Claims
- 1. A method for modifying a composition to increase its acid catalytic activity, said composition comprising a solid source of aluminum and a eolite characterized by an effective silica to alumina mole ratio of at least about 50 and a constraint index of about 1 to 12, which method comprises contacting said composition at a temperature of about 60.degree. to 200.degree. C. for about 2 to 72 hours with an aqueous ammonium solution under ammonia gas pressure such that a pH of at least about 10 is maintained in said solution.
- 2. The method of claim 1 wherein the silica to alumina mole ratio is an effective mole ratio of at least about 100.
- 3. The method of claim 1 wherein said resulting composition is calcined.
- 4. The method of claim 1 wherein said ammonium is provided by an ammonium source selected from the group consisting of (NH.sub.4).sub.2 CO.sub.3, NH.sub.4 OH and (NH.sub.4).sub.2 HPO.sub.4.
- 5. The method of claim 4 wherein said silica to alumina mole ratio is at least about 660.
- 6. The method of claim 1 wherein said zeolite has a structure selected from the group consisting of ZSM-5, ZSM-5/ZSM-11, ZSM-11, ZSM-12, ZSM-23, ZSM-35, ZSM-38, ZSM-48 and zeolite beta.
- 7. The method of claim 6 wherein said aqueous ammonium solution has an ammonium concentration of about 1 to 15N.
- 8. The method of claim 6 wherein the ammonia gas pressure is applied autogenously, and the ammonium concentration is about 5 to 12N.
- 9. The method of claim 7 wherein said ammonia gas pressure ranges from 5 to 1000 psig.
- 10. The method of claim 9 wherein said zeolite is combined with an inorganic oxide matrix.
- 11. The method of claim 10 wherein said contacting occurs at a temperature ranging from about 90.degree. to 150.degree. C.
- 12. The method of claim 11 wherein said contacting occurs in the presence of a weak acid having a pKa of at least about 2 at 25.degree. C.
- 13. The method of claim 11 wherein said contacting occurs in the presence of an alkylammonium hydroxide.
- 14. The method of claim 11 wherein said ammonium source is NH.sub.4 OH.
- 15. The method of claim 11 wherein said silica to alumina mole ratio is at least about 660.
- 16. The method of claim 11 wherein said zeolite has the structure of ZSM-5.
- 17. The method of claim 16 wherein said aqueous ammonium ion solution has an ammonium concentration of about 1N to 15N.
- 18. The method of claim 17 wherein said ammonia gas pressure ranges from about 5 to 1000 psig.
- 19. The method of claim 18 wherein said inorganic matrix is alumina.
- 20. The method of claim 19 wherein said contacting occurs at a temperature ranging from about 90.degree. to 150.degree. C.
- 21. The method of claim 12 wherein said contacting occurs in the presence of a weak acid selected from the group consisting of H.sub.2 CO.sub.3, H.sub.3 BO.sub.3 and citric acid.
- 22. The method of claim 13 wherein said alkylammonium hydroxide is tetrapropylammonium hydroxide.
- 23. The method of claim 1 wherein said zeolite is calcined after said contacting.
- 24. The method of claim 1 further comprising contacting the modified composition with steam.
CROSS REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of copending U.S. Application Ser. No. 140,359, filed Jan. 4, 1988, now U.S. Pat. No. 4,837,398, which is a continuation in part of U.S. Application Ser. No. 081,955, filed Aug. 5, 1987, now abandoned, the entire disclosures of which are expressly incorporated herein by reference.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
3404086 |
Plank et al. |
Oct 1968 |
|
4596704 |
Miale et al. |
Jun 1986 |
|
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
140359 |
Jan 1988 |
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Parent |
081955 |
Aug 1987 |
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