Claims
- 1. A copolymer produced by radically copolymerizing monomers in the presence of an effective amount of one or more peroxides represented by the following formula: ##STR18## wherein n is an integer from 2-4,
- R.sub.1 and R.sub.2 may be the same or different and are selected from the group consisting of hydrogen and lower alkyl or R.sub.1 and R.sub.2 may combine to form a C.sub.5 -C.sub.7 aliphatic ring, R.sub.3 has a valency of n and
- when n=2, R.sub.3 is an alkylene group having 8-12 carbon atoms, an alkynylene group having 8-12 carbon atoms or a group of the general formula: ##STR19## wherein q=0 or 1, and
- R.sub.7 is an isopropenyl group, a 2-hydroxyisopropyl group, and an isopropyl group: ##STR20## wherein R.sub.8, R.sub.9 and R.sub.10 are independently selected from the group consisting of alkyl, alkenyl and aryl groups all of which may be optionally substituted with one or more of hydroxyl, amino, epoxy and carboxy groups, hydrogen, or two of R.sub.8, R.sub.9 and R.sub.10 may combine to form a ring; or the group --COOR.sup.6 where R.sup.6 is hydrogen or an optionally substituted alkyl, alkenyl or aryl group; and
- when n=3, R.sub.3 =1,2,4-triisopropylbenzene-.alpha.,.alpha.',.alpha."-triyl; and
- for n=2-4,
- R.sub.3 can be a silicon-containing group and
- X is an electron withdrawing group and together with R.sub.1, may combine to form a C.sub.5 -C.sub.7 aliphatic ring,
- m is 0 or 1 and
- Z is selected from the group consisting of ##STR21##
- 2. The copolymer of claim 1, wherein from 0.001 to 30.0 mole percent of said peroxide, based on the moles of polymerizable monomer, is employed as the effective amount.
- 3. The copolymer of claim 1 wherein said polymerizable monomer is selected from the group consisting of acrylates, methacrylates, styrene, styrene derivatives, vinyl esters, dienes, acrylonitrile and .alpha.-olefins.
- 4. The copolymer of claim 1 wherein R.sub.3 of the peroxides is selected from the group consisting of an alkyl group containing 4-18 carbon atoms; an alkenyl group having 5-18 carbon atoms or 1-vinylcyclohexyl, all of which may be optionally substituted with one or more of hydroxyl, amino, epoxy, and carboxy groups; p-menth-8-yl; and group of formula ##STR22## wherein: p is 0, 1 or 2; and
- R.sub.7 is an isopropenyl group, a 2-hydroxyisopropyl group, or an isopropyl group of formula: ##STR23## wherein: R.sub.8, R.sub.9 and R.sub.10 are independently selected from the group consisting of alkyl, alkenyl and aryl groups, all of which may be optionally substituted with one or more of hydroxyl, amino, epoxy and carboxy groups, hydrogen, or two of R.sub.8, R.sub.9 and R.sub.10 may combine to form a ring;
- and when n is 2, R.sub.3 is an alkylene group having 8-12 carbon atoms, an alkynylene group having 8-12 carbon atoms, or a group of formula ##STR24## wherein: q is 0 or 1; and
- R.sub.7 has the above-indicated meaning; and when n is 3, R.sub.3 is 1,2,4-triisopropylbenzene-.alpha.,.alpha.',.alpha."-triyl; and for n is 1-4, R.sub.3 can be a silicon-containing group.
- 5. The copolymer of claim 1 wherein X is an electron withdrawing group, optionally substituted with hydroxy, amino, epoxy or carboxy.
- 6. The copolymer of claim 1 wherein X is a group selected from the group consisting of alkoxycarbonyl, alkoxy, phenyl, substituted aromatic groups, aryloxycarbonyl, carboxy, acyloxy, aryloxy, epoxy, carbamoyl, halogen, halocarbon, carbonate sulfones, sulfoxides, phosphonates, phosphine oxide, hydroxy, amino, --CONH.sub.2, --CON, cyano, and a group containing two or more of these functionalities which may be the same or different.
Priority Claims (1)
Number |
Date |
Country |
Kind |
892028895 |
Nov 1989 |
EPX |
|
Parent Case Info
The present application is a divisional application of Ser. No. 08/857,916, filed on May 15, 1992, now U.S. Pat. No. 5,708,104.
Divisions (1)
|
Number |
Date |
Country |
Parent |
857916 |
May 1992 |
|