Patent Grant
10400385
The present invention relates to drying machines, and in particular, to clothes dryers such as those used in homes, laundromats and other facilities
Fabric care appliances designed to clean articles of clothing include washers and dryers. A typical dryer includes a drum, which receives pre-washed articles of clothing therein. Activation of the dryer causes the drum to rotate while heated air is passed into and out of the drum. The clothes, and more particularly the water content therein, is heated sufficiently to change the water from a liquid to a gas (vaporization), whereupon the water vapor is ejected with the exiting airflow, and the clothes are “dried.”
Gas dryers, which use electricity to power various electrically operated components (such as a motor, timer, buzzer alarms, lights, and other “on-board” electrical devices), are labeled as gas dryers because they use gas valves and other gas-related components to allow for heat to be generated for use in the drying process. In contrast, electric dryers do not incorporate any gas components but instead have air-to-air electrical heat resistance element coils allowing for the generation of heat for the drying process.
Despite their popularity, conventional clothes dryers have a number of drawbacks. First among these is that such dryers use significant (many might say excessive) amounts of energy. The average full-sized 240 volt, clothes dryer consumes power on the order of about 4000 to 7000 Watts, such that the clothes dryer typically consumes energy at a higher rate than any other appliance in a home except for the household refrigerator. This is particularly undesirable in the case of conventional gas-powered and electric clothes dryers, given the costs and environmental impact associated with consuming such energy resources.
Further, not only do conventional clothes dryers demand heavy amounts of power, but also such conventional clothes dryers fail to make efficient use of this power. In order to heat articles of clothing for drying purposes, these appliances rely on either a gas-based or electric-based heat source that the U.S. government itself (e.g., the Department of Energy) apparently does not consider to be particularly energy efficient. Indeed, clothes dryers are so inefficient that no clothes dryer on the market is currently listed as qualifying for the U.S. Government's Energy Star rating (see www.energystar.gov).
The poor efficiency of conventional clothes dryers is largely due to the fact that clothes dryers simply do not use large amounts of the energy that is input to the dryers. Most conventional clothes dryers operate by passing dry, heated air around and through the clothes being dried, such that the clothes are heated up and moisture within the clothes evaporates. The heated, moist air is then exhausted out of the dryer and out into the environment (typically, outside the facility housing the dryer). Given this design, clothes dryers continuously expel, as waste, large amounts of heat energy during operation and, indeed, much of the heated air that is directed toward clothes during operation of the dryer simply passes by the clothes and is vented out of the machine without ever contributing to the drying of the clothes.
Clothes dryers also waste heat energy in other ways. For example, much of the heat generated by clothes dryers simply escapes from the dryers due to some combination of radiation, conduction, and convection before the heat ever reaches the clothes. Further, even to the extent that the heat generated by a clothes dryer reaches and heats the clothes, the energy still is often wasted. In particular, once the clothes drying cycle has been completed, the heat energy stored in the clothes further is wasted, as the clothes sit idle within the clothes dryer. Thus, clothes dryers not only require undesirably large amounts of energy in order to operate, but also waste significant portions of that energy.
What is needed is a clothes drying machine that uses less energy and/or is more energy efficient than conventional clothes drying machines, while still providing similar drying capabilities (e.g. while still drying significant amounts of clothes in comparable amounts of time).
An apparatus for drying articles of clothing (“clothes”) includes a drum, a fan/blower for pulling air through the drum, and means for intentionally lowering the gas pressure in the drum to lower the boiling point of the liquid water contained in the clothes in the drum, which thus requires less heat energy to change the state of the water from liquid to gas. The apparatus for drying clothes further includes a heat capacitor in a closed-loop fluid path that stores heat energy from an electric heating element located in the path, and the apparatus is operated in a first phase wherein the a fan/blower pulls air through the drum and the heating element is on to transfer heat to the heat capacitor and dry clothes in the drum and in a second phase wherein the heating element is off, but the fan/blower continues to operate to pull air through the drum and draw heat energy stored in the heat capacitor to continue to dry the clothes.
A drying machine for drying clothing includes a housing; a drying compartment assembly including a drum having an internal drum pressure and being sized and configured to receive moisture-laden clothing, the drum mounted for rotation with the housing; rotation means for rotating the drum; a guide apparatus for guiding air in a path including through the drum; an air moving apparatus located after the drum and operable to only pull air through the guide apparatus and through the drum; a heating apparatus located before the drum and being for heating air moving through the guide apparatus, the heating apparatus including a heating element having on and off conditions and including a heat capacitor containing a liquid for storing heat and for releasing stored heat to air moving through the guide apparatus when the heating element is in its off condition and the drum is rotating; power means for providing power as needed to components of the drying machine including at least the drying compartment assembly, rotation means; guide apparatus, air moving apparatus, heating apparatus, and control apparatus; a control apparatus for controlling at least one of the drying compartment assembly, the rotation means; guide apparatus, the air moving apparatus, the heating apparatus, and the power means; and, restrictor means for restricting the air flow rate through the guide apparatus entering the drum whereby the drum pressure is more than trivially lower than ambient air pressure.
It is an object of the present invention to provide an improved device for drying clothing.
Further objects and advantages of the present invention will become apparent from the following description of the preferred embodiment.
For the purposes of promoting an understanding of the principles of the invention, reference will now be made to the embodiment illustrated in the drawings and specific language will be used to describe the same. It will nevertheless be understood that no limitation of the scope of the invention is thereby intended, and alterations and modifications in the illustrated device, and further applications of the principles of the invention as illustrated therein are herein contemplated as would normally occur to one skilled in the art to which the invention relates.
Referring to
Housing 11 has a generally box-like shape and is made of any appropriate material for housing the components described herein including, but not limited to, sheet metal, aluminum, or plastic. Housing 11 is intended to also include a variety of other elements connected and/or contained therein or thereto, including, but not limited to, brackets, screws, damping elements, wires, and leveling feet, such as are necessary and/or desired to facilitate the smooth, quiet and reliable operation of a clothes dryer. Such elements are well known in the art and are otherwise omitted from further discussion and illustration. Other applications for the present invention may suggest or dictate other materials be used for the housing and/or any of the other components of dryer 10. For example, and without limitation, a dryer 10 intended for use in a heavy commercial application may include a housing and/or other components thereof that are made of a high strength steel alloy, or a dryer for use in a marine application may have the housing and other components made of a corrosion-resistant materials, such as stainless steel.
Clothes dryer 10 also includes a control panel 21 located at the top of housing 11, control panel 21 holding the majority of elements of control apparatus 17, as is common with many conventional dryers. Control apparatus 17 includes such controls (as at 22 and 23) as are necessary and desired to enable a user to select the various options for operation of dryer 10 as are provided thereby and include, but are not limited to, one or more dials, pushbuttons, touch screens and/or microphones (24), the microphone(s) being operationally coupled with a computer (30) having voice recognition software to enable dryer 10 to be voice controlled. Control apparatus 17 is also contemplated to include one or more indicator elements (such as at 25) as are necessary and/or desired to provide the user with information about the state of operation of dryer 10. Such indicator elements include, but are not limited to, one or more lights, LED readouts, audio speakers, and/or visual displays, the latter including, for example, an LCD display screen 29. Such elements could, for example, enable controlling the dryer cycle, function as a pump indicator to indicate when the fluid circulating pump is operational or exhibits a defect Other indicator elements could include a point-of-use indicator light to indicate that the heater is working properly and a timer selection dial 22. These and other controls are shown in the embodiment of
Housing 11 also defines an opening 27 in the front side panel 26 to provide access to the clothes drying drum 31 (
Drive apparatus 32 includes any appropriate and known apparatus for rotating drum 31 on or within its support apparatus, such as a motor 43 with an output shaft 44 that drives a belt 45 that surrounds shaft 42 and drum 31, substantially as shown. Other means as are known in the art for supporting and rotating drum 31 are contemplated by the present invention, including but not limited to, those that would support drum 31 to rotate about a horizontal axis, a vertical axis or one in between. Alternative embodiments contemplate drum 31 being shaped other than cylindrical. For example, and without limitation, drum 31 could be conically or frustoconically shaped and/or could be mounted for rotation on a spindle coaxially connected therewith. Alternative embodiments contemplate drum 31 being moved other than rotationally such as, and without limitation, either randomly or in a path that is somewhat or entirely predefined, such path being linear, curved or a combination thereof. For example and without limitation, drum 31 may be oriented with its opening facing upwardly and drum 31 may be agitated by any appropriate motivating device in a reciprocal path along a vertical axis. Alternative embodiments contemplate drum 31 being stationery, and having a clothing agitating element contained therein that agitates and mixes the clothes during the drying cycle. Such configuration may be particularly useful in a combination washer/dryer where such agitator is the same for the wash, rinse and drying cycles. Generally, the shape of drum 31 and method and path of agitation of drum 31 and/or clothes contained therein may be varied in almost limitless ways so long as there is an air inlet and outlet to drum 31 in communication with guide apparatus 13.
Thus far, the components of clothes dryer 10, as shown in
Outlet guide box 58 is contemplated to be the same in both known dryer 50 and dryer 10 of the present embodiment. Outlet guide box 58 defines air inlet and air outlet openings 67 and 68 at its opposing upper and lower ends 69 and 70, respectively. Air outlet opening 68 is open to atmosphere, and air inlet opening 67 is connected in communication with air outlet opening 35 of drum 31. An air moving apparatus 14 is located in outlet guide box 58, between air inlet and outlet openings 67 and 68. Air moving apparatus 14 is a fan 71 powered by a fan motor 72. Alternative embodiments contemplate a fan placed at any appropriate position on the air inlet side of air guiding apparatus 13, that is, blowing air into the heat exchanger. Such “blowing” fan system would be in place of fan 71 or could be in addition to fan 71. In electric or gas dryers or in the current dryer 10, the size, shape and position of outlet guide box 58 may vary, but its function remains to guide air from an outlet opening 35 of drum 31 and out to atmosphere. Alternative embodiments discussed herein contemplate the guide apparatus largely recirculating the air to withdraw the moisture in a condenser instead of venting it to atmosphere.
In accordance with clothes dryer 10 of the present invention, the air moving within guide apparatus 13 and through drum 31 of drying compartment assembly 12 is heated by heating apparatus 15, which uses a heated fluid to facilitate heating the air before it is directed into drum 31. Referring to
Heating element 84 extends into heater housing 83 to be in communication with the liquid flowing in closed-loop path 80. In response to control apparatus 17, which receives temperature readings from sensor 88 and/or from one or more other sensors located within the path of air in guide apparatus 13, heating element 84 is appropriately activated to heat the liquid flowing in closed-loop path 80 to a particular point-of-use temperature Tp, as measured at sensor 88. The point-of-use temperature Tp is contemplated to be between about 125° F. and 250° F. In one embodiment, the point-of-use temperature Tp is preferred to be between about 135° F. and 180° F. In one embodiment, hydronic heater 84 (also an immersion heater) is contemplated to operate at 110 volts and to draw between about 1500 watts and 2000 watts and to maintain a standard rate of clothes drying.
In one embodiment, using a hydronic clothes dryer in accordance with dryer 10 of
Referring to
Pump 78 is any liquid pump suitable and capable of moving water or other heat exchange liquid through the hydronic heater fluid path 80. The fluid moving in hydronic heater fluid path 80 is a liquid and, in one embodiment, is water. Alternative embodiments are contemplated wherein the liquid used for circulation within hydronic heater fluid path 80 is other than water, such as Paratherm NF. Paratherm NF, which is a non-fouling, non-toxic, food friendly liquid commercially available from Paratherm Corporation, 4 Portland Road, West Conshohocken Pa. 19428 USA. Paratherm NF has a specific heat of approximately 0.475 Btu/lb-° F. (compared with a value of about 1.0 Btu/lb-° F. for water), and therefore heats to the point-of-use temperature Tp faster than water. Though water may be referred to herein as a primary liquid for use in hydronic heater 76, it is to be understood that all alternative liquids that provide similar and, preferably, superior operating characteristics are contemplated, particularly Paratherm NF, and use of the term water herein is intended to mean water and all such alternatives. Alternative embodiments are contemplated wherein other fluids may be used within heating apparatus 15. For example and without limitation, both water and Paratherm NF are contemplated to stay in a liquid state during the intended operative drying cycle. Alternative embodiments contemplate a fluid that changes between its liquid and gas states during operation. Alternative embodiments are contemplated wherein the liquid used in the hydronic heater fluid path 80 comprises part water and part some non-water liquid, as is used in many automobile radiator systems.
Heating apparatus 15 is also provided with an expansion tank 100 comprising a gas-pressurized closed cylinder 101 with at least one port 102 that is connected via a tube 103 in fluid communication with the tubing 90 of heat exchanger 77. In the event of a momentary blockage or pressure spike in hydronic heater fluid path 80, excess liquid in path 80 can escape into cylinder 101. The gas pressure of cylinder 101 is set at the desired liquid relief pressure of the hydronic heater fluid path 80. Once the pressure spike is relieved, the overflow liquid in cylinder 101 moves through the same tube 103 back into the hydronic heater fluid path 80. Alternative embodiments are contemplated wherein expansion tank 100 is provided with a mechanism, such as with a hydraulic or pneumatic piston, to variably adjust the relief pressure value in expansion tank 100. Alternative embodiments are contemplated wherein port 102 and tube 103 include a one way pressure relief valve (not shown) to function as the inlet to cylinder 101 only when a pressure relief threshold has been exceeded, and cylinder 101 is also provided with an outlet port and tube 105 that has its own one way pressure relief valve (not shown) to permit flow only from cylinder 101 back into hydronic heater fluid path 80 after the pressure spike has been relieved.
Air moving apparatus 14 comprises motorized fan 71, and guide apparatus 13 for guiding air in a path (such path also being designated at 13 in
Filter element 20 (
Power means 16 is appropriately connected (at 16) with drying compartment assembly 12, guide apparatus 13, air moving apparatus 14, heating apparatus 15, control means 17, condensing apparatus 19, and any other power needing component, to power such elements, as necessary. While typical electric dryers such as dryer 50 require a 220 volt power source, dryer 10 is contemplated to run with comparable or better performance with a 110 power source and to draw considerably less wattage. Generally, power means 16 comprises the necessary wiring and plug to connect with a readily available power source such as and without limitation, a wall outlet providing 110 volts on a 15 amp circuit. Alternative embodiments contemplate power means 16 including some degree of solar power. For example and without limitation, and as discussed in greater detail herein, one or more standard hot water solar panels may be fluidly connected to the hydronic heater fluid path 80 to contribute a substantial amount of heat to the liquid flowing within hydronic heater fluid path 80. By further example, one or more solar photovoltaic panels may be connected with power means 16 to provide some or all of the electric power needed to run clothes dryer 10. Such hot water solar panels and solar photovoltaic panels are well known, and any variation and combination thereof as would facilitate operation of dryer 10 in any desired climate or condition is hereby contemplated to be part of the present invention. Alternative embodiments are contemplated to include any other available energy source capable of providing electricity to the remaining components of dryer 10. Alternative embodiments are also contemplated to provide operation of dryer 10 on less than 110 volts on a 15 amp circuit.
Alternative embodiments are contemplated wherein guide apparatus 13 includes one or more flow diverter valves 117 to direct or moderate air flow therein to achieve a desired flow rate and/or heat transfer rate. For example and without limitation, a valve 117 may be positioned anywhere in the airflow path 13 to the increase airflow rate therein in the event a temperature sensor indicates the temperature inside drum 31 has exceeded a certain value. Such valve 117 is contemplated to be variably openable with a motor element connected therewith to open and close such valve and to be connected with and powered by the power means 16 and to be connected with and controlled by the control apparatus 17. Such valves are well known and readily available.
Referring to
Referring to
Referring to
The hose, tubing and/or other liquid channeling component(s) that form the coil or liquid carrying structure of heat exchanger 77, 135 or other device can be formed from a variety of different materials and have a variety of different characteristics. For example, in some embodiments, the coil could be formed from ⅜″ diameter tubing, while in other embodiments the tubing could be anywhere from 5/16″ to ¾″ in diameter (or a variety of other sizes). Also, in some embodiments, the heating apparatus 15 could include more than one such coil or similar device. For example, the heating device could include two of the coils 135 shown in
Depending upon the particular arrangement of the coil or other component(s) within heating apparatus 15, as well as depending upon the level to which the heated water or other liquid is heated, the air passing through the heating device can be heated to varying degrees. Preferably, the surface area available in heating apparatus 15 that interacts with the air is relatively large, to increase the rate of transfer of heat from heating apparatus 15 to the air as it passes along the surface thereof. For this reason, it would typically be preferable to increase the number of loops of tube of coil 135 in the embodiment shown in
It should also be noted that, in some embodiments (none of which is shown), various air-directing components could be employed in (e.g., as part of) heating apparatus 15 and/or around the heating apparatus that would govern or at least influence the manner of air flow in relation to and through the heating device. For example, in some such embodiments, one or more air vanes or fins could be positioned alongside or even in a manner protruding through the coil 135 or finned tubing array 89, causing air to proceed through the coil 135 or array 89 in a particular manner in relation thereto. Further for example, in some of these embodiments, the air would be directed so as to proceed in a manner that was substantially perpendicular to the plane determined by the coil (e.g., out of the page when viewing
The Hydronic heater 76, otherwise known as a point-of-use water heater, can be any of a variety of generally small water heaters sized and configured to fit within housing 11 of the clothes dryer 10, such as certain point-of-use water heaters manufactured by the InSinkErator Company of Racine, Wis., for example, the Model W154 4-gallon point-of-use water heater or the Model W152 2½-gallon point-of-use water heater. In the embodiment of
Although the clothes dryer 10 shown in
Clothes dryer 10 of
The various operable components and supporting elements of retrofit kit 140—the heating apparatus 15, retrofit guide apparatus 142, expansion tank 100 (if desired), and appropriate electrical connection elements 143—are connected by appropriate means, such as and without limitation, clips, straps, pins, Velcro®, screws, brackets bolts and/or adhesive, to the inside of rear housing member 141 in a manner so that rear housing member 141 can be applied to the rear of the dryer 50 to be modified, and the aforementioned components of retrofit kit 140 will nest properly in a desired place relative to the remaining elements of the original dryer 50. Referring to
In use, to modify known dryer 50 with retrofit kit 140, with the rear panel 109 of known dryer 50 exposed, the inlet guide box 57 or similar structure and the electrical heating apparatus 64 is removed. In electric dryers, the heating apparatus 64 will typically be located inside of inlet guide box 57, and both guide box 57 and its heating apparatus 64 may be removed as a unit. In gas dryers, the heating apparatus 64 is a gas burner and may be located in or connected to the corresponding inlet guide box 57, and the two may be removed as a unit. Or, the gas heating apparatus 64 may be located in a pocket 153 under drum 31, and it may have to be removed separately. Once inlet guide box 57 and heating apparatus 64 (and their corresponding connections, of course) are removed, the various appropriate electrical connection elements 143 of retrofit kit 140 are connected to the appropriate connection sites in known dryer 50. These will primarily be power source connections. Where known dryer 50 includes a computer controlled control apparatus 17 with basic or sophisticated readouts, user input elements and the capability to receive temperature and other sensor data, such connections are also made. Retrofit kit 140 is contemplated to contain any or all of such sensors as are contained in dryer 10 of
Referring to
The solar cells of solar panel array 176 only add energy to solar heating system 172 when adequate sunlight is provided to those solar cells. Consequently, the solar heating system 172 may also include an additional heat storage assembly 197 that includes an auxiliary storage tank 198, a heat exchanger 199 positioned in storage tank 175 and an auxiliary heater pump 199. Connected as shown in
Also shown in
Preferably, condensing unit 121 is set at a dew point that is equal to the maximum condensing temperature of the super-heated, moisture-laden air passing through condensing unit 121 such that the heated air exiting condensing unit 121 is not substantially lower in temperature than the moist, heated air entering condensing unit 121. That is, preferably, the heat that is absorbed by condensing unit 121 from the moist, heated air is that which is associated with the heating of the moisture within the clothes and changing it from a liquid to a gaseous state.
It is preferred to operate condensing unit 121 so that only a phase change is accomplished (condensation of the moisture in the airflow) without substantially lowering the temperature of the corresponding airflow. Based upon the principles of latent heat contained in a fluid medium or water vapor (e.g., the heated, moisture-laden air emanating from the drum 31), a phase change can occur whereby the water vapor in the airflow is changed to water and its sensible heat (the stored energy released in the phase change from water vapor to water) is deposited directly on the coils of the condenser where the condensation occurred and no heat is lost from the airflow to the coils. By plotting the dew point of a known fluid medium's characteristics via a psychrometric chart, one is able to coordinate resultant measurements, and to thereby optimize moisture removal without substantially reducing the temperature of the corresponding airflow.
In at least some embodiments, the information from the psychrometric chart can be automatically obtained from (e.g., calculated by) the computer 30 of dryer 120 or controller (or other computer-type device, such as a programmable logic device or a microprocessor) that is implemented within the dryer (e.g., implemented within the condensing unit). The data of the psychrometric chart in some embodiments can be stored in a lookup table or other memory device in such computer or similar device, and the condensing unit's coil temperature can be automatically adjusted to accommodate variable changes in temperature as dictated by the changing temperature of the dryer's fluid medium (e.g., air) while circulating through the damp clothing.
For example, when the dryer initially begins its heating or drying cycle, the clothing within the dryer's drum 31 will be substantially cool and saturated with moisture. A dual temperature/moisture sensor that is in communication with computer 30 will monitor the cool air emanating from drum 31. Information is sent by such sensor to the computer 30, which then processes the information and, in turn, automatically adjusts the condensing surface temperature of the coil of condensing unit 121.
As the drying cycle continues, the clothing articles will pick up additional heat, but contain less water vapor. This information is collected by the dual temperature/humidity sensor sensing the hotter, dryer air emanating from the tumbler, and is in turn provided to the computer 30 for processing, which, in turn, will cause a change in temperature of the condensing chamber. The fluid medium (e.g., air emanating from drum 31) continues to be monitored until the temperature/humidity sensor senses that the clothes have reached a moisture level consistent with dried clothing conditions. In some embodiments, the temperature/humidity sensors are manufactured to sense certain levels of “bone-dry mass” contained within the drum 31, and this information is incorporated into the sensor.
In alternate embodiments, a variety of other condensing devices, heat exchangers, or similar devices can be used to perform the function of removing moisture from the moist, heated air emanating from drum 31.
Referring to
The clothes dryers 10 and 120 and retrofit dryers with kit 140 shown and discussed herein are advantageous in comparison with conventional dryers such as dryer 50 in a number of ways. To begin with, the use of Paratherm NF, heated water, or other liquid to heat the air within the dryer has in tests been shown to be a reasonably efficient manner of heating air. By keeping the water to a reasonably high temperature (e.g., 190 degrees F.) but not too high of a temperature, the amount of heat that is lost from the dryer in the form of radiation/convection/conduction, and not used to heat the clothes, is kept to a lesser level than in many conventional dryers.
With respect to embodiments employing point-of-use water heaters, in particular, the dryer efficiency is enhanced simply because the dryer generates about only as much heat as is necessary to keep the air within the dryer heated to a particular level. In particular, in the case of externally mounted tanks, the hot water is pumped from an external, insulated tank, (2.5 cups from a 2.5 gallon reservoir in the latter case). It is thus possible to continue to provide prolonged heat, even when the point-of-use water heater has reached its pre-set temperature setting and terminated its energy output. This has been demonstrated in tests to result in an effective energy efficiency concept, since the tests have shown that for every 30 minutes of energy required by the point-of-use heater, 30 minutes of heat are generated without the consumption of additional energy by the point-of-use heater.
Additionally, the use of Paratherm NF, heated water (or other fluid) to heat the air within the dryer has in tests been shown to be advantageous in terms of providing improved drying of clothes in terms of the characteristics of the dried clothes. In particular, in contrast to the clothes dried using conventional gas or electric-powered clothes dryers, which often overheat/overdry the clothes, clothes dried through the use of heated water (or other fluid) tends not to be overheated and tends to have a fresh feel and smell without scorching/burning, even without the use of any fabric softeners. Further, the use of heated water (or other fluid) to heat the air tends to further reduce the risk of igniting lint within the dryer and thus tends to enhance dryer safety.
Further, in embodiments such as that of
Referring to
Also, although it is believed that the manner of operation of the present inventive dryers involving the heating of air through the use of heated fluid enhances the safety of such dryers in comparison with many conventional dryers, this is not intended to constitute a representation that the present inventive dryers will be absolutely safe or that any other dryers will produce unsafe operation. Safety depends on a wide variety of factors outside of the scope of the present invention including, for example, a variety of different design, installation, and maintenance factors. While the present inventive dryers are intended to be highly reliable, all physical systems are susceptible to failure.
An alternative embodiment is contemplated wherein the air pressure within the dryer's drum 31 is substantially reduced to a fixed or modulated pressure during normal dryer operation to correspond to a lower boiling point temperature. A fixed pressure, as used in this application, means the gas pressure in the drum is relatively constant during normal operation. Such pressure could be set at a particular level and left there during the drying cycle, though be changeable if desired, or the components of the dryer 10 could be constructed to create a lower gas pressure inside the drum 31, but where the dryer 10 is not equipped to further modulate such pressure during normal operation. Alternative embodiments are contemplated wherein the gas pressure is dynamic, that is, is capable of modulation and is modulated during the drying cycle to vary the moisture removal rate during its normal operation. The primary purpose of modulating the pressure within the dryer's drum is to change the boiling point of the moisture or water molecules normally contained within prewashed articles of clothing.
The “boiling point” of a liquid is substantially affected by the environmental pressure surrounding the liquid. The environmental pressure is the ambient air pressure surrounding and, typically within, the dryer 10. As an example, pure “water” is known to reach a boiling point of 100° C. (212° F.) under 760 mmHg (29.92 inches) of mercury, but when water is subjected to an “atmospheric pressure” of say, 20.0 inches of mercury, its boiling point temperature is reduced to about 90° C. (194° F.), and at 10.0 inches of mercury, the boiling point temperature is about 71° C. (159° F.). A lower boiling point temperature significantly reduces the amount of thermal energy required for vaporizing the moisture in the clothing placed in a conventional gas or electric clothes dryer. The advantage of using less thermal energy to dry prewashed articles of clothing becomes apparent in many ways and is a desired objective of the present invention.
Conventional clothes dryers vaporize water in moisture-laden clothing by heating the air as it travels through its heater box or air channel, and the heat is then transferred into the confined volume of the drying compartment (the “drum”), which contains the moisture-laden clothing. The air is generally heated by a gas burner assembly (a gas dryer) or an electric resistance heat element (an electric dryer). The performance of these heat generating devices are highly susceptible to changes in both the volume of air and its rate of flow (cfm). Too much airflow at higher velocities will create undesirable cooling effects, thus reducing the efficiencies of both the gas and electric dryers. Electric resistance heat elements, subjected to excessive airflow (cfm) will over-cool, causing longer drying times and increased energy consumption. Conversely, if insufficient airflow is passed over the electric resistance coils or through the gas dryer's air channel, the dryer may overheat reducing element life and potentially causing dryer fires. Another consequence of this form of overheating in such air or gas dryers is that when the heating element overheats, the dryer's thermal control unit will terminate (shut off) the heating element (electric coil or gas flame) until the components cool down and the thermostat signals the heating system element to restart. This on/off cycle (or “rapid cycling”) when often repeated during the drying cycle results in a highly energy inefficient drying cycle. Rapid cycling in an electric dryer will also significantly shorten the life of the heating element. Conventional dryers are thus typically designed to avoid such reduced airflow overheating.
Nevertheless, after the air has been heated and as the wet clothing loses its moisture to the heated air through evaporation, both gas and electric dryers will operate more efficiently when increased ventilation or exhausting of the (vaporized) moisture-laden air occurs. Increased air velocities are produced by the dryer's blower/fan assembly. To minimize the negative effects that higher airflow velocities have on conventional gas or electric resistance heat elements, significant airflow must often be redirected around and away from these conventional heating elements, while yet maintaining the optimum maximum flow rate and the dryer's ability to feed air to the blower/fan air intake port for proper exhaust and ventilation of the humidified air stream from inside the drying compartment.
To overcome the internal high/low airflow conflict found in current conventional clothes dryers, dryer cabinets and other components are designed to bypass or redirect a significant portion of the dryer's airflow. This is generally accomplished by intentionally creating air leaks or gaps in the cabinet and other non-sealed areas so that “make-up” air is available to the blower/fan air intake port for its high velocity exhaust, while ensuring the heating apparatus(es) receive the proper or optimum air flow. The high flow rate of the blower/fan constitutes an off-setting effect for conventional gas and electric dryers, but offers a useful, novel, and superior way to heat and vaporize the water molecules in pre-washed articles of clothing by the development of a cabinet and other components that together decrease the relative pressure inside the dryer's drum via the inherent pressure drop that occurs when airflow passes through a fin-tube heat exchanger of particular density.
The alternative embodiment contemplated here comprises a modification to the dryer 10 of
In one embodiment of dryer 10, for example, the fin density of heat exchanger 77 is increased to a desired level to create a sufficient level of turbulence and/or air flow resistance in the airflow passing therethrough, which restricts the flow rate therethrough and through opening 34 and, for a particular fan 71, the gas pressure inside drum 31 (the “drum pressure”) during normal operation of dryer 10 is decreased. This is a fixed pressure embodiment. The fin density (or other fin configuration parameter) may be selected to provide whatever drum pressure is desired. In one embodiment, the fin density is selected to cause at least about a five percent reduction in air flow rate through the heat exchanger, and a ten percent reduction in another embodiment.
It is noted that the housing or cabinet 11 is uniquely constructed and sealed so that air volume entering drum 31 is solely dependent and controlled by airflow entering drum 31 through air inlet 34, at which is adjacently mounted heat exchanger 77. Heat exchanger 77 is constructed so that the air that passes through opening 34 must pass exclusively through heat exchanger 77, or so that the certain portion of air flow that does pass through heat exchanger 77 is restricted enough to produce the desired drum pressure. The fan/blower assembly 71 is a high velocity device that exerts sufficient suction to pull air into the drum and, with the airflow restriction (of heat exchanger 291 or other appropriate restrictor device), reduce the drum pressure enough to significantly reduce the boiling point therein and reduce the energy needed to dry the clothes. In one embodiment, the fan/blower assembly 71 exerts sufficient suction to exhaust up to 2400 cubic feet per minute (cfm), and this high airflow capacity contributes to producing a lower drum pressure in the drum 31 containing moisture-laden articles of clothing.
It is noted that air pressures may vary somewhat throughout a particular guide apparatus 13 and that the drum pressure may inherently be slightly lower than environmental or ambient pressure in one conventional dryer to another. That is, trivial restrictions to airflow may inherently be produced by the general structure of a dryer 10, such as from inlet screens, inlet covers, air flow guide channels and the like. While these elements may produce a trivial or minute decrease in drum pressure, the present invention contemplates a non-trivial and intentional drop in drum pressure to cause a significant lowering of the boiling point of the moisture in the clothes and, consequently, a significant decrease in the energy required to dry the load of clothes in the drum. While any intentional static and/or dynamic decrease in drum pressure is desired, the decrease in drum pressure is desired to be at least about 3 inches of mercury and preferably greater than 5 inches of mercury. Preferred embodiments decrease the drum pressure as much as possible to commensurately lower the boiling point of the moisture, but not so much as to reduce the ability of the air to receive and carry away the water vapor to the extent of cancelling or defeating the gains made by reducing the boiling point.
In other embodiments, instead of or in addition to the restriction to the flow rate through heat exchanger 77, one or more other elements of guide apparatus 13 or fan 71 may be modified to produce a desired drum pressure. For example, fan 71 may be made to exert a greater suction which, in view of the given structure of guide apparatus 13, may be strong enough to exert a lower drum pressure than with a fan 71 of lower power. Alternatively or in addition, the valve, such as at valve 134 in
Referring to
It is noted that, in the alternative embodiments, lowering the drum pressure may produce optimal results with the hydronic heating apparatus 15, but apparatus for static or dynamic lowering of the drum pressure can produce substantially improved drying results in conventional dryers that use standard electric or gas heating apparatuses instead of a hydronic heating apparatus.
Referring to
Referring to
As with the drum 31 of clothes dryer 10, an annular nylon, felt or similar appropriate material wear ring 277 is interposed between the rear, annular edge 288 of drum 273 and substantially adjacent, annular surface 279 of the back plate 262 to minimize the escape of hot air from within drum 273 and to minimize friction between drum 273 and back plate 262. A similar wear ring 280 is interposed between the front, annular edge 281 of drum 273 and the mating, annular surface 282 of front plate 261.
Air moving apparatus 244 includes a motor 285 and a fan/blower 283 that is rotated by the output shaft 284 of motor 285. Motor 285 also rotates drum 273 via a pulley 286 at the opposing end of the motor's output shaft 284, the pulley 286 being engaged with a belt 287 that encircles and engages with drum 273, as shown. The fan/blower 283 pulls air through housing inlet 351, heat exchanger 291, drum 273, and airflow exit passageway 258, which leads into fan/blower 283. From there, fan/blower 283 blows the same airflow stream out of housing 241 through an exhaust tube 288. As is known in dryer configurations such as the dryer 240 shown in
Referring to
Heater housing 295 is generally tubular, its generally cylindrical, hollow inside defining a distal heating chamber 303 (with an axis 302) that is sized to receive the outer end 304 of heating element 296. At its outer end, heater housing 295 defines the outlet port 297 and another three ports 305-307, all of which permit communication with heating chamber 303 and the fluid contained therein. At port 305 is secured an operating thermostat 310; at port 306 is secured a high limit thermostat 311; and at port 312 is secured a pressure relief valve 312. In one embodiment, operating thermostat 310 has a trip temperature of 330° F.; high limit thermostat 311 has a trip temperature of 350° F.; and pressure relief valve 312 is set at 1.5 atm.
Pump 292 includes a pump housing 315 and a pump motor assembly 316. Pump housing 315 defines a proximal heating chamber 317 (with an axis 318) that extends all the way through housing 315. Pump 292 also defines a pump chamber 321 that has an axis 322 that is generally orthogonal to and offset from axis 318 of proximal heating chamber 317. Pump chamber 321 is sized and positioned so that it intersects (at 323) and is in communication with proximal heating chamber 317, as shown in
Pump motor assembly 316 includes a motor 326, an impeller 327 mounted to the output shaft of motor 326, and a bracket 325 for mounting motor 326 to the side of pump housing 315 so that impeller 327 is rotatably received within pump chamber 321 and a portion of impeller 327 extends through intersect opening 323 and into proximal heating chamber 317. Heater housing 295 is rigidly connected with pump housing 315 so that distal and proximal heating chambers 303 and 317 are coaxially aligned to form a common, main heating chamber 328. In assembly, the looped rod 329 of heating element 296 extends into main heating chamber 328 and is secured therein by the threaded and sealed engagement between the head 331 of heating element 296 and the threaded heating element port 332 of proximal heating chamber 317.
When pump motor 326 is on, impeller 327 rotates, which pulls fluid entering through inlet port 299 into pump chamber 321, through intersection 323 and moves it into main heating chamber 328 to be heated by heating element 296 and forced out outlet port 297. Operating thermostat 310 and high limit thermostat 311 are electrically connected in series between the power source (not shown) and the electrical connector 334 of heating element 296 (e.g. wire 335 from the power source (not shown), wire 336 between high limit thermostat 311 and operating thermostat 310, and wire 337 to heating element connector 334. When power is supplied to heating element 296, the fluid within main heating chamber 328 is heated. When pump 292 is on, rotating impeller 327 moves fluid through the closed-loop fluid flow path, that is, out of heater housing 295, through heat exchanger 291, and back into pump housing 315.
Operating thermostat 310 is designed with a trip temperature of 330° F. and a reset temperature of 310° F., and high limit thermostat 311 is designed with a trip temperature of 350° F. and has a reset button 340 that must be manually depressed after a trip to reset the high limit thermostat 311. Thus, if fluid in the main heating chamber 328 reaches the trip temperature (330° F.), the operating thermostat sensor head (not shown, but exposed to the fluid within main heating chamber 328 through its port 305) will detect the high temperature, and the operating thermostat 310 will open, which will cut current flow to heating element 296 (as also seen in the schematic shown in
If operating thermostat 310 fails to cut the power to heating element 296, the fluid temperature may continue to rise, but if it then reaches the high limit temperature (350°), the high limit thermostat 311 will trip (open), which will, likewise, open and cut current flow to heating element 296. In another embodiment, high limit thermostat 311 is connected with control apparatus 247 to shut down the dryer 240 altogether if it is tripped, as shown in the schematic of
As described herein, the fluid in closed-loop fluid path 80 is a liquid, the pressure of which at initial charging and in operation is desired to be at 1.0 psig. Pressure relief valve 312 is screwed into the threaded port 307 at the distal end of heater housing 295 and is set at 5.0 psig.
Referring to
It is noted that the preferred embodiment contemplates the foregoing configuration and its controlled drum inlet path 361 restrict all air entering inlet 351 pass through heat exchanger 291 and into drum 273, and that no other airflow be permitted to enter housing 241 (and thus “leak” into drum 273) without the aforementioned effect of airflow restriction to lower drum pressure. In such configuration, the controlled drum inlet path 361 is “tight”. Alternative embodiments are contemplated wherein the sealing of housing 241, of the components creating the controlled drum inlet path 361 (i.e. a tight seal between the heat exchanger 291 and back panel 252), and of other components of clothes dryer 240 be somewhat less perfect. In other words, the preferred embodiment contemplates that clothes dryer 240 incorporate all measures available to restrict airflow into drum 273 to the controlled drum inlet path 361 where its flow into drum 273 can be restricted, as desired (i.e. by the flow restricting configuration of the heat exchanger 291), to lower the gas pressure in drum 273. However, alternative embodiments include those where, for example, the controlled drum inlet path 361 is tight, but the housing is not tightly sealed so that air can enter housing 241. In such configuration, air may “leak” from within housing 241 and into drum 273 between the opposing annular drum edges 278 and 281 and the mating annular surfaces 279 and 282. Or, the housing may be tightly sealed, but the controlled drum inlet path 361 may not be “tight”. In either case, the restriction to airflow through the airflow restrictor means (the heat exchanger 291) will still have a significant effect in lowering the gas pressure in drum 273 and thus on reducing the energy needed to dry the clothes.
Alternative embodiments are contemplated wherein other structure provides the desired closed, airflow conduit that extends between the airflow inlet 351 of dryer housing back panel 255 and the airflow inlet 352 of the drum 273. For example, the airflow inlet of the dryer housing 241 may be located anywhere in the housing walls (i.e. not directly aligned with the inlet airflow inlet path to heat exchanger 291, as seen in
In this embodiment, the housing back panel 255 and rear drum mounting plate 262, as well as heat exchanger mounting plate 358, are shown to be relatively planar, but alternative configurations are contemplated where any of these components are non-planar, and the size, configuration and assembly of such components still creates the controlled drum inlet path 361 restricting airflow entering housing inlet 351 to travel only to and through drum inlet 352.
Referring to
In another embodiment, heat exchanger 291 has a double bank pattern, but instead of a crossover pattern, it has a down and up pattern. That is, the tubing snakes from an inlet all the way at the top (such as at one of the tubing inlets 372 of the double crossover pattern), down to the bottom (such as at tubing outlet 373) where it crosses over to the front bank 368 (such as at the other tubing outlet 374), and back up to an outlet at the top (such as at the other tubing inlet 375 of the double crossover pattern).
Each of the fins 343 is non-planar. That is, they are bent, preferably along parallel lines, such lines being generally aligned in the intended direction 376 of the airflow entering heat exchanger 291. The bending of each fin forms a wave pattern (as shown), which configuration contributes to the airflow restriction caused by heat exchanger 291. In one embodiment, the fins are packed between 8 and 12 fins per inch (measuring between opposing side walls 347 and 348, and preferably about 10 fins per inch.
Clothes dryer 240 may be originally constructed to include the various recited components (i.e. housing 241, drying compartment assembly 242, guide apparatus 243 air moving apparatus 244, heating apparatus 245, power means 246, control apparatus 247, etc.), or it may be constructed by retrofitting a standard clothes dryer (such as dryer 50 of
In the “timed” drying type of dryer, the user selects from one or more drying options, all of which ultimately are based on a preset “timed” drying cycle, the duration of which is set once the option is selected. That is, a user may turn a dial (for example) to select within a “towels” option or a “delicates” option. In the “towels” option, the dryer's heating element may be at full capacity, but in the “delicates” option, the heating element may be at only half capacity. In both cases, however, the location of the dial within the “towels” or “delicates” option will determine how long the dryer runs (i.e. how long the drum rotates and the dryer's fan motor pulls air through the heating element and drum chamber). In all cycle options, once the dial (or other user control) is released, the dryer will run for the time associated with whatever position the dial is set.
In the “automatic” type of dryer, the user may likewise select from a variety of different drying options, such as “towels”, “normal”, delicates”, etc., and the dryer's own control apparatus will sense ambient and/or operating parameters which may include one or more of: ambient air temperature, ambient relative humidity, temperature and humidity level in the drum, etc. The control apparatus will process such data, calculate the time necessary to dry clothes in the drum and, purportedly, will control the time of drum rotation and fan and heating element operation needed to dry the clothes.
In the present embodiment, control apparatus 247 is contemplated to either augment or replace the control apparatus of the underlying dryer 50, whether it be the “timed” or the “automatic” type of dryer.
In one embodiment where the control system of an automatic type of dryer, is augmented by control apparatus 247, the heating apparatus 245, guide apparatus 243 and/or air moving apparatus 244 are controlled by the control apparatus 247 separately from, but are tied into, as necessary, the underlying dryer's control apparatus. In one embodiment, control apparatus 247 includes a countdown timer or similar mechanical and/or electrical mechanism that has either a pre-set (a fixed-automatic setting) or a variable (variable-automatic setting) heater-on-time (HOT). The HOT begins with the dryer being started (at t=0) upon which action (1) the fan/blower motor 285 starts, which rotates the drum and runs fan/blower 283; and (2) heating element 296 turns on and pump 292 starts. Consequently, the fluid in the closed-loop fluid path 80 is heated (rapidly) by heating element 296 and circulated through closed-loop fluid path 80, which includes the path through the tubing 344 of heat exchanger 291; air is drawn in through housing inlet 351, through heat exchanger 291 (where it gains heat energy from fluid circulating in the closed-loop fluid path 80) and into drum 273 wherein the heat energy of the air is transferred to the water molecules in the clothes. The water molecules thus change state from liquid to gas and are removed by the airflow as it continues its journey out the drum 273, through the fan/blower 14 and out the exhaust tube 288.
Because the airflow is restricted before entering drum, the pull exerted by fan/blower 14 causes a reduced gas pressure in drum 273, and less energy is needed for the water molecules to change state from liquid to gas. It can also be said that for a given set of attendant parameters (ambient temperature, pressure and relative humidity, starting weight of clothes dry, starting weight of clothes wet, temperature of starting load of clothes wet, etc.), the reduced gas pressure in the drum permits such load of clothes—as opposed to the same load, but without the intentionally added restriction to airflow—to exhibit any one of the following or a combination of at least two of the following: (1) to be dried in the same time, but using less energy; (2) to be dried in the same time, but exhibit a lower average exit airflow temperature; (3) use the same amount of energy, but dry in less time; and (4) exhibit a lower average exit airflow temperature, but dry in less time.
The exit airflow temperature is the temperature taken somewhere in the exhaust tube 288, and the average exit airflow temperature is determined from sampled readings taken during a particular drying cycle.
As the dryer 240 continues to operate, the fluid in the closed-loop fluid path 80 heats, thus retaining energy. In a standard dryer, the typically metal inlet guide box 57, heating element 64, and to an even lesser extent, other nearby, typically metal components of dryer 50 will heat up during operation, as well. But, when the heat element 64 is turned off, box 57, element 64 and nearby components will quickly cool down toward ambient temperature—that is, lose the energy they obtained from heating element 64. The same can be said for the typically metal housing, tubing and other nearby components of dryer 240, except for the fluid within path 80, which includes that which is within the main heating chamber 328, pump 292, heat exchanger 291 and the various tubing 293. Such fluid constitutes a heat capacitor (generally referred to at 380), which stores energy generated from the heating element 296, and which has not yet been transferred to the airflow passing through heat exchanger 291. Thus, as dryer 240 operates, the temperature of the fluid in path 80 rises to a generally steady state level, at which point the fluid (the “heat capacitor”) has a level of stored energy.
In one embodiment, the fluid contained and circulated within heat capacitor 380 is a liquid such as Paratherm NF, or a similar liquid that is preferably non-fouling and non-toxic, commercially available (such as from Paratherm Corporation, 4 Portland Road, West Conshohocken Pa. 19428 USA). Such liquid (like Paratherm NF) should have a specific heat capacity considerably less than water. Water has a specific heat capacity of 1.0 Btu/lb-° F., while Paratherm NF has a value of about 0.475 Btu/lb-° F., which enables the liquid to retain significantly more heat energy and to deliver such heat energy in the later stages of the drying cycle after the heating element 296 has been turned off. In this embodiment, the heat capacitor of closed-loop fluid path 80 holds about 600 ml of liquid. Alternative embodiments are contemplated wherein heat capacitor 380 holds more or less liquid, as desired, to “tune” the operation of clothes dryer 240. That is, as described below, the heat energy retained in heat capacitor 380 is withdrawn in later stages of the drying cycle, after heating element 296 is turn off.
After the heater-on-time (HOT) has elapsed, the heating element 296 is turned off by the countdown timer (or other mechanical and/or electrical device), but the other dryer components continue to operate. Thus, drum 273 continues to rotate; fan/blower 283 continues to pull air through drum 273—at a reduced pressure; and the pump 292 continues to circulate the liquid in heat capacitor 380 through the closed-loop fluid path 80, including through heat exchanger 291 where energy continues to be imparted to the air flowing therethrough. The retained heat energy in heat capacitor 380 gradually diminishes as its temperature asymptotically approaches ambient temp. During this stage of energy withdrawal from heat capacitor 380, no energy is being used by heating element 296, but sufficient energy is still being delivered to the clothes in drum 273. And, because the gas pressure in drum 273 is intentionally lowered by the airflow restriction of the heat exchanger 291 and/or other airflow restricting elements, the heat energy imparted by the slowly cooling heat capacitor 380 continues to effectively dry the clothes.
Effective and efficient drying is thus achieved by starting the dryer (at t=0), which starts heating element 296, pump 292 and drum/fan motor 285 and, after the heat-on-time has elapsed, turning the heating element 296 off, while leaving the drum/fan motor 285 and fluid pump 292 on. During this secondary heat recovery stage (recovering the heat energy stored in heat capacitor 380), little additional energy is used (just that necessary to run the pump 292 and drum/fan motor 285 which, in one embodiment, is only about 6.25 watts. Dryer 240 is then stopped either manually, after a pre-set secondary energy recovery time, or upon sensing the state, for example, between 1.0% and 2.0% remaining moisture content (“RMC”), as provided in the corresponding government regulations for dryers under 10 CFR 430 Subpart B, Appendix D, D1 and D2. In one embodiment, for a load of clothes weighing about 8.0 lbs. with about 54% added moisture content, the heater-on-time is between about 30 and 40 minutes. With the heating element 296 turned off and the drum and fan continuing to run, the load of clothes is dried to where the remaining moisture content (“RMC”) is between about 1.0% and 2.0% in about an additional 10 minutes or less. In a preferred embodiment, the heater-on-time is between about 34 and 38 minutes, and the same load is dried to between about 1.0% and 2.0% RMC in about an additional 10 minutes or less.
Clothes dryer 240 may also be provided with an expansion chamber 400. Like expansion tank 100 of dryer 10 (
In assembly, a vacuum is pulled on the closed-loop fluid path 80. Closed-loop fluid path 80 is then charged with the desired amount of liquid (i.e. about 600 ml of Paratherm NF) to a pressure of about 1.0 psig. Pressure relief valve 406 is set at about 5.0 psig. While the present embodiment includes two pressure relief valves (pressure relief valve 312 connected with heater housing 295 and pressure relief valve 406 of expansion chamber 400), the invention contemplates that only one of the pressure relief valves would be necessary.
As used herein, the term “hydronic” (i.e. “hydronic clothes dryer 10”, “hydronic clothes drying system 170”, “closed-loop hydronic fluid path 80”, “hydronic heater 76”, “hydronic heater 227”, etc.) contemplates water (the initial fluid in the closed-loop fluid path), as well as any other appropriate liquid, to be the fluid circulated in a closed-loop fluid path to transfer heat to the airflow passing through the heat exchanger to dry clothes placed within the dryer's drum. It was later learned that liquids having a lower specific heat capacity (such as Paratherm NF) provided improved performance. In view of this combination of heat generated by an electric resistance heat element, which heat is then transferred via a closed-loop fluid (liquid) path with heat exchanger to the airflow pulled into the drum, the invention is considered to more accurately be called a hybrid electric dryer.
Various inlet and outlet airflow velocities and volumetric flow rates have been suggested and postulated herein as contributing to and/or resulting from the airflow restriction of the present invention, but as noted herein, the most important operating characteristics are that, with a given fan/blower pulling air through the inlet and drum, an airflow restriction is intentionally introduced, between the drum and the housing inlet (or at the housing inlet) to restrict the airflow and lower the pressure in the drum.
While the invention has been illustrated and described in detail in the drawings and foregoing description, the same is to be considered as illustrative and not restrictive in character, it being understood that only the preferred embodiment and limited additional embodiments have been shown and described and that all changes and modifications that come within the spirit of the invention are desired to be protected. It is specifically intended that the present invention not be limited to the embodiments and illustrations contained herein.
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| PCT/US2015/024533 | 4/6/2015 | WO | 00 |
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| WO2015/154081 | 10/8/2015 | WO | A |
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