Claims
- 1. A process for preparing amine-sulfide terminated polymers comprising:
- forming an aqueous reaction mixture of water,
- one or more monomers wherein at least 20 percent by weight of the one or more monomers are monoethylenically unsaturated acids, or salts thereof,
- one or more amine-thiols, and
- one or more water-soluble initiators; and maintaining the aqueous reaction mixture at an elevated temperature to form amine-sulfide terminated polymers.
- 2. The process of claim 1, wherein the amine-thiol is selected from the group consisting of: amino acids containing one or more amines and one or more thiols; derivatives, peptides and polypeptides of amino acids containing one or more amines and one or more thiols; and derivatives, peptides and polypeptides of amino acids containing one or more thiols and one or more protected amines wherein the protecting group is capable of being removed.
- 3. The process of claim 1, wherein the amine-thiol is selected from the group consisting of: cysteine, N-acyl cysteine, cystine and glutathione.
- 4. The process of claim 1, wherein the amine-thiol is selected from the group consisting of: cysteine, N-acyl cysteine, and glutathione.
- 5. The process of claim 1, wherein the amine-thiol is an aminoalkyl thiol.
- 6. The process of claim 1, wherein the amine-thiol is aminoethane thiol.
- 7. The process of claim 1, wherein the one or more monomers are acrylic acid, methacrylic acid or salts thereof.
- 8. The process of claim 1, wherein the one or more monoethylenically unsaturated acids are selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid, vinylacetic acid, maleic acid, maleic anhydride, 1,2,3,6-tetrahydrophthalic anhydride, 3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride, 5-norbornene-2,3-dicarboxylic anhydride, bicyclo[2.2.2]-5-octene-2,3-dicarboxylic anhydride, 3-methyl-1,2,6-tetrahydrophthalic anhydride, 2-methyl-1,3,6-tetrahydrophthalic anhydride, itaconic acid, mesaconic acid, fumaric acid, citraconic acid, 2-acrylamido-2-methylpropanesulfonic acid, allylsulfonic acid, allylphosphonic acid, allyloxybenzenesulfonic acid, 2-hydroxy-3-(2-propenyloxy) propanesulfonic acid, isopropenylphosphonic acid, vinylphosphonic acid, styrenesulfonic acid, vinylsulfonic acid and the alkali metal and ammonium salts thereof.
- 9. The process of claim 1 wherein, up to about 80 percent by weight of the one or more monomers are monoethylenically unsaturated acid-free monomers.
- 10. The process of claim 9 wherein the monoethylenically unsaturated acid-free monomers are selected from the group consisting of acrylamide, methacrylamide, N-tertiarybutylacrylamide, N-methylacrylamide, N,N-dimethylacrylamide, methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, butyl methacrylate, isobutyl methacrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, and hydroxyethyl methacrylate.
Parent Case Info
This is a divisional of application Ser. No. 36,595, filed Mar. 24, 1993, now U.S. Pat. No. 5,298,585.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
4217260 |
Daniel et al. |
Aug 1980 |
|
4699950 |
Sato et al. |
Oct 1987 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
2051317 |
Apr 1972 |
DEX |
Divisions (1)
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Number |
Date |
Country |
Parent |
36595 |
Mar 1993 |
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