Aluminum alloy excellent in cutting ability, aluminum alloy materials and manufacturing method thereof

FIELD OF THE INVENTION

The present invention relates to Al—Mg—Si series aluminum alloys excellent in cutting ability, aluminum alloy materials and manufacturing methods thereof.

BACKGROUND ART

In cutting aluminum alloy materials, there are problems that it is required to perform steps of disposing chips which is long and continuous and removing burrs generated at a corner of a product at the time of lathing or burrs generated at around a drilled hole at the time of drilling.

In order to solve these problems, an easy-to-cut aluminum alloy capable of suppressing cutting ability and burr generation by adding low fusing point elements such as Pb, Bi and Sn to enhance chip fractionizing nature, is proposed.

However, these low fusing point elements are often segregated at a crystal grain boundary. As a result, these elements tend to be partially fused by heat generated during, for example, heavy machining processing, which in turn results in crack generation. Furthermore, manufacturing and using such easy-to-cut aluminum alloy materials containing Pb that is a toxic element causes a serious problem from a viewpoint of earth environmental protection and also deteriorates recycling of aluminum products.

Accordingly, an easy-to-cut aluminum alloy containing Si or Cu as an alternative element of the aforementioned low fusing point element is developed.

For example, Japanese Unexamined Laid-open Patent Publication No. H11-12705 discloses an aluminum alloy to be forged containing Si: 3-11 mass %, Japanese Unexamined Laid-open Patent Publication No. H9-249931 discloses a high corrosion resistant aluminum alloy containing Si: 1.5-12.0 mass %, and Japanese Unexamined Laid-open Patent Publication No. H2-97638 discloses an aluminum alloy for magnetic tape contact component use containing Si: 2.0-12.5 mass % and Cu: 1.0-6.5 mass %. In these aluminum alloy materials, hard Si particles are dispersed in the aluminum matrix so that the Si particles can be ground at the time of cutting or the Si particles and the matrix interface thereof can be exfoliated to thereby break the chips into small pieces. Since these aluminum alloy materials do not contain low fusing point elements, they are excellent in recycling nature, and also excellent in corrosion resistance and heat resistance.

Furthermore, these aluminum alloy materials are manufactured by homogenizing a cast extruding billet of predetermined compositions, then extruding the billet at 400-600° C., into an extruded article at 350-550° C., and then quenching the extruded article at a die exit or performing a solution treatment after cutting the extruded article into a long cut article of 1-5 m length.

In the aforementioned conventional easy-to-cut aluminum alloy, however, if the alloy contains 5% or more of Si, since a large amount of Si particles are dispersed therein, there is a drawback that the Si particles having acute-angle portions attack a cutting edge of a cutting tool, and therefore the cutting tool will be heavily worn down or the cutting tool will be damaged, thereby shortening the life. On the other hand, in an aluminum alloy containing a large amount of Cu, there is a drawback that the alloy is poor in corrosion resistance.

Furthermore, in the aforementioned manufacturing process, although the Si particle may sometimes become 1 μm or less at the time of casting the billet, the particle tends to grow up to a size exceeding 1 μm due to a heat treatment of 300° C. or more, which is performed after the casting. Accordingly, the Si particle grows during each processing, i.e., homogenizing processing, extruding processing, quenching processing at a die exit and solution treatment processing, and finally grows up to a size of 5-10 μm. As a result, the alloy material obtained by performing the aforementioned series of processing is poor in cutting ability as compared to a cast member, which causes heavy abrasion or damage of a cutting tool. Concretely, if large Si particles with a mean particle diameter exceeding 5 μm exist in the aluminum matrix, tool damage such as tool abrasion or tool chipping will become serious. Furthermore, the tool damage deteriorates the quality of the machined surface obtained by a long and continuous cutting processing. Furthermore, if alumite processing is executed to the aluminum alloy materials containing such large and rough Si particles, there is a problem that the alumite coating thickness becomes uneven since the generation rate of alumite coat differs between the Si particles exposed to, the surface and the aluminum matrix.

SUMMARY OF THE INVENTION

In view of the aforementioned technical background, the present invention aims to provide aluminum alloys excellent in cutting ability, capable of suppressing abrasion and damage such as chipping of a cutting tool and having better alumite processability, aluminum alloy materials and manufacturing methods thereof.

The present invention includes aluminum alloys roughly classified by chemical composition into four types, aluminum alloy materials each having metal texture corresponding to each chemical composition, and methods for manufacturing these aluminum alloy materials.

A first aluminum alloy comprises Mg: 0.3-6 mass %, Si: 0.3-10 mass %, Zn: 0.05-1 mass %, Sr: 0.001-0.3 mass %, and the balance being aluminum and impurities.

In the first aluminum alloy, it is preferable that the content of Mg is 0.5-1.1 mass %. It is preferable that the content of Si is 1.5-5 mass %. It is preferable that the content of Zn is 0.1-0.3 mass %. It is preferable that the content of Sr is 0.005-0.05 mass %.

A second aluminum alloy comprises Mg: 0.3-6 mass %, Si: 0.3-10 mass %, Zn: 0.05-1 mass %, Sr: 0.001-0.3 mass %, one or more of selective additional elements selected from the group consisting of Cu: 0.01% or more but less than 1 mass %, Fe: 0.01-1 mass %, Mn: 0.01-1 mass %, Cr: 0.01-1 mass %, Zr: 0.01-1 mass %, Ti: 0.01-1 mass %, Na: 0.001-0.5 mass %, Ca: 0.001-0.5 mass %; and the balance being Aluminum and impurities.

In the second aluminum alloy, it is preferable that the content of Mg is 0.5-1.1 mass %. It is preferable that the content of Si is 1.5-5 mass %. It is preferable that the content of Zn is 0.1-0.3 mass %. It is preferable that the content of Sr is 0.005-0.05 mass %.

In the second aluminum alloy, it is preferable that the selective additional element is Cu. It is preferable that the selective additional element is Fe. It is preferable that the selective additional element is one or more elements selected from the group consisting Cr and Mn. It is preferable that the selective additional element is Zr. It is preferable that the selective additional element is Ti. It is preferable that the selective additional element is one or more elements selected from the group consisting of Na and Ca.

Furthermore, in the second aluminum alloy, it is preferable that the content of Cu is 0.1-0.3 mass %. It is preferable that the content of Fe is 0.1-0.3 mass %. It is preferable that the content of Mn is 0.1-0.3 mass %. It is preferable that the content of Cr is 0.1-0.3 mass %. It is preferable that the content of Zr is 0.1-0.3 mass %. It is preferable that the content of Ti is 0.1-0.3 mass %. It is preferable that the content of Na is 0.005-0.3 mass %. It is preferable that the content of Ca is 0.005-0.3 mass %.

A first aluminum alloy material according to the present invention is an aluminum alloy material having chemical composition as recited in claim 1. That is, an aluminum alloy material composed of an aluminum alloy, wherein the aluminum alloy comprises Mg: 0.3-6 mass %, Si: 0.3-10 mass %, Zn: 0.05-1 mass %, Sr: 0.001-0.3 mass %, and the balance being aluminum and impurities, as a chemical composition thereof, and wherein a mean particle diameter of Si particle is 1-5 μm and a mean aspect ratio of Si particle is 1-3, as an alloy texture of the aluminum alloy.

In this aluminum alloy material, it is preferable that the mean particle diameter of the Si particle is 3 μm or less. The mean aspect ratio of the Si particle is preferably 2 or less.

A second aluminum alloy material according to the present invention is an aluminum alloy material having chemical composition as recited in claim 2. That is, an aluminum alloy material is composed of an aluminum alloy, wherein the aluminum alloy comprises Mg: 0.3-6 mass %, Si: 0.3-10 mass %, Zn: 0.05-1 mass %, Sr: 0.001-0.3 mass %, and the balance being aluminum and impurities, as a chemical composition thereof, and wherein a mean particle diameter of Si particle is 1-5 μm and a mean aspect ratio of Si particle is 1-3, as an alloy texture of the aluminum alloy.

One of the aluminum alloy materials according to the present invention is composed of the first or second aluminum alloy in chemical composition, i.e., any one of aluminum alloys as recited in claims 1-24, and a mean particle diameter of Si particle is 1-5 μm and a mean aspect ratio of Si particle is 1-3, as an alloy texture of the aluminum alloy.

In the above aluminum materials, it is preferable that the mean particle diameter of the Si particle is 3 μm or less. The mean aspect ratio of the Si particle is preferably 2 or less.

A method for manufacturing the first aluminum alloy material is a method for suitably used to manufacture the first aluminum alloy material. That is, a method for manufacturing an aluminum alloy material, comprises: making a billet at a casting rate of 10-180 mm/min., the billet composed of aluminum alloy comprising Mg: 0.3-6 mass %, Si: 0.3-10 mass %, Zn: 0.05-1 mass %, and Sr: 0.001-0.3 mass %, and the balance being aluminum and impurities; homogenizing the billet at 400-570° C. for 6 hours or more to obtain a homogenized billet; extruding the homogenized billet at a billet temperature of 300-550° C., an extrusion rate of 0.5-100 m/min. and an extrusion ratio of 10-200 into an extruded article having a predetermined configuration; executing a solution treatment to the extruded article at 400-570° C. for 1 hour or more; and aging the solution treated extruded article at 90-300° C. for 1-30 hours.

In the aforementioned aluminum alloy material manufacturing method, it is preferable that the casting rate is 30-130 mm/min. The homogenization is preferably performed at 500-545° C. for 10 hours or more. The extrusion is preferably performed at the billet temperature of 350-500° C., the extrusion rate of 2-30 m/min. and the extrusion ratio of 20-85. The solution treatment is preferably performed at 500-545° C. for 3 hours or more. The aging is preferably performed at 140-200° C. for 3 -20 hours. It is preferable that the solution treated extruded article is drawn at a reduction rate of 5-30% into a predetermined configuration, and thereafter the aging is performed. Especially, the reduction rate of the drawing is preferably 10-20%.

A method for manufacturing the second aluminum alloy material is a method for suitably used to manufacture the second aluminum alloy material. That is, a method for manufacturing an aluminum alloy material, comprises: making a billet at a casting rate of 10-180 mm/min., the billet composed of aluminum alloy comprising Mg: 0.3-6 mass %, Si: 0.3-10 mass %, Zn: 0.05-1 mass %, and Sr: 0.001-0.3 mass %, one or more selective additional elements selected from the group consisting of Cu: 0.01 mass % or more but less than 1 mass %, Fe: 0.01-1 mass %, Mn: 0.01-1 mass %, Cr: 0.01-1 mass %, Zr: 0.01-1 mass %, Ti: 0.01-1 mass %, Na: 0.001-0.5 mass %, Ca: 0.001-0.5 mass %, and the balance being aluminum and impurities; homogenizing the billet at 400-570° C. for 6 hours or more to obtain a homogenized billet; extruding the homogenized billet at a billet temperature of 300-550° C., an extrusion rate of 0.5-100 m/min., and an extrusion ratio of 10-200 into an extruded article having a predetermined configuration; executing a solution treatment to the extruded article at 400-570° C. for 1 hour or more; and aging the solution treated extruded article at 90-300° C. for 1-30 hours.

In the aforementioned method for manufacturing an aluminum alloy material, it is preferable that the casting rate is 30-130 mm/min. The homogenization is preferable performed at 500-545° C. for 10 hours or more. The extrusion is preferably performed at the billet temperature of 350-500° C., the extrusion rate of 2-30 m/min. and the extrusion ratio of 20-85. The solution treatment is preferably performed at 500-545° C. for 3 hours or more. The aging is preferably performed at 140-200° C. for 3-20 hours. It is preferable that the solution treated extruded article is drawn at a reduction rate of 5-30% into a predetermined configuration, and thereafter the aging is performed. Especially, it is preferable that the reduction rate of the drawing is 10-20%.

A third aluminum alloy comprises: Mg: 0.1-6 mass %; Si: 0.3-12.5 mass %; Cu: 0.01 mass % or more but less than 1 mass %; Zn: 0.01-3 mass %; Sr: 0.001-0.5 mass %; and the balance being aluminum and impurities.

In the third aluminum alloy, it is preferable that the content of Mg is 0.3-5 mass %. The content of Si is preferably 0.8-12 mass %. The content of Cu is preferably 0.1-0.8 mass %. The content of Zn is preferably 0.05-1.5 mass %. The content of Sr is preferably 0.005-0.3 mass %.

A fourth aluminum alloy comprises: Mg: 0.1-6 mass %; Si: 0.3-12.5 mass %; Cu: 0.01 mass % or more but less than 1 mass %; Zn: 0.01-3 mass %; Sr: 0.001-0.5 mass %; one or more of selective additional elements selected from the group consisting of Ti: 0.001-1 mass %, B: 0.0001-0.03 mass %, C, 0.0001-0.5 mass %, Fe: 0.01 -1 mass %, Cr: 0.01-1 mass %, Mn: 0.01-1 mass %; Zr: 0.01-1 mass %, V: 0.01-1 mass %, Sc: 0.0001-0.5 mass %, Ni: 0.005-1 mass %, Na: 0.001-0.5 mass %, Sb: 0.001-0.5 mass %, Ca: 0.001-0.5 mass %, Sn: 0.01-1 mass %, Bi: 0.01-1 mass %, In: 0.001-0.5 mass %; and the balance being Aluminum and impurities.

In the fourth aluminum alloy, it is preferable that the content of Mg is 0.3-5 mass %. The content of Si is preferably 0.8-12 mass %. The content of Cu is preferably 0.1-0.8 mass %. The content of Zn is preferably 0.05-1.5 mass %. The content of Sr is preferably 0.005-0.3 mass %.

In the fourth aluminum alloy, it is preferable that the selective additional element is one or more elements selected from the group consisting of Ti, B, C and Sr. The selective additional element is preferably Fe. The selective additional element is preferably one or more elements selected from the group consisting Cr and Mn. The selective additional element is preferably one or more elements selected from the group consisting Zr and V. The selective additional element is preferably Ni. The selective additional element is preferably one or more elements selected from the group consisting Na, Sb and Ca. The selective additional element is preferably one or more elements selected from the group consisting Sn, Bi and In.

In the fourth aluminum alloy, it is preferable that the content of Ti is 0.003-0.5 mass %. The content of B is preferably 0.0005-0.01 mass %. The content of C is preferably 0.001-0.3 mass %. The content of Fe is preferably 0.05-0.7 mass %. The content of Cr is preferably 0.03-0.7 mass %. The content of Mn is preferably 0.03-0.7 mass %. The content of Zr is preferably 0.03-0.7 mass %. The content of V is preferably 0.03-0.7 mass %. The content of Sc is preferably 0.01-0.3 mass %. The content of Ni is preferably 0.03-0.7 mass %. The content of Na is preferably 0.005-0.3 mass %. The content of Sb is preferably 0.005-0.3 mass %. The content of Ca is preferably 0.005-0.3 mass %. The content of Sn is preferably 0.05-0.5 mass %. The content of Bi is preferably 0.05-0.5 mass %. The content of In is preferably 0.01-0.3 mass %.

A third aluminum alloy material according to the present invention is an alloy material having chemical composition of the third aluminum alloy. That is, an aluminum alloy material composed of aluminum alloy is composed of an aluminum alloy comprising Mg: 0.1-6 mass %, Si: 0.3-12.5 mass %, Cu: 0.01 mass % or more but less than 1 mass %, Zn: 0.01-3 mass %, Sr: 0.001-0.5 mass %, and the balance being aluminum and impurities, wherein, in metal texture, a mean dendrite arm spacing is 1-200 μm, a dendrite boundary zone includes eutectic Si particles of 0.01-5 μm of mean particle diameters and other second phase particles, and an eutectic lamella texture in which a mean skeleton line length (Lm) in a longitudinal direction is 0.5 μm or more and a mean width (Wm) is 0.5 μm or more is formed in a shape of a network.

In the aluminum alloy material, it is preferable that, in the eutectic lamella texture, the eutectic Si particles and other second phase particles exist 500 pieces/mm²or more in total, and the area share of these particles is 0.1-50%. The mean dendrite arm spacing is preferably 3-100 μm. The mean particle diameter of the eutectic Si particle is preferably 0.1-3 μm. Preferably, the eutectic lamella texture has a mean skeleton line length (Lm) of 3 μm or more and a mean width (Wm) of 1 μm or more. The mean ratio (L/Wm) of the skeleton line length to the skeleton width in the eutectic lamella texture is preferably 3 or more.

Furthermore, it is preferable that the eutectic Si particles and other second phase particles exist 1,000 pieces/mm²or more in total. The area share of the eutectic Si particles and other second phase particles is preferably 0.3-40%.

A fourth aluminum alloy material according to the present invention is an alloy material having chemical composition of the third aluminum alloy. That is, an aluminum alloy material is composed of an aluminum alloy, wherein the aluminum alloy comprises Mg: 0.1-6 mass %; Si: 0.3-12.5 mass %; Cu: 0.01 mass % or more but less than 1 mass %; Zn: 0.01-3 mass %; Sr: 0.001-0.5 mass %; one or more of selective additional elements selected from the group consisting of Ti: 0.001-1 mass %, B:0.0001-0.03 mass %, C, 0.0001-0.5 mass %, Fe: 0.01-1 mass %, Cr: 0.01-1 mass %, Mn: 0.01-1 mass %, Zr: 0.01-1 mass %, V: 0.01-1 mass %, Sc: 0.0001-0.5 mass %, Ni: 0.005-1 mass %, Na: 0.001-0.5 mass %, Sb: 0.001-0.5 mass %, Ca: 0.001-0.5 mass %, Sn: 0.01-1 mass %, Bi: 0.01-1 mass %, In: 0.001-0.5 mass %; and the balance being Aluminum and impurities, and wherein, in metal texture, a mean dendrite arm spacing is 1-200 μm, a dendrite boundary zone includes eutectic Si particles of 0.01-5 μm of mean particle diameter and other second phase particles, and an eutectic lamella texture in which a mean skeleton line length (Lm) in a longitudinal direction is 0.5 μm or more and a mean width (Wm) is 0.5 μm or more is formed in a shape of a network.

In the aforementioned aluminum alloy material, in the eutectic lamella texture, the eutectic Si particles and other second phase particles exist 500 pieces/mm²or more in total, and the area share of these particles is 0.1-50%. The mean dendrite arm spacing is preferably 3-100 μm. The mean particle diameter of the eutectic Si particle is preferably 0.1-3 μm. Preferably, the eutectic lamella texture has a mean skeleton line length (Lm) of 3 μm or more and a mean width (Wm) of 1 μm or more. The mean ratio (L/Wm) of the skeleton line length to the skeleton width in the eutectic lamella texture is preferably 3 or more.

A method for manufacturing the third aluminum alloy material is a method for suitably used to manufacture the third aluminum alloy material. That is, a method for manufacturing an aluminum alloy material, the method comprises: continuously casting molten aluminum alloy to obtain a shape member having a prescribed cross section at a casting rate of 30-5000 mm/min. and a cooling rate of 10-600 r/sec., the molten aluminum alloy comprising Mg: 0.1-6 mass %, Si: 0.3-12.5 mass %, Cu: 0.01 mass % or more but less than 1 mass %, Zn: 0.01-3 mass %, Sr: 0.001-0.5 mass % and the balance being aluminum and impurities and held at the solidus temperature or more; thereafter aging the shape member at 100-300° C. for 0.5-100 hours.

In the aforementioned method for manufacturing an aluminum alloy material, it is preferable that the casting rate is 100-2000 mm/min. The cooling rate is preferably 30-300° C./sec. The aging is preferably performed at 120-220° C. for 1-30 hours. Preferably, the shape member is a non-hollow member. It is preferable that the shape member circumscribes to a circle with a diameter of 10-150 mm in cross section. It is preferable that the method further comprises a step of removing a surface layer portion of a 0.1-10 mm depth from the continuously cast shape member. The removed surface layer portion is preferably 0.2-5 mm in depth.

It is preferable that the method further comprises the step of performing a secondary forming processing of a cross-sectional area decreasing ratio of 30% or less to the shape member after the continuous casting at a temperature of 400° C. or below. The processing temperature is preferably 250° C. or below. The cross-sectional area decreasing ratio is preferably 20% or less.

A method for manufacturing the fourth aluminum alloy material is a method for suitably used to manufacture the fourth aluminum alloy material. That is, a method for manufacturing an aluminum alloy material, comprises: continuously casting molten aluminum alloy to obtain a shape member having a prescribed cross section at a casting rate of 30-5,000 mm/min. and a cooling rate of 10-600° C./sec., the molten aluminum alloy comprising Mg: 0.1-6 mass %, Si: 0.3-12.5 mass %, Cu: 0.01 mass % or more but less than 1 mass %, Zn: 0.01-3 mass %, Sr: 0.001-0.5 mass %, one or more of selective additional elements selected from the group consisting of Ti: 0.001-1 mass %, B: 0.0001-0.03 mass %, C, 0.0001-0.5 mass %, Fe: 0.01-1 mass %; Cr: 0.01-1 mass %, Mn: 0.01-1 mass %, Zr: 0.01-1 mass %, V: 0.01-1 mass %, Sc: 0.0001-0.5 mass %, Ni: 0.005-1 mass %, Na: 0.001-0.5 mass %, Sb: 0.001-0.5 mass %, Ca: 0.001-0.5 mass %, Sn: 0.01-1 mass %, Bi: 0.01-1 mass %, In: 0.001-0.5 mass %, and the balance being aluminum and impurities and held at the solidus temperature or more; thereafter aging the shape member at 100-300° C. for 0.5-100 hours.

In the aforementioned method for manufacturing an aluminum alloy material, it is preferable that the casting rate is 100-2,000 mm/min. The cooling rate is 30-300° C./sec. The aging is preferably performed at 120-220° C. for 1-30 hours. Preferably, the shape member is a non-hollow member. It is preferable that the shape member circumscribes to a circle with a diameter of 10-150 mm in cross section. It is preferable that the method further comprises a step of removing a surface layer portion of a 0.1-10 mm depth from the continuously cast shape member. Preferably, the removed surface layer portion is 0.2-5 mm in depth.

Furthermore, it is preferable that the method further comprises the step of performing a secondary forming processing of a cross-sectional area decreasing ratio of 30% or less to the shape member after the continuous casting at a temperature of 400° C. or below. The processing temperature is preferably 250° C. or below. Furthermore, the cross-sectional area decreasing ratio is preferably 20% or less.

In the following explanation, the aforementioned four types of first to fourth aluminum alloys will be detailed by classifying them into the first and second aluminum alloys containing Mg, Si, Zn and Sr as common indispensable elements and the third and fourth aluminum alloys containing Mg, Si, Cu, Zn and Sr as common indispensable elements. Following the explanation of each aluminum alloy composition, the aluminum alloy materials and the manufacturing methods thereof corresponding to these compositions will be explained.

I. The First and Second Aluminum Alloys, Alloy Materials, and the Manufacturing Methods (Claims 1-46)

The first and second aluminum alloys and the alloy materials having the chemical compositions thereof suppress abrasion and damage of a cutting tool by rounding and fining Si particles while securing good cutting ability caused by the enhanced chip breakable nature due to the Si particles. Furthermore, in addition to the strengthening by the main deposit, Mg₂Si, the strength of the alloys are notably improved by the excessive Si particles, as compared to conventional alloys.

Hereinafter, the reasons for adding each element and for limiting the amount of each element in the aluminum alloys and the alloy materials will be detailed.

In the composition of the aforementioned aluminum alloy, four elements of Mg, Si, Zn and Sr are essential elements. The first aluminum alloy (claims 1-5) according to the present invention comprises these 4 elements and the balance being aluminum and impurities.

Mg is dissolved in an alloy matrix and dispersed as deposits such as Mg₂Si created by bonding with excessive Si, etc in the matrix, to thereby enhance the mechanical property, especially proof strength and further improve the cutting ability of the alloy by the synergistic effect with other solid solution type elements. If the Mg content is less than 0.3 mass %, the aforementioned effects cannot be obtained sufficiently. To the contrary, if the Mg content exceeds 6.0 mass %, oxidation of an alloy molten metal is promoted and plastic-working nature deteriorates. Accordingly, the Mg content should be 0.3-6 mass %. Preferably, the Mg content is 0.5-1.1 mass %.

Since only few amount of Si can be dissolved in an aluminum, Si is dispersed in the matrix as a single particle of Si except for the amount required for compound formation. In the alloy texture in which Si particles are dispersed, since the Si particles are ground by a cutting tool and/or the Si particle and the aluminum base phase are peeled at the interface, the chips can be easily broken, resulting in improved cutting ability. Furthermore, the Si particles become round and fine by Sr added as an essential element, or Na, Ca added as an arbitrary element, which also improves the cutting ability. If Si content is less than 0.3 mass %, sufficient chip breaking effects cannot be obtained. To the contrary, if Si content exceeds 10 mass %, although the chip breaking effects can be improved, a cutting tool will be abraded heavily, causing deteriorated productivity. Accordingly, it is necessary that Si content is 0.3-10 mass %. From this point of view, the preferable Si content is 1.5-5 mass %.

Zn dissolves in an alloy matrix, while Zn bonds with Mg and disperses in a matrix as deposit of MgZn₂. This improves the mechanical property of the aluminum alloy and the cutting ability of the alloy by the synergistic effects of other dissolve type elements. If Zn content is less than 0.05 mass %, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Zn content exceeds 1 mass %, the corrosion resistance may deteriorate. Accordingly, it is necessary that Zn content is 0.05-1 mass %. Furthermore, if the Zn content falls within the range, it is effective in improving an alumite coat generation rate, and therefore the alloy can be suitably used for a product to which alumite processing is performed for the purpose of improving the abrasion resistance. The preferable Zn content is 0.1-0.3 mass %.

Sr makes eutectic Si at the time of solidification and proeutectic Si round and fine when Sr coexists with Si. This indirectly improves the chip breaking nature, which in turn improves the cutting ability and suppresses abrasion and damage on a cutting tool. Furthermore, Sr has effects of making Si particles disperse uniformly and finely at the steps of continuous casting, extrusion, drawing, etc., thereby further improving the cutting ability. If Sr content is less than 0.001 mass %, the aforementioned effects cannot be obtained sufficiently and the Si particle cannot be rounded, causing acute portions, which results in heavy abrasion of a cutting tool. To the contrary, if Sr exceeds 0.3 mass %, the aforementioned effects will be saturated, resulting in fruitless addition. Accordingly, Sr should be 0.001-0.3 mass %. Preferably, the Sr content is 0.005-0.05 mass %.

The second aluminum alloy according to the present invention (Claims 6-24) is an aluminum alloy containing the aforementioned four essential elements as basic compositions and further containing one or more arbitrary combined elements selected from the group consisting of eight elements, Cu, Fe, Mn, Cr, Zr, Ti, Na and Ca for the purpose of further improving various characteristics of the alloy.

Cu dissolves in an alloy matrix, while Cu bonds with Al and disperses in a matrix as deposit of CuAl₂. This improves the mechanical property and cutting ability of an aluminum alloy by the synergistic effects with other dissolve type elements. If Cu content is less than 0.01 mass %, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Cu content exceeds 1 mass %, there is a possibility that corrosion resistance deteriorates. Accordingly, it is preferable that Cu content is 0.01 or more but less than 1 mass %. More preferably, the Cu content is 0.1-0.3 mass %.

Fe is an inevitable element contained in an aluminum alloy. The content falling within the range of 0.01-1 mass % is a normal amount contained during manufacturing an aluminum alloy. Therefore, no special step for decreasing Fe content is required. Furthermore, if Fe content falls within the aforementioned range, since only a few amount of Fe bonds with Si, Si, which is effective to improve chip breaking effect, can be distributed as an individual particle, which can maintain outstanding chip breaking nature. In order to decrease the Fe content less than 0.01 mass %, the cost increases. To the contrary, if Fe content exceeds 1 mass %, Fe compounds with Si increase and Si individual particles decrease, resulting in deteriorated chip breaking nature. It is preferable that Fe content is 0.1-0.3 mass %.

Mn and Cr are elements to be added in order to improve mechanical strength by suppressing recrystallization in an aluminum alloy and enhance corrosion resistance. If Mn content and Cr content is less than 0.01 mass % respectively, it is difficult to obtain sufficient recrystallization inhibition effect and improve mechanical property and corrosion resistance. Furthermore, the chip breaking nature in the cross-sectional direction becomes unstable because of the recrystallized large particles. To the contrary, if the content exceeds 1 mass %, the hot deformation resistance at the time of extrusion increases, resulting in deteriorated productivity. Therefore, it is preferable that Mn content and Cr content are 0.01-1 mass % respectively. Furthermore, if Mn and Cr content falls within the aforementioned range, since only a few amount thereof bonds with Si, Si, which is effective in improving chip breaking effect, can be distributed as an individual particle, which can maintain outstanding chip breaking nature. More preferable Mn content and Cr content are 0.1-0.3 mass %, respectively.

Zr is an elements to be added in order to improve mechanical strength by suppressing generation of large particle due to recrystallization in an aluminum alloy and enhance corrosion resistance. Furthermore, intermetallic compounds are formed by Zr and Al, and dispersed in a matrix. This improves cutting ability. If Zr content is less than 0.01 mass %, it is difficult to obtain sufficient recrystallization inhibition effect and improve mechanical property and corrosion resistance. Furthermore, the chip breaking nature in the cross-sectional direction becomes unstable because of the recrystallized large particles, and the cutting improvement effect is poor. To the contrary, if the content exceeds 1 mass %, the extrusion nature and/or castability deteriorates remarkably. Therefore, it is preferable that Zr content is 0.01-1 mass %. From this view point, more preferable Zr content is 0.1-0.3 mass %.

Ti is, similar to Zr, an elements to be added in order to improve mechanical strength by suppressing generation of large particle due to recrystallization in an aluminum alloy and enhance corrosion resistance. If Ti content is less than 0.01 mass %, it is difficult to obtain sufficient recrystallization inhibition effect and improve mechanical property and corrosion resistance. Furthermore, the chip breaking nature in the cross-sectional direction becomes unstable because of the recrystallized large particles, and the cutting improvement effect is poor. To the contrary, if the content exceeds 1 mass %, the extrusion nature and/or castability deteriorates remarkably. Therefore, it is preferable that Ti content is 0.01-1 mass %. From this view point, more preferable Ti content is 0.1-0.3 mass %.

Na and Ca are elements to be added, similar to the aforementioned Sr, in order to round Si particle and disperse Si particles uniformly. If Na content is less than 0.001 mass %, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Na content exceeds 0.5 mass %, the effects will be saturated. Accordingly, it is preferable that Na content is 0.001-0.5 mass %. If Ca content is less than 0.001 mass %, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Ca content exceeds 0.5 mass %, the effects will be saturated. Accordingly, it is preferable that Ca content is 0.001-0.5 mass %. More preferably, Na content is 0.005-0.3 mass %, Ca content is 0.005-0.3 mass %.

In the aluminum alloy and alloy material according to the present invention, since Sr, which is effective in rounding Si individual particle and dispersing Si particles uniformly, is contained as an essential element, an addition of Na and Ca is arbitrary. Therefore even if these elements are not added, the rounding of Si particle and uniform dispersibility of Si particles are secured.

As for the aforementioned eight elements to be arbitrarily selected, the aforementioned effects can be obtained by adding at least one element or two or more arbitrarily combined elements to the essential four elements. The aluminum alloys as recited in claims 11-16 include selective additional element(s) in order to obtain a predetermined effect. In cases where two or more elements are added, it is also preferable to selectively combine two or more elements different in effect. For example, these selective additional elements are classified into: A group element (Cu) which improves mechanical property by deposit such as CuAl₂; B group element (Fe) which distributes Si as individual particles; C group element (Cr, Mn) which improves mechanical strength by suppressing recrystallization; D group element (Ti) which improves mechanical strength by suppressing generation of large and rough particles due to recrystallization and also improves corrosion resistance; E group element (Zr) which improves mechanical strength by suppressing generation of large and rough particles due to recrystallization, improves corrosion resistance and also improves cutting ability by forming intermetallic compounds; and F group elements (Na, Ca) which are effective in rounding Si particle and making Si particle into small pieces. Then, one or two or more arbitrarily combined groups are added to the essential elements. As for the group comprising plural elements, one or more elements are arbitrarily selected within the group. In cases where arbitrary additional elements are selected per one group, the content of each element should fall within the aforementioned range.

The first and the second aluminum alloy materials (Claims 25-27 and Claims 28-30) defines the chemical compositions of an alloy falling within the range of the aforementioned first and the second aluminum alloys (claims 1 and 6 respectively) and the mean particle diameter and mean aspect ratio of Si particle in an alloy texture.

Although Si particles improve cutting ability by serving as chip breaking origins at the time of cutting, it is required that Si particle is fine and spherical in order to suppress abrasion of a tool and that the mean particle diameter is 1-5 μm and the mean aspect ratio is 1-3. Si particle has a tendency that the mean particle diameter and the mean aspect ratio become larger as the Si content increases. Although good cutting ability can be obtained even if the mean particle diameter exceeds 5 μm, a tool will be abraded heavily if the mean aspect ratio becomes larger. Accordingly, in this invention, in order to realize both good cutting ability and suppressed abrasion of a tool, the mean particle diameter and mean aspect ratio of Si particle are specified within the aforementioned range. From the viewpoint of obtaining outstanding cutting ability and suppressing abrasion of a tool, the preferable mean particle diameter of Si particle is 3 μm or less, and the preferable mean aspect ratio is two or less.

The first and second aluminum alloys mentioned above can be manufactured by the method for manufacturing the first and second aluminum alloy materials respectively (Claims 31-38, Claims 39-46). That is, the alloy material in which fined and rounded Si particles are distributed uniformly can be manufactured by using an alloy having predetermined chemical compositions and specifying the processing conditions of from a casting and extrusion of a billet to a drawing of the extruded article and heat treatment conditions.

A billet is formed at the casting rate of 10-180 mm/min. During this casting, the Si—Sr compound in a molten metal serves as a nucleus, and rounded proeutectic Si and eutectic Si are dispersed in the aluminum. As a result, fined and rounded Si particles can be obtained by the following heat treatment and extruding processing, or the drawing processing. Furthermore, since Si particles are rarely partially segregated at the crystal grain boundary and uniformly distributed in a cross-section, stable chip breaking nature can be obtained. If the casting rate is less than 10 mm/min., Si particle becomes larger and the particle distribution becomes rough. Therefore, stable chip breaking nature cannot be obtained. To the contrary, if the casting rate exceeds 180 mm/min., a casting surface may become bad or solidification crack may occur. The preferable casting rate is 30-130 mm/min.

The homogenization processing of the billet is performed by holding the billet at 400-570° C. for 6 hours or more. Since this homogenization processing causes stable growth of Si particles and dissolving of other dissolve type elements, no partial segregation at the dendrite boundary zone or the crystal grain-boundary occurs. Accordingly, the cutting ability, mechanical property and corrosion resistance of the finally obtained alloy material become good. If the homogenization processing performed at less than 400° C., or for less than 6 hours, Si particle does not stably grows, and dissolve type elements are not dispersed, and not dissolved in the aluminum. Accordingly, corrosion resistance deteriorates at the segregated portion, and stable chip breaking nature cannot be obtained. To the contrary, if the temperature exceeds 570° C., voids are formed in the alloy texture by the eutectic fusion of aluminum and other each element, causing a deterioration of mechanical property. The preferable homogenization processing condition is to hold the billet at 500-545° C. for 10 hours or more.

The extrusion is performed at the billet temperature of 300-550° C., the extrusion product rate of 0.5-100 m/min. and the extrusion ratio of 10-200. By performing the extrusion under the conditions, Si particles will be dispersed uniformly at the crystal grain boundary without causing partial segregation, which does not spoil the cutting ability, mechanical property and corrosion resistance of the finally obtained alloy material. Furthermore, the productivity will be also good. If the billet temperature is less than 300° C., the extrusion rate will deteriorate, resulting in poor productivity. The productivity will also deteriorate when the extrusion product rate is less than 0.5 m/min. Furthermore, if the extrusion ratio is less than 10, the distributed state of Si particles will not become uniform, and Si particles will be partially segregated at the old dendrite boundary zone. This causes unstable cutting ability and deteriorated mechanical property and corrosion resistance. To the contrary, if the billet temperature exceeds 550° C., the extrusion product rate exceeds 100 m/min. or the extrusion ratio exceeds 200, tears, pickups and the like arise on the surface of the extruded member, resulting in deteriorated surface quality. The preferable billet temperature is 350-500° C., the preferable extrusion product rate is 2-30 m/min., and the preferable extrusion ratio is 20-85.

The solution treatment after the extrusion is performed by holding the billet at 400-570° C. for 1 hour or more. This solution treatment rounds Si particle, and therefore stable chip breaking nature can be obtained. Furthermore, the solution treatment decreases the partial segregation at the crystal grain boundary of the additional element, and therefore high mechanical property and high corrosion resistance can be obtained. If the solution treatment condition is less than 400° C. or less than 1 hour, mechanical strength becomes insufficient and chip breaking nature becomes poor. To the contrary, if the temperature exceeds 570° C., partial fusion at the crystal grain boundary occurs, and mechanical property deteriorates remarkably. The preferable solution treatment is performed by holding the billet at 500-545° C. at 3 hours or more.

The aging treatment is performed by holding the billet at 90-300° C. for 1-30 hours. This causes the maximum strength and good chip breaking nature of the aluminum alloy material. If the aging temperature is less than 90° C. or the holding time is less than 1 hour, the aging becomes insufficient, the finished surface at the time of cutting becomes rough and the mechanical property deteriorates. To the contrary, if the aging temperature exceeds 300° C. or the aging time exceeds 30 hours, the aging becomes excessive, which deteriorates chip breaking nature and mechanical property. The preferable aging is performed by holding the billet at 140-200° C. for 3-20 hours.

The extruded member after the solution treatment is preferably drawn at a reduction rate of 5-30% into a predetermined configuration. This drawing forms a predetermined configuration, and also can improve the mechanical property by fining the recrystallized structure of the surface formed at the time of extrusion. Furthermore, high dimensional accuracy in the longitudinal direction can be obtained. If the drawing reduction rate is less than 5%, the aforementioned effect becomes poor. To the contrary, if it exceeds 30%, tension breaks may occur at the time of drawing. The preferable reduction is 10-20%.

Other manufacturing conditions follow those for a conventional method.

II. The Third and Fourth Aluminum Alloys, Alloy Materials, and the Manufacturing Methods (Claims 47-119)

The third and fourth aluminum alloys and the aluminum alloy materials including the chemical compositions thereof can further enhance the cutting ability due to Si particles obtained by the predetermined chemical compositions by further specifying the metal texture, and can suppress abrasion and damage on a cutting tool by controlling Si particle size.

Hereinafter, the reasons for adding each element and for limiting the amount of each element in the aluminum alloys and the alloy materials will be detailed.

In the composition of the aforementioned aluminum alloy, five elements of Mg, Si, Cu, Zn and Sr are essential elements. The third aluminum alloy (claims 47-52) according to the present invention comprises these five elements and the balance being aluminum and impurities.

Mg is dissolved in an alloy matrix and dispersed as deposits such as Mg₂Si created by bonding with Si, etc in the matrix, to thereby enhance the mechanical property, especially proof strength and further improve the cutting ability of the alloy by the synergistic effect with other solid solution type elements. If the Mg content is less than 0.1 mass %, the aforementioned effects cannot be obtained sufficiently. To the contrary, if the Mg content exceeds 6 mass %, oxidation of an alloy molten metal is promoted and plastic-working nature also deteriorates. Accordingly, the Mg content should be 0.1-6 mass %. Preferably, the Mg content is 0.3-5 mass %.

Since only a few amount of Si can be dissolved in an aluminum, Si is dispersed in the matrix as a single particle of Si except for the amount required for compound formation. Especially, the eutectic Si particles solidified and formed by the quick cooling at the time of the continuous casting of this invention become fine particles of 5 μm or less, and form eutectic lamella texture together with other second phase particles at the dendrite boundary zone. At the time of cutting, a cutting tool causes separation of the eutectic lamella texture, grinding of the eutectic Si particles, and/or interfacial peeling between the eutectic Si particles and the aluminum host phase. As a result, the chips become easy-to-break, which improves cutting ability remarkably. Furthermore, the Si particles are rounded and fined by Sr added as an essential element or Na, Ca added as an arbitrary element, which also improves the cutting ability. If Si content is less than 0.3 mass %, chip breaking nature, i.e., cutting ability improving effects, cannot be obtained sufficiently. To the contrary, if Si content exceeds 12.5 mass %, although the cutting ability can be improved, many big and rough eutectic Si particles are formed. Therefore, cutting tool damages such as abrasion and/or chipping occur heavily, causing deteriorated productivity. Accordingly, it is necessary that Si content is 0.3-12.5 mass %. From this point of view, the preferable Si content is 0.8-12 mass %, more preferably 1.2-8.5 mass %.

Cu dissolves in an alloy matrix, while Cu bonds with Al and disperses in a matrix as deposit of CuAl₂, etc. This improves the mechanical property and cutting ability of an aluminum alloy by the synergistic effects with other dissolve type elements. Furthermore, the CuAl₂also exists in the eutectic lamella texture, and improves cutting ability by participating the separation of the eutectic lamella texture at the time of cutting. If Cu content is less than 0.01 mass %, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Cu content exceeds 1 mass %, corrosion resistance may deteriorate. Accordingly, the Cu content is 0.01 or more but less than 1 mass %. More preferably, the Cu content is 0.1-0.8 mass %.

Zn dissolves in an alloy matrix, while Zn bonds with Mg and disperses in a matrix as deposit of MgZn₂, etc. This improves the mechanical property of the aluminum alloy and the cutting ability of the alloy by the synergistic effects of other dissolve type elements. If Zn content is less than 0.01 mass %, the aforementioned effects cannot be obtained sufficiently. To the contrary, if Zn content exceeds 3 mass %, there is a possibility that corrosion resistance deteriorates. Accordingly, it is necessary that Zn content is 0.01-3 mass %. Furthermore, if the Zn content falls within the range, it is effective in improving an alumite coat generation rate, and therefore the alloy can be suitably used for a product to which alumite processing is performed for the purpose of improving the abrasion resistance. The preferable Zn content is 0.05-1.5 mass %.

Sr makes eutectic Si at the time of solidification and proeutectic Si round and fine when Sr coexists with Si. This indirectly improves the chip breaking nature, which in turn improves the cutting ability and suppresses abrasion and damage such as chipping on a cutting tool. Furthermore, Sr has effects of making Si particles disperse uniformly and finely at the steps of continuous casting and/or the following secondary forming processing, thereby further improving the cutting ability. If Sr content is less than 0.001 mass %, the aforementioned effects cannot be obtained sufficiently, and the Si particle cannot be rounded, causing acute portions, which results in heavy abrasion or damage such as chipping of a cutting tool. To the contrary, if Sr exceeds 0.5 mass %, the aforementioned effects will be saturated, resulting in fruitless addition. The preferable Sr content is 0.005-0.3 mass %.

The fourth aluminum alloy according to the present invention (Claims 53-81) is an aluminum alloy containing the aforementioned five essential elements as basic compositions and further containing one or more arbitrary combined elements selected from the group consisting of sixteen elements, Ti, B, C, Fe, Cr, Mn, Zr, V, Sc, Ni, Na, Sb, Ca, Sn, Bi and In for the purpose of further improving various characteristics of the alloy.

Ti makes an ingot texture fine, and suppresses appearance of macro patterns and/or solidification cracks, which will be generated on the cut surface when the ingot texture is rough. If Ti content is less than 0.001 mass %, an ingot fining effect is poor. To the contrary, if it exceeds 1 mass %, rough Ti—Al series compounds will be formed, which may deteriorate castability and/or ductility of the aluminum alloy. Accordingly, it is preferable that Ti content is 0.001-1 mass %. The more preferable Ti content is 0.003-0.5 mass %.

B makes an ingot texture fine like Ti, and suppresses appearance of macro patterns and/or solidification cracks, which will be generated on the cut surface when the ingot texture is rough. If B content is less than 0.0001 mass %, an ingot fining effect is poor. To the contrary, if it exceeds 0.03 mass %, hard particles will be formed, which may increase abrasion and/or damages such as chipping. Accordingly, it is preferable that B content is 0.0001-0.03 mass %. The more preferable Ti content is 0.0005-0.01 mass %.

Fe is an element inevitably contained in an aluminum alloy. The content falling within the range of 0.01-1 mass % is a normal amount contained during manufacturing an aluminum alloy. Therefore, no special step for decreasing Fe content is required. Furthermore, if Fe content falls within the aforementioned range, since only a few amount of Fe bonds with Si, Si, which is effective to improve chip breaking effect, can be distributed as an individual particle, which can maintain outstanding chip breaking nature. In order to decrease the Fe content less than 0.01 mass %, the cost increases. To the contrary, if Fe content exceeds 1 mass %, Fe compounds with Si increase and Si individual particles decrease, resulting in deteriorated chip breaking nature. The more preferable Fe content is 0.05-0.7 mass %.

Zr and V make an ingot texture fine, and suppresses appearance of macro patterns and/or solidification cracks, which will be generated on the cut surface when the ingot texture is rough, like Ti and B. Furthermore, an intermetallic compound is formed between aluminum and cutting ability improves because they disperse to a matrix. If the content of each element is less than 0.01 mass %, the aforementioned effect is poor. To the contrary, if it exceeds 1 mass %, castability deteriorates. Accordingly, it is preferable that the content of each element is 0.01-1 mass %. The preferable content is 0.03-0.7 mass %. Furthermore, Zr has an effect of improving mechanical strength by suppressing the recrystallization and enhancing corrosion resistance, like below-mentioned Cr and Mn. As for these effects, if Zr content is less than 0.01 mass %, the mechanical property and corrosion resistance cannot be improved, and the chip breaking nature in the cross-sectional direction becomes unstable since large and rough particles are formed by recrystallization. To the contrary, if it exceeds 1 mass %, the hot deformation resistance at the time of secondary forming processing increases, resulting in deteriorated productivity. Accordingly, it is preferable that Zr content is 0.01-1 mass %, more preferably 0.03-0.7 mass %.

Cr and Mn are elements to be added in order to improve mechanical strength by suppressing recrystallization in an aluminum alloy and enhance corrosion resistance. If Cr content and Mn content are less than 0.01 mass % respectively, it is difficult to obtain sufficient recrystallization inhibition effect and improve mechanical property and corrosion resistance. Furthermore, the chip breaking nature in the cross-sectional direction becomes unstable because of the recrystallized large particles. To the contrary, if the content exceeds 1 mass %, the hot deformation resistance at the time of extrusion increases, resulting in deteriorated productivity. Therefore, it is preferable that Mn content and Cr content are 0.01-1 mass % respectively. Furthermore, if Mn and Cr content fall within the aforementioned range, since only a few amount thereof bonds with Si, Si, which is effective in improving chip breaking effect, can be distributed as an individual particle, which can maintain outstanding chip breaking nature. More preferable Mn content and Cr content are 0.03-0.7 mass %, respectively.

Sc and C make an ingot texture fine, and suppresses appearance of macro patterns and/or solidification cracks, which will be generated on the cut surface when the ingot texture is rough, like Zr, V, B and Ti. If these elements are less than 0.0001 mass % respectively, the aforementioned effect cannot be obtained sufficiently. To the contrary, if they exceed 0.5 mass % respectively, they bond with aluminum or other elements to form hard particles, which causes heavy abrasion or damage on a cutting tool. Accordingly, it is preferable that the contents are 0.0001-0.5 mass %. Their more preferable contents are 0.01-0.3 mass %, respectively.

Ni forms Ni—Al series intermetallic compounds to improve cutting ability. If Ni content is less than 0.005 mass %, the aforementioned effect cannot be obtained sufficiently. To the contrary, if the content exceeds 1 mass %, castability and corrosion resistance deteriorates. Accordingly, it is preferable that Ni content is 0.005-1 mass %, more preferably 0.03-0.7 mass %.

Na, Sb and Ca make eutectic Si at the time of solidification and proeutectic Si round and fine when they coexist with Si, like Sr. This indirectly improves the chip breaking nature, which in turn improves the cutting ability and suppresses abrasion and damage such as chipping on a cutting tool. If the content of each of these elements is less than 0.001 mass %, the aforementioned effects cannot be obtained sufficiently. To the contrary, if it exceeds 0.5 mass %, the aforementioned effects will be saturated, resulting in fruitless addition. Accordingly, it is preferable that each content is 0.001-0.5 mass %, more preferably 0.005-0.3 mass %.

Sn, Bi and In further improve cutting ability when they coexist with Si. The content thereof should be Sn: 0.01-1 mass %, Bi: 0.01-1 mass % and In: 0.001-0.5 mass %. If each content is below the lower limit, the aforementioned effects cannot be obtained sufficiently. To the contrary, if it exceeds the upper limit, the corrosion resistance deteriorates, and the quality of the finished surface also deteriorates since tears will be generated at the time of cutting, especially at the time of deep cutting. Furthermore, cracks will be induced at the time of the hot deformation. Their preferable content is Sn: 0.05-0.5 mass %, Bi: 0.05-0.5 mass %, and In: 0.01-0.3 mass %.

As for the aforementioned sixteen elements to be arbitrarily selected, the aforementioned effects can be obtained by adding at least one element or two or more arbitrarily combined elements to the essential five elements. The aluminum alloys as recited in claims 48-54 include selective additional element(s) in order to obtain predetermined effects. In cases where two or more elements are added, it is also preferable to selectively combine two or more elements different in effect. For example, these selective additional elements are classified into: A group element (Ti, B, C, Sc) which has an effect of fining an ingot texture and suppressing an appearance of a macro pattern and solidification cracks; B group element (Fe) which distributes Si as individual particles; C group element (Cr, Mn) which improves mechanical strength by suppressing recrystallization; D group element (Zr, V) which has effects of fining an ingot texture and of suppressing an appearance of a macro pattern and solidification cracks, and further improves cutting ability due to the formation of intermetallic compounds; E group element (Ni) which improves cutting ability by forming intermetallic compounds; F group element (Na, Sb, Ca) which has an effect of rounding and fining Si particle; and G group element (Sn, Bi, In) which improves cutting ability when it coexists with Si. Then, one or two or more arbitrarily combined groups are added to the essential elements. As for the group comprising plural elements, one or more elements are arbitrarily selected within the group. In cases where arbitrary additional elements are selected per one group, the content of each element should fall within the aforementioned range.

The third and fourth aluminum alloy materials (Claims 82-89 and Claims 90-97) define the chemical compositions of an alloy so as to fall within the range of the aforementioned third and fourth aluminum alloys (Claims 47 and 53), and specify the metal texture.

FIGS. 1 and 2 show an example of metal texture of an aluminum alloy material manufactured by casting according to the present invention. FIG. 3 shows an example of metal texture of an aluminum alloy material manufactured by performing processing such as heat treatment and extrusion after casting. The aluminum alloy material shown in FIG. 3 corresponds to the alloy material mentioned in the paragraph entitled “BACKGROUND ART” and pointed out that a further improvement is required in respect of cutting ability and abrasion of a tool.

In FIGS. 1 and 2, the portion shown with light color (in FIG. 1, the portion indicated as proeutectic α-Al) is a dendrite. At the boundary zone thereof, eutectic lamella texture (shown as dark colored portion) including eutectic Si particles (indicated as eutectic Si in FIG. 1) and other second phase particles is distributed in the shape of a three dimensional network. To the contrary, FIG. 3 showing the conventional aluminum alloy material reveals that the second phase of the dendrite boundary zone has been divided and Si particles have been changed to an independently distributed texture form.

The aluminum alloy material according to the present invention is made by considering the fact that the differences of the aforementioned metal textures influence cutting ability and abrasion and/or damage on a cutting tool. Concretely, the aluminum alloy material defines the dendrite arm spacing (hereinafter referred as “DAS”) and the eutectic lamella texture formed at the dendrite boundary zone.

In the metal texture, it is required that the average DAS (see FIG. 1) is 1-200 μm. The reason for limiting the average DAS within the aforementioned range is as follows. If the average DAS is less than 1 μm, although the cooling rate at the time of casting should be 1,000° C./sec. or more, the cooling rate exceeds the manufacture limitation as an ingot member. To the contrary, if the average DAS exceeds 200 μm, cutting ability and mechanical property will remarkably deteriorate. The preferable average DAS is 3-100 μm.

At the dendrite boundary zone, an eutectic lamella texture containing the eutectic Si particles each having a mean particle diameter of 0.01-5 μm and other second phase particles is formed in the aluminum host phase. At the time of cutting, the eutectic Si particles, even a single Si particle, become chip breaking origins, which improves cutting ability. Furthermore, the eutectic Si particles form layer-like eutectic lamella texture, and the eutectic lamella texture can be separated as if the eutectic lamella texture is peeled off, which improves cutting ability. Since such eutectic lamella texture is distributed in a continuous three-dimensional network, the aforementioned separation occurs continuously. As a result, cutting ability can be improved and abrasion of a cutting tool can be suppressed. To the contrary, in the metal texture form shown in FIG. 3, since Si particles as chip breaking origins are independently distributed, the cutting ability and abrasion of a cutting tool is inferior to those of the metal texture distributed in the shape of a network as shown in FIGS. 1 and 2.

If the mean particle diameter of the eutectic Si particle is less than 0.01 μm, the cutting ability improvement effect is poor. Furthermore, The eutectic Si particle tends to increase in size as the Si content increases. If the mean particle diameter exceeds 5 μm, although good cutting ability can be obtained, a tool will be heavily abraded or damaged such as chipped as the grain size becomes larger. Accordingly, in order to realize both good cutting ability and suppression of tool damage, the mean particle diameter of eutectic Si particle is limited to 0.01-5 μm. Especially, from the viewpoint of suppressing tool damage, the preferable mean particle diameter is 0.1-3 μm.

The aforementioned other second phase particles are particles generated between Al, such as a CuAl₂and Al—Fe—Si series, Al—Mn—Si series, Al—Cr—Si series and Al—Fe series, and an additional element. The preferable mean particle diameter is 0.1-0.3 μM.

As shown in FIG. 1, the size the eutectic lamella texture is represented by the skeleton line length (L) in the longitudinal direction and the width (W). The skeleton line length (L) is the length of the skeleton line showing the frame of the eutectic lamella texture, and the width (W) is the maximum width in the direction perpendicular to the skeleton line. In the present invention, the eutectic lamella texture is defined by the mean values of the aforementioned length and width and the ratio thereof, wherein the mean skeleton line length (Lm) is 0.5 μm or more, and the mean width (Wm) is 0.5 μm or more. If the mean skeleton line length (Lm) and mean width (Wm) are less than 0.5 μm, respectively, good cutting ability cannot be obtained. The preferable average skeleton line length (Lm) is 3 μm or more, and the preferable average width (Wm) is 1 μm or more. Furthermore, it is preferable to be a long and slender configuration in which the mean value (L/Wm) of the ratio (L/W) of the skeleton line length (L) to the mean width (W) is 3 or more, because this configuration is excellent in continuous separation.

In the aforementioned eutectic lamella texture, if the number of particles of the eutectic Si particles and the other second phase particles constituting the eutectic lamella texture and the area share are specified, more excellent cutting ability can be obtained. That is, in the eutectic lamella texture, it is preferable that the eutectic Si particles and other second phase particles exist 500 pieces/mm²or more in total, and the area share of these particles is 0.1-50%. If the total number of particles is less than 500 pieces/mm²or the area share is less than 0.1%, the cutting ability improving effect becomes poor. Furthermore, the number of eutectic Si particles and the area share tend to become larger as the Si content increases, and even if the area share exceeds 50%, good cutting ability can be obtained. However, if the area share exceeds 50%, the mechanical strength of the alloy material, especially the ductility ability (tensile strength) and the corrosion resistance, deteriorates. Therefore, the upper limit of the area share should be 50%. From the viewpoint of suppressing deterioration of mechanical strength and corrosion resistance while keeping cutting ability, the especially preferable total number of the eutectic Si particles and other second phase particles is 1,000 pieces/mm²or more, and the especially preferable area share is 0.3-40%.

The aluminum alloy material having the aforementioned metal texture is manufactured by the methods according to claims 79-89. That is, the alloy material having network-shaped eutectic lamella texture can be manufactured by using an alloy having a predetermined chemical compositions and specifying the terms and conditions of casting.

A molten aluminum alloy having predetermined chemical compositions and held at not less than the solidus temperature is continuously cast at the casting rate of 30-5,000 mm/min. and the cooling rate of 10-600° C./sec. to form a shape member having a predetermined cross-section. In the solidification process, fine and rounded eutectic Si particles each having a nucleus of Si—Sr compound in a molten metal are dispersed in the aluminum, and dendrite grows up to mean DAS in the aforementioned range. At the dendrite boundary zone, eutectic lamella texture containing eutectic Si particles and other second phase particles is formed in the shape of a network of a certain size.

If the casting rate is below 30 mm/min., eutectic Si particles become rough to cause a low-density distribution of particles, resulting in poor cutting ability and heavy damage of cutting tool. To the contrary, if the casting rate exceeds 5,000 mm/min., a shape member having a predetermined cross-section cannot be obtained. Furthermore, casting defects such as solidification cracks and pores occur, which may cause poor casting surface. The preferable casting rate is 50-3,000 mm/min., more preferably 100-2,000 mm/min.

If the cooling rate is less than 10° C./sec., eutectic Si particles become rough to cause a low-density distribution of particles, causing heavy damage of cutting tool. To the contrary, in order to attain the cooling rate exceeding 600° C./sec., special equipment and special process control are required, which deteriorates productivity. Furthermore, a cost problem will also arise. The preferable cooling rate is 30-500° C./sec., more preferably 30-300° C./sec.

The continuous casting method is not limited to a specific one as long as the aforementioned casting conditions can be attained. A vertical-type continuous casting process and a horizontal continuous casting process can be exemplified. Furthermore, direct cooling can be recommended in order to attain the aforementioned cooling rate.

The cross-sectional configuration of the shape member to be cast is not limited at all. A circular cross-section configuration, a polygonal cross-sectional configuration and, other heteromorphic cross-sectional configuration can be exemplified. Anon-hollow member can be recommended. Furthermore, a hollow member which includes a hollow portion in a cross section is also included in the present invention.

In case of a non-hollow member, it is preferable that the member has a cross section circumscribed to a circle with a diameter of 10-150 mm. If the diameter of the circumscribed circle is less than 10 mm, the molten metal flow deteriorates remarkably, which makes it difficult to form a predetermined configuration. To the contrary, if the diameter exceeds 150 mm, the cooling becomes insufficient due to the increased cross-section, which makes it difficult to attain the aforementioned cooling rate. As a result, it becomes difficult to form a network-shaped eutectic lamella texture, which in turn may cause deterioration of cutting ability.

The aging treatment to the continuously cast shape member is performed by holding the member at 100-300° C. for 0.5-100 hours. During this period, the element dissolved at the time of casting is deposited in the host phase, causing maximum mechanical strength and excellent cutting ability. If the aging temperature is less than 100° C. or the holding time is less than 0.5 hours, the aging becomes insufficient. Thus, the quality of the finished surface at the time of cutting deteriorates, and neither cutting ability nor mechanical strength increases. Furthermore, if the aging temperature exceeds 300° C. or the holding time exceeds 100 hours, the aging will be excessive, resulting in deteriorated cutting ability and decreased mechanical strength. The preferable aging conditions are to hold the member at 120-220° C. for 1-30 hours.

The surface layer of the cast shape member includes heterogeneous layers, such as an inverse-segregation layer, a chill layer and a rough cell layer, which are formed at the time of solidification. Since the heterogeneous layers deteriorate the quality of shape member, it is preferable to remove the heterogeneous layers by eliminating the surface depth of 0.1-10 mm. If the elimination amount of the surface layers is less than 0.1 mm, the heterogeneous layer cannot be removed sufficiently. The elimination of 10 mm depth can exclude the heterogeneous layers assuredly. Elimination of more than 10 mm depth has no significance, and the materials will be wasted. The preferable elimination amount is 0.2-5 mm in depth. The surface layer elimination may be performed after the casting but before the aging, or after the aging but before the secondary-forming processing. Furthermore, the elimination method is not limited, and peeling processing and scalping processing can be exemplified.

If necessary, the cast shape member may be subjected to secondary forming processing to form a predetermined shape before or after the aging. The secondary forming processing method is not limited to a specific so long as the method is a plastic working method by which a cross-section area decreases. Drawing, extruding and rolling can be exemplified. It is preferable that the processing is performed under the conditions of: the working temperature of 400° C. or less; and the cross-sectional area reduction ratio (i.e., cross-sectional area before processing/cross-sectional area after processing) is 30% or less. If the working temperature exceeds 400° C., the eutectic Si particles dispersed in the eutectic lamella texture condenses to become rough and spherical shape, which deteriorates cutting ability. Furthermore, if the processing is performed so that the cross-sectional area reduction ratio exceeds 30%, the eutectic lamella texture is fractured, which deteriorates cutting ability and alloy material quality. The preferable conditions of the secondary forming processing are: the working temperature of 250° C. or less and the cross-sectional area reduction ratio of 20% or less.

Furthermore, the heat treatment, such as homogenization processing and solution treatment, before the aging treatment or before the secondary forming processing may be performed appropriately.

The aluminum alloy material cast according to the present invention or the member to which the secondary forming processing was performed after the casting is cut by a saw, a shear, etc. For example, although the member may be cut into a short member less than 1 m in length, a long member 1-10 m in length or a blank member, these cut members are included in this invention irrespective of length.

Other manufacturing conditions follow a conventional method.

Each invention has the following effects.

According to the invention as recited in claim 1, since Si particles are fined and rounded by Sr, an aluminum alloy that is excellent in chip breaking nature and causes less abrasion or damage of a cutting tool can be obtained. Furthermore, since the aluminum alloy contains Mg and Zn, the aluminum alloy is excellent in alumite processability and plastic-working nature.

According to the invention as recited in claim 2, the aluminum alloy more excellent in mechanical property can be obtained.

According to the invention as recited in claim 3, an aluminum alloy is more excellent in cutting ability can be obtained.

According to the invention as recited in claim 4, an aluminum alloy more excellent in mechanical property and alumite processability can be obtained.

According to the invention as recited in claim 5, since Si particles are further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.

According to the invention as recited in claim 6, since Si particle can be further rounded and fined by Sr, or by Si and Na, Ca, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained. An aluminum alloy excellent in mechanical property, corrosion resistance, alumite processability and plastic-working nature because of the existence of Mg and Zn can be obtained. Cu improves mechanical property. Fe promotes dispersion of Si as an individual particle, which improves cutting ability. Cr and Mn enhance mechanical strength. Zr enhances mechanical strength, corrosion resistance and cutting ability. Furthermore, Ti enhances mechanical strength and corrosion resistance.

According to the invention as recited in claim 7, the aluminum alloy more excellent in mechanical property can be obtained.

According to the invention as recited in claim 8, an aluminum alloy which is more excellent in cutting ability can be obtained.

According to the invention as recited in claim 9, an aluminum alloy which is more excellent in mechanical property and alumite processability can be obtained.

According to the invention as recited in claim 10, since Si particle are further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.

According to the invention as recited in claim 11, an aluminum alloy more excellent in mechanical property can be obtained.

According to the invention as recited in claim 12, since Si are dispersed as an individual particle, more excellent chip-breaking nature can be maintained.

According to the invention as recited in claim 13, an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.

According to the invention as recited in claim 14, an aluminum alloy more excellent in mechanical property, corrosion resistance and cutting ability can be obtained.

According to the invention as recited in claim 15, an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.

According to the invention as recited in claim 16, since Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.

According to the invention as recited in claim 17, an aluminum alloy more excellent in mechanical property can be obtained.

According to the invention as recited in claim 18, since Si can be dispersed as an individual particle, more excellent chip-breaking nature can be maintained.

According to the invention as recited in claim 19 or 20, an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.

According to the invention as recited in claim 21, an aluminum alloy more excellent in mechanical property, corrosion resistance and cutting ability can be obtained.

According to the invention as recited in claim 22, an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.

According to the invention as recited in claim 23 or 24, since Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.

According to the invention as recited in claim 25, since Si particle is fined and rounded, the aluminum alloy material has good chip breaking nature, and causes less abrasion and damage on a cutting tool. Furthermore, it is also excellent in mechanical property, alumite processability and plastic working nature by other additional elements.

According to the invention as recited in claim 26, since the aforementioned Si particle is fined, there are still less abrasion and damage on a cutting tool.

According to the invention as recited in claim 27, since the aforementioned Si particle is rounded, there are still less abrasion and damage on a cutting tool.

According to the invention as recited in claim 28, since Si particle is fined and rounded, the aluminum alloy material has good chip breaking nature, and causes less abrasion and damage on a cutting tool. Furthermore, it is also excellent in mechanical property, alumite processability and plastic working nature by other additional elements.

According to the invention as recited in claim 29, since the aforementioned Si particle is fined, there are still less abrasion and damage on a cutting tool.

According to the invention as recited in claim 30, since the aforementioned Si particle is rounded, there are still less abrasion and damage on a cutting tool.

According to the invention as recited in claim 31, it is possible to manufacture the first aluminum alloy material which has fined and rounded Si particles, has good chip breaking nature, causes less abrasion and damage on a cutting tool, and is excellent in mechanical property, alumite processability and plastic working nature.

According to the invention as recited in claim 32, an aluminum alloy material with the best cutting ability can be manufactured.

According to the invention as recited in claim 33, an aluminum alloy material with the best cutting ability, mechanical property and corrosion resistance can be manufactured.

According to the invention as recited in claim 34, an aluminum alloy material with the best cutting ability, mechanical property and corrosion resistance can be manufactured. Furthermore, productivity is also excellent.

According to the invention as recited in claim 35, an aluminum alloy material with the best mechanical property and corrosion resistance can be manufactured.

According to the invention as recited in claim 36, an aluminum alloy material with the best mechanical property can be manufactured.

According to the invention as recited in claim 37, an aluminum alloy material which has fined surface recrystallized structure, and is excellent especially in mechanical property can be manufactured.

According to the invention as recited in claim 38, an aluminum alloy material whose mechanical property is further improved can be manufactured.

According to the invention as recited in claim 39, it is possible to manufacture the second aluminum alloy material which has fined and rounded Si particles, has good chip breaking nature, causes less abrasion and damage on a cutting tool, and is excellent in mechanical property, alumite processability and plastic working nature.

According to the invention as recited in claim 40, an aluminum alloy material with the best cutting ability can be manufactured.

According to the invention as recited in claim 41, an aluminum alloy material with the best cutting ability, mechanical property and corrosion resistance can be manufactured.

According to the invention as recited in claim 42, an aluminum alloy material with the best cutting ability, mechanical property and corrosion resistance can be manufactured. Furthermore, productivity is also excellent.

According to the invention as recited in claim 43, an aluminum alloy material with the best mechanical property and corrosion resistance can be manufactured.

According to the invention as recited in claim 44, an aluminum alloy material with the best mechanical property can be manufactured.

According to the invention as recited in claim 45, an aluminum alloy material which has fined surface recrystallized structure, and is excellent especially in mechanical property can be manufactured.

According to the invention as recited in claim 46, an aluminum alloy material whose mechanical property is further improved can be manufactured.

According to the invention as recited in claim 47, since Si particle is fined and rounded by Sr, and eutectic lamella texture is formed at the dendrite boundary zone, it is possible to obtain an aluminum alloy material comprised of this alloy which is excellent in cutting ability and causes less abrasion and damage on a cutting tool. Furthermore, it is possible to obtain an aluminum alloy which is excellent in mechanical property, especially tensile property, corrosion resistance, alumite processability and plastic working nature because of the existence of Mg, Cu and Zn.

According to the invention as recited in claim 48, an aluminum alloy more excellent in mechanical property can be obtained.

According to the invention as recited in claim 49, an aluminum alloy more excellent in cutting ability can be obtained.

According to the invention as recited in claim 50, an aluminum alloy more excellent in mechanical property and cutting ability can be obtained.

According to the invention as recited in claim 51, an aluminum alloy more excellent in mechanical property and alumite processability can be obtained.

According to the invention as recited in claim 52, since Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.

According to the invention as recited in claim 53, since Si particle is fined and rounded by Sr, or Sr and any one of Na, Sb and Ca, and eutectic lamella texture is formed at the dendrite boundary zone, it is possible to obtain an aluminum alloy material comprised of this alloy which is excellent in cutting ability and causes less abrasion and damage on a cutting tool. Furthermore, Mg, Zn and Cu improve mechanical property, especially tensile characteristics, corrosion resistance, alumite processability and plastic working nature. Furthermore, any one of Ti, B, C and Sc causes fined ingot texture and suppresses appearance of macro patterns and solidification cracks. Fe promotes dispersion of Si as an individual particle, which improves cutting ability. Cr and Mn improve mechanical strength. Zr or V fines ingot texture, suppresses appearance of macro patterns and solidification cracks, and further improves cutting ability by forming intermetallic compounds. Ni forms intermetallic compounds, which improves cutting ability. Any one of Sn, Bi and In improves cutting ability.

According to the invention as recited in claim 54, an aluminum alloy more excellent in mechanical property can be obtained.

According to the invention as recited in claim 55, an aluminum alloy more excellent in cutting ability can be obtained.

According to the invention as recited in claim 56, an aluminum alloy more excellent in mechanical property and cutting ability can be obtained.

According to the invention as recited in claim 57, an aluminum alloy more excellent in mechanical property and alumite processability can be obtained.

According to the invention as recited in claim 58, since Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.

According to the invention as recited in claim 59, an aluminum alloy in which ingot texture is fined and appearance of macro patterns and solidification cracks are suppressed can be obtained.

According to the invention as recited in claim 60, since Si can be dispersed as an individual particle, more excellent chip-breaking nature can be maintained.

According to the invention as recited in claim 61, an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.

According to the invention as recited in claim 62, an aluminum alloy in which ingot texture is fined, appearance of macro patterns and solidification cracks are suppressed and cutting ability is excellent, can be obtained.

According to the invention as recited in claim 63, an aluminum alloy more excellent in cutting ability can be obtained.

According to the invention as recited in claim 64, since Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.

According to the invention as recited in claim 65, an aluminum alloy more excellent in cutting ability can be obtained.

According to the invention as recited in any one of claims 66-68, an aluminum alloy in which ingot texture is fined and appearance of macro patterns and solidification cracks are suppressed can be obtained.

According to the invention as recited in claim 69, since Si can be dispersed as an individual particle, more excellent chip-breaking nature can be maintained.

According to the invention as recited in claim 70 or 71, an aluminum alloy more excellent in mechanical property and corrosion resistance can be obtained.

According to the invention as recited in claim 72 or 73, an aluminum alloy in which ingot texture is fined, appearance of macro patterns and solidification cracks are suppressed and cutting ability is excellent, can be obtained.

According to the invention as recited in claim 74, an aluminum alloy in which ingot texture is fined and appearance of macro patterns and solidification cracks are suppressed can be obtained.

According to the invention as recited in claim 75, an aluminum alloy more excellent in cutting ability can be obtained.

According to the invention as recited in any one of claims 76-78, since Si particle can be further rounded and fined, an aluminum alloy which is excellent in chip breaking nature and causes less damage or abrasion of a cutting tool can be obtained.

According to the invention as recited in any one of claims 79-81, an aluminum alloy more excellent in cutting ability can be obtained.

According to the invention as recited in claim 82, since eutectic Si particles can be served as chip breaking origins independently, cutting ability is improved. Furthermore, since eutectic lamella texture can be continuously separated, cutting ability is improved. Furthermore, since the eutectic Si particles are fined and rounded, abrasion and damage on a cutting tool can be suppressed. Furthermore, this aluminum alloy is also excellent in mechanical property, especially tensile characteristics, corrosion resistance, alumite processability and plastic-working nature.

According to the invention as recited in claim 83, an aluminum alloy material which is more excellent in cutting ability and capable of suppressing abrasion and damage on a cutting tool can be obtained.

According to the invention as recited in claim 84, an aluminum alloy material which is further improved in cutting ability and mechanical characteristics can be obtained.

According to the invention as recited in claim 85, abrasion and damage on a cutting tool can be suppressed while keeping excellent cutting ability.

According to the invention as recited in claim 86, an aluminum alloy material which is further improved in cutting ability can be obtained.

According to the invention as recited in claim 87, an aluminum alloy material which is further improved in cutting ability can be obtained.

According to the invention as recited in claim 88, cutting ability can be further improved, and abrasion and damage on a cutting tool can be suppressed.

According to the invention as recited in claim 89, cutting ability can be further improved, and abrasion and damage on a cutting tool can be suppressed.

According to the invention as recited in claim 90, since eutectic Si particles can be served as chip breaking origins independently, cutting ability is improved. Furthermore, since eutectic lamella texture can be continuously separated, cutting ability is improved. Furthermore, since the eutectic Si particles are fined and rounded, abrasion and damage on a cutting tool can be suppressed. Furthermore, this aluminum alloy is also excellent in mechanical property, especially tensile characteristics, corrosion resistance, alumite processability and plastic-working nature.

According to the invention as recited in claim 91, an aluminum alloy material which is more excellent in cutting ability and capable of suppressing abrasion and damage on a cutting tool can be obtained.

According to the invention as recited in claim 92, an aluminum alloy material which is further improved in cutting ability and mechanical characteristics can be obtained.

According to the invention as recited in claim 93, abrasion and damage on a cutting tool can be suppressed while keeping excellent cutting ability.

According to the invention as recited in claim 94, an aluminum alloy material which is further improved in cutting ability can be obtained.

According to the invention as recited in claim 95, an aluminum alloy material which is further improved in cutting ability can be obtained.

According to the invention as recited in claim 96, cutting ability can be further improved, and abrasion and damage on a cutting tool can be suppressed.

According to the invention as recited in claim 97, cutting ability can be further improved, and abrasion and damage on a cutting tool can be suppressed.

According to the invention as recited in claim 98, it is possible to manufacture the third aluminum alloy material that has eutectic Si particles and eutectic lamella texture, causes less abrasion and damage on a cutting tool while keeping outstanding cutting ability, and is excellent in mechanical property, especially tensile characteristics, corrosion resistance, alumite processability and plastic-working nature.

According to the invention as recited in claim 99 or 100, especially, the aforementioned eutectic Si particles and aforementioned eutectic lamella texture can be formed assuredly.

According to the invention as recited in claim 101, since the elements dissolved can fully deposited at the time of casting, an aluminum alloy material excellent especially in cutting ability and mechanical property can be manufactured.

According to the invention as recited in claim 102, a non-hollow member having the aforementioned eutectic Si particles and eutectic lamella texture can be manufactured.

According to the invention as recited in claim 103, especially the molten metal flow is good, and the aforementioned cooling rate can be easily achieved.

According to the invention as recited in claim 104, surface heterogeneous layers can be eliminated, and therefore a high quality aluminum alloy material can be obtained.

According to the invention as recited in claim 105, heterogeneous layers can be eliminated assuredly.

According to the invention as recited in claim 106, aggregation of eutectic Si particles and/or destruction of eutectic lamella texture can be prevented, and therefore an aluminum alloy material can be processed into any desired configuration while maintaining excellent cutting ability.

According to the invention as recited in claim 107 or 108, cutting ability can be maintained assuredly even if a secondary forming processing is performed.

According to the invention as recited in claim 109, it is possible to manufacture the third aluminum alloy material that has eutectic Si particles and eutectic lamella texture, causes less abrasion and damage on a cutting tool while keeping outstanding cutting ability, and is excellent in mechanical property, especially tensile characteristics, corrosion resistance, alumite processability and plastic-working nature.

According to the invention as recited in claim 110 or 111, especially, the aforementioned eutectic Si particles and aforementioned eutectic lamella texture can be formed assuredly.

According to the invention as recited in claim 112, since the elements dissolved can fully deposited at the time of casting, an aluminum alloy material excellent especially in cutting ability and mechanical property can be manufactured.

According to the invention as recited in claim 113, a non-hollow member having the aforementioned eutectic Si particles and eutectic lamella texture can be manufactured.

According to the invention as recited in claim 114, especially the molten metal flow is good, and the aforementioned cooling rate can be easily achieved.

According to the invention as recited in claim 115, surface heterogeneous layers can be eliminated, and therefore a high quality aluminum alloy material can be obtained.

According to the invention as recited in claim 116, heterogeneous layers can be eliminated assuredly.

According to the invention as recited in claim 117, aggregation of eutectic Si particles and/or destruction of eutectic lamella texture can be prevented, and therefore an aluminum alloy material can be processed into any desired configuration while maintaining excellent cutting ability.

According to the invention as recited in claims 118 and 119, cutting ability can be maintained assuredly even if a secondary forming processing is performed.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a photograph showing metal texture of an aluminum alloy material corresponding to claims 71-75 of the present invention.

FIG. 2 is a photograph showing other metal texture of other aluminum alloy material corresponding to claims 71-75 of the present invention.

FIG. 3 is a photograph showing metal texture of a conventional aluminum alloy material.

FIG. 4 is a photograph showing a cut surface of 98.2% peel rate to evaluate the quality of the machined surface of Example IIA.

FIG. 5 is a photograph showing the cut surface 3.4% peel rate to evaluate the quality of the machined surface of Example IIA.

FIG. 6 is a cross-sectional view of a principal part of a gas pressurization type hot top casting apparatus used in Examples IIA, IIB and IIC.

FIG. 7 is a cross-sectional view of a principal part of a horizontal continuous casting apparatus used in Example IIB.

EXAMPLES

I. First and Second Aluminum Alloys, Aluminum Alloy Materials and Manufacturing Methods Thereof (Examples Corresponding to Claims 1-46)

Aluminum alloys of compositions of Al No. I-1-I-17 shown in Table 1 were prepared. The alloy No. I-1 and I-2 includes Mg, Si, Zn and Sr, and the balance being aluminum and impurities, and the compositions correspond to claims 1-5 of the present invention. The alloys Nos. I-3 to I-12 include eight optional selective elements in the aforementioned elements, and the compositions correspond to claims 6-24. The alloys Nos. I-13 to I-17 are comparative compositions.

From these aluminum alloy materials, round bars were made by billet casting, extrusion, and drawing.

First, a billet was made at the casting rate of 80 mm/min. by DC casting. The billet was homogenized by holding at 520° C. for 10 hours, and then extruded into a round bar with a diameter of 15 mm at the billet temperature of 450° C., the extrusion product rate of 12 m/min., and the extrusion ratio of 35. This extruded member is held at 540° C. for 3 hours for a solution treatment, then drawn at the reduction rate of 25%, and aged by holding at 160° C. for 5 hours to thereby obtain a test piece.

On each prepared test piece (drawn member), the proof strength of 0.2%, the tensile strength and the fracture elongation were measured. Further, the chip breaking nature, the corrosion resistance, the abrasion of a tool, the alumite processability and the plastic-working nature were evaluated by the following method.

[Chip Breaking Nature, Tool Abrasion]

Each test piece was wet cut using a superhard chip at the cutting rate of 150 m/min., the feeding rate of 0.2 mm/rev. to form a slit of 1.0 mm depth. The chip breaking nature was evaluated by chip number/100 g.

[Corrosion Resistance]

A salt spray test based on JIS Z2371 was performed, and the corrosion resistance was measured by the corrosion weight loss due to 1,000 hours spray.

[Tool Abrasion]

Continuous cutting for 5 minutes is performed under the conditions of cutting rate of 200 m/min., feeding rate of 0.2 mm/rev., and slitting of 10 mm by dry type cutting using a high-speed slab cutting-edge byte, and the abrasion width of the byte's flank was measured.

[Alumite Processability]

Sulfuric acid alumite processing was conducted by a conventional method, and evaluation was performed by the thickness of the generated alumite coat.

[Plastic-Working Nature]

This was evaluated by the rate of the limit lump rate obtained by a lump nature examination. In this examination, The crack generating limitation by cold working (forging) was investigated and evaluated by this result.

These results are collectively shown in Table 1. Regarding the chip breaking nature, the corrosion resistance, the abrasion of a tool, the alumite processability and the plastic-working nature, they were evaluated relatively on the basis of comparison alloy No. I-13. “◯” denotes a performance equivalent to the comparison alloy No. I-13, “⊚” denotes a performance superior to the comparison alloy, “Δ” denotes a performance inferior to the comparison alloy, and “X” denotes a performance further inferior to the comparison alloy.

TABLE 1CharacteristicsTensilecharacteristicsAlloyChemical compositions of Al—Mg—Si series alloy0.2% proofTensileFractureNo.(mass %, balance being Al and impurities)strengthstrengthelongation(I-n)MgSiZnSrCuFeMnCrZrTiNaCaOtherN/mm²N/mm²%Invention11.01.80.30.03—————————29031515.520.64.80.20.05—————————3153389.031.01.80.30.030.20.20.01——————30533514.041.02.80.30.030.20.20.01——————31234012.051.04.80.30.030.20.20.01——————32834811.061.02.80.30.010.20.20.01——————31033912.571.02.80.30.030.20.20.01——————31533612.681.02.80.30.030.20.20.010.2—————32034513.591.02.80.30.030.20.20.01—0.02————31534013.5101.02.80.30.030.20.20.01——0.02———31834012.5111.02.80.30.030.20.20.01———0.005——31034013.0121.02.80.30.030.20.20.01————0.005—30533513.5Comparative131.00.8——0.20.20.10—————Pb: 0.528031016.0Bi: 0.5141.02.80.3—0.20.20.01——————32234212.1151.04.80.3—0.20.20.01——————32733911.6161.011.50.30.030.20.20.01——————2953159.5171.011.50.3—0.20.20.01——————2903097.9AlloyCharacteristicsNo.Cutting divisionCorrosionAlumitePlastic-working(I-n)natureresistanceTool AbrasionprocessabilitynatureInvention1◯◯⊚⊚◯2◯◯⊚⊚◯3◯◯⊚⊚◯4◯◯◯⊚◯5⊚◯◯◯◯6◯◯◯⊚◯7◯◯◯⊚◯8◯◯◯⊚◯9◯◯◯⊚◯10◯◯◯⊚◯11◯◯⊚⊚◯12◯◯⊚⊚◯Comparative13◯◯◯◯◯14◯◯Δ◯◯15◯◯Δ◯Δ16⊚ΔXΔX17⊚ΔXΔX
In this Table, the underlined numeral is out of the scope of the invention.

Furthermore, on the invention alloys No. I-1, I-3 to I-5, I-11, I-12 and comparison alloys No. I-14 to I-17, the mean particle diameter of Si particle, the particle diameter range, the mean aspect ratio thereof were examined. The results are shown in Table 2 which also shows the Si content, Sr content, Na content, Ca content, chip-breaking nature and abrasion of a tool which affect the above.

TABLE 2Si particleMeanRange ofOther CharacterAlloySi, Sr, Na, Ca contentparticleParticleMeanCuttingNo.(mass %)diameterdiameteraspectdivisionTool(I-n)SiSrNaCa(μm)(μm)rationatureAbrasionInvention11.80.03——1.20.3-3.31.5◯⊚31.80.03——1.20.3-3.21.3◯⊚42.80.03——3.10.8-4.22.3◯◯54.80.03——4.91.2-6.62.8⊚◯112.80.030.005—3.00.7-4.22.3◯⊚122.80.03—0.0053.10.7-4.12.1◯⊚Comparative142.8———3.30.1-5.54.1◯Δ154.8———4.20.1-6.94.2◯Δ1611.50.03——6.5 0.5-12.13.6⊚X1711.5———6.8 0.3-11.24.9⊚X

From the results shown in Tables Nos. 1 and 2, it was confirmed that the aluminum alloy materials of the invention alloy Nos. I-1 to I-12 are excellent in chip breaking nature and abrasion of a tool since the particles are fined and rounded irrespective of Si addition.

II. Third and Fourth Aluminum Alloys, Alloy Materials and Manufacturing Methods Thereof

(Examples Corresponding to Claims 47-119)

A. Compositions of Aluminum Alloy

Aluminum alloys having compositions of alloy No. IIA-1 to IIA-129 shown in Table 3-8 were prepared. Each of the alloy Nos. IIA-1 to IIA-30 includes Mg, Si, Cu, Zn, Sr and the balance being aluminum and impurities. The compositions correspond to claims 47-52 of the invention. Alloys No. IIA-1 to IIA-10 are comparative compositions. Alloy No. IIA-41 to IIA-108 (except for IIA-93, 94 and 97) has the basic compositions of Alloy No. IIA-30, and Alloys No. IIA-109 to IIA-129 have the basic compositions of Alloy No. IIA-109 to IIA-129. Both the alloys Furthermore, sixteen optional selective elements are added to the above alloys. Alloy No. IIA-94 has basic compositions of Alloy No. IIA-7 (Mg: 1 mass %, Si: 0.8 mass %, Cu: 0.2 mass %, Zn: 0.2 mass %, Sr: 0.03 mass %), Alloy No. IIA-93 and 97 have basic compositions of Alloy (Mg: 1 mass %, Si: 1.5 mass %, Cu: 0.2 mass %, Zn: 0.2 mass %, Sr: 0.03 mass %). Optional additional elements are added to the above alloys. Alloy No. IIA-41 to IIA-129 are compositions corresponding to claims 53-81.

Using these aluminum alloys as the casting materials, a non-hollow member of a round cross-section with a diameter of 53 mm was cast vertically and continuously by the below-mentioned gas pressurization type hot top casting method.

[Gas Pressurization Type Hot Top Casting]

In the gas pressurization type hot top casting apparatus shown in FIG. 6, the reference numeral “1” denotes a mold for forming the external periphery of an ingot, and “2” denotes a cylindrical molten metal receiving tub disposed at the upper portion of the mold 1.

The mold 1 has an annular cavernous portion 3 for circulating a cooling medium such as water therein. This cavernous portion 3 is provided with a plurality of port mouths 4 opening toward the outside. The cooling medium C introduced into the cavernous portion 3 through an introductory tubing which is not illustrated performs a primary cooling of the cast member S by cooling the mold 1, and is spouted from the port mouths 4 to perform a secondary cooling of the casting S. Furthermore, the inner upper surface 1a of the mold 1 is lower than the exterior upper surface 1b, to thereby form a gap 6 opened to a gas passage 5 between the inner upper surface 1a and the lower surface of the molten metal tub 2.

The lower inner part of the molten metal tub 2 is protruded horizontally toward the inner side of the mold 1 to form an over hang portion 7. Accordingly, the pressurized gas F introduced into the gas passage 5 through the gas introduction passage 8 from the exterior is introduced under the overhang portion 7 from the gap 6. This excludes the molten metal from the region immediately under the over hang portion 7 to thereby make the molten metal contact to the inner peripheral surface of the mold 1 at the position far below the upper end of the mold 1. The contact distance between the molten metal and the mold 1 is controlled by the flow rate of the pressurized gas F, which in turn controls the primary cooling time and the solidification process to obtain a cast member S excellent in metal texture. In the figure, “M” shows the overhang amount of the overhang portion 7.

Furthermore, lubricating oil is introduced into a supply passage 9 from the exterior through a passage which is not illustrated, and supplied to the inner peripheral surface of the mold 1 through numeral fine feed mouths 10 branched from the supply passage 9. “11” denotes a heat-resistant packing member fitted in the slot cut in the upper surface of the mold 1 to prevent the leak of the gas passing through the gap 6.

According to the vertical-type continuous casting apparatus, the casting rate and cooling rate of the present invention can be attained, and a cast member with outstanding characteristics, such as cutting ability, can be manufactured.

The casting conditions were the casting conditions b shown in the following Table 9, and all of the alloys were continuously cast successfully.

Subsequently, the surface portion of the cast non-hollow member of 1.5 mm depth was eliminated. Thereafter, aging was performed by holding the member at 170° C. for 11 hours, to thereby obtain a test piece.

About each test piece, the mechanical properties, such as 0.2% proof strength, tensile strength, fracture elongation (tensile characteristics), were measured, and the homogeneity of metal texture, plastic-working nature, cutting ability, abrasion of a tool, quality of the machined surface, corrosion resistance, alumite processability were examined by the following method. Then, except for the mechanical properties, they were evaluated relatively by comparing with various characteristics of the extruded member consist of JIS A6262 alloy in the five following grades.

⊚⊚: Extremely excellent
⊚: Excellent
◯: Equivalent
Δ: Slightly poor
X: Very poor

[Homogeneity of Metal Texture]

It is evaluated by size of dendrite texture, measured result on space, size of eutectic lamella texture, form, continuity and homogeneity in a test piece cross-section.

[Plastic-Working Nature]

It is evaluated by drawing at the cross-sectional area reduction ratio of 20% and using the change rate of characteristics from the results of the cutting ability examination and the tensil test.

[Cutting Ability]

Wet cutting was performed by using a superhard chip at the cutting rate of 150 m/min., feeding rate of 0.2 mm/rev. to form a slit of 1.0 mm depth, and the chip breaking nature is examined from chips number/100 g. Then, the cutting ability is evaluated by the chip breaking nature.

[Abrasion of a Tool]

[Quality of Finished Surface]

It was evaluated by the rate (%) of the peeled portion existing in a unit area (1 mm²) on the cut surface of the test piece cut by the aforementioned cutting test. As examples of cut surfaces, FIG. 3 shows the cut surface of 98.2% peeled rate, and FIG. 4 shows the cut surface of 3.4% peeled rate.

[Cutting Crack Nature]

Wet cutting was performed by using a superhard chip at the cutting rate of 150 m/min., feeding rate of 0.2 mm/rev. to form a slit of 3.0 mm depth, and the chip breaking nature is examined from chips number/100 g. Then, the Cutting crack nature was evaluated by the incidence rate (%) of the cutting cracks within a unit area (1 mm²).

[Corrosion Resistance]

A salt spray test based on JIS Z2371 was performed, and the corrosion resistance was measured by the corrosion weight loss due to 1,000 hours spray.

[Alumite Processability]

Sulfuric acid alumite processing was conducted by a conventional method, and evaluation was performed by the thickness of the generated alumite coat.

These results are shown in Tables 3-8.

TABLE 3Various characteristicsCompositions of Al alloyMechanical propertyAlloy(mass %, balance being Al and0.2% proofTensileNo.impurities)strengthstrengthFractureTexturePlastic-working(IIA-n)MgSiCuZnSrN/mm²N/mm²elongation %homogeneitynatureInvention10.32.80.20.20.032853207.2⊚◯22.02.80.20.20.033053308.6◯◯34.02.80.20.20.033073308.0◯◯45.02.80.20.20.033003258.0◯◯56.02.80.20.20.032903207.8◯◯61.00.30.20.20.0328031514.5⊚◯71.00.80.20.20.0330533013.0⊚◯81.04.00.20.20.0332634012.1⊚◯91.06.00.20.20.033203309.6◯◯101.08.00.20.20.033053259.0◯◯111.010.00.20.20.032903108.0◯◯121.012.00.20.20.032903158.1◯◯141.02.80.050.20.0328031012.6⊚◯151.02.80.10.20.0328032013.0⊚◯161.02.80.30.20.0330834013.9⊚◯171.02.80.50.20.0334037614.2⊚◯181.02.80.80.20.0335039513.0⊚◯191.02.80.20.010.0330533014.5⊚◯201.02.80.20.050.0330832515.0⊚◯Various characteristicsAlloyQuality ofNo.finishedCutting crackCorrosionAlumite(IIA-n)Cutting alibityTool AbrasionsurfacenatureresistanceprocessabilityInvention1⊚⊚◯⊚⊚⊚2⊚⊚◯⊚⊚⊚3⊚⊚◯⊚⊚⊚4◯◯⊚⊚◯◯5◯◯⊚⊚◯◯6◯⊚⊚⊚⊚⊚7◯⊚⊚⊚⊚⊚8⊚◯◯⊚⊚⊚9⊚◯◯⊚⊚⊚10⊚◯◯⊚◯◯11⊚◯◯⊚◯◯12⊚◯◯⊚◯◯14◯⊚◯⊚⊚⊚15◯⊚◯⊚⊚⊚16⊚⊚◯⊚⊚⊚17⊚⊚⊚⊚⊚⊚18⊚◯⊚⊚◯⊚19⊚⊚⊚⊚⊚◯20⊚⊚⊚⊚⊚◯

TABLE 4

Various characteristics

Compositions of Al alloy
Mechanical property

Alloy
(mass %, balance being
0.2% proof
Tensile

No.
Al and impurities)
strength
strength
Fracture
Texture
Plastic-working

(IIA-n)
Mg
Si
Cu
Zn
Sr
N/mm²
N/mm²
elongation %
homogeneity
nature

Invention
21
1.0
2.8
0.2
0.1
0.03
315
335
14.3
⊚
◯

22
1.0
2.8
0.2
0.5
0.03
332
356
11.2
⊚
◯

23
1.0
2.8
0.2
1.0
0.03
335
350
12.6
⊚
◯

24
1.0
2.8
0.2
1.5
0.03
340
355
10.9
⊚
◯

25
1.0
2.8
0.2
0.2
0.005
306
319
12.6
⊚
◯

26
1.0
2.8
0.2
0.2
0.01
310
332
15.6
⊚
◯

27
1.0
2.8
0.2
0.2
0.05
308
327
16.2
⊚
◯

28
1.0
2.8
0.2
0.2
0.1
301
320
15.8
⊚
◯

29
1.0
2.8
0.2
0.2
0.2
301
322
15.1
⊚
◯

30
1.0
2.8
0.2
0.2
0.03
303
326
14.6
⊚
◯

Comparative
31
0.01
2.8
0.2
0.2
0.03
265
305
8.2
⊚
◯

32

7.0

2.8
0.2
0.2
0.03
280
300
7.5
◯
◯

33
1.0

0.1

0.2
0.2
0.03
272
298
17.6
⊚
◯

34
1.0

14.0
0.2
0.2
0.03
335
358
4.1
Δ
◯

35
1.0
2.8

—

0.2
0.03
285
310
10.6
⊚
◯

36
1.0
2.8

1.2

0.2
0.03
358
396
12.6
◯
◯

37
1.0
2.8
0.2

—

0.03
290
316
13.1
⊚
◯

38
1.0
2.8
0.2

4.0

0.03
390
421
10.60
◯
◯

39
1.0
2.8
0.2
0.2

—

270
295
8.2
Δ
◯

40
1.0
2.8
0.2
0.2

0.8

305
321
14.6
◯
◯

Various characteristics

Alloy

Quality of

No.

finished
Cutting crack
Corrosion
Alumite

(IIA-n)
Cutting alibity
Tool Abrasion
surface
nature
resistance
processability

Invention
21
⊚
⊚
⊚
⊚
⊚
◯

22
⊚
⊚
⊚
⊚
◯
◯

23
⊚
⊚
⊚
⊚
◯
◯

24
⊚
⊚
◯
⊚
◯
◯

25
⊚
⊚
⊚
⊚
⊚
◯

26
⊚
⊚
⊚
⊚
⊚
◯

27
⊚
⊚
⊚
⊚
◯
◯

28
⊚
⊚
⊚
⊚
◯
◯

29
⊚
⊚
⊚
⊚
◯
◯

30
⊚
⊚
⊚
⊚
⊚
⊚

Comparative
31
⊚
◯
X
Δ
◯
◯

32
Δ
◯
X
Δ
◯
Δ

33
Δ
⊚
◯
⊚
◯
◯

34
⊚
Δ
Δ
◯
Δ
Δ

35
Δ
⊚
◯
◯
⊚
⊚

36
◯
◯
◯
◯
Δ
◯

37
⊚
⊚
⊚
⊚
⊚
Δ

38
⊚
⊚
⊚
⊚
Δ
◯

39
⊚
Δ
◯
◯
◯
◯

40
⊚
◯
Δ
◯
Δ
◯

In this Table, the underlined numeral is out of the scope of the invention.

TABLE 5

Al alloy compositions

(mass %) Basic
Various characteristics

compositions Mg: 1.0,
Mechanical property

Alloy
Si: 2.8, Cu: 0.2, Zn: 0.2,
0.2% proof
Tensile

No.
Sr: 0.03, balance: Al and
strength
strength
Fracture
Texture
Plastic-working

(IIA-n)
impurities
N/mm²
N/mm²
elongation %
homogeneity
nature

Invention
41
Ti: 0.003
298
319
12.8
⊚
◯

42
Ti: 0.02
302
320
14.6
⊚
◯

43
Ti: 0.3
308
325
13.1
⊚
◯

44
B: 0.0005
302
330
15.1
⊚
⊚

45
B: 0.005
305
320
15.2
⊚
⊚

46
B: 0.01
308
329
14.6
⊚
◯

47
C: 0.01
305
320
15.1
⊚
◯

48
C: 0.15
295
315
14.0
⊚
◯

49
Fe: 0.05
285
318
16.2
⊚
◯

50
Fe: 0.2
296
325
15.1
⊚
◯

51
Fe: 0.7
291
323
13.6
◯
◯

52
Cr: 0.03
305
318
14.1
⊚
◯

53
Cr: 0.2
302
325
16.2
⊚
◯

54
Cr: 0.7
308
330
15.1
◯
◯

55
Mn: 0.1
309
328
14.6
⊚
◯

56
Mn: 0.3
319
338
12.5
⊚
◯

57
Zr: 0.1
310
329
13.6
⊚
◯

58
Zr: 0.3
312
329
12.9
⊚
◯

59
Zr: 0.7
309
336
14.9
◯
◯

60
V: 0.1
296
318
10.2
⊚
◯

61
V: 0.3
296
322
11.2
⊚
◯

Various characteristics

Alloy

Quality of

No.

finished
Cutting crack
Corrosion
Alumite

(IIA-n)
Cutting alibity
Tool Abrasion
surface
nature
resistance
processability

Invention
41
⊚
⊚
⊚
⊚
⊚
◯

42
⊚
⊚
⊚
⊚
⊚
◯

43
⊚
⊚
⊚
⊚
⊚
◯

44
⊚
◯
◯
⊚
⊚
⊚

45
⊚
◯
◯
⊚
⊚
⊚

46
⊚
◯
◯
⊚
⊚
⊚

47
⊚
⊚
⊚
⊚
⊚
◯

48
⊚
⊚
⊚
⊚
⊚
◯

49
⊚
⊚
⊚
⊚
⊚
⊚

50
⊚
⊚
⊚
⊚
⊚
⊚

51
⊚
◯
◯
⊚
◯
◯

52
⊚
⊚
◯
⊚
⊚
⊚

53
⊚
⊚
⊚
⊚
⊚
⊚

54
⊚
◯
⊚
⊚
◯
◯

55
⊚
⊚
⊚
⊚
⊚
⊚

56
⊚
⊚
⊚
⊚
⊚
⊚

57
⊚
⊚
⊚
⊚
⊚
⊚

58
⊚
⊚
⊚
⊚
⊚
⊚

59
⊚
⊚
⊚
⊚
◯
◯

60
⊚
⊚
⊚
⊚
⊚
⊚

61
⊚
⊚
⊚
⊚
⊚
⊚

TABLE 6

Al alloy

compositions

(mass %)

Basic

compositions

Mg:1.0, Si:2.8,
Various characteristics

Cu:0.2, Zn:0.2,
Mechanical property

Quality

Sr:0.03,
0.2% proof
Tensile

Texture
Plastic-

of
Cutting

Alumite

Alloy No.
balance:Al and
strength
strength
Fracracture
homo-
working
Cutting
Tool
finished
crack
Corrosion
process-

(IIA-n)
impurities
N/mm²
N/mm²
elongation %
geneity
nature
alibity
Abrasion
surface
nature
resistance
ability

In-
62
Sc: 0.07
300
325
14.6
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

ven-
63
Sc: 0.16
310
330
13.1
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

tion
64
Ni: 0.003
302
320
15.2
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

65
Ni: 0.2
315
340
11.6
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

66
Ni: 0.7
318
342
10.9
◯
◯
⊚
⊚
◯
⊚
◯
◯

67
Na: 0.01
300
320
13.6
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

68
Na: 0.1
302
328
13.1
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

69
Sb: 0.01
305
325
13.0
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

70
Sb: 0.1
304
326
12.9
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

71
Ca: 0.01
301
322
14.6
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

72
Ca: 0.1
298
320
12.6
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

73
Ca: 0.3
300
325
12.4
◯
◯
⊚
⊚
⊚
⊚
◯
◯

74
Sn: 0.05
315
335
13.2
⊚
◯
⊚
⊚
⊚
⊚
⊚
⊚

75
Sn: 0.2
308
330
14.2
⊚
◯
⊚
⊚
⊚
⊚
◯
◯

76
Sn: 0.4
310
328
13.9
⊚
◯
⊚
⊚
⊚
⊚
◯
◯

77
Bi: 0.05
305
332
14.1
⊚
◯
⊚
⊚
⊚
⊚
⊚
⊚

78
Bi: 0.2
300
326
14.8
⊚
◯
⊚
⊚
⊚
⊚
⊚
◯

79
Bi: 0.4
305
328
12.9
⊚
◯
⊚
⊚
⊚
⊚
◯
◯

80
In: 0.01
300
320
16.2
⊚
◯
⊚
⊚
⊚
⊚
⊚
⊚

81
In: 0.1
302
330
12.6
⊚
◯
⊚
⊚
⊚
⊚
◯
◯

82
In: 0.3
305
328
14.1
⊚
◯
⊚
⊚
⊚
⊚
◯
◯

TABLE 7

Al alloy compositions

(mass %)
Various characteristics

Basic composition Mg: 1.0,
Mechanical property

Alloy
Si: 2.8, Cu: 0.2, Zn: 0.2,
0.2% proof
Tensile

No.
Sr: 0.03, balance: Al and
strength
strength
Fracture
Texture

(IIA-n)
impurities
N/mm²
N/mm²
elongation %
homogeneity

Invention
88
Ti: 0.1, Fe: 0.1
306
321
12.6
⊚

89
Ti: 0.1, Mn: 0.1
302
320
12.8
⊚

90
Ti: 0.1, Cr: 0.1
310
321
10.9
⊚

91
Cr: 0.1, Ni: 0.1
308
320
11.6
⊚

92
Sn: 0.3, Bi: 0.1
309
330
14.6
⊚

93
Si: 1.5, Sn: 0.4, In: 0.02**
298
323
12.9
⊚

94
Si: 0.8, Sn: 0.5, Bi: 0.5*
289
319
11.6
⊚

95
Ti: 0.1, Sn: 0.1
292
320
12.1
⊚

96
Fe: 0.2, Cr: 0.1
299
323
14.6
⊚

97
Si: 1.5, Sn: 0.3, In: 0.05**
316
331
12.6
⊚

98
Fe: 0.2, Ca: 0.1
301
320
13.9
⊚

99
Ti: 0.1, Fe: 0.2, Cr: 0.1
302
326
14.1
⊚

100
Fe: 0.2, Zr: 0.1, Ni: 0.1
300
315
10.6
⊚

101
Fe: 0.2, Zr: 0.1, Bi: 0.1
305
319
10.8
⊚

102
Ti: 0.1, Fe: 0.2, Cr: 0.1, Sb: 0.05
295
322
14.6
⊚

103
Ti: 0.1, Fe: 0.2, Mn: 0.1, Cr: 0.1
290
320
15.1
⊚

104
Ti: 0.1, Fe: 0.2, V: 0.1, Ca: 0.1, Sn: 0.1
295
319
14.0
⊚

105
C: 0.1, Fe: 0.2, Mn: 0.1, Zr: 0.1, Na: 0.1
290
315
12.6
⊚

106
B: 0.1, Fe: 0.2, Mn: 0.1, Zr: 0.1, In: 0.1
286
310
12.1
⊚

107
B: 0.1, Fe: 0.2, Mn: 0.1, Ni: 0.1, In: 0.1
292
318
14.6
⊚

108
Fe: 0.2, B, Mn, Zr, Ni, Sb, In: 0.1 respectively
290
320
12.6
⊚

Alloy
Various characteristics

No.
Plastic-
Cutting

Quality of
Cutting crack
Corrosion
Alumite

(IIA-n)
working nature
alibity
Tool Abrasion
finished surface
nature
resistance
processability

Invention
88
◯
⊚
⊚
⊚
⊚
⊚
◯

89
◯
⊚
⊚
⊚
⊚
⊚
◯

90
◯
⊚
⊚
⊚
⊚
⊚
◯

91
◯
⊚
⊚
⊚
⊚
⊚
⊚

92
◯
⊚⊚
⊚⊚
◯
⊚
⊚
◯

93
◯
⊚⊚
⊚⊚
◯
⊚
◯
◯

94
◯
⊚
⊚
◯
◯
◯
◯

95
◯
⊚
⊚
⊚
⊚
⊚
◯

96
◯
⊚
⊚
⊚
⊚
⊚
◯

97
◯
⊚⊚
⊚⊚
⊚
⊚
◯
⊚

98
◯
⊚
⊚
⊚
⊚
⊚
◯

99
◯
⊚
⊚
⊚
⊚
⊚
◯

100
◯
⊚
⊚
⊚
⊚
⊚
◯

101
◯
⊚
⊚
⊚
⊚
◯
◯

102
◯
⊚
⊚
⊚
⊚
⊚
◯

103
◯
⊚
⊚
⊚
⊚
⊚
◯

104
◯
⊚
⊚
⊚
⊚
◯
◯

105
◯
⊚
⊚
⊚
⊚
⊚
◯

106
◯
⊚
⊚
⊚
⊚
◯
◯

107
◯
⊚
⊚
⊚
⊚
◯
◯

108
◯
⊚
⊚
⊚
⊚
◯
◯

Note:

*denotes: Si: 0.8 mass %,

**denotes: Si: 1.5 mass %, Mg, Cu, Zn, Sr: same mass %

TABLE 8

Al alloy compositions

(mass %)
Various characteristics

Basic compositions Mg: 1.0,
Mechanical property

Alloy
Si: 8.0, Cu: 0.2, Zn: 0.2,
0.2% proof
Tensile

No.
Sr: 0.03, balance: Al and
strength
strength
Fracture
Texture

(IIA-n)
impurities
N/mm²
N/mm²
elongation %
homogeneity

Invention
109
Ti: 0.02
302
319
11.6
⊚

110
B: 0.005
302
318
10.9
⊚

111
C: 0.1
298
319
12.1
⊚

112
Fe: 0.2
302
321
12.0
⊚

113
Cr: 0.2
303
319
10.1
⊚

114
Mn: 0.1
302
322
14.6
⊚

115
Zr: 0.3
305
320
13.6
⊚

116
V: 0.1
302
319
12.0
⊚

117
Sc: 0.07
305
322
11.8
⊚

118
Ni: 0.2
300
318
10.1
⊚

119
Na: 0.1
305
321
13.9
⊚

120
Sb: 0.1
300
322
14.1
⊚

121
Ca: 0.1
300
320
13.6
⊚

122
Sn: 0.2
308
329
13.2
⊚

123
Bi: 0.2
307
320
14.9
⊚

124
In: 0.1
302
318
12.6
⊚

125
Ti: 0.1, Fe: 0.2
298
319
10.6
⊚

126
Ti: 0.1, Ni: 0.1
297
316
10.1
⊚

127
Ti: 0.03, Fe: 0.2, Cr: 0.1
289
316
11.1
⊚

128
B: 0.1, Fe: 0.2, Mn: 0.1, Ni: 0.1, In: 0.1
280
314
11.0
⊚

129
Fe: 0.2, B, Mn, Zr, Ni, Sb, Sc: 0.1 respectively
282
316
10.9
⊚

Various characteristics

Alloy

Quality of

No.
Plastic-working

finished
Cutting crack
Corrosion
Alumite

(IIA-n)
nature
Cutting alibity
Tool Abrasion
surface
nature
resistance
processability

Invention
109
◯
⊚
⊚
⊚
⊚
⊚
◯

110
◯
⊚
⊚
⊚
⊚
⊚
⊚

111
◯
⊚
⊚
⊚
⊚
⊚
◯

112
◯
⊚
⊚
⊚
⊚
⊚
⊚

113
◯
⊚
⊚
⊚
⊚
⊚
⊚

114
◯
⊚
⊚
⊚
⊚
⊚
⊚

115
◯
⊚
⊚
⊚
⊚
⊚
⊚

116
◯
⊚
⊚
⊚
⊚
⊚
⊚

117
◯
⊚
⊚
⊚
⊚
⊚
◯

118
◯
⊚
⊚
⊚
⊚
⊚
◯

119
◯
⊚
⊚
⊚
⊚
⊚
◯

120
◯
⊚
⊚
⊚
⊚
⊚
◯

121
◯
⊚
⊚
⊚
⊚
⊚
◯

122
◯
⊚
⊚
⊚
⊚
⊚
◯

123
◯
⊚
⊚
⊚
⊚
◯
◯

124
◯
⊚
⊚
⊚
⊚
◯
◯

125
◯
⊚
⊚
⊚
⊚
⊚
◯

126
◯
⊚
⊚
⊚
⊚
⊚
◯

127
◯
⊚
⊚
⊚
⊚
◯
◯

128
◯
⊚
⊚
⊚
⊚
◯
◯

129
◯
⊚
⊚
⊚
⊚
⊚
◯

TABLE 9

Casting condition a
Casting condition b

Molten metal
730°
C.
730°
C.

temperature

Amount of cooling
40
little/min.
40
little/min.

water

Casting diameter
Diameter 120 mm
Diameter 53 mm

Casting rate
150
mm/min.
300
mm/min.

Lubricating oil
Castor oil
Castor oil

Amount of Lubricating
1
cc/min.
1
cc/min.

oil

Gas
Air
Air

Gas flow rate
0.5
litter/min.
0.5
litter/min.

Protruded amount of
10
mm
10
mm

overhang portion (M)

From the results of Tables 3-8, it was confirmed that the aluminum alloy of compositions according to the present invention has outstanding homogeneity of metal texture, plastic-working nature, cutting ability (including quality of finished surface and cutting crack nature), corrosion resistance and alumite processability, and that abrasion of a tool can also be suppressed at the time of cutting.

B. Metal Texture and Manufacture Conditions

The manufacturing test of aluminum alloy materials were performed using IIA-30 (Table 4) and IIA-127 (Table 8) among the alloys of the above-mentioned compositions.

As for the casting No. IIB-1, IIB-2, IIB-5 and IIB-6, it was cast by the vertical-type continuous casting method. As for the casting No. IIB-3, IIB-4, IIB-7 and IIB-8, it was cast by the horizontal continuous casting method. Each cast member was formed into a non-hollow member (round bar) having a round cross-section. The detail of the casting method and casting conditions are as follows. Furthermore, as comparative examples, casting No. IIB-9, IIB-10 were cast by a metal mold.

[Vertical-Type Continuous Casting]

Two types of non-hollow members having of round cross-section were made under the casting conditions a and b shown in Table 9 by the same gas pressurizing type hot top casting method as employed in the aforementioned example of “A. Aluminum alloy chamical compositions.”

[Horizontal Continuous Casting]

In the horizontal continuous casting apparatus shown in FIG. 7, the reference numeral “20” denotes a mold, “21” denotes a tundish, “22” denotes a fire resistance conductor for introducing molten metal into the mold 20 from the tundish 21. Furthermore, “23” and “24” denote fire resistance plates for specifying the opening diameter of the molten metal inlet 32 from the conductor 22 to the mold 20.

The mold 20 has an annular cavernous, portion 25 in which cooling medium C such as water circulates, and is provided with a plurality of port mouths 26 opened from the cavernous portion 25 toward the outside. The mold 20 has the annular cavernous portion 25 which circulates cooling mediums C, such as water, to the inside, and a plurality of port mouths 26 which perform opening outside from this cavernous portion 25 are formed. The cooling medium C introduced into the cavernous portion 25 through an introductory tubing which is not illustrated performs a primary cooling of the cast member S by cooling the mold 20, and is blown off from the port mouth 26 to perform a secondary cooling of the casting S.

Furthermore, lubricating oil is introduced into a supply passage 28 via a passage 27 from the exterior, and is supplied to the inner peripheral surface 20a of the mold 20 via a number of supply canaliculus 29 branched from the supply passage 28.

In FIG. 7, “31” denotes an exit of the tundish 21, and “32” denotes a molten metal inlet.

According to the horizontal continuous casting apparatus, the casting rate and cooling rate of the present invention can be attained, and a cast member having outstanding characteristics, such as cutting ability, can be manufactured.

Two kinds of non-hollow members having round cross-section were manufactured under the casting conditions c and d shown in the following Table 10.

TABLE 10Casting condition cCasting condition dMolten metal730°C.730°C.temperature intundishAmount of cooling8litter/min.8litter/min.waterCasting diameterDiameter of 25 mmDiameter of 10 mmCasting rate800mm/min.3,000mm/min.Lubricating oilcastor oilcastor oilAmount of0.2cc/min.0.2cc/min.Lubricating oilDiameter of molten5mm5mmmetal input

[Metal Mold Casting]

The cast molds No. IIB-9 and IIB-10, which are comparative examples, are ingots obtained by the sand-mold type test mold (ISO mold) under the casting conditions shown in the following Table 11.

To the cast members No. IIB-1 to IIB-4 and IIB-9, aging of 170° C.×11 hours was performed, and then scalping processing was performed to eliminate the surface of 1.5 mm depth, to thereby obtain test members. To the cast members No. IIB-5 to IIB-8 and IIB-10, scalping processing was performed to eliminate the surface of 1.5 mm depth, and then aging of 170° C.×11 hours was performed, to thereby obtain test members.

The metal texture of each of these test pieces was observed, and the average DAS, the distribution state of the particle in the eutectic lamella texture, (the mean particle diameter of the eutectic Si particle, the number of particles and the area share of the eutectic Si particles and the second phase particles), the eutectic lamella texture size (the mean skeleton line length Lm, the mean width Wm, these ratio L/Wm) were examined. The main points of the manufacture conditions of each casting example are again shown in Table 11, the observation results of the metal texture are shown in Table 11.

TABLE 11Casting conditionsCastingCastingmethod,CastingCastCoolingAgingNo.AlloyCastingratediameterrateTemp.(IIB-n)No.conditionsMm/min.mm° C./min.° C.Hours hInvention1IIA-30Vertical, a 150120 20170112Vertical, b 30053 403Horizontal, d3,000104004Horizontal, c 800251005IIA-127Vertical, a 150120 206Vertical, b 30053 407Horizontal, d3,000104008Horizontal, c 80025100Compartive9IIA-30Mold 10200 0.51701110IIA-127Mold 10200 0.5Metal textureEutectic lamella textureDistribution state ofMeanparticleskeletonCastingMeanMeanParticlelineMeanNo.DASdiameterAreanumberlengthwidth(IIB-n)μmμmshare %Pieces/mm²Lm, μmWm, μmL/WmInvention115.90.783.12.7 × 10³42.44.69.2220.40.912.95.9 × 10³50.64.910.334.90.453.62.9 × 10⁴49.53.215.547.60.503.01.8 × 10⁴44.63.911.458.71.027.52.7 × 10⁴108.64.126.5612.41.557.72.7 × 10⁴112.45.321.274.50.656.92.7 × 10⁴70.24.117.187.21.017.62.7 × 10⁴88.63.723.9Compartive922.76.204.23.5 × 10³10.32.14.91016.27.229.52.5 × 10³15.54.63.4
The underlined means the data falls out of the scope of the invention.

About each test piece, the mechanical properties of 0.2% proof strength, tensile strength, fracture elongation were measured, and the casting nature, cutting ability, abrasion of a tool, quality of the finished surface, cutting crack nature and corrosion resistance were examined by the same method as in the aforementioned alloy composition test. Furthermore, the existence and the number of internal defects were also evaluated relatively. Furthermore, the comprehensive quality as an alloy material was evaluated. The evaluation was made as the following four grade relative evaluations.

⊚: Excellent
◯: Slightly excellent
Δ: Slightly poor

X: Very poor

TABLE 12CastingNo.MechanicalProductivityQuality ofCutting crackCorrosionOverall(II B-n)propertyCastabilityCutting abilityTool abrasionfinished surfacenatureresistanceInternal defectevaluationIn-1⊚⊚⊚⊚⊚⊚⊚⊚⊚vention2⊚◯◯⊚⊚⊚◯⊚◯3◯◯⊚⊚⊚⊚◯⊚◯4⊚⊚⊚⊚⊚⊚⊚⊚⊚5⊚⊚⊚⊚⊚⊚⊚⊚⊚6◯⊚◯⊚⊚⊚◯⊚◯7⊚◯⊚⊚⊚⊚⊚⊚◯8⊚⊚⊚⊚⊚⊚⊚⊚⊚Com-9ΔΔXΔXΔΔXXparative10XΔXΔXΔΔXX

From the results of Table 12, it was confirmed that the aluminum alloy material manufactured by the method of this invention has an eutectic lamella texture where Si particles are dispersed finely in the metal texture, and therefore has outstanding cutting ability (including quality of finished surface and cutting crack nature) and corrosion resistance.

C. Aging Treatment and Secondary Forming Processing

Using the alloys No. IIA-30 and IIA-127 as casting materials, a non-hollow of a round cross-section with a diameter of 53 mm was made under the casting conditions b shown in Table 7 by the same gas pressurization type hot top casting as the aforementioned example of “A. chemical composition of an aluminum alloy.” The surface portion of the cast non-hollow member of 1.5 mm depth was eliminated by peeling processing, and then aging is performed under the conditions shown in Table 13. Furthermore, to the processing No. IIC-5 to IIC-8 and IIC13 to IIC-16, drawing processing was given thereto at the temperature shown in Table 13 and the cross-sectional area reduction ratio. Drawing was performed well in all processing No.

About each test piece manufactured, the mechanical properties of 0.2% proof strength, tensile strength, fracture elongation were measured, and the cutting ability, abrasion of a tool, quality of the finished surface, cutting crack nature and impact property were evaluated. The impact property was examined by the following method and the examination method of the other items was performed by the same method as in the aforementioned alloy compositions examination. The evaluation was made as the following four grade relative evaluations. In this examination, the mechanical property was evaluated as relative evaluation.

⊚: Excellent
◯: Slightly excellent
Δ: Slightly poor
X: Very poor

[Impact Property]

The metallic material impact test based on JIS Z2202 and JIS Z2242 was performed, and the impact property was evaluated by the charpy impact.

TABLE 13Drawing processingCross-sectionVarious characteristicsTreatmentAgingareaQuality ofCuttingNo.Temp.Temp.reductionMechanicalCuttingToolfinishedcrackCorrosionImpact(IIC-n)Alloy No.° C.Time H° C.ratio %propertyabilityabrasionsurfacenatureresistancepropertyInvention1IIA-3017011 ——⊚⊚◯⊚⊚◯◯2IIA-301606——◯◯◯◯⊚◯◯3IIA-3016015 ——⊚⊚◯⊚⊚◯◯4IIA-302007——⊚⊚◯⊚⊚◯◯5IIA-301609Room temp. 5⊚⊚◯⊚⊚◯◯6IIA-301608Room temp.10⊚⊚◯⊚⊚◯◯7IIA-301707Room temp.10⊚⊚◯⊚⊚◯◯8IIA-302004Room temp.10⊚⊚◯⊚⊚◯◯9IIA-12717011 ——⊚⊚◯⊚⊚◯◯10IIA-1271606——⊚⊚◯⊚⊚◯◯11IIA-12716015 ——◯◯◯◯⊚◯◯12IIA-1272007——⊚⊚◯⊚⊚◯◯13IIA-1271609Room temp. 5⊚⊚◯⊚⊚◯◯14IIA-1271608Room temp.10⊚⊚◯⊚⊚◯◯15IIA-1271707Room temp.10⊚⊚◯⊚⊚◯◯16IIA-1272004Room temp.10⊚⊚◯⊚⊚◯◯Com-17IIA-303101——XΔ◯Δ◯ΔΔparative18IIA-30160105 ——XΔ◯Δ◯ΔΔ19IIA-1273101——XΔ◯Δ◯ΔΔ20IIA-127160105 ——XΔ◯Δ◯ΔΔ
In this Table, the underlined numeral is out of the scope of the invention.

From the result shown in Table 13, it was confirmed that, by giving the aging treatment to a cast member under the conditions of the invention, outstanding mechanical property, cutting ability (including quality of finished surface and cutting crack nature), corrosion resistance and impact property can be obtained, and abrasion of a tool can be suppressed. Furthermore, it was also confirmed that the secondary forming processing under the conditions of the invention enables forming processing without deteriorating various characteristics, especially cutting ability.

As mentioned above, since the aluminum alloy material of the invention is excellent in cutting ability, the member can be applied to materials of various kinds of member accompanied by cutting processing. Furthermore, since no toxic Pb is contained, not bad influence is given to the environment and recycle nature is also preferable. Therefore, the material is excellent from the viewpoint of earth environment protection.

It should be appreciated that the terms and descriptions herein are not used for limiting the scope of the invention, but used only for explanatory purposes, and the invention does not eliminate any feature equivalent to the feature disclosed and explained herein, and permits any modifications and substitutions within the scope of the present invention defined by the appended claims.

Number	Date	Country	Kind
2002-148340	May 2002	JP	national
2001-224661	Jul 2001	JP	national

	Number	Date	Country
Parent	10202669	Jul 2002	US
Child	11236523	Sep 2005	US

Aluminum alloy excellent in cutting ability, aluminum alloy materials and manufacturing method thereof

Information

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Date Filed

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Inventors

Original Assignees

CPC

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Abstract

Description

Claims

Priority Claims (2)

CROSS REFERENCE TO RELATED APPLICATIONS

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