounds in the clean room is attributable to organic phosphorus compounds (phosphoric esters) contained in the sealing material tightly sealing a portion between the filter medium and the frame of the air filter, and surface material for walls and floors for the phosphorus compounds and attributable to boron oxides contained in glass fibers as the filter medium of the air filter for the boron compounds.
From the findings described above, the present invention provides a clean room in which at least the surface material of the walls and the floors, the filter medium of the air filter and the sealing material for tightly sealing the portion between the filter medium and the frame are formed of such a material as not releasing organic phosphorus compounds and boron compounds into the air.
Further, the present invention provides a clean room in which the material releases gaseous organic phosphor compounds in an amount of 10 μg or less per 1 g of the material by the purge & trap method and leaches boron compounds in, an amount of 20 μg or less per 1 g of the material after immersing in ultra-pure water for 28 days.
As described above, even when the constituent materials for the clean room are formed of a material containing the organic phosphorus compounds and the boron compounds, if the amount of the gaseous organic phosphorus compounds released from the constituent material is reduced to 10 μg or less per 1 g by the purge & trap method, and the boron compounds leached after immersion in ultra-pure water for 28 days is reduced to 20 μg or less per 1 g, it is possible that the organic phosphorus compounds and the boron compounds are not present in the clean room air when the clean room is operated in a usual state (at a temperature of 23° C., humidity of 30-40% and a flow rate of air passing the air filter of 0.3-0.4 m/s)
Further, the present invention provides a clean room in which the sealing material is a polyurethane resin type sealing material containing diphenyl methane diisocyanate as a diisocyanate constituting the main ingredient thereof and, when a phosphoric acid ester is contained as a liquefying agent therefor, the molecular weight of the phosphoric acid ester is determined as 300 or more.
In conventional clean rooms, phosphoric acid esters are used as the liquefying agent for the polyurethane resin type sealing material containing diphenyl methane diisocyanate (additive for making diphenyl methane diisocyanate at high purity into a liquid state at a normal temperature) and as a plasticizer or a flame retardant for the vinyl chloride resin type sheet as the surface material for the walls and the floors. Among them, while the carboxylic acid or the like having 400 or more molecular weight shown in (e) described above can be used instead of the phosphoric acid, and aluminum hydroxide, antimony trioxide or the like can be used instead of the phosphoric acid ester for the flame retardant, but there is no substitute for the phosphoric acid ester as the liquefying agent.
Then, if the phosphoric acid ester used is triethyl phosphate (molecular weight 18-2), tributyl phosphate (molecular weight 266) and tris (,B-chloroethyl) phosphate (molecular weight 285) having 300 or less molecular weight, gaseous substances of them are entrained by air passing through the air filter and present in the clean room air in the usual clean rooms described above, but when those having 300 or more molecular weight are used, gaseous substances of them are not present in the clean room air.
Accordingly, it is possible that the phosphoric acid ester is not present the clean room air by using a phosphoric acid ester having 300 or more molecular weight as the liquefying agent and by using the substitute described above or a phosphoric acid ester having 300 or more molecular weight for the plasticizer and the flame retardant.
Further, the present invention provides a clean room in which the phosphoric acid ester used as the liquefying agent is at least one of the substances shown in (h) below. (h) tri-2-ethylhexyl phosphate (molecular weight 435), tributoxyethyl phosphate (molecular weight 398), trioleylphosphate (molecular weight 849), triphenyl phosphate (molecular weight 326), tricresol phosphate (molecular weight 368), trixylenyl phosphate (molecular weight 410), cresyl phenyl phosphate (molecular weight 340), xylenyl diphenyl phosphate (molecular weight 354), 2-ethylhexyl diphenyl phosphate (molecular weight 362), condensed aromatic aphosphoric acid ester (molecular weight not less than 400), tris (tridecyl) phosphite (molecular weight 629) and triphenyl phosphite (molecular weight 310).
Further, the present invention provides a local facility in which at least the surface material for the walls, the filter medium for the air filter and the sealing material tightly sealing a portion between the filter medium and the frame are formed of a material not releasing organic phosphorus compounds and boron compounds in the air.
Further, the present invention provides a local facility in which the material releases gaseous organic phosphorus. Compounds in an amount of 10 μg or less per 1 g of the material by the purge & trap method, and leaches the boron compound in an amount of 20 μg or less per 1 g of the material after immersing in ultra-pure water for 28 days.
Further, the present invention provides a local facility in which the sealing material is a polyurethane resin type sealing material, and contains diphenyl methane diisocyanate as a diisocyanate constituting the main Ingredient thereof and, when the phosphoric acid ester is contained as the liquefying agent therefor, the molecular weight of the phosphoric acid ester is 300 or more.
Further, the present invention provides a local facility in which the phosphoric acid ester used as the liquefying agent is at least one of the substances shown in (h).
As described above also in the local facility, it is possible that the gaseous organic phosphorus compounds or boron compounds are not present in the air at the inside of the local facility by constituting the wall material and the air filter in the same manner as in the case of the clean room.
Accordingly, the clean room and the local facility are particularly suitable to the production of semiconductors.
The air filter according to the present invention is manufactured in the same manner as conventional air filters for use in clean rooms, by treating glass fibers or organic fibers such as of polytetrafluoro ethylene with a treatment agent containing, for example, a binder made, of an acrylic resin or the like, a non-silicone type water repellent, a plasticizer and an antioxidant thereby forming a cloth-like filter medium, putting the filter medium into a frame of a predetermined size and tightly sealing a portion between the frame and the filtration medium with a sealing material, in which those not forming gaseous organic substances during use of the clean room are selected and used as the treatment agent and the sealing material. Specifically, the treatment agent is adapted to satisfy the above definitions (a)-(c), while the sealing material is adapted to satisfy the above definitions (e)-(g).
Further, when the fibers for the filter medium are glass fibers, a silicone oil not containing cyclosiloxanes having 10, silicone atoms or less is used, or glass fibers coated with a silicone oil are subjected to a heat treatment in a clean air stream, to remove cyclosiloxanes having 10 silicone atoms or less, so that cyclosiloxanes having 10 silicone atoms or less are not contained in the filter medium.
Further, in order that the phosphorus compounds and the boron compounds are not present in the clean room and the local facility, at least the surface material for the walls, and the floors (only for the walls in the local facility not equipped with floors), the filter medium for the air filter and the sealing material for tightly sealing a portion between the filter medium and the frame are formed of a material not releasing the organic phosphorus compounds and the boron compounds in the air. Specifically, as the materials described above, those releasing gaseous organic phosphorus compounds in an amount of 10 μg or less per 1 g of the material by the purge & trap method and leaching the boron compounds in an amount of 20 m g or less per 1 g of the material after immersing in super-purified water for 28 days are used.
Details for the mode of practicing the present invention will be explained below referring to concrete examples.
In Nos. 1-5 and 7-12, air filters were manufactured by using glass fibers or fluoro-fibers as the filter medium, in which the non-silicone type water repellent, the plasticizer and the anti oxidant contained in the treatment agent, the main ingredient for the sealing material and the plasticizer and the antioxidant contained in the sealing material had constitutions shown in the following Tables 1 to 3. In No. 6, commercially available ULPA filters were used as they were, and the ingredients for each of the constituent materials were analyzed and examined by the following analyzing method.
Abbreviations in each of the tables show the following substances.
In Nos. 1-5, glass fibers for use in commercially available ULPA filters (coated with a silicone oil upon spinning) removed with siloxanes having 10 silicon atoms or less by heating in a clean air stream at 120° C. for 6 hours were used. When 400 mg of the glass fibers were analyzed by the following P&T (dynamic headspace), -GC/MS′;met-hod, siloxane having 10 silicon atoms or less contained in the glass fibers were less than the detection limit value by the analyzing method.
In Nos. 6-9, glass fibers for use In commercial ULPA filters (coated with a silicone oil upon spinning) were used as they were.
In No. 10, silicone oil KF99 manufactured by Shinetsu Chemical Industry Co. was charged in a vacuum distillation device, and kept at 200° C. at a vacuum degree of 5 mHg to remove low boiling ingredients, by which the siloxanes having 10 silicon atoms or less contained in the silicone oil were, removed sufficiently to less than the detection limit value by the analysis using the following P&T-GC/MS method. In the analysis, quartz fibers deposited with several mg of a silicone oil after vacuum distillation were used as the specimen. Then, glass fibers obtained by coating the silicone oil not containing siloxanes having 10 silicon atoms or less as the reinforcing material upon spinning were used as the fibers for the filter medium.
In Nos. 11 and 12, fluoro-fibers (polytetrafluoroethylene: PTFE) were used as the fibers for the filter medium. The fibers are not coated with the silicone oil. <P&T (Purge & Trap: Dynamic headspace method) -GC/MS method>
A predetermined amount of the specimen is filled in a test tube, the test tube is heated at 150° C. for 30 min while flowing a helium gas to the inside, volatile ingredients are trapped in a trap tube cooled to −80° C., and the ingredients in the trap tube are heated rapidly to 300° C. under a helium gas stream into a gaseous state, which are introduced into a GS/MS device.
The GC device is HP-5890A manufactured by Hewlett-Packard Co. and the MS device is HP-5970B of the same company. The column for the GC device is HP-ULTRA 2 (OV-5 system) of the same company having 0.2 mm inner diameter, 25 mm length and 0.33 μm thickness. The temperature condition upon measurement by the GC device is as follows.
Initial temperature 40° C. temperature elevation at a rate of 100C/min →final temperature 280° C. (kept for 15 min). Further, the carrier gas in the GC device is helium, the injection method is a split method, and a split ratio is 1/200. The ionization method for the MS device is an electron impact method and the detection range is 25 to 1000 at m/z.
The quantitative analysis is conducted by preparing a calibration line for an organic substance identified on every peak for each of the ingredients or, if plurality of peaks appear, all ingredients are indicated using n-decane as a reference substance by the concentration converted based on n-decane as a standard according to a calibration curve thereof. Thus, the content and the kind of the volatile organic materials in the specimen are measured.
(Treating Agent)
In Nos. 1-5 and 7-12, the non-silicone type water repellent, the plasticizer and the antioxidant shown in each of the tables were blended at each of the ratios on every samples (values based on 100 parts by weight of the water repellent are indicated as parts by weight in ( ) each of the tables), which are dissolved in a 1:1 solvent mixture of acetone and toluene and incorporated with a predetermined amount of an acrylic resin binder, the solution was impregnated into glass fibers spread and overlaid into a sheet like web of a predetermined size and then dried to prepare a cloth-like filter medium. About 1 g of the non-silicone type water repellent was used for the filter medium for one unit of the filter.
(Sealing Material)
Sealing materials were manufactured by blending, the main ingredients for the sealing materials (main agent and curing agent) and plasticizers (plus antioxidant and lubricant in Nos. 1, 2, 6 to, 8 10, 11) shown in each of the tables at each of ratios (values based on 100 parts-by weight of the main ingredient are indicated as parts by weight in ( ) each of the tables) on every samples and the filter medium was placed and tightly sealed in an aluminum frame (600 mm×600 mm ×100 mm, one-half size of commercial product) by using the sealing material to prepare air filters.
In Nos. 1 and 2 using the polyurethane type sealing material, the curing agent and the main ingredient (diisocyanate comprising methylene diphenyl diisocyanaie as the main ingredient) were mixed as such a blending ratio that the equivalent amount of active hydrogen in the former is greater than the equivalent amount of the isocyanate group in the latter.
Further, an amine type curing agent was used for No. 4, and a treatment of removing volatile organic substances (mainly amines remaining after curing) was conducted by winding a ribbon heater around the frame after curing and heating at about 130° C. for 4 hours.
For each of the sealing materials, the releasing amount of the organic substances was measured by using a portion cutout therefrom three days after curing (several tens milligram) and by the analysis by the P&T (Dynamic headspace)-GC/MS method described above. The results are also shown collectively in each of the tables. For No. 4, the measurement was conducted to the sealing material after the treatment of removing the organic substances described above.
(Performance Test for Air Filter: Measurement for Dust Removing Efficiency)
For the thus manufactured air filter, particles of dioctyl phthalate (DOP) were blown at a blow rate of 5.3 cm/sec to the entire surface on one side, the number of DOP particles contained in the air near the filter medium surface on the blown side (number of particles at the inlet) and the number of DOP particles contained in the air in the vicinity of the filter medium surface on the opposite side (number of particles at the exit) are counted by a particle counter respectively and it is judged as satisfactory if the number of particles at the exit is 100 n/ft3 or less for the number of particles at the inlet of 107n/ft3 (that is, if the removing efficiency is 99.999% or higher). The efficiency for removing dusts for each of the air filters measured by this method, which is referred to as “COLD DOP Method”, is shown in each of the tables. (Gasket)
Each of the thus obtained air filters was attached to a frame of a blower filter unit by way of the gasket shown in each of the tables respectively. Further, the releasing amount of the organic substances was also measured for the gasket by using a portion cutout therefrom. The results are also shown collectively in each of the tables.
The gasket used is as shown below GI was formed by mixing the main agent and the curing agent of the main ingredient, the plasticizer, the antioxidant and the lubricant and cast molding them. Further, G2-G4 were formed by heat-kneading the rubber material as the main ingredient, the plasticizer, the antioxidant and the lubricant and extrusion molding them by an extrusion molder. For G5 and G6, commercial products were used as they were.
Clean rooms were fabricated by using each of the blower filter units, forming wall materials by dry-sealing of partitions finished by bake coating, and forming floor materials by using stainless steel sheets as the surface material of a free access floor. The amount of organic substances released was 0.1 μg/g or less both for the wall materials and the floor materials according to the analysis by the P&T-(Dynamic headspace) method described above. After 3 days operation of the clean rooms, silicon wafers of 6 inch diameter were placed and-left for 6 hours in it, and the amount and the kind of the organic substances adsorbed on the wafer were analyzed by using the following SWA device. The results are also shown collectively in each of the tables.
<Analysis by SWA Device>
The SWA device is a silicon wafer analyzer (trade name of products) manufactured by G. L. Science Co. having the following trap device, TCT (Thermal Desorption Cold Trap Injector) device, and GC/MS device. The trap device is adapted to desorb materials adsorbed on the surface of a wafer and collect desorbed ingredients. The TCT'device is adapted to heat the ingredients collected by the trap device to 300° C. in a helium gas stream, then introduce them into a capillary tube cooled to −130° C. by liquid nitrogen and collect them under cooling. The ingredients collected by the TCT device are rapidly heated to 300° C. in a helium gas stream and introduced into the GC/MS device.
Referring to the GC/MS device used herein, the GC device is HP-5890A and MS devices is HP-5971A. HP-5 (25 mm length, 0.2 mm inner diameter, 0.33 μm film thickness) is used for the column of the GC device and temperature condition upon measurement by the GC device is as follows.
Initial temperature 80° C. (kept for 10 min) temperature elevation at a rate of 7° C./min→final temperature 300° C. (kept for 10 min).
Other procedures than the above are identical with those in the P&T (Dynamic headspace)-GC/MS -Method, by which the content and the kind of the organic substances adsorbed on the wafer surface are measured. According to this method, analysis is possible to the order of several ng (10−9 g) per one wafer.
As can be seen from the results, in Nos. 1-5 and Nos. 10 and 11 corresponding to each of the embodiments of the present invention, gaseous organic substances present in the clean room can be reduced and the amount of the organic substances adsorbed to the silicon wafer placed in the clean room can be reduced to less than 1/10 compared with the case of a conventional ULPA filter (No. 6) or a filter using a plasticizers and antioxidants, etc. of lower molecular weight (Nos. 7-9, 12). Also, the dust removing efficiency dusts is higher than 99.999%, which does not deteriorate the performance as the air filter.
As the floor material, the wall material, the filter medium of the air filter (prefilter: for external air intake port, main filter for clean air blown out port), and the sealing material for securing the filter medium and the frame of the air filter, the following materials were used in the combination shown in Tables 4 and 5 to fabricate each of clean rooms. The size (inner size) of each clean room was 6,000×7200×3,700 mm.
(Floor Material)
A vinyl chloride laying sheet (1) (2. 0 mm, thickness) was prepared by adding an epoxidized soybean oil as a plasticizer, stearyl -β-(3, 5-di-t-butyl -4-hydroxyphenyl) propionate as an antioxidant, aluminum hydroxide as a flame retardant and stearyl amide ethylene oxide adduct as an antistatic agent to a polyvinyl chloride resin. A vinyl chloride laying sheet (2) (2.0 mm thickness) is a commercially available product (antistatic FLOORLIUM, manufactured by Tori Co.).
A floor for a clean room was formed by appending either one of the vinyl chloride sheets or a commercially available stainless steel sheet to a free access floor made of aluminum.
(Wall Material)
A vinyl chloride cloth (1) (0.28 mm thickness) was prepared by adding 1-3-butylene glycol adipate as a plasticizer, 2,2-methylene-bis(4-methyl-B-t-butyl phenyl) as an antioxidant, antimony trioxide as a flame retardant and stearyl amide ethylene -oxide adduct as an antistatic agent to a polyvinyl chloride resin. A vinyl chloride cloth (2) (1.0 mm thickness) is a commercially available product (SG 1533 manufactured by Sangetsu Co.).
Walls for the clean room were constituted by appending either one of the vinyl chloride clothes to the wall surface, or disposing a partition for use in a clean room manufactured by COMMANY Co. (partition made of a steel sheet applied with bake coating at the surface).
(Air Filter)
As a filter medium for use in prefilters (P.F) and main filer (ULPA filter: U.F), three kinds of glass fiber filter mediums (1)-(3-) of different chemical compositions, filter medium made of polyester fibers and filter medium made of fluoro-fibers (PTFE fibers) were provided.
As the sealing material for securing the filter medium to the frame, polyurethane resin type sealing materials (1) and (2) and an epoxy resin type sealing material were provided. The polyurethane type sealing materials (1) and (2) are two component sealing material containing pure MDI 4-4′-Methylene (phenyl isocyanate) diisocyanate at high purity, manufactured by Nippon Polyurethane Industry Co.) as the main agent, and trioleyl phosphate was blended to the sealing material (1) and tributyl phosphate was blended to the sealing material (2) each by 0.3% by weight as the liquefing agent for MDI, other compositions being identical with those of the sealing materials (1) and (2).
A frame made of aluminum and having an inner size of 600×1200×100 was used.
The ULPA filter was attached to an opening of a clean room ceiling not using a gasket after the complete cure of the sealing material, while the prefilter was attached to an external air intake port of a duct directing to the ceiling after complete cure of the sealing material.
(Method of Analyzing Each of Constituent Materials)
Each of the surface materials of the floor material and the wall material, the filter medium and the sealing material for the air filter (three days after curing for the sealing material) used was cut out by a predetermined amount, subjected to qualitative analysis for organic substances and quantitative analysis for organic phosphorous compounds by the P&T-GC/MS method shown in Example 1, and the boron content was analyzed by the following method. The detection limit value of the quantitative analysis for the organic phosphorous compound by the method described above is 1.0 μg/g.
(Method of Analyzing Boron Content)
A cut out specimen was immersed in a predetermined amount of ultra-pure water (specific resistivity of higher than 18.6 MΩ) for 28 days, the ultra-pure water was introduced into an ICP/MS device (model HP-4500 of Hewlett Packard Co.), inorganic substances leached out in the ultra-pure water were analyzed and the content of boron was determined quantitatively by using a calibration curve prepared for an aqueous boric acid at a known concentration. The detection limit value for the quantitative analysis by the method is 0.1 μg/g.
(Evaluation of Clean Room)
In each of the clean rooms, external air (fresh air) passing the prefilters and return air from the inside of the clean room were mixed and sent to a chamber at the back of the ceiling, and then passed through the ULPA filters at the ceiling and supplied into the clean room, in which the mixing ratio between the return air and the fresh air was set to 10:1. Then, each of the clean rooms was operated continuously for two weeks at an air flow rate at the exit from the ULPA filter to 0.40 m/s, at a temperature of 23° C. and at a relative humidity of 40%, in an unattended state with nothing being placed at the inside and, subsequently, air in each of the clean rooms was taken out to analyze organic substances and inorganic substances contained in the air.
For the analysis of the organic substances, 40 liter of air in the clean room were introduced into a TENAX tube (trade name of Chromepack Co.) thereby adsorbing organic ingredients contained in the air. Then, the TENAX tube was installed to a TCT device (refer to Example 1), the organic ingredients adsorbed to the TENAX tube were taken out by the TCT device, heated and then introduced into the GC/MS device. The detection limit value for the quantitative analysis by this method is-10 ng/m3.
Inorganic substances were analyzed by introducing air in the clean room at a flow rate of 10 liter per min for 24 hours into an impinger containing 200 ml of ultra-pure water (specific resistivity of higher than 18.6 MΩ), leaching the inorganic ingredients contained in the air into the ultra-pure water, and introducing the ultra-pure water into the ICP/MS device (model HP-4500 of Hewlett Packard Co.). The detection limit value for the quantitative analysis by this method is 20 ng/m3.
The results for each of the analyses are also shown collectively in Tables 4 and 5.
As can be seen from the results, in the clean rooms of Nos. 21-24 corresponding to the embodiments of the present invention, analysis values for the organic phosphorus compounds and the boron compounds in the clean room air are below the detection limit values. Since the organic phosphorous compounds and the boron compounds are not present in the air at the inside of the clean rooms, such clean rooms are particularly suitable as those used for semiconductor production. On the contrary, the clean rooms Nos. 25-28 corresponding to the comparative examples of the present invention are not preferred since either the organic phos-phorus compounds or the boron compounds are present in the clean room air, and there is a worry of causing unnecessary doping as the clean room for semiconductor production.
In this Example 2, the ULPA filter is attached to the opening of the clean room ceiling without using the gasket. When an urethane rubber type gasket is used, it is desirable to use a phosphoric acid ester having 300 or more molecular weight as the liquefying material for diphenyl methane isocyanate, like that in the sealing material for securing the filter medium to the frame.
The wall material, the filter medium for the air filter (ULPA filter) and the sealing material for securing the filter medium and the frame of the air filter were used in the combination shown in Table 6 to fabricate each of local facilities for use in semiconductor production apparatus. Each of the constituent materials was analyzed in the same manner as in Example 2.
Then, each of the local facilities was placed in No. 21 clean room in Example 2 and air in the clean room (fresh air and return air mixed and passed through the ULPA filter in the clean room) was introduced into the ULPA filter of the local facility for Nos. 31 and 33. Further, for Nos. 32 and 34, only the fresh air was introduced into the ULPA filter of the local facility. In this way, after continuous two week operation of each of the local facilities in No. 21 clean room under the conditions described above, air in each of the local facilities was taken out and the organic substances and inorganic substances contained in the air were analyzed in the same manner as in Example 2.
The results for each analysis were also shown in Table 6.
As can be seen from the results, in the local facilities of Nos. 31 and 33 corresponding to the embodiments of the present invention, analysis values for the organic phosphorus compounds and the boron compounds in the air at the inside of the local facilities are below the detection limit values and, since the organic phosphorus compounds and ,the boron compounds are not present in the local facilities, such local facilities are particularly suitable as the local facility for use in semiconductor production. On the contrary, the local facilities of Nos. 32 and 34 corresponding to the comparative examples of the present invention are not desired, since either the organic phosphorus compounds or the boron compounds are present in the air at the inside of the local facilities and there if a worry of causing unnecessary doping-for the local facility used in the semiconductor production.
Also in this Example 3, the ULPA filter is attached to the ceiling opening of the local facility without using gaskets. In a case of using urethane rubber type gaskets, it is desirable to use a phosphoric acid ester having 300 or more weight as the liquefying material for the diphenyl methane isocyanate like that in the sealing4material for securing the filter medium to the frame.
An MOS diode such as an MOS capacitors and an MOSFET (Metal Oxide Field Effect Transistor) in which a gate oxide film and a gate electrode are formed successively on a semiconductor substrate constitutes a basic structure of a semiconductor device. If organic substances are adsorbed on the gate oxide film, it is considered that voltage withstanding characteristics of the oxide film are deteriorated. This is described in the following documents (a)-(d). Further, the following document (e) describes that the yield of the semiconductor devices is lowered when the voltage withstanding characteristics are deteriorated.
In the following Examples 4 and 5, circumstance between the gate oxide film forming step and the gate electrode forming step were changed and the voltage withstanding characteristics of the gate oxide film constituting the MOS diode were investigated. When the gate oxide film has favorable voltage withstanding, the production yield of semiconductor devices (products including semiconductor circuits) can be improved.
(a) “Influence of Organic Contaminant on Breakdown Characteristics of MOS Capacitors with Thin SiO2”, by Takenobu Yoshio, Shin Yokoyama, Tsukuru Suzuki and Toshiaki Fujii; cited from Extended Abstracts of the 2000 International Conference on Solid State Devices and Materials, Sendai, 2000, pp 552-553.
(b) “Organic Contaminant of silicon Wafer in Clean Room Air and its Impact to Gate Oxide Integrity”, by D. Imafuku, W. Mizubayashi, S. Miyazaki, M, Hirose, Y. Wakayerna, S. Kobayashi; cited from Symposium Proceedings Volume 477, Science and Technology of Semiconductor Surface Preparation.
(c) “The Effect of Organic Compounds Contamination on the Electrical Characteristics of Ultra-Thin Gate Oxide Films”, by Yoshihide WAKAYAMA, Takeshi OHKAWA, Osamu NAKAMURA, Sadao KOBAYASHI, Shigetoshi SUGAWA, Herzl AHARONI, Tadabiro OHMI; cited from Extended Abstracts of 2000 International Conference on Solid State Devices and materials, Sendai, 2000, pp. 550-551.
(d) “Evaluation for Organic Materials Adsorbed on Wafer Surface and Application Thereof”, Ayako Shiinazaki, Makiko Tamaoki, Hiromi Sasaki and Tsuyosi Matsumura; cited from Pretext No. 2 of 39th Associated Symposium of Applied Physics (1992, Spring), page 686.
(e) “Chemical Contamination in Semiconductor Process Circumstance and Countermeasure Therefor” (from Realize Co, issued Oct. 31, 1997) pp 19-41.
Three n-type silicon wafers (semiconductor substrates) each of 6 inch diameter were provided. At first, the wafers were put in a thermal oxidation furnace to form silicon oxide films on the surface of each wafer.
PSG (Phospho Silicate Glass) film (silicon oxide film with addition of phosphorus oxide) was formed on the rear face of each wafer (the face on the side opposite to the surface where the oxide film was formed).
Then, photolithography and etching were conducted to remove the silicon oxide film on each wafer by a predetermined pattern to expose a capacitance forming portion of the upper surface of the wafer (at 100 places).
Then, each wafer formed a gate oxide film of 5 nm thickness at an exposed portion on the upper surface of each wafer. All the steps described above were conducted in the No. 1 clean room of Example 1.
Then, after taking each wafer out of the dry oxidation apparatus, one of them (No. 41: sample for example) was left as it was in No. 1 clean room of Example 21 for 24 hours. One of the remaining two wafers (No. 42: sample for reference) was left for 24 hours being put in a argon box where the inside was a argon atmosphere at high concentration. The remaining one (No. 43: sample for comparative example) was placed in another argon box and, after transportation to No. 7 clean room of Example 1, taken out of the argon box and left in the clean room for 24 hours.
Then, the wafers were loaded in the CVD apparatus and an n-type polysilicon film (gate electrode) was formed on the gate oxide film. Then, an aluminum electrode for a terminal was formed at a predetermined position of the polysilicon film on each wafer by a vacuum vapor deposition method. Then, MOS capacitors (MOS diodes) were cut out by the number of 100 from each of three wafers.
To thus obtained three kinds of MOS capacitors by the number of 300 which were different in the sample leaving circumstance between the gate oxide film forming step and the gate electrode forming step (100 for each circumstance), an electric field was applied and the change in the current density with increase of the electric intensity was examined. It has been known that a normal MOS capacitor provides a normal curve in which the current density is constant at about 1×10−9A/cm2 at an electric field intensity of about 6 MV/cm, the current density increases when the electric field intensity exceeds 6 MV/cm and the current density converges at about 10 A/cm2 when the electric field intensity reaches about 13 MV/cm.
Among Nos. 41 to 43 samples, in No. 43 sample (left in No. 7 clean room of Example 1), the electric field intensity was 10 MV/cm and the current density increased abruptly being deviated from the normal curve in 40 out of 100 MOS capacitors. That is, breakdown occurred at an electric intensity of 10 MV/cm. On the other hand, in the samples for No. 41 (left in No. 1 clean room of Example 1) and No. 42 (left in nitrogen box), no breakdown occurred even at an electric field intensity of 13 MV/cm for all of 100 MOS capacitors.
That is, it has been found that MOS capacitors comparable with the reference and having no problem in the performance are obtained when the sample leaving circumstance between the gate oxide film forming step and the gate electrode forming step is inside the No. 1 clean room of Example 1, but MOS capacitors of low performance are tended to be obtained when the sample leaving circumstance is inside the in No. 7 clean room of Example 1.
No. 7 clean room of Example 1 provides such a circumstance that the amount of organic substances adsorbed on the upper surface of the 6 inch silicon wafer left for six hours reaches 586 ng (3.21 ng/cm2) as shown in Table 2. Further, in the clean room, C12-C18 aliphatic hydrocarbons, Si3-Si10 siloxanes, dioctyl phthalate, 2,6-di-t-butyl-p-cresol, tributyl phosphate and the like are released from the filter medium and the sealing material that constitute the air filter and the gasket into the clean room, and such organic substances are adsorbed on the wafer.
On the other hand, No. 1 clean room of Example 1 provides such a circumstance that the amount of organic materials adsorbed on the upper surface of the 6 inch silicon wafer left for six hours is 28 ng (0.153 ng/cm2) as shown in Table 1. Further, since the organic substances as described above are not released from the filter medium and the sealing material that constitute the air filter and the gasket, there is no adsorption of such organic substances on the wafer.
Accordingly, it is supposed that the performance of MOS capacitors is deteriorated when the organic substances are adsorbed on the upper surface of the wafer after forming the gate oxide film and before forming the gate electrode.
From the foregoings, it can be seen that MOS diodes with no deterioration of the performance caused by organic substances can be obtained in the production process for MOS diodes such as MOS capacitors or MOSFETs (metal oxide semiconductor field effect transistor) by conducting the gate oxide film forming step and the gate electrode forming step in a circumstance that the amount of organic substances adsorbed on the upper surface of a 6 inch silicon wafer left for 6 hours is 50 ng (0.274 ng/cm2) or less.
Further, the circumstance described above can be obtained where the amount of the gaseous organic substances released from the filter medium constituting the air filter used in a clean room and a local facility is reduced to 10 μg or less per 1 g of the sample when heated at 150° C. for 30 min by a purge & trap method and the amount of the gaseous organic substances released from the sealing material constituting the air filter is reduced to 50 μg or less per 1 g of the sample when heated at 150° C. for 30 min by a purge & trap method, or in a case where the amount of gaseous organic substances released from the gasket is reduced to 50 μg per 1 g of the sample when heated at 150° C. for 30 min by a purge & trap method when the air filter is attached to a support frame of a ceiling of the clean room constituting an opening in the presence of a gasket between the air filter and the support frame, as in Nos. I to 5 Example 1.
At first, the step of forming the gate oxide film to three silicon wafers was conducted in the same method as in Example 4. However, all of the steps were conducted in No. 21 clean room of Example 2. In the clean room, a wafer stocker (local facility) A of the same constitution as the local facility No. 32 of Example 3 and a wafer stocker B of the same constitution as the local facility No. 34 of Example 3 were located.
Since the wafer stocker B has the same constitution as No. 34 local facility of the Example 3, boron is contained at a concentration of 105 ng/m3 and tributyl phosphate is contained at a concentration of 250 ng/m3 in air at the inside as shown in Table 6. On the contrary, since the wafer stocker A has the same constitution as No. 32 local facility of Example 3, boron and organic phosphorus compounds are not contained in air at the inside as shown in Table 6.
Then, just after taking each wafer out of the dry oxidation apparatus, one of the three wafers (No. 51: sample for example) was stored for 24 hours in the wafer stocker A. One of the remaining two wafers (No. 52: Sample for reference) was placed in a nitrogen box where the inside is a nitrogen atmosphere at a high concentration and stored for 24 hours. The remaining one (No. 53: sample for comparative example) was stored for 24 hours in the wafer stocker B.
Then, the wafers were loaded in the CVD apparatus disposed in No. 21 clean room of Example 2 and, after forming the polysilicon film and the aluminum electrode by the same method as in Example 4, MOS capacitors (MOS diodes) were cut out by the number of 100 from each of three wafers.
To thus obtained three kinds of MOS capacitors by the number of 300 which were different in the stock circumstance between the gate oxide film forming step and the gate electrode forming step (100 for each circumstance), an electric field was applied and the change in current density with increase of the electric field was examined.
Among Nos. 51 to 53 samples, in No. 53 sample (stored in wafer stoker B), 40 out of 100 MOS capacitors were deviated from a normal curve at an electric field intensity of 10 MV/cm and the current density increased abruptly. That is, breakdown was caused at an electric field intensity of 10 MV/cm. On the contrary, in No. 51 sample (stored in wafer stocker A) and No. 52 sample (stored in nitrogen box), breakdown was not caused in all of 100 MOS capacitors even at an electric field intensity of 13 MV/cm.
As described above, it has been found that MOS capacitors comparable with the reference and having no problem in the performance can be obtained when stored in the wafer stocker A between the gate oxide film forming step and the gate electrode forming step, but MOS capacitors of low performance tend to be obtained when stored in the wafer stocker B. That is, it is considered that since tributyl phosphate is present in the wafer stocker B, tributyl phosphate is adsorbed on the upper surface of the wafer after forming the gate oxide film to lower the performance of the resultant MOS capacitor in No. 53 stored in the wafer stocker B.
From the foregoings, it can be seen that MOS diodes with no lowering of the performance caused by organic substances can be obtained in the method of manufacturing MOS diodes such as MOS capacitors and MOSFETs (Metal Oxide Semiconductor Field Effect Transistor), in a case where the gate electrode is not formed directly after forming the gate oxide film, by storing the surface material of the wall and the filter medium and the sealing material that constitute the air filter in a local facility (such as wafer stocker) in which the amount of gaseous organic phosphorus compounds released when heated at 150° C. for 30 min by the purge & trap method is 10 μg or less per 1 g of the material and the boron compounds leached by being immersed in super pure water for 28 days is 20 μg or less per 1 g of the material.
As described above according to the air filter of the present invention, since the releasing amount of gaseous organic substances can be decreased in the clean room or the local facility having the filter disposed to an air introduction path, the air filter according to the present invention is suitable to a clean room or a local facility, for example, of semiconductor production factories.
Then, since the releasing amount of the gaseous organic substances is reduced in the clean room and the local facility according to the present invention having the air filter described above, if the clean room or the local facility (semiconductor production apparatus) is used, for example, in the industry of semitonductor production, the adsorption amount of the organic substances to silicon wafers is decreased to improve the yield.
Further, since unnecessary doping to silicon wafers may not be caused in the clean room and the local facility of the present invention in which t he organic phosphorus compounds and boron compounds are not present, they are particularly suitable to the clean room and the local facility for use in semiconductor production.
| Number | Date | Country | Kind |
|---|---|---|---|
| 7-192090 | Jul 1995 | JP | national |
This application is a Continuation-in-Part of U.S. Ser. No. 09/736,647 filed Dec. 13, 2000, now U.S. Pat. No. 6,471,740, which is itself a continuation of U.S. Ser. No. 09/405,756, filed Sep. 27, 1999, now U.S. Pat. No. 6,293,982, which is itself a divisional of U.S. Ser. No. 08/817,007, filed Mar. 27, 1997, now U.S. Pat. No. 5,997,598, which was filed under 35 U.S.C. 371 as the national stage application of PCT/JP96/02076, filed Jul. 25, 1996, and published as WO97/04851 on Feb. 13, 1997.
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| Number | Date | Country | |
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| Number | Date | Country | |
|---|---|---|---|
| Parent | 08817007 | Mar 1997 | US |
| Child | 09405756 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 09405756 | Sep 1999 | US |
| Child | 09736647 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 09736647 | Dec 2000 | US |
| Child | 10093587 | US |
