.alpha.-substituted-propionic acid esters

Information

  • Patent Grant
  • 5055222
  • Patent Number
    5,055,222
  • Date Filed
    Monday, September 18, 1989
    35 years ago
  • Date Issued
    Tuesday, October 8, 1991
    32 years ago
Abstract
An optically active compound exhibiting high speed response properties when used as a component of liquid crystal materials used in a liquid crystal display mode utilizing ferroelectricity, and a liquid crystal composition containing the compound are provided, which compound is expressed by the formula ##STR1## wherein R.sup.1 represents alkyl, alkoxy or alkoxycarbonyl each of 2 to 18 C, R.sup.2 represents alkyl of 3 to 18 C or alkoxy of 1 to 18 C and A represents a member selected from a group of two directly bonded six-membered rings having a halogen atom, cyano group, methyl group or trifluoromethyl group attached thereonto and * represents an unsymmetric carbon atom.
Description
Claims
  • 1. An optically active compound expressed by the formula ##STR37## wherein R.sup.1 represents an alkyl group 2-12 carbon atoms, R.sup.2 represents an alkyl group of 3-8 carbon atoms, and * represents an unsymmetric carbon atom.
  • 2. A liquid crystal composition comprising at least two components at least one of which is an optically active compound of the formula (I) as set forth in claim 1.
  • 3. A liquid crystal composition according to claim 2, exhibiting chiral smectic phase.
  • 4. A liquid crystal composition according to claim 2, exhibiting chiral nematic phase.
  • 5. A liquid crystal display element containing a liquid crystal composition which comprises at least two components at least one of which is an optically active compound of the formula (I) as set forth in claim 1 and exhibits chiral smectic phase.
Priority Claims (2)
Number Date Country Kind
61-267206 Nov 1986 JPX
61-313310 Dec 1986 JPX
BACKGROUND OF THE INVENTION

This application is a division of now abandoned application, Ser. No. 07/119,067 filed on Nov. 10, 1987 now abandoned. 1. Field of the Invention This invention relates to a novel compound suitable as a component of liquid crystal compositions, and more particularly it relates to a chiral compound having an optically active group and a liquid crystal composition containing the same, particularly a ferroelectric liquid crystal composition. 2. Description of the Related Art At present, TN (twisted nematic) mode display has been most broadly employed as liquid crystal display elements, but it is inferior in the aspect of the response rate to emissive mode display elements (electroluminescence, plasma display, etc.); hence various improvements in this respect have been attempted, but it does not appear that a possibility of improvement to a large extent remains. Thus, various liquid crystal display devices based on another principle in place of that of TN mode display elements have been attempted, and as one such device, there is a display mode making use of ferroelectric liquid crystals (N. A. Clark et al, Applied Phys. lett., 36,899 (1980)). This mode makes use of chiral smectic phases such as chiral smectic C phase (hereinafter abbreviated to SC.sup.* phase), and the temperature range exhibiting these phases is preferred to be in the vicinity of room temperature. In addition, as liquid crystal phases exhibiting ferroelectricity, not only SC.sup.* phase but also chiral smectic F, G, H, I, J, etc. phases have been known. In order to search for compounds having superior characteristics as a component of liquid crystal materials used for liquid crystal display mode making use of the ferroelectricity, the present inventors have extensively searched for a large number of compounds and have attained the present invention. The present invention resides in: an optically active compound expressed by the formula ##STR2## wherein R.sup.1 represents an alkyl group, an alkoxy group or an alkoxycarbonyl group each of 2 to 18 carbon atoms, R.sup.2 represents an alkyl group of 3 to 18 carbon atoms or an alkoxy group of 1 to 18 carbon atoms, A represents ##STR3## wherein X represents hydrogen atom, fluorine atom, chlorine atom, cyano group, methyl group or trifluoromethyl group, and the symbol * represents an unsymmetric carbon atom, and a liquid crystal composition containing at least one of the above-mentioned optically active compounds.

US Referenced Citations (11)
Number Name Date Kind
4592858 Higuchi et al. Jun 1986
4613209 Goodby et al. Sep 1986
4650600 Heppke et al. May 1987
4695651 Higuchi et al. Sep 1987
4723018 Shinozaki et al. Feb 1988
4725688 Taguchi et al. Feb 1988
4732699 Higuchi et al. Mar 1988
4744918 Heppke et al. May 1988
4775223 Yoshinaga et al. Oct 1988
4834904 Krause et al. May 1989
4876026 Saito et al. Oct 1989
Foreign Referenced Citations (6)
Number Date Country
164814 Dec 1985 EPX
175591 Mar 1986 EPX
63-44551 Feb 1988 JPX
63-63664 Mar 1988 JPX
8705012 Aug 1987 WOX
8803525 May 1988 WOX
Non-Patent Literature Citations (1)
Entry
Goodby et al., Liquid Crystals & Ordered Fluids, vol. 4, pp. 1-32 (1984).
Divisions (1)
Number Date Country
Parent 119067 Nov 1987