The present invention relates to No-NOx Burners and their applications. It relates particularly to Aphlogistic (flameless) non-surface No-NOx Burners and their applications.
Fossil fuels are burned throughout the industrialized world to generate heat for heating homes and commercial buildings, for power generation, for use in industrial processes, and for many other applications.
In recent years there has been increasing concern over the NOx produced by burning fossil fuels in conventional type burners. In fact governments in many regions of the world are introducing and enforcing ever more restrictive regulation with regards to NOx production.
To reduce the NOx produced from burning fossil fuels, a special type of burner can be used. Such a burner is referred to generally as a low NOx burner. These special burners are effective in reducing the NOx produced from burning fossil fuels, but they still emit significant amounts of NOx. Furthermore, they are very complex and expensive.
There is therefore a pressing need for an inexpensive No-NOx burner which produces essentially zero (relative to ambient NOx) NOx during the combustion of natural gas or other fuel. Such No-NOx burners can be used in domestic, commercial, and industrial applications.
The reason conventional burners produce NOx is that temperatures within the flame far exceed the temperature required for NOx to be formed from atmospheric oxygen and nitrogen. Further, the peak temperatures of the flame change from well in excess of 3,000 degrees F. to much lower temperatures when combustion is complete. This rapid quenching assures that the unstable NOx compounds within the flame are frozen into metastable compounds of NOx.
To prevent the formation of NOx in the first place, a special burner is required which will promote complete combustion at a much lower temperature so that the adiabatic flame temperature is reduced.
Several approaches to achieving low NOx combustion currently exist. One approach is to use a catalytic burner; however, as is well known in the art, catalytic burners are very expensive and are prone to failure from numerous causes such as catalyst poisoning or particulate blinding, etc.
Another approach is to use surface combustion type burners. Low NOx burners using surface combustion technology are currently commercially available from manufacturers such as Alzeta Corporation which markets them under the Duratherm trademark (see http://www.alzeta.com/products/duratherm.asp). However the surface combustion technology is expensive and problematic and prone to failure and is limited to low capacity per sq. ft.
Still another approach to attaining low NOx combustion is Flue Gas Recirculation (FGR) technology. FGR technology is very expensive and complicated.
All of these technologies can attain low NOx performance; however none of these technologies can achieve zero-NOx performance. Therefore, there is a pressing need for a simple and inexpensive burner that can achieve low NOx performance and even zero NOx performance.
This application discloses a No-NOx burner which is capable of achieving low and even zero NOx from the flameless non-surface combustion of fossil fuel such as natural gas, propane, butane, etc.
In a first embodiment, a flameless burner capable of zero-NOx and zero-CO comprises an Air-Fuel Ratio Attainment Means (AFRAM) and an Air-Fuel Mixing Means (AFMM) in fluid communication with the AFRAM to thoroughly mix the air and fuel to provide a readily combustible mixture, and one or more Radiant Combustion Zone (RCZ), and a Combustion Initiation Means (CIM) located in a combustion-initiation-contact position to initiate the combustion in the RCZ. The AFRAM is connected to a source of fuel and to a source of air, the AFRAM having means to achieve the required proportions of fuel and air there-through. The RCZ comprises one or more flow passages having a fluid flow inlet in fluid communication with the supply plenum of the AFMM and a hot gas discharge opening. During operation, the RCZ provides the intense radiant energy required to initiate and complete the combustion process and to promote and enhance flame-less non-surface combustion in the RCZ.
In a second embodiment of the flameless burner, the fluid communication between the supply plenum of the AFMM and the RCZ is provided by one or more high velocity fluid flow passages. Each passage has a cross-sectional flow area which is sufficient to create a gas velocity greater that the flame velocity to prevent pre-ignition in the supply plenum of the AFMM.
Another embodiment of the flameless burner further comprises a flow permeable structure (FPS) located in the fluid flow inlet of the RCZ to prevent pre-ignition in the supply plenum of the AFMM. The FPS may have through flow passages or may be a ceramic honeycomb with through flow passages or may be a porous ceramic structure with random through flow passages, or may be a wire mesh structure.
Another embodiment of the flameless burner further comprises an IR radiation reflector in the RCZ. The IR radiation reflector is located proximate to or at the flow discharge opening of the RCZ to intensify the IR radiation in the RCZ. The IR radiation reflector may be a porous FPS or a peripheral flow baffle.
In yet another embodiment of the flameless burner, the RCZ is configured as a flat, hollow disc which comprises a flat bottom which contains the fluid flow inlet for fluid communication with the supply plenum of the AFMM, a flat top, and a cylindrical wall. The hot gas discharge opening is a plurality of orifices on the cylindrical wall of the hollow disc. Further, the AFRAM may comprise an air eductor.
The following is a list of term used in this disclosure and their specific meanings as applied herein.
Flame: As used herein the word “flame” may also mean combustion with no radiation that is visible to the human eye.
Aphlogistic Burner: A fuel-burner in which the combustion of the fuel occurs without the presence of a visible flame.
Burner supply plenum: The burner supply plenum is the chamber which feeds air and fuel to the premix type burner element. A well designed burner supply plenum provides well mixed air and fuel and also provides very even flow and very even pressure distribution to the burner.
Flameless combustion cell: A flameless combustion cell is one of a plurality of small passages or cavities for promoting and enhancing flameless combustion in the burner.
Flame back: Flame back is the movement of the hot products of combustion from the combustion chamber into the supply plenum. This is undesirable as it will cause combustion in the supply plenum.
Glow back: Glow back is the process of heating the combustion guard from the hot end towards the cold end so that the fuel-air mixture in the burner supply plenum attains the auto ignition temperature. Glow back must be controlled so that the glow does not reach the burner supply plenum. If glow back occurs, the fuel and air will be ignited and will combust within the supply plenum; this situation is undesirable.
Radiation Combustion Zone (RCZ): The RCZ is a partially enclosed space which glows with intense infra-red radiation wherein flameless non-surface combustion takes place.
Non-Surface Combustion: Non-Surface Combustion is the phenomenon wherein the oxidation reactions involving the fuel and oxygen take place away from the containing surfaces and within the gas envelope (or boundary of the gaseous body) of the fuel and air mixture.
Infra-Red Radiation Reflector (IRRR): The IRRR is an element of a structure which reflects the infrared (IR) radiation in the RCZ so that the IR radiation is generally contained within the RCZ.
Combustion Trap: Any structure which contains one or more IR radiation reflecting surfaces while allowing combustion products to pass through.
Combustion Guard: Any structure that prevents glow back or flameback.
Porous Structure: Porous structure is a fluid permeable solid, which can be utilized as the combustion guard or the combustion trap. The porous structure can be a matrix with randomly oriented flow-passages or an extrusion with regularly oriented flow passages or a wire mesh.
Peripheral Flow Baffle (PFB): Is a flow disrupting element placed in the path of flow of a fluid. When a fluid encounters a PFB, its flow is re-directed around the periphery of the PFB.
Air-Fuel Ratio Attainment Means (AFRAM): The AFRAM is a device wherein the proportions of the fuel and the combustion air can be set so as to provide a combustible mixture. The AFRAM can have control means such as valves for active control of the proportion of the fuel and air. Alternately, the AFRAM could have fuel and air inlet ports which are pre-designed to allow the desired quantities of fuel and air into the AFRAM.
Air-Fuel Mixing Means (AFMM): The AFMM is a device wherein the fuel and air from the AFRAM are well mixed to sustain combustion in the RCZ. The AFMM could be a simple plenum or could be more elaborately designed with mixing vanes and other elements, both static or moving, to facilitate thorough mixing of the fuel and air.
Combustion Initiation Means (CIM): is any device such as a spark igniter, pilot flame, glow igniter or other device suitably positioned to initiate the combustion process in the RCZ.
Described herein is a burner which is capable of producing zero NOx and zero CO by passing a thoroughly mixed stream of air and fuel at an appropriate air/fuel ratio to maintain a temperature below the NOx forming threshold through a radiant combustion zone. During operation, the radiant combustion zone provides the intense radiant energy required to initiate and complete the non-surface combustion process. The temperature in the RCZ is controlled by the Air Fuel ratio which can be adjusted to attain low NOx and further zero NOx. The combustion temperature can be directly controlled with a suitable Air Fuel ratio. Increasing the excess air reduces the combustion temperature. This reduction in combustion temperature reduces the thermal NOx that is formed by the reaction of nitrogen with oxygen that normally takes place at the higher combustion temperatures of a conventional burner. Further the oxidation reaction does not produce carbon-monoxide and there is complete oxidation of the hydrocarbons to carbon-dioxide and water. The air and fuel provide the heat energy to keep the radiant combustion zone hot. The non-surface combustion according to this method is flameless and is capable of low NOx or no-NOx operation.
AFRAM 110 is configured as a Y-branched flow passage which has a larger flow passage 112 for the flow of the combustion air into AFRAM 110 and a smaller flow passage 114 for the flow of the fuel into AFRAM 110. Control means 112c is provided in flow passage 112 for the control of the quantity of combustion air that can enter AFRAM 110. Control means 112c could be a valve such as a butterfly valve, or a slide-gate valve, or any other manually or automatically activated fluid flow control device. A similar control means 114c is provided in flow passage 114 for the control of the quantity of fuel that can enter AFRAM 110. It is not necessary that active flow control elements be used as control means 112c and 114c. The control of fuel and air could be achieved by designing the dimensions and inlets of passages 112 and 114 so that pre-determined quantities of air and fuel are passively drawn into AFRAM 110. Thus AFRAM 110 is a means to attain the required quantities of fuel and air into burner 100. A volumetric Air to Fuel ratio (with natural gas as the fuel) in the range of 10 to 22 is sufficient to enable sustained combustion of the Fuel Air Mixture (FAM). The exact air-fuel ratio chosen for a particular application will be determined to attain the desired level of NOx or zero NOx and to meet other operating requirements as is well known in the art. For example, boiler operators may choose to operate with lower excess air to produce a low level of NOx within regulations while maximizing heating efficiency.
The two flow passages 112 and 114 of AFRAM 110 merge into a single outlet flow passage 116. During the operation of burner 100, fuel is drawn through inlet 114i in flow passage 114 and through control means 114c. The fuel mixes with air which is drawn through inlet 112i in flow passage 112 and through control means 112c. The fuel air mixture flows into outlet flow passage 116 from where it exits into AFMM 120 wherein it is mixed thoroughly.
AFMM 120 is configured as a flow passage with optional mixing vanes 120m. However, it will be obvious to persons having ordinary skill in the art that other mixing means such as a longer plenum or vanes or baffles (not shown) or multiple fuel ports may be provided within AFFM 120 to enhance the mixing of the fuel and air within AFMM 120. The fuel-air mixture exits AFMM 120 into the combustion guard.
The combustion guard is configured as a tapered outlet 116t on flow passage 116. The fuel-air mixture in tapered outlet 116t accelerates as it flows towards outlet 116e from which it emerges as a high velocity jet into RCZ 130. The high velocity of the fuel-air mixture as it exits outlet 116e acts as a combustion guard for preventing flame back of the flames into the AFMM 120.
RCZ 130 is configured as a flow passage 130f with an inlet 130i which may be larger than the outlet 116e of AFMM 120 and an open outlet 130e. Flow passage 130f is lined internally with insulation 130n. During operation of burner 100, the surface 130s of insulation 130n becomes hot and produces and reflects IR radiation to enable RCZ 130 to perform and function as a radiant non-surface combustion chamber. For efficient reflection of the IR radiation, it is recommended that the aspect ratio (length divided by hydraulic diameter) of flow passage 130f be between 1 to 10.
CIM 140 is located in a combustion-initiation-contact position to initiate the combustion of the fuel-air mixture as it exits AFMM 120. During the initial light-up phase of operation of aphlogistic burner 100, CIM 140 is activated to initiate the combustion of the fuel-air mixture as it exits though flow outlet 116e of tapered flow passage 116t. Initially, flames are produced after the outlet 116e of tapered flow passage 116t. However, after insulation 130n heats up, its internal surfaces 130s begin to produce IR radiation and also reflect the IR radiation produced by combustion and flameless combustion will occur within RCZ 130. At this stage of operation, the burner provides flameless non-surface combustion without any NOx and Carbon-monoxide being produced by the combustion process. It will obvious that burner 100 could be operated with less excess air to produce ultra-low NOX.
CIM 140 is located in a combustion-initiation-contact position at outlet 130e of RCZ 130 to initiate the combustion of the fuel-air mixture as it exits RCZ 130. During the initial light-up phase of operation of aphlogistic burner 100, CIM 140 is activated to initiate the combustion of the fuel-air mixture as it exits though flow outlet 130e of RCZ 130. Initially, flames are produced at the outlet 130e of RCZ 130. The high velocity of the fuel-air mixture out of outlet 116e acts as a combustion guard for preventing flame back of the combustion into the AFMM 120. After insulation 130n heats up, its internal surfaces 130s become hot and produce and reflect the IR radiation and flameless non-surface combustion starts to occur within RCZ 130. At this stage of operation, the burner provides flameless non-surface combustion with low or no NOx and Carbon-monoxide being produced by the non-surface combustion process.
While the above embodiments of aphlogistic burner 100 use a high velocity fuel-air mixture to prevent flameback into AFMM 120, other means of preventing flameback can be practiced.
In the embodiment of the porous structure 122 shown in
In another embodiment of the porous structure 122 shown in
Yet other structures are possible for use as porous structure 122. Such structures and modifications to above described structures will be obvious to persons having ordinary skills in the art.
In the above described embodiments, the internal surfaces of the cavities act as IR radiation reflectors reflecting IR radiation from the surfaces back into the fuel-air mixture. Thereby cavities in porous structure 122 essentially function as flameless non-surface combustion cells. In simple terms, flameless non-surface combustion cells are essentially cavities on the radiation producing face of burner 100. The cavities are designed to be large enough to cause the flame to retract back to the combustion section of porous structure 122. The containment of the flame within the cavities assures rapid heating of the miniature RCZs to attain the auto-ignition temperature of the gaseous fuel-air mixture which, as described above, permeates or flows into the cavities from AFMM 120 through the combustion guard. If the cavities are too small to prevent flameback from occurring, the heating of the miniature RCZs will depend on glow back only. In such a case, the heating of the miniature RCZs will be much slower or may be inadequate to cause auto-ignition of the fuel to occur within the cavities when using natural gas as a fuel. The applicant has experimentally determined that a cavity cross-sectional dimension of about 4-mm (0.15 inch) is very adequate to promote rapid flame-back within the cavity to cause auto-ignition of the fuel to occur within the cavity.
The wall thickness “t” (shown in
The material of construction of porous structure 122 should provide good strength at all temperatures, good tolerance to thermal shock, and have a high emissivity. The material of construction of porous structure 122 also should be unaffected chemically by the products of combustion of the fuel.
While the cavities have been shown as elongated passages in the above figures, they could have any suitable configuration.
It is contemplated that the above described embodiments of aphlogistic burner 100 of
While all of the above embodiments of aphlogistic burner 100 described above are shown with a straight flow through flow passage 130f which functions as the RCZ 130, it will be obvious to persons skilled in the art that flow passage 130 could have any suitable configuration, which could include bends and turns and other flow re-directions.
For example,
To increase the surface area within the RCZ, ribs, bumps and other perturbations can be molded into the ceramic insulation 410r and 420r. Yet other means of adding surface area within the RCZ could be considered also. Furthermore, the perturbations can be designed to provide a swirling movement to the flue gases as they exit the circumferential outlet of the burner. This arrangement may be particularly useful for domestic hot water heaters wherein the swirl will ensure even heating and heat transfer in the lower section below the hot water tank. The swirl will also accelerate as it enters the central pipe within the hot water heater tank. The high angular velocity will enhance heat transfer in this central pipe.
As another example,
While the above description contains many specific details, these details should not be construed as limiting the scope of the embodiment but merely as providing illustrations of several possible embodiments. For example, the combustion guard is shown as tapered nozzles in the above described figures. However, it will be quite obvious that the combustion guard could be designed with various other physical configurations which would provide a high velocity to the fuel-air mixture prior to its introduction into the RCZ. For example, the combustion guard could be designed as a straight-through high velocity tube. Alternatively, the combustion guard could be designed as a constricted tube, for example, with an orifice shaped constriction, or with a venturi shaped constriction for low pressure drop. Other designs of the combustion guard could include tubes with high velocity bends. These and other such variations to the design of the combustion guard will be obvious to persons having ordinary skill in the art. Therefore, the scope of the embodiments should be determined by the following claims and their legal equivalents rather than by the examples described herein.
This application claims priority from U.S. Provisional Patent Application No. 61/539,050 filed on Sep. 26, 2011 and from International Application No. PCT/US 12/56783 filed on Sep. 23, 2012.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US2012/056783 | 9/23/2012 | WO | 00 | 9/22/2013 |
Number | Date | Country | |
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61539050 | Sep 2011 | US |