Patent Application
20080028979
In one aspect, the present invention is a process for preventing fouling of compressor blades used to compress gasses. In the practice of the process of the present invention the dispersants can be applied to compressor blades in any way known to those of ordinary skill in the art of applying such materials to be useful for preventing fouling. In one embodiment, the additives are sprayed onto the compressor blades in the form of an aerosol. In another embodiment, the additives are injected into the gas stream being compressed, upstream of the compressor, as an aerosol that is then carried to the compressor blades by the gas being compressed. In still another embodiment, the additives are employed as part of a wash solution applied directly or indirectly to the compressor parts.
In another aspect, the invention is an antifoulant dispersant including isopropylhydroxyl amine (IPHA) and an N,N-dialkylamide of a fatty acid. This combination of components is hereinafter referred sometimes as dispersant or antifouling dispersant. The antifouling dispersant has the functionality of dispersing polymerized hydrocarbons and inhibiting the auto-polymerization of hydrocarbons thereby reducing polymers forming. The IPHA component of the antifouling dispersants functions to inhibit auto-polymerizations. The N,N-dialkylamide component acts to disperse hydrocarbons and polymers and has a general formula:
wherein:
Typically, R is an alkenyl group having one or more unsaturated bonds and having from 12 to 20 carbons. The N,N-dialkylamide may be a single compound but in some embodiments is a mixture of compounds. For example, in one embodiment the N,N-dialkylamide used to prepare the dispersant of the invention is DMAD which is available from Buckman Laboratories of Canada, Ltd., Vaudreuil, Quebec, Canada. The DMAD products are believed to consist primarily of a mixture of two N,N-dialkylamides having the formulae:
along with a minor amount of similar saturated compounds.
The two components of the dispersants of the present invention may be brought together in ratios of IPHA to N,N-dialkyl fatty acid amides in weight ratios ranging from 10:1 to 1:10. In some embodiments this ratio may be from 1:1 to 1:10. In other embodiments, this ratio may be from 1:1 to 1:2. All points intermediate in these ranges is also within the scope of the present invention.
While the dispersants may be used or applied neat, in one embodiment of the invention, the dispersant is prepared using a solvent. The solvents which are useful with the present invention include any solvent in which: a) the IPHA and N,N-dialkylamide of a fatty acid are soluble or can be stably suspended and b) the resulting solution or suspension is miscible with water at a concentration of at least 100 weight ppm of solution or suspension in water. Exemplary solvents include, but are not limited to benzyl alcohol, 2-phenoxyethanol, 2-(methoxymethoxy)ethanol, 2-butoxyethanol, 2-(isopentyloxy)ethanol, 2-(hexyloxy)ethanol, diethylene glycol, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol, triethylene glycol monomethyl ether, liquid polyethylene glycol, 1-methoxy-2-propanol, 1-ethoxy-2-propanol, dipropylene glycol, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, and a low molecular weight polypropylene glycol. Commercial solvents such as Butyl Carbitol and Butyl CELLOSOLVE™, which consists primarily of and Butyl CARBITOL™, which consists primarily of ethylene glycol monobutyl ether may be used and are available from DOW.
When a solvent is present, it may be present in a weight ratio of solvent to dispersant of from about 4:1 to about 1:1.
The components of the dispersants may be brought together in any way that is known to be useful to those of ordinary skill in preparing chemical compositions for industrial use. For example, the components may be admixed sequentially or all at once. The dispersants of the invention may be prepared using a batch process or they may be prepared using a continuous process.
The dispersants of the present invention have a useful synergy, the mixed components performing better together than the individual components singularly.
While the dispersants of the present invention are effective at preventing compressor fouling, there is a second property of these dispersants that is also desirable. The dispersants of the invention have the desirable property of not creating emulsions with resultant foaming in, for example, knockout pots. Knockout pots are used most applications where a compressor is employed and is often a point where dispersants may accumulate. While the dispersant of the invention may not act to break existing emulsions, they do not of themselves cause emulsions, unlike many other dispersants used for preventing compressor fouling.
While the dispersants of the present invention are useful in compressors used for an ethylene process production process, they are also useful in other similar applications and with other equipment. For example, the dispersants of the invention may be used with any process where process equipment will come into contact with ethylene cracked gassed. Another application of the invention is ethylene and acrylonitrile quench water systems. The dispersants of the application may be used with ethylene dilution steam generators and acrylonitrile purification systems. Many polymer processes have monomer recovery systems which are subject to fouling and are good target applications for the dispersants of the invention. Process water strippers and waste water strippers used with petrochemical processes such as styrene, butadiene, acrylonitrile, and ethylene processes are potential applications for the dispersants of the invention. Finally, ethylene acid gas scrubbers and butadiene solvent recovery systems are also end use applications of the dispersants of the present invention. The dispersants can be desirably used in any process which has process equipment subject to fouling with polymers. The dispersants are especially desirable in applications where foaming would problematic. In addition to processes that consume or produce at least one of styrene, butadiene, acrylonitrile, and ethylene are potential applications of the dispersants.
For the purposes of the present application, the term process equipment means compressors, fans, impellers, pumps, vacuum pumps, valves, heat exchangers; sensors, and the like, that are associated with the process and which may be subject to fouling. This term also includes supersets of these components where more than one of the components is part of a “system” such as, for example, a stripper where hydrocarbons are removed from an aqueous process stream, or a knockout pot.
The following examples are provided to illustrate the present invention. The examples are not intended to limit the scope of the present invention and they should not be so interpreted. Amounts are in weight parts or weight percentages unless otherwise indicated.
A dispersant of the present invention is prepared by admixing 7.5 parts IPHA, 10 parts DMAD (a fatty acid dimethylamide available from Buckman Laboratories of Canada), 40 parts Butyl CARBITOL, and 42.5 parts water.
The dispersant is tested according to ASTM-873 also known as the induced gums test. This test method determines the tendency of a hydrocarbon to form gums under accelerated aging conditions. In this method 100 ml of a hydrocarbon is placed into a bomb and air is introduced to attain a pressure of about 100 psi (689 kPa). The bomb is then kept at 100° C. for four hours. After the completion of the test, bomb is cooled rapidly and the pressure is released slowly. The liquid phase of the sample is evaporated 160° C. under a nitrogen purge for 30 minutes then at about 220° C. under a steam purge for 30 minutes. The value of potential gum is determined using weight differentials. The dispersant is tested at a concentration of 100 ppm. A control is prepared and tested wherein no dispersant is included in the hydrocarbon.
The results are shown below in Table 1
Example 1 is repeated substantially identically except that the dispersant is prepared by admixing 6 parts IPHA, 20 parts DMAD, 40 parts Butyl CARBITOL, and 34 part of water.
The dispersant prepared in Example 1 (Dispersant I) is tested according to the following procedure.
100 ml of a hydrocarbon is placed into a bomb and nitrogen is introduced to attain a pressure of about 100 psi (689 kPa). The bomb is then kept at 100° C. for four hours. After the completion of the test, bomb is cooled rapidly and the pressure is released slowly. The liquid phase of the sample is evaporated 160° C. under a nitrogen purge for 30 minutes then at about 220° C. under a steam purge for 30 minutes. The value of potential gum is determined using weight differentials. The dispersant is tested at a concentration of 12 ppm. A control is prepared and tested wherein no dispersant is included in the hydrocarbon.
The results are shown below in Table 2.
Example 3 is repeated substantially identically except that the dispersant is tested at 25 ppm.
The results are shown below in Table 2.
Example 3 is repeated substantially identically except that diethylhydroxyl amine (DEHA) is used (Dispersant III) instead of IPHA.
The results are shown below in Table 2.
Example 3 is repeated substantially identically except that Dispersant III is used at a concentration of 25 ppm.
The results are shown below in Table 2.
Example 3 is repeated substantially identically except that the dispersant is IPHA alone and it is used at a concentration of 1.875 ppm.
The results are shown below in Table 2.
Example 3 is repeated substantially identically except that the dispersant is DMAD alone and it is used at a concentration of 2.5 ppm.
The results are shown below in Table 2.
#Represents the level of IPHA found in Example 4.
##Represents the level of DMAD found in Example 4.
This application claims priority to the U.S. Provisional Patent Application having Ser. No. 60/835,298; that was filed on Aug. 3, 2006; the contents of which are fully incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| 60835298 | Aug 2006 | US |
