Patent Grant
9718733
The present invention relates to the technical field of concrete superplasticizers, and more particularly to an amphoteric betaine-type polycarboxylate superplasticizer and a preparation method thereof.
With the continuous development of construction industry and science and technology, concretes become increasingly widely used, and thus increasingly higher requirements are imposed on the technical performance of the concretes. In practice, use of additives is confirmed to be a major way to advance the concrete technology, because with them, the concrete is adapted to meet various construction requirements, and has the advantages of low investment, quick action, convenient generalization for use, notable technical and economical benefits, and others. Superplasticizer is one of the most important concrete additives.
In recent years, high performance and pollution free are development tendency in research and production of concretesuperplasticizers. For example, maleic anhydride-based and acrylic high-performance concretesuperplasticizers are widely used in hydraulic and road engineering requiring durable concretes in America, Japan, Italia and other countries. Although the technology is mature, the process is complex and the reaction condition is harsh, which are unfavorable for generalization.
The research on high-performance superplasticizer has progressed to the 3rd generation of polycarboxylate superplasticizers, which are further subdivided into four classes, that is, copolymers of vinyl monomers, propylene oxide copolymers, polyamide/polyimide type copolymers, and amphoteric vinyl polymers. The amphoteric vinyl polymer superplasticizer is a class of highly effective superplasticizer which exhibits the highest performance in the 3rd generation of high-potent superplasticizers.
Betaine-type amphoteric monomers are a class of functional monomers that are widely used hitherto, which generally have a polymerizable alkenyl moiety and a betaine pendant moiety with electrically neutral amphoteric feature in their structure, and are of a carboxylic betaine type and a sulfonic betaine type. Amphoteric polymers having a net charge of 0 and anti-polyelectrolyte solution behaviors may be obtained from homopolymerization or copolymerization of these betaine-type amphoteric monomers alone or with other neutral monomers under certain conditions. These amphoteric polymers arouse great interest due to the high chemical and thermal stability, high hydration capacity, and the inclusion of equal number of quaternary ammonium cations and sulfonate anions that are insusceptible to the pH of the solution.
Patents CN101538352A, CN102627744B, and CN102443177B successively disclose a method for preparing an amphoteric polymeric superplasticizer, mainly through copolymerization of two cationic monomers. However, the process is complex. At present, there is no amphoteric polycarboxylate superplasticizer based on betaine monomers disclosed.
In light of the above technical problems, the present invention provides an amphoteric betaine-type polycarboxylate superplasticizer and a preparation method thereof, so as to overcome the defect in the prior art that there is no betaine-type amphoteric polycarboxylate superplasticizer.
The present invention employs the following technical solution. An amphoteric betaine-type polycarboxylate superplasticizer is provided, which is obtained through aqueous solution polymerization of a monomer A, a monomer B and a monomer C at a weight ratio of (1-30%):(20-50%):(20-50%) in the presence of an initiator;
where the monomer A has a general formula of
in which R1 is H or CH3, R2 is O or NH, R3 is any one of CH3, CH2CH3, and CH2CH2CH3, and Y is any one of COO, SO3, and PO3;
the monomer B has a general formula of
in which R4 is H or CH3, and m is the average addition moles of oxyethylene and is an integer selected from 1-100; and
the monomer C has a general formula of
in which R5 is H or CH3.
The present invention further provides a method for preparing an amphoteric betaine-type polycarboxylate superplasticizer, comprising:
placing a monomer A and a monomer B in a reaction vessel, adding water, and stirring;
then adding a monomer C to the reaction vessel, stirring, and adding water to adjust in such a manner that the total weight of the monomers accounts for 10-20% of the total weight of the aqueous solution, in which the weight ratio of the monomer A, the monomer B, and the monomer C is (1-30%):(20-50%):(20-50%);
under an inert atmosphere, adding an initiator when the temperature is raised to 60-100° C.; and
reacting for 4-6 hrs with thermal insulation, and after the reaction is complete, adjusting the pH to 5-7, to obtain an aqueous solution of the amphoteric betaine-type polycarboxylate superplasticizer;
where the monomer A has a general formula of
in which R1 is H or CH3, R2 is O or NH, R3 is any one of CH3, CH2CH3, and CH2CH2CH3, and Y is any one of COO, SO3, and PO3;
the monomer B has a general formula of
in which R4 is H or CH3, and m is the average addition moles of oxyethylene and is an integer selected from 1-100; and
the monomer C has a general formula of
in which R5 is H or CH3.
The method for preparing an amphoteric betaine-type polycarboxylate superplasticizer according to the present invention is simple in reaction process, environmentally friendly and free of contaminations. The prepared betaine-type polycarboxylate superplasticizer has an amphoteric structure and a strong dispersibility for concretes. The reaction system is free of Cl−ions, thus causing no corrosion to construction materials. The superplasticizer is widely applicable to production of high-performance concretes, recycled concretes, moisture-retention concretes, ceramic products, and brick and tile products for enhancing the fluidity, reducing the water consumption, and lowering the energy consumption.
To make the technical problem, technical solution and beneficial effects of the present invention more clear, the present invention is described in further detail with reference to examples below. It should be understood that the specific examples described herein is merely provided for illustrating, instead of limiting, the present invention.
An embodiment of the present invention provides an amphoteric betaine-type polycarboxylate superplasticizer, which is obtained through aqueous solution polymerization of a monomer A, a monomer B and a monomer C at a weight ratio of (1-30%):(20-50%):(20-50%) in the presence of an initiator;
where the monomer A has a general formula of
in which R1 is H or CH3, R2 is O or NH, R3 is any one of CH3, CH2CH3, and CH2CH2CH3, and Y is any one of COO, SO3, and PO3;
the monomer B has a general formula of
in which R4 is H or CH3, and m is the average addition moles of oxyethylene and is an integer selected from 1-100; and
the monomer C has a general formula of
in which R5 is H or CH3.
An embodiment of the present invention further provides a method for preparing an amphoteric betaine-type polycarboxylate superplasticizer, comprising:
where the monomer A has a general formula of
in which R1 is H or CH3, R2 is O or NH, R3 is any one of CH3, CH2CH3, and CH2CH2CH3, and Y is any one of COO, SO3, and PO3;
the monomer B has a general formula of
in which R4 is H or CH3, and m is the average addition moles of oxyethylene and is an integer selected from 1-100; and
the monomer C has a general formula of
in which R5 is H or CH3.
In Step (1), adding water and stirring are preferably done by adding deionized water and then stirring to uniformity, followed by addition of the monomer C as described in Step (2), in which the weight percentages of the three monomers are 1-30%, 20-50%, and 20-50% respectively. After the three monomers are uniformly mixed, deionized water is added to adjust in such a manner that the total weight of the three monomers accounts for 10-20% of the total weight of the aqueous solution.
In Step (3), the aqueous initiator solution is required to be added under an inert (nitrogen) atmosphere when the temperature is raised to 60-100° C. while stirring. The initiator is a water soluble free radical initiator, and preferably ammonium persulfate, potassium persulphate, or a redox initiator. The initiator is used in an amount of 0.5-2% of the total weight of the monomers. The initiator is slowly added batchwise and preferably in three batches, such that ⅓ of the total weight of the initiator is added dropwise per hour.
In Step (4), after the addition of the initiator is complete, the reaction is continued for 4-6 hrs with thermal insulation by maintaining the temperature constant. After the reaction is complete, the reaction solution is cooled to room temperature, and then adjusted to pH5-7 at room temperature, by adding preferably 1-3 mol/L and more preferably 3 mol/L of a basic aqueous NaOH solution. The prepared aqueous superplasticizer solution was adjusted to have a weight percentage of 10-30%.
The method for preparing an amphoteric betaine-type polycarboxylate superplasticizer according to the present invention is simple in reaction process, environmentally friendly and free of contaminations. The prepared betaine-type polycarboxylate superplasticizer has an amphoteric structure and a strong dispersibility for concretes. The reaction system is free of Cl−ions, thus causing no corrosion to construction materials. The superplasticizer has a stable performance, a high water reducing rate, a high adaptability to cements, and a good compounding effect, thus being widely used in production of high-performance concretes, recycled concretes, moisture-retention concretes, ceramic products, and brick and tile products for enhancing the fluidity, reducing the water consumption, and lowering the energy consumption.
10 g of methyl allyl polyoxyethylene ether with a molecular weight of 1000(MPEG1000), and 2 g of N,N-dimethyl(methacryloyloxyethyl)ammonium propanesulfonate (DMPAS) were fed to a reaction vessel containing 100 g of distilled water, heated, and stirred to uniformity. Then, 5 g of acrylic acid (AA) was added. When the temperature of the water bath was raised to 75° C. while stirring, a first 0.05 g of ammonium persulfate was added, and reacted for 1 h; then an additional 0.05 g of ammonium persulfate was added, and reacted for another 1 h; and subsequently, a last 0.05 g of ammonium persulfate was added. After reaction with thermal insulation for 4 hrs, the aqueous solution was cooled to room temperature and adjusted to pH 6-7 with 3 mol/L of a NaOH solution, and the aqueous solution was adjusted to have a solid content of 20%. In this manner, a betaine-type polycarboxylate superplasticizer of MPEG-DMPAS-AA-1 was obtained. Following the test method in National Standard GB 8077-2000, the superplasticizer was tested to have a cement paste fluidity of 265 mm.
10 g of methyl allyl polyoxyethylene ether with a molecular weight of 2000 (MPEG2000), and 4 g of N,N-dimethyl-N-methacrylamidopropyl-N-propanesulfonate (DMHAS) were fed to a reaction vessel containing 100 g of distilled water, heated, and stirred to uniformity. Then, 5 g of methacrylic acid (MA) was added. When the temperature of the water bath was raised to 75° C. while stirring, a first 0.06 g of ammonium persulfate was added, and reacted for 1 h; then an additional 0.06 g of ammonium persulfate was added, and reacted for another 1 h; and subsequently, a last 0.06 g of ammonium persulfate was added. After reaction with thermal insulation for 4 hrs, the aqueous solution was cooled to room temperature and adjusted to pH6-7 with 3 mol/L of a NaOH solution, and the aqueous solution was adjusted to have a solid content of 25%. In this manner, a betaine-type polycarboxylate superplasticizer of MPEG-DMHAS-MA-2 was obtained. Following the test method in National Standard GB 8077-2000, the superplasticizer was tested to have a cement paste fluidity of 245 mm.
10 g of allyl polyoxyethylene ether with a molecular weight of 1000(TPEG1000), and 4 g of N,N-dimethyl(methacryloyloxyethyl)ammonium propanesulfonate (DMPAS) were fed to a reaction vessel containing 100 g of distilled water, heated, and stirred to uniformity. Then, 5 g of methacrylic acid (MA) was added. When the temperature of the water bath was raised to 75° C. while stirring, a first 0.07 g of ammonium persulfate was added, and reacted for 1 h; then an additional 0.07 g of ammonium persulfate was added, and reacted for another 1 h; and subsequently, a last 0.07 g of ammonium persulfate was added. After reaction with thermal insulation for 4 hrs, the aqueous solution was cooled to room temperature and adjusted to pH6-7 with 3 mol/L of a NaOH solution, and the aqueous solution was adjusted to have a solid content of 15%. In this manner, a betaine-type polycarboxylate superplasticizer of TPEG-DMPAS-MA-3 was obtained. Following the test method in National Standard GB 8077-2000, the superplasticizer was tested to have a cement paste fluidity of 295 mm.
10 g of allyl polyoxyethylene ether with a molecular weight of 2000 (TPEG2000) and 6 g of N,N-dimethyl-N-methacrylamidopropyl-N-propanesulfonate (DMHAS) were fed to a reaction vessel containing 100 g of distilled water, heated, and stirred to uniformity. Then, 5 g of methacrylic acid (MA) was added. When the temperature of the water bath was raised to 75° C. while stirring, a first 0.08 g of ammonium persulfate was added, and reacted for 1 h; then an additional 0.08 g of ammonium persulfate was added, and reacted for another 1 h; and subsequently, a last 0.08 g of ammonium persulfate was added. After reaction with thermal insulation for 4 hrs, the aqueous solution was cooled to room temperature and adjusted to pH6-7 with 3 mol/L of a NaOH solution, and the aqueous solution was adjusted to have a solid content of 30%. In this manner, a betaine-type polycarboxylate superplasticizer of TPEG-DMHAS-MA-4 was obtained. Following the test method in National Standard GB 8077-2000, the superplasticizer was tested to have a cement paste fluidity of 305 mm.
10 g of allyl polyoxyethylene ether with a molecular weight of 3000(TPEG3000), and 8 g of N,N-dimethyl(methacryloyloxyethyl)ammonium propanesulfonate (DMPAS) were fed to a reaction vessel containing 100 g of distilled water, heated, and stirred to uniformity. Then, 5 g of acrylic acid (AA) was added. When the temperature of the water bath was raised to 75° C. while stirring, a first 0.09 g of ammonium persulfate was added, and reacted for 1 h; then an additional 0.09 g of ammonium persulfate was added, and reacted for another 1 h; and subsequently, a last 0.09 g of ammonium persulfate was added. After reaction with thermal insulation for 4 hrs, the aqueous solution was cooled to room temperature and adjusted to pH6-7 with 3 mol/L of a NaOH solution, and the aqueous solution was adjusted to have a solid content of 20%. In this manner, a betaine-type polycarboxylate superplasticizer of TPEG-DMPAS-AA-5 was obtained. Following the test method in National Standard GB 8077-2000, the superplasticizer was tested to have a cement paste fluidity of 270 mm.
The forgoing description merely gives preferred examples of the present invention, and is not intended to limit the present invention. Any modifications, equivalent replacements and variations made without departing from the spirit and principle of the present invention are embraced in the protection scope of the present invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2014 1 0101519 | Mar 2014 | CN | national |
The present application is a Continuation application of PCT application No. PCT/CN2014/091013 filed on Nov. 13, 2014, which claims the benefit of Chinese patent application No. 201410101519.9 filed on Mar. 18, 2014. All the above are hereby incorporated by reference.
| Number | Date | Country |
|---|---|---|
| 101538352 | Sep 2009 | CN |
| 102453194 | May 2012 | CN |
| 102617065 | Aug 2012 | CN |
| 102443177 | Mar 2013 | CN |
| 102627744 | Jun 2013 | CN |
| 103253886 | Aug 2013 | CN |
| Entry |
|---|
| 1st Office Action of counterpart Chinese Patent Application No. 201410101519.9 issued on Oct. 26, 2015. |
| Number | Date | Country | |
|---|---|---|---|
| 20160185663 A1 | Jun 2016 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/CN2014/091013 | Nov 2014 | US |
| Child | 15063531 | US |
