Claims
- 1. An antiperspirant-deodorant composition comprising in a cosmetic carrier as the active compound to inhibit perspiration and the formation of body odor, an effective amount of a compound having the formula ##STR5## wherein X is selected from the group consisting of chlorine, bromine and R.sub.1 SO.sub.3 wherein R.sub.1 is selected from the group consisting of alkyl having from 1 to 4 carbon atoms, phenyl, p-chlorophenyl, p-hydroxyphenyl and 2-oxo 10-bornanyl, and R represents a member selected from the group consisting of chlorine, methyl and methoxy.
- 2. The composition of claim 1 wherein said active compound is selected from the group consisting of
- bis-(2-N-oxypyridyl thio) aluminum chloride,
- bis-(2-N-oxypyridyl thio) aluminum bromide,
- bis-(2-N-oxypyridyl thio) aluminum camphosulfonate,
- bis-(2-N-oxypyridyl thio) aluminum p-toluenesulfonate,
- bis-(2-N-oxypyridyl thio) aluminum p-hydroxybenzenesulfonate,
- bis-(2-N-oxypyridyl thio) aluminum methanesulfonate,
- bis-(4-chloro-2-N-oxypyridyl thio) aluminum chloride,
- bis-(6-chloro-2-N-oxypyridyl thio) aluminum chloride,
- bis-(4-methoxy-2-N-oxypyridyl thio) aluminum p-chlorobenzenesulfonate,
- bis-(6-methoxy-2-N-oxypyridyl thio) aluminum bromide,
- bis-(5-chloro-2-N-oxypyridyl thio) aluminum camphosulfonate and
- bis-(6-methyl-2-N-oxypyridyl thio) aluminum chloride.
- 3. The composition of claim 1 wherein said active compound is present in an amount between 0.01 and 5% by weight of said composition.
- 4. The composition of claim 1 wherein said active compound is present in an amount of about 0.05 and 2% by weight of said composition.
- 5. The composition of claim 1 in the form of a lotion, cream, stick, powder or aerosol spray.
- 6. The composition of claim 1 in lotion form, wherein said active compound is present in an amount of about 0.01 and 0.1% by weight of said composition and wherein said cosmetic carrier is selected from the group consisting of water and an aqueous solution of a lower alkanol selected from the group consisting of ethanol and isopropanol.
- 7. The composition of claim 1 in aerosol spray form and packaged under pressure wherein said active compound is present in an amount of about 0.01 to 5% by weight of said composition and which also includes liquified propellant gas under pressure.
- 8. The composition of claim 1 in cream form, wherein said active compound is present in an amount of about 0.01 to 5% by weight of said composition and wherein said cosmetic carrier is a water-in-oil emulsion.
- 9. The composition of claim 8, wherein said water-in-oil emulsion comprises about 10-50 weight percent oil and 90-50 weight percent water.
- 10. The composition of claim 1 in stick form, wherein said active compound is present in an amount of about 0.01 to 5% by weight of said composition and is emulsified in said cosmetic carrier which is a mixture of a member selected from the group consisting of water, lower alkanol or a mixture thereof and wax.
- 11. The composition of claim 1 in powder form wherein said active compound is present in an amount of about 0.01 to 5% by weight of said composition and wherein said cosmetic carrier is talc.
- 12. The composition of claim 7 which also includes an anhydrous alcohol selected from the group consisting of ethanol and isopropanol.
- 13. The composition of claim 7 which also includes talc.
- 14. A compound of the formula ##STR6## wherein X is R.sub.1 SO.sub.3 wherein R.sub.1 represents a member selected from the group consisting of alkyl having from 1 to 4 carbon atoms, phenyl, p-methylphenyl, p-chlorophenyl, p-hydroxyphenyl and 2-oxo 10-bornanyl radical and R represents a member selected from the group consisting of chlorine, methyl and methoxy.
- 15. The compound of claim 14 selected from the group consisting of
- bis-(2-N-oxypyridyl thio) aluminum camphosulfonate,
- bis-(2-N-oxypyridyl thio) aluminum p-toluenesulfonate,
- bis-(2-N-oxypyridyl thio) aluminum p-hydroxybenzenesulfonate,
- bis-(2-N-oxypyridyl thio) aluminum methanesulfonate,
- bis-(4-methoxy 2-N-oxypyridyl thio) aluminum p-chlorobenzenesulfonate and
- bis-(5-chloro 2-N-oxypyridyl thio) aluminum camphosulfonate.
- 16. A process for preparing a compound of claim 14 comprising reacting in an anhydrous solvent selected from the group consisting of methanol, ethanol, isopropanol, tertio-butyl alcohol, benzene, toluene, chloroform and dichlorethane, a 2-pyridine thiol N-oxide of the formula ##STR7## wherein R represents a member selected from the group consisting of hydrogen, chlorine, methyl and methoxy, with aluminum isopropylate and reacting the resulting reaction product with sulfonic acid having the formula R.sub.1 SO.sub.3 H wherein R.sub.1 represents a member selected from the group consisting of alkyl having 1-4 carbon atoms, phenyl, p-methylphenyl, p-chlorophenyl, p-hydroxyphenyl and 2-oxo 10-bornanyl.
- 17. The process of claim 16 wherein the molar ratio of said 2-pyridine thio N-oxide to aluminum isopropylate is 2:1.
Priority Claims (1)
Number |
Date |
Country |
Kind |
65350 |
May 1972 |
LU |
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Parent Case Info
This is a division of application Ser. No. 294,072, filed Oct. 2, 1972, now U.S. Pat. No. 3,953,450.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
3347863 |
Ottman |
Oct 1967 |
|
3953450 |
Bouillon |
Apr 1976 |
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Divisions (1)
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Number |
Date |
Country |
Parent |
294072 |
Oct 1972 |
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