Patent Application
20220362797
The present disclosure relates to apparatus and methods for coating substrates with washcoats. In particular, it relates to the coating of substrates used for purification of exhaust gases.
Large numbers of emissions control devices comprising coated monolithic substrates are manufactured each year. One of the principal uses of such devices is for the treatment of exhaust gases, such as the exhaust gases produced by a power plant or by an internal combustion engine, particularly a vehicular internal combustion engine. The monolithic substrate contains a plurality of channels that bring the exhaust gas into contact with a coating on the channel walls within the substrate. This coating may trap, oxidise and/or reduce constituents of the exhaust gas that are hazardous to human health or that are environmentally unfriendly. The monolithic substrate may also be a filter substrate, which can remove soot (i.e. particulate matter), such as the soot produced by internal combustion engines.
A substrate for purification of exhaust gases may typically comprise a monolithic substrate that is provided with passages for the through-flow of exhaust gases. The substrate may be provided with a coating, which may be a catalytic coating. The coating may be applied to the substrate as a washcoat that is passed through the passages of the substrate. Various methods for applying the coating to a substrate are known. One such method involves applying washcoat to a first face of the substrate (e.g. an upper face) and subjecting an opposite, second face (e.g. a lower face) of the substrate to at least a partial vacuum to achieve movement of the washcoat through the passages. After coating the substrate may be dried and calcined.
The substrate may be configured as a flow-through substrate wherein each passage is open at both the first and second faces of the substrate and the passage extends through the whole length of the substrate. Consequently, exhaust gases entering through a first face of the substrate into a passage pass through the substrate within the same passage until the exhaust gases exit a second face of the substrate. Alternatively, the substrate may be configured as a filter substrate, in which some passages are plugged at a first face of the substrate and other passages are plugged at a second face of the substrate. In such a configuration, exhaust gases entering through a first face of the substrate into a first passage flow along that first passage part-way along the substrate and then pass through a filtering wall of the substrate into a second passage. The exhaust gases then pass along said second passage and out of a second face of the substrate. Such an arrangement has become known in the art as a wall-flow filter.
The coated filter substrate or product may, for example, be a filter substrate comprising an oxidation catalyst (e.g. a catalysed soot filter [CSF]), a selective catalytic reduction (SCR) catalyst (e.g. the product may then be called a selective catalytic reduction filter [SCRF] catalyst), a NOx adsorber composition (e.g. the product may then be called a lean NOx trap filter [LNTF]), a three-way catalyst composition (e.g. the product may then be called a gasoline particulate filter [GPF]), an ammonia slip catalyst [ASC] or a combination of two or more thereof (e.g. a filter substrate comprising a selective catalytic reduction (SCR) catalyst and an ammonia slip catalyst [ASC]).
The substrate may be coated in a single dose wherein washcoat may be applied to the substrate in a single step with the substrate remaining in a single orientation. Alternatively, the substrate may be coated in two doses. For example, in a first dose the substrate is in a first orientation with a first face uppermost and a second face is lowermost. A coating is applied to the first face and coats a portion of the length of the substrate. The substrate is then inverted so that the second face is uppermost. A coating is then applied to the second face in order to coat the portion of the substrate that was uncoated by the first dose. Beneficially, a two-dose process may allow different coatings to be applied to each end of the substrate.
To provide best performance of the substrate it may be beneficial to ensure that the substrate is fully coated so that the surface area of the coated substrate is maximised. However, it is also beneficial to ensure that portions of the substrate are not coated by more than one layer of washcoat (for example, in a two-dose process) as this can lead to increased pressure loss within the substrate. It is therefore desirable that the process of applying the washcoat to substrates achieves reliable and controllable coating profiles of the substrates.
WO 99/47260 describes a general method for coating a monolithic support. A method of coating a flow-through honeycomb substrate is exemplified in WO 99/47260. This method is typically used to apply a washcoat having a relatively high viscosity.
One method that shows good results for uniformly applying washcoat onto the walls of a filter substrate is described in WO 2011/080525. WO 2011/080525 describes a method of coating a honeycomb monolith substrate comprising a plurality of channels with a liquid comprising a catalyst component, which method comprising the steps of: (i) holding a honeycomb monolith substrate substantially vertically; (ii) introducing a pre-determined volume of the liquid into the substrate via open ends of the channels at a lower end of the substrate; (iii) sealingly retaining the introduced liquid within the substrate; (iv) inverting the substrate containing the retained liquid; and (v) applying a vacuum to open ends of the channels of the substrate at the inverted, lower end of the substrate to draw the liquid along the channels of the substrate.
Another method for the application of a washcoat onto the walls of a filter substrate is described in WO2015/145122. The method utilises a “showerhead” comprising a plurality of apertures arranged to deposit the liquid evenly onto the upper end face of the filter substrate.
The substrate may have a uniform, or near uniform, structure throughout its cross-section and along its longitudinal length. Alternatively, the substrate may have a non-uniform structure. For example, the substrate may have a non-uniform structure throughout its cross-section, i.e. on a plane taken perpendicular to the longitudinal axis of the substrate. For example, the substrate may comprise a strengthened peripheral region wherein the wall thickness of the passages in the peripheral region is greater than in the central region of the substrate. The wall thickness may increase over a gradient towards an outer skin of the substrate. Whilst this type of substrate structure may offer a better substrate strength and durability the present applicant has found that it can cause problems with achieving reliable and controllable coating profiles as the strengthened peripheral region may have a greater water uptake due to the increased wall thickness.
In a first aspect the present disclosure provides a substrate coating apparatus comprising:
Advantageously, the substrate coating apparatus of the present disclosure comprising such a partition ring enables more reliable and controllable coating profiles of substrates that have strengthened peripheral regions. In particular, the partition ring may enable a greater volume of washcoat to be directed onto the peripheral region of the face of the substrate thereby enabling a greater volume of washcoat to be drawn through the peripheral region of the substrate compensating for the greater water uptake in that region due to the increased wall thickness.
The substrate coating apparatus may be configured in use to bring the partition ring into contact with the face of the substrate such that the partition ring is centrally located on the face of the substrate. The partition ring may be mobile in a direction along a longitudinal axis of the substrate such that a face-to-face contact between the partition ring and the face of the substrate may be maintained during movement of the substrate along the longitudinal axis.
The substrate coating apparatus may further comprise a guide mechanism for maintaining alignment of the partition ring. The guide mechanism may comprise a plurality of guide pins that extend transverse to a longitudinal axis of the partition ring and are configured to contact an exterior surface of the partition ring at spaced locations around a circumference of the partition ring. Alternatively, the guide mechanism may comprise a guide ring that extends transverse to a longitudinal axis of the partition ring and is configured to contact an exterior surface of the partition ring.
The partition ring may be sized relative to the face of the substrate such that the width of the peripheral region is 5 to 15 mm, preferably 8 to 12 mm, more preferably 10 mm.
The showerhead plate may overhang in use both the central region and at least a part of the peripheral region of the face of the substrate. The showerhead plate diameter may be equal to or greater than a diameter of the substrate.
The substrate coating apparatus may further comprise a collecting collar that is locatable around the face of the substrate to collect and channel washcoat towards the peripheral region. The collecting collar may be formed by a portion of a headset of the substrate coating apparatus.
The plurality of nozzles apertures of the showerhead plate may be arranged in concentric circular arrays. The showerhead plate may comprise no nozzle apertures in an annulus above the location of the partition ring.
The washcoat showerhead may further comprise a housing having an inlet for receiving the washcoat from the conduit and a baffle;
Advantageously, the washcoat showerhead comprising such a baffle may result in more even coating of the substrate and, in particular, may produce more reliable and controllable coating profiles. The use of a baffle may be particularly beneficial for products where there may be a desire to use washcoats which have a relatively low viscosity and minimal rheology properties. The present applicant has found that this can also cause problems with achieving reliable and controllable coating profiles of the substrates because the rheology of the washcoat means that it is difficult to apply the washcoat uniformly to the upper face of the substrate. With low viscosity washcoats it has been found to be difficult to ensure a uniform discharge of the washcoat from the showerhead plate. This can lead to problems of uncoated portions of the substrate after coating, where too little washcoat is applied to a region of the substrate, or alternatively ‘pull-through’, where excess substrate is drawn out of the lower face of the substrate, where too much washcoat is applied to a region of the substrate.
The baffle and the partition ring may be beneficially used in combination as they may, in combination, both ensure a more controllable discharge of the washcoat from the showerhead plate and a more controllable volume of washcoat applied to both the central region and peripheral region of the face of the substrate.
The baffle may comprise four arms extending from the impermeable central body, the four arms defining four flow apertures circumferentially arranged around the impermeable central body; and optionally the four arms may be equispaced circumferentially around the impermeable central body. The plurality of arms may extend radially from the impermeable central body; and optionally wherein a width of each of the plurality of arms may increase from a location proximate to the impermeable central body to a location distal the impermeable central body. Four arms may be provided.
The impermeable central body may be circular in shape in plan view. The impermeable central body may have a diameter greater than a diameter of the inlet to the housing; and optionally wherein a central longitudinal axis of the inlet and a central axis of the impermeable central body may be coincident. The impermeable central body may have a diameter of 20 to 55 mm; preferably 25 to 50 mm; more preferably selected to be 27, 35 or 50 mm.
The inlet of the housing may have an internal diameter of up to 25.4 mm (1 inch).
An upper face of the impermeable central body facing the inlet may comprise a protrusion; preferably wherein the protrusion is a conical, or part-conical surface.
Advantageously, the provision of a protrusion on the upper face has been found to minimise turbulence within the washcoat showerhead as the washcoat is directed to the periphery of the showerhead plate.
The baffle may be mounted to at least one of the housing and the showerhead plate; preferably wherein the baffle is mounted to only the housing. The baffle may be mounted to mounting points of the housing which surround, but do not impinge on, the inlet of the housing. The baffle may be mounted by fixatives extending between the plurality of arms and at least one of the housing and the showerhead plate. The fixatives may extend from a distal end of each of the plurality of arms. The fixatives may be located on a pitch circle diameter of 65 to 75 mm; preferably 70 mm, and may be centred on a central axis of the impermeable central body. Preferably the fixatives are located outside the diameter of the impermeable central body.
Advantageously, it has been found that positioning the fixatives outside the diameter of the impermeable central body may minimise interference of the fixatives with the incoming washcoat resulting in a more even distribution of washcoat onto the upper face of the substrate.
The showerhead cavity may have a depth of 12 to 40 mm; preferably 15 to 30 mm.
The impermeable central body may be spaced from the showerhead plate by a gap of 5 to 10 mm.
Advantageously, it has been found that locating the impermeable central body at a spacing of 5 to 10 mm from the showerhead plate may improve washcoat circulation within the showerhead cavity, and in particular enable enough washcoat to flow back to the centre of the upper face of the showerhead plate to achieve a more even distribution of washcoat onto the upper face of the substrate.
The baffle for forming a part of a washcoat showerhead described above comprises an impermeable central body and a plurality of arms extending from the impermeable central body, the plurality of arms defining a plurality of flow apertures circumferentially arranged around the impermeable central body.
The plurality of arms may extend radially from the impermeable central body; and/or a width of each of the plurality of arms may increase from a location proximate to the impermeable central body to a location distal the impermeable central body; and/or the impermeable central body may be circular in shape in plan view; and/or the impermeable central body may have a diameter of 20 to 55 mm; preferably 25 to 50 mm; more preferably selected to be 27, 35 or 50 mm; and/or an upper face of the impermeable central body may comprise a protrusion; preferably wherein the protrusion is a conical, or part-conical surface; and/or the plurality of arms may be provided with mounting points for connecting fixatives; and/or the mounting points may be located at a distal end of each of the plurality of arms; and/or the mounting points may be located on a pitch circle diameter of 65 to 75 mm; preferably 70 mm, and may be centred on a central axis of the impermeable central body.
In a second aspect, the present disclosure provides a substrate coating system comprising the substrate coating apparatus as described above and a substrate. Various substrates are known including flow-through substrates (e.g. monolithic flow-through substrates) and filter substrates (e.g. monolithic filter substrates), beads and ceramic foams. However, preferably the substrate is selected from a flow-through substrate or a filter substrate (for example, a wall-flow filter substrate).
A flow-through substrate generally comprises a plurality of channels, typically extending therethrough, wherein each channel is open at both ends (i.e. an open end at the inlet and an open end at the outlet). The channels are formed between a plurality of walls. The walls generally comprise a non-porous material. A flow-through monolithic substrate comprising an array of parallel channels extending therethrough is also referred to herein as a honeycomb monolithic substrate.
By contrast, a filter substrate comprises a plurality of channels, wherein each channel has an open end and a closed end (e.g. a blocked or plugged end). Each channel is typically separated from an adjacent or neighbouring channel by a wall. The wall comprises, or consists essentially of, a porous material. Such porous materials are well known in the art.
In general, a filter substrate comprises a plurality of inlet channels and a plurality of outlet channels. Each inlet channel has an open end at a first face of the substrate and a closed (e.g. blocked or plugged) end at an opposite second face of the substrate (i.e. the second end is the opposite end to the first end), and each outlet channel has a closed (e.g. blocked or plugged) end at the first face of the substrate and an open end at the opposite second face of the substrate.
In a filter substrate, each channel having an open end at a first face of the substrate and a closed end at a second (i.e. opposite) face of the substrate is typically adjacent to a channel having a closed end at the first face of the substrate and an open end at the second (i.e. opposite) face of the substrate. Fluid communication between the channels is via a wall (e.g. through the porous material) of the substrate.
The wall typically has a thickness of 0.002 to 0.1 inches (0.05 to 2.54 mm), such as 0.005 to 0.050 inches (0.12 to 1.27 mm), particularly 0.010 to 0.025 inches (0.25 to 0.64 mm).
Typically, the channels of a filter substrate have alternately closed (e.g. blocked or plugged) and open ends. Thus, each inlet channel may be adjacent to an outlet channel, and each outlet channel may be adjacent to an inlet channel. When viewed from either end of the filter substrate, the channels may have the appearance of a chessboard.
However, the filter substrate may have an inlet channel (i.e. a “first” inlet channel) that is adjacent to another inlet channel (i.e. a “second” inlet channel) and optionally to an outlet channel, such as the “first” outlet channel and/or the “second” outlet channel. The filter substrate may have an outlet channel (i.e. a “first” outlet channel) that is adjacent to another outlet channel (i.e. a “second “outlet” channel) and optionally to an inlet channel, such as the “first” inlet channel and/or the “second” inlet channel.
The filter substrate may have from 100 to 700 cells (or “channels”) per square inch (“cpsi”), particularly 250 to 400 cpsi.
The substrate may comprise a peripheral zone extending along the longitudinal length of the substrate, wherein the peripheral zone has an enhanced strength relative to a central zone of the substrate by virtue of an increased wall thickness in the peripheral zone compared to the central zone. The peripheral zone extends radially from the external edge of the substrate towards the centre of the substrate for a length of about 20 cells, preferably about 10 cells. Preferably the peripheral zone extends radially from the external edge of the substrate towards the centre of the substrate uniformly for a length of about 20 cells, more preferably about 10 cells.
In a third aspect, the present disclosure provides a method of coating a substrate with a washcoat using a substrate coating apparatus;
The method may further comprise aligning the partition ring in contact with the face of the substrate such that the partition ring is centrally located on the face of the substrate.
The method may further comprise moving the partition ring in a direction along a longitudinal axis of the substrate such that a face-to-face contact between the partition ring and the face of the substrate is maintained when moving the substrate along the longitudinal axis.
The method may further comprise not discharging washcoat from the showerhead plate within an annulus above the location of the partition ring.
The substrate may be selected from a flow-through substrate or a filter substrate, as described above.
A washcoat comprises a liquid and typically a catalyst component. The liquid may be a solution or a suspension. The suspension may be a colloidal suspension, such as a sol, or a non-colloidal suspension. When the liquid is a solution or a suspension, then it may be an aqueous solution or an aqueous suspension. Typically, the liquid is a suspension, particularly an aqueous suspension.
Typically, the liquid comprises a catalyst component. The expression “catalyst component” encompasses any component that may be included in a washcoat formulation that contributes to the activity of the resulting emissions control device, such as a platinum group metal (PGM), a support material (e.g. refractory oxide) or a zeolite. It is to be understood that the term “catalyst component” does not require that the component itself has catalytic activity in the strict sense of the meaning of the term “catalyst” (e.g. increasing the rate of reaction). For example, the catalyst component can refer to a material that is able to store or absorb NOx or a hydrocarbon. Liquids (e.g. washcoats) comprising a catalyst component are known to those skilled in the art. The catalyst component(s) included in the liquid will depend on the product that is to be manufactured.
The coated filter substrate or product obtained by a method of the invention or using an apparatus of the invention may, for example, be a filter substrate comprising an oxidation catalyst (e.g. a catalysed soot filter [CSF]), a selective catalytic reduction (SCR) catalyst (e.g. the product may then be called a selective catalytic reduction filter [SCRF] catalyst), a NOx adsorber composition (e.g. the product may then be called a lean NOx trap filter [LNTF]), a three-way catalyst composition (e.g. the product may then be called a gasoline particulate filter [GPF]), an ammonia slip catalyst [ASC] or a combination of two or more thereof (e.g. a filter substrate comprising a selective catalytic reduction (SCR) catalyst and an ammonia slip catalyst [ASC]).
In addition to the “catalyst component”, the liquid may further comprise a formulation aid. The term “formulation aid” refers to a component that is included in the liquid to modify its chemical or physical properties for coating onto a filter substrate. The formulation aid may, for example, aid the dispersion of a catalytic component in the liquid or change the viscosity of the liquid. The formulation aid may not be present in the final coated filter substrate product (e.g. it may decompose or degrade during calcination). The formulation aid may, for example, be an acid, a base, a thickener (e.g. organic compound thickener) or a binder.
The washcoat may have a viscosity of 1-3000 cP at 50 rpm Brookfield, preferably 100-3000 cP at 50 rpm Brookfield, more preferably less than 600 cP at 50 rpm Brookfield; in one embodiment the washcoat has a viscosity of 100 to 3000 cP at 50 rpm Brookfield, in another embodiment the washcoat has a viscosity of 1 to 350 cP at 50 rpm Brookfield, more preferably 1 to 100 cP at 50 rpm Brookfield. In the present application all viscosity measurements refer to measurements carried out on a Brookfield DV-II+ Pro (LV) viscometer using a SC4-18 spindle, available from Brookfield Engineering Laboratories, Inc., Middleboro, Mass., USA.
The washcoat may be supplied to the washcoat showerhead from a supply of washcoat using a piston which is movable within a bore, the bore having an internal diameter of 38 mm to 170 mm and the piston being moved at 45-150 mm/s.
The washcoat may be supplied to the washcoat showerhead at a rate of 9-540 cm3s−1, preferably at a rate of 9-270 cm3s−1.
Embodiments of the present disclosure will now be described, by way of example only, with reference to the accompanying drawings, in which:
The present disclosure will now be described further. In the following passages different aspects/embodiments of the disclosure are defined in more detail. Each aspect/embodiment so defined may be combined with any other aspect/embodiment or aspects/embodiments unless clearly indicated to the contrary. In particular, any feature indicated as being preferred or advantageous may be combined with any other feature or features indicated as being preferred or advantageous. It is intended that the features disclosed in relation to the products may be combined with those disclosed in relation to the method and vice versa.
The substrate coating apparatus 1 may comprise a depositor 2 having a housing 40 containing apparatus for activating a dispensing mechanism. As shown, the dispensing mechanism may comprise a piston 41 which is axially moveable within a bore 42 to displace a fluid out of an outlet 43 towards a conduit 35 located downstream of the depositor 2.
The coating apparatus 1 may further comprises a hopper 3 defining a hopper reservoir 30 having an outlet 31 connecting with the outlet 43 of the depositor 2 via a diaphragm valve 32. The hopper 3 may be filled with a washcoat that has been formulated and pre-mixed at another location. The washcoat may be pumped into the hopper reservoir 30 or may be fed under gravity into the hopper reservoir 30 through suitable conduits.
The outlet 43 of the depositor 2 fluidly connects with the conduit 35 which in turn may extend into fluid communication with a dosing valve 4. A washcoat showerhead 5 may be connected to a lower face of the dosing valve 4 with the washcoat showerhead 5 being positioned above the substrate 10.
The substrate 10 may be located and positioned between a headset 6 and a pallet insert 8. A vacuum apparatus including a vacuum cone 7 may be located beneath the substrate 10.
The substrate 10 may be a monolithic block having a substrate body 11 which may have a uniform cross-sectional shape along its longitudinal length. The substrate body 11 may have a circular or near circular shape in cross-section. The substrate body 11 may have a diameter, d.
The substrate body 11 may be positioned to extend between the headset 6 and the pallet insert 8 such that an upper face 12 of the substrate body 11 is upper most and a lower face 13 of the substrate body 11 is lowermost. The washcoat showerhead 5 may be located above the headset 6 and may be preferably aligned with the headset 6 and substrate 10 such that a central longitudinal axis, x, of the washcoat showerhead 5 is coincident with the central longitudinal axis of both the headset 6 and substrate 10 as shown in
The washcoat showerhead 5 may comprise a showerhead housing 21 to which may be coupled, on a lower side, a showerhead plate 23 by means of bolts 28. An adaptor plate 27 may be coupled to an upper side of the showerhead housing 21, also by means of bolts.
The showerhead housing 21 may comprise a centrally located aperture defining an inlet 22 to a showerhead cavity 24 that is defined between the showerhead housing 21 and the showerhead plate 23. The axis of the inlet 22 may be coincident with longitudinal axis x. The adaptor plate 27 may also comprise a centrally located aperture, which may be coincident with longitudinal axis x, and sized to receive a central portion 20 of the showerhead housing 21. The dosing valve 4 may be brought into, and held in, fluid communication with the inlet 22 of the showerhead housing 21.
The showerhead plate 23 may be provided with an array of nozzle apertures 25.
In use, diaphragm valve 32 is opened and washcoat is drawn into the bore 42 from the hopper reservoir 30 by movement of the piston to the right (as viewed in
The partition ring 60 is dimensioned to be smaller than the upper face 12 of the substrate 10. The internal diameter, p, is thus smaller than the diameter, d, of the substrate 10.
The partition ring 60 may have the same cross-sectional shape as the upper face 12 of the substrate 10. Alternatively, the shape of the partition ring 60 may differ from the shape of the upper face 12 of the substrate 10. Preferably, the partition ring 60 is annular. The partition ring 60 may be cylindrical in plan view. The partition ring 60 may be right cylindrical. The partition ring 60 may have a cross-sectional shape that is circular on a plane taken perpendicular to a longitudinal axis of the partition ring 60. As most clearly seen in
As shown in
The partition ring 60 may be sized relative to the upper face 12 of the substrate 10 such that the width, w, of the peripheral region is 5 to 15 mm, preferably 8 to 12 mm, more preferably 10 mm. The substrate 10 may have a typical diameter up to around 330 mm.
The showerhead cavity 24 of the washcoat showerhead 5 may have a depth of 12 to 40 mm, preferably 15 to 30 mm. The showerhead cavity 24 may have a diameter of 150 to 200 mm, preferably 160 to 170 mm. The showerhead plate 23 may extend across the full diameter of the showerhead cavity 24. Nozzle apertures 25 may be arrayed across the showerhead plate 23. The nozzle apertures 25 may be arrayed in a regular or irregular array. The nozzle apertures 25 may be arranged in a plurality of concentric circular arrays.
The showerhead plate 23 may overhang in use both the central region 14 and the peripheral region 15 of the substrate 10. The showerhead plate 23 may have a diameter that is equal to or greater than the diameter, d, of the filter substrate 10.
The substrate coating apparatus 1 may further comprise a collecting collar 75 which may form a part of the headset 6. The collecting collar 75 may comprise a sloped inner face 74. The collecting collar 75 may be positioned adjacent and/or around the upper face 12 of the substrate 10 with the sloped inner face 74 extending downwardly and inwardly towards the peripheral region 15 of the upper face 12. Preferably the collecting collar 75 forms a fluid tight seal against the substrate 10 to prevent, or substantially prevent, leakage of washcoat in use down an outer skin of the substrate 10.
The substrate coating apparatus 1 may further comprise a guide mechanism which may act to obtain and maintain correct alignment of the partition ring 60 with the upper face 12 of the substrate 10. In particular, it may be preferable to ensure that the longitudinal axis of the partition ring 60 is coincident with the longitudinal axis of the substrate 10 such that the partition ring 60 is centred on the upper face 12 of the substrate 10. Alternatively, or in addition, it may be beneficial to ensure that the lower rim 76 of the partition ring 60 rests in face-to-face contact, and maintains face-to-face contact, with the upper face 12 of the substrate 10 during use.
The guide mechanism may comprise a plurality of guide pins that extend transverse to the longitudinal axis of the partition ring 60 and are configured to contact an exterior surface of the sidewall 78 of the partition ring 60 at spaced locations around a circumference of the partition ring 60. The guide pins may be moveably mounted on the headset 6, for example extending from the collecting collar 75.
As shown in
The showerhead plate 23 may be provided with nozzle apertures 25. The nozzle apertures 25 may be arranged in arrays.
An alternative version of showerhead plate 23 is shown in
In use, the substrate 10 will be typically moveable into and out of engagement with the headset 6 by moving the substrate 10 longitudinally upwards and downwards. As noted above, the partition ring 60 may be provided within the headset 6 and mounted thereto by means of the guide ring 62. The substrate 10 may be first positioned on the pallet insert 8 and then lifted into engagement with the headset 6. During this motion, the upper face 12 of the substrate 10 may come into contact with the lower rim 76 of the partition ring 60. Further upward movement of the substrate 10 to bring it into sealing engagement with the headset 6 may at the same time result in upward movement of the partition ring 60 within the guide ring 62 thus ensuring that the lower rim 76 maintains a face-to-face contact with the upper face 12. Thus, with the substrate 10 in its final position the partition ring 60 may be located centrally on the upper face 12 and in face-to-face contact with the upper face 12.
Washcoat 9 may then be displaced onto the upper face 12 by discharging washcoat out of the nozzle apertures 25 of the showerhead plate 23. The washcoat may be supplied to the washcoat showerhead 5 from a supply of washcoat using the piston 41 of the depositor 2. The piston 41 is movable within the bore 42, and the bore 42 may have an internal diameter of 38 mm to 170 mm and the piston 41 may be moved at 45-150 mm/s. The washcoat is displaced along conduit 35 through dosing valve 4 and into the washcoat showerhead 5. The washcoat may be supplied to the washcoat showerhead 5 at a rate of 7-640 cm3s−1.
Discharge of the washcoat 9 from the nozzle apertures 25 will cause a proportion of the washcoat 9 to be discharged into the central region 14 of the upper face 12, i.e. discharged into the interior of the partition ring 60 while a remainder of the washcoat 9 will be discharged into the peripheral region 15 of the upper face 12—either directly or via running down the sloped inner face 74 of the collecting collar 75, where present. In this way, a greater proportion of the washcoat 9 may be discharged onto the peripheral region 15 of the upper face 12 than would be the case if the partition ring 60 were not present. After depositing the washcoat 9, the washcoat 9 is drawn through the passages of the substrate body 11 by the suction force applied by the vacuum cone 7.
A selective catalytic reduction (SCR) catalyst washcoat for a filter substrate was prepared having a solids content of 35% and a viscosity of 58 cP at a spindle rotation speed of 25 rpm; and a viscosity of 32 cP at a spindle rotation speed of 100 rpm; using a Brookfield DV-II+ Pro (LV) and a SC4-18 spindle.
The washcoat was coated onto an Enhanced Peripheral Strength aluminium titanate filter (available from Corning) with a diameter of 163.4 mm and height of 193 mm.
Coating was carried out using the apparatus shown in
As shown in
To ameliorate the effect seen in
The same washcoat as the Comparative Example was used and applied to the same substrate—an Enhanced Peripheral Strength aluminium titanate filter (available from Corning) with a diameter of 163.4 mm and height of 193 mm.
The partition ring 60 had an internal diameter of 143 mm, leading to a width, w, of the peripheral region of 10 mm.
The resultant coating profile is shown in
The baffle 50 comprises an impermeable central body 51 and a plurality of arms 52 which extend from the impermeable central body 51 to define a plurality of flow apertures 53 circumferentially arranged around the impermeable central body 51.
The baffle 50 may be mounted to the showerhead housing 21 by means of bolts 29 that may extend through bolt apertures 55 towards the distal end of each of the arms 52. The mounting points of baffle 50 may surround, but preferably do not impinge on, the inlet 22 of the showerhead housing 21. The bolts 29 may be 4 mm bolts. Each of the bolt apertures 55 may be surrounded by a standoff ring 56 which may serve to define the spacing between an upper face 57 of the baffle 50 and an upper interior face of the showerhead housing 21 as well as defining a spacing 26 between a lower face 58 of the baffle 50 and an upper interior face of the showerhead plate 23. Each standoff ring 56 may have a height of 4 to 6 mm, preferably 4.5 mm. The spacing 26 may be 5 to 10 mm, preferably approximately 8 mm.
As most clearly seen in
The length of the arms 52a-d may be relatively short compared to the diameter of the impermeable central body 51. The arms 52a-4 may have a uniform width and depth. In the illustrated example of
The baffle 50 may be formed of stainless steel, for example type 316.
The first version of baffle 50 may find particular beneficial use when coating a substrate 10 that has a circular cross-sectional shape and a diameter less than approximately 175 mm, more particularly less than 172.8 mm. The first version of baffle 50 may also find particular beneficial use when coating a substrate 10 that has a non-circular cross-sectional shape. Further, the first version of baffle 50 may find particular beneficial use when coating a substrate 10 for a selective catalytic reduction filter (SCRF), a light duty diesel catalytic soot filter (LDD CSF), or a gasoline particulate filter (GPF).
The length of the arms 52a-d is longer than in the first version. In the illustrated example of
The arms 52a-4 may have a uniform depth. The width of the arms 52a-d may taper. The width of each of the plurality of arms 52a-d may increase from a location proximate to the impermeable central body 51 to a location distal the impermeable central body 51.
The baffle 50 may be formed of stainless steel, for example type 316.
The second version of baffle 50 may find particular beneficial use when coating a substrate 10 that has a diameter greater than approximately 250 mm, more particularly greater than 266.7 mm. Further, the second version of baffle 50 may find particular beneficial use when coating a substrate 10 for a heavy-duty diesel filter (HDD).
The length of the arms 52a-d is longer than in the second version. In the illustrated example of
The arms 52a-4 may have a uniform depth. As with the second version, the width of the arms 52a-d may taper. The width of each of the plurality of arms 52a-d may increase from a location proximate to the impermeable central body 51 to a location distal the impermeable central body 51.
The baffle 50 may be formed of stainless steel, for example type 316.
The third version of baffle 50 may find particular beneficial use when coating a substrate 10 that has a diameter between 170 mm and 275 mm, more particularly between 172.8 mm and 266.7 mm. Further, the third version of baffle 50 may find particular beneficial use when coating a substrate 10 for a catalytic soot filter (CSF).
In use, as noted above, washcoat may be supplied to the washcoat showerhead 5 from a supply of washcoat using the piston 41 of the depositor 2. The piston 41 is movable within the bore 42, and the bore 42 may have an internal diameter of 38 mm to 170 mm and the piston 41 may be moved at 45-150 mm/s. The washcoat is displaced along conduit 35 through dosing valve 4 and into the washcoat showerhead 5. The washcoat may be supplied to the washcoat showerhead 5 at a rate of 7-640 cm3s−1.
Washcoat may enter the showerhead cavity 24 through the inlet 22. The washcoat comes into contact with the impermeable central body 51 of the baffle (including the conical or part-conical protrusion where present) before reaching the showerhead plate 23. The washcoat is therefore deflected laterally towards the periphery of the showerhead cavity 24 so that the washcoat does not immediately reach the nozzle apertures 25 located at or near the centre of the showerhead plate 23. The washcoat flows through the plurality of flow apertures 53a-d of the baffle and then circulates within the showerhead cavity 24 to pass through the nozzle apertures 25. Due to the configuration of the size and shape of the arms 52a-d and flow apertures 53a-d it may be enabled that sufficient washcoat recirculates back to a centre of the showerhead plate 23 such that a uniform or near uniform discharge of washcoat through the nozzle apertures 25 is achieved.
Discharge of the washcoat 9 from the nozzle apertures 25 will cause a proportion of the washcoat 9 to be discharged into the central region 14 of the upper face 12, i.e. discharged into the interior of the partition ring 60 while a remainder of the washcoat 9 will be discharged into the peripheral region 15 of the upper face 12—either directly or via running down the sloped inner face 74 of the collecting collar 75, where present. In this way, a greater proportion of the washcoat 9 may be discharged onto the peripheral region 15 of the upper face 12 than would be the case if the partition ring 60 were not present. After depositing the washcoat 9, the washcoat 9 is drawn through the passages of the substrate body 11 by the suction force applied by the vacuum cone 7.
In all versions of the substrate coating apparatus 1, the washcoat may comprise a liquid and typically a catalyst component. The liquid may be a solution or a suspension. The suspension may be a colloidal suspension, such as a sol, or a non-colloidal suspension.
When the liquid is a solution or a suspension, then it may be an aqueous solution or an aqueous suspension. Typically, the liquid is a suspension, particularly an aqueous suspension.
Typically, the liquid comprises a catalyst component. The expression “catalyst component” encompasses any component that may be included in a washcoat formulation that contributes to the activity of the resulting emissions control device, such as a platinum group metal (PGM), a support material (e.g. refractory oxide) or a zeolite. It is to be understood that the term “catalyst component” does not require that the component itself has catalytic activity in the strict sense of the meaning of the term “catalyst” (e.g. increasing the rate of reaction). For example, the catalyst component can refer to a material that is able to store or absorb NOx or a hydrocarbon. Liquids (e.g. washcoats) comprising a catalyst component are known to those skilled in the art. The catalyst component(s) included in the liquid will depend on the product that is to be manufactured.
The coated filter substrate or product obtained by a method of the invention or using an apparatus of the invention may, for example, be a filter substrate comprising an oxidation catalyst (e.g. a catalysed soot filter [CSF]), a selective catalytic reduction (SCR) catalyst (e.g. the product may then be called a selective catalytic reduction filter [SCRF] catalyst), a NOx adsorber composition (e.g. the product may then be called a lean NOx trap filter [LNTF]), a three-way catalyst composition (e.g. the product may then be called a gasoline particulate filter [GPF]), an ammonia slip catalyst [ASC] or a combination of two or more thereof (e.g. a filter substrate comprising a selective catalytic reduction (SCR) catalyst and an ammonia slip catalyst [ASC]).
In addition to the “catalyst component”, the liquid may further comprise a formulation aid. The term “formulation aid” refers to a component that is included in the liquid to modify its chemical or physical properties for coating onto a filter substrate. The formulation aid may, for example, aid the dispersion of a catalytic component in the liquid or change the viscosity of the liquid. The formulation aid may not be present in the final coated filter substrate product (e.g. it may decompose or degrade during calcination). The formulation aid may, for example, be an acid, a base, a thickener (e.g. organic compound thickener) or a binder.
The washcoat may have a viscosity of 1-3000 cP at 50 rpm Brookfield, preferably 100-3000 cP at 50 rpm Brookfield, more preferably less than 600 cP at 50 rpm Brookfield; in one embodiment the washcoat may have a viscosity of 100 to 3000 cP at 50 rpm Brookfield, in another embodiment the washcoat may have a viscosity of 1 to 350 cP at 50 rpm Brookfield, more preferably 1 to 100 cP at 50 rpm Brookfield. (All measurements obtained on a Brookfield DV-II+ Pro (LV) viscometer using a SC4-18 spindle.)
In order to maximise utilisation of the substrate volume and to prevent applying multiple coats to portions of the substrate 10 and to prevent pull-through of the washcoat, it is desirable to achieve a consistent and predictable coating profile. For example, a flat coating profile is desirable as illustrated schematically in
Finally,
A catalyst washcoat for a substrate was prepared having a solids content of 10% and a Newtonian viscosity of 5 cP over a spindle rotation speed 25-100 rpm using a Brookfield DV-II+ Pro (LV) and a SC4-18 spindle.
When the washcoat was coated onto a silicon carbide filter substrate using the coating apparatus 1 of
This was found to result in a v-shaped, uneven, coating profile shown in
To ameliorate the effect seen in
A silicon carbide filter substrate 10 of 143.8 mm diameter was then coated using this baffle plate 50 and the same catalyst washcoat as the above comparative example. A more even coating profile was obtained as shown by the x-ray image of
To ameliorate the effect seen in
A silicon carbide filter substrate 10 of 330.3 mm diameter was then coated using this baffle plate 50 and the same catalyst washcoat as the above comparative example. A more even coating profile was obtained as shown by the x-ray image of
To ameliorate the effect seen in
A silicon carbide filter substrate 10 of 172.8 mm diameter was then coated using this baffle plate 50 and the same catalyst washcoat as the above comparative example. A more even coating profile was obtained as shown by the x-ray image of
As noted above, the present applicant has found that desirable flat, or near flat, coating profiles may be achieved over a wide range of sizes of substrate including those which comprise a strengthened peripheral region wherein the wall thickness of the passages in the peripheral region is greater than in the central region of the substrate by using a partition ring 60 as described herein, optionally in combination with a washcoat showerhead 5 that comprises a baffle 50 as described herein.
For the avoidance of doubt, the entire contents of all documents acknowledged herein are incorporated herein by reference.
Further aspects and embodiments of the present disclosure are set out in the following clauses:
Clause 1. A substrate coating apparatus comprising:
Clause 2. A substrate coating apparatus as described in Clause 1, wherein the substrate coating apparatus is configured in use to bring the partition ring into contact with the face of the substrate such that the partition ring is centrally located on the face of the substrate.
Clause 3. A substrate coating apparatus as described in Clause 1 or Clause 2, wherein the partition ring is mobile in a direction along a longitudinal axis of the substrate such that a face-to-face contact between the partition ring and the face of the substrate may be maintained during movement of the substrate along the longitudinal axis.
Clause 4. A substrate coating apparatus as described in any preceding Clause, further comprising a guide mechanism for maintaining alignment of the partition ring.
Clause 5. A substrate coating apparatus as described in Clause 4, wherein the guide mechanism comprises a plurality of guide pins that extend transverse to a longitudinal axis of the partition ring and are configured to contact an exterior surface of the partition ring at spaced locations around a circumference of the partition ring.
Clause 6. A substrate coating apparatus as described in Clause 4, wherein the guide mechanism comprises a guide ring that extends transverse to a longitudinal axis of the partition ring and is configured to contact an exterior surface of the partition ring.
Clause 7. A substrate coating apparatus as described in any preceding Clause, wherein the partition ring is sized relative to the face of the substrate such that the width of the peripheral region is 5 to 15 mm, preferably 8 to 12 mm, more preferably 10 mm.
Clause 8. A substrate coating apparatus as described in any preceding Clause, wherein the showerhead plate overhangs in use both the central region and at least a part of the peripheral region of the face of the substrate.
Clause 9. A substrate coating apparatus as described in any preceding Clause, wherein the showerhead plate diameter is equal to or greater than a diameter of the substrate.
Clause 10. A substrate coating apparatus as described in any preceding Clause, further comprising a collecting collar that is locatable around the face of the substrate to collect and channel washcoat towards the peripheral region.
Clause 11. A substrate coating apparatus as described in any preceding Clause, wherein the plurality of nozzles apertures of the showerhead plate are arranged in concentric circular arrays.
Clause 12. A substrate coating apparatus as described in any preceding Clause, wherein the showerhead plate comprises no nozzle apertures in an annulus above the location of the partition ring.
Clause 13. A substrate coating apparatus as described in any preceding Clause, wherein the washcoat showerhead further comprises a housing having an inlet for receiving the washcoat from the conduit and a baffle;
Clause 14. A substrate coating apparatus as described in Clause 13, wherein the baffle comprises four arms extending from the impermeable central body, the four arms defining four flow apertures circumferentially arranged around the impermeable central body; and optionally the four arms are equispaced circumferentially around the impermeable central body.
Clause 15. A substrate coating apparatus as described in Clause 13 or Clause 14, wherein the impermeable central body has a diameter greater than a diameter of the inlet to the housing; and optionally wherein a central longitudinal axis of the inlet and a central axis of the impermeable central body are coincident.
Clause 16. A substrate coating apparatus as described in any of Clauses 13 to 15, wherein the impermeable central body has a diameter of 20 to 55 mm; preferably 25 to 50 mm; more preferably selected to be 27, 35 or 50 mm.
Clause 17. A substrate coating apparatus as described in any of Clauses 13 to 16, wherein the inlet of the housing has an internal diameter of up to 25.4 mm (1 inch).
Clause 18. A substrate coating apparatus as described in any of Clauses 13 to 17, wherein an upper face of the impermeable central body facing the inlet comprises a protrusion; preferably wherein the protrusion is a conical, or part-conical surface.
Clause 19. A substrate coating apparatus as described in any of Clauses 13 to 18, wherein the showerhead cavity has a depth of 12 to 40 mm; preferably 15 to 30 mm.
Clause 20. A substrate coating apparatus as described in any of Clauses 13 to 19, wherein the impermeable central body is spaced from the showerhead plate by a gap of 5 to 10 mm.
Clause 21. A substrate coating system comprising the substrate coating apparatus of any preceding claim and a substrate; preferably a substrate selected from a wall flow filter substrate and a flow-through substrate.
Clause 22. A substrate coating system as described in Clause 21, wherein the substrate comprises a peripheral zone extending along the longitudinal length of the substrate, wherein the peripheral zone has an enhanced strength relative to a central zone of the substrate by virtue of an increased wall thickness in the peripheral zone compared to the central zone.
Clause 23. A method of coating a substrate with a washcoat using a substrate coating apparatus;
Clause 24. The method of Clause 23, further comprising aligning the partition ring in contact with the face of the substrate such that the partition ring is centrally located on the face of the substrate.
Clause 25. The method of Clause 23 or Clause 24, comprising moving the partition ring in a direction along a longitudinal axis of the substrate such that a face-to-face contact between the partition ring and the face of the substrate is maintained when moving the substrate along the longitudinal axis.
Clause 26. The method of any of Clauses 23 to 25, further comprising not discharging washcoat from the showerhead plate within an annulus above the location of the partition ring.
Clause 27. The method of any of Clauses 23 to 26, wherein the substrate is selected from a wall flow filter substrate and a flow-through substrate
Clause 28. The method of any of Clauses 23 to 27, wherein the washcoat comprises an oxidation catalyst, a selective catalytic reduction (SCR) catalyst, a NOx adsorber composition, a three-way catalyst composition, an ammonia slip catalyst [ASC] or a combination of two or more thereof.
Clause 29. The method of any of Clauses 23 to 28, wherein the washcoat has a viscosity of 1-3000 cP at 50 rpm Brookfield, preferably 100-3000 cP at 50 rpm Brookfield, more preferably less than 600 cP at 50 rpm Brookfield; in one embodiment the washcoat has a viscosity of 100 to 3000 cP at 50 rpm Brookfield, in another embodiment the washcoat has a viscosity of 1 to 350 cP at 50 rpm Brookfield, more preferably 1 to 100 cP at 50 rpm Brookfield.
Clause 30. The method of any of Clauses 23 to 29, wherein the washcoat is supplied to the washcoat showerhead from a supply of washcoat using a piston which is movable within a bore, the bore having an internal diameter of 38 mm to 170 mm and the piston being moved at 45-150 mm/s.
Clause 31. The method of any of Clauses 23 to 30, wherein the washcoat is supplied to the washcoat showerhead at a rate of 9-540 cm3s−1, preferably at a rate of 9-270 cm3s−1.
| Number | Date | Country | Kind |
|---|---|---|---|
| 1819455.5 | Nov 2018 | GB | national |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 16695817 | Nov 2019 | US |
| Child | 17813948 | US |
