This patent disclosure relates generally to internal combustion engines and, more particularly, to split-combustion engines.
Split combustion in internal combustion engines of various types is known. In a typical split combustion engine, the intake and compression strokes or phases are performed in one engine cylinder, commonly referred to as the compressor, and the combustion and exhaust strokes or phases are performed in a second engine cylinder, which is commonly referred to as the combustor. The compressed air charge from the compressor is transferred to the combustor via a transfer duct. As can be appreciated, the compressed air charge is at a high pressure and typically travels through the transfer duct at supersonic speeds.
In a typical split combustion engine, combustion fuel is added to the compressed air charge either in the transfer duct or directly into the combustor. Typically, a transfer valve is positioned between the compressor cylinder and the transfer duct. The compressor piston has a phased crank-angle delay relative to the combustor cylinder, and the combustion occurs after the combustor cylinder has reached top dead center (TDC). In this way, the combustor piston can begin to move downwards while the compressor piston is still moving upwards to ensure that the combusting mixture of fuel and air in the combustor cylinder does not recirculate back into the compressor cylinder.
As can be appreciated, typical split combustion engines involve two engine cylinders in compressor/combustor pairs. Thus, an engine having an even number of cylinders will typically operate such that half of the engine's cylinders are operating as compressors, while the other half are operating as combustors, where each compressor is paired with a corresponding combustor. One drawback of typical split combustion engines is uneven heat distribution in the engine block that results from half of the engine's cylinders undergoing combustion strokes twice per engine revolution, while the other half never undergo a combustion stroke. This uneven heat distribution can cause thermal issues for all engine components involved, as well as drive different design parameters for each cylinder type and for the crankcase, which ultimately leads to increased engine complexity, additional and specialized components and development costs.
The disclosure describes, in one aspect, an internal combustion engine. The engine includes a cylinder case forming a cylinder bore, which has a piston reciprocally disposed therewithin that is moveable between top dead center (TDC) and bottom dead center (BDC) positions. The piston is connected to a rotatable crankshaft such that a position of the piston within the cylinder bore is related to a crank shaft angle. A cylinder head is disposed to cover an open end of the cylinder bore and defines one end of a variable volume within the cylinder bore between the cylinder head and the piston. An intake manifold is fluidly connectable with the variable volume through an intake valve, and an exhaust manifold is fluidly connectable with the variable volume through an exhaust valve.
In one disclosed embodiment, a transfer manifold is fluidly connectable with the variable volume via a transfer duct through a transfer valve, and is further fluidly connectable with the variable volume via a combustion conduit through a combustion valve. A fuel injector is associated with the variable volume and adapted to provide a predetermined amount of fuel into the variable volume. A valve activation mechanism is configured to selectively open and close each of the intake, exhaust, transfer and combustion valves, such that: the intake valve opens when the piston undergoes an intake stroke as it moves from the TDC position towards the BDC position to fill the variable volume with fluid from the intake manifold, the variable volume is closed when the piston undergoes a compression stroke as it moves from the BDC position towards the TDC position to compress fluid present therein and yield a compressed charge, the transfer valve opens to provide the compressed charge to the transfer manifold, where the compressed charge is collected, the combustion valve opens to admit a compressed charge from the transfer manifold into the variable volume, the variable volume is closed when the piston undergoes a combustion stroke as it moves from the TDC position towards the BDC position to combust a fluid/air mixture present therein, and the exhaust valve opens when the piston undergoes an exhaust stroke as it moves from the BDC position towards the TDC position to evacuate the variable volume from at least a portion of exhaust gas that is present therein.
In another aspect, the disclosure describes an internal combustion engine having first and second pluralities of cylinders. The engine includes a cylinder case forming first and second pluralities of cylinder bores. Each cylinder bore has a piston reciprocally disposed therewithin and moveable between top dead center (TDC) and bottom dead center (BDC) positions. Each piston is connected to a rotatable crankshaft such that a position of each piston within a respective cylinder bore is related to a crank shaft angle. A cylinder head is disposed to cover an open end of the cylinder bores such that first and second pluralities of variable volumes are defined within each respective cylinder bore between the cylinder head and the respective piston. An intake manifold is fluidly connectable with the first and second pluralities of variable volumes through a respective intake valve associated with each variable volume, and an exhaust manifold is fluidly connectable with the first and second pluralities of variable volumes through a respective exhaust valve associated with each variable volume.
In one disclosed embodiment, a first transfer manifold is fluidly connectable with the first plurality of variable volumes via a respective transfer conduit and a respective transfer valve, and is further fluidly connectable with the second plurality of variable volumes via a respective combustion conduit and a respective combustion valve. A second transfer manifold is fluidly connectable with the second plurality of variable volumes via a respective transfer conduit and a respective transfer valve, and is further fluidly connectable with the first plurality of variable volumes via a respective combustion conduit and a respective combustion valve. A fuel injector is associated with each of the combustion conduits of the first and second pluralities of variable volumes, and is adapted to provide a predetermined amount of fuel into each variable volume. A valve activation mechanism is configured to selectively open and close each of the intake, exhaust, transfer and combustion valves, of each of the first and second pluralities of variable volumes, such that: the intake valve of one of the first plurality of variable volumes opens when the respective piston undergoes an intake stroke as it moves from the respective TDC position towards the BDC position to fill the one of the first plurality of variable volumes with fluid from the intake manifold; the one of the first plurality of variable volumes is closed when the piston undergoes a compression stroke as it moves from the respective BDC position towards the TDC position to compress fluid present therein and yield a compressed charge; the transfer valve corresponding to the one of the first plurality of variable volumes opens to provide the compressed charge to the first transfer manifold, where the compressed charge is collected; the combustion valve corresponding to the one of the first plurality of variable volumes opens to admit a compressed charge from the second transfer manifold into the one of the first plurality of variable volumes; the one of the first plurality of variable volumes is closed when the respective piston undergoes a combustion stroke as it moves from the respective TDC position towards the BDC position to combust a fluid/air mixture present therein; and the exhaust valve corresponding to the one of the first plurality of variable volumes opens when the respective piston undergoes an exhaust stroke as it moves from the BDC position towards the TDC position to evacuate the one of the first plurality of variable volumes from at least a portion of exhaust gas that is present therein.
In yet another aspect, the disclosure describes a method for operating an internal combustion engine. The method includes at least partially opening an intake valve during an intake stroke of a cylinder, the cylinder defining a variable volume as a piston moves from a top dead center (TDC) position towards a bottom dead center (BDC) position. The intake valve is closed to fluidly isolate an air charge within the variable volume, and a compression stroke is performed, during which the piston moves from the BDC position towards the TDC position, such that the air charge becomes a compressed air charge. A transfer valve is at least partially opened at a predetermined piston position within the cylinder to release the compressed charge from the variable volume and into a transfer manifold, which collects one or more compressed air charges. A combustion valve is opened to admit a compressed charge into the variable volume from the transfer manifold, and a predetermined amount of fuel is provided in mixing relation with the compressed charge entering the variable volume. The combustion valve is closed and a combustion stroke of the cylinder is performed. An exhaust stroke of the cylinder is then performed, during which an exhaust valve at least partially opens to release at least a portion of exhaust gas present in the variable volume into an exhaust manifold.
This disclosure relates to internal combustion engines configured to operate under an alternating split-cycle combustion arrangement. Accordingly, although the various operating strokes for combustion are split between different engine cylinders, each engine cylinder is configured to selectively operate either as a compressor cylinder or as a combustion cylinder. In this way, engine operation is flexible and heat loading of the engine is distributed across all engine cylinders. Three main embodiments are presented herein for engines configured for split combustion operation. In a first embodiment, an engine 100 (
A block diagram for the engine 100 is shown in
The cylinder 104 defines a variable volume 110 that, in the illustrated orientation, is laterally bound by the walls of the bore 106 and is closed at its ends by a top portion or crown of the piston 108 and by a surface 112 of the cylinder head 113, which is typically referred to as the flame deck. The variable volume 110 changes between maximum and minimum capacity as the piston 108 reciprocates within the bore 106 between bottom dead center (BDC) and top dead center (TDC) positions, respectively.
In reference to
Apart from the transfer manifold 130 and the fluid interconnections of the engine cylinders 104 therewith, the engine 100 can otherwise have any appropriate air system configuration. In the exemplary embodiment of the engine 100 shown in
The turbine 136 drives the compressor 138, which compresses filtered, ambient air from an intake duct 142 to provide compressed, charge air to an air conduit 144. The air conduit 144 includes an optional charge air cooler (CAC) cooler 146, which cools the charge air before it is provided to the intake manifold 122. The illustrated engine 100 further includes a high pressure loop (HPL) exhaust gas recirculation (EGR) system, but other types of EGR systems such as low or intermediate pressure systems may be used. Depending the requirements of the specific engine application, the EGR system may be omitted entirely. In the illustrated embodiment, the EGR system includes an EGR cooler 148 that fluidly interconnects the exhaust manifold 126 with the intake manifold 122 such that cooled exhaust gas can be provided to the intake of the engine. An EGR valve 150 is disposed to meter the amount of exhaust gas recirculated in this fashion.
The engine 100 further includes an electronic controller 152. The electronic controller 152 may be a single controller or may include more than one controller disposed to control various functions and/or features of the engine 100 and/or features of a vehicle or machine in which the engine 100 is installed. For example, a master controller, used to control the overall operation and function of a machine, may be cooperatively implemented with a motor or engine controller used to control the engine 100. In this embodiment, the term “controller” is meant to include one, two, or more controllers that may be associated with the engine 100 and that may cooperate in controlling various functions and operations of the engine 100 (
Accordingly, the controller 152 is associated with each of the fuel injectors 132 and the EGR valve 150 and configured to selectively control their operation. The controller 152 is further associated with sensors and actuators of the engine such as crankshaft and/or camshaft position sensors (not shown), engine speed and/or torque sensors (not shown), and other known sensors and actuators that participate in providing functions and information to the controller 152 to control and monitor engine operation.
The engine 100 advantageously operates in an alternating split combustion mode, thus overcoming the drawbacks of typical split combustion engine cycles. Specifically, where particular cylinders in typical split combustion engines consistently operate either as compressor or combustor cylinders, each of the cylinders 104 of the engine 100 is configured to selectively operate at times either as a compressor or as a combustor cylinder. In this way, heat may be distributed relatively evenly across the crankcase 102, cylinder head 113, or any other heavy metal engine structures. The alternating split combustion mode of operation of each cylinder 104 is accomplished by the activation at specific periods of the intake, exhaust and transfer valves 114, 116 and 118 (
Graph 200 illustrates a plurality of engine parameters in time-aligned fashion for the sake of discussion. At the top, a first curve 202 illustrates a position of an engine piston within its corresponding bore, for example, the piston 108 that reciprocates within bore 106, plotted against a range of crankshaft angles. The piston position alternates between TDC and BDC positions, which are plotted along the vertical axis 203, and, when piston position is plotted against crankshaft angles 204, which are illustrated in the horizontal axis, produces a generally sinusoidal curve. The alternating split combustion cycle of each piston in the illustrated embodiment repeats continuously during engine operation such that each piston alternates between operation as a compressor cylinder and as a combustor cylinder.
To illustrate one embodiment for accomplishing this alternating split cycle combustion, the various strokes of operation are described relative to the operation of the various valves and fuel injector(s) that are associated with each cylinder. The operation of the cylinder as a compressor is described first, but it should be appreciated that each cylinder continuously operates in alternating fashion as either a combustor or a compressor cylinder. Further, the operation of the engine 100 (
The first curve 202 represents the position of the piston within the bore. The position of the intake valve(s) 206, for example, the intake valve 114 (
In more particular reference to the graph 200, each cylinder undergoes an intake stroke over a range of crankshaft angles 214. During this time, the piston moves within the bore from a TDC position a BDC position within the bore, thus increasing the volume of the cylinder. Also during this time, an intake valve opens, as shown by curve 216, to admit air or a fluid mixture of air and exhaust gas from the intake manifold to fill the expanding cylinder volume. The degree and duration of opening of the intake valve can vary, for example, in accordance with a Miller cycle of operation, and thus the mass of fluid entering the cylinder can be controlled.
Having admitted a fluid or mixture of fluids into the cylinder, the cylinder undergoes a compression stroke over a range of crankshaft angles 218. During this time, the piston moves from the BDC position towards the TDC position such that the fluid present within the cylinder, which is maintained in a closed condition, can be compressed. Towards the end of the compression stroke, for example, before the piston has reached the TDC position and while the fluid within the cylinder is in a compressed state in the absence of fuel or other combustible agents, the transfer valve may open, as shown by curve 220, to release the compressed fluid into a transfer manifold, for example, the transfer manifold 130 (
Turning now back to the graph 200, the solid-line curves illustrate the operating condition in which the transfer manifold acts as a passage for compressed fluid. In this condition, the piston reaches the TDC position as the transfer valve closes, and a second intake stroke is carried out over a range of crankshaft angles 222. During the second intake stroke, the intake valve may open at least momentarily, as shown by curve 224, to admit sufficient air into the cylinder to allow for an expansion of the cylinder volume without producing a negative pressure therein that may increase the parasitic load of the engine. As can be appreciated, the opening of the intake valve during this second intake stroke is optional and may be omitted in favor of retaining a small amount of air from the previous compression stroke, which was retained in the cylinder by early closing of the transfer valve before the total amount of fluid in the cylinder was expelled.
In the illustrated embodiment, the intake valve is opened during the second intake stroke 222 after the piston has reached the TDC position. After the piston reaches the BDC position at the end of the second intake stroke 222, it begins to once again move towards the TDC position while the cylinder undergoes a second compression stroke over a range of crankcase angles 226. During this time, an insignificant amount of air or other fluids is present in the cylinder because the mass present in the cylinder at this time will not be relied upon to provide the oxygen for the subsequent combustion stroke. Rather, the piston is moved close to the TDC position in preparation of receiving a compressed air charge in the cylinder. At this time, while the role of the cylinder thus far has been that of a compressor cylinder in a split combustion arrangement, the role of the cylinder changes to that of a combustor cylinder. The two cylinder strokes over crank angle ranges 222 and 226 can be referred to as “dead” strokes because they do not contribute to the positive power output of the engine.
As the piston approaches the TDC position during the second compression stroke 226, the transfer valve once again opens, as shown by curve 228. Unlike the previous opening of the transfer valve to remove compressed fluid from the cylinder, this time the opening of the transfer valve is for admitting a super-compressed air or mixture into the cylinder before the piston has reached the TDC position. The compressed charge admitted into the cylinder at this time is a charge that was compressed by a different engine cylinder and removed therefrom during a period 218 for that cylinder.
As the compressed charge enters the cylinder, for example, through a transfer passage having a fuel injector associated therewith, such as the transfer passage 128 having injector 132 therein (see
At the end of the power stroke 232, the piston reaches the BDC position and begins to move back towards TDC position while the cylinder undergoes an exhaust stroke over a range of crankshaft angles 234. During the exhaust stroke 234, the exhaust valve opens as shown by curve 236 to allow exhaust gas to evacuate the contracting cylinder volume. In the illustrated embodiment, the exhaust valve is closed early such that at least some exhaust gas is pushed out into the intake manifold as the intake valve opens again early, as shown by curve 238, in preparation of initiation of the first intake stroke of the cycle, which corresponds to the intake stroke 214 previously described. In this way, the alternating split cycle repeats in each of the engine cylinders where each cylinder alternates between a compressor mode and a combustor mode.
As an alternative to having dead strokes, the capacity of the transfer manifold can be increased such that high pressure fluids may be collected and stored therein during engine operation. The compressed fluids collected and stored within the transfer manifold may be used to immediately supply fluids to engine cylinders for initiating a combustion stroke immediately after the compression stroke 218 and thus avoid having dead strokes. The valve events associated with this type of operation are shown in dashed-line curves in graph 200.
Accordingly, once the cylinder has completed the compression stroke 218 as previously discussed, the piston reaches the TDC position. Immediately or shortly thereafter, the transfer valve opens once more, as shown by curve 240 to admit an amount of compressed fluids into the cylinder. At the same time, the fuel injector is activated as shown by curve 242 to supply the fuel that will mix with the incoming air charge into the cylinder to create conditions favorable for combustion. In this operating condition, the range of crank angles 222 for cylinder expansion represents a combustion stroke, and the range 226 that follows, which represents the motion of the cylinder back towards TDC, represents and exhaust stroke and the exhaust valve opens to release spent gases to the exhaust manifold, as shown by curve 244. After the exhaust stroke 226 is completed, operation of the cylinder repeats with the subsequent intake stroke, similar to stroke 214 previously described.
In one embodiment of an engine having a plurality of cylinders, such as the engine 100 (
Activation of the various valves of each cylinder can be accomplished in any appropriate fashion including using dedicated actuators selectively operating each valve, variable valve actuation systems, and other known methods. Such variable or selective valve activation systems may provide added flexibility in the operation of the engine where various Miller effects and/or control of the combustion or compression operating mode of each cylinder can be determined for each crankshaft revolution. For example, at low engine power operating modes, certain combustor mode events for certain cylinders may be skipped in favor of additional compressor mode events at those cylinders, which can provide more fuel efficient engine operation.
In the embodiment illustrated in
To address considerations relating to fast successive valve activations, for example, the successive activations of the transfer valve as shown by curves 220 and 240 in graph 200 (
Accordingly, in reference to
Relative to the capacity of the transfer passage 130, and to minimize losses in flow momentum and effects of the enthalpy of the air charge being transferred between cylinders, an alternative embodiment for an engine 500 having first and second transfer manifolds 502 and 504 is shown in
More specifically, each transfer passage 128 of each of the cylinders 104 belonging to the first plurality of cylinders 506 is fluidly connected to the first transfer manifold 502. The first transfer manifold 502 is further fluidly connected to each combustion passage 402 of each of the cylinders 104 belonging to the second plurality of cylinders 508. Similarly, each transfer passage 128 of each of the cylinders 104 belonging to the second plurality of cylinders 508 is fluidly connected to the second transfer manifold 504, and each combustion passage 402 of each of the cylinders 104 belonging to the first plurality of cylinders 506 is connected to the second transfer manifold 504.
During operation, compressed charge provided by one of the first plurality of cylinders 506 operating in a compressor mode is collected in the first transfer manifold 502. From there, compressed charge is provided for combustion in one of the second plurality of cylinders 508. Similarly, compressed charge provided by one of the second plurality of cylinders 508 operating in compressor mode is collected in the second transfer manifold 502, from where it is provided to the first plurality of cylinders 506. By separating the two pluralities of cylinders 506 and 508 in this fashion, the volume of each of the first and second transfer manifolds 502 and 504 can be made smaller relative to the volume of a single transfer manifold 130 (
It is noted that, although the engine 500 is shown having two pluralities of cylinders 506 and 508 and two transfer manifolds 502 and 504, more than two cylinder pluralities operating with more than two transfer manifolds may be used. Additionally, even though the cylinders in the first and second pluralities of cylinders are shown grouped together, they may be grouped in any other desired configuration, including having cylinders belonging in different pluralities being disposed in an alternating fashion within the cylinder case. Along these lines, different engine configurations, such as V-engines, may have cylinders grouped by cylinder banks or across cylinder banks, as desired.
The present disclosure is applicable to split combustion engines. A flowchart for a method of operating an alternating split combustion engine is shown in
While the compressed charge is entering the cylinder, fuel is provided to the cylinder in mixing relation with the incoming compressed charge at 616. The cylinder undergoes a combustion stroke at 618 and an exhaust stroke at 620, during which the exhaust valve may be partially open to allow a portion or the entire exhaust gas content of the cylinder to exit the cylinder into the exhaust manifold. Optionally, this process may be repeated continuously at each engine cylinder during engine operation.
It will be appreciated that the foregoing description provides examples of the disclosed system and technique. However, it is contemplated that other implementations of the disclosure may differ in detail from the foregoing examples. All references to the disclosure or examples thereof are intended to reference the particular example being discussed at that point and are not intended to imply any limitation as to the scope of the disclosure more generally. All language of distinction and disparagement with respect to certain features is intended to indicate a lack of preference for those features, but not to exclude such from the scope of the disclosure entirely unless otherwise indicated.
Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context.
Number | Name | Date | Kind |
---|---|---|---|
6216667 | Pekar | Apr 2001 | B1 |
6508233 | Suhre et al. | Jan 2003 | B1 |
6543225 | Scuderi | Apr 2003 | B2 |
6609371 | Scuderi | Aug 2003 | B2 |
6722127 | Scuderi et al. | Apr 2004 | B2 |
6880502 | Scuderi | Apr 2005 | B2 |
6952923 | Branyon et al. | Oct 2005 | B2 |
6983732 | Kuo et al. | Jan 2006 | B2 |
6986329 | Scuderi et al. | Jan 2006 | B2 |
7004115 | Patton | Feb 2006 | B2 |
7017536 | Scuderi | Mar 2006 | B2 |
7121236 | Scuderi et al. | Oct 2006 | B2 |
7201156 | Wait | Apr 2007 | B1 |
7353786 | Scuderi et al. | Apr 2008 | B2 |
7481190 | Scuderi | Jan 2009 | B2 |
7513224 | Heaton | Apr 2009 | B2 |
7536984 | Lou | May 2009 | B2 |
7571699 | Forner, Sr. et al. | Aug 2009 | B2 |
7588001 | Branyon et al. | Sep 2009 | B2 |
7603970 | Scuderi et al. | Oct 2009 | B2 |
7628126 | Scuderi | Dec 2009 | B2 |
7637234 | Tussing et al. | Dec 2009 | B2 |
7690337 | Pirault et al. | Apr 2010 | B2 |
7810459 | Branyon et al. | Oct 2010 | B2 |
7823547 | Forner, Sr. et al. | Nov 2010 | B2 |
7954461 | Branyon et al. | Jun 2011 | B2 |
7954462 | Scuderi et al. | Jun 2011 | B2 |
7954463 | Branyon et al. | Jun 2011 | B2 |
7963259 | Meldolesi et al. | Jun 2011 | B2 |
8006656 | Branyon et al. | Aug 2011 | B2 |
8256390 | Bonner | Sep 2012 | B1 |
20050000485 | Kuo et al. | Jan 2005 | A1 |
20050115547 | Bryant | Jun 2005 | A1 |
20050126522 | Ruggiero | Jun 2005 | A1 |
20070157894 | Scuderi et al. | Jul 2007 | A1 |
20080201058 | Bryant | Aug 2008 | A1 |
20090235881 | Bonner | Sep 2009 | A1 |
20090272368 | Branyon et al. | Nov 2009 | A1 |
20100229806 | Kemeny | Sep 2010 | A1 |
20100275878 | Phillips | Nov 2010 | A1 |
20120167566 | Gentili et al. | Jul 2012 | A1 |
20120192841 | Meldolesi et al. | Aug 2012 | A1 |
Number | Date | Country |
---|---|---|
WO 2011045642 | Apr 2011 | WO |
Entry |
---|
Coney et al., “A Novel Internal Combustion Engine with Simultaneous Injection of Fuel and Pre-Compressed Pre-Heated Air,” ASME Paper No. ICEF 2002-485, ICE vol. 39, pp. 67-77. |
Gronlund et al., “Valve Train Design for a New Gas Exchange Process,” SAE International 2004-01-0607, 13 pp. (2004). |
Musu et al., “CFD Study of HCPC Turbocharged Engine,” SAE International 2010-00-2107, 12 pp. (Oct. 25, 2010). |
Musu et al., “Clean Diesel Combustion by Means of the HCPC Concept,” SAE Int. J. Engines, vol. 3:1, Apr. 12, 2010, pp. 964-981. |
Musu et al., “Homogeneous Charge Progressive Combustion (HCPC) CFD Study of an Innovative Diesel HCCI Concept,” SAE International 2009-01-1344, 14 pp. (2009). |
Musu et al., “Improvements in Efficiency and Mixture Formation for an Innovative Diesel HCCI Concept,” ASME Paper No. ICEF 2002-485, ASME 2009 Tech. Conf., Sep. 20-24, 2009, pp. 181-190. |
Tamagna et al., “A Preliminary Study Towards an Innovative Diesel HCCI Combustion,” ASME Paper No. ICEF 2007-1743, ASME 2009 Tech. Conf., Oct. 14-17, 2007, pp. 329-341. |
Tiainen et al., “Novel Two-Stroke Engine Concept, Feasibility Study,” SAE International 2003-01-3211, 15 pp. (2003). |
“New Split-Cycle Concept to Control Diesel HCCI Combustion,” Green Car Congress, Oct. 25, 2010, downloaded from http://www.greencarcongress.com/2010/10/hcpc-20101025.html. |
Int'l Search Report for WO2011/045642, 3 pp., Jun. 15, 2011. |
Number | Date | Country | |
---|---|---|---|
20130298888 A1 | Nov 2013 | US |