1. Field of the Invention
The present invention relates to an antenna device used in a radio frequency IC device such as an RFID device that performs contactless communication by near-field transmission and a radio frequency IC device including the antenna device.
2. Description of the Related Art
Japanese Unexamined Patent Application Publication No. 2001-010264 discloses a contactless IC card used as an RFID device.
In order to obtain a good state of communication, the sharpness (Q) of the resonance circuit is controlled by controlling a resistance value Rad of the adjusting resistor 14 included in the resonance circuit and a resonance frequency is controlled by the capacitance Cad of an adjusting capacitor 15.
When such an IC card moves closer to a reader/writer so as to communicate with the reader/writer, however, antenna coils included in both of them are coupled and the inductance values of the antenna coils are changed. As a result, the resonance frequencies of the resonance circuits including the antenna coils are changed and gains are significantly changed.
An S11 characteristic (return loss) is represented by a characteristic curve Ra in
On the other hand, as illustrated in
Under the above-described condition in which the antenna included in the radio frequency IC device 200 and the antenna included in the reader/writer 300 are coupled by near-field transmission, as both of them get closer to each other, the resonance frequencies of both of the antennas are shifted in the direction of a lower frequency. If this antenna resonance frequency is lower than a frequency used by the radio frequency IC device 200 (that is, a communication frequency represented by a symbol fs in
In the conventional art, in order to prevent the resonance frequency from being lower than the communication frequency even if the resonance frequency is shifted in the direction of a lower frequency, it is required that the resonance frequency of the antenna device be set to a frequency that is 10 to 20 percent higher than the communication frequency in advance. Furthermore, in order to make communication possible even under the condition in which the resonance frequency is higher than the communication frequency, it is required that the value Q of a resonance circuit including an antenna coil be set to a low value by disposing a resistor in the resonance circuit as illustrated in
However, under the conditions allowing the radio frequency IC device 200 to communicate with the reader/writer 300 even if they are excessively close to each other, a resonance frequency of an antenna of the radio frequency IC device 200, which is obtained when the distance therebetween is normal, is shifted to a direction of a frequency higher than the communication frequency. Accordingly, if the distance between the radio frequency IC device 200 and the reader/writer 300 is larger than the normal distance, antenna gains are significantly reduced. Consequently, a sufficient communication distance cannot be obtained.
Furthermore, when the value Q of the resonance frequency including an antenna coil is set to a lower value, a relatively stable gain can be obtained with the broad characteristics of the resonance circuit even if the resonance frequency is shifted. On the other hand, however, since the value Q is set to a lower value, a gain is lowered regardless of the distance between the radio frequency IC device and the reader/writer.
Preferred embodiments of the present invention provide an antenna device in which the characteristics thereof are not significantly changed despite the influence of changes in the distance between a radio frequency IC device and a reader/writer and also provide a radio frequency IC device capable of achieving communication with high reliability.
An antenna device according to a preferred embodiment of the present invention includes an antenna coil arranged to transmit or receive a radio frequency communication signal to or from an external device, and an additional resonance circuit that is connected to the antenna resonance circuit, including at least one inductor, and that has a resonance frequency characteristic different from that of the antenna resonance circuit.
In the above-described configuration, for example, the resonance frequency of the additional resonance circuit is preferably set to a frequency lower than the resonance frequency of the antenna resonance circuit. As a result, the decrease in the resonance frequency of the antenna resonance circuit can be minimized and prevented by the resonance frequency of the additional resonance circuit even if a radio frequency IC device moves closer to the external device such as a reader/writer, antenna coils included both of them are magnetically coupled, and inductance values are thereby increased. Consequently, the amount of change in the resonance frequency of the antenna resonance circuit is reduced and a high gain can be stably obtained.
Conversely, the resonance frequency of the additional resonance circuit is preferably set to a frequency higher than the resonance frequency of the antenna resonance circuit, and is preferably set such that the resonance frequency of the antenna resonance circuit is higher than a communication frequency even in the condition in which the radio frequency IC device is excessively close to the reader/writer (the external device). As a result, even if the radio frequency IC device moves away from the reader/writer, an increase in the resonance frequency of the antenna resonance circuit (movement of it to the resonance frequency of the additional resonance circuit) can be prevented and minimized. Consequently, the amount of the change in the resonance frequency of the antenna resonance circuit is reduced, and the condition in which the resonance frequency of the antenna resonance circuit is near the communication frequency can be maintained over a wide communication range.
A magnetic field coupling between the antenna coil and the inductor included in the additional resonance circuit may be achieved. As a result, even if the resonance frequency of the antenna resonance circuit moves closer to the resonance circuit of the additional resonance circuit in accordance with the increase in an inductance value, it cannot easily jump over the resonance frequency of the additional resonance circuit. This can enhance the stability of the resonance frequency of the antenna resonance circuit.
The additional resonance circuit is, for example, a parallel resonance circuit. As a result, the inductance value of the additional resonance circuit can be a small value. This leads to the miniaturization of the additional resonance circuit.
For example, the antenna resonance circuit is connected in series to the additional resonance circuit. As a result, the magnetic field coupling between the antenna coil included in the antenna resonance circuit and the inductor included in the additional resonance circuit can be more easily achieved.
In particular, the resonance frequency of the antenna resonance circuit is preferably set to a frequency higher than a frequency used by the radio frequency IC device (a communication frequency), and the resonance frequency of the additional resonance circuit is set to a frequency lower than the communication frequency. As a result, as the radio frequency IC device including the antenna device moves closer to the external device such as a reader/writer, the resonance frequency of the antenna resonance circuit moves closer to the communication frequency. A higher gain can be therefore obtained.
For example, inductors included in the additional resonance circuits may individually include two adjacent lines of different lengths.
In this configuration, the range of resonance frequencies of the additional resonance circuits can be broadened. The effects of minimizing and preventing the change in the resonance frequency of the antenna resonance circuit can be enhanced by using the additional resonance circuits.
The inductor included in the additional resonance circuit may be magnetically shielded. As a result, even if the radio frequency IC device including the antenna device moves closer to the external device such as a reader/writer, the magnetic field coupling between the antenna device and the antenna coil included in the external device can be prevented. Accordingly, the inductance value of the inductor included in the additional resonance circuit is not changed. This can stabilize the resonance frequency of the additional resonance circuit. The resonance frequency of the antenna resonance circuit can be further stabilized.
The additional resonance circuit may be provided in a multilayer substrate including a magnetic substance. As a result, a thin device can be obtained, and the upsizing of the device due to the installation of the additional resonance circuit can be prevented. Furthermore, magnetic shielding can be simultaneously performed.
An output inductor may be connected in series to an input portion for receiving a signal transmitted from a radio frequency IC and may be provided in the multilayer substrate. As a result, an impedance matching circuit including the radio frequency IC and the antenna device is simultaneously provided in the multilayer substrate. The device can therefore be further miniaturized.
The capacitance component of the additional resonance circuit may be a chip capacitor and may be disposed on a surface of the multilayer substrate or in the multilayer substrate. As a result, the multilayer substrate can be further miniaturized, and an area required for the multilayer substrate can be reduced in the radio frequency IC device.
A radio frequency IC device according to a preferred embodiment of the present invention includes an antenna device including a multilayer substrate and a radio frequency IC chip disposed on a surface of the multilayer substrate or in the multilayer substrate. As a result, a module (an RFID module) including a radio frequency IC chip can be provided. The installation of the antenna device and the radio frequency IC in the radio frequency IC device can be easily performed.
According to a preferred embodiment of the present invention, a decrease in the resonance frequency of the antenna resonance circuit can be minimized and prevented by the resonance frequency of the additional resonance circuit even if the radio frequency IC device moves closer to the external device such as a reader/writer, antenna coils included both of them are magnetically coupled, and inductance values are therefore increased. Consequently, the amount of change in the resonance frequency of the antenna resonance circuit is reduced and a high gain can be stably obtained.
Conversely, even if the radio frequency IC device moves away from the external device, the change in the resonance frequency of the antenna resonance circuit can be minimized and prevented. Consequently, the condition in which the resonance frequency of the antenna resonance circuit is near the communication frequency can be maintained over a wide communication range.
Other features, elements, steps, characteristics and advantages of the present invention will become more apparent from the following detailed description of preferred embodiments of the present invention with reference to the attached drawings.
An antenna device 101 preferably includes the antenna resonance circuit AR and the additional resonance circuit LC1. The radio frequency IC device 201 preferably includes the antenna device 101 and the radio frequency IC 21.
The radio frequency IC device 201 is, for example, an RFID card. The antenna coil La has a spiral conductor pattern inside the card. The conductor pattern has a plurality of turns and is located along the periphery of the card. The capacitor Ca includes opposite electrodes between which a dielectric layer is sandwiched. The inductor L1 and the capacitor C1 are provided in a ferrite multilayer substrate. This ferrite multilayer substrate and the radio frequency IC 21 are sealed in the card, whereby a single RFID card is provided.
Each of
If the additional resonance circuit LC1 illustrated in
However, in a condition where the antenna of the radio frequency IC device and the antenna of the reader/writer are excessively close to each other, as illustrated in
On the other hand, if the antenna device 101 according to the first preferred embodiment is used, a resonance frequency fla of the additional resonance circuit LC1 is approximately 12.9 MHz and the resonance frequency foa of the antenna resonance circuit AR is approximately 15.2 MHz in the normal condition as illustrated in
In the condition in which the radio frequency IC device 201 is excessively close to the reader/writer, as illustrated in
As illustrated in
Next, the relationship between the resonance frequency of the additional resonance circuit LC1 and the decrease in the resonance frequency of the antenna resonance circuit AR, which is caused by magnetic field coupling between the antenna resonance circuit AR and the antenna of the reader/writer, will be described with reference to
As the radio frequency IC device 201 moves closer to the reader/writer, as illustrated in
Thus, the additional resonance circuit LC1 prevents the resonance frequency of the antenna resonance circuit AR from becoming lower than the resonance frequency flb thereof.
If a stronger magnetic field coupling between the antenna coil La included in the radio frequency IC device 201 and the antenna coil included in the reader/writer is achieved and the resonance frequency of the antenna resonance circuit is further lowered, as illustrated in
If the additional resonance circuit LC1 is not included, as illustrated in
On the other hand, in the antenna device 101 according to the first preferred embodiment, the impedance at the communication frequency of about 13.56 MHz (the position of the marker [1] in the drawings) exists in the upper half of each of the Smith charts regardless of whether the radio frequency IC device is located at an appropriate distance from the reader/writer or is excessively close to the reader/writer. That is, it can be understood that the impedance represents inductivity and the magnetic field coupling between the antennas of both of them is achieved.
Thus, the radio frequency IC device 201 can stably communicate with the reader/writer even if the distance between them is changed.
The magnetic field coupling between the antenna coil La and the inductor L1 included in the additional resonance circuit LC1, which are illustrated in
In the first preferred embodiment, the resonance frequency of the antenna resonance circuit AR is preferably set to a frequency higher than the communication frequency fs, and the resonance frequency of the additional resonance circuit LC1 is preferably set to a frequency lower than the resonance frequency of the antenna resonance circuit AR. In the second preferred embodiment, an example in which the resonance frequency of the additional resonance circuit LC1 is preferably set to a frequency higher than the resonance frequency of the antenna resonance circuit AR will be described.
In the condition in which the radio frequency IC device is located at an appropriate distance from the reader/writer, the magnetic field coupling between both of the antennas of the radio frequency IC device and the reader/writer is weak. Accordingly, as illustrated in
Thus, the radio frequency IC device can stably communicate with the reader/writer even if the distance between them is changed.
Next, some examples of the configuration of the additional resonance circuit will be described as the third preferred embodiment with reference to
In an example illustrated in
In an example illustrated in
In an example illustrated in
In an example illustrated in
In the configurations illustrated in
In the above-described examples of the third preferred embodiment, the radio frequency IC 21 is a balanced IC arranged to receive or output a signal, and the antenna device is therefore also a balanced antenna device. In an example of the third preferred embodiment illustrated in
The fourth preferred embodiment is an example in which the stability of the resonance frequency of the antenna resonance circuit is further enhanced using two additional resonance circuits.
As the radio frequency IC device according to the fourth preferred embodiment moves closer to a reader/writer, the resonance frequency fo of the antenna resonance circuit is lowered. However, the additional resonance circuit LC1 reduces the amount of the shift of the resonance frequency fo of the antenna resonance circuit in a direction of a lower frequency. The resonance frequencies fo and f1 are determined such that the resonance frequency fo does not jump over the communication frequency fs even in the condition in which the radio frequency IC device is excessively close to the reader/writer. If the radio frequency IC device moves apart from the reader/writer, the resonance frequency fo of the antenna resonance circuit is shifted in a direction of a higher frequency. However, the shift amount is reduced by the second additional resonance circuit LC2. Accordingly, the resonance frequency fo of the antenna resonance circuit AR can always be in the vicinity of the communication frequency fs regardless of the distance between the radio frequency IC device and the reader/writer. Thus, by disposing at least two additional resonance frequency circuits, the resonance frequency of the antenna resonance circuit can be stabilized in both of the direction of a lower frequency and the direction of a higher frequency.
As another example, both of the resonance frequencies of the two additional resonance circuits may exist on the side of a frequency lower or higher than the resonance frequency of the antenna resonance circuit. In this case, as compared with the case in which only a single additional resonance circuit is disposed, the stability of the resonance frequency of the antenna resonance circuit is further enhanced.
In each of the circuit configurations illustrated in
The antenna coil La has a spiral conductor pattern inside the card. The conductor pattern has a plurality of turns and is located along the periphery of the card. The capacitor Ca includes opposite electrodes between which a dielectric layer is sandwiched.
The module 22 includes two adjacent lines SL1 and SL2 having different lengths and the radio frequency IC (chip) 21.
A capacitance is generated between the two lines SL1 and SL2 included in the module 22. Two additional resonance circuits preferably include the generated capacitance and the inductances of the lines SL1 and SL2. Accordingly, if the radio frequency IC device 207 is equivalently represented by a lumped-constant circuit, the lumped-constant circuit is the same as the circuit according to the fourth preferred embodiment illustrated in
The antenna device 108 has the antenna coil La, the capacitor Ca, a first additional resonance circuit including the inductor L2 and the capacitor C2, and a second additional resonance circuit including the inductor L2 and the capacitor C2. Components other than the radio frequency IC 21 and the antenna coil La are included in a module 23.
In the upper layer 23a of the multilayer substrate, the inductor L1 and the inductor L2 are magnetically coupled. In the lower layer 23b of the multilayer substrate, the two output inductors L3 and L4 are magnetically coupled.
Thus, by achieving the magnetic field coupling between the inductors L1 and L2, the intervals of the resonance frequencies of the two additional resonance circuits can be fixed.
Chip capacitors corresponding to the capacitors C1, C2, C5, C6, and C7 illustrated in
Consequently, almost all of the required components can be included in a single module. Accordingly, for example, at the time of making an RFID card, the RFID card can be made only by forming the antenna coil La on the card in the form of a conductive pattern and installing the module 23 in the card.
In the case of a mobile telephone having an RFID function, the antenna coil La may be provided using a coil electrode disposed in the mobile telephone.
While preferred embodiments of the present invention have been described above, it is to be understood that variations and modifications will be apparent to those skilled in the art without departing the scope and spirit of the present invention. The scope of the present invention, therefore, is to be determined solely by the following claims.
Number | Name | Date | Kind |
---|---|---|---|
3364564 | Kurtz et al. | Jan 1968 | A |
3740742 | Thompson et al. | Jun 1973 | A |
4654641 | Ferguson et al. | Mar 1987 | A |
4794397 | Ohe et al. | Dec 1988 | A |
5232765 | Yano et al. | Aug 1993 | A |
5253969 | Richert | Oct 1993 | A |
5337063 | Takahira | Aug 1994 | A |
5374937 | Tsunekawa et al. | Dec 1994 | A |
5399060 | Richert | Mar 1995 | A |
5491483 | D'Hont | Feb 1996 | A |
5680106 | Schrott et al. | Oct 1997 | A |
5757074 | Matloubian et al. | May 1998 | A |
5903239 | Takahashi et al. | May 1999 | A |
5936150 | Kobrin et al. | Aug 1999 | A |
5955723 | Reiner | Sep 1999 | A |
5995006 | Walsh | Nov 1999 | A |
6104311 | Lastinger | Aug 2000 | A |
6107920 | Eberhardt et al. | Aug 2000 | A |
6172608 | Cole | Jan 2001 | B1 |
6181287 | Beigel | Jan 2001 | B1 |
6190942 | Wilm et al. | Feb 2001 | B1 |
6259369 | Monico | Jul 2001 | B1 |
6271803 | Watanabe et al. | Aug 2001 | B1 |
6335686 | Goff et al. | Jan 2002 | B1 |
6362784 | Kane et al. | Mar 2002 | B1 |
6367143 | Sugimura | Apr 2002 | B1 |
6378774 | Emori et al. | Apr 2002 | B1 |
6406990 | Kawai | Jun 2002 | B1 |
6448874 | Shiino et al. | Sep 2002 | B1 |
6462716 | Kushihi | Oct 2002 | B1 |
6542050 | Arai et al. | Apr 2003 | B1 |
6600459 | Yokoshima et al. | Jul 2003 | B2 |
6634564 | Kuramochi | Oct 2003 | B2 |
6664645 | Kawai | Dec 2003 | B2 |
6763254 | Nishikawa | Jul 2004 | B2 |
6828881 | Mizutani et al. | Dec 2004 | B2 |
6927738 | Senba et al. | Aug 2005 | B2 |
6963729 | Uozumi | Nov 2005 | B2 |
7088307 | Imaizumi | Aug 2006 | B2 |
7112952 | Arai et al. | Sep 2006 | B2 |
7119693 | Devilbiss | Oct 2006 | B1 |
7129834 | Naruse et al. | Oct 2006 | B2 |
7248221 | Kai et al. | Jul 2007 | B2 |
7250910 | Yoshikawa et al. | Jul 2007 | B2 |
7276929 | Arai et al. | Oct 2007 | B2 |
7317396 | Ujino | Jan 2008 | B2 |
7405664 | Sakama et al. | Jul 2008 | B2 |
7843345 | Lazar | Nov 2010 | B2 |
20020011967 | Goff et al. | Jan 2002 | A1 |
20020044092 | Kushihi | Apr 2002 | A1 |
20020067316 | Yokoshima et al. | Jun 2002 | A1 |
20030020661 | Sato | Jan 2003 | A1 |
20030178483 | Wakabayashi | Sep 2003 | A1 |
20040001027 | Killen et al. | Jan 2004 | A1 |
20040066617 | Hirabayashi et al. | Apr 2004 | A1 |
20040217915 | Imaizumi | Nov 2004 | A1 |
20040219956 | Iwai et al. | Nov 2004 | A1 |
20040227673 | Iwai et al. | Nov 2004 | A1 |
20050092836 | Kudo | May 2005 | A1 |
20050099337 | Takei et al. | May 2005 | A1 |
20050125093 | Kikuchi et al. | Jun 2005 | A1 |
20050140512 | Sakama et al. | Jun 2005 | A1 |
20050232412 | Ichihara et al. | Oct 2005 | A1 |
20050236623 | Takechi et al. | Oct 2005 | A1 |
20050275539 | Sakama et al. | Dec 2005 | A1 |
20060001138 | Sakama et al. | Jan 2006 | A1 |
20060055601 | Kameda et al. | Mar 2006 | A1 |
20060071084 | Detig et al. | Apr 2006 | A1 |
20060109185 | Iwai et al. | May 2006 | A1 |
20060145872 | Tanaka et al. | Jul 2006 | A1 |
20060158316 | Eckstein | Jul 2006 | A1 |
20060158380 | Son et al. | Jul 2006 | A1 |
20060170606 | Yamagajo et al. | Aug 2006 | A1 |
20060267138 | Kobayashi | Nov 2006 | A1 |
20070004028 | Lair et al. | Jan 2007 | A1 |
20070018893 | Kai et al. | Jan 2007 | A1 |
20070040028 | Kawamata | Feb 2007 | A1 |
20070052613 | Gallschuetz et al. | Mar 2007 | A1 |
20070158438 | Fukuda et al. | Jul 2007 | A1 |
20070164414 | Dokai et al. | Jul 2007 | A1 |
20070247387 | Kubo et al. | Oct 2007 | A1 |
20070252700 | Ishihara et al. | Nov 2007 | A1 |
20070252703 | Kato et al. | Nov 2007 | A1 |
20070285335 | Bungo et al. | Dec 2007 | A1 |
20080024156 | Arai et al. | Jan 2008 | A1 |
20080087990 | Kato et al. | Apr 2008 | A1 |
20080169905 | Slatter | Jul 2008 | A1 |
20080218344 | Lazar | Sep 2008 | A1 |
20080272885 | Atherton | Nov 2008 | A1 |
20090002130 | Kato | Jan 2009 | A1 |
20090009007 | Kato et al. | Jan 2009 | A1 |
20090065594 | Kato et al. | Mar 2009 | A1 |
Number | Date | Country |
---|---|---|
199859794 | Sep 1998 | AU |
102 58 670 | Jun 2004 | DE |
0 694 874 | Jan 1996 | EP |
0 977 145 | Feb 2000 | EP |
50-143451 | Nov 1975 | JP |
62-127140 | Aug 1987 | JP |
03-262313 | Nov 1991 | JP |
04-150011 | May 1992 | JP |
05-327331 | Dec 1993 | JP |
6-53733 | Feb 1994 | JP |
06-077729 | Mar 1994 | JP |
06-177635 | Jun 1994 | JP |
07-183836 | Jul 1995 | JP |
08-056113 | Feb 1996 | JP |
8-87580 | Apr 1996 | JP |
11-149537 | Jun 1996 | JP |
08-176421 | Jul 1996 | JP |
08-279027 | Oct 1996 | JP |
08-307126 | Nov 1996 | JP |
08-330372 | Dec 1996 | JP |
09-014150 | Jan 1997 | JP |
09-245381 | Sep 1997 | JP |
09-252217 | Sep 1997 | JP |
09-270623 | Oct 1997 | JP |
9-512367 | Dec 1997 | JP |
10-069533 | Mar 1998 | JP |
10-505466 | May 1998 | JP |
10-171954 | Jun 1998 | JP |
10-293828 | Nov 1998 | JP |
11-039441 | Feb 1999 | JP |
11-085937 | Mar 1999 | JP |
11-149538 | Jun 1999 | JP |
11-219420 | Aug 1999 | JP |
11-220319 | Aug 1999 | JP |
11-298368 | Oct 1999 | JP |
11-328352 | Nov 1999 | JP |
11-346114 | Dec 1999 | JP |
11-515094 | Dec 1999 | JP |
2000-21128 | Jan 2000 | JP |
2000-021639 | Jan 2000 | JP |
2000-022421 | Jan 2000 | JP |
2005-229474 | Jan 2000 | JP |
2000-059260 | Feb 2000 | JP |
2000-085283 | Mar 2000 | JP |
2000-090207 | Mar 2000 | JP |
2000-132643 | May 2000 | JP |
2000-137778 | May 2000 | JP |
2000-137785 | May 2000 | JP |
2000-148948 | May 2000 | JP |
2000-172812 | Jun 2000 | JP |
2000-174539 | Jun 2000 | JP |
2000-510271 | Aug 2000 | JP |
2000-269725 | Sep 2000 | JP |
2000-276569 | Oct 2000 | JP |
2000-286634 | Oct 2000 | JP |
2000-286760 | Oct 2000 | JP |
2000-311226 | Nov 2000 | JP |
2000-321984 | Nov 2000 | JP |
3075400 | Nov 2000 | JP |
2001-010264 | Jan 2001 | JP |
2001-028036 | Jan 2001 | JP |
2007-18067 | Jan 2001 | JP |
2001-043340 | Feb 2001 | JP |
2001-66990 | Mar 2001 | JP |
2001-101371 | Apr 2001 | JP |
2001-505682 | Apr 2001 | JP |
2001-168628 | Jun 2001 | JP |
2001-240046 | Sep 2001 | JP |
2001-256457 | Sep 2001 | JP |
2001-514777 | Sep 2001 | JP |
2001-319380 | Nov 2001 | JP |
2001-331976 | Nov 2001 | JP |
2001-332923 | Nov 2001 | JP |
2001-344574 | Dec 2001 | JP |
2001-351084 | Dec 2001 | JP |
2001-352176 | Dec 2001 | JP |
2002-7985 | Jan 2002 | JP |
2002-024776 | Jan 2002 | JP |
2002-042076 | Feb 2002 | JP |
2002-063557 | Feb 2002 | JP |
2002-505645 | Feb 2002 | JP |
2002-76750 | Mar 2002 | JP |
2002-150245 | May 2002 | JP |
2002-175508 | Jun 2002 | JP |
2002-183690 | Jun 2002 | JP |
2002-185358 | Jun 2002 | JP |
2002-204117 | Jul 2002 | JP |
2002-522849 | Jul 2002 | JP |
2002-230128 | Aug 2002 | JP |
2002-252117 | Sep 2002 | JP |
2002-298109 | Oct 2002 | JP |
2002-319008 | Oct 2002 | JP |
2002-362613 | Dec 2002 | JP |
2002-373029 | Dec 2002 | JP |
2002-373323 | Dec 2002 | JP |
2002-374139 | Dec 2002 | JP |
2003-006599 | Jan 2003 | JP |
2003-016412 | Jan 2003 | JP |
2003-030612 | Jan 2003 | JP |
2003-44789 | Feb 2003 | JP |
2003-046318 | Feb 2003 | JP |
2003-58840 | Feb 2003 | JP |
2003-067711 | Mar 2003 | JP |
2003-069335 | Mar 2003 | JP |
2003-076947 | Mar 2003 | JP |
2003-085501 | Mar 2003 | JP |
2003-085520 | Mar 2003 | JP |
2003-87008 | Mar 2003 | JP |
2003-87044 | Mar 2003 | JP |
2003-099720 | Apr 2003 | JP |
2003-099721 | Apr 2003 | JP |
2003-110344 | Apr 2003 | JP |
2003-132330 | May 2003 | JP |
2003-134007 | May 2003 | JP |
2003-155062 | May 2003 | JP |
2003-158414 | May 2003 | JP |
2003-187207 | Jul 2003 | JP |
2003-187211 | Jul 2003 | JP |
2003-188338 | Jul 2003 | JP |
2003-198230 | Jul 2003 | JP |
2003-209421 | Jul 2003 | JP |
2003-216919 | Jul 2003 | JP |
2003-218624 | Jul 2003 | JP |
2003-233780 | Aug 2003 | JP |
2003-242471 | Aug 2003 | JP |
2003-243918 | Aug 2003 | JP |
2003-249813 | Sep 2003 | JP |
2003-288560 | Oct 2003 | JP |
2003-309418 | Oct 2003 | JP |
2003-332820 | Nov 2003 | JP |
2004-082775 | Mar 2004 | JP |
2004-88218 | Mar 2004 | JP |
2004-096566 | Mar 2004 | JP |
2004-253858 | Sep 2004 | JP |
2004-287767 | Oct 2004 | JP |
2004-297249 | Oct 2004 | JP |
2004-297681 | Oct 2004 | JP |
2004-319848 | Nov 2004 | JP |
2004-326380 | Nov 2004 | JP |
2004-334268 | Nov 2004 | JP |
2004-336250 | Nov 2004 | JP |
2004-343000 | Dec 2004 | JP |
2004-362190 | Dec 2004 | JP |
2004-362341 | Dec 2004 | JP |
2004-362602 | Dec 2004 | JP |
2005-124061 | May 2005 | JP |
2005-129019 | May 2005 | JP |
2005-136528 | May 2005 | JP |
2005-165839 | Jun 2005 | JP |
2005-167327 | Jun 2005 | JP |
2005-190417 | Jul 2005 | JP |
2005-191705 | Jul 2005 | JP |
2005-210676 | Aug 2005 | JP |
2005-210680 | Aug 2005 | JP |
2005-217822 | Aug 2005 | JP |
2005-236339 | Sep 2005 | JP |
2005-244778 | Sep 2005 | JP |
2005-275870 | Oct 2005 | JP |
2005-284352 | Oct 2005 | JP |
2005-295135 | Oct 2005 | JP |
2005-311205 | Nov 2005 | JP |
2005-321305 | Nov 2005 | JP |
2005-335755 | Dec 2005 | JP |
2005-346820 | Dec 2005 | JP |
2005-352858 | Dec 2005 | JP |
2006-031766 | Feb 2006 | JP |
2006-39902 | Feb 2006 | JP |
2006-67479 | Mar 2006 | JP |
2006-72706 | Mar 2006 | JP |
2006-80367 | Mar 2006 | JP |
2006-92630 | Apr 2006 | JP |
2006-102953 | Apr 2006 | JP |
2006-148518 | Jun 2006 | JP |
2006-174151 | Jun 2006 | JP |
2006-195795 | Jul 2006 | JP |
2006-203187 | Aug 2006 | JP |
2006-203852 | Aug 2006 | JP |
2006-217000 | Aug 2006 | JP |
2006-232292 | Sep 2006 | JP |
2006-270212 | Oct 2006 | JP |
2006-302219 | Nov 2006 | JP |
2006-309401 | Nov 2006 | JP |
2007-043535 | Feb 2007 | JP |
2007-65822 | Mar 2007 | JP |
2007-122542 | May 2007 | JP |
2007-150868 | Jun 2007 | JP |
2007-164369 | Jun 2007 | JP |
2007-166379 | Jun 2007 | JP |
2007-180805 | Jul 2007 | JP |
11-175678 | Jan 2009 | JP |
9100176 | Mar 1992 | NL |
9100347 | Mar 1992 | NL |
9840846 | Sep 1998 | WO |
9967754 | Dec 1999 | WO |
0010122 | Feb 2000 | WO |
03079305 | Sep 2003 | WO |
2004036772 | Apr 2004 | WO |
2004070879 | Aug 2004 | WO |
2004072892 | Aug 2004 | WO |
2005073937 | Aug 2005 | WO |
2005115849 | Dec 2005 | WO |
2006045682 | May 2006 | WO |
2007083574 | Jul 2007 | WO |
2007105348 | Sep 2007 | WO |
2007125683 | Nov 2007 | WO |
2007138857 | Dec 2007 | WO |
Number | Date | Country | |
---|---|---|---|
20090166434 A1 | Jul 2009 | US |
Number | Date | Country | |
---|---|---|---|
61016912 | Dec 2007 | US |