Alloy used for production of a rare-earth magnet and method for producing the same

Description

BACKGROUND OF INVENTION
1. Field of Invention
The present invention relates to an alloy, which becomes the raw material of a rare-earth containing magnet, and to a production method of the same. In a two-alloy mixing method being used for the production of high-performance Nd--Fe--B magnet, two alloys, i.e., an alloy having a composition close to the stoichiometric Nd.sub.2 Fe.sub.14 B (main-phase alloy), on which the magnetism is based, and an alloy having high concentration of a rare-earth element (boundary-phase alloy) are mixed. The alloy according to the present invention is pertinent as the latter alloy.
2. Description of Related Art
All of the Nd--Fe--B magnets usually produced industrially have somewhat richer rare-earth composition than the stoichiometric Nd.sub.2 Fe.sub.14 B composition. A phase (referred to as the R rich phase) having high concentration of a rare earth element (R), such as Nd, is therefore formed in the ingot of the magnet alloy.
It is known that the R-rich phase plays an important role as follows in the Nd based magnet.
(1) The R-rich phase has a low melting point and hence is rendered to a liquid phase in the sintering step of the magnet production process. The R-rich phase contributes, therefore, to densification of the magnet and hence enhancement of remanence.
(2) The R-rich phase eliminates the defects of the grain boundaries of the R.sub.2 T.sub.14 B phase, which defects lead to the nucleation site of the reversed magnetic domain. The coercive force is thus enhanced.
(3) Since the R-rich phase is non-magnetic and magnetically isolates the main phases from one another, the coercive force is thus enhanced.
Development of the Nd--Fe--B magnet implemented in recent years is to furthermore enhance the magnetic properties, particularly the energy product (BH) max. Since it is necessary to increase the volume fraction of the Nd.sub.2 Fe.sub.14 B phase, on which the magnetism is based, in such high-performance magnet, the magnetic composition must be close to the stoichiometric composition. The R-rich phase becomes correspondingly so small that the above effects (1) through (3) are diminished. It is thus extremely difficult to enhance the coercive force. The high-performance Nd magnet contains, therefore, a very small amount of the R-rich phase, which is active and liable to be seriously oxidized. When the R-rich phase is oxidized in the production process of a magnet, the properties of the magnet are thus liable to deteriorate. In other words, the permissible oxygen amount is lower as the performance of the magnet becomes higher.
The two-alloy mixing method is a recent proposal to solve the problems as described above. The two-alloy mixing method is that the main-phase alloy, the composition of which is close to the stoichiometric Nd.sub.2 Fe.sub.14 B phase on which the magnetism is based, and the boundary-phase alloy having high concentration of a rare-earth element, which alloy is rendered to a liquid phase at sintering to promote sintering and subsequently forms the boundary phase, are prepared separately, and then simultaneously finely crushed or separately crushed followed by mixing. Subsequently, the sintering is carried out by a conventional method.
It is possible to enhance the volume fraction of the boundary-phase alloy in the two-alloy mixing method and to improve the fine dispersion property of the R-rich phase. The oxidation of the more oxidizable boundary-phase alloy than the main-phase alloy during the magnet production process can be prevented by means of adding Co having a chemically stabilizing effect to the boundary-phase alloy prepared in the two-alloy mixing method. This effect is furthermore enhanced by means of adding Co of increased concentration. It is thus possible to produce an improved magnet with low oxygen.
Production of the boundary-phase alloy by means of a conventional ingot-casting method or a super-quenching method is known. No matter which method is employed for producing a boundary-phase alloy, the resultant alloy must be finely crushed by the conventional method. However, the boundary-phase alloy contains a rare-earth element in higher concentration than that contained in the magnet alloy prepared by the conventional single-alloy method; hence, a new phase, which deteriorates the crushability, evolves in the former alloy. The boundary-phase alloy prepared by the heretofore proposed method exhibits extremely poor fine crushability as compared with the magnet alloy produced by the conventional single-alloy method. An important task, therefore, is to improve the crushability of the boudary-phase alloy.
The fine-crushing step comprises the greatest proportion of the cost of the magnet production process and is also important because the properties of the magnet are greatly influenced by such step as follows. Unless the post-crushing average grain-size and distribution of grain size are adequate, the dispersion of the boundary-phase alloy becomes so non-uniform in the magnet alloy that promotion of the liquid phase sintering, and hence high densification of the magnet alloy, become difficult. It also becomes difficult to attain the relatively fine and uniform grain-size which is necessary for obtaining a high performance magnet. It seems that the morphology of the R.sub.2 T.sub.14 B and R.sub.2 T.sub.17 phases contained in the boundary-phase alloy, such as the volume fraction, size and the like of such phases, plays an important role in the crushability of the boundary-phase alloy. It also seems that the morphology of a richer R-phase (an intermediate phase) than the R.sub.2 T.sub.17 phase contained in the boundary-phase alloy is influenced by the morphology of the R-rich phase and plays a role to a less important extent in the crushability of the boundary-phase alloy. It is impossible by means of either the conventional ingot-casting method or the rapid-cooling method to control the morphology of such phases and hence to form a structure attaining improved crushability.
SUMMARY OF INVENTION
It is an object of the present invention to solve the above-described problems and hence to provide a boundary-phase alloy pertinent to the production of a high-performance rare-earth based magnet alloy by means of a two-alloy blending method. That is, an alloy, which has improved crushablity, i.e., the most important property in the magnet-production process, is provided.
It is another object of the present invention to solve the above-described problems and hence to provide a method for producing a boundary-phase alloy pertinent to the production of a high-performance Nd-based magnet alloy by means of a two-alloy blending method.
The centrifugal casting method is industrially established as a method for producing tubular castings. In the centrifugal casting method, the melt-feeding method, the casting speed, the cooling method and the like are devised in the present invention, to enable production of a boundary-phase alloy having little segregation and improved crushability. The centrifugal casting method is applied for producing a rare-earth magnet alloy, for example, in Japanese Unexamined Patent Publication No. Hei 1-171,217. This method provides, however, tubular castings which are used as a magnet as they are, and are, therefore, unrelated to the crushing. This publication does not mention at all a technique, according to which the boundary-phase alloy with little segregation and improved crushability, can be produced by means of controlling the casting speed and the like.
In the present invention, influence of the alloy structure upon the fine crushability, which is the most important in the magnet production process, is elucidated in detail. As a result, it was discovered that, among the constituent phases of the boundary-phase alloy, the volume fraction and size of the R.sub.2 T.sub.17 phase and the R.sub.2 T.sub.14 B phase exerts great influence upon the fine crushability of the boundary-phase alloy. Thus, the inventive alloy was developed.
More particularly, the present invention is related to an alloy used for the production of a magnet alloy, wherein the alloy consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy and Pr, 1% by weight or less of B and the balance being Fe, the volume fraction of the R.sub.2 T.sub.17 phase and the R.sub.2 T.sub.14 B phase is 25% or more in the alloy and, further, the average size of R.sub.2 Fe.sub.17 phase is 20 .mu.m or less. More preferably, the alloy consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy and Pr, and at least one element selected from the group consisting of 35% by weight or less of Co, 4% by weight or less of Cu, 3% by weight or less of Al and 3% by weight or less of Ga, and the balance being Fe, the volume fraction of the R.sub.2 T.sub.17 phase (T is Fe or Fe, a part of which is replaced with at least one element selected from the group consisting of Co, Cu, Al and Ga) is 25% or more in the alloy and, further, the average size of the R.sub.2 Fe.sub.17 phase is 20 .mu.m or less.
The invention of the production method is related to a method for producing an alloy used for the production of a rare-earth magnet, comprising the steps of:
preparing an alloy-melt (a) which consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy and Pr, and the balance being Fe, and the alloy melt (b), which consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy and Pr, 1% by weight or less of B, and the balance being Fe;
feeding the alloy melt into a rotary tubular mold having an inner surface and onto one or more predetermined portions of the inner surface;
rotating the rotary tubular mold around its longitudinal central axis;
accumulating the alloy melt onto the inner surface of the mold at an average rate of 0.1 cm/second or less; and,
centrifugally casting the alloy melt being accumulated at said average rate. The alloy may further contain at least one element selected from the group consisting of 35% by weight or less of Co, 4% by weight or less of Cu, 3% by weight or less of Al and 3% by weight or less of Ga.
According to an embodiment of the present invention, the cast melt is brought into contact with an inert gas-containing atmosphere, preferably containing 20% or more of helium.
According to another embodiment, a cooling gas, which comprises an inert gas, is blown onto the inner surface of the rotary tubular mold, during the centrifugal casting.
A rare-earth magnet alloy can be produced according to the present invention by the method comprising the steps of:
crushing a first alloy produced by the method of the present invention;
preparing a second alloy having a composition of essentially R.sub.2 Fe.sub.14 B;
crushing the second alloy; and,
mixing the powder of first and second alloys.
In the alloy composition according to the present invention, at least one rare-earth element (R) selected from the group of Nd, Dy and Pr is 35% by weight or more, so as to attain advantages of the two-alloy mixing method and to appreciably distinguish the composition from that of the single-alloy method. On the other hand, the rare-earth element (R) is 60% by weight or less, because the activity of the alloy becomes so drastically high at more than 60% by weight of the rare-earth element that the alloy becomes difficult to handle due to oxidation. Furthermore, the ductility is so increased as to make the crushing extremely difficult.
Co is an element that suppresses the oxidation of the boundary-phase alloy and also improves the temperature dependency of the remanence of the sintered magnet. The Co content is, however, preferably 35% by weight or less, because the coercive force of the magnet is lowered at more than 35% by weight of Co.
The stoichiometric composition of Nd.sub.2 T.sub.14 B, on which the magnetism of the complete magnet is based, corresponds to just 1.00% by weight of B. Such B may be added to the boundary-phase alloy without incurring any problem. The R.sub.2 T.sub.14 B, which is formed in the boundary-phase alloy due to the B addition, refines the structure and contributes to enhancement of the crushability. For this purpose the addition of B is necessary. The addition amount of B is preferably 0.01% by weight or more. However, when the addition amount of B exceeds 1% by weight, it becomes necessary to decrease the B content of the main-phase alloy, i.e., one of the two materials. In such a case, the Fe phase is liable to form when the main-phase alloy is melted and cast. As a result, the fine crushability of the main-phase alloy is impaired and the magnetic properties of the sintered magnet are lowered. The B content of the boundary-phase alloy must, therefore, be 1% by weight or less.
Cu has an effect of minimizing the temperature dependency of the coercive force in the heat treatment which may be carried out subsequent to the sintering in the final magnet production process. Since the coercive force of the Co-added alloy sharply depends on temperature to show a peak, when such alloy is heat-treated in a furnace having temperature distribution, the coercive force becomes unstable, so that the production control becomes difficult. When Cu is further added to the Co-added alloy, the temperature dependence of the coercive force is minimized. The Cu addition enables, therefore, stable enhancement of the coercive force. Furthermore, the Cu addition lowers the melting point of the boundary-phase alloy, thus the liquid-phase sintering is promoted. The Cu content is, however, preferably 4% by weight or less, because the remanence of a sintered magnet becomes low at more than 4% by weight of Cu.
Al and Ga improve the coercive force as well. The content of Al and Ga is preferably 3% by weight or less, because the remanence of a sintered magnet becomes low at more than 3% by weight of Al and Ga.
It was discovered that the total volume fraction and size of R.sub.2 T.sub.17 phase and R.sub.2 T.sub.14 B phase, which are the constituent phases of boundary-phase alloy, are greatly changed depending upon the casting method and conditions of the boundary-phase alloy. The R.sub.2 T.sub.17 phase and R.sub.2 T.sub.14 B phase are the R.sub.2 Fe.sub.17 and R.sub.2 Fe.sub.14 B, respectively, when the boundary-phase alloy consists of a rare-earth element (R), Fe and B. The R.sub.2 T.sub.17 phase and R.sub.2 T.sub.14 B phase are the R.sub.2 Fe.sub.17 and R.sub.2 Fe.sub.14 B, Fe of which may be partly replaced with Co, Cu, Al or Ga, when the boundary-phase alloy contains these elements.
It was discovered that the fine crushability is improved when the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phase is 25% or more and the respective phase has average size of 20 .mu.m or less. It was furthermore discovered that, under such structure a phase (hereinafter referred to as the "intermediate phase"), which has an intermediate R content between those of the R.sub.2 T.sub.14 B phase and the most R-rich phase, is decreased and finely divided and, this fact improves the crushability. Therefore, the total volume fraction of the R.sub.2 T.sub.17 phase and the R.sub.2 T.sub.14 B phase is set at 25% or more, and average size of R.sub.2 T.sub.17 phase and the R.sub.2 T.sub.14 B phase is set at 20 .mu.m or less in the present invention. Desirably, the total volume fraction of the R.sub.2 T.sub.17 phase and the R.sub.2 T.sub.14 B phase is set at 30% or more. The R.sub.2 T.sub.17 phase and the R.sub.2 T.sub.14 B phase are desirably 2 .mu.m or more in size, because at finer size the finely crushed powder is not single crystalline and hence the orientation degree tends to be low in the compacting step under magnetic field.
The size of the R.sub.2 T.sub.17 phase and the R.sub.2 T.sub.14 B phase can be determined for example as follows. A structure-observing photograph by an electron microscope (back-scattered electron image) is used to obtain the number "n" of the phases, which are cut by perpendicular two line segments, and the total length L of the line segments overlapping the phases, and the .SIGMA. L/n is calculated, like the cutting method illustrated in JIS G 0552.
As a result of analysis of the intermediate phases by using EDX and XRD, it turned out that the intermediate phases are formed variously depending upon the alloy composition, such as R.sub.5 T.sub.17, R.sub.1 T.sub.3, R.sub.1 T.sub.2 and the like.
The melting and casting method is now described. According to the present invention, pure metals, such as a rare-earth element, or mother alloys are melted to provide an alloy under vacuum or an inert-gas atmosphere, such as Ar, as in the conventional method. The melting furnace is not specifically limited. For example, an ordinarily used vacuum induction furnace may be used. The casting after melting is carried out by centrifugal casting. The centrifugal casting apparatus consists basically of a rotary driving mechanism and a tubular mold, as in an apparatus usually used for producing steel tubes or the like. The shape of a mold can be determined by considering the operability, such as easiness in constructing a plant, casting, mold-maintenance and setting, and withdrawal of a cast ingot, while the microstructure of an ingot, which is important in the present invention, is not influenced by the shape of a mold. The mold has appropriately an inner diameter of 200 mm or more and length five times or less the inner diameter of the mold, taking into consideration of the above factors.
The rotary speed of a mold may practically be such that the melt does not fall down upon arrival at the top, that is, the rotary speed generates at least 1 G of accelerating speed. When the centrifugal force is further increased, the cast melt is liable to spread over the mold wall, thereby enhancing the cooling effect and hence the structure homogenity. In order to achieve these effects, the rotary speed is so set to attain 3 G or more, preferably 5 G or more.
The melt-feeding rate at the casting is extremely important for the following reasons and is set at a condition completely different from that for obtaining ordinary tubular castings. In the ordinary centrifugal casting, the melt retains the molten state, while it is caused to flow in the longitudinal direction at uniform thickness. In addition, the casting completes in a short period of time so as to avoid the formation of casting defects, such as cold shut.
It is important in the present invention for the previously fed melt into the mold to start to solidify before the succeeding feed of melt. The average accumulating rate of melt onto the inner surface of a mold should desirably be lower. Specifically, the average accumulating rate is 0.1 cm/second or less, desirably 0.05 cm/second or less. The lower limit of average melt-accumulating rate is desirably approximately 0.005 cm/second in the light of productivity or the like. The average accumulating rate is an increasing rate of the thickness of the casting and is expressed by M/S, in which the melt-feeding amount (volume) per unit time (M) is divided by the total area (S) of mold inner-surface (the area where the melt is fed). By means of casting under such condition, the already cast melt starts to solidify before the next melt is fed. That is, the vicinity of the surface of the cast-metal layer is always under the semi-solidified state. An alloy ingot with fine structure and little segregation can be obtained. Particularly in the case of a boundary-phase alloy used for producing a high-performance Nd magnet, the R.sub.2 T.sub.17 phase and the R.sub.2 T.sub.14 B phase are of increased total volume fraction and are finely dispersed. This results in division of the intermediate phases. An ingot having improved crushability can, therefore, be produced.
Melt must be fed at an amount per unit time exceeding a certain level of flowability such that the melt does not clog the melt-feeding port and trough for feeding the melt onto the inner surface of a mold in the centrifugal casting apparatus. However, along with expansion of the scale of a plant, the melting amount and hence the total area of the mold are increased. It is, therefore, technically easy to set the average accumulating rate at a low value, even without decreasing the feeding amount of melt. Furthermore, the melt can be more thinly fed onto the inner surface of a mold and hence the growth of solidification layer can be promoted by means of feeding the melt onto the inner surface of a mold from two or more nozzles, or reciprocating the feeding port of melt in the longitudinal direction of a mold during casting.
The casting atmosphere should be inert gas such as argon, helium or the like, or a mixture of these gases. Since particularly helium has a high heat conductivity, it enables to increase the cooling rate of melt and ingot. Helium is, therefore, effective for increasing the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases and refining these phases. Desirably, the casting is carried out in an inert-gas atmosphere which contains 20% or more of helium, so as to realize the above described effects.
Furthermore, the cooling effect of a mold can be enhanced and hence the solidification can be promoted by means of blowing, during casting, inert gas toward the inner surface of a mold through a gas-cooling nozzle provided in the inner space of a mold. Such a cooling equipment is easy to install within a mold, since a thorough space is provided within the mold of a centrifugal casting apparatus. Inert gas such as argon, helium or the like or mixture of these gases can be used as the blowing gas. Also in this case, pure helium or a helium-containing gas having a high mixture ratio of helium can enhance the cooling rate.
A cast ingot is usually crushed and used for producing a sintered magnet. For crushing, the crusher such as a jet mill, a ball mill or a vibrating mill is used to obtain fine powder approximately from 2 to 6 .mu.m, preferably from 3 to 5 .mu.m in size.
A coating agent is usually preliminarily applied in an apropriate amount onto the inner-surface of a mold in the centrifugal casting method for producing a tubular casting alloy, so as to prevent erosion of the mold, to improve the surface quality and permit easy withdrawal of the cast ingot. The coating agent is also applied on the inner surface of a mold in the case of most conventional casting method of rare-earth magnet alloy as well. Since the coating agent is applied with the aid of a water-containing binder, the coating agent must be thoroughly dried before using. Otherwise, the coating agent may be incorporated in the alloy and hence incurs the possibility of detrimental effect on the magnetic properties of a magnet.
Since there is no danger of mold erosion according to the method of the present invention, in which the thermal load per unit surface area of the mold is low, a coating agent is, therefore, not necessarily used in the present invention. The application and drying of the coating agent, the cost of which impedes cost reduction effort, can, therefore, be omitted. The method according to the present invention is, therefore, appropriate as the industrial process.
In the centrifugal casting, a sufficient space is left within a mold even after the casting once terminates. Since it is not an objective of the present invention to obtain a cast tube having a predetermined thickness, the cast product may not be withdrawn out of the mold upon termination of each casting operation. Instead, the next operation can be initiated such that the raw materials of the next batch are loaded and then melted in a crucible, and, then, the laminate casting on the inner surface of the already cast alloy ingot may be implemented. This method decreases such work as preparation of a metallic casting mold, withdrawal of an ingot and the like. The working efficiency can, thus, be enhanced.
The examples of the present invention and the comparative examples are hereinafter described with reference to the following drawings.

BRIEF DESCRIPTION OF DRAWINGS
FIG. 1 is a general view of the centrifugal casting apparatus used in the examples.

EXAMPLES
Examples 1-4
The raw-material alloys were blended to provide the compositions given in Table 1 and melted in a high-frequency vacuum-induction furnace using an alumina crucible under a low-pressure argon-gas environment at 200 torr. Helium gas was admitted, directly before the casting, into the furnace to attain the atmospheric pressure in the furnace. For the casting, the centrifugal casting apparatus shown in FIG. 1 was used. The inner diameter and length of the mold were 500 mm and 1000 mm, respectively. The casting was carried out at an average accumulating rate of melt of 0.03 cm/second.
In FIG. 1, 1 denotes the vacuum chamber, in which the crucible 2, the primary stationary tundish 3a, the secondary reciprocating tundish 3b and the rotary tubular mold 4a are equipped. The rotary tubular mold 4a is rotated by a rotary driving mechanism 6. The melt is caused to flow from the crucible 2 through the primary stationary tundish 3a to the secondary reciprocating tundish 3b. The melt was poured from it into the rotary tubular mold 4a to form an ingot 5 on the inner surface of rotary tubular mold 4a. The rotation speed of the rotary tubular mold 4a was set at 267 rpm to attain the centrifugal accelerating force of 20 G. The secondary reciprocating tundish 3b, on which the melt-feeding ports 7 were provided at a distance of 7 cm, was reciprocated in a longitudinal direction of the mold at a stroke of 6 cm and once per second. Thickness of the resultant alloy ingots was 5-6 mm in each case.
Furthermore, the cross-sectional microstructure of the alloy ingots was observed with a back-scattered electron image by using a secondary electron microscope and the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases and the average size of the respective phases were measured by an image analyzer. The results are shown in Table 1.
Each alloy-ingot had a total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases more than 25% and good microstructure.
The respective alloy ingots were crushed in argon gas to approximately 5 mm. The powder was held for 1 hour in hydrogen gas at room temperature, then heat-treated at 600.degree. C. under vacuum and crushed by a Brown mill in nitrogen gas to the size under 35 mesh. The crushed powder was further milled by a jet mill in the nitrogen gas at a feed rate of 80 g/min. The average particle size of jet-milled powder was measured by a Fisher-type sub-sieve sizer. The results are shown in Table 1. The average particle esize of the jet-milled particles from each alloy ingot was less than 4 .mu.m.
The crushability is defined by A/80, in which A is the feeding rate in g/min, at which rate the average particle size of 3.5 .mu.m is obtained, and is divided by 80 g/min. The crushability indicates, therefore, the crushing efficiency. The greater A/80 is, the better the crushing efficiency, while the crushing efficiency is worse at a value of A/80 closer to zero. The crushability of Examples 1 through 4 is indicated in Table 1. The crushability of each alloy ingot is improved.
Comparative Examples 1-4
The raw-material alloys were blended to provide the same compositions as in Examples 1-4, and were melted in a high-frequency vacuum-induction furnace using an alumina crucible under a low-pressure argon-gas environment at 200 torr. Argon gas was admitted, directly before the casting, into the furnace to attain the atmospheric pressure in the furnace. The melt was then cast into a box-type mold made of iron to form a 20 mm-thick ingot having the compositions as shown in Table 2.
The cross-sectional microstructure of the alloy ingots was observed with a back scattered electron microscope and the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases and the average size of the respective phases were measured by an image analyzer. The results are shown in Table 2. Each alloy-ingot had a total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases less than 25%. This microstructure cannot be said to be improved.
The resultant alloy-ingots were crushed and milled by the same method as in Examples 1 through 4. The crushability is mentioned in Table 2. The average particle size of the respective jet-milled alloy ingots was 4 .mu.m or more. The crushability is poor.
Examples 5-7
The alloy ingots having the compositions shown in Table 1 were produced by the same centrifugal casting method as in Examples 1 through 4. However, the gas, which was admitted, directly before the casting to attain the atmospheric pressure, was argon gas. In addition, in Examples 6 and 7, helium gas was continuously blown toward the inner surface of a mold, from the start of casting until thorough cooling of the alloy ingot. Thickness of the resultant alloy ingots was 5-6 mm in each case.
The cross-sectional microstructure of the respective alloy ingots was observed with a back-scattered electron microscope by an image analyzer. The total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases and the average size of the respective phases were measured. The results are shown in Table 1.
Each alloy-ingot had a total volume fraction of the R.sub.2 T.sub.17 phase more than 25% and an improved microstructure.
The respective alloy ingots were crushed and milled under the same conditions as in Examples 1-4. The average particle size of jet-milled powder was measured by a Fisher-type sub-sieve sizer. The results are shown in Table 1. The crushability defined in Examples 1 through 4 is also shown in Table 1. The average particle size of the jet-milled powder was less than 4 .mu.m in each alloy ingot. The crushability is also improved.
Comparative Examples 5-7
The alloy ingots having the compositions shown in Table 2 were produced by the same method as Comparative Examples 1 through 4, in which the melt was cast into a box mold made of iron to form 20 mm-thick ingots.
The cross-sectional microstructure of the respective alloy ingots was observed with a back-scattered electron microscope. The image of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases were formed by an image-analyzer. The total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases and the average size of the respective phases were investigated. The results are shown in Table 2.
Each alloy-ingot had a total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases less than 25%. It cannot be said that the microstructure is improved.
The resultant alloy ingots were crushed and milled under the same conditions as in Examples 1-4. The average particle size of jet-milled powder was measured by a Fisher-type sub-sieve sizer. The results are shown in Table 2. The average size of the jet-milled powder was more than 4 .mu.m in each alloy ingot. The crushability defined in Examples 1 through 4 is also shown in Table 2. The crushability was very poor, because the average grain size of the milled particles could not be refined down to 3.5 .mu.m, notwithstanding the fact that the feeder rate was considerably slowed down in Comparative Examples 6 and 7.
Comparative Example 8
The alloy having the same composition as that of Example 1 was centrifugally cast by the same method as in Examples 1 through 4 to produce alloy ingots having a thickness of from 5 to 6 mm. The average accumulating rate was 0.12 cm/second.
The cross-sectional microstructure of the alloy ingots was observed with a back scattered electron microscope and the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases and the average size of the respective phases were measured by an image analyzer. The results are shown in Table 3. Each alloy-ingot had a total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases less than 25%. It cannot be said that the microstructure is improved.
The resultant alloy ingots were crushed and milled by the same method as in Examples 1 through 4. The crushability defined in Examples 1 through 4 is given in Table 3. The average particle size of the jet milled powder was more than 4 .mu.m and the crushablity was poor, as well.
Comparative Examples 9-10
The raw-material alloys were blended to provide the compositions as shown in Table 2, and were melted in a high-frequency vacuum-induction furnace using an alumina crucible under a low-pressure argon-gas environment at 200 torr. Argon gas was admitted, directly before the casting, into the furnace to attain the atmospheric pressure in the furnace. The melt was then poured onto a single water-cooled roll made of copper rotating at circumferential speed of 1 meter/second. The ingots in the form of a strip, each having a thickness of from 0.2 to 0.3 mm were obtained.
The cross-sectional microstructure of the alloy ingots was observed with a back scattered electron microscope and the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases and the average size of the respective phases were measured by an image analyzer. The results are shown in Table 2. Each alloy-ingot had a total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases less than 25%. This microstructure cannot be said to be improved. In addition, the proportion of the intermediate phases was high.
The resultant alloy-ingots were jet-milled under the same conditions as in Examples 1 through 4. The crushability is mentioned in Table 2. The average particle size of the respective jet-milled alloy ingots was more than 4 .mu.m. The crushability was poor as well. The average particle size could not be as fine as 3.5 .mu.m, at a very slow feeding rate in Comparative Example 9. The average size could be as fine as 3.5 .mu.m, at a very slow feeding rate in Comparative Example 10 so that the crushability was extremely poor.
Comparative Example 11
An ingot in the form of a strip, having the composition as shown in Table 2, was obtained by the single-roll casting method as in Comparative Examples 9 and 10. This ingot was further subjected to heat treatment in argon atmosphere at 1000.degree. C. for 24 hours.
The cross-sectional microstructure of the alloy ingot was observed with a back-scattered electron microscope, and the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases and the average size of these phases were investigated by an image-analyze. The investigated results of the total volume fraction and size of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases and the average size of these phases are shown in Table 2. The total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases was 32% and high. However, the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases was 70 .mu.m in size and large-sized. In addition, the intermediate phase coarsely grew to 300 .mu.m.
The resultant alloy ingot was then milled by using a jet mill under the same conditions as in Examples 1-4 to obtain fine powder. The average particle size of jet-milled powder was measured by a Fisher-type sub-sieve sizer. The results are shown in Table 2. The crushability defined in Examples 1 through 4 is also shown in Table 2. The average particle size of the jet-milled powder was more than 4 .mu.m, and the crushability was poor as well. This seems to be attributable to the fact that, although the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases are at high volume fraction, they are are coarse.
Examples 8-10
An alloy melt, composition of which was 28% by weight of Nd, 1.2% by weight of Dy, 1.2% by weight of B, the balance being Fe, was cast by a single roll method under an argon-gas atmosphere, to form a main-phase alloy in the form of a thin strip. The cooling roll used was a water-cooled roll made of copper, 600 mm in diameter. The circumferential speed was 1 m/second.
The boundary phase-alloys obtained in Examples 1, 3 and 4 in 20% by weight and the main phase alloy in 80% by weight were mixed together. Hydrogen was absorbed in these alloys at room temperature and then emitted at 600.degree. C. The mixture was then roughly crushed to obtain the milled alloy-powder having average particle size of 15 .mu.m. The fine milling with the use of a jet mill was then carried out to obtain finely milled magnet powder having average size of 3.5 .mu.m. The resultant finely milled powder was compacted under magnetic field of 15 kOe and pressure of 1.5 ton/cm.sup.2. The resultant compact was sintered at 1090.degree. C. for 4 hours in vacuum. The first-stage heat treatment was then carried out at 850.degree. C. for 1 hour, and the second-stage heat treatment was carried out at 520.degree. C. for 1 hour. The magnetic properties of the obtained magnets are shown in Table 4. The properties of each magnet are improved.
Comparative Examples 12-15
The boundary phase-alloys obtained in Comparative Examples 1, 9, 10 and 11 in 20% by weight and the main phase alloy in 80% by weight produced by the same methods as in Examples 7-9 were mixed. The magnets were produced as in Examples 8-10. The jet-milled powder mixture had an average particle size of 3.7 .mu.m and was slightly coarser than that of Examples 8-10. The magnetic properties of the obtained magnets are shown in Table 4.
In Comparative Example 12 (the boundary-phase alloy of Comparative Example 1), since the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases is low, the jet-milled powder of the boundary-phase alloy is of large average particle size and poor dispersion property. The coercive force is, therefore, low.
In Comparative Examples 13 and 14 (the boundary-phase alloy of Comparative Example 9 and 10), the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases is low, so that the powder does not consist of these phases. The size of the main-phase alloy powder is too small. The remanence was, therefore, very low.
In Comparative Example 15 (the boundary-phase alloy of Comparative Example 11), since this alloy is heat-treated to increase the total volume fraction of the R.sub.2 T.sub.17 and R.sub.2 T.sub.14 B phases, the jet-milled fine powder consisted of these phases. The remanence was, therefore, high. However, the jet-milled fine powder was of large average particle size and hence of poor dispersion property. The coercive force was, therefore, very low.
TABLE 1__________________________________________________________________________ Casting Condition Average Average R.sub.2 T.sub.17 phase particle accumu- R.sub.2 T.sub.14 size of lating Total Average jetComposition of En- rate Thickness volume Size (.mu.m) milledAlloy Ingot (wt. %) vironment of melt Gas of alloy fraction R.sub.2 T.sub.17 R.sub.2 T.sub.14 powder CrushNd Dy Co B X Fe casting (cm/sec) cooling (mm) (%) phase phase (.mu.m) ability__________________________________________________________________________Example 1 43.0 1.2 15.0 0.1 Cu = 2.0 Bal Ar + He 0.03 no 5-6 39 5 5 3.5 1.0Example 2 48.2 -- -- 0.4 -- Bal Ar + He 0.03 no 5-6 39 4 5 2.7 2.4Example 3 38.0 10.2 -- 0.5 Al = 0.9 Bal Ar + He 0.03 no 5-6 39 5 4 2.9 1.9Example 4 38.0 10.2 -- 0.5 Ga = 0.9 Bal Ar + He 0.03 no 5-6 39 5 5 3.1 1.5Example 5 43.0 1.2 2.5 0.5 Cu = 0.4 Bal Ar 0.03 no 5-6 38 6 5 3.4 1.1Example 6 34.6 17.9 28.2 0.4 Cu = 2.0 Bal Ar 0.30 yes 5-6 30 6 6 3.8 0.6 Al = 1.5 HeExample 7 34.6 17.9 28.2 0.4 Cu = 2.0 Bal Ar 0.03 yes 5-6 31 6 6 3.9 0.5 Ga = 1.5 He__________________________________________________________________________ Remarks: Pr, which is nonseparable from the Nd component, is contained in Nd.
TABLE 2__________________________________________________________________________ R.sub.2 T.sub.17 phase Average R.sub.2 T.sub.14 phase particle Casting Condition Average size of jet-Composition of Environment Thickness Total Size (.mu.m) milledComparative Alloy Ingot (wt. %) at at of alloy volume R.sub.2 T.sub.17 R.sub.2 T.sub.14 B powder CrushExample No. Nd Dy Co B X Fe casting (mm) fraction phase phase (.mu.m) ability__________________________________________________________________________1 43.0 1.2 15.0 0.1 Cu = 2.0 Bal Ar 20 20 12 11 4.7 0.102 48.2 -- -- 0.4 -- Bal Ar 20 21 11 10 4.0 0.603 38.0 10.2 -- 0.5 Al = 0.9 Bal Ar 20 19 12 12 4.3 0.304 38.0 10.2 -- 0.5 Ga = 0.9 Bal Ar 20 19 12 12 4.6 0.155 43.0 1.2 2.5 0.5 Cu = 0.4 Bal Ar 20 18 11 12 4.9 0.556 34.6 17.9 28.2 0.4 Cu = 2.0 Bal Ar 20 15 15 14 5.3 0.01 Al = 1.57 34.6 17.9 28.2 0.4 Cu = 2.0 Bal Ar 20 15 15 14 5.4 0.01 Ga = 1.59 43.0 1.2 15.0 0.1 Cu = 2.0 Bal Ar 0.2-0.3 8 5 5 5.2 0.0110 38.0 10.2 -- 0.5 Al = 0.9 Bal Ar 0.2-0.3 5 3 4 4.5 0.1511 38.0 10.2 -- 0.5 Al = 0.9 Bal Ar 0.2-0.3 32 68 70 4.1 0.30__________________________________________________________________________ Remarks: Pr, which is nonseparable from the Nd component, is contained in Nd.
TABLE 3__________________________________________________________________________ Casting Condition Average Average R.sub.2 T.sub.17 phase particle accumu- R.sub.2 T.sub.14 size of lating Total Average jetComposition of En- rate Thickness volume Size (.mu.m) milledAlloy Ingot (wt. %) vironment of melt Gas of alloy fraction R.sub.2 T.sub.17 R.sub.2 T.sub.14 powder CrushNd Dy Co B X Fe casting (cm/sec) cooling (mm) (%) phase phase (.mu.m) ability__________________________________________________________________________Comparative 43.0 1.2 15.0 0.1 Cu = 2.0 Bal Ar + He 0.12 no 5-6 21 11 10 4.5 0.20Example 8__________________________________________________________________________ Remarks. Pr, which in nonseparable from the Nd component, is contained in Nd.
TABLE 4__________________________________________________________________________Composition of mixedboundary-phase alloy Magnetic propertiesand main-phase alloy (wt. %) Br iHc (BH).sub.maxNd Dy Co B X Fe (kG) (kOe) (MGOe) Remarks__________________________________________________________________________Example 8 31.0 1.2 3.0 1.0 Cu = 0.4 Bal 13.6 15.3 44.5 Example 1, Centrifugal CastingExample 9 30.0 3.0 -- 1.1 Al = 0.2 Bal 12.8 18.2 39.6 Example 3, Centrifugal CastingExample 10 30.0 3.0 -- 1.1 Ga = 0.2 Bal 12.6 19.6 38.5 Example 4, Centrifugal CastingComparative 31.0 1.2 3.0 1.0 Cu = 0.4 Bal 13.5 12.5 43.2 Comparative Example 1Example 12 Metal-mold castingComparative 31.0 1.2 3.0 1.0 Cu = 0.4 Bal 12.9 14.4 39.5 Comparative Example 9Example 13 Strip-form ingotComparative 30.0 3.0 -- 1.1 Al = 0.2 Bal 12.1 15.5 34.7 Comparative Example 10Example 14 Strip-form ingotComparative 30.0 3.0 -- 1.1 Al = 0.2 Bal 12.7 16.2 38.6 Comparative Example 11Example 15 Strip, Heat treatment__________________________________________________________________________ Remarks. Pr, which is nonseparable from the Nd component, is contained in Nd.

Claims

1. An alloy used for the production of a rare-earth magnet, wherein said alloy consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy and Pr, 1% by weight or less of B, and the balance being Fe, and has 25% or more of the total volume fraction of an R.sub.2 Fe.sub.17 phase and an R.sub.2 Fe.sub.14 B phase and 20 .mu.m or less of the average size of each of the R.sub.2 Fe.sub.17 phase and the R.sub.2 Fe.sub.14 B phase.
2. An alloy used for the production of a rare-earth magnet, wherein said alloy consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy and Pr, 1% by weight or less of B, and at least one element selected from the group consisting of 35% by weight or less of Co, 4% by weight or less of Cu, 3% by weight or less of Al and 3% by weight or less of Ga, and the balance being Fe, and has 25% or more of the total volume fraction of an R.sub.2 T.sub.17 phase (T is Fe, or Fe, a part of which is replaced with at least one element selected from the group consisting of Co, Cu, Al and Ga) and an R.sub.2 T.sub.14 B phase (T is the same as defined above) and 20 .mu.m or less of the average size of each of the R.sub.2 T.sub.17 phase and the R.sub.2 T.sub.14 B phase.
3. A method for producing an alloy used for the production of a rare-earth magnet, comprising the steps of:
preparing an alloy-melt which consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy and Pr, 1% by weight or less of B, and the balance being Fe;
feeding the alloy melt into a rotary tubular mold having an inner surface and onto one or more predetermined portions of the inner surface;
rotating the rotary tubular mold around its longitudinal central axis;
accumulating the alloy melt onto the inner surface of a mold at an average rate of 0.1 cm/second or less; and,
centrifugally casting the alloy melt being accumulated at said average rate.
4. A method for producing an alloy used for the production of a rare-earth magnet, comprising the steps of:
preparing an alloy-melt which consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy and Pr, 1% by weight or less of B, at least one element selected from the group consisting of 35% by weight or less of Co, 4% by weight or less of Cu, 3% by weight or less of Al and 3% by weight or less of Ga, and the balance being Fe;
feeding the alloy melt into a rotary tubular mold having an inner surface and onto one or more portions of the inner surface;
rotating the rotary tubular mold around its longitudinal central axis;
accumulating the alloy melt onto the inner surface of a mold at an average rate of 0.1 cm/second or less; and,
centrifugally casting the alloy melt being accumulated at said average rate.
5. A method for producing an alloy used for the production of a rare-earth magnet alloy according to claim 3 or 4, wherein the average accumulating rate is from 0.005 to 0.1 cm/second.
6. A method for producing an alloy used for the production of a rare-earth magnet alloy according to claim 3 or 4, further comprising a step of reciprocating a means for feeding the alloy melt in the longitudinal direction of the rotary tubular mold.
7. A method for producing an alloy used for the production of a rare-earth magnet alloy according to claim 3 or 4, further comprising a step of bringing the cast melt into contact with an atmosphere containing inert-gas.
8. A method for producing an alloy used for the production of a rare-earth magnet alloy according to claim 7, wherein the inert-gas containing atmosphere contains 20% or more of helium.
9. A method for producing an alloy used for the production of a rare-earth magnet alloy according to claim 3 or 4, further comprising a step of blowing a cooling gas, which comprises an inert-gas, onto the inner surface of the rotary tubular mold, during the centrifugal casting.
10. A method for producing an alloy used for the production of a rare-earth magnet alloy according to claim 3 or 4, further comprising steps of:
bringing the cast melt into contact with an inert-gas containing atmosphere; and,
blowing a cooling gas, which comprises an inert-gas, onto the inner surface of the rotary tubular mold, during the centrifugal casting.
11. A method for producing an alloy used for the production of a rare-earth magnet alloy according to claim 3 or 4, wherein the alloy melt is fed on the inner surface of the rotary tubular mold; said inner surface is metallic and not covered by a coating agent.
12. A method for producing an alloy used for the production of a rare-earth magnet alloy according to claim 3 or 4, wherein the alloy melt is fed on the inner surface of the rotary tubular mold; said inner surface consists of cast alloy formed by the method of claim 3 or 4.
13. A rare-earth magnet produced by the steps comprising the steps of:
crushing a first alloy produced by the method of claim 3 or 4;
preparing a second alloy having a composition of essentially R.sub.2 T.sub.14 B;
crushing the second alloy;
mixing the powder of the first and second alloys;
compacting the powder mixture under a magnetic field, thereby forming a powder compact; and,
sintering the powder compact.
14. A rare-earth alloy powder used for producing a rare-earth magnet, wherein said powder is produced by crushing the alloy according to claim 1 or 2.
15. A rare-earth powder used for producing a rare-earth magnet according to claim 14, wherein said alloy is produced by a method comprising the steps of:
preparing an alloy-melt which consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy, and Pr, 1% by weight or less of B, and the balance being Fe;
feeding the alloy melt into a rotary tubular mold having an inner surface and onto one or more predetermined portions of the inner surface;
rotating the rotary tubular mold around its longitudinal central axis;
accumulating the alloy melt onto the inner surface of a mold at an average rate of 0.1 cm/second or less; and
centrifugally casting the alloy melt being accumulated at said average rate.
16. A rare-earth powder used for producing a rare-earth magnet according to claim 14, wherein said alloy is produced by a method comprising the steps of:
preparing an alloy-melt which consists of from 35 to 60% by weight of at least one rare-earth element (R) selected from the group consisting of Nd, Dy and Pr, 1% by weight or less of B, at least one element selected from the group consisting of 35% by weight or less of Co, 4% by weight or less of Cu, 3% by weight or less of Al and 3 % by weight or less of Ga, and the balance being Fe;
feeding the alloy melt into a rotary tubular mold having an inner surface and onto one or more portions of the inner surface;
rotating the rotary tubular mold around its longitudinal central axis;
accumulating the alloy melt onto the inner surface of a mold at an average rate of 0.1 cm/second or less; and
centrifugally casting the alloy melt being accumulated at said average rate.
17. A rare-earth alloy powder used for producing a rare-earth magnet according to claim 16, wherein said rare-earth alloy powder has an average particle-size of 4 .mu.m or less.
18. A rare-earth alloy powder used for producing a rare-earth magnet according to claim 15, wherein said rare-earth alloy powder has an average particle-size of 4 .mu.m or less.

US Referenced Citations (5)

Number	Name	Date
5387291	Kaneko et al.	Feb 1995
5447578	Ozaki et al.	Sep 1995
5647886	Kitazawa et al.	Jul 1997
5948179	Hasegawa et al.	Sep 1999
5963774	Sasaki et al.	Oct 1999

Alloy used for production of a rare-earth magnet and method for producing the same

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